WO2010098677A2 - Exhaust gas cleaning apparatus and method for cleaning an exhaust gas - Google Patents
Exhaust gas cleaning apparatus and method for cleaning an exhaust gas Download PDFInfo
- Publication number
- WO2010098677A2 WO2010098677A2 PCT/NO2010/000075 NO2010000075W WO2010098677A2 WO 2010098677 A2 WO2010098677 A2 WO 2010098677A2 NO 2010000075 W NO2010000075 W NO 2010000075W WO 2010098677 A2 WO2010098677 A2 WO 2010098677A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- exhaust gas
- cold flame
- flow path
- gas
- flame gas
- Prior art date
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims abstract description 48
- 239000012530 fluid Substances 0.000 claims abstract description 81
- 238000002485 combustion reaction Methods 0.000 claims abstract description 68
- 238000004891 communication Methods 0.000 claims abstract description 23
- 239000012535 impurity Substances 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims description 63
- 239000002245 particle Substances 0.000 claims description 52
- 238000010438 heat treatment Methods 0.000 claims description 15
- 238000009833 condensation Methods 0.000 claims description 8
- 230000005494 condensation Effects 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 abstract description 21
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 21
- 239000013618 particulate matter Substances 0.000 abstract description 10
- 239000007789 gas Substances 0.000 description 326
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 29
- 239000000446 fuel Substances 0.000 description 21
- 230000003647 oxidation Effects 0.000 description 21
- 238000007254 oxidation reaction Methods 0.000 description 21
- 239000003054 catalyst Substances 0.000 description 16
- 239000002828 fuel tank Substances 0.000 description 13
- 239000004071 soot Substances 0.000 description 11
- 239000004215 Carbon black (E152) Substances 0.000 description 10
- 230000001105 regulatory effect Effects 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000006096 absorbing agent Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 238000011144 upstream manufacturing Methods 0.000 description 4
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000001603 reducing effect Effects 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 239000003245 coal Substances 0.000 description 2
- 238000005485 electric heating Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
- F23G7/061—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating
- F23G7/065—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating using gaseous or liquid fuel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
- F01N3/025—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using fuel burner or by adding fuel to exhaust
- F01N3/0253—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using fuel burner or by adding fuel to exhaust adding fuel to exhaust gases
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
- F01N3/025—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using fuel burner or by adding fuel to exhaust
- F01N3/0253—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using fuel burner or by adding fuel to exhaust adding fuel to exhaust gases
- F01N3/0256—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using fuel burner or by adding fuel to exhaust adding fuel to exhaust gases the fuel being ignited by electrical means
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/103—Oxidation catalysts for HC and CO only
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/105—General auxiliary catalysts, e.g. upstream or downstream of the main catalyst
- F01N3/106—Auxiliary oxidation catalysts
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/49—Detecting, diagnosing or indicating an abnormal function of the EGR system
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
- F23J15/022—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
- F23J15/025—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow using filters
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2240/00—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
- F01N2240/30—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a fuel reformer
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/04—Adding substances to exhaust gases the substance being hydrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/05—Adding substances to exhaust gases the substance being carbon monoxide
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2006—Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating
- F01N3/2046—Periodically cooling catalytic reactors
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/22—Control of additional air supply only, e.g. using by-passes or variable air pump drives
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/30—Arrangements for supply of additional air
- F01N3/32—Arrangements for supply of additional air using air pump
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
- F23C2900/99001—Cold flame combustion or flameless oxidation processes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
Definitions
- the present invention relates to an exhaust gas cleaning apparatus and a method for the cleaning of exhaust gas which originates from a combustion process.
- the exhaust gas cleaning apparatus and the related method is particularly suitable for removing unwanted combustion products like NOx, hydrocarbons and soot which is present in the exhaust gas.
- the present invention also relates to the use of a cold flame gas to remove NOx and particulate matter from an exhaust gas.
- the cold flame is a phenomenon which has so far not received much attention.
- a cold flame the fuel is partially oxidized in preheated air and the temperature is kept constant at about 45O 0 C. The temperature is independent of air/fuel ratio and residence time.
- a gaseous fuel is hereafter called a cold flame gas.
- a definition of a cold flame gas may then be a gas which is formed by partial oxidation of a hydrocarbon (fuel) in a mixture of air and hydrocarbon and wherein only a relatively small fraction of the air (5-10% of the air) is consumed in the oxidation.
- Exhaust gas from combustion engines may contain impurities such as particulate matter (soot), NOx and incomplete combustion products, i.e. hydrocarbons (HC) and CO.
