WO2010079712A1 - Fuel gas production method - Google Patents
Fuel gas production method Download PDFInfo
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- WO2010079712A1 WO2010079712A1 PCT/JP2009/071627 JP2009071627W WO2010079712A1 WO 2010079712 A1 WO2010079712 A1 WO 2010079712A1 JP 2009071627 W JP2009071627 W JP 2009071627W WO 2010079712 A1 WO2010079712 A1 WO 2010079712A1
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- water
- fuel gas
- tourmaline
- oil
- emulsion
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
- C10L1/328—Oil emulsions containing water or any other hydrophilic phase
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0222—Preparation of oxygen from organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0222—Preparation of oxygen from organic compounds
- C01B13/0225—Peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1217—Alcohols
- C01B2203/1223—Methanol
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1217—Alcohols
- C01B2203/1229—Ethanol
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1252—Cyclic or aromatic hydrocarbons
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Definitions
- the present invention mainly relates to a method for producing fuel gas for producing fuel gas from special water and liquid raw materials such as kerosene.
- Patent Document 1 and Patent Document 2 show a method of producing hydrogen gas from kerosene or the like and water vapor.
- Patent Document 1 hydrogen gas is generated by desulfurizing a liquid raw material such as kerosene in a desulfurizer and mixing the desulfurized liquid raw material and water vapor in a reformer.
- raw material hydrocarbons such as kerosene are brought into contact with a desulfurization catalyst to desulfurize, steam is added to the desulfurized raw material hydrocarbons, and then heated, and the raw material hydrocarbons are brought into contact with a steam reforming catalyst to produce methane.
- High-purity hydrogen is obtained by producing a rich gas and heating the resulting methane-rich gas to contact the steam reforming catalyst.
- Patent Document 1 and Patent Document 2 obtain hydrogen gas by desulfurizing sulfur from a liquid raw material such as kerosene, mixing steam with desulfurized kerosene, or mixing the steam and then heating. .
- a liquid raw material such as kerosene
- an odor such as sulfur is generated when the generated hydrogen gas is burned.
- Patent Document 1 and Patent Document 2 a large amount of fuel such as kerosene is used as a main raw material for obtaining hydrogen, and thus the cost of the main raw material is high.
- the present invention uses a large amount of special water as a main raw material and uses only a small amount of a liquid raw material such as kerosene, thereby producing a fuel gas that produces hydrogen gas and oxygen gas at a low cost. It is intended to provide a method. Another object of the present invention is to provide an inexpensive method for producing fuel gas that can eliminate the generation of odor during combustion without providing a desulfurization step.
- the fuel gas production method according to the present invention is a special water in which water is first passed through an ion exchange resin, and then either tourmaline and rhyolite or granite rock are passed first and the other later. And an emulsion comprising a mixture of a liquid raw material and a vegetable oil, wherein the weight ratio of the special water is 99.4 out of a total of 100% of the weight ratio of the special water, the liquid raw material and the vegetable oil.
- the emulsion containing the weight ratio of the liquid raw material of 0.5% or more and the weight ratio of the vegetable oil of 0.1% or more is contained in a sealed state in a container, and the emulsion in the sealed container is Hydrogen gas and oxygen gas are generated in the sealed container by heating with a heating means.
- the weight ratio of the special water is 89.9% or less, and the weight ratio of the liquid raw material is 10% or more.
- the present invention is characterized in that the emulsion in the airtight container is heated in a state where tourmaline is put in the airtight container.
- the present invention is characterized in that the emulsion in the closed container is heated in a state in which at least one of alumina or silica is put in the tourmaline in the closed container.
- the present invention provides the liquid raw material among kerosene, light oil, a mixture of light oil and kerosene, heavy oil, a mixture of heavy oil and kerosene, gasoline, naphtha, ethanol, methanol, benzene, toluene, xylene, liquefied petroleum gas, and liquefied city gas. It is characterized by having made any one of these.
- the present invention is characterized in that, when the liquid raw material is kerosene, gasoline or naphtha, the vegetable oil is a mixture of castor oil and at least one of rapeseed oil, sunflower oil or rice oil. .
- the present invention is characterized in that when the liquid raw material is any one of light oil, a mixture of light oil and kerosene, heavy oil, a mixture of heavy oil and kerosene, ethanol, and methanol, the vegetable oil is castor oil.
- the rhyolite is a rock composed of at least one of obsidian, pearlite and pine stone.
- the present invention is characterized in that the tourmaline used for producing the special water is mixed with a metal composed of at least one of aluminum, stainless steel and silver.
- an emulsion (liquid emulsion fuel) is produced from special water (creation water), a liquid raw material, and vegetable oil, and the emulsion is heated to produce a fuel gas (hydrogen gas and oxygen gas). ).
- Creation water which is a component that produces an emulsion, contains hydrogen ions (H + ), hydrogen (H 2 ), hydroxyl groups (OH ⁇ ), active hydrogen, dissolved oxygen, and hydronium ions (H 3 O). + ) And hydroxyl ions (H 3 O 2 ⁇ ).
- Liquid raw materials such as kerosene constituting the emulsion are effective for improving the ignitability when igniting the fuel gas and for increasing the combustion temperature of the fuel gas.
- the temperature at which the combustion gas is combusted can be raised to a high temperature by setting the generation water to 90% or less and the liquid raw material such as kerosene to about 10% or more.
- the vegetable oil can be emulsified smoothly by mixing castor oil with at least one of rapeseed oil, sunflower oil or rice oil. be able to. Moreover, the emulsion stable state can be maintained for a long period (from 1 week to 1 month or more).
