WO2010059363A1 - Sulfur-containing cycloaliphatic compound, process for its preparation, filled sulfur-vulcanizable elastomer composition containing same and articles fabricated therefrom - Google Patents

Sulfur-containing cycloaliphatic compound, process for its preparation, filled sulfur-vulcanizable elastomer composition containing same and articles fabricated therefrom Download PDF

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WO2010059363A1
WO2010059363A1 PCT/US2009/062515 US2009062515W WO2010059363A1 WO 2010059363 A1 WO2010059363 A1 WO 2010059363A1 US 2009062515 W US2009062515 W US 2009062515W WO 2010059363 A1 WO2010059363 A1 WO 2010059363A1
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ethyl
toluene
ester
bis
cyclohexyl
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PCT/US2009/062515
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English (en)
French (fr)
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Michael Joseph O'brien
Robert James Perry
Richard W. Cruse
William Michael York
Carla Recker
Thomas Kramer
Katharina Herzog
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Momentive Performance Materials Inc.
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Priority to KR1020117012277A priority Critical patent/KR101687203B1/ko
Priority to CN200980153394.1A priority patent/CN102272212B/zh
Priority to BRPI0920680A priority patent/BRPI0920680A2/pt
Priority to EP09752587.7A priority patent/EP2342275B1/en
Priority to JP2011534751A priority patent/JP5681635B2/ja
Priority to CA2740170A priority patent/CA2740170A1/en
Publication of WO2010059363A1 publication Critical patent/WO2010059363A1/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C381/00—Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C381/00—Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
    • C07C381/04—Thiosulfonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/21—Cyclic compounds having at least one ring containing silicon, but no carbon in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025—Crosslinking or vulcanising agents; including accelerators
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/549—Silicon-containing compounds containing silicon in a ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02—Copolymers with acrylonitrile

Definitions

  • the present invention relates to organosulfur compounds, processes for their preparation, filled sulfur-vulcanizable compositions containing organosulfur compounds as crosslinkers (vulcanizing agents) and articles such as tires, tire tread, weather stripping, hose, belts, seals, gaskets, shoe soles, and the like, fabricated from such compositions.
  • organosulfur compounds as crosslinkers (vulcanizing agents) and articles such as tires, tire tread, weather stripping, hose, belts, seals, gaskets, shoe soles, and the like, fabricated from such compositions.
  • Elemental sulfur is commonly used as a vulcanizing agent for unsaturated diene elastomers (rubbers).
  • the crosslinks formed with sulfur are primarily polysulfidic crosslinks that increase the thermal stability of the elastomer vulcanizates.
  • the bridging group often contains unstable linkages such as ether or ester linkages or lacks the flexibility needed to dissipate energy that can propagate cracks when a crosslinked (cured) elastomer is subjected to mechanical stress.
  • crosslinker for sulfur-vulcanizable elastomers that improves the wear properties of articles manufactured therefrom, e.g., weather stripping, hose, belts, seals, gaskets, shoe soles, tires and tire components, specifically, tear and abrasive wear, while maintaining hardness, lower tan delta values at temperatures above 4O 0 C and increased tan delta values at temperatures of from 5°C to - 15°C.
  • G is a saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO-] n [R 2 SiO-] p group of valence n; each R independently is a monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 1 or 2; n is an integer of from 3 to 6; and p is an integer of from 0 to 3.
  • the foregoing sulfur- containing cycloaliphatic compound is prepared by the process which comprises:
  • a curable filled elastomer composition which comprises:
  • G is a saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO-] n [R 2 SiO-] p group of valence n; each R independently is a monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 1 or 2; n is an integer of from 3 to 6; and, p is an interger of from 0 to 3.
  • an article such as a tire or tire component such as tread, hose, belt, seal, gasket, and the like, is fabricated by molding a quantity of the foregoing curable filled elastomer composition into the shape of the desired article and thereafter curing the composition.
  • Coupled agent means an agent capable of establishing an effective chemical and/or physical bond between a vulcanizable elastomer and its filler.
  • Effective coupling agents have functional groups capable of bonding physically and/or chemically with filler, for example, between a silicon atom of the coupling agent and the hydroxyl (OH) surface groups of the filler to form a surface-O-Si bond, e.g., a siloxane when the surface contains silanols as in the case of silica, and, for example, sulfur atoms which are capable of bonding physically and/or chemically with the elastomer as a result of vulcanization (curing).
  • filler means a substance that is added to the elastomer to either extend the elastomer or to reinforce the elastomeric network.
  • Reinforcing fillers are materials whose moduli are higher than the organic polymer of the elastomeric composition and are capable of absorbing stress from the organic polymer when the elastomer is strained.
  • Fillers include fibers, particulates, and sheet-like structures and can be composed of inorganic materials such as silicates, silica, clays, ceramics, carbon, diatomaceous earth, and organic materials such as organic polymers.
  • the filler can be essentially inert to the other ingredients with which it is admixed or it can be reactive therewith.
  • Particulate filler means a particle or grouping of particles that form aggregates or agglomerates.
  • Particulate fillers that are useful herein can be essentially inert to coupling agents with which they are admixed, e.g., silane coupling agents, or they can be reactive therewith.
  • carrier means a porous polymer or high surface area filler that has a high adsorption or absorption capability and is capable of carrying up to 75 percent liquid ingredient while maintaining its free-flowing and dry properties.
  • Useful carriers herein are essentially inert to liquids and are capable of releasing or deabsorbing liquids when added to the sulfur-vulcanizable elastomeric composition.
  • G is a saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO-] n [R 2 SiO-] p group of valence n; each R independently is a monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 1 or 2; n is an integer of from 3 to 6; and, p is an integer of from 0 to 3.
  • the expression "monovalent hydrocarbon group” means any hydrocarbon group from which one hydrogen atom has been removed and is inclusive of alkyl, alkenyl, alkynyl, cyclic alkyl, cyclic alkenyl, cyclic alkynyl, aryl, aralkyl and arenyl.
  • alkyl means any monovalent, saturated straight, branched or cyclic hydrocarbon group
  • alkenyl means any monovalent straight, branched, or cyclic hydrocarbon group containing one or more carbon-carbon double bonds where the site of attachment of the group can be either at a carbon-carbon double bond or elsewhere therein
  • alkynyl means any monovalent straight, branched, or cyclic hydrocarbon group containing one or more carbon-carbon triple bonds and, optionally, one or more carbon-carbon double bonds, where the site of attachment of the group can be either at a carbon-carbon triple bond, a carbon-carbon double bond or elsewhere therein.
