WO2010107142A1 - Method for producing an environmentally-friendly biodegradable container for exterminating cockroaches, and container - Google Patents

Method for producing an environmentally-friendly biodegradable container for exterminating cockroaches, and container Download PDF

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WO2010107142A1
WO2010107142A1 PCT/KR2009/001319 KR2009001319W WO2010107142A1 WO 2010107142 A1 WO2010107142 A1 WO 2010107142A1 KR 2009001319 W KR2009001319 W KR 2009001319W WO 2010107142 A1 WO2010107142 A1 WO 2010107142A1
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container
composition
biodegradable
environmentally
weight
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PCT/KR2009/001319
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French (fr)
Korean (ko)
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조규연
최은이
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Joh Kyu Yeon
Choi Eun Yi
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Priority to PCT/KR2009/001319 priority Critical patent/WO2010107142A1/en
Publication of WO2010107142A1 publication Critical patent/WO2010107142A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/12Making granules characterised by structure or composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/203Solid polymers with solid and/or liquid additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • C08L101/16Compositions of unspecified macromolecular compounds the macromolecular compounds being biodegradable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037Other properties
    • B29K2995/0059Degradable
    • B29K2995/006Bio-degradable, e.g. bioabsorbable, bioresorbable or bioerodible
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers

Definitions

  • the present invention relates to an environment-friendly biodegradable container manufacturing method and container for the fight against cockroaches,
  • PLA and PBS, PBSA, PBA any one selected from materials and biodegradable nanocomposite material is mixed to form a composition, and then added to the composition, butanediol, succinic acid and trifaniltostate after the polymerization process under reduced pressure and extruded pellets
  • the detoxifier is a place where the cockroach containing insecticides eats the food that the cockroach likes to eat, and the cockroach eats it to kill the cockroach. It is known that attractant dietary substances in which dietary substances and cockroaches are actively attracted are effective.
  • a attractant or attractant dietary substance attracted by cockroaches is mainly used in such a container.
  • ground products such as crude grains, blood, millet, buckwheat, corn, peanut, soybean, rice bran, pulverized powder or mixtures thereof
  • sake lees dried sake lees, semi-dried sake lees, bread crumbs, pupa flour, kina flour, starch and the like
  • 53-113027 Japanese Patent Publication No. 53-113027
  • food substances that are particularly attractive include starches such as sweet potatoes, taro and cornstarch, assortments such as flour, buckwheat flour, and rice flour, thin rivers such as rice bran and bran, and soybean forge Oils such as rice wine, starch rice, starch rice, beer rice wine, etc., by-products such as fish meal, meat meal, blood meal, soybean, pumpkin, carrot, etc. (Japanese Patent Laid-Open No. 60-54303) ), Milk, cheese, krill, powdered insect feed, bran, flour, wood flour or mixtures thereof (Japanese Patent Application Laid-Open No. 62-278930), Sesame Oil (Japanese Patent Laid-Open Publication No. 53-91140), Biscuits Crumb, cracker crumb, fishmeal, pupa powder, kina flour, flour, corn flour, sugar and the like (Japanese Patent Laid-Open No. 55-94302) and the like are known.
  • starches such as sweet potatoes,
  • examples of the attractant include fatty acid esters composed of fatty acids having 4 to 10 carbon atoms and polyhydric alcohols (Japanese Patent Laid-Open No. 48-58126), aromatic compounds having aromatic aromatic compounds such as aldehydes, ketones, phenols, alcohols, Amines, carboxylic acids or esters thereof (Japanese Patent Application Laid-Open No. 50-42053), residues without stimulating components from moth tar or acetic acid (Japanese Patent Laid-Open Publication No. 50-46842), non-reducing starch intermediate hydrolysates (Japanese Patent Japanese Patent Application Laid-Open No.
  • Attractable materials tend to be expensive in terms of unstable availability of raw materials and difficult manufacturing, which is not satisfactory in terms of practicality.
  • the cockroach catcher itself is made of a synthetic resin and there is a problem in terms of the environment when discarding. It is the most urgent task of our time to find a means to do this.
  • the present invention is an environment-friendly biodegradable cockroach eradication container manufacturing method and the container to solve the above problems,
  • the present invention composed of the above configuration is not only reduce the environmental load, because it is completely decomposed in a quick time in the natural state when discarded, because it produces anti-mold and antibacterial activity and phytoncide, even when installed in the kitchen or indoors when using the sanitary and beneficial benefits to the human body And, incineration does not generate toxic gases or smoke can bring a very environmentally beneficial effect.
  • FIG. 1 is a block diagram showing a method for producing a container for combating environmentally friendly biodegradable cockroach of the present invention.