- FIG. 1 It is a block diagram which shows an example of the manufacturing apparatus which produces the special water used for the manufacturing method of the fuel gas which concerns on this invention. It is sectional drawing of the soft water generator used for the manufacturing apparatus shown in FIG. It is principal part sectional drawing of the ion generator used for the manufacturing apparatus shown in FIG. It is a block diagram which shows the other example of the manufacturing apparatus which produces the special water used for the manufacturing method of the fuel gas which concerns on this invention. It is a block diagram which shows the airtight container used for this invention.
- the fuel gas production method of the present invention is to produce an emulsion mainly from special water, a liquid raw material such as kerosene, and vegetable oil, and produce the fuel gas using the emulsion.
- FIG. 1 is a configuration diagram showing an embodiment of a device for producing fresh water.
- the first soft water generator 10, the second soft water generator 12, the ion generator 14, and the rock storage container 16 are sequentially connected in series via connecting pipes 18 a, 18 b, and 18 c.
- water having a pressure such as tap water is supplied from the water supply pipe 20 to the first soft water generator 10 through the communication pipe 22 to the first soft water generator 10.
- An inlet opening / closing valve 24 such as a faucet is provided between the water supply pipe 20 and the communication pipe 22, and a check valve 26 is provided in the middle of the communication pipe 22.
- a discharge pipe 28 is attached to the outlet side of the rock container 16, and an outlet opening / closing valve 30 is provided at the tip or middle of the discharge pipe 28.
- the water fed from the water supply pipe 20 passes through the first soft water generator 10, the second soft water generator 12, the ion generator 14, and the rock storage container 16 in this order, and the outlet opening / closing valve 30. Is taken out from the discharge pipe 28 by opening.
- the water stored in the water tank is introduced into the first soft water generator 10 via the water supply pipe 20 by a pump. In this case, a check valve 26 is provided between the pump and the first soft water generator 10.
- the first soft water generator 10 and the second soft water generator 12 contain a large amount of granular ion exchange resin 32 therein, and a cross-sectional view thereof is shown in FIG.
- the main bodies 34 of the soft water generators 10 and 12 have a cylindrical shape, and have water inlets 36a and 36b on the upper and lower ends of the cylindrical shape.
- shield members 38a and 38b each having a hole in the center are provided on the inner wall at a position slightly away from the upper and lower end surfaces. Between the pair of shield members 38a, 38b, the ion exchange resin 32 is stored in a fine mesh 40.
- the shield member 38 having a hole in the center is provided on the inner wall at a position slightly apart from the upper and lower entrances 36a, 36b.
- the net 40 containing the ion exchange resin 32 is disposed between the pair of shield members 38. This is because the spaces 42a and 42b are formed in the vicinity of the entrances 36a and 36b.
- the reason why the water is allowed to enter and exit from the central hole of the shield members 38 a and 38 b is that the water always contacts the ion exchange resin 32.
- the reason why the ion exchange resin 32 is put into the net 40 is that the granular ion exchange resin 32 can be taken out together with the net 40 when the granular ion exchange resin 32 is taken out for cleaning.
- the first soft water generator 10 and the second soft water generator 12 have a height of, for example, 80 cm and an inner diameter of 10 cm.
- the storage height of the ion exchange resin 32 is set to 70 cm (the spaces 42 a and 42 b exist above and below). At this time, the storage height of the ion exchange resin 32 needs to be high enough to allow ion exchange with water.
- the storage height of the ion exchange resin 32 becomes too high (for example, when the storage height of the ion exchange resin 32 is about 200 cm or more), the ion exchange resin 32 becomes a resistance of water, and the inside of the soft water generator.
- the storage height of the ion exchange resin 32 is set to a height at which the flow rate does not decrease.
- the container for storing the ion exchange resin 32 is divided into two because the height of the first soft water generator 10 and the second soft water generator 12 is as high as the ion generator 14 and the rock container 16. This is to keep the pressure low and to prevent the flow rate from decreasing due to the pressure loss of water passing therethrough. It is also possible to combine the two soft water generators 10 and 12 into one soft water generator.
- the ion exchange resin 32 is for removing metal ions such as Ca 2+ , Mg 2+, and Fe 2+ contained in water to soften the water. In particular, the water hardness is reduced to zero. It is for lowering to a near extent.
- a strongly acidic cation exchange resin (RzSO 3 Na) obtained by uniformly sulfonating a spherical copolymer of styrene / divinylbenzene is used. This ion exchange resin 32 causes the following ion exchange reaction with metal ions such as Ca 2+ , Mg 2+ and Fe 2+ contained in water.
- the metal ions such as Ca 2+ , Mg 2+, and Fe 2+ are removed from the water by passing through the ion exchange resin 32 to become soft water. Further, by passing through the ion exchange resin 32, Na + , OH ⁇ , and hydronium ions (H 3 O + ) are generated in the water. However, chlorine (Cl) contained in tap water passes through without being ionized. Depending on the type of the ion exchange resin 32, Na + may not be generated.
- FIG. 1 a partial cross-sectional view of the ion generator 14 is shown in FIG.
- the ion generator 14 is configured such that a plurality of cartridges 44 are connected in series in the vertical direction in the same arrangement.
- Each cartridge 44 contains either granular tourmaline 46 or a mixture of granular tourmaline 46 and plate-like metal 48.
- Tourmaline has a positive electrode and a negative electrode.
- the positive electrode and the negative electrode allow water to have an electromagnetic wave having a wavelength of 4 to 14 microns, and cut water clusters to hydronium. This is for generating ions (H 3 O + ).
- the energy of the electromagnetic wave having a wavelength of 4 to 14 microns is 0.004 watt / cm 2 .