  • alkyls examples include methyl, ethyl, propyl and isobutyl.
  • alkenyls include vinyl, propenyl, allyl, methallyl, ethylidenyl norbornane, ethylidene norbornyl, ethylidenyl norbornene and ethylidene norbornenyl.
  • alkynyls include acetylenyl, propargyl and methylacetylenyl.
  • cyclic alkyl examples include bicyclic, tricyclic and higher cyclic structures as well as the aforementioned cyclic structures further substituted with alkyl, alkenyl, and/or alkynyl groups.
  • Representative examples include norbornyl, norbornenyl, ethylnorbornyl, ethylnorbornenyl, cyclohexyl, ethylcyclohexyl, ethylcyclohexenyl, cyclohexylcyclohexyl and cyclododecatrienyl.
  • aryl means any monovalent aromatic hydrocarbon group
  • aralkyl means any alkyl group (as defined herein) in which one or more hydrogen atoms have been substituted by the same number of like and/or different aryl (as defined herein) groups
  • arenyl means any aryl group (as defined herein) in which one or more hydrogen atoms have been substituted by the same number of like and/or different alkyl groups (as defined herein).
  • aryls include phenyl and naphthalenyl.
  • aralkyls include benzyl and phenethyl.
  • arenyls include tolyl and xylyl.
  • the stereochemistry about the cycloalkyl ring G is usually determined in the preparation of the poly-alkenyl-substituted cycloalkane intermediate or reactant.
  • the reaction conditions can effect the stereochemistry about the cyclohexyl ring. Distillation of the polyalkenyl-substituted cycloalkane or other separation methods such as preparative liquid chromatography can also be used to obtain the desired ratio of stereochemical isomers.
  • Representative and non-limiting examples of monovalent hydrocarbon group R in the sulfur-containing cycloaliphatic compound of the invention are methyl, ethyl, propyl, isopropyl, butyl, 2-ethylhexyl, cyclohexyl, cyclopentyl, phenyl, benzyl, tolyl, xylyl, methylbenyzl, and the like.
  • the divalent linking group, -C 3 H 23 -, between the thiosulfonato group and the cycloalkyl ring can be linear or branched. It is preferred that the -C 3 H 23 - group be linear with the thiosulfonato group being on the terminal position.
  • divalent linking group is methylene, ethylene, propylene, butylene and hexylene.
  • Preferred linking groups are ethylene and propylene.
  • sulfur-containing cycloaliphatic compounds of the invention include: methanethiosulfonic acid 2-[4,6-bis- (2-methanesulfonylsulfanyl-ethyl)-2,4,6-trimethyl-[l,3,5,2,4,6]trioxatrisilinan-2-yl]-ethyl ester; benzenethiosulfonic acid 2-[4,6-bis-(2-benzenesulfonylsulfanyl-ethyl)-2,4,6- trimethyl-[l,3,5,2,4,6]trioxatrisilinan-2-yl]-ethyl ester, toluenethiosulfonic acid 2-[4,6- bis-(2-toluenesulfonylsulfanyl-ethyl)-2,4,6-trimethyl-[l,3,5,2,4,6]trioxatrisilinan-2-yl]
  • Preferred sulfur-containing cycloaliphatic compounds herein include methanethiosulfonic acid S- ⁇ 2-[bis-2,4-(2-methanesulfonylsulfanyl-ethyl)-cyclohexyl]- ethyl ⁇ ester, benzenethiosulfonic acid S- ⁇ 2-[bis-2,4-(2-benzenesulfonylsulfanyl-ethyl)- cyclohexyl]-ethyl ⁇ ester, toluene-4-thiosulfonic acid S- ⁇ 2-[bis-2,4-(2-toluene-4- sulfonylsulfanyl-ethyl)-cyclohexyl]-ethyl ⁇ ester, a mixture comprising of 80 weight percent of toluene-4-thiosulfonic acid S- ⁇ 2-[cis,cis-bis-2,4-(2-toluen
  • the sulfur-containing cycloaliphatic compound of the invention can be prepared by the process which comprises:
  • Step (c): G-[C 3 H 23 -SH] n + n X'-X 2 ⁇ G-[C 3 H 28 -SX '] punish + n HX 2
  • Step (d): G-[C 8 H 23 -SX '] contest + n RS(O) b M + ⁇ G[-C a H 23 -S-S(O) b -R]n + n M + X " , wherein:
  • G is a saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO-] n [R 2 SiO-] p group of valence n; each R independently is a monovalent hydrocarbon of up to 20 carbon atoms; each R 1 independently is a monovalent hydrocarbon of up to 20 carbon atoms; each R 2 independently is a monovalent hydrocarbon of up to 20 carbon atoms or M + , wherein M + is an alkali metal cation; each occurrence of X 1 independently is a halogen atom selected from chlorine, bromine or iodine; each occurrence of X 2 independently is selected from X 1 and a succinimido group; each occurrence of subscripts a, b, and c independently is an integer wherein a is of from 2 to 6; b is 1 or 2; c is of from O to 4; n is an
  • the isomeric mixture of the sulfur-containing cycloaliphatic compounds is determined by the stereochemistry of the polyvalent cycloaliphatic compound containing three to five alkenyl groups, G-[C c H 2c -CHOH 2 ] n where G, c and n are defined above.
  • the stereochemical structure of the reactants is not altered in the addition reaction of the thiocarboxylic acid group in step (a).
  • Trivinylcyclohexanes which are the preferred starting materials for producing the sulfur-containing cycloaliphatic compounds of the present invention, can be formed by pyrolysis of l.S.Q-cyclododecatriene. The conversion of the 1,5,9-cyclododecatriene at elevated temperature, and optionally in the presence of a catalyst, results in the formation of the trivinylcyclohexane compound, as disclosed in U.S. Patent No. 3,011,003 and British Patent No. 848,637, the entire contents of which are incorporated by reference herein.
  • step (a) wherein the thiocarboxylic acid is reacted with a polyvalent cycloaliphatic compound containing three to five alkenyl groups may optionally be carried out in the presence of a free radical reagent.