  • PLA [30-30% by weight of PLA and 30-50% by weight of any material selected from PBS, PBSA, PBA, 10-20% by weight of the biodegradable nanocomposite material to form a composition;
  • FIG. 1 is a block diagram showing a method for producing a container for combating environmentally friendly biodegradable cockroach of the present invention.
  • composition by mixing 30 to 40% by weight of PLA and 30 to 50% by weight of any material selected from PBS, PBSA, PBA, 10 to 20% by weight of the biodegradable nanocomposite material;
  • the pellet is completed by the step of injection molding at a temperature of 170 ⁇ 190 °C.
  • the biodegradable resin PLA (Poly Lactic Acid, polylactic acid) is a polymer of a low molecular weight compound (monomer) present in the body, such as lactic acid, but does not exist in nature, PLA is generally hydrolyzed by water It is known to be degraded by microorganisms after low molecular weight and is widely used as an environmentally friendly raw material.
  • the PLA 30-40% by weight and also biodegradable resins PBS (polybutylene succinate, Poly butylene succinate), PBSA (poly butylene succinate adipate), PBA (polybutylene ate, Poly butylene adipate) Select any one of 30 to 50% by weight of the mixed and 10 to 20% by weight of the biodegradable nanocomposite material to form a composition,
  • butanediol, succinic acid, and trifanyltostate are added to any one selected from PBS, PBSA, and PBA.
  • Environmentally-friendly biodegradable cockroaches are subjected to the first 180-200 ° C. and the second 220-240 ° C. polymerization under reduced pressure. The container for combat is complete.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Catching Or Destruction (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a method for producing an environmentally-friendly biodegradable container for exterminating cockroaches, and to a container. More particularly, the present invention relates to a method for producing an environmentally-friendly biodegradable container for exterminating cockroaches, and also relates to the container, wherein said method comprises the steps of mixing one of PLA, PBS, PBSA, and PBA together with biodegradable nanocomposites to produce a composition, adding butanediol, succinic acid, and triphenyl phosphate to the composition, polymerizing the composition under reduced pressure, extruding and pelletizing the composition, and injection-molding the pellet. The thus-produced container is naturally and completely degraded in a short time in nature when discarded, thereby reducing the burden on the environment. As the container also has anti-fungal and anti-microbial activities, and emits phytoncide, it is not only sanitary and beneficial to the human body when installed in a kitchen or an indoor area, but also generates no toxic gases or smoke when incinerated.

Description

환경친화적 생분해성 바퀴벌레 퇴치용 용기제조방법 및 용기Eco-friendly biodegradable cockroach control method and container manufacturing
본 발명은 바퀴벌레 퇴치를 위한 친환경적인 생분해성 용기 제조방법 및 용기에 관한 것으로 구체적으로는, The present invention relates to an environment-friendly biodegradable container manufacturing method and container for the fight against cockroaches,
PLA와 PBS나 PBSA, PBA중 선택된 어느 한 소재와 생분해성 나노복합소재를 혼합하여 조성물을 형성한 다음, 상기 조성물에 부탄디올과 숙신산과 트리패닐토스테이트를 첨가 감압하에서 중합과정을 거친 후 압출하여 펠렛화하고 상기 펠렛을 사출성형함으로서 폐기시 자연상태에서 빠른 시간내에 완전분해되므로 환경부하를 줄일 뿐만 아니라 항곰팡이 및 항균력 발생 및 피톤치드를 발산하므로 사용시 주방이나 실내에 설치하더라도 위생적이고도 인체에 이로울 뿐만 아니라 소각시 유독가스나 연기가 발생되지 않는 환경친화적 생분해성 바퀴벌레 퇴치용 용기제조방법 및 용기에 관한 것이다.PLA and PBS, PBSA, PBA any one selected from materials and biodegradable nanocomposite material is mixed to form a composition, and then added to the composition, butanediol, succinic acid and trifaniltostate after the polymerization process under reduced pressure and extruded pellets By discharging the pellets and disintegrating the pellets within a short time in a natural state when disposing, it not only reduces the environmental load but also generates anti-mildew and antimicrobial activity and phytoncide, so it is not only hygienic and human-friendly even when installed in the kitchen or indoors. It relates to an environmentally friendly biodegradable cockroach control method and container that does not generate toxic gas or smoke upon incineration.
