WO2010112410A1 - Polymerizable compositions - Google Patents

Abstract

The invention relates to the use of triazenes of formula (I) wherein Q is a direct bond or a bivalent radical -(CR₈R₉)-, Z₁ is -O-, -NR₁₀-, -CH₂-,-(CR₁₁R₁₂)- or -C(=O)- and R₁ to R₁₂ are optionally substituted hydrocarbon residues, as precursors for radicals useful in reactions triggered by free radicals, such as polymerization of unsaturated monomers and degradation of polyolefins. Most of the triazenes of formula (I) are novel and claimed, too, as well as the preparation of triazenes of formula (I) and polymerisable compositions comprising them.

Description

Polymerizable compositions

The invention relates to the use of triazene compounds as source of radicals (in particular as polymerization initiators), to polymerizable compositions comprising these triazenes and to new triazene compounds.

Free-radical polymerization belongs to the most important polymerization methods. It is used for preparing many commercially important polymers such as polystyrene, PVC, polyacrylates, polymethacrylates, PAN and other polymers. For technical details, reference may be made to the still relevant standard work G. Odian, Principles of Polymerization, McGraw-Hill New York 1991.

Free-radical polymerizations are started using initiators. Examples of initiators which have become established in polymer technology are azo compounds, dialkyl peroxides, diacyl peroxides, hydroperoxides, thermolabile C-C-dimers, redox systems and photoinitiators. Reference is made to the "Handbook of Free Radical Initiators", (ET. Denisov, T.G. Denisova, T.S. Pokidova, J. Wiley & Sons, Inc. Hobo- ken, New Jersey, 2003).

Despite their widespread use, the known polymerization initiators have various disadvantages. Thus, for example, peroxides are extremely readily ignitable and sustain fire and present thus potential explosion hazards, so that their manufacture, storage, transport and use has to involve costly safety precautions. Some initiators further generate toxic products, as e.g. AIBN.

There is therefore a general need for new initiators for free-radical polymerization processes which have a satisfactory safety profile.

WO 2001 / 90113 A1 , WO 2004/ 081 100A1 and WO 2006/051 047 A1 more recently disclosed sterically hindered N-acyloxyamines and N-substituted imides as new classes of polymerization initiators.

EP 09150183.3 (8.1.2009), which relates to isoureas as polymerization initiators, is a European patent application according to Art. 54(3) EPC and Rule 64.3 PCT. We have now developed specific triazene compounds which behave as efficient initiators of free radical polymerization or of other processes which are triggered off by free radicals, for example controlled the degradation of polyolefins. Though there is no duty for inventors to give any theoretical explanations, we believe that the mechanism of this action is due to the homolytical cleavage of the inventive triaze- nes which leads to polymerization effective free radicals according to the following equation:

The stimulus triggering the radical generation can be heat, infrared or near infrared radiation or visible light of a suitable wavelength. Photochemical and thermochemi- cal decomposition of triazenes each leading to free radicals have been reported by O. Nuyken et al. (Makromol. Chem. 194, 3385 [1993]) and K. Albert et al. (Bull. Chem. Soc. Jap. 49, 2537 [1976]), respectively.

Additionally, the stimulus triggering the radical generation can be a redox reaction induced by suitable redox-active species such as e.g. ascorbic acid, glucose, hyd- roquinone or iron (II) sulphate. Such redox initiated decompositions of triazenes are described by V.Ya. Andakuskin et al. (Zh. Obsh. Khim. 26, 3789 [1956]).

The inventive polymerization effective triazenes are of formula

(I), wherein

Q is a direct bond or a bivalent radical -(CR₈Rg)-;

Zi is -O-, -NR10-, -CH₂-, -(CR11R12)- or -C(=O)-, preferably -(CR11R12)-; Ri and R2 are each independently from the other Ci-C6A_Lκyl, or Ri and R2 are together C₄-C₇A_Lκylene, thus forming a preferably 5-, 6-, 7- or 8-membered cyclic group with the C-atom to which they are attached;

R₃ and R₄ are each independently from the other Ci-C₆A_Lκyl, or R₃ and R₄ are to- gether C₄-C₇A_Lκylene, thus forming a preferably 5-, 6-, 7- or 8-membered cyclic group with the C-atom to which they are attached;

R₅ and R₆ are each independently from the other H, Ci-C₆A_Lκyl, C₆-Ci₀aryl or C₇-Ci₂arA_Lκyl, or R₅ and R₆ are together oxygen, thus forming a carbonyl group together with the C-atom to which they are attached;

R₇ is C₆-C₂₄aryl, C₇-C₂₄arA_Lκyl, Ci-C₂₄heteroaryl or C₂-C₂₄heteroarA_Lκyl;

R₈ and R₉ are each independently from the other H or Ci-C₆A_Lκyl;

R10 is hydrogen, Ci-C₆A_LKyl, C₆-Ci₀aryl or -O-C(=O)-Ri₃;

R11 is hydrogen or Ci-C₆A_Lκyl;

Ri2 is Ri4,

CN, OH, ORi₄, NH₂, NHR₁₄, NR₁₄R₁₅, O-C(=O)-R₁₆, NH-C(=O)-R₁₆ or NR₁₄-C(=O)-R₁₆, preferably OH, OR₁₄, NH₂, NHR₁₄, NR₁₄R₁₅, O-C(=O)-R₁₆, NH-C(=O)-R₁₆ or NR₁₄-C(=O)-R₁₆;

or R₁₁ and R₁₂ are together C₂-C₂oA_Lκylene which is uninterrupted or once or twice interrupted by -O- and/or -NR₁₇-, thus forming a preferably 5- or 6-membered ring with the C-atom to which they are attached, which C₂-C₂oA_Lκylene can optionally be annelated with benzo or naphtho, and which C₂-C₂₀A_Lκylene is further unsubstituted or substituted by 1 or 2, identical or different groups -OH or -O-C(=O)-R₁₃;

R₁₃ is H, R₁₈, OR₁₈, NR₁₈R₁₉, COOR₂₀, R₂₁-COOR₂₀ or R₂₂(-COOR₂₀)-COOR₂₃;

R₁₄ and R₁₅ are each independently from the other C₁-C₆ALKyI, C₇-C₁₂arA_Lκyl or C₆-C₁₀aryl; - A -

or Ri₄ and Ri₅ are together C₂-C6Aι_κylene which is uninterrupted or once or twice interrupted by -O- and/or -NRi₇-, thus forming a preferably 5- or 6-membered ring with the N-atom to which they are attached;

Ri6 is H, Ri8, OR18, NRi₈Ri9, COOR₂₀, R21-COOR20 or R₂₂C-COOR₂O)-COOR₂₃;

Ri₇ is H or Ci-C₆A_LKyl;

R18 and Rig are each independently from the other Ci-C₃6A_Lκyl, C₂-C₅₄A_Lκenyl, C₂-C₂₄A_LKinyl, C₆-Ci₀aryl, C₇-C₄₆arA_LKyl or C₂-C36A_Lκenylene-C₆-Cioaryl;

or R18 and R19 are together C₂-C₃6A_Lκylene or C₂-C₅₄A_Lκenylene which is uninterrupted or once or twice interrupted by -O- and/or -NRi₇-, thus forming a preferably 5- or 6-membered ring with the N-atom to which they are attached;

R₂i is Ci-Ci₂A_Lκylene, C₂-Ci₂A_Lκenylene, C₂-Ci₂A_Lκinylene, C₆-Ci₀arylene, C₇-Ci₈arA_Lκylene or C₂-C₁₈ALKenylene-C6-C₁₀arylene;