  • Effective amounts of peroxide or hydroperoxide free radical agent can range from 0.01 to 2, and preferably from 0.1 to 0.5, weight percent based upon the weight of the cycloaliphatic compound containing three to five alkenyl groups.
  • the source of the oxygen can be pure oxygen gas, air or a mixture of oxygen and an inert gas. Mixtures of oxygen and inert gas can contain from 3 to 15 weight percent oxygen with the balance being inert gas. Air or mixtures of oxygen and inert gas are generally preferred due to the difficulties in handling pure oxygen in the presence of organic materials and of these, air is preferred.
  • the source of UV radiation can be a mercury lamp equipped with a quartz window.
  • cycloaliphatic compounds containing three to five alkenyl groups include 1 ,2,4-trivinylcyclohexane, 1,2,4- tripropenylcyclohexane, 1, 3,5-trihexenylcyclohexane, 1,3,5,7-tetravinylcyclooctane, 1,3,5,7,9-pentavinylcyclodecane, and mixtures of at least 80 weight percent cis,cis,cis- 1,2,4-trivinyl cyclohexane and at least 5 weight percent cis-trans-cis- 1,2,4- trivinylcyclohexane.
  • thiocarboxylic acids include thioacetic acid, thiopropanoic acid, thiobutanoic acid, thiohexanoic acid, and the like.
  • peroxide and hydroperoxide free radical reagents include di(2,4-dichlorobenzoyl) peroxide, tert-butyl peroxypivalate, dilauroyl peroxide, dibenzoyl peroxide, tert-butyl peroxy-2-ethylhexanoate, l,l-di(tert- butylperoxy)-3,3,5-trimethylcyclohexane, di(tert-butylperoxy)cyclohexane, tert-butyl peroxy-3,5,5-trimethylhexanoate, tert-butyl peroxyacetate, tert-butyl peroxybenzoate, di-
  • step (a) can be carried out at sub-ambient temperature, ambient temperature or elevated temperature, at sub-atomospheric, atmospheric or supra-atmospheric pressure and in the absence or presence of solvent.
  • a suitable temperature range is from 0 0 C to 200 0 C and is preferably from 40 0 C to 150 0 C.
  • the reaction will ordinarily be run to completion. The time required to achieve this will depend upon the particular reaction conditions employed and whether a catalyst is used. Reaction times of from 5 minutes to 24 hours are usually suitable.
  • atmospheric pressure is used.
  • Typical solvents include hydrocarbon solvents, including aromatic and aliphatic solvents, and chlorinated solvents.
  • the amount of alcohol can vary from stoichimetric to a large excess. Typically, from 1 to 20 equivalents of alcohol are used to affect the transesterification.
  • the acyl group can be removed by saponification in the present of alkali metal hydroxide.
  • Typical alkaline catalysts include lithium hydroxide, sodium hydroxide, potassium hydroxide, sodium methoxide, sodium ethoxide, potassium methoxide, potassium ethoxide, and the like.
  • the halogenation reaction of step (c) is effected by reacting the poly- mercapto-cycloaliphatic compound G-[CaH 28 -SH] n , resulting from step (b) with a halogen-containing oxidizing agent of the structure X ! -X 2 where G, X 1 , X 2 and n are defined above.
  • the halogenation reaction of step (c) can be carried out at sub-ambient temperature, ambient temperature or elevated temperature, at sub-atomospheric, atmospheric or supra-atmospheric pressure and in the absence or presence of solvent.
  • the temperature of the reaction can range from -10 0 C to 200 0 C and is preferably within the range of from 0 0 C to 50 0 C.
  • the reaction will ordinarily be carried out to completion. Reaction times will vary depending upon the reaction condition utilized. Reaction times of from 5 minutes to 24 hours are generally suitable.
  • atmospheric pressure is employed in order to prevent the loss of halogenating reactant.
  • Typical solvents include hydrocarbon solvents, including aromatic and aliphatic solvents, and halogenated solvents, including fluorinated and chlorinated solvents. Perhalogenated solvents, such as carbon tetrachloride are preferred to prevent reaction of the halogenating reactant with the solvent.
  • the reaction shown in step (d) can be carried out at sub-ambient temperature, ambient temperature or at elevated temperature, at sub-atomospheric, atmospheric or supra-atmospheric pressure and in the absence or presence of solvent.
  • the preferred temperature range in from -15°C to 100 0 C. It is also preferred to carry out the reaction in the presence of a solvent, in order to maintain a slurry of the reactants.
  • Aprotic solvents such as aromatic and aliphatic solvent, chlorinated solvents and oxygenated solvent such as ethers, ketones and esters are preferred.
  • the sulfur-containing cycloaliphatic compound of the invention is particularly useful as a crosslinker for sulfur-vulcanizable elastomers (i).
  • the sulfur-containing cycloaliphatic compound therefore has three to five tie points to a rubber molecule. Although not wishing to be constrained by theory, it is believed that higher numbers of tie points, such as greater than 6, can result in a localized area in the bulk rubber that is very crowded and cannot effectively transfer stress, or energy, to the polymer chains or fillers.
  • the orientation enables the reactive groups to attach to different polymer chains thereby improving the crosslinking efficiency.
  • the cycloaliphatic ring is flexible, alternating between boat, chair and twist conformations. Under high stress, the ring is able to change to conformations that offer a pathway for absorbing energy. In the absence of this property, energy would be directed to bond scission resulting in poor wear and fatigue properties in the cured rubber composition.
  • Aromatic rings are planar and stiff and therefore cannot undergo these conformational changes.
  • the preferred conformation about the cycloaliphatic ring, especially when the ring is a 1 ,2,4-substitutedcyclohexyl group, is the all -cis structure.
  • the concentration of sulfur- vulcanizable elastomer(s) (i) in the curable filled elastomer composition herein can range from 10 to 99, preferably from 50 to 95, and more preferably from 60 to 85, weight percent of the entire weight of the composition.
  • the concentration of particulate filler (ii) in the curable filled elastomer composition of the invention can range from 0.5 to 90, preferably from 5 to 60, and more preferably from 10 to 50, weight percent of the entire weight of the composition.
  • the concentration of crosslinking sulfur-containing cycloaliphatic compound (iii) of the invention in the filled sulfur- vulcanizable elastomer composition can range from 0.05 to 30, preferably from 0.5 to 10, and more preferably from 2 to 5, weight percent of the entire weight of the composition.