종래부터 바퀴벌레의 퇴치 또는 박멸에 관해서는 여러가지 연구가 이루어지고 있으며, 이중 바퀴벌레가 스스로 퇴치 또는 박멸수단 또는 용기에 접근하도록 하는 방법으로서, 식독제나 점착제가 설치된 용기를 이용하는 것이 대표적으로 알려져 있다.Background Art Conventionally, various studies have been made regarding the eradication or eradication of cockroaches. As a method for allowing the cockroaches to approach or eradicate the cockroaches by itself, it is known to use a container provided with an insecticide or an adhesive.
식독제(食毒劑)는 살충제를 함유시킨 바퀴벌레가 즐겨 먹는 음식물을 바퀴벌레가 출입하는 장소에 놓고, 이것을 바퀴벌레가 먹음으로써, 바퀴벌레를 사멸시키는 것인데, 이 살충제를 함유시키기 위한 식이(食餌)로서는 바퀴벌레의 식이 물질 및 바퀴벌레가 적극적으로 유인되는 유인성 식이 물질이 유효하다는 것이 알려져 있다.The detoxifier is a place where the cockroach containing insecticides eats the food that the cockroach likes to eat, and the cockroach eats it to kill the cockroach. It is known that attractant dietary substances in which dietary substances and cockroaches are actively attracted are effective.
점착제가 설치된 용기를 이용하는 경우에는 이러한 용기에 바퀴벌레가 유인되는 유인성 물질이나 유인성의 식이 물질을 주로 사용한다.In the case of using a container provided with an adhesive, a attractant or attractant dietary substance attracted by cockroaches is mainly used in such a container.
상기한 바와 같은 바퀴벌레의 식이 물질로서는 예컨대, 조, 피, 기장, 메밀, 옥수수, 낙화생, 대두, 쌀겨 등의 곡류, 두류 혹은 이들의 혼합물의 분쇄물(일본 특허 공개 소53-38626호 공보), 술지게미, 술지게미의 건조물, 술지게미의 반건조물이나 빵가루, 번데기 가루, 키나가루, 전분 등과의 병용(일본 특허 소53-113027호 공보)이 알려져 있다.As a dietary substance of the cockroach as described above, for example, ground products such as crude grains, blood, millet, buckwheat, corn, peanut, soybean, rice bran, pulverized powder or mixtures thereof (Japanese Patent Laid-Open No. 53-38626), The use of sake lees, dried sake lees, semi-dried sake lees, bread crumbs, pupa flour, kina flour, starch and the like (Japanese Patent Publication No. 53-113027) is known.
또 식이 물질 중에서도 특히 유인성이 있는 식이 물질로서는 고구마, 토란, 콘스타치 등의 전분류, 밀가루, 메밀가루, 쌀가루 등의 분류(粉類), 쌀겨, 밀기울 등의 박강류(粕糠類), 대두 지게미, 면실(綿實) 지게미 등의 유박류(油粕類), 전분 지게미, 맥주 지게미 등의 제조 지게미류, 어분, 육분, 혈분 등의 부산물, 대두, 호박, 당근 등(일본 특허 공개 소60-54303호 공보), 밀크, 치즈, 크릴 가루, 분말 곤충 사료, 밀기울, 밀가루, 목분 혹은 이들의 혼합물(일본 특허 공개 소62-278930호 공보), 참기름(일본 특허 공개 소53-91140호 공보), 비스켓 부스러기, 크래커 부스러기, 어분, 번데기 가루, 키나가루, 밀가루, 옥수수 가루, 설탕 등(일본 특허 공개 소55-94302호 공보) 등이 알려져 있다.Among the dietary substances, food substances that are particularly attractive include starches such as sweet potatoes, taro and cornstarch, assortments such as flour, buckwheat flour, and rice flour, thin rivers such as rice bran and bran, and soybean forge Oils such as rice wine, starch rice, starch rice, beer rice wine, etc., by-products such as fish meal, meat meal, blood meal, soybean, pumpkin, carrot, etc. (Japanese Patent Laid-Open No. 60-54303) ), Milk, cheese, krill, powdered insect feed, bran, flour, wood flour or mixtures thereof (Japanese Patent Application Laid-Open No. 62-278930), Sesame Oil (Japanese Patent Laid-Open Publication No. 53-91140), Biscuits Crumb, cracker crumb, fishmeal, pupa powder, kina flour, flour, corn flour, sugar and the like (Japanese Patent Laid-Open No. 55-94302) and the like are known.