- the tourmaline 46 may be a product obtained by finely pulverizing tourmaline stones, but is commercially available with a weight ratio of tourmaline, ceramic, and aluminum oxide (including silver) of about 10:80:10. It may be a tourmaline mixture called a tourmaline pellet. The ceramic contained in this tourmaline pellet acts to separate the positive and negative electrodes.
- the tourmaline 46 disappears in a predetermined period (for example, about 3 months at a diameter of 4 mm) by stirring the water by mixing the tourmaline 46 at a ratio of 10% or more by weight with respect to the ceramic and heating at 800 ° C. or higher. 46 can be made.
- the tourmaline 46 is increased in strength by heating, and the wear period can be extended.
- the ion exchange resin 32 is passed to make the water soft water whose hardness is close to zero, and the tourmalines 46 are rubbed together in the soft water. With soft water having a hardness close to zero, it is possible to prevent magnesium and calcium from adhering to the negative electrode of the tourmaline 46, and it is possible to prevent the tourmaline 46 from acting as a positive and negative electrode.
- the metal 48 at least one kind of metal such as aluminum, stainless steel, or silver is used.
- the metal 48 is preferably a metal that does not generate rust or dissolve in water.
- aluminum has a bleaching action as well as a bactericidal action and an antibacterial action
- stainless steel has a bactericidal action and an antibacterial action
- a cleaning improvement action
- silver has a bactericidal action and an antibacterial action. Yes.
- copper and lead cannot be used because they have toxicity. Also, expensive materials such as gold cannot be used because of cost.
- the weight ratio of the tourmaline 46 and the metal 48 is preferably 10: 1 to 1:10. Beyond that range, there is too much material on one side, and the effects of both materials cannot be demonstrated simultaneously.
- the cartridge 44 has a cylindrical shape with one end open, and a plurality of holes 52 are provided on the bottom surface 50 thereof.
- the size of the hole 52 is set so that the tourmaline 46 and the metal 48 do not pass through the hole 52 of the bottom surface 50.
- each cartridge 44 has a bottom surface 50 provided with a large number of holes 52 on the lower side, and a tourmaline 46 and a metal 48 are placed on the bottom surface 50. And it sets so that the inside of each cartridge 44 may flow from lower to higher.
- each cartridge 44 the water that has passed through the numerous holes 52 in the bottom surface 50 is set so as to be sprayed onto the tourmaline 46 and the metal 48 from the bottom to the top.
- the tap water has a high water pressure
- the water having the water pressure collides with the tourmaline 46 and the metal 48 in the cartridge 44 vigorously, and the tourmaline 46 and the metal 48 are agitated in the cartridge 44 by the power of the water.
- the size and number of the holes 52 are set.
- the cartridges 44 having an inner diameter of 5 cm and a storage volume of 7 cm in depth are stacked in four stages, and the tourmaline 46 and the metal 48 are sufficiently stored in the cartridge 44. Is set to an amount that can move freely within the cartridge 44.
- the number of cartridges 44 may be increased or decreased, or a single cartridge 44 with a larger storage volume may be used.
- the tourmaline 46 and the metal 48 are dispersed in the plurality of cartridges 44 having a small accommodation volume, and the plurality of cartridges 44 are connected, whereby the stirring efficiency of the tourmaline 46 and the metal 48 is increased by the momentum of water. Can be increased.
- each cartridge 44 can be easily attached and detached by means of, for example, screwing, and the tourmaline 46 is easily refilled in each cartridge 44. It can be so.
- the metal 48 does not dissolve in water and need not be replenished. However, the entire cartridge 44 containing the tourmaline 46 and the metal 48 can be replaced.
- the accommodation volume of the cartridge 44 may be changed according to the flow rate of use.
- the tourmaline 46 rubs against each other so that the positive and negative electrodes are dissolved in the water. Further, in order to cut the water cluster and generate a large amount of hydronium ions (H 3 O + ), only the tourmaline 46 may be accommodated in the cartridge 44. However, by mixing the metal 48 with the tourmaline 46, the negative ions generated in the tourmaline 46 when they come into contact with each other can be further increased.
- tourmaline 46 has a plus electrode and a minus electrode
- water (H 2 O) is dissociated into hydrogen ions (H + ) and hydroxide ions (OH ⁇ ).
- hydronium ions (H 3 O + ) having a surface active action are generated by hydrogen ions (H + ) and water (H 2 O).
- the amount of hydronium ions (H 3 O + ) generated is much larger than the amount generated by the ion exchange resin 32.
- a part of the hydronium ion (H 3 O + ) is combined with water (H 2 O) to become a hydroxyl ion (H 3 O 2 ⁇ ) and a hydrogen ion (H + ).
- the water that has passed through the ion generator 14 is then allowed to pass through the inside of the rock container 16 that stores rocks containing a large amount of silicon dioxide (rocks containing approximately 65 to 76% silicon dioxide) among the igneous rocks.
- the igneous rocks (divided into volcanic rocks and plutonic rocks), as rocks 54 containing a large amount of silicon dioxide, volcanic rocks include rhyolite such as obsidian, pearlite, and pine sebite, and plutonic rocks include granite.
- the rock container 16 stores at least one kind of rocks among these rocks. Rhyolite such as obsidian, pearlite and pine stone, or granite has negative electrons.
- rock containing a large amount of silicon dioxide (rhyolite such as obsidian, pearlite, and pine sebite, or granite) have a redox potential of ⁇ 20 to ⁇ 240 mV in the raw state.
- the rock 54 excludes what dissolves in water.
- the rock container 16 is a cylinder having an inner diameter of 10 cm and a height of 80 cm, for example, and a rock 54 containing a large amount of silicon dioxide among igneous rocks having a size of about 5 mm to 50 mm, for example, is reduced in the flow rate of water. Contains no amount.