R₂₂ is Ci-Ci₂A_Lκantriyl, C₂-Ci₂A_Lκentriyl, C₃-Ci₂A_Lκintriyl, benzotriyl, naphthotriyl, C₇-Ci₈benzoA_Lκantriyl, Cn-C₂₂naphthoA_Lκantriyl, C₂-Ci₂A_Lκantriyl-C₆-Ci₀arylene, C₂-Ci₂A_Lκenylene-benzotriyl, C₂-Ci₂A_Lκenylene-naphthotriyl or C₂-C₁₂Aι_κentriyl- C₆-Ci₀arylene;

each R₂₀ or R₂₃ stands independently from any other R₁, R₂, R₃, R₄, R₅, Re, R7, Rn, R18, Ri9, R20 or R₂₃ for H, R₁S, OR₁S, NRΪSRΪΘ, COOR₂O, R₂₁-COOR₂O,

A_LK stands for a linear or once or several times branched and /or mono- or poly- cyclic hydrocarbon residue including spiro residues, in which hydrocarbon residue one or more -CH₂- groups may be replaced by -S- or -NH-, one or more -CH groups may be replaced by -N and /or one or more non-adjacent -CH₂- groups may be replaced by -O-;

each hydrocarbon residue A_LK in R₁, R₂, R3, R4, R5, Re, R7, Rs, Rg, R10, Rn, RM, Ri5, Ri7, R18, Rig, R21 and R₂₂ is independently from all others unsubstituted or substituted by one or more identical or different substituents selected from the group consisting of Br, Cl, F, I, NO₂, OR₂₄, SR₂₄, SCN, CN, N(R₂₄)R₂₅, N(R₂₄)-C(=O)-R₂₅, N(R₂₄)-COOR₂₅, N(COR₂₄)COR₂₅, COOR₂₄, C00^~[l M^m+], COR₂₄, O-C(=O)R₂₄, C(=O)NR₂₄R₂₅, O-C(=O)N R₂₄R₂₅, SO₃H, SO₃ ^~[± M^m+], SO₂NR₂₄R₂₅, S(=O)R₂₄, SO₂R₂₄ and P(=O)(OR₂₄)OR₂₅;

R₂₄ and R₂₅ are each independently from any other H, Ci-Ci₈alkyl, C₇-Ci₈aralkyl, C₆-C₂₄aryl or Ci-C₂₄heteroaryl;

or R₂₄ and R₂₅ are each independently from any other H, Ci-Ci₈alkyl, C₇-Ci₈aralkyl, C₆-C₂₄aryl or Ci-C₂₄heteroaryl, and R₂₄ and R₂₅ are additionally bound together through a direct bond or bridged over a O, S, NH, N-Ci-Ci₈alkyl, N-C₇-Ci₈aralkyl, N-C₆-C₂₄aryl or N-Ci-C₂₄heteroaryl bridge;

M^m+ is an organic or inorganic cation;

m is 1 , 2, 3 or 4; and n is 1 , 2, 3 or 4, preferably 1 or 2.

The residue 'A_Lκ' is instantly used instead of 'alk' or 'cycloalk' in combination with standard IUPAC terminology except for the optional oxa-, thia- or aza-substitution being omitted, depending on its number of free valences and eventual presence of double or triple bonds, 'A_Lκene' standing for residues comprising one or more double bonds as well as optionally single bonds however excluding aromatic residues and 'A_Lκine' standing for residues comprising one or more triple bonds as well as optionally single and /or double bonds, the maximal number of double and triple bonds in said residue 'A_Lκene' or 'A_Lκine' being totally no more than one half of the number of C atoms in said residue 'A_Lκene' or 'A_Lκine'.

C₆-C₂₄Aryl, C₇-C₂₄arA_Lκyl, Ci-C₂₄heteroaryl and C₂-C₂₄heteroarA_Lκyl can be mono- or polycyclic, condensed or conjugated, or two or more aromatic or heteroaromatic groups may be bridged with an alkylene group. C₆-C₂₄Aryl, C7-C₂₄arA_Lκyl, Ci-C₂₄he- teroaryl or C₂-C₂₄heteroarA_LKyl are for example phenyl, benzyl, naphthyl, indyl, in- denyl, fluorenyl, acenaphthyl, biphenylyl, anthracyl, o-, m- or p-terphenyl.

NR₂₄R₂₅ is for example dimethylamino, diethylamino or dibutylamino, or, when R₂₄ and R₂₅ are additionally bound together through a direct bond or over a bridge, further morpholino, pyrrolidino, piperidino, 4-methyl-1-piperazinyl or carbazol-9-yl.

The maximal number of substituents in each hydrocarbon residue A_Lκ is equal to the number of hydrogens which can be substituted. For example, it is possible part or all hydrogens to be substituted, such as in trifluoromethyl, 2,2,2-trifluoroethyl or perfluoropentyl. There can, however, also be different substituents on the same hydrocarbon residue A_Lκ-

In bivalent and trivalent groups, the valences can be in any position. For example, phenylene is o-, m-, or p-Cβl-U, and in alkylene or alkanetriyl the valences may be geminal, terminal or in any other intermediate position.

M^m+ is for example a Na⁺, K⁺, Ca²⁺, Mg²⁺, Al³⁺, AICI²⁺, AIOH²⁺, Zr⁴⁺, ZrO²⁺, NH₄ ⁺, N⁺(Ci-C₂₄alkyl)₄ or any other inorganic, organometallic or organic cation. The

.m+ . nature of M is not essential for the performance of the instant compounds.

The inventive compounds of formula (I) are prepared, for example, in close analogy to known methods, such as:

• Coupling amines with diazonium salts for example according to the conditions disclosed by J. Benson ("The high nitrogen compounds", J. Wiley and Sons [1984]), L. Lunazzi et al. (J. Chem. Soc. Perkin II, 686-691 [1978]) or Ch. S. Rondestvedt and S. J. Davis (J. Org. Chem. 200-203 [1957]):

the diazonium salts being most conveniently prepared through diazotation of aromatic or heteroaromatic amines as described by, e.g., H. Zollinger ("Diazo- chemistry I", VCH [1994]).

Examples of suitable amines are aniline; o-, m-, p-chloro-aniline; o-, m-, p-nitro- aniline; o-, m-, p-carboxy-aniline; o-,m-,p-methoxycarbonyl-aniline; p-sulfoaniline; p-aminosulfonyl-aniline; 2,5-dichloro-aniline; 2-methyl-5-chloro-aniline; 2-nitro- 4-chloro-aniline; 2-nitro-4-methyl-aniline; 2-nitro-4-methoxy-aniline; 2-methoxy- 4-nitro-aniline; 2-trifluoromethy-4-chloro-aniline; 2,5-bis(methoxyacarbonyl)-ani- line; 2,4,5-trichloro-aniline; 4-carbamoyl-aniline; 2-methyl-5-carbamoyl-aniline; 2- chloro-δ-methylaminocarbonyl-aniline; 2-methoxy-5-phenylaminocarbonyl-anili- ne; 2-methoxycarbonyl-5-(2,5-dichlorophenyl-amino)-carbonyl-aniline; 2,5-di- methoxy-5-methylaminosulfonyl-aniline; 3,3'-dichloro-benzidine; o-tolidine; o-di- anisidine; 2,2',5,5'-tetrachloro-benzidine; 2-sulfo-4-methyl-aniline; 2-sulfo-4-me- thyl-5-chloro-aniline; 2-sulfo-4-chloro-5-carboxy-aniline; 2-sulfo-4-chloro-5-me- thyl-aniline; 1-sulfo-2-amino-naphthalene; 2-amino-thiazole; 2-amino-5-bromo- thiadiazole; 2-amino-5-ethyl-1 ,3,4-thiadiazole; 2-amino-5-methyl-1 ,3,4-thiadiazo- Ie; 2-amino-5-t-butyl-1 ,3,4-thiadiazole; 2-amino-5-ethylthio-1 ,3,4-thiadiazole; 2- amino-4,5-dicyano-1 H-imidazole; 5-amino-1 ,3-diphenyl-pyrazole; 5-amino-3- phenyl-1 ,2,4-thiadiazole and 2-amino-benzothiazole.