  • Fillers can be used as carriers for liquid sulfur-containing cycloaliphatic compounds. Fillers that are used as carriers should be non-reactive with sulfur- containing cycloaliphatic compounds. The non-reactive nature of such fillers will be demonstrated by the ability of a sulfur-containing cycloaliphatic compound to be extracted from the filler at greater than 50 percent of its original loading therein using an organic solvent. The extraction procedure is described in U. S. Patent No. 6,005,027, the entire contents of which are incorporated by reference herein. Fillers and carriers include, but are not limited to, porous organic polymers, carbon black, diatomaceous earth, and silicas.
  • Reinforcing fillers useful in the present invention include fillers in which the silanes are reactive with the surface of the filler.
  • Representative examples of such fillers include, but are not limited to, siliceous fillers, metal oxides such as silica (pyrogenic and/or precipitated), titanium, aluminosilicate and alumina, clays, talc, and the like.
  • the fillers may be provided in the hydrated form. Particulate, precipitated silica is especially useful as filler, particularly when the silica has reactive surface silanols.
  • the porosity of a filler can be determined, e.g., by the known technique of mercury porosimetry. In accordance with this method, the pores of a filler are penetrated with mercury after a thermal treatment to remove volatiles. Test conditions utilize a 100 mg sample and the removal of volatiles over 2 hours at 105 0 C and ambient to 2000 bars pressure. Mercury porosimetry may be performed according to the method described by Winslow et al. in ASTM bulletin, p.39 (1959) or according to DIN 66133. For the measurement, a CARLO-ERBA Porosimeter 2000 may be used. The average mercury porosity specific surface area for a silica filler herein should range from 100 to 300 m 2 /g.
  • the pore size distribution for a preferred silica, alumina or aluminosilicate filler according to such mercury porosity measurement is considered herein to be such that five percent or less of its pores have a diameter of less than 10 nm, 60 to 90 percent of its pores have a diameter of 10 to 100 nm, 10 to 30 percent of its pores have a diameter at 100 to 1,000 nm and 5 to 20 percent of its pores have a diameter of greater than 1,000 nm.
  • Suitable silica fillers include those having an average particle size, e.g., in the range of from 10 to 50 nm as determined by electron microscopy, although smaller and larger particle sizes are also useful.
  • Various commercially available silicas that are suitable for use herein include, e.g., those from PPG Industries such as HI-SIL 210 and HI-SIL 243, etc.; those from Rhone-Poulenc such as ZEOSIL 1165MP; those from Degussa such as VN2 and VN3, etc., and those from Huber such as HUBERSIL 8745.
  • one or more fillers are combined with silane coupling agent.
  • the filler can be a mixture of siliceous filler such as silica, alumina and/or aluminosilicate and a carbon black reinforcing pigment.
  • the filler component can be a mixture of from 15 to 95 weight percent of siliceous filler with the balance being carbon black, e.g., one having a CTAB value of from 80 to 150, and can contain from 0.1 to 20 weight percent of a silane coupling agent, including, illustratively, one or more of 3-mercaptopropyltriethoxysilane, bis-(3-triethoxysilylpropyl) tetrasulfide, bis-(3- triethoxysilylpropyl)disulfide, S-thiooctanonic acid, 3-triethoxysilylpropyl ester, and a silylated core polysulfide, the structures of which are disclosed in U.S.
  • a silane coupling agent including, illustratively, one or more of 3-mercaptopropyltriethoxysilane, bis-(3-triethoxysilylpropyl) tetrasulfide, bis
  • the weight ratio of siliceous filler to carbon black is at least 3 to 1, preferably at least 10 to 1 and more preferably at least 30 to 1.
  • Filler mixtures can contain from 60 to 95 weight percent of silica, alumina and/or aluminosilicate and, correspondingly, from 40 to 5 weight percent carbon black, and from 0.1 to 20 weight percent silane coupling agent, with the proviso that the mixture of the components add up to 100 percent.
  • the siliceous filler and carbon black may be pre-blended or blended together in the manufacture of the vulcanized rubber.
  • Sulfur-vulcanizable elastomers (i) herein include conjugated diene homopolymers and copolymers and copolymers of at least one conjugated diene and aromatic vinyl compound.
  • Suitable organic polymers for preparation of rubber compositions are well known in the art and are described in various textbooks including "The Vanderbilt Rubber Handbook,” Ohm, R.F., R.T. Vanderbilt Company, Inc., 1990 and in the “Manual for the Rubber Industry,” Kemperman, T. and Koch, S. Jr., Bayer AG, LeverKusen, 1993.
  • the sulfur- vulcanizable elastomer is solution-prepared styrene-butadiene rubber (SSBR), e.g., one having a styrene content of from 5 to 50, and preferably from 9 to 36, percent.
  • SSBR solution-prepared styrene-butadiene rubber
  • the sulfur-vulcanizable elastomer is selected from the group consisting of emulsion-prepared styrene-butadiene rubber (ESBR), natural rubber (NR), ethylene- propylene copolymers and terpolymers (EP, EPDM), acrylonitrile-butadiene rubber (NBR), polybutadiene (BR), and the like, and mixtures thereof.
  • Suitable conjugated diene elastomers include, but are not limited to, isoprene and 1,3-butadiene and suitable vinyl aromatic elastomers include, but are not limited to, styrene and alpha methyl styrene.
  • Useful polybutadienes include those typically containing about 90 percent by weight of the units in the cis-l,4-butadiene form.
  • the sulfur-vulcanizable elastomer (i) may be selected, e.g., from at least one of cis-l,4-polyisoprene rubber (natural and/or synthetic), emulsion polymerization- prepared styrene/butadiene copolymer rubber, organic solution polymerization-prepared styrene/butadiene rubber, 3,4-polyisoprene rubber, isoprene/butadiene rubber, styrene/isoprene/butadiene terpolymer rubber, cis-l,4- ⁇ olybutadiene, medium vinyl polybutadiene rubber (35-50 percent vinyl), high vinyl polybutadiene rubber (50-75 percent vinyl), styrene/isoprene copolymers, emulsion polymerization-prepared styrene/butadiene/acrylonitrile terpolymer rubber and butadiene/acrylonitrile cop
  • an emulsion polymerization-prepared styrene/butadiene (ESBR) having a relatively conventional styrene content of from 20 to 28 percent bound styrene, or an ESBR having a medium to relatively high bound styrene content of from 30 to 45 percent, may be used.