또한, 유인성 물질로서는, 예컨대 탄소수가 4 내지 10개인 지방산과 다가 알콜로 이루어진 지방산 에스테르(일본 특허 공개 소48-58126호 공보), 방향(芳香)을 갖는 방향족 화합물로 알데히드, 케톤, 페놀, 알콜, 아민, 카르본산 또는 그 에스테르(일본 특허 공개 소50-42053호 공보), 목타르 또는 목초산에서 자극 성분을 제거한 잔류물(일본 특허 공개 소50-46842호 공보), 비환원성 전분 중간 가수 분해물(일본 특허 공개 소50-88235호 공보), 만톨 및/또는 에틸만톨(일본 특허 공개 소52-38024호 공보), 메이플, 프에누그리크, 백화, 이들의 정제물, 효모 추출물 및 카라멜(일본 특허 공개 소52-82728호 공보), 알로에 식물 및/또는 알로에 식물의 추출물(일본 특허 공개 소61-291505호 공보), 제비붓꽃 종자유, 붓꽃 종자유, 노꽃창포 종자유, 달마히오우기 종자유(일본 특허 공개 소62-135403호 공보)등이 알려져 있다. 더욱이 바퀴벌레 해충의 분비물, 변, 그 추출물 또는 사체나 껍데기 등의 해충 자체가 같은 동료를 집합적으로 유인하는 것도 제안되어 있다(일본 특허 공개 소50-95432호 공보, 일본 특허 공개 평5-4904호 공보, 일본 특허 공개 평4-342511호 공보).In addition, examples of the attractant include fatty acid esters composed of fatty acids having 4 to 10 carbon atoms and polyhydric alcohols (Japanese Patent Laid-Open No. 48-58126), aromatic compounds having aromatic aromatic compounds such as aldehydes, ketones, phenols, alcohols, Amines, carboxylic acids or esters thereof (Japanese Patent Application Laid-Open No. 50-42053), residues without stimulating components from moth tar or acetic acid (Japanese Patent Laid-Open Publication No. 50-46842), non-reducing starch intermediate hydrolysates (Japanese Patent Japanese Patent Application Laid-Open No. 50-88235), Mantol and / or ethylmantol (Japanese Patent Laid-Open No. 52-38024), Maple, Phenolic, Whitening, Purified products thereof, Yeast extract and Caramel (Japanese Patent Publication) Japanese Patent Application Laid-Open No. 52-82728), an aloe plant and / or an extract of an aloe plant (Japanese Patent Laid-Open No. 61-291505), violet iris seed oil, iris seed oil, yellow iris seed oil, dharmahigi seed oil (Japanese Patent Laid-Open) JP 62-135403, etc.) are known. Moreover, it is also proposed that the secretions, stools, extracts of cockroach pests, or pests such as carcasses and shells collectively attract the same peers (Japanese Patent Application Laid-open No. 50-95432, Japanese Patent Laid-Open No. 5-4904). Japanese Unexamined Patent Publication No. Hei 4-342511).
그러나, 상기와 같은 식이 물질이나 유인성의 식이 물질은 음식물이므로 변질을 피할 수 없어 바퀴벌레의 끽식성이 저하되고, 그 때문에 유인력이 저하되는 것을 방지할 수 없었다. However, since the above-mentioned dietary substances and attractable dietary substances are foods, deterioration is inevitable, and the cockroach's edible property is lowered, and therefore, the attraction of the attracting force cannot be prevented.
또한, 품질의 차이를 피할 수 없으므로 한번에 여러곳에 배치되어 사용되는 식독제로서의 사용시에는 개개의 식이를 물어뜯는 데에 따른 차가 있다고 하는 문제와, 그 때문에 사용자의 불신이 생긴다고 하는 문제도 있었다.In addition, there is a problem that there is a difference in biting individual diets when used as an antidote used at various places because the difference in quality cannot be avoided, and there is a problem of distrust of the user.
또 이 먹지 않는 먹이와 먹고 남은 먹이는 시간이 경과됨에 따라 부패나 변질이 생겨, 악취나 곰파이 등이 발생하고 특히 주방 등의 사용장소에서는 불쾌하며 비위생적이다. 또 다른 해충의 서식을 초래할 우려도 있다.In addition, the food that is not eaten and leftover food is decayed or deteriorated as time passes, odor or gompie occurs, especially in places such as kitchen, unpleasant and unsanitary. There is also concern that it may result in another pest infestation.
한편, 유인성 물질은 원재료의 입수가 불안정하고, 제조가 어렵다는 점에서 비용이 높아지는 경향이 있어서 실용성 측면에서 만족스러운 것은 아니었다.Attractable materials, on the other hand, tend to be expensive in terms of unstable availability of raw materials and difficult manufacturing, which is not satisfactory in terms of practicality.