- the incomplete combustion products can be removed by an oxidation catalyst, while particulate matter can be removed from the exhaust gas with a particle filter.
- NOx can be removed catalytically from the exhaust gas if the exhaust gas is slightly reducing (as in an Otto engine) or otherwise by an NOx absorber (for instance for exhaust gas from a compression ignition engine).
- an NOx absorber and a oxidation catalyst are used today. After some time in use, the particle filter and the NOx absorber must be regenerated. Such a cleaning process requires two operations since the particle filter is regenerated under high temperature (about 600 0 C) in an oxidizing environment while the NOx absorber is regenerated at lower temperatures in a reducing environment (about 500 0 C with CO gas).
- the objective of the present invention is therefore to provide a simplified apparatus and a simplified method for the treatment of exhaust gas from a combustion process.
- Impurities are in the description and in the claims defined to include soot particles, NOx (nitrogen oxides), hydrocarbons and other substances that can be removed (oxidized or reduced) by the cold flame gas.
- an exhaust gas cleaning apparatus for cleaning of exhaust gas which originates from a combustion process in a combustion chamber where the exhaust gas cleaning apparatus comprises an exhaust gas flow path which is arranged in fluid communication with the combustion chamber and through which the exhaust gas is flowing, and - a cold flame gas supply which provides a cold flame gas.
- the cold flame gas supply is further arranged in fluid communication with the exhaust gas flow path such that the cold flame gas can be injected into the exhaust gas flowing in the exhaust gas flow path and thereby, at least partly, remove impurities, like NO x and/or particulate matter (for example soot) and/or hydrocarbons, which are present in the exhaust gas.
- impurities like NO x and/or particulate matter (for example soot) and/or hydrocarbons, which are present in the exhaust gas.
- the combustion chamber may be part of an internal combustion engine, for example a compression ignition engine (imprecisely called a diesel engine) or an Otto- engine.
- the exhaust gas is removed from the combustion chamber through an exhaust flow path like for example a conduit, a pipe, a tube or any other suitable means for conducting the exhaust gas.
- the combustion chamber may also be part of an incineration plant or a power plant based on a combustion process of for example coal or any other combustible material. Other areas of use of the present invention are also easily conceivable.
- the combustion chamber is the place wherein the combustion of the combustible material takes place producing the exhaust gas which needs cleaning.
- the combustion chamber may obviously take many different forms depending on the technical field of use, i.e.
- the exhaust gas cleaning apparatus preferably includes feeding means (not shown in the figures) for feeding the combustible matter into the combustion chamber.
- the fuel tank preferably feeds hydrocarbon fuel to the cold flame gas generator only.
- a cold flame gas supply which can be connected to the exhaust flow path with a fluid line such that the cold flame gas may be injected into the exhaust gas flowing in the exhaust flow path.
- the fluid line is preferably provided with the necessary valve means such that injection of cold flame gas into the exhaust flow path can be regulated.
- the cold flame gas generator may be regulated by adjusting the amount of fuel and/or air which is fed to the cold flame gas generator.
- the valve means are preferably automatically controlled based on measurements of temperature and/or pressure and/or measurements related to the composition of the exhaust gas taken at one or several positions in the exhaust gas flow path.
- the exhaust gas and the cold flame gas are mixed in a mixing chamber in the exhaust flow path.
- the mixing chamber can simply be a portion of the exhaust flow path itself as long as an efficient mixing of the exhaust gas and the cold flame gas is ensured.
- the exhaust gas flow path can be provided with a mixing chamber through which the exhaust gas flows and in which the cold flame gas and the exhaust gas is mixed.
- the mixing chamber can be configured as a conduit with an increased diameter or cross sectional area as compared to the same of the exhaust gas flow path.
- the mixing chamber can be configured as a larger container to which the exhaust gas flow path is connected.
- the cold flame gas is preferably injected into the exhaust flow path upstream the mixing chamber, or into an upstream end portion of the mixing chamber, relatively close to the point where the exhaust gas enters the mixing chamber.
- mixing means in the mixing chamber, i.e. either in the exhaust flow path or in the mixing chamber, for enhanced mixing of the exhaust gas and the cold flame gas.
- Such mixing means can comprise a porous material through which the exhaust gas and the cold flame gas flow and are thereby getting mixed.