• Condensation of hydrazines with nitroso-aromates or nitroso-heteroaromates according to the general scheme disclosed, e.g., by R. K. Saksena and M. A. Khan (Indian J. Chem. 443-444 [1989]):

the hydrazines being most conveniently prepared as described, e.g., by W. D. Hinsberg, P. G. Schultz and P. B. Dervan (J. Am. Chem. Soc. 766-773 [1982]), and reacted with well known nitroso-aromates or nitroso-heteroaromates.

• Condensation of N-nitrosoamines with aminoaromates or amino-heteroaromates according to the general scheme disclosed, e.g., by L. M. Mironovich, V. K. Promonenkov and S. E. Bogushevich (Khimiya Geterotsiklicheskikh Soedinenii 6, 833-835 [1987]):

the N-nitrosoamines being most conveniently prepared in analogy to the proce- dure described, e.g., by W. D. Hinsberg, P. G. Schultz and P. B. Dervan (J. Am. Chem. Soc. 766-773 [1982]).

• Condensation of N-alkoxydiazenium salts with aminoaromates or amino-hetero- aromates according to the following general scheme:

wherein R₂₉ is Ci-C₃6A_Lκyl, C2-C₅₄A_Lκenyl, C2-C₂₄A_Lκinyl, C₆-Ci₀aryl,

C₇-C₄₆arA_Lκyl or C₂-C₃6A_Lκenylene-C6-Cioaryl, A is the anion of an inorganic, or- ganometallic or organic acid, and the N-alkoxydiazenium salts being most conveniently prepared and reacted with the amines in analogy to the procedure described, e.g., by G. V. Shustov, N. B. Tavakalyan, L. L. Shustova, I. I. Chervin and R. G. Kostyanovskii (Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya 5, 1058-1063 [1980])).

The compounds of formula (I) are used as polymerization initiators, polymerization auxiliaries or molecular weight modifiers in polymerizable compositions comprising at least one ethylenically unsaturated, polymerizable monomer or oligomer, prefe- rably in polymerizable compositions used for preparing coatings.

The compounds of formula (I) are further used as flame retardants, for example as disclosed in WO 05/030852, the contents of which are entirely incorporated herein by reference.

The invention therefore further provides a composition comprising (a) an ethylenically unsaturated, polymerizable monomer or oligomer and

(b) an effective, thermally or actinically radicals generating amount of a compound of formula (I).

The component (b) is most adequately used in the composition in a molar amount such that from 0.01 to 30, preferably from 0.05 to 10, particularly preferably from 0.1 to 1.0 triazene functional groups N-N=N-R₇ are present per 100 ethylenically unsaturated functional groups C=C of the polymerizable monomer or oligomer (a).

It is sufficient for the instant polymerization that each one of the components (a) and (b) are present. However, it is generally useful to use a mixture of more than one components (a), for example from 2 to 100 components (a). In particular, oligomers are usually mixtures of components having different molecular weights. More than one components (b) can also advantageously be used, for example from 2 to 100 components (b). When more than one components (b) are used, they can have similar or different reactivities, in the latter case enabling stepwise polymeri- sation. It is also possible to add further components (a) and /or (b) at any stage after the polymerization has been started.

Oligomers in the sense of the invention are compounds obtainable by linking together from 2 to about 50, preferably from 3 to 20 ethylenically unsaturated units, which compounds still comprise at least one ethylenically unsaturated double bonds and usually have a molecular weight of from 150 to 5000 Da.

Ethylenically unsaturated, polymerizable monomers or oligomers are generally known radically polymerizable compounds having at least one ethylenically unsaturated double bond, including monomers, prepolymers, oligomers and copolymers of any thereof. Non-limiting examples of such monomers include:

• ethylenically unsaturated polymerizable monomers selected from the group consisting of alkenes, conjugated dienes, styrenes, acrolein, vinyl acetate, vinylpyrrolidone, vinylimidazole, maleic anhydride, acrylic acid, acrylic acid derivatives, vinyl halides and vinylidene halides, such as ethylene, isoprene, 1 ,3-butadiene and α-C₅-Ci₈alkenes, styrene and styrenes substituted on the phenyl group by from one to three substituents selected from the group consisting of hydroxy, Ci-C₄alkoxy, e.g. methoxy or ethoxy, halogen, e.g. chlorine, amino and Ci-C₄alkyl, e.g. methyl or ethyl, such as methyl styrene, chloromethyl styrene, o-, m-, or p-hydroxystyrene;

• unsaturated carboxylic acids such as acrylic acid, methacrylic acid, crotonic acid, itaconic acid, maleic acid, or fumaric acid and salts, esters and amides thereof, as well as unsaturated fatty acids such as linolenic acid and oleic acid, acrylic and methacrylic acid being preferred; such unsaturated carboxylic acids optio- nally being used in admixture with saturated di- or poly-carboxylic acids, such as malonic acid, succinic acid, glutaric acid, adipic acid, sebacic acid, 1 ,4-cyclohe- xane dicarboxylic acid, tetrachlorophthalic acid, tetrabromophthalic acid, phthalic anhydride, tetrahydrophthalic acid, isophthalic acid, terepthalic acid, trimellitic acid, heptanedicarboxylic acid, dodecanedicarboxylic acid orhexahydrophthalic acid;

• unsaturated carboxylic acid esters derived from above-mentioned unsaturated carboxylic acids and mixtures of unsaturated carboxylic acids, wherein the esters are for example alkyl esters such as methyl, ethyl, 2-chloroethyl, N-dimethylami- noethyl, n-butyl, isobutyl-, pentyl, hexyl, cyclohexyl, 2-ethylhexyl, octyl, isobomyl or [2-exobomyl] esters; benzyl esters; phenyl, benzyl or o-, m- and p-hydroxy- phenyl esters; hydroxy alkyl esters such as 2-hydroxyethyl, 2-hydroxypropyl, 4-hydroxybutyl, 3,4-dihydroxybutyl or glycerol [1 ,2,3-propanetriol] esters; epoxy alkyl esters such as glycidyl, 2,3-epoxybutyl, 3,4-epoxy butyl, 2,3-epoxycyclo- hexyl or 10,11-epoxyundecyl esters; amino alkyl or mercapto alkyl esters; or po- lyfunctional esters as described below;

• unsaturated carboxylic acid amides derived from above-mentioned unsaturated carboxylic acids and mixtures of unsaturated carboxylic acids, wherein the amides groups may be similar as for above-mentioned esters, for example (meth)acryl amides or N-substituted (meth)acryl amides such as N-methylol- acrylamide, N-methylolmethacrylamide, N-ethylacryamide, N-ethylmethacryl- amide, N-hexylacrylamide, N-hexylmethacrylamide, N-cyclohexylacrylamide, N-cyclohexylmethacrylamide-, N-hydroxyethylacrylamide, N-phenylacrylamide, N-phenylmethacrylamide, N-benzylacrylamide, N-benzylmetacrylamide, N-nitrophenylacrylamide, N-nitrophenylmethacrylamide, N-ethyl- N-phenylacrylamide, N-ethyl- N-phenylmethacrylamide, N-(4-hydroxyphenyl)acrylamide, and N-(4-hydroxyphenyl)methacrylamide or IBMAA (N-isobutoxymethyl acryl- amide, or amides with aliphatic polyvalent amines;

• (Meth)acrylnitriles;

• unsaturated acid anhydrides such as itaconic anhydride, maleic anhydride, 2,3-dimethyl maleic anhydride or 2-chloromaleic anhydride;

• vinyl ethers such as isobutyl vinyl ether, ethyl vinylether, 2-chloroethyl vinylether, hydroxyethyl vinylether, propyl vinylether, butyl vinylether, isobutyl vinyl ether, octyl vinylether or phenyl vinylether;