또한, 바퀴벌레를 구제하는 하나의 수단으로서, 바퀴벌레를 포획하는 장치(바퀴벌레 포획기)가 수많이 제안되어 있지만, 종래 시판되고 있는 바퀴벌레 포획기는 모두 포획기 내에 바퀴벌레가 침입하지 않으면 바퀴벌레를 포획할 수 없다고 하는 결점이 있다. 이들 결점을 보완하기 위해 바퀴벌레가 즐겨 끽식하는 물질이나 바퀴벌레를 유인하는 향기 물질을 포획기내에 설치하는 등의 방법이 제안되어 있지만, 모두 실제의 집이나 식당 등의 현장에서 바퀴벌레를 포획기 내로 침입하게 하는 효과가 충분하다고는 말할 수 없다.In addition, as a means of extinguishing cockroaches, a number of devices for catching cockroaches (roach catchers) have been proposed. However, all of the commercially available cockroach catchers cannot catch cockroaches unless the cockroaches invade them. There is a flaw. In order to make up for these shortcomings, methods such as cockroach feeding and fragrance attracting cockroaches have been proposed in the trap, but they are intended to invade the cockroach into the trap at actual places such as homes and restaurants. I can not say that the effect is enough.
상기와 같은 문제점 이외에도 바퀴벌레 포획기 자체가 합성수지제로 이루어진 것으로서 폐기시 환경적인 측면에서 문제점이 있는 것으로서 이와 같은 환경적 폐해가 상기 언급한 바퀴벌레의 포획여부를 떠나서 더욱 문제라 할 수 있으며 이와 같은 문제를 해결하기 위한 수단이 강구되어야 하는 것이 현 시대의 가장 절실한 과제라 할 수 있다.In addition to the above problems, the cockroach catcher itself is made of a synthetic resin and there is a problem in terms of the environment when discarding. It is the most urgent task of our time to find a means to do this.
본 발명인 환경친화적 생분해성 바퀴벌레 퇴치용 용기제조방법 및 그 용기는 상기의 문제점을 해결하기 위한 것으로서,The present invention is an environment-friendly biodegradable cockroach eradication container manufacturing method and the container to solve the above problems,
기존의 합성수지의 환경호르몬, 유해중금속, 온실가스, 연소폐기시 유해가스 유발에 대한 문제점을 해소하기 위한 것으로서 매립 또는 소각을 통해 폐기하여도 환경오염을 전혀 일으키지 않고 또한 유독가스 및 연기발생이 없어 안정성이 높은 환경친화적 생분해성 바퀴벌레 퇴치용 용기를 제조하는데 본 발명의 목적이 있다.It is to solve the problems of environmental hormone, harmful heavy metal, greenhouse gas, and harmful gas in the combustion waste of existing synthetic resin, and it does not cause any environmental pollution even when disposed of through landfill or incineration, and also has no toxic gas and smoke. It is an object of the present invention to make a container for combating this highly environmentally friendly biodegradable cockroach.
상기 목적을 달성하기 위한 본 발명인 환경친화적 생분해성 바퀴벌레 퇴치용 용기제조방법 및 그 용기의 구체적인 해결적 수단은,Environmentally friendly biodegradable cockroach for the production of a container for achieving the above object and a specific solution means of the container,
[PLA 30~40중량%와 PBS나 PBSA, PBA중 선택된 어느 한 소재 30~50중량%, 생분해성 나노복합소재 10~20중량% 혼합하여 조성물을 형성하는 단계; 상기 조성물에 부탄디올과 숙신산과 트리패닐토스테이트를 첨가 감압하에서 1차 180~200℃, 2차 220~240℃ 중합과정을 거치는 단계; 상기 중합과정을 거친 조성물을 온도 180~190℃로 압출하여 펠렛화하는 단계; 상기 펠렛을 온도 170~190℃로 사출성형하는 단계로 이루어진 환경친화적 생분해성 바퀴벌레 퇴치용 용기제조방법]으로 구성함으로서 기술적 해결을 달성할 수 있다.[30-30% by weight of PLA and 30-50% by weight of any material selected from PBS, PBSA, PBA, 10-20% by weight of the biodegradable nanocomposite material to form a composition; Adding butanediol, succinic acid, and trifanyltostate to the composition, followed by a first 180-200 ° C., second 220-240 ° C. polymerization process under reduced pressure; Extruding the composition subjected to the polymerization process at a temperature of 180 to 190 ° C. to pelletize the composition; Environmentally friendly biodegradable cockroach eradication container manufacturing method consisting of the step of injection molding the pellet at a temperature of 170 ~ 190 ℃] can be achieved by a technical solution.