- the mixing means may also comprise blades or similar devices which are arranged in the mixing chamber and which are arranged such that the mixing means causes turbulence in the flow and thereby a more efficient mixing of the exhaust gas and the cold flame gas. A more even mix of exhaust gas and cold flame gas results in more efficient chemical reactions between components of the cold flame gas on one hand and the impurities in the exhaust gas on the other hand.
- the cold flame gas supply may simply comprise a cold flame gas generator which is arranged in fluid communication with the exhaust gas flow path.
- Cold flame generators will be known to a skilled person in the art and their construction are not explained any further here.
- the cold flame gas generator may be placed outside the exhaust gas flow path in which case there are separate supply fluid lines for air and hydrocarbon fuel to the cold flame gas generator.
- the cold flame gas generator is arranged within the exhaust gas flow path.
- a separate supply fluid line for hydrocarbon fuel is then provided.
- Oxygen for the cold flame gas generator is in this case preferably supplied through air in the exhaust gas, or alternatively through a separate supply fluid line for air providing air from outside the exhaust gas flow path.
- the air supply may be preheated by using a heat exchanger which utilizes the heat energy contained in the exhaust gas to preheat the air.
- the cold flame gas supply may also comprise a reservoir for cold flame gas where the reservoir can be arranged in fluid communication with the cold flame gas generator and the exhaust gas flow path through fluid lines.
- the reservoir itself may be configured as an inline conduit with a larger inner diameter than the fluid line connecting the cold flame gas generator and the exhaust gas flow path.
- the length of the reservoir conduit should be decided according to the desired storing capacity of the reservoir.
- the reservoir may be configured as a separate tank, which may be suitable when a larger quantity of cold flame gas needs to be stored.
- there is preferably provided a bypass fluid line such that the cold flame gas can flow directly from the cold flame gas generator to the exhaust gas flow path without passing through the reservoir.
- valve means in the fluid lines including any bypass fluid line, which regulates the flow of cold flame gas from the cold flame gas generator to the reservoir and/or to the exhaust gas flow path, and from the reservoir to the exhaust gas flow path.
- the exhaust gas flow path can therefore receive a controllable quantity of cold flame gas.
- the reservoir comprises heating means such that the temperature of the cold flame gas which is stored in the reservoir is kept above the condensation point of the cold flame gas.
- the heating means may comprise a heat exchanger and fluid lines connecting the heat exchanger and the exhaust gas flow path such that the cold flame gas can be heated by the exhaust gas.
- valve means in the fluid lines such that the temperature of the cold flame gas can be kept within a desired temperature interval, which is above the condensation point of the cold flame gas.
- the exhaust gas is used to heat the cold flame gas generator. This can be done in the same way as the cold flame gas reservoir is heated, as explained above.
- the exhaust gas cleaning apparatus further comprises an exhaust gas return loop (EGR-loop) through which a part of the exhaust gas flowing in the exhaust flow path can be returned to the combustion chamber.
- the EGR-loop comprises a fluid line which preferably extends from the exhaust gas flow path downstream the mixing zone and to the combustion chamber.
- the fluid line is preferably provided with valve means such that the amount of exhaust gas which is returned to the combustion chamber can be regulated. Generally, up to 40% of the exhaust gas may be returned through the EGR-loop.
- the EGR-loop comprises a EGR-loop particle filter such that any particular matter like soot particles, which has not been oxidized by the cold flame gas, can be removed.
- it is arranged in fluid communication with the cold flame gas supply.
- the fluid communication can be effected by fluid lines extending from the reservoir for cold flame gas or the cold flame gas generator to the EGR-loop particle filter.
- valve means in fluid line such that the flow of cold flame gas to EGR-loop particle filter can be controlled and regulated.
- the exhaust gas flow path is also provided with an exhaust gas flow path particle filter such that the exhaust gas flows through the exhaust gas flow path particle filter before the cold flame gas is injected into the exhaust gas flow path. At least a part of the particulate matter, like soot-particles, can then be removed from the exhaust gas before cold flame gas is injected into the exhaust gas.
- the exhaust gas flow path particle filter may further be arranged in fluid communication with the cold flame gas supply such that the exhaust gas flow path particle filter can be regenerated by the cold flame gas.
- the fluid communication can be effected by fluid lines extending from the reservoir for cold flame gas or the cold flame gas generator to the exhaust gas flow path particle filter.
- valve means in fluid line such that the flow of cold flame gas to exhaust gas flow path particle filter can be controlled and regulated.
- particle filters may be regenerated using cold flame gas
- an oxidation catalyst is provided in the exhaust gas flow path downstream the EGR-loop. The oxidation catalyst will remove the hydrocarbons and CO which were not oxidized by the cold flame gas.