- water first passes through the ion exchange resin, then passes through tourmaline 46 (or a mixture of tourmaline 46 and metal 48), and then passes through the rock container 16. Things are special water (creative water).
- the creation water includes Na + , Cl ⁇ , H + , OH ⁇ , H 2, hydronium ion (H 3 O + ), hydroxyl ion (H 3 O 2 ⁇ ), and active hydrogen. And a large amount of dissolved oxygen.
- the energy of the water has an electromagnetic wave with a wavelength of 4 to 14 microns, which is 0.004 watt / cm 2 , and an oxidation-reduction potential of ⁇ 20 to ⁇ 240 mV.
- water used in producing the fuel gas production method according to the present invention water was passed in the order of ion exchange resin 32, tourmaline 46 (or a mixture of tourmaline 46 and metal 48), and rock 54. Use fresh water.
- FIG. 1 water is passed in the order of ion exchange resin 32, tourmaline 46 (or a mixture of tourmaline 46 and metal 48), and rock 54, but water is passed in this order, but water is passed through ion exchange resin 32, rock 54, tourmaline 46 (or The tourmaline 46 and the metal 48 may be mixed). That is, as shown in FIG. 4, water may be passed through the first soft water generator 10, the second soft water generator 12, the rock container 16, and the ion generator 14 in this order.
- the water passed through the rock 54 has an oxidation-reduction potential of ⁇ 20 to ⁇ 240 mV. If hot water is used instead of water, the negative redox potential is further stabilized. Furthermore, the water that has passed through the rock 54 contains a large amount of dissolved oxygen and active hydrogen.
- Creation water has many characteristics listed below.
- A There is a surface active action. Creation water contains hydronium ions (H 3 O + ) and hydroxyl ions (H 3 O 2 ⁇ ), and has a surface active action (OW type emulsion emulsification action).
- B There is a weak energy (nurturing light) effect. Tourmaline emits weak energy (electromagnetic waves with a wavelength of 4 to 14 microns). This weak energy cuts a large cluster of water and releases toxic gases and heavy metals contained in the cluster to the outside from the water.
- C It contains hydrogen ions (H + ), hydrogen gas, and hydroxyl groups (OH ⁇ ).
- D It has a redox potential of ⁇ 20 to ⁇ 240 mV.
- E Contains dissolved oxygen and active hydrogen.
- liquid raw material used in the present invention it is desirable to use petroleum-based fuel such as kerosene, but other than petroleum-based fuel (for example, liquefied natural gas or liquefied coal-based gas) may be used.
- petroleum-based fuel such as kerosene
- other than petroleum-based fuel for example, liquefied natural gas or liquefied coal-based gas
- Liquid raw materials include kerosene, light oil, a mixture of light oil and kerosene, heavy oil, a mixture of heavy oil and kerosene, gasoline, naphtha, ethanol, methanol, benzene, toluene, xylene, liquefied petroleum gas (LPG), liquefied city gas ( A liquefied coal-based gas, a liquefied petroleum-based gas, a liquefied natural gas) or the like may be used.
- LPG liquefied petroleum gas
- a liquefied coal-based gas, a liquefied petroleum-based gas, a liquefied natural gas may be used.
- kerosene gasoline or naphtha as a liquid raw material
- a castor oil mixed with at least one of rapeseed oil, sunflower oil or rice oil Creation water and liquid raw material can be emulsified.
- other than kerosene, gasoline or naphtha as liquid raw material light oil, mixture of light oil and kerosene, heavy oil, mixture of heavy oil and kerosene, ethanol, methanol, liquefied petroleum gas, liquefied city gas
- castor oil as vegetable oil
- the created water and the liquid raw material can be emulsified. If fuel gas is generated from an emulsion using vegetable oil as an emulsifier, dioxins are not generated, and environmental pollution can be prevented.
- the weight ratio of the special water is 99.4% or less
- the weight ratio of the liquid raw material is 0.5% or more
- the vegetable oil The weight ratio is 0.1% or more, and the emulsion water of these weights, the liquid raw material, and the vegetable oil are mixed to produce an emulsion.
- the emulsion produced by mixing the creation water, the liquid raw material, and the vegetable oil is stored in the container 60.
- the creation water, the liquid raw material, and the vegetable oil may be separately put in the container 60 and mixed and stirred to produce an emulsion composed of the creation water, the liquid raw material, and the vegetable oil in the container 60.
- the upper opening of the container 60 is closed with a lid 62, and the inside of the container 60 is sealed.
- the lid 62 is provided with a nozzle 66 having a communication passage 64 formed therein for communication between the inside of the container and the outside of the container.
- An opening / closing valve 68 for opening and closing the communication passage 64 is provided in the middle of the nozzle 66. Yes.
- a barometer 70 that measures the pressure inside the container 60
- a thermometer 72 that measures the temperature inside the container 60 are attached.
- the upper shape of the container 60 is preferably a conical shape or a pyramid shape such that the horizontal cross section gradually narrows toward the lid 62.
- a heating means 74 for heating the emulsion in the container 60 is provided below the bottom surface of the container 60.
- the heating means 74 is not limited to thermal power, and the arrangement position of the heating means 74 is not limited to the lower part of the bottom surface.
- the container 60 is filled with, for example, a liquid emulsion at a height of about 1 ⁇ 4 to 3, and the container 60 is covered with a lid 62 so that the container 60 is sealed. Heat the emulsion inside.
- the heating means 74 may be anything that produces a heating temperature to the extent that the emulsion in the sealed container 60 is boiled (e.g., that produces a heating temperature up to about 400 ° C.), and in particular, needs to produce a high temperature of about 1000 ° C.