상기와 같은 구성으로 이루어진 본 발명은 폐기시 자연상태에서 빠른 시간내에 완전분해되므로 환경부하를 줄일 뿐만 아니라 항곰팡이 및 항균력 발생 및 피톤치드를 발산하므로 사용시 주방이나 실내에 설치하더라도 위생적이고도 인체에 이로운 장점이 있고, 소각시 유독가스나 연기가 발생되지 않아 환경적으로 매우 유익한 효과를 가져올 수 있다.The present invention composed of the above configuration is not only reduce the environmental load, because it is completely decomposed in a quick time in the natural state when discarded, because it produces anti-mold and antibacterial activity and phytoncide, even when installed in the kitchen or indoors when using the sanitary and beneficial benefits to the human body And, incineration does not generate toxic gases or smoke can bring a very environmentally beneficial effect.
이상에서 본 발명에 있어서 특정의 바람직한 실시예를 들어 도시하고 설명하였으나, 본 발명은 상기한 실시예에 한정되지 아니하며 본 발명의 정신을 벗어나지 않는 범위내에서 당해 발명이 속하는 기술분야에서 통상의 지식을 가진 자에 의해 다양한 변경과 수정이 가능할 수 있을 것이다. While specific embodiments of the present invention have been illustrated and described above, the present invention is not limited to the above-described embodiments and the general knowledge in the art to which the present invention pertains does not fall within the spirit of the present invention. Various changes and modifications may be made by the person who owns them.
도 1은 본 발명인 환경친화적 생분해성 바퀴벌레 퇴치용 용기 제조방법을 나타낸 블럭도이다. 1 is a block diagram showing a method for producing a container for combating environmentally friendly biodegradable cockroach of the present invention.
본 발명인 환경친화적 생분해성 바퀴벌레 퇴치용 용기의 실시를 위한 최선의 해결적 수단은,The best solution for the implementation of the container for the fight against environmentally friendly biodegradable cockroach,
[PLA 30~40중량%와 PBS나 PBSA, PBA중 선택된 어느 한 소재 30~50중량%, 생분해성 나노복합소재 10~20중량% 혼합하여 조성물을 형성하는 단계;[30-30% by weight of PLA and 30-50% by weight of any material selected from PBS, PBSA, PBA, 10-20% by weight of the biodegradable nanocomposite material to form a composition;
상기 조성물에 부탄디올과 숙신산과 트리패닐토스테이트를 첨가 감압하에서 1차 180~200℃, 2차 220~240℃ 중합과정을 거치는 단계;Adding butanediol, succinic acid, and trifanyltostate to the composition, followed by a first 180-200 ° C., second 220-240 ° C. polymerization process under reduced pressure;
상기 중합과정을 거친 조성물을 온도 180~190℃로 압출하여 펠렛화하는 단계;Extruding the composition subjected to the polymerization process at a temperature of 180 to 190 ° C. to pelletize the composition;
상기 펠렛을 온도 170~190℃로 사출성형하는 단계로 이루어진 환경친화적 생분해성 바퀴벌레 퇴치용 용기제조방법과 Method for producing a container for the fight against environmentally friendly biodegradable cockroach consisting of injection molding the pellet at a temperature of 170 ~ 190 ℃
PLA 30~40중량%와 PBS나 PBSA, PBA중 선택된 어느 한 소재 30~50중량%, 생분해성 나노복합소재 10~20중량%를 온도 180~190℃로 압출화하여 된 환경친화적 생분해성 바퀴벌레 퇴치용 용기와,Fighting environmentally friendly biodegradable cockroaches made by extruding 30-40 wt% PLA, 30-50 wt% of any material selected from PBS, PBSA or PBA, and 10-20 wt% of biodegradable nanocomposites at a temperature of 180-190 ° C. For containers,
PBS나 PBSA, PBA중 선택된 어느 한 소재에 부탄디올과 숙신산과 트리패닐토스테이트를 첨가 감압하에서 1차 180~200℃, 2차 220~240℃ 중합과정을 거쳐서 된 환경친화적 생분해성 바퀴벌레 퇴치용 용기]를 그 구성적 특징으로 함으로서 상기의 목적을 달성할 수 있다.Addition of butanediol, succinic acid, and trifanyltostate to any selected material from PBS, PBSA, and PBA. The above object can be achieved by making the structural feature thereof.
상기와 같은 발명의 실시로 인하여 기술적 해결을 달성하기 위한 구체적인 구성 및 작용에 대하여 도면과 함께 설명하고자 한다.Due to the implementation of the invention as described above will be described with reference to the specific configuration and operation for achieving the technical solution.
도 1은 본 발명인 환경친화적 생분해성 바퀴벌레 퇴치용 용기 제조방법을 나타낸 블럭도이다.1 is a block diagram showing a method for producing a container for combating environmentally friendly biodegradable cockroach of the present invention.