- the exhaust gas flow path may be provided with air supply means upstream the oxidation catalyst such that air is fed into the exhaust gas flow path before the exhaust gas enters the oxidation catalyst.
- the method includes the steps of providing a cold flame gas, and injecting the cold flame gas into the exhaust gas flowing in the exhaust gas flow path.
- impurities like NO x and/or particulate matter (for example soot) and/or hydrocarbons, at least partly, removed from the exhaust gas.
- the combustion chamber may be part of an internal combustion engine, for example a compression ignition engine (imprecisely called a diesel engine) or an Otto- engine.
- the exhaust gas is removed from the combustion chamber through an exhaust flow path like for example a conduit, a pipe, a tube or any other suitable means for conducting the exhaust gas.
- the combustion chamber may also be part of an incineration plant or a power plant based on a combustion process of for example coal or any other combustible material. Other areas of use of the present invention are also easily conceivable.
- the combustion chamber is the place wherein the combustion of the combustible material takes place producing the exhaust gas which needs cleaning.
- the combustion chamber may obviously take many different forms depending on the technical field of use, i.e. in an engine, an incineration plant, a power plant etc.
- the method may include the step of providing a mixing chamber through which the exhaust gas is flowing and injecting the cold flame gas such that the cold flame gas and the exhaust gas in the mixing chamber.
- the method may include the step of providing mixing means for enhanced mixing of the exhaust gas and the cold flame gas.
- mixing means may include a porous material that the exhaust gas and the cold flame gas passes through in such a way that the two gases are mixed.
- blades or other types of mechanical mixing means may be provided in the mixing chamber such that there is created turbulence in the fluid flow which enhances the mixing of exhaust gas and cold flame gas.
- the method includes the step of producing cold flame gas in a cold flame gas generator. As explained above, cold flame generators are well known to the skilled person in the art.
- the method may include the step of storing the cold flame gas, which has been produced by the cold flame gas generator, in a reservoir.
- the reservoir may be configured as an inline conduit with a larger diameter as compared to the fluid line connecting the cold flame gas generator and the exhaust gas flow path.
- the reservoir is configured as larger container. In both cases there may be provided a bypass fluid line such that the cold flame gas may flow directly from the cold flame gas generator to the exhaust gas flow path.
- the method may include the step of heating the cold flame gas which is stored in the reservoir such that the temperature of the cold flame gas is kept above the condensation point of the cold flame gas.
- the heating may be carried out using a heat exchanger which is arranged in fluid communication with the exhaust gas flow path such that the heat energy contained in the exhaust gas can be used to heat the cold flame gas in the reservoir or to keep the cold flame gas at a steady temperature above the condensation point.
- An alternative for heating or keeping the cold flame gas in the reservoir at a temperature above the condensation point would be to use one or more regular electric heating elements.
- the cold flame gas generator may also be heated or kept warm in the same way by using heat energy in the exhaust gas or alternatively by using electric heating elements.
- the method may include the step of returning a part of the exhaust gas flowing in the exhaust gas flow path to the combustion chamber in an EGR-loop.
- the EGR-loop comprises a fluid line connected to the exhaust gas flow path and the combustion chamber.
- the method includes the step of removing particles in the exhaust gas flowing in the EGR-loop by providing an EGR-loop particle filter in the EGR-loop.
- the method may include the step of arranging the EGR-loop particle filter in fluid communication with the cold flame gas supply such that the EGR-loop particle filter can be regenerated by the cold flame gas.
- the method may include the step of providing an exhaust gas flow path particle filter in the exhaust gas flow path.
- the method may further include the step of arranging the exhaust gas flow path particle filter in fluid communication with the cold flame gas supply such that the exhaust gas flow path particle filter can be regenerated by the cold flame gas.
- the method may include the step of providing an oxidation catalyst in the exhaust flow path downstream the injection of the cold flame gas.
- the method may include the step of injecting air into the exhaust gas flow path upstream the oxidation catalyst such that the temperature in the oxidation catalyst can be regulated and enough oxygen for the oxidation process in the oxidation catalyst can be ensured.
- a cold flame gas to remove impurities, like NO x and/or particulate matter (for example soot) and/or hydrocarbons, from an exhaust gas by injecting the cold flame gas into the exhaust gas, where the exhaust gas may originate from a combustion process in for example an internal combustion engine, an incineration plant, a power plant etc.