- the pressure in the container 60 is increased by the fuel gas generated from the emulsion heated and boiled in the container 60. Since the maximum pressure in the container 60 due to the heated and boiled gas is defined by each country, for example, when the pressure in the sealed container 60 exceeds about 50% of the specified pressure, the heating force by the heating means 74 is reduced or the heating is stopped. Then, the heating force by the heating means 74 is adjusted so that the pressure in the sealed container 60 does not reach the specified pressure.
- a large amount of oxygen gas is generated in the sealed container 60 from hydroxyl groups (OH ⁇ ), hydroxyl ions (H 3 O 2 ⁇ ), and dissolved oxygen. Further, vaporized kerosene or the like is generated in the sealed container 60. That is, it is considered that the fuel gas generated by the present invention is composed of hydrogen gas, oxygen gas, vaporized kerosene and the like (which may be natural gas or the like).
- the liquid raw material uses liquefied petroleum gas or liquefied city gas (liquefied coal-based gas, liquefied petroleum-based gas, liquefied natural gas), a large amount of hydrogen gas may be generated from liquefied petroleum gas or liquefied city gas. It is clear from the experiment.
- high-pressure fuel gas hydrogen gas, oxygen gas, vaporized kerosene, etc. in the sealed container 60 is mixed from the nozzle 66. Is sprayed toward the outside of the container 60.
- the gas injected from the nozzle 66 to the outside is ignited, it becomes a powerful flame and burns. It can be seen that the fuel gas contains a large amount of hydrogen gas because it does not burn only with oxygen gas and combustion continues with the weight ratio of liquid raw materials such as kerosene being as low as about 1%, for example. .
- the liquid raw material such as kerosene is gradually increased in weight ratio, for example, from 1% to 10% or 20%, so that the ignition state is improved and the flame is increased.
- liquid raw materials such as kerosene are vaporized by heating and are effective in improving the ignitability of the fuel gas and increasing the combustion temperature.
- the weight ratio of the liquid raw material such as kerosene is increased, the combustion temperature of the fuel gas increases.
- the weight ratio of the liquid raw material such as kerosene becomes 10% or more, the flame becomes large and the combustion temperature increases.
- the weight ratio of the liquid raw material such as kerosene may be 10% or more.
- the combustion temperature by the fuel gas can be gradually increased, but it is not necessary to increase the weight ratio of the liquid raw material such as kerosene to 30% or more from the viewpoint of economic efficiency. Conceivable.
- hydrogen peroxide H 2 O 2
- Hydrogen peroxide mixed in the emulsion is 0.1% or more with respect to 100% of the weight of the emulsion.
- a mixture of hydrogen peroxide and emulsion is placed in a sealed container 50, and the sealed container 60 in which the emulsion and hydrogen peroxide are mixed is heated by the heating means 74.
- the heating means 74 By adding hydrogen peroxide into the sealed container 60 and heating with the heating means 74, not only oxygen gas is generated from the hydrogen peroxide itself, but also a large amount of oxygen gas is generated from the created water. That is, it is considered that the generation of a large amount of oxygen gas from the created water is induced by hydrogen peroxide.
- the amount of oxygen generated from the generation water is 0.0 ml after 0 hours, 2.0 ml after 24 hours, 7.2 ml after 48 hours, 14.8 ml after 72 hours, and 33.5 ml after 96 hours. Met.
- the amount of oxygen generated from tap water is 0.0 ml after 0 hours, 0.0 ml after 24 hours, and 0.0 ml after 48 hours. After 72 hours, the amount was 0.6 ml, and after 96 hours, the amount was 1.2 ml. From this test result, it can be seen that the amount of generated oxygen is significantly higher in the case where hydrogen peroxide is mixed with fresh water than in the case where hydrogen peroxide is mixed with tap water.
- This test result is obtained by allowing the mixed material to stand in a thermostatic chamber.
- a mixture of the creation water and hydrogen peroxide is heated in the sealed container 60, so that the mixture of the creation water and hydrogen peroxide (from tap water and excess water) is heated. It can be seen that a large amount of oxygen is generated in a short time compared to a mixture with hydrogen oxide).
- methane gas and ethane gas are also used in small amounts compared to the amount of oxygen generated. appear. These methane gas and ethane gas are used when the high-pressure fuel gas in the sealed container 60 (a mixture of hydrogen gas, oxygen gas, vaporized kerosene, etc.) is injected from the nozzle 66 toward the outside of the container 60. It promotes the combustion.
- the high-pressure fuel gas in the sealed container 60 a mixture of hydrogen gas, oxygen gas, vaporized kerosene, etc.
- tourmaline 76 is put in the sealed container 60.
- the sealed container 60 containing the emulsion and tourmaline 76 is heated by the heating means 74, the plus and minus electrodes of the tourmaline 46 are dissolved into the liquid emulsion by heat and pressure, and the emulsion is constituted by plus and minus electricity. A large amount of active hydrogen is generated from the created water.
- the active hydrogen generated in a large amount decomposes the sulfur content from the liquid raw material such as kerosene, the fuel gas does not contain the sulfur content, and no odor is generated even if the fuel gas is burned.
- the tourmaline 76 is added, at least one material 78 of alumina or silica may be mixed together. Sulfur can be decomposed with active hydrogen generated in large quantities by tourmaline 76, but by mixing alumina or silica with tourmaline 76 in tourmaline 76, sulfur can be more reliably removed from liquid raw materials such as kerosene contained in the emulsion. be able to.
- the material 78 made of at least one of alumina and silica promotes the desulfurization effect from the emulsion. As a result, the odor can be completely extinguished when the fuel gas generated in the sealed container 60 is burned.
- the tourmaline 46 may be a granular material obtained by finely pulverizing tourmaline stone, the weight ratio of tourmaline, ceramic, and aluminum oxide (including silver) is about 10:80:10. It may be a tourmaline mixture called a commercially available tourmaline pellet.