• vinyl esters such as vinyl acetate, vinyl chloroacetate, vinyl butyrate and vinyl benzoate;

• vinyl chloride or vinylidene chloride;

• N-vinyl heterocyclic compounds, such as N-vinylpyrrolidone or suitably substituted vinylpyrrolidones, N-vinylcarbazol or 4-vinylpyridine;

• diacrylate esters such as 1 ,6-hexane diol diacrylate (HDDA), ethylene glycol diacrylate, propylene glycol diacrylate, tripropylene glycol diacrylate, neopentyl glycol diacrylate, hexamethylene glycol diacrylate and bisphenol A diacrylate;

• divinylbenzene, divinyl succinate, diallyl phthalate, triallyl phosphate, triallyl iso- cyanurate or tris(2-acryloylethyl) isocyanurate;

• esters of multifunctional alcohols, for example aromatic polyols such as hydro- quinone, 4,4'-dihydroxydiphenyl, 2,2-di(4-hydroxyphenyl)propane, novolaks or resols, or, especially, aliphatic and cycloaliphatic polyols including e.g. alkyle- nediols having preferably from 2 to 12 carbon atoms, such as ethylene glycol, 1 ,2- or 1 ,3-propanediol, 1 ,2-, 1,3- or 1 ,4-butanediol, pentanediol, hexanediol, octanediol, dodecanediol, diethylene glycol, triethylene glycol, polyethylene glycols having molecular weights of preferably from 200 to 1500, 1 ,3-cyclo- pentanediol, 1,2-, 1 ,3- or 1 ,4-cyclohexanediol, 1,4-dihydroxymethylcyclohexane, glycerol, tris(β-hydroxyethyl)amine, trimethylolethane, trimethylolpropane, penta- erythritol, dipentaerythritol and sorbitol, these polyols being optionally partially or fully esterified by one or by different unsaturated carboxylic acid(s), it being pos- sible for the free hydroxyl groups in partial esters to be modified, for example etherified, or esterified by other carboxylic acids; or esters of polyepoxides based on these polyols, especially from aromatic polyols and epichlorohydrin, as well as polymers and copolymers that contain hydroxyl groups in the polymer chain or in side groups, such as polyvinyl alcohol and copolymers thereof, polymetha- crylic acid hydroxyalkyl esters or copolymers thereof, or oligoesters having hydroxyl terminal groups; such as trimethylolpropane triacrylate, trimethylolethane triacrylate, trimethylolpropane trimethacrylate, trimethylolethane trimethacrylate, tetramethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetra- ethylene glycol diacrylate, pentaerythritol diacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, dipentaerythritol diacrylate, dipentaerythritol triacrylate, dipentaerythritol tetraacrylate, dipentaerythritol pentaacrylate, dipentaerythritol hexaacrylate, tripentaerythritol octaacrylate, pentaerythritol dimethacrylate, pentaerythritol trimethacrylate, dipentaerythritol dimethacrylate, dipentaerythritol tetramethacrylate, tripentaerythritol octamethacrylate, pentaerythritol diitaconate, dipentaerythritol trisitaconate, dipentaerythritol pentaitaconate, dipentaerythritol hexaitaconate, ethylene glycol diacrylate, 1 ,3-butanediol diacrylate, 1 ,3-butanediol dimethacrylate, 1 ,4-butanediol diitaconate, sorbitol triacrylate, sorbitol tetraacrylate, pentaerythritol-modified triacrylate, sorbitol tetramethacrylate, sorbitol pentaacrylate, sorbitol hexaacrylate, oligoester acrylates or methacrylates, glycerol di- or tri-acrylate, 1 ,4-cyclohexane diacrylate, bisacryla- tes or bismethacrylates of polyethylene glycol having a molecular weight of from 200 to 1500 Da, dipropylene glycol diacrylate, tripropylene glycol diacrylate, glycerol ethoxylate triacrylate, glycerol propoxylate triacrylate, trimethylolpropane ethoxylate triacrylate, trimethylolpropane propoxylate triacrylate, pentaerythritol ethoxylate tetraacrylate, pentaerythritol propoxylate triacrylate, pentaerythritol propoxylate tetraacrylate, neopentyl glycol ethoxylate diacrylate or neopentyl glycol propoxylate diacrylate; • non limiting examples of higher molecular weight (oligomeric) polyunsaturated compounds (also known as prepolymers) are esters of ethylenically unsaturated mono- or poly-functional carboxylic acids as described above and polyols or po- lyepoxides; polymers having ethylenically unsaturated groups in the chain or in side groups, such as unsaturated polyesters, polyamides and polyurethanes and copolymers thereof; alkyd resins; polybutadiene or butadiene copolymers, poly- isoprene or isoprene copolymers, polymers or copolymers having (meth)acrylic groups in side chains such as methacrylated urethanes or also mixtures of one or more such polymers; or

• aminoacrylates; or mixtures of any number of any thereof in any proportions, independently from their functionality, optionally in combination with further reactive components such as so-called aminoacrylates, that is, oligomers based on acrylates which has been modified by reaction with primary or secondary amines, as described, for example, by Gaske in US 3844916, by Weiss et al. in EP 0280222, by Meixner ef a/, in US 5482649 or by Reich et al. in US 5734002. Commercial aminoacrylates are, for example, Ebecryl^® 80, Ebecryl^® 81 , Ebecryl^® 83, Ebecryl^® P115, Ebecryl^® 7100 (UCB Chemicals), Laromer^® PO 83F, Laromer^® PO 84F, Laromer^® PO 94F (BASF), Photomer^® 4775 F, Photomer^® 4967 F (Cognis) , CN501 ™, CN503™ or CN550™ (Cray Valley).

Polymers, preferably coatings, may advantageously be prepared from the instant compositions. To prepare a polymer, preferably a coating, the components (a) and (b) of the formulation and optionally colourants and /or additives are applied uniformly to a substrate by means of known coating techniques, for example by spin- coating, immersion, knife coating, curtain pouring, brush application or spraying, especially by electrostatic spraying and reverse-roll coating, or also by electropho- retic deposition. The quantity applied (coating thickness) and the nature of the substrate (layer support) are dependent on the desired field of application. The coating thicknesses are generally comprised in the range of from 0.1 μm to more than 300 μm, though the coatings may if desired also be thicker, for example 1 - 5 mm. The wet coatings are then cured by polymerization as described below.

The instant coatings should be understood also to comprise printing inks (as long as wet) and prints (dry after curing).

Depending on their specific composition, the coatings can be applied as printing inks, liquid coatings, powder coatings or gelcoats on any desired substrate. Suitable are substrates of any kind, for example wood, textiles, paper, ceramics, glass, glass fibres, plastics such as polyester, polyethylene terephthalate, poly- olefins or cellulose acetate, especially in the form of films, and also metals such as Al, Cu, Ni, Fe, Zn, Mg, Co, GaAs, Si or SiO₂, to which there can be applied a protective or decorative layer, if desired by image-wise exposure and /or on an already existing coating, such as a primer.

The above-described compositions may further comprise customary additives, which may, as an alternative, also be added after the polymerization. Such additives can be added in usual small amounts, e.g. UV-absorbers or light stabilizers, e.g. compounds selected from the group consisting of hydroxyphenylbenzotri- azoles, hydroxyphenylbenzophenones, oxalamides and hydroxyphenyl-s-triazines. Particularly suitable light stabilizers are those selected from the group consisting of sterically hindered amines (HALS), e.g. of the 2-(2-hydroxyphenyl)-1 ,3,5-triazine or 2-hydroxyphenyl-2H-benzotriazole type. Examples of light stabilizers of the 2-(2- hydroxyphenyl)-1 ,3,5-triazine type are known for example from US-4, 619,956, EP 0434608, US-5,198,498, US-5,322,868, US-5,369,140, US-5,298,067, WO- 94/ 18278, EP 0704437, GB-2,297,091 or WO-96/28431.