- impurities like NO x and/or particulate matter (for example soot) and/or hydrocarbons
- Figure 1 discloses a first embodiment of the exhaust gas cleaning apparatus 100.
- a fuel tank 10 for a hydrocarbon fuel like diesel fuel is connected to a combustion chamber 12 by fluid line 50.
- a cold flame gas generator 16 is connected to the fuel tank 10 via fluid line 53.
- a valve means 80 controls and regulates the flow of fuel from the fuel tank 10 to the cold flame gas generator 16.
- An air supply 17 is connected to the cold flame gas generator 16 via fluid line 54. Necessary equipment for the air supply 17, like an air compressor, filters or valve means, are not shown on the figures.
- the exhaust gas cleaning apparatus 100 preferably includes feeding means (not shown in the figures) for feeding the combustible matter into the combustion chamber.
- the fuel tank 10 preferably feeds hydrocarbon fuel to the cold flame gas generator 16 only.
- a mixing chamber 14 is connected to the combustion chamber 12 via exhaust gas flow path 51.
- the mixing chamber can be a part of the exhaust gas fluid pipe itself, a fluid line section with increased diameter compared to that of the exhaust gas flow path or a container.
- the mixing chamber 14 may be provided with mixing means that enhances the mixing of the exhaust gas and the cold flame gas. After the mixing chamber 14, the exhaust gas leaves through exhaust gas flow path 52.
- Exhaust gas flow paths 51, 52 may be in the form of conduits, pipes, tubes or other suitable means for conducting the exhaust gas.
- the cold flame gas generator 16 is connected to the mixing chamber 14 via fluid line 55.
- Valve means 81 controls and regulates the flow of cold flame gas from the cold flame gas generator 16 to the mixing chamber 14.
- FIG 2 shows a similar embodiment to the embodiment shown in Figure 1.
- the cold flame gas generator 16 is in this embodiment provided inline with the exhaust gas flow path between the combustion chamber 12 and the mixing chamber 14.
- Exhaust gas flow path 56 connects the combustion chamber 12 and the cold flame gas generator 16, while the exhaust gas flow path 57 connects the cold flame gas generator 16 and the mixing chamber 14. It is also possible to combine the cold flame gas generator 16 and the mixing chamber 14 into one unit.
- the exhaust gas flow path 57 is then redundant.
- the oxygen necessary in the production of the cold flame gas is supplied through air in the exhaust gas.
- a supply fluid line 59 provides fuel to the cold flame gas generator 16.
- Valve means 83 controls and regulates the flow of fuel from the fuel tank 10 to the cold flame gas generator 16.
- FIG 3 shows an embodiment of the exhaust gas cleaning apparatus 100 where there is provided a reservoir 18 for cold flame gas.
- Providing the reservoir 18 ensures that there are sufficient reserves of cold flame gas available when that is necessary, for example during full admission of a combustion engine.
- the reservoir shown in this embodiment of the invention is an inline reservoir which may be formed by a length of pipe, tube or similar which has a larger diameter than the fluid lines 60, 61.
- the combustion chamber 12 is connected to the fuel tank 10 via fluid line 50 and to the mixing chamber 14 via exhaust gas flow path 51.
- the cold flame gas generator 16 is connected to the fuel tank 10 via fluid line 53 and to the reservoir 18 via fluid line 60.
- the exhaust gas cleaning apparatus 100 preferably includes feeding means (not shown in the figures) for feeding the combustible matter into the combustion chamber.
- the fuel tank 10 preferably feeds hydrocarbon fuel to the cold flame gas generator 16 only.
- the reservoir is connected to the mixing chamber 14 via fluid line 61.
- Valve means 80 controls and regulates the flow of fuel from the fuel tank 10 to the cold flame gas generator 16.
- Valve means 84 controls and regulates the flow of cold flame gas from the cold flame gas generator 16 to the reservoir 18, while valve means 85 controls and regulates the flow of cold flame gas from the reservoir 18 to the mixing chamber 14.
- the cold flame gas generator is connected to an air supply 17 via fluid line 54 and the exhaust gas leaves the mixing chamber 14 through exhaust gas flow path 52 after being cleaned.
- Figure 4 shows an embodiment of the exhaust gas cleaning apparatus 100 with a reservoir 20 for the cold flame gas.
- the cold flame gas generator 16 is connected to the mixing chamber 14 via fluid line 62.
- the reservoir 20 is connected to the cold flame gas generator 16 via fluid line 63 which is connected to fluid line 62, as shown in the figure, or directly to the cold flame gas generator 16.