- the ceramic contained in the tourmaline pellet has a function of generating a positive electrode and a negative electrode.
- the weight ratio of tourmaline, ceramic and aluminum oxide is preferably about 10: 1 to 1:10. Beyond that range, there is too much material on one side, and the effects of both materials cannot be demonstrated simultaneously.
- the amount of tourmaline 76 or the mixture of tourmaline 76 and at least one material 78 of alumina or silica that is put into the sealed container 60 is, for example, at least enough to satisfy the bottom surface of the sealed container 60.
- a special water (creative water) is produced from a liquid raw material such as kerosene and vegetable oil, and the emulsion is heated to produce a fuel gas containing hydrogen gas and oxygen gas. Is to be manufactured. Moreover, by producing the fuel gas with a large weight ratio of water (creation water), that is, a small weight ratio of the liquid raw material, a fuel gas containing hydrogen gas and oxygen gas can be produced at a low cost. Is.
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Abstract
Description
12 第2軟水生成器
14 イオン生成器
16 岩石収納器
32 イオン交換樹脂
46 トルマリン
48 金属
54 岩石
60 容器
62 蓋
66 ノズル
74 加熱手段
76 トルマリン
78 トルマリンとアルミナかシリカの少なくとも1つの材料 DESCRIPTION OF
2RzSO3Na + Ca2+ → (RzSO3)2Ca + 2Na+
2RzSO3Na + Mg2+ → (RzSO3)2Mg + 2Na+
2RzSO3Na + Fe2+ → (RzSO3)2Fe + 2Na+
即ち、イオン交換樹脂32を通すことによって、水に含まれているCa2+やMg2+やFe2+等を除去することができる。イオン交換樹脂32として強酸性カチオン交換樹脂(RzSO3Na)を用いることによって、ナトリウムイオン(Na+)が発生する。イオン交換樹脂32は、Na+以外のものが発生するものであっても構わないが、Na+を発生するものの方が好ましい。水が水道水であれば、その水道水の中にはCa2+やMg2+やFe2+等の金属イオンの他に塩素が含まれているが、水道水がイオン交換樹脂32を通ることによって、この塩素には何も変化が生じない。 The
2RzSO 3 Na + Ca 2+ → (RzSO 3 ) 2 Ca + 2Na +
2RzSO 3 Na + Mg 2+ → (RzSO 3 ) 2 Mg + 2Na +
2RzSO 3 Na + Fe 2+ → (RzSO 3 ) 2 Fe + 2Na +
That is, by passing the
H2O → H+ + OH- ・・・(1)
H2O + H+ → H3O+ ・・・(2)
即ち、(1)(2)に示すように、イオン交換樹脂32を通ることによって、水からは水酸化イオン(OH-)とヒドロニウムイオン(H3O+)とが発生する。 On the other hand, when water (H 2 O) passes through the
H 2 O → H + + OH − (1)
H 2 O + H + → H 3 O + (2)
That is, as shown in (1) and (2), hydroxide ions (OH − ) and hydronium ions (H 3 O + ) are generated from water by passing through the
H2O → H+ + OH- ・・・(1)
更に、水素イオン(H+)と水(H2O)とによって、界面活性作用を有するヒドロニウムイオン(H3O+)が発生する。このヒドロニウムイオン(H3O+)の発生量は、前記イオン交換樹脂32によって発生する量よりはるかに多い量である。
H2O + H+ → H3O+ ・・・(2)
このヒドロニウムイオン(H3O+)の一部は、水(H2O)と結びついてヒドロキシルイオン(H3O2 -)と水素イオン(H+)になる。
H3O+ + H2O → H3O2 - + 2H+ ・・・(3) Since
H 2 O → H + + OH − (1)
Further, hydronium ions (H 3 O + ) having a surface active action are generated by hydrogen ions (H + ) and water (H 2 O). The amount of hydronium ions (H 3 O + ) generated is much larger than the amount generated by the
H 2 O + H + → H 3 O + (2)
A part of the hydronium ion (H 3 O + ) is combined with water (H 2 O) to become a hydroxyl ion (H 3 O 2 − ) and a hydrogen ion (H + ).