  • Emulsion polymerization-prepared styrene/butadiene/acrylonitrile terpolymer rubbers containing from 2 to 40 weight percent bound acrylonitrile in the terpolymer are also contemplated as diene based rubbers for use in this invention.
  • the cured, i.e., vulcanized, elastomer composition herein contains a sufficient amount of filler(s) (ii) as to exhibit a reasonably high modulus, as for example a modulus at 100 percent strain of greater than 8 MPa, and high resistance to tear, as for example, a tear strength of greater than 25 N.
  • the combined weight of the filler may be as low as 5 to 100 parts per hundred parts (phr).
  • the combined weight of the filler is from 25 to 85 phr and at least one precipitated silica is utilized as a filler in another embodiment.
  • the silica may be characterized as having a BET surface area, as measured using nitrogen gas, from 40 to 600, and preferably from 50 to 300, m 2 /g.
  • the BET method of measuring surface area is described in the Journal of the American Chemical Society, Volume 60, page 304 (1930).
  • the silica may also be characterized as having a dibutylphthalate (DBP) absorption value of from 100 to 350, and preferably of from 150 to 300.
  • DBP dibutylphthalate
  • the silica, as well as the aforesaid alumina and aluminosilicate may have a CTAB surface area of from 100 to 220.
  • CTAB surface area is the external surface area as determined with cetyl trimethylammonium bromide with a pH of about 9. The method is described in ASTM D 3849.
  • a vulcanized elastomer article is typically prepared by thermomechanically mixing the sulfur-vulcanizable elastomer(s) (i), filler(s) (ii) and sulfur-containing cycloaliphatic crosslinker(s) (iii) in a sequentially step-wise manner to provide a curable elastomer followed by molding and curing the compositions to provide the article.
  • the elastomer (s) and various elastomer compounding ingredients typically are blended in at least one, and often (in the case of silica-filled low rolling resistance tires) two or more, preparatory thermomechanical mixing stage(s) in suitable mixers.
  • Such preparatory mixing is referred to as nonproductive mixing or non-productive mixing steps or stages.
  • Such preparatory mixing usually is conducted at temperatures of from 14O 0 C to 200 0 C, and for some compositions from 15O 0 C to 17O 0 C.
  • a final mixing stage in a final mixing stage, sometimes referred to as a productive mixing stage, curing agents, and possibly one or more additional ingredients, are mixed with the rubber compound or composition at lower temperatures, e.g., from 5O 0 C to 13O 0 C, in order to prevent or retard premature curing of the sulfur-vulcanizable rubber, sometimes referred to as scorching.
  • the rubber mixture also referred to as a rubber compound or composition, typically is allowed to cool, sometimes after or during a process of intermediate mill mixing, between the aforesaid various mixing steps, for example, to a temperature of about 50 0 C or lower.
  • the desired quantity of the composition is introduced into a mold of appropriate configuration and at a temperature of from 130 0 C to 200 0 C, vulcanization of the rubber is achieved through reaction with the sulfur-containing groups of the sulfur-containing cycloaliphatic crosslinker herein and any other sources of free sulfur that may be present in the composition.
  • Thermomechanical mixing refers to the phenomenon whereby under the high shear conditions in a rubber mixer, the shear forces and associated friction occurring as a result of mixing the rubber compound, or some blend of the rubber compound itself and rubber compounding ingredients in the high shear mixer, the temperature autogeneously increases, i.e., it "heats up". Several chemical reactions may occur at various steps in the mixing and curing processes.
  • One or more other sulfur sources may be used, for example, in the form of elemental sulfur such as, but not limited to, Se.
  • a sulfur donor is considered herein to be a sulfur-containing compound which liberates free, or elemental, sulfur at a temperature in the range of from 140 0 C to 19O 0 C.
  • Such sulfur donors include polysulfide vulcanization accelerators and organosilane polysulfides with at least two connecting sulfur atoms in their polysulfide bridges.
  • the amount of free sulfur source in the curable composition herein can be controlled or adjusted as a matter of choice relatively independently of the addition of the sulfur-containing cycloaliphatic crosslinker.
  • the rubber composition can comprise 100 parts by weight rubber (phr) of at least one sulfur- vulcanizab Ie rubber selected from the group consisting of conjugated diene homopolymers and copolymers, and copolymers of at least one conjugated diene and aromatic vinyl compound, from 5 to 100 phr, and preferably from 25 to 80 phr, of at least one filler, up to 5 phr curing agent, and from 0.05 to 25 phr of at least one sulfur-containing cycloaliphatic compound of the present invention as crosslinker.
  • rubber phr
  • the sulfur- vulcanizab Ie rubber selected from the group consisting of conjugated diene homopolymers and copolymers, and copolymers of at least one conjugated diene and aromatic vinyl compound, from 5 to 100 phr, and preferably from 25 to 80 phr, of at least one filler, up to 5 phr curing agent, and from 0.05 to 25 phr of at
  • the filler composition can comprise from 1 to 85 weight percent carbon black based on the total weight of the filler composition and from 0.5 to 10 parts by weight of at least one sulfur-containing cycloaliphatic compound of the present invention as crosslinker based on the total weight of the rubber composition.
  • the rubber composition can be prepared by first blending rubber, filler and silane coupling agent, or rubber and filler pretreated with all or a portion of the silane coupling agent, if needed, in a first thermomechanical mixing step to a temperature of from 12Q 0 C to 200 0 C for from 2 to 20 minutes.
  • the sulfur-containing cycloaliphatic crosslinker and other curing agent(s), if present, are then added in a subsequent thermomechanical mixing step at a temperature of from 5O 0 C to 100 0 C for 1 to 30 minutes.
  • the temperature is then increased to from 13O 0 C to 200 0 C with curing being accomplished in from 5 to 60 minutes.
  • the process may also comprise the additional steps of preparing an assembly of a tire or sulfiir-vulcanizable rubber with a tread comprised of the rubber composition prepared according to this invention and vulcanizing the assembly at a temperature in the range of from 13O 0 C to 200 0 C.