이하 본 발명에 대하여 구체적으로 설명하기 전에 우선 본 발명인 환경친화적 생분해성 바퀴벌레 퇴치용 용기 제조방법에 대하여 도면과 함께 설명하고 이로 인한 용기에 대하여 설명하고자 한다.Hereinafter, the present invention will be described with reference to the drawings for the container manufacturing method for environmentally friendly biodegradable cockroach eradication before the present invention will be described in detail with respect to the resulting container.
본 발명의 환경친화적 생분해성 바퀴벌레 퇴치용 용기제조방법은,Environmentally-friendly biodegradable cockroach eradication container manufacturing method of the present invention,
도 1에 도시된 바와 같이,As shown in FIG. 1,
PLA 30~40중량%와 PBS나 PBSA, PBA중 선택된 어느 한 소재 30~50중량%, 생분해성 나노복합소재 10~20중량% 혼합하여 조성물을 형성하는 단계;Forming a composition by mixing 30 to 40% by weight of PLA and 30 to 50% by weight of any material selected from PBS, PBSA, PBA, 10 to 20% by weight of the biodegradable nanocomposite material;
상기 조성물에 부탄디올과 숙신산과 트리패닐토스테이트를 첨가 감압하에서 1차 180~200℃, 2차 220~240℃ 중합과정을 거치는 단계;Adding butanediol, succinic acid, and trifanyltostate to the composition, followed by a first 180-200 ° C., second 220-240 ° C. polymerization process under reduced pressure;
상기 중합과정을 거친 조성물을 온도 180~190℃로 압출하여 펠렛화하는 단계;Extruding the composition subjected to the polymerization process at a temperature of 180 to 190 ° C. to pelletize the composition;
상기 펠렛을 온도 170~190℃로 사출성형하는 단계로 완성되는 것이다.The pellet is completed by the step of injection molding at a temperature of 170 ~ 190 ℃.
구체적으로 상기 생분해성 수지인 PLA(Poly Lactic Acid, 폴리유산)는 유산이라고 하는 생체내 등에 존재하는 저분자량 화합물(모노머)의 중합체이지만 천연에는 존재하지 않으며, PLA는 일반적으로 물에 의하여 가수분해되어 저분자화한 후 미생물에 의하여 분해된다고 알려져 있어 친환경적인 원료로 널리 이용되고 있는 것이며,Specifically, the biodegradable resin PLA (Poly Lactic Acid, polylactic acid) is a polymer of a low molecular weight compound (monomer) present in the body, such as lactic acid, but does not exist in nature, PLA is generally hydrolyzed by water It is known to be degraded by microorganisms after low molecular weight and is widely used as an environmentally friendly raw material.
상기 PLA 30~40중량%와 또한 생분해성 수지인 PBS(폴리부틸렌 석시, Poly butylene succinate), PBSA(폴리부틸렌 석시 네이트,Poly butylene succinate adipate), PBA(폴리부틸렌 네이트, Poly butylene adipate)중 어느 하나를 선택하여 30~50중량%를 혼합하고 생분해성 나노복합소재 10~20중량% 혼합하여 조성물을 형성한 후, The PLA 30-40% by weight and also biodegradable resins PBS (polybutylene succinate, Poly butylene succinate), PBSA (poly butylene succinate adipate), PBA (polybutylene ate, Poly butylene adipate) Select any one of 30 to 50% by weight of the mixed and 10 to 20% by weight of the biodegradable nanocomposite material to form a composition,
상기 조성물에 부탄디올과 숙신산과 트리패닐토스테이트를 첨가 감압하에서 1차 180~200℃, 2차 220~240℃ 중합과정을 거친후,After the butanediol, succinic acid and tripaniletostate were added to the composition under a first 180-200 ° C. and second 220-240 ° C. polymerization under reduced pressure,
상기 중합과정을 거친 조성물을 온도 180~190℃로 압출하여 펠렛화한 다음, After pelletizing the composition passed through the polymerization process at a temperature of 180 ~ 190 ℃,
상기 펠렛을 온도 170~190℃로 사출성형함으로서 본 발명인 환경친화적 생분해성 바퀴벌레 퇴치용 용기제조방법이 완성되며,By injection molding the pellets at a temperature of 170 to 190 ° C, a method for manufacturing a container for combating environmentally-friendly biodegradable cockroaches is completed.