H 3 O + + H 2 O → H 3 O 2 − + 2H + (3)
Cl + e- → Cl- ・・・(4)
このCl-と前記Na+とはイオンとして安定した状態になる。安定した状態とは、蒸発することなくイオン状態が長期間保たれることを意味する。また、前記ヒドロキシルイオン(H3O2 -)もイオンとして安定した状態になる。水が岩石54を通過することによって、イオン生成器14を通過した水と比べて、ヒドロニウムイオン(H3O+)が更に発生し、かつヒドロキシルイオン(H3O2 -)も水素イオン(H+)も更に発生する。
H2O + H+ → H3O+ ・・・(2)
H3O+ + H2O → H3O2 - + 2H+ ・・・(3)
水が岩石54を通過することによって、その他に、以下の反応も発生する。
OH- + H+ → H2O ・・・(5)
2H+ + 2e- → 2H2 ・・・(6)
更に、水が岩石収納器16を通過すると、岩石54のマイナス電子によって、水の酸化還元電位が+340mVから-20~-240mVになる。水に代えてお湯を使うと、マイナスの酸化還元電位がより安定する。更に、岩石54を通過した水は、溶存酸素や活性水素を大量に含む。 When the water that has passed through the
Cl + e - → Cl - ··· (4)
This Cl − and the Na + are in a stable state as ions. The stable state means that the ionic state is maintained for a long time without evaporating. The hydroxyl ion (H 3 O 2 − ) is also stable as an ion. By passing the water through the
H 2 O + H + → H 3 O + (2)
H 3 O + + H 2 O → H 3 O 2 − + 2H + (3)
In addition to the passage of water through the
OH − + H + → H 2 O (5)
2H + + 2e − → 2H 2 (6)
Further, when water passes through the
Cl + e- → Cl- ・・・(4)
このCl-とイオン交換樹脂32によって発生したNa+とはイオンとして安定した状態になる。なお、イオン交換樹脂32を通過した水であっても、Na+を含まない場合もある。
イオン交換樹脂32を通過した水には、前記(1)(2)に示すように、H+とOH-とヒドロニウムイオン(H3O+)とが存在する。イオン交換樹脂32を通過した水が、その後、岩石54を通過することによって、以下の反応も発生する。
OH- + H+ → H2O ・・・(5)
H2O + H+ → H3O+ ・・・(2)
2H+ + 2e- → 2H2 ・・・(6)
この反応においては、ヒドロニウムイオン(H3O+)が、イオン交換樹脂32によって発生する量よりも更に多くの量が発生する。
以上のように、イオン交換樹脂32の後に岩石54を通過することによって、水の中に従来から存在したNa+とOH-と、新たに発生するCl-とヒドロニウムイオン(H3O+)とが存在することになる。また、岩石54を通過させた水は、酸化還元電位が-20~-240mVになる。水に代えてお湯を使うと、マイナスの酸化還元電位が更に安定する。更に、岩石54を通過した水は、溶存酸素や活性水素を大量に含む。 In FIG. 4, the water that has passed through the
Cl + e - → Cl - ··· (4)
This Cl − and Na + generated by the
The water that has passed through the
OH − + H + → H 2 O (5)
H 2 O + H + → H 3 O + (2)
2H + + 2e − → 2H 2 (6)
In this reaction, a larger amount of hydronium ions (H 3 O + ) than that generated by the
As described above, by passing through the
H2O → H+ + OH- ・・・(1)
H2O + H+ → H3O+ ・・・(2)
このヒドロニウムイオン(H3O+)は大量に発生する。またヒドロニウムイオン(H3O+)の一部はヒドロキシルイオン(H3O2 -)になる。
H3O+ + H2O → H3O2 - + 2H+ ・・・(3)
この結果、トルマリン46と金属48を通過させた水には、ヒドロニウムイオン(H3O+)と、ヒドロキシルイオン(H3O2 -)と、OH-と、H+とが増加する。 The water that has passed through the
H 2 O → H + + OH − (1)
H 2 O + H + → H 3 O + (2)
This hydronium ion (H 3 O + ) is generated in large quantities. A part of the hydronium ion (H 3 O + ) becomes a hydroxyl ion (H 3 O 2 − ).
H 3 O + + H 2 O → H 3 O 2 − + 2H + (3)
As a result, hydronium ions (H 3 O + ), hydroxyl ions (H 3 O 2 − ), OH − , and H + increase in water that has passed through the
(a)界面活性作用がある。
創生水はヒドロニウムイオン(H3O+)及びヒドロキシルイオン(H3O2 -)を含み、界面活性作用(OW型エマルジョン乳化作用)を有する。
(b)微弱エネルギ(育成光線)作用がある。
トルマリンは微弱エネルギ(4~14ミクロンの波長の電磁波)を放出する。この微弱エネルギは水の大きいクラスターを切断して、クラスター内に抱えこまれていた有毒ガスや重金属類を水から外部に放出する。
(c)水素イオン(H+)と、水素ガスと、水酸基(OH-)とを含んでいる。
(d)-20~-240mVの酸化還元電位を有している。
(e)溶存酸素や活性水素を含んでいる。 Creation water has many characteristics listed below.
(A) There is a surface active action.
Creation water contains hydronium ions (H 3 O + ) and hydroxyl ions (H 3 O 2 − ), and has a surface active action (OW type emulsion emulsification action).
(B) There is a weak energy (nurturing light) effect.
Tourmaline emits weak energy (electromagnetic waves with a wavelength of 4 to 14 microns). This weak energy cuts a large cluster of water and releases toxic gases and heavy metals contained in the cluster to the outside from the water.
(C) It contains hydrogen ions (H + ), hydrogen gas, and hydroxyl groups (OH − ).
(D) It has a redox potential of −20 to −240 mV.
(E) Contains dissolved oxygen and active hydrogen.
Claims (9)
- 水を最初にイオン交換樹脂に通過させその後にトルマリンと流紋岩か花崗岩かの岩石とのどちらか一方を先に他方を後に通過させた特殊な水と、液体原料と、植物油とを混合して成るエマルジョンであって、前記特殊な水と前記液体原料と前記植物油の重量比の合計100%のうち、前記特殊な水の重量比を99.4%以下とし、前記液体原料の重量比を0.5%以上とし、前記植物油の重量比を0.1%以上としたエマルジョンを容器内に密閉状態で収容し、前記密閉容器内の前記エマルジョンを加熱手段で加熱することで密閉容器内に水素ガスと酸素ガスとを発生させることを特徴とする燃料ガスの製造方法。 The water is first passed through the ion exchange resin and then mixed with special water that has passed either tourmaline and rhyolite or granite rocks first and then the other, liquid feed, and vegetable oil. The total weight ratio of the special water, the liquid raw material, and the vegetable oil is 100%, the special water weight ratio is 99.4% or less, and the liquid raw material weight ratio is An emulsion containing 0.5% or more and a weight ratio of the vegetable oil of 0.1% or more is stored in a sealed state in a container, and the emulsion in the sealed container is heated by a heating means in a sealed container. A method for producing a fuel gas, characterized by generating hydrogen gas and oxygen gas.