The preferred colourants are pigments, especially organic pigments such as those listed in the Colour Index.

The compositions may further comprise other customary additives, e.g. fillers such as calcium carbonate, silicates, glass or glass fibre material, talcum, kaolin, mica, barium sulphate, metal oxides and hydroxides, carbon black, graphite, pulverized wood and pulverized or fibrous material from other natural products, synthetic fib- res, plasticizers, lubricants, emulsifiers, pigments, fluidizers, catalysts, optical brighteners, flame retardants, antistatics or blowing agents.

Hence, the invention also pertains to the use of the instant compounds of formula (I) to generate radicals in reactions triggered by the presence of radicals, as well as a process for preparing polymeric matter, preferably in the form of coatings, by using compositions comprising compounds of formula (I).

The invention further provides a process for preparing the above-described oligomer, cooligomer, polymer or copolymer by free-radical polymerization using the above-described compounds of formula (I).

Free radical polymerization includes thermal polymerisation, including thermal curing, IR-curing and NIR-curing, and /or UV polymerisation. Thermal curing refers to the application of convection heat or IR- or NIR-radiation after the mixture has been applied to the substrate. In case of powder coatings, the adhered powder coating is first melted to form a surface layer preferably by convection heat. Convection heat usually leads to temperatures of from 50°C to 250°C.

The NIR radiation used in the process according to the invention is short-wave infrared radiation in the wavelength range from about 750 nm to about 1500 nm, preferably from 750 nm to 1200 nm. Radiation sources for NIR radiation include, for example, conventional NIR radiation emitters, which are available commercially (for example, from Adphos).

The IR radiation used in the process according to the invention is medium wave radiation in the wave length range from about 1500 nm to about 3000 nm and /or longer-wave infra-red radiation in the wave length range above 3000 nm. Such IR radiation emitters are available commercially, too (for example, from Heraeus).

The invention further provides a generally applicable, inventive process for the controlled degradation of polyolefins wherein the compounds of formula (I) are used to lower the molecular weight of polyolefins, preferably polypropylene, pro- pylene copolymers or polypropylene blends.

In the instant degradation process, the compounds of formula (I) are adequately incorporated into the polyolefin to be degraded in concentrations of from about 0.001 to 5.0% by weight, preferably from 0.01 to 2.0% by weight and particularly prefe- rably from 0.02 to 1.0% by weight, based on the total weight of the polyolefin to be degraded. Such amounts are effective for desirably reducing the molecular weight. The compounds of formula (I) can be added as individual compounds or as mixtures to the polyolefin to be degraded.

The polyolefin-type polymers to be degraded encompass in particular propylene homopolymers, propylene copolymers and polypropylene blends. Propylene copolymers may be build up from olefin mixtures comprising propylene and various proportions of comonomers, generally up to 90% by weight, preferably up to 50% by weight of comonomers, based on the olefin mixture. Examples of comonomers are olefins such as 1 -olefins, e.g. ethylene, 1-butene, isobutylene, 1-pentene, 1-hexe- ne, 1-heptene or 1-octene; cycloolefins, e.g. cyclopentene, cyclohexene, norbome- ne or ethylidenenorbome; dienes such as butadiene, isoprene, 1 ,4-hexadiene, cyc- lopentadiene, dicyclopentadiene or norbomadiene; acrylic acid derivatives; or unsaturated carboxylic anhydrides such as maleic anhydride.

Polypropylene blends which can be used are mixtures of polypropylene with poly- olefins. Examples are blends of polypropylene with polyethylenes such as high density polyethylene (HDPE), high molecular weight high density polyethylene (HMW HDPE), ultra high molecular weight high density polyethylene (UHMW HDPE), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), branched low density polyethylene (BLDPE) or ethylene-propylene-diene terpolymers (EPDM) containing small proportions of diene.

Incorporation into the polymers can be carried out, for example, by mixing the compounds of formula (I) or mixtures thereof and, if desired, further additives into the polymers using the methods customary in process technology. lncorporation can, alternatively, also be carried out at temperatures which do not yet cause decomposition of the polymers (latent compound). The polymers prepared in this way can subsequently be heated a second time and subjected to an elevated temperature for a sufficient period of time so that the desired polymer degradation occurs.

Preferably, Ri, R₂, R3 and R₄ are each independently from the other Ci-C₆A_Lκyl, especially methyl or ethyl, and R₅ and Re are each independently from the other H or Ci-C₆A_Lκyl, especially H, methyl or ethyl. Most preferred, the total number of C atoms in R₁, R₂, R3 and R₄ is at least 5, preferably at least 6. More preferably, these preferred scopes may be combined with other preferences disclosed herein, such as n = 1 or n = 2.

Further preferred are the triazenes

Ri, R2, R3 and R₄ are each independently from the other C₁-C₄ALKyI;

R₆ and R₁₁ are each independently from the other H or C₁-C₄ALKyI;

R₇ is C₆-C₁₄aryl or d-C₁₂heteroaryl;

R₁₆ is H, R₁₈, OR₁₈, NR₁₈R₁₉, R₂₁-COOR₂₀, R₂₁-CON(R₂₀)R₂₇, R₂₂(-COOR₂₀)-COOR₂₃ or R₂₂(-CON(R₂₀)R₂₇)-CON(R₂₃)R₂₈;

R₁₈ and R₁₉ are each independently from the other C₁-C₃₆A₁KyI, C₂-C₅₄A_Lκenyl, C₆-C₁₄aryl, C₇-C₄₆arA_Lκyl or C₂-C₃₆A_Lκenylene-C₆-C₁₀aryl; or R₁₈ and R₁₉ are together C₂-C₃₆A_Lκylene or C₂-C₅₄A_Lκenylene which is uninterrupted or once or twice interrupted by -O-, -NH- and/or -N(Ci-C₄A_Lκyl)-, thus forming a preferably 5- or 6-membered ring with the N-atom to which they are attached;

each R₂₀ or R₂₃ stands for H, Ri₈, ORi₈, NRi₈Ri₉, COOR₂₀, R₂I-COOR₂₀,

R₂₂(-COOR₂₀)-COOR₂₃ or

R₂i is Ci-Ci₂A_Lκylene, C₂-Ci₂A_Lκenylene, C₆-Ci₀arylene or C₂-Ci₂A_Lκenyle- ne-C₆-Ci₀arylene;

R₂₂ is Ci-Ci₂A_Lκantriyl, C₂-Ci₂A_Lκentriyl, benzotriyl, C₇-Ci₈benzoA_Lκantriyl, C₂-Ci₂A_Lκantriyl-C₆-Ci₀arylene, C₂-Ci₂A_Lκenylene-benzotriyl or C₂-Ci₂A_Lκentriyl- C₆-Ci₀arylene;

R₂₆ is O, NH or N(Ci-C₄A_LKyl);

R₂₇ and R₂₈ are each independently from the other H, Ci-C₂₄alkyl, C₇-C₂₄aralkyl, C₆-C₂₄aryl or Ci-C₂₄heteroaryl;

n is 1 or 2; and

A_LK is an unsubstituted or substituted hydrocarbon residue as defined above.

In formula (lie), Rn is preferably bound to Ci-C₄A_Lκyl in geminal position, thus forming a spiro compound which optionally may form further fused or spiro rings when R₁₁ is cyclic.

Most preferred are the triazenes of formulae (Ha), (lib) or (lie), wherein Ri, R₂, R₃ and R₄ are independently from each other methyl or ethyl, R₆ is H or methyl and n is 1 or 2.

The above-mentioned preferred compounds are of course also preferred as com- ponents of the instant compositions and for use in the instant polymerization and degradation processes or as flame retardants.