상기와 같은 제조방법에 의해 완성된 용기를 구체적으로 설명하면,Referring to the container completed by the manufacturing method as described above,
PLA 30~40중량%와 PBS나 PBSA, PBA중 선택된 어느 한 소재 30~50중량%, 생분해성 나노복합소재 10~20중량%를 온도 180~190℃로 압출화하여 된 환경친화적 생분해성 바퀴벌레 퇴치용 용기가 완성되며,Fighting environmentally friendly biodegradable cockroaches made by extruding 30-40 wt% PLA, 30-50 wt% of any material selected from PBS, PBSA or PBA, and 10-20 wt% of biodegradable nanocomposites at a temperature of 180-190 ° C. The container is completed,
바람직하게는, PBS나 PBSA, PBA중 선택된 어느 한 소재에 부탄디올과 숙신산과 트리패닐토스테이트를 첨가 감압하에서 1차 180~200℃, 2차 220~240℃ 중합과정을 거침으로서 환경친화적 생분해성 바퀴벌레 퇴치용 용기가 완성되는 것이다.Preferably, butanediol, succinic acid, and trifanyltostate are added to any one selected from PBS, PBSA, and PBA. Environmentally-friendly biodegradable cockroaches are subjected to the first 180-200 ° C. and the second 220-240 ° C. polymerization under reduced pressure. The container for combat is complete.

Claims (3)

  1. PLA 30~40중량%와 PBS나 PBSA, PBA중 선택된 어느 한 소재 30~50중량%, 생분해성 나노복합소재 10~20중량% 혼합하여 조성물을 형성하는 단계;Forming a composition by mixing 30 to 40% by weight of PLA and 30 to 50% by weight of any material selected from PBS, PBSA, PBA, 10 to 20% by weight of the biodegradable nanocomposite material;
    상기 조성물에 부탄디올과 숙신산과 트리패닐토스테이트를 첨가 감압하에서 1차 180~200℃, 2차 220~240℃ 중합과정을 거치는 단계;Adding butanediol, succinic acid, and trifanyltostate to the composition, followed by a first 180-200 ° C., second 220-240 ° C. polymerization process under reduced pressure;
    상기 중합과정을 거친 조성물을 온도 180~190℃로 압출하여 펠렛화하는 단계;Extruding the composition subjected to the polymerization process at a temperature of 180 to 190 ° C. to pelletize the composition;
    상기 펠렛을 온도 170~190℃로 사출성형하는 단계로 이루어진 것을 특징으로 하는 환경친화적 생분해성 바퀴벌레 퇴치용 용기제조방법.Method for producing an environment-friendly biodegradable cockroach control container comprising the step of injection molding the pellet at a temperature of 170 ~ 190 ℃.
  2. PLA 30~40중량%와 PBS나 PBSA, PBA중 선택된 어느 한 소재 30~50중량%, 생분해성 나노복합소재 10~20중량%를 온도 180~190℃로 압출화하여 된 것을 특징으로 하는 환경친화적 생분해성 바퀴벌레 퇴치용 용기.Environmentally friendly, characterized in that by extruding 30 to 40% by weight of PLA, 30 to 50% by weight of any material selected from PBS, PBSA, PBA, 10 to 20% by weight of biodegradable nanocomposites at a temperature of 180 ~ 190 ℃ Container for combating biodegradable cockroaches.
  3. 제 2 항에 있어서,The method of claim 2,
    PBS나 PBSA, PBA중 선택된 어느 한 소재에 부탄디올과 숙신산과 트리패닐토스테이트를 첨가 감압하에서 1차 180~200℃, 2차 220~240℃ 중합과정을 거쳐서 된 것을 특징으로 하는 환경친화적 생분해성 바퀴벌레 퇴치용 용기.Addition of butanediol, succinic acid, and trifanyltostate to any one selected from PBS, PBSA, and PBA Environmentally-friendly biodegradable cockroaches, characterized in that the first 180 ~ 200 ℃, the second 220 ~ 240 ℃ polymerization process under reduced pressure Fighting container.
PCT/KR2009/001319 2009-03-17 2009-03-17 Method for producing an environmentally-friendly biodegradable container for exterminating cockroaches, and container WO2010107142A1 (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005200517A (en) * 2004-01-14 2005-07-28 Asahi Fiber Glass Co Ltd Fiber-reinforced polylactic acid-based resin composition
KR20090008119A (en) * 2008-05-30 2009-01-21 유영선 Nature biodegradable and heat resistant multipurpose spoon containing saw blade, fork and spoon

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005200517A (en) * 2004-01-14 2005-07-28 Asahi Fiber Glass Co Ltd Fiber-reinforced polylactic acid-based resin composition
KR20090008119A (en) * 2008-05-30 2009-01-21 유영선 Nature biodegradable and heat resistant multipurpose spoon containing saw blade, fork and spoon

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