- 前記特殊な水の重量比を89.9%以下とし、前記液体原料の重量比を10%以上としたことを特徴とする請求項1記載の燃料ガスの製造方法。 2. The method for producing fuel gas according to claim 1, wherein the weight ratio of the special water is 89.9% or less and the weight ratio of the liquid raw material is 10% or more.
- 前記密閉容器内にトルマリンを入れた状態で前記密閉容器内のエマルジョンを加熱することを特徴とする請求項1または2記載の燃料ガスの製造方法。 The method for producing fuel gas according to claim 1 or 2, wherein the emulsion in the sealed container is heated in a state where tourmaline is placed in the sealed container.
- 前記密閉容器内にトルマリンを入れたものに、アルミナかシリカの少なくとも1つを入れた状態で、前記密閉容器内のエマルジョンを加熱することを特徴とする請求項3記載の燃料ガスの製造方法。 4. The method for producing fuel gas according to claim 3, wherein the emulsion in the sealed container is heated in a state in which at least one of alumina or silica is placed in the tourmaline in the sealed container.
- 前記液体原料を、灯油,軽油,軽油と灯油の混合物,重油,重油と灯油の混合物,ガソリン,ナフサ,エタノール,メタノール,ベンゼン,トルエン,キシレン,液化石油ガス,液化都市ガスのうちのいずれか一つとしたことを特徴とする請求項1乃至4のうちいずれか1項記載の燃料ガスの製造方法。 The liquid raw material is one of kerosene, light oil, a mixture of light oil and kerosene, heavy oil, a mixture of heavy oil and kerosene, gasoline, naphtha, ethanol, methanol, benzene, toluene, xylene, liquefied petroleum gas, and liquefied city gas. The fuel gas production method according to any one of claims 1 to 4, wherein the fuel gas is produced.
- 前記液体原料が灯油またはガソリンまたはナフサの場合に、前記植物油を、ひまし油に菜種油かひまわり油か米油のうちの少なくとも1つを混合したものとしたことを特徴とする請求項5記載の燃料ガスの製造方法。 6. The fuel gas according to claim 5, wherein when the liquid raw material is kerosene, gasoline or naphtha, the vegetable oil is a mixture of castor oil and at least one of rapeseed oil, sunflower oil or rice oil. Manufacturing method.
- 前記液体原料を、軽油,軽油と灯油の混合物,重油,重油と灯油の混合物,エタノール,メタノールのうちのいずれか一つとした場合に、前記植物油をひまし油としたことを特徴とする請求項5記載の燃料ガスの製造方法。 6. The vegetable oil is castor oil when the liquid raw material is any one of light oil, a mixture of light oil and kerosene, heavy oil, a mixture of heavy oil and kerosene, ethanol, and methanol. Fuel gas production method.
- 前記流紋岩は、黒曜石,真珠岩及び松脂岩のうち少なくとも1つから成る岩石としたことを特徴とする請求項1乃至7のうちいずれか1項記載の燃料ガスの製造方法。 The method for producing fuel gas according to any one of claims 1 to 7, wherein the rhyolite is a rock composed of at least one of obsidian, pearlite, and pinestone.
- 前記特殊な水を生成する際に使用するトルマリンにアルミニウム,ステンレス及び銀のうちの少なくとも1つから成る金属を混合させたものとしたことを特徴とする請求項1乃至7のうちいずれか1項記載の燃料ガスの製造方法。 The tourmaline used for producing the special water is a mixture of at least one of aluminum, stainless steel, and silver. The manufacturing method of the fuel gas of description.
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JPH07132284A (en) * | 1993-11-09 | 1995-05-23 | Fukai Toshiko | Method for producing water having purifying activation action and device therefor |
JP2006096667A (en) * | 2002-11-07 | 2006-04-13 | Fukai Takaaki | Method for producing water capable of lowering blood sugar level |
WO2007088923A1 (en) * | 2006-02-03 | 2007-08-09 | Nissan Motor Co., Ltd. | Hydrogen generation system, fuel cell system, and fuel cell vehicle |
WO2008139791A1 (en) * | 2007-05-15 | 2008-11-20 | Toshiharu Fukai | Oil emulsion |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1034491C (en) * | 1994-06-16 | 1997-04-09 | 刘之政 | Hydrogen making method from water and device thereof |
CN2298059Y (en) * | 1997-01-10 | 1998-11-25 | 任洪建 | Device for manufacturing oxygen and hydrogen |
-
2009
- 2009-12-25 KR KR1020117015490A patent/KR20110112317A/en not_active Application Discontinuation
- 2009-12-25 CN CN200980154313XA patent/CN102272038A/en active Pending
- 2009-12-25 JP JP2010545732A patent/JPWO2010079712A1/en active Pending
- 2009-12-25 WO PCT/JP2009/071627 patent/WO2010079712A1/en active Application Filing
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2010
- 2010-01-06 TW TW099100173A patent/TW201033115A/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07132284A (en) * | 1993-11-09 | 1995-05-23 | Fukai Toshiko | Method for producing water having purifying activation action and device therefor |
JP2006096667A (en) * | 2002-11-07 | 2006-04-13 | Fukai Takaaki | Method for producing water capable of lowering blood sugar level |
WO2007088923A1 (en) * | 2006-02-03 | 2007-08-09 | Nissan Motor Co., Ltd. | Hydrogen generation system, fuel cell system, and fuel cell vehicle |
WO2008139791A1 (en) * | 2007-05-15 | 2008-11-20 | Toshiharu Fukai | Oil emulsion |
Also Published As
Publication number | Publication date |
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KR20110112317A (en) | 2011-10-12 |
TW201033115A (en) | 2010-09-16 |
JPWO2010079712A1 (en) | 2012-06-21 |
CN102272038A (en) | 2011-12-07 |
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