- Valve means 87 controls and regulates the flow of fluid from the cold flame gas generator 16 to the reservoir 20.
- the reservoir 20 is connected to the mixing chamber 14 via fluid line 64 which is connected to fluid line 62, as shown in the figure, or directly to the mixing chamber 14.
- Valve means 88 controls and regulates the flow of cold flame gas from the reservoir 20 to the mixing chamber 14.
- Valve means 86 controls and regulates the flow of cold flame gas through flow line 62 directly to the mixing chamber 14. Thus, if valve means 87, 88 are closed, the fluid line 62 can act as a bypass fluid line for the reservoir 20.
- Figure 5 shows an embodiment of the exhaust gas cleaning apparatus 100 in which there is included an EGR-loop 68.
- the fuel tank 10 is connected to the combustion chamber 12 via fluid line 50.
- the combustion chamber 12 is connected to the mixing chamber 14 via exhaust gas flow path 51. After the mixing chamber 14 the exhaust gas leaves through the exhaust gas flow path 52.
- the cold flame gas generator 16 is connected to the fuel tank 10 via fluid line 53 and valve means 80 controls and regulates the flow of hydrocarbon fuel to the cold flame gas generator 16.
- the air supply 17 supplies air to the cold flame generator 16 through fluid line 54.
- the exhaust gas cleaning apparatus 100 preferably includes feeding means (not shown in the figures) for feeding the combustible matter into the combustion chamber.
- the fuel tank 10 preferably feeds hydrocarbon fuel to the cold flame gas generator 16 only.
- the cold flame gas generator 16 is connected to the mixing chamber 14 through fluid lines 65 and 66.
- Valve means 89 controls and regulates the flow of cold flame gas from the cold flame gas generator 16 to the mixing chamber 14.
- the EGR-loop in its simplest form, includes a fluid line 68 which is connected to the exhaust gas flow path 52, as shown on the figure, or alternatively to exhaust gas flow path 51, and to the combustion chamber 12 (this is not shown on the figure) such that a portion of the exhaust gas can be returned to the combustion chamber 12.
- Valve means 91 controls and regulates the flow of exhaust gas through the EGR-loop.
- the EGR-loop shown on figure 5 also includes a EGR-loop particle filter 22 for removal of any particulate matter like soot, which may be present in the exhaust gas.
- the particle filter is connected to the exhaust gas flow path 51, 52 via the above mentioned fluid line 68 and to the combustion chamber 12 via fluid line 69. Furthermore, a fluid line 61 connects the EGR-loop particle filter 22 to the fluid line 65 and thereby the cold flame generator 16, such that the EGR-loop particle filter 22 may be regenerated when it is becoming clogged by soot. Valve means 90 controls and regulates the flow of cold flame gas from the cold flame gas generator 16 to the EGR-loop particle filter 22.
- Figure 6 shows an embodiment of the exhaust gas cleaning apparatus 100 in which includes a reservoir 20 as described in connection with the embodiment shown in figure 4, an EGR-loop as described in connection with the embodiment shown in figure 5, cold flame gas generator 16 as described in connection with all embodiments except the embodiment in figure 2 and a combustion chamber 12 and a mixing chamber 14 as described in connection with the embodiment shown on for example figure 1. These features will therefore not be explained again.
- the embodiment shown on figure 6 does also includes an exhaust gas flow path particle filter 24 connected to the combustion chamber 12 via exhaust gas flow path 73 and to the mixing chamber 14 via exhaust gas flow path 74.
- the exhaust gas flow path particle filter 24 is also connected to the cold flame gas generator via fluid lines 70 and 71 such that regeneration of the exhaust gas flow path particle filter 24 may take place when the exhaust gas flow path particle filter 24 gets clogged by soot.
- Valve means 92 controls the flow of cold flame gas from the cold flame gas generator 16 to the exhaust gas flow path particle filter 24.
- the EGR-loop particle filter 22 is connected to the cold flame gas generator 16 via fluid lines 70 and 72 for regeneration of the EGR-loop particle filter 22 when it is clogged by soot.
- Valve means 93 controls and regulates the flow of cold flame gas from the cold flame gas generator 16 to the EGR-loop particle filter 22.
- an oxidation catalyst 26 arranged downstream the mixing chamber 14.
- the oxidation catalyst 26 oxidizes substances like hydrocarbons and CO which may still be present in the exhaust gas after the mixing chamber 14.
- an air supply 28 may be connected to exhaust gas flow path 79 such that air can be fed into the exhaust gas before entering the oxidation catalyst 26.