The triazenes of formula (I) are novel with only the following few exceptions:

Hence, the invention also pertains to a compound of formula (I), with the proviso

that the triazene of formula (I) is not of formula

Though the compounds excluded by above proviso are neither novel nor preferred, they can also be used as polymerization or degradation initiators according to the invention.

The compounds of formulae (I), (Ha), (lib) or (lie) can also very advantageously be used in replacement for the sterically hindered N-acyloxyamines and N-substituted imides of WO 2001 /90 113A1 , WO 2004/081 100A1 and WO 2006 /051 047 A1 , the entire contents of which are incorporated herein by reference, according to the procedures disclosed therein.

The examples which follow illustrate the invention, without limiting it ("%" are by weight where not otherwise specified):

Example 1 : 9.31 g Aniline is added to a mixture of 50 g ice and 29.4 ml aqueous HCI (32% w/w). Then, a solution of 6.90 g NaNO₂ in 30 ml water is slowly added while keeping the temperature between -5 and 0°C. To this solution, a cold (-5°C) solution of 15.7 g 2,2,6,6-tetramethyl-4-hydroxypiperidine in 30 ml water and 9.8 ml aqueous HCI (32% w/w) and a cold solution of 16 g NaOH in 40 ml water are slowly added sequentially while keeping the temperature in the range from -5 to 0°C. The thick brown suspension is allowed to warm up to 23°C and is then diluted with 100 ml dichloromethane. The organic phase is separated, evaporated and chro- matographed on silica gel with hexane-ethylacetate (2 : 1 ) to afford 17.4 g of 2,2,6,6-tetramethyl-1-phenyldiazenyl-piperidin-4-ol as a slightly yellow oil which solidifies on standing. A sample of this material is recrystallized from dichloro- methane-hexane to afford light yellow solid, m.p. 68-70°C.

MS: M⁺ = 261 (Ci₅H₂₃N₃O = 261.37);

¹H-NMR (CDCI₃, 300 MHz), δ (ppm): 7.4-7.1 (m, 5 ArH), 4.2-4.1 (m, 1 H), 2.03-1.4 (m, 4H), 1.72 s (2* CH₃), 1.43 (s, 2^χ CH₃). Example 2: 2.15 ml Benzoylchloride are dropwise added to a solution of 4.42 g 2,2,6,6-tetramethyl-1-phenyldiazenyl-piperidin-4-ol (see example 1 ) and 0.1 g 4-dimethylaminopyridine in 35 ml pyridine. The resulting mixture is stirred 4 hours at 23°C, then diluted with 300 ml ice-water. The precipitate is filtered off and re- crystallized twice from methanol to afford 4.43 g of benzoic acid 2,2,6,6-tetra- methyl-1-phenyldiazenyl-piperidin-4-yl ester as an off-white solid, m.p. 89-91 °C.

¹H-NMR (CDCI₃, 300 MHz), δ (ppm): 8.067-8.05 (d, J= 5.1 Hz, 1 ArH), 7.6-7.05 (m, 8 ArH), 5.5-5.4 (m, 1 H), 2.23-1.95 (m, 4H), 1.74 (s, 2^χ CH₃), 1.54 (s, 2^χ CH₃).

Example 3: 9.6 g Benzenediazonium tetrafluoroborate are added to a cold (0°C) solution of 18.3 g 2,6-diethyl-2,3,6-trimethyl-piperidine (prepared as described in WO 2000 /046202) in 100 ml dichloromethane. The solution is allowed to warm to 23°C within 10 hours, then further stirred at 23°C for 30 hours, washed with 1 M-HCI (2 x 100 ml) and evaporated. The brown oil is chromatographed on silica gel with hexane-ethylacetate (98 : 2) to afford 2.48 g of 2,6-diethyl-2,3,6-trimethyl-piperidin- 1-yl)-phenyl-diazene as a slightly yellow oil.

GC-MS: 4 closely spaced peaks each with M⁺ = 287 (Ci₈H₂₉N₃ = 287.45);

¹H-NMR (CDCI₃, 300 MHz), δ (ppm): 7.4-7.0 (m, 5 ArH), 2.9-0.6 (m, 24H).

Example 4: A mixture of concentrated HCI (30ml, 32%) and water (30ml) is char- ged into 100 ml three necked round bottomed flask followed by addition of p-To- luidine (1Og, 0.0.093mol). The mixture is cooled to 0 to 5 ⁰C and solution of sodium nitrite (11.2 g, 0.16 mol) in water (15 ml) is added into it while maintaining the temperature at 0 to 5 ⁰C. This reaction mixture is then slowly added into a solution of 2,2,6,6-tetramethyl-4-hydroxypiperidine (69 g, 0.44 mol) in acetonitrile (2000 ml) and the mixture is stirred at 0 to -5 ⁰C for 1h. The reaction mass is filtered and the mother liquor evaporated to dryness at 40 ⁰C. The solid residue is extracted with cyclohexane (500ml) and diethyl ether (800 ml). The extracts are decolorized with charcoal (25g) filtered through bed of celite and concentrated at 25 C to afford 6.Og of 2,2,6,6-Tetramethyl-1- (p-tolyl-diazenyl)-piperidine-4-ol as a yellow solid, m.p. 85-86 ⁰C.

¹HNMR (ppm, d₆-DMSO; 7.19 (d, J = 8.4, 2H), 7.12 (d, J = 8.4, 2H), 4.7 (broad s, 1 H), 3.93 (broad t, 1 H), 2.26 (s, 3H), 1.90 (m, 2H), 1.59-1.53 (s, 8H), 1.35 (s, 6H). MS (275, M⁺)

Example 5: A mixture of concentrated HCI (15 ml, 32%) and water (15 ml) is charged into 100 ml three necked round bottomed flask followed by addition of 4-nitro- aniline (5g, 0.04 mol). The mixture is cooled to 0 to 5 ⁰C and solution of sodium nitrite (4.14 g, 0.06mol) in water (5 ml) is added into it while maintaining tempe-ra- ture 0 to 5⁰C. This reaction mixture is then slowly added into a solution of sodium tetrafluoroborate (6.6 g, 0.06mol) in water (60 ml) at 0 to 5 ⁰C. The resulting solution of diazonium tetrafluoroborate salt is then added to solution of 2,2,6,6-tetra- methyl-4-hydroxypiperdine (25.1g, 0.16mol) in acetonitrile (1000 ml) ) and the mixture is stirred at 0 to -5⁰C for 1h. This reaction mixture filtered and mother liquor is evaporated to dryness at 40 ⁰C. The residue is extracted with diethyl ether (200ml) the extract is decolorized with charcoal (50 g), filtered through bed of celite and concentrated to dryness to afford 0.56g of 2,2,6, 6-Tetramethyl-1-(4-nitrophe- nyldiazenyl)-piperidin-4-ol as a yellow solid, m.p. 108-110 ⁰C.

¹HNMR (ppm, d₆-DMSO); 8.20 (d, J = 8.8, 2H), 7.47 (d, J = 8.8, 2H), 4.80 (s, 1 H), 4.14 (broad t, 1 H), 1.98 (m, 2H), 1.62 (brad s, 8H), 1.42 (s, 6H). MS (306, M⁺)

Example 6: 50 g crushed ice are added to a solution of 2-bromoaniline in 4ml THF and 4ml aqueous HCI (32% w/w). The yellow suspension is diazotized at -5°C by treatment with a solution of 1.1 g sodium nitrite in 10 ml water. After 3 h, a solution of 2.76 g 2,2,6,6-tetramethyl-4-hydroxypiperidine in 1.5 ml aqueous HCI (32% w/w) and 1 ml THF are added dropwise to the thick yellow suspension at -3°C. Addition of water (ca. 20 ml) is necessary to keep the mixture well stirrable. The reaction mixture is then neutralized by adding dropwise 8.8 ml of aqueous sodium hydroxide (30% w/w) and 4 ml THF between 0 and 2°C The brownish mixture is extracted with ethyl acetate. The organic phase is separated, evaporated and chromatogra- phed on silica gel with hexane-ethylacetate (3 : 1 ), yielding 1.11 g of 1-(2-bromo- phenyl-diazenyl)-2,2,6,6-tetramethyl-piperidin-4-ol as a red-brown solid, m.p. 81 °C.