  • additives e.g., silane coupling agents, curing aids, e.g., sulfur compounds, including activators, retarders and accelerators, processing additives such as oils, plasticizers, tackifying resins, silicas, other fillers, pigments, fatty acids, zinc oxide, waxes, antioxidants and antiozonants, peptizing agents, reinforcing materials such as, for example, carbon black, and so forth.
  • processing additives such as oils, plasticizers, tackifying resins, silicas, other fillers, pigments, fatty acids, zinc oxide, waxes, antioxidants and antiozonants, peptizing agents, reinforcing materials such as, for example, carbon black, and so forth.
  • additives are selected based upon the intended use and on the sulfur vulcanizable material selected for use, and such selection is within the knowledge of one of skill in the art, as are the required amounts of such additives known to one of skill in the art.
  • the vulcanization may be conducted in the presence of additional sulfur vulcanizing agents.
  • suitable sulfur vulcanizing agents include, for example elemental sulfur (free sulfur) or sulfur-donating vulcanizing agents, for example, an amino disulfide, polymeric polysulfide or sulfur olefin adducts which are conventionally added in the final, productive, rubber composition mixing step.
  • the sulfur vulcanizing agents which are common in the art are used, or added in the productive mixing stage, in an amount ranging from 0.4 to 3 phr, or even in some circumstances up to 8 phr, with a range of from 1.5 to 2.5 phr in one embodiment and from 2 to 2.5 phr in another embodiment.
  • Vulcanization accelerators i.e., additional sulfur donors
  • benzothiazoles alkyl thiuram disulfides, guanidine derivatives and thiocarbamates.
  • Specific representatives of these accelerators include mercapto benzothiazole, tetramethyl thiuram disulfide, benzothiazole disulfide, diphenylguanidine, zinc dithiocarbamate, alkylphenoldisulfide, zinc butyl xanthate, N-dicyclohexyl-2-benzothiazolesulfenamide, N-cyclohexyl-2-benzothiazolesulfenamide,
  • Other sulfur donors include, e.g., thiuram and morpholine derivatives.
  • Accelerators are used to control the time and/or temperature required for vulcanization and to improve the properties of the vulcanizate.
  • a single accelerator system may be used, i.e., a primary accelerator.
  • a primary accelerator is used in total amounts ranging from 0.5 to 4, and preferably from 0.8 to 1.5, phr.
  • Combinations of primary and a secondary accelerators can also be used with the secondary accelerator being present in smaller amounts, e.g., from 0.05 to about 3 phr, in order to activate and to improve the properties of the vulcanizate. Delayed action accelerators and/or vulcanization retarders may also be used.
  • Suitable types of accelerators are amines, disulfides, guanidines, thioureas, thiazoles, thiurams, sulfanamides, dithiocarbamates and xanthates.
  • the primary accelerator is a sulfenamide.
  • the secondary accelerator can be a guanidine, dithiocarbamate or thiuram compound.
  • Typical amounts of tackif ⁇ er resins are from 0.5 to 10 phr, and preferably from 1 to 5 phr.
  • Typical amounts of processing aids are 1 to 50 phr. Suitable processing aids include, e.g., aromatic, naphthenic and/or paraff ⁇ nic processing oils.
  • Typical amounts of antioxidants are from 1 to 5 phr. Representative antioxidants include diphenyl-p-phenylenediamine and others, such as, for example, those identified in the "Vanderbilt Rubber Handbook" (1978), pages 344-346.
  • Typical amounts of antiozonants are from 1 to 5 phr.
  • Typical amounts of fatty acids e.g., stearic acid, if used are from 0.5 to 3 phr.
  • Typical amounts of zinc oxide are from 2 to 5 phr.
  • Typical amounts of waxes e.g., microcrystalline waxes, are from 1 to 5 phr.
  • Typical amounts of peptizers e.g., pentachlorothiophenol and dibenzamidodiphenyl disulfide, are from 0.1 to 1 phr.
  • the cured rubber compositions of this invention can be used for various purposes such as the manufacture of tires, weather stripping, hose, belts, seals, gaskets, shoe soles, and the like.
  • the rubber compositions described herein are particularly useful for manufacturing tire treads but can be used for all other parts of a tire as well.
  • the tires can be built, shaped, molded and cured by any of various methods which are well known to those skilled in the art.
  • the ethanol and ethyl acetate were removed by distillation. The addition of ethanol and removal of ethanol and ethyl acetate were repeated two more times.
  • the l,2,4-tris(2-mercaptoethyl)cyclohexane intermediate (1,884 grams) was a pale yellow hazy liquid.
  • This example illustrates the preparation of toluene-4-thiosulfonic acid S- ⁇ 2- [bis-2,4-(2-toluene-4-sulfonylsulfanyl-ethyl)-cyclohexyl]-ethyl ⁇ ester.
  • the mixture was stirred at ambient temperature for 2.5 hours then filtered to remove succinimide.
  • the succinimide solid was washed with carbon tetrachloride ( 150milliliters) and the filtrate added to the reaction mixture.
  • the reaction mixture was added slowly over a period of 1.5 hours to a slurry of sodium toluene sulfinate (300 grams, 1.7 mol.) in tetrahydrofuran (700 milliliters) while maintaining the temperature less than 25°C.
  • the mixture was stirred for 2.5 hours, filtered through Celite and the filtrate was stripped under vacuum by slowly increasing vacuum from 100 mm Hg to less than 1 mm Hg while maintaining the temperature in a range of 60 to 7O 0 C.
  • This example illustrates the preparation of an isomeric mixture containing 84.82 weight percent cis-toluene-4-thiosulfonic acid S- ⁇ 2-[cis,cis-bis-2,4-(2-toluene-4- sulfonylsulfanyl-ethyl)-cyclohexyl]-ethyl ⁇ ester.
  • a mixture of stereochemical isomers of 1 ,2,4-trivinylcyclohexane was prepared by fractional distillation.
  • the distillation unit consisted of a S-liter round bottom flask, a strip silvered column (inner diameter of 51 mm, height of 1,470 mm) equipped with stainless steel flat mesh screen supporting a 316 stainless steel Propac 0.16 mesh ball, size rating 0.16 inch packing material, and a reflux condenser.
  • Trivinylcyclohexane (4,150 grams) and 4-tert-butylcatechol (4.5 grams) were charged to the flask.
  • the pressure was reduced to within the range of 6.5 torr to 7.3 torr and the temperature to within the range of 90.0 0 C to 90.8 0 C.