- the addition of air can be used to control the temperature in the oxidation catalyst 26 and to ensure that there is enough oxygen present for the oxidation process.
- Valve means 97 controls and regulates the flow of air into the exhaust gas flow path 79.
- Figure 7 shows an embodiment of the exhaust gas cleaning apparatus 100 which is similar to the embodiment shown on figure 3.
- the embodiment in figure 7 does, however, include heating means 30 for the reservoir 18 and heating means 32 for the cold flame gas generator 16.
- the heating means 30, 32 may, as shown in this embodiment of the invention, be heat exchangers which utilizes the heat energy in the exhaust gas to heat the cold flame gas in the reservoir 18 or the cold flame gas generator 16.
- the heating means 32 is connected to the exhaust gas flow path 51, as shown on the figure, or alternatively to exhaust gas flow path 52, via fluid lines 75 and 77 for incoming exhaust gas and fluid lines 78 and 76 for outgoing exhaust gas.
- Valve means 96 controls and regulates the flow of exhaust gas through the heating means 30 based on the temperature of the cold flame gas in the reservoir 18, which must be kept above the condensation point for the cold flame gas.
- the heating means 32 is connected to the exhaust gas flow path 51, or alternatively exhaust gas flow path 52, by fluid line 75 for incoming exhaust gas and fluid line 76 for outgoing exhaust gas.
- Valve means 95 controls and regulates the flow of exhaust gas through the heating means 32.
- Valve means 94 may also be included. The other features shown on figure 7 are explained in connection with the embodiment shown on figure 3 and will not be repeated here.
- control unit which registers temperature, pressure and other relevant measurements and controls the valve means and other functions of the exhaust gas cleaning apparatus 100 which are controllable, based on the measurements.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Toxicology (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Exhaust Gas After Treatment (AREA)
- Exhaust-Gas Circulating Devices (AREA)
- Incineration Of Waste (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10707981.6A EP2406546B1 (en) | 2009-02-27 | 2010-02-26 | Exhaust gas cleaning apparatus and method for cleaning an exhaust gas |
CN2010800184715A CN102439361A (en) | 2009-02-27 | 2010-02-26 | Exhaust gas cleaning apparatus and method for cleaning an exhaust gas |
CA2753906A CA2753906A1 (en) | 2009-02-27 | 2010-02-26 | Exhaust gas cleaning apparatus and method for cleaning an exhaust gas |
US13/203,487 US20120051990A1 (en) | 2009-02-27 | 2010-02-26 | Exhaust gas cleaning apparatus and method for cleaning an exhaust gas |
JP2011552000A JP2012519249A (en) | 2009-02-27 | 2010-02-26 | Exhaust gas purification device and exhaust gas purification method |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0903447.1 | 2009-02-27 | ||
GB0903447A GB2468159B (en) | 2009-02-27 | 2009-02-27 | Exhaust gas cleaning apparatus and method for cleaning an exhaust gas |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010098677A2 true WO2010098677A2 (en) | 2010-09-02 |
WO2010098677A3 WO2010098677A3 (en) | 2011-05-05 |
Family
ID=40565904
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/NO2010/000075 WO2010098677A2 (en) | 2009-02-27 | 2010-02-26 | Exhaust gas cleaning apparatus and method for cleaning an exhaust gas |
Country Status (7)
Country | Link |
---|---|
US (1) | US20120051990A1 (en) |
EP (1) | EP2406546B1 (en) |
JP (1) | JP2012519249A (en) |
CN (1) | CN102439361A (en) |
CA (1) | CA2753906A1 (en) |
GB (1) | GB2468159B (en) |
WO (1) | WO2010098677A2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101802353B (en) * | 2007-08-30 | 2013-04-17 | 酷焰技术有限公司 | Exhaust gas apparatus and method for the regeneration of a Nox trap and a particle filter |