MS: M⁺ = 340/342 (Ci₅H₂₂Br N₃O = 340.26);

¹H-NMR (CDCI₃, 300 MHz), δ (ppm): 7.6-7.0 (m, 4 ArH), 4.2-4.1 (m, 1 H), 2.0-1.3 (m, 4H), 1.73 s (2* CH₃), 1.48 (s, 2^χ CH₃). Example 101 (polymerization of n-butyl acrylate): Materials_, and [.Methods

• All solvents and monomers are distilled under argon or under reduced pressure via a Vigreux column shortly before use.

• All reaction mixtures are freed of oxygen by purging with argon using the freeze/thaw technique and subsequently maintained under argon gas prior to the polymerization.

• The reactants are in the form of a clear homogeneous solution before commencement of the polymerization reaction.

• The monomer conversion is determined via ¹H-NMR by integrating the signals of the polymer and unreacted monomer.

• The polymers are characterized by GPC (gel permeation chromatography).

• GPC: a two-piston production model pump Rheos^® 4000 from Flux Instruments (represented by Ercatech AG, Bern, Switzerland) is used. The pump output is 1 ml/min. The chromatography is carried out on two Plgel 5 μm mixed-C columns (Polymer Instruments, Shropshire UK) connected in series at 40°C in THF. These columns are calibrated using polystyrene having M_n values in the range from 200 to 2000000. The fractions are measured using an Rl detector ERC-7515A (Ercatech) at 30⁰C.

130.7 mg of the compound according to example 1 and 6.41 g of n-butyl acrylate are placed in a 50 ml three-necked round-bottom flask provided with thermometer, condenser and magnetic stirrer and the mixture is degassed. The flask is immersed into an oil bath kept at 120°C. A rapid exothermic polymerization occurs. The clear solution is heated to 120°C for 5 hours under argon, then cooled to 23°C to afford poly-n-butylacrylate as a light yellow, hard resin. The polymer is insoluble in chloroform or tetrahydrofuran, indicating a quantitative polymerization though characterization via NMR or GPC is impracticable.

Examples 102-103: It is proceeded as in Example 101 , with the difference that the compound according to example 1 is replaced by the compounds according to Examples 2 and 3, respectively.

Example 104: (Polymerization of a coating composition)

The following unsaturated polymerizable composition is used (w/w %) Urethane-acrylate (Ebecryl 4858, UCB Chemicals / Cytec) 50% 1 ,6- Hexandiol diacrylate (UCB Chemicals / Cytec) 30%

Tripropylene glycol diacrylate (UCB Chemicals / Cytec) 20%

1 % of a compound (see Table 1) is dissolved in this composition and the resulting mixture is submitted to Differential scanning calorimetry (DSC) measurement. The activity of the tested compound is manifested by the exothermic curing reaction which is characterized by the Onset, Peak and Endset temperatures as well as the amount of heat liberated (exothermy).

The following DSC parameters are used:

Apparatus: DSC 30 (Mettler)

Temperature Gradient: 5 ° C / Min

Temperature Range: 30 - 300 ° C

Measurement under Nitrogen, flow rate 5ml / Min Sample amount: approx. 10 mg compound in an aluminum cup

The results summarized in the Table 1 show that no curing occurs with the blank formulation but that distinct exothemic curing is observed with the examples of the inventive compounds. Table 1:

Claims

Claims:

1. A composition comprising

(a) an ethylenically unsaturated, polymerizable monomer or oligomer and

(b) an effective, thermally or actinically radicals generating amount of a compound

of formula wherein

Q is a direct bond or a bivalent radical -(CR₈Rg)-;

Zi is -O-, -NR10-, -CH₂-, -(CR11R12)- or -C(=O)-, preferably -(CR11R12)-;

Ri and R2 are each independently from the other Ci-C6A_Lκyl, or Ri and R2 are together C₄-C₇A_Lκylene, thus forming a preferably 5-, 6-, 7- or 8-membered cyclic group with the C-atom to which they are attached;

R₃ and R₄ are each independently from the other Ci-C₆A_Lκyl, or R₃ and R₄ are together C₄-C₇A_Lκylene, thus forming a preferably 5-, 6-, 7- or 8-membered cyclic group with the C-atom to which they are attached;

R₅ and R₆ are each independently from the other H, Ci-C₆A_Lκyl, C₆-Ci₀aryl or C₇-Ci₂arA_Lκyl, or R₅ and R₆ are together oxygen, thus forming a carbonyl group together with the C-atom to which they are attached;

R₇ is C₆-C₂₄aryl, C₇-C₂₄arA_Lκyl, Ci-C₂₄heteroaryl or C₂-C₂₄heteroarA_LKyl;

R₈ and R₉ are each independently from the other H or Ci-C₆A_Lκyl;

R10 is hydrogen, Ci-C₆A_LKyl, C₆-Ci₀aryl or -O-C(=O)-Ri₃;

Rn is hydrogen or Ci-C₆A_Lκyl;

R12 is Ri,, C(=O)-Ri4, CN, OH, ORi₄, NH₂, NHRi₄, NRi₄Ri₅, O-C(=O)-Ri₆, NH-C(=O)-Ri6 or NRi₄-C(=O)-Ri₆, preferably OH, ORi₄, NH₂, NHRi₄, NRi₄Ri₅, O-C(=O)-Ri6, NH-C(=O)-Ri6 or NRi₄-C(=O)-Ri₆;

or Rn and Ri₂ are together C₂-C₂₀A_Lκylene which is uninterrupted or once or twice interrupted by -O- and/or -NRi₇-, thus forming a preferably 5- or 6-membered ring with the C-atom to which they are attached, which C₂-C₂oA_Lκylene can optionally be annelated with benzo or naphtho, and which C₂-C₂oA_Lκylene is further unsubstituted or substituted by 1 or 2, identical or different groups -OH or -O-C(=O)-Ri₃;

Ri3 is H, Ri8, ORi8, NRi₈Ri9, COOR₂₀, R₂I-COOR₂₀ or R₂₂(-COOR₂₀)-COOR₂₃;

Ri₄ and Ri₅ are each independently from the other Ci-C₆A_Lκyl, C₇-Ci₂arA_Lκyl or

or Ri₄ and Ri₅ are together C₂-C₆A_Lκylene which is uninterrupted or once or twice interrupted by -O- and/or -NRi₇-, thus forming a preferably 5- or 6-membered ring with the N-atom to which they are attached;

Ri6 is H, Ri8, ORi8, NRi₈Ri9, COOR₂₀, R₂I-COOR₂₀ or R₂₂(-COOR₂₀)-COOR₂₃;

Ri₇ is H or Ci-C₆A_LKyl;

Ri8 and Ri₉ are each independently from the other Ci-C₃6A_Lκyl, C₂-C₅₄A_Lκenyl, C₂-C₂₄A_LKinyl, C₆-Ci₀aryl, C₇-C₄₆arA_LKyl or C₂-C₃6A_Lκenylene-C₆-Ci₀aryl;

or Ri8 and Ri₉ are together C₂-C₃₆A_Lκylene or C₂-C₅₄A_Lκenylene which is uninterrupted or once or twice interrupted by -O- and/or -NRi₇-, thus forming a preferably 5- or 6-membered ring with the N-atom to which they are attached;

R₂i is Ci-Ci₂A_Lκylene, C₂-Ci₂A_Lκenylene, C₂-Ci₂A_Lκinylene, C₆-Ci₀arylene, C₇-Ci₈arA_Lκylene or C^CisALKenylene-Ce-Cioarylene;