  • the boiling rate was maintained at 6 drops per second.
  • the distillate was collected and analyzed by gas chromatography.
  • the gas chromatography column and conditions were a DB-5 column, 30 meters long, 0.32 millimeter internal diameter, 0.25 micron film, a flame ionization detector, 60 psi air, 50 psi helium and 30 psi hydrogen pressure.
  • the temperature profile had a starting temperature of 8O 0 C, a ramp at 10 0 C per minute to 25°C, a hold for 10 minutes at 250 0 C, a second ramp at 10 0 C per minute to 300 0 C and a final hold of 5 minutes at 300 0 C.
  • the mixture was composed of a low boiling isomer (84.2 weight percent), a slightly higher boiling isomer (14.4 weight percent) and a mixture of two high boiling isomers (1.3 weight percent).
  • the low boiling component was assigned to the cis,cis,cis-l ,2,4- trivinylcyclohexane.
  • the other three isomers contain both cis and trans stereochemistry.
  • This example illustrates the preparation of the compound l-toluene-4- thiosulfonic acid S-(6-toluene-4-sulfonylsulfanyl) hexyl ester whose structure is:
  • N-chlorosuccinimide (13.3 grams, 0.099 mol) was slurried with carbon tetrachloride (100 milliters) in a 500-milliliter, 3-neck flask equipped with a thermocouple, mechanical stirrer and dropping funnel, and nitrogen gas atmosphere.
  • a solution of trimetholpropane tris-(3-mercapto propionate) (12.0 grams, 0.030 mol) in carbon tetrachloride (20 milliliters) was added over 11 minutes while maintaining the temperature below 25 0 C. The reaction medium was stirred at ambient temperature for 4 hours after which it was filtered.
  • N-chlorosuccinimide (18.0 grams, 0.135 mol.) was slurried with carbon tetrachloride (130 milliliters) in a 500-milliliter, 3-neck flask equipped with a thermocouple, mechanical stirrer and dropping funnel, and nitrogen gas atmosphere.
  • a solution of pentaerythritol tetrakis(3-mercapto propionate) (15.0 grams, 0.0307 mol.) in carbon tetrachloride (30 milliliters) and chloroform (30 milliliters) was added over 45 minutes while maintaining the temperature under 26 0 C.
  • the solid material which formed was filtered and washed with carbon tetrachloride (50 milliliters) and the washing combined with the filtrate.
  • the filtrate was added over a 30-minute period to a slurry of sodium toluenesulfinate (24 grams, 0.135 mol.) in tetrahydrofuran (80 milliters). After 2 hours, the reaction mixture was filtered through Celite to provide a clear yellow solution. The filtrate was concentrated and devolatilized to provide 12.0 grams of a thick, light brown oil.
  • a model low rolling resistance passenger tire tread formulation as described in Table 1 below and a mix procedure were used to evaluate representative examples of the sulfur-containing cycloaliphatic compounds of the present invention.
  • the mixing was done as follows in a "B" BANBURY® (Farrell Corp.) mixer with a 103-cubic inch (1, 690-centimeter) chamber volume.
  • the mixing of the rubber was done in two steps. The mixer was turned on with the mixer at 80 rpm and the cooling water at 71° C.
  • the rubber polymers were added to the mixer and ram down mixed for 30 seconds.
  • the silica and the other ingredients in the masterbatch of Table 1 except for the silane coupling agent, curatives and the oils were added to the mixer and ram down mixed for 60 seconds.
  • the mixer speed was reduced to 35 rpm after which the silane and oils of the materbatch were added to the mixer and ram down mixed for 60 seconds.
  • the mixer throat was dusted down and the ingredients ram down mixed until the temperature reached 149°C.
  • the ingredients were then mixed for an additional 3 minutes and 30 seconds.
  • the mixer speed was adjusted to maintain the temperature between 152°C and 157°C.
  • the rubber was dumped (removed from the mixer), a sheet was formed on a roll mill set at about 85°C to 88°C, and then allowed to cool to ambient temperature.
  • the masterbatch was recharged into the mixer.
  • the mixer's speed was 80 rpm
  • the cooling water was set at 71 0 C and the batch pressure was set at 6MPa.
  • the masterbatch was ram down mixed for 30 seconds, the temperature of the masterbatch was thenbrought up to 149 0 C after which the mixer's speed was reduced to 32 rpm and the rubber mixed for 3 minutes and 20 seconds at a temperature between 152 0 C and 157 0 C.
  • the rubber was dumped from the mixer, the sulfur- containing cycloaliphatic compound and curative were added and mixed and a sheet was formed on a roll mill set at about 85°C to 88 0 C, and then allowed to cool to ambient temperature.
  • the dynamic parameters, G'ini t i a i. ⁇ G ⁇ G", ⁇ and tan ⁇ max, were extracted from the non-linear responses of the rubber compounds at small strains.
  • steady state values of tan ⁇ were measured after 15 minutes of dynamic oscillations at strain amplitudes of 35% (at 6O 0 C).
  • Temperature dependence of dynamic properties was also measured from about -8O 0 C to +8O 0 C at small strain amplitudes (1 or 2%) at a frequency of 10 Hz.
  • styrene-butadiene rubber Buna VSL 5025 (non-oil extended) from Lanxess; silica: Zeosil 1165MP from Rhodia; carbon black (N-330); process oil: Sundex 8125 from Sun Oil; ZnO: Kadox 720C from ZincCorp.; stearic acid: Industrene R from Witco, Crompton; 6 PPD:(Flexzone 7P from Uniroyal); TMQ: Naugard Q from Crompton; wax: Sunproof Improved from Uniroyal, Crompton; sulfur: Rubbermakers Sulfur 104 from Harwick; CBS: Delac S from Uniroyal, Crompton; DPG: DPG from Uniroyal, Crompton; silane: Silquest A-1589 silane from Momentive Performance Materials. Table 2. Summer Passenger Car Tread Compounding Results
  • Rubber compositions were prepared wherein the formulations were based on natural rubber (NR). These formulations are representative for rubber compositions used in truck tire tread. The mixing, curing and testing procedures were identical to Comparative Example 8. The formulation is presented in Table 4. The results are presented in Table 5. Table 4. Truck NR Tread Compounding Formulations
  • tread formulations of Table 4 are as follows: natural rubber: (SMR-L); TBBS: Delac NS from Uniroyal; CTP: carbon treated phthalic anhydride retarder from Lanxess; carbon black (N-330); zinc oxide: Kadox 720C from ZincCorp.; stearic acid: Industrene R from Witco, Crompton; 6PPD: Flexzone 7P from Uniroyal; wax: Sunproof Improved from Uniroyal, Crompton; sulfur: Rubbermakers Sulfur 104 from Harwick.