GB2510171B (en) | 2013-01-28 | 2015-01-28 | Cool Flame Technologies As | Method and cleaning apparatus for removal of SOx and NOx from exhaust gas |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6793693B1 (en) | 1998-07-29 | 2004-09-21 | Heinrich Köhne | Method for utilizing a fuel by using exothermic pre-reactions in the form of a cold flame |
Family Cites Families (19)
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DE3608838A1 (en) * | 1986-03-17 | 1987-09-24 | Fev Forsch Energietech Verbr | METHOD FOR REGENERATING FILTER SYSTEMS FOR THE EXHAUST GASES OF COMBUSTION ENGINES |
JPH05222923A (en) * | 1992-02-06 | 1993-08-31 | Hino Motors Ltd | Nox-in-engine-exhaust-gas reducing device by means of catalyst |
JP3421958B2 (en) * | 1995-09-22 | 2003-06-30 | 日野自動車株式会社 | Exhaust gas purification device for turbocharged engine |
JP4423727B2 (en) * | 2000-03-02 | 2010-03-03 | 日産自動車株式会社 | Internal combustion engine with fuel reformer |
JP3815215B2 (en) * | 2000-12-11 | 2006-08-30 | 日産自動車株式会社 | Exhaust gas purification device for internal combustion engine |
WO2004046514A1 (en) * | 2002-11-15 | 2004-06-03 | Catalytica Energy Systems, Inc. | Devices and methods for reduction of nox emissions from lean burn engines |
EP1594594B1 (en) * | 2003-02-12 | 2012-05-23 | Delphi Technologies, Inc. | SYSTEM FOR NOx ABATEMENT |
DE10354368A1 (en) * | 2003-11-20 | 2005-06-30 | Enginion Ag | Motor vehicle with internal combustion engine and auxiliary unit |
GB2408470B (en) * | 2003-11-25 | 2007-06-13 | Arvin Internat | An internal combustion engine exhaust system |
JP2007518551A (en) * | 2003-12-29 | 2007-07-12 | ナンヤン テクノロジカル ユニヴァーシティ | System and method of using a cold hydrogen flame for the decomposition of volatile organic compounds (VOCS) and odorous substances |
US20050274107A1 (en) * | 2004-06-14 | 2005-12-15 | Ke Liu | Reforming unvaporized, atomized hydrocarbon fuel |
EP1791783A1 (en) * | 2004-09-20 | 2007-06-06 | Shell Internationale Research Maatschappij B.V. | A process for the catalytic partial oxidation of a liquid hydrocarbonaceous fuel |
JP2006242020A (en) * | 2005-03-01 | 2006-09-14 | Hino Motors Ltd | Exhaust emission control device |
JP2007009701A (en) * | 2005-06-28 | 2007-01-18 | Hino Motors Ltd | Exhaust emission control device for engine |
WO2007037652A1 (en) * | 2005-09-30 | 2007-04-05 | Korea Institute Of Energy Research | Heating device for exhaust gas in internal-combustion engine |
JP2007177672A (en) * | 2005-12-27 | 2007-07-12 | Hino Motors Ltd | Exhaust emission control device |
CA2539232C (en) * | 2006-03-22 | 2008-01-08 | Westport Research Inc. | Multi-fuel storage system and method of storing fuel in a multi-fuel storage system |
FR2902828B1 (en) * | 2006-06-27 | 2008-09-26 | Renault Sas | EXHAUST LINE OF A DIESEL ENGINE AND METHOD OF DESULFATATION |
CN101802353B (en) * | 2007-08-30 | 2013-04-17 | 酷焰技术有限公司 | Exhaust gas apparatus and method for the regeneration of a Nox trap and a particle filter |
-
2009
- 2009-02-27 GB GB0903447A patent/GB2468159B/en not_active Expired - Fee Related
-
2010
- 2010-02-26 EP EP10707981.6A patent/EP2406546B1/en active Active
- 2010-02-26 CN CN2010800184715A patent/CN102439361A/en active Pending
- 2010-02-26 WO PCT/NO2010/000075 patent/WO2010098677A2/en active Application Filing
- 2010-02-26 JP JP2011552000A patent/JP2012519249A/en active Pending
- 2010-02-26 CA CA2753906A patent/CA2753906A1/en not_active Abandoned
- 2010-02-26 US US13/203,487 patent/US20120051990A1/en not_active Abandoned
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6793693B1 (en) | 1998-07-29 | 2004-09-21 | Heinrich Köhne | Method for utilizing a fuel by using exothermic pre-reactions in the form of a cold flame |
Also Published As
Publication number | Publication date |
---|---|
GB0903447D0 (en) | 2009-04-08 |
EP2406546B1 (en) | 2015-12-23 |
EP2406546A2 (en) | 2012-01-18 |
CN102439361A (en) | 2012-05-02 |
JP2012519249A (en) | 2012-08-23 |
CA2753906A1 (en) | 2010-09-02 |
WO2010098677A3 (en) | 2011-05-05 |
GB2468159A (en) | 2010-09-01 |
US20120051990A1 (en) | 2012-03-01 |
GB2468159B (en) | 2011-11-09 |
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