R₂₂ is Ci-Ci₂A_Lκantriyl, C₂-Ci₂A_Lκentriyl, C₃-Ci₂A_Lκintriyl, benzotriyl, naphthotriyl, C₇-Ci₈benzoA_Lκantriyl, Cn-C₂₂naphthoA_Lκantriyl, C₂-Ci₂A_Lκantriyl-C₆-Ci₀arylene, C₂-Ci₂A_Lκenylene-benzotriyl, C₂-Ci₂A_Lκenylene-naphthotriyl or C₂-Ci₂A_Lκentriyl- C₆-Ci₀arylene;

each R₂O or R₂3 stands independently from any other R₁, R₂, R3, R4, R5, Re, R7, Rn, R18, Ri9, R20 or R₂3 for H, R₁S, OR₁S, NR₁₈R₁Q, COOR₂O, R₂₁-COOR₂O,

A_LK stands for a linear or once or several times branched and /or mono- or polycyclic hydrocarbon residue including spiro residues, in which hydrocarbon residue one or more -CH₂- groups may be replaced by -S- or -NH-, one or more -C^H groups may be replaced by -N and /or one or more non-adjacent -CH₂- groups may be replaced by -O-;

each hydrocarbon residue A_LK in R₁, R₂, R₃, R₄, R₅, Re, R7, Rs, Rg, R10, Rn, RM, Ri5, Ri7, R18, Rig, R21 and R₂₂ is independently from all others unsubstituted or substituted by one or more identical or different substituents selected from the group consisting of Br, Cl, F, I, NO₂, OR₂₄, SR₂₄, SCN, CN, N(R₂₄)R₂₅, N(R₂₄)-C(=O)-R₂₅, N(R₂₄)-COOR₂₅, N(COR₂₄)COR₂₅, COOR₂₄, COO^"[l ^|Vl^m+], COR₂₄, O-C(=O)R₂₄, C(=O)NR₂₄R₂₅, O-C(=O)N R₂₄R₂₅, SO₃H, SO₃ ^"[l ^|Vl^m+], SO₂NR₂₄R₂₅, S(=O)R₂₄, SO₂R₂₄ and P(=O)(OR₂₄)OR₂₅;

R₂₄ and R₂₅ are each independently from any other H, d-dsalkyl, C₇-C₁₈aralkyl, C₆-C₂₄aryl or d-C₂₄heteroaryl;

or R₂₄ and R₂₅ are each independently from any other H, d-dsalkyl, C₇-C₁₈aralkyl, C₆-C₂₄aryl or d-C₂₄heteroaryl, and R₂₄ and R₂₅ are additionally bound together through a direct bond or bridged over a O, S, NH, N-d-C₁₈alkyl, N-C₇-C₁₈aralkyl, N-C₆-C₂₄aryl or N-d-C₂₄heteroaryl bridge;

M^m+ is an organic or inorganic cation;

m is 1 , 2, 3 or 4; and n is 1 , 2, 3 or 4, preferably 1 or 2.

2. A composition according to claim 1 , wherein the effective, thermally or actinically radicals generating amount is such that from 0.01 to 30, preferably from 0.05 to 10, particularly preferably from 0.1 to 1.0 triazene functional groups N-N=N-R₇ are present in the compound (b) of formula (I) per 100 ethylenically unsaturated functional groups C=C of the polymerizable monomer or oligomer (a).

3. A triazene compound of formula (I) as defined in claim 1 , with the proviso that

the triazene of formula (I) is not of formula

4. A compound according to claim

(lib) or (lie), wherein

Ri, R2, R3 and R₄ are each independently from the other Ci-C₄A_Lκyl;

R₆ and Rn are each independently from the other H or Ci-C₄A_Lκyl;

R₇ is C₆-Ci₄aryl or d-Ci₂heteroaryl;

R16 is H, R18, OR18, NRi₈Ri9, R21-COOR20, R2i-CON(R₂₀)R27, R₂2(-COOR₂o)-COOR₂3 or R₂₂(-CON(R₂o)R₂₇)-CON(R₂₃)R₂8;

R₁8 and Rig are each independently from the other Ci-C₃6A_Lκyl, C₂-C₅₄A_Lκenyl, C₆-Ci₄aryl, C₇-C₄₆arA_Lκyl or C₂-C₃6A_Lκenylene-C6-Cioaryl; or Ri₈ and R19 are together C₂-C₃6A_Lκylene or C₂-C₅₄A_Lκenylene which is uninterrupted or once or twice interrupted by -O-, -NH- and/or -N(Ci-C₄A_Lκyl)-, thus forming a preferably 5- or 6-membered ring with the N-atom to which they are attached;

each R₂₀ or R₂₃ stands for H, Ri₈, ORi₈, NRi₈Ri₉, COOR₂₀, R₂I-COOR₂₀,

R₂₂(-COOR₂₀)-COOR₂₃ or

R₂i is Ci-Ci₂A_Lκylene, C₂-Ci₂A_Lκenylene, C₆-Ci₀arylene or C₂-Ci₂A_Lκenylene-C₆-Ci₀arylene;

R₂₂ is Ci-Ci₂Aι_κantriyl, C₂-Ci₂A_Lκentriyl, benzotriyl, C₇-Ci₈benzoA_Lκantriyl,

C₂-Ci₂A_Lκantriyl-C₆-Ci₀arylene, C₂-Ci₂A_Lκenylene-benzotriyl or C₂-Ci₂A_Lκentriyl- C₆-Ci₀arylene;

R₂₆ is O, NH or N(Ci-C₄A_LKyl);

R₂₇ and R₂₈ are each independently from the other H, Ci-C₂₄alkyl, C₇-C₂₄aralkyl, C₆-C₂₄aryl or Ci-C₂₄heteroaryl;

n is 1 or 2; and A_LK is an unsubstituted or substituted hydrocarbon residue as defined in claim 3.

5. A compound according to claim 3 or 4, wherein Z₁ is -(CR11R12)- and R12 is OH, ORi₄, NH₂, NHRi₄, NRi₄Ri₅, 0-C(=0)-Ri₆, NH-C(=O)-Ri₆ or NRi₄-C(=O)-Ri₆.

6. A compound according to claim 3, 4 or 5, wherein R₁, R₂, R₃ and R₄ are each independently from the other C₁-C₆ALKyI, especially methyl or ethyl, and R₅ and R₆ are each independently from the other H or C₁-C₆ALKyI, especially H, methyl or ethyl.

7. A compound according to claim 3, 4, 5 or 6, wherein the total number of C atoms in R₁, R₂, R₃ and R₄ is at least 5, preferably at least 6.

8. A process for the preparation of a compound according to claim 3, 4, 5, 6 or 7, wherein an amine is coupled with a diazonium salt, a hydrazine is condensed with a nitroso-aromate or a nitroso-heteroaromate, a N-nitrosoamine is condensed with an aminoaromate or an amino-heteroaromate, or a N-alkoxydiazenium salt is condensed with an aminoaromate or an amino-heteroaromate.

9. The use of a compound according to claim 3, 4, 5, 6 or 7 to generate radicals in a reaction triggered by the presence of radicals, or as a flame retardant.

10. The use of a composition according to claims 1 or 2 for preparing polymeric matter, preferably in the form of coatings, by free-radical polymerization.

11. A process for preparing oligomeric, cooligomeric, polymeric or copolymeric matter, preferably in the form of a coating, characterized in that a composition according to claims 1 or 2 is subjected to convection heat and /or to UV-, IR- or NIR-radiation.

12. A process for the controlled degradation of a polyolefin, preferably polypropylene, a propylene copolymer or a polypropylene blend, wherein a compound according to claim 3, 4, 5, 6 or 7 is used to lower the molecular weight of said polyolefin.