  • the rubber compositions of these examples were prepared, cured and tested in accordance with the procedures of Comparative Example 5.
  • the formulations for the natural rubber formulations are given in Table 6, below.
  • the examples explore the effects of adding toluene-4-thiosulfonic acid S- ⁇ 2-[bis-2,4-(2-toluene-4-sulfonylsuIfanyl-ethyl)- cyclohexyl]-ethyl ⁇ ester as compared to adding 1 -toluene-4-thiosulfonic acid S-(6- toluene-4-sulfonylsulfanyl) hexyl ester to the natural rubber compositions.
  • the test results are presented in Table 7, below.
  • the rubber compositions containing the sulfur-containing cycloaliphatic compound of the present invention, toluene-4-thiosulfonic acid S- ⁇ 2-[bis-2,4-(2-toluene- 4-sulfonylsulfanyl-ethyl)-cyclohexyl]-ethyl ⁇ ester shows a 22 percent and 21 percent improvement in Graves Tear, as measured by ASTM D 1004 Standard Test Method for Tear Resistance (Graves Tear), when compared to rubber compositions containing no additive and a difunctional additive, 1 -toluene-4-thiosulfonic acid S-(6-toluene-4- sulfonylsulfanyl) hexyl ester, while maintaining the other physical properties.
  • the mixer throat was dusted down and the ingredients were ram down mixed until the temperature reached 150 0 C.
  • the ingredients were then mixed for an additional 3 minutes and 30 seconds.
  • the mixer speed was adjusted to hold the temperature between 150 0 C and 155 0 C.
  • the rubber was dumped (removed from the mixer), a sheet was formed on a roll mill set at about 85 0 C to 90 0 C, and then was allowed to cool to ambient temperature.
  • the rubber compound prepared in the first step was recharged into the mixer.
  • the mixer's speed was 80 rpm
  • the cooling water was set at 71 0 C and the ram pressure was set at 25 psi.
  • the rubber compound prepared in the first step was ram down mixed for 150 seconds while the temperature of the mixture was brought up to 150 0 C, and then the mixer was reduced to 50 rpm.
  • the rubber was mixed for 40 seconds at temperatures between 150 0 C and 155°C.
  • the rubber was dumped (removed from the mixer) and a sheet was formed on a roll mill set at about 85°C to 90 0 C. The rubber was allowed to cool to ambient temperature.
  • a third step the mixer speed was set to 50 rpm, the cooling water was set at 71 0 C and the ram pressure was set at 25 psi.
  • the rubber compound prepared in the second step and the curatives were ram down mixed for 190 seconds while the temperature of the final mixture was brought up to 1 15 0 C.
  • the rubber was dumped (removed from the mixer), a sheet was formed on a roll mill set at about 85°C to 9O 0 C, and then was allowed to cool to ambient temperature.
  • the curing condition was 160 0 C for 20 minutes.
  • the truck tread showed 22 percent and 21 percent increase in Graves tear resistance when compared to the compounds containing not sulfur-containing cycloaliphatic compounds and DBTCH, respectfully.
  • the Graves tear resistance is an indicator of improved wear under harsh conditions.
  • rubber compositions referred to in the examples above have been described as truck tread compositions, these rubber compositions are expected to be suitable for other industrial rubber-based goods, including, illustratively, for conveyor belts.
  • a model shoe sole formulation as described in Table 10 below and a mix procedure are used to evaluate representative examples of the thiocarbamoyldisulfanyl- functional cycloaliphatic compounds of the present invention.
  • the mixing is done as follows in a "B" BANBURY® (Farrell Corp.) mixer with a 103-cubic inch (1,690-cubic centimeter) chamber volume.
  • the mixing of the rubber is done in two steps. The first step is to prepare a rrubber compound without curatives.
  • the mixer is turned on with the mixer at speed number 2 and full cooling water.
  • the rubber polymers are added to the mixer and are ram down mixed for 30 seconds.
  • Half of the silica is added to the mixer and are ram down mixed for 30 seconds.
  • Half of the silica and the oil are added to the mixer and are ram down mixed for 30 seconds. All of the remaining ingredients of the rubber compound except for the curatives are added to the mixer and are ram down mixed for 30 seconds.
  • the mixer is dust down and is ram down mixed for 15 seconds, and then the mixer speed is increased to number 3 and mixture is ram down mixed for an additional 15 seconds.
  • the rubber is dumped (removed from the mixer), a sheet is formed on a roll mill set at about 49 0 C to 55°C, and then is allowed to cool to ambient temperature.
  • the final mixture is prepared.
  • the rubber compound prepared in the first step is recharged into the roll mill at about 49°C to 55°C and the curative package is added.
  • the curative package is mixed in and then is cut six times on each side.
  • a sheet is formed on a roll mill set and then is allowed to cool to ambient temperature.
  • Table 10 Model Shoe Sole Compounding Formulation
  • cis-butadiene rubber Budene 1207 from Goodyear Corporation
  • natural rubber SMR-L
  • nitrile rubber Perbunan NT 2445 form Bayer
  • silica HiSiI 233 form PPG
  • diethylene glycol from Dow Corporation BHT: butylated hydroxytoluene from Asia Pacific
  • ZnO Kadox 720C from ZincCorp.
  • stearic acid Industrene R from Witco, Crompton
  • wax Sunolite 240 from Witco Corporation
  • activator Rhenofit 2555 from Rhein-Chemie
  • dispenser Aflux 12 from Rhein-Chemie
  • homogenizer Phenosin N260 from Rhein-Chemie
  • sulfur Rhenogran S-80 from Rhein-Chemie
  • MBTS Thiofide from Flexsys
  • MBT Thiotax MBT from Flexsys
  • TMTM Rheno

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PCT/US2009/062515 2008-10-30 2009-10-29 Sulfur-containing cycloaliphatic compound, process for its preparation, filled sulfur-vulcanizable elastomer composition containing same and articles fabricated therefrom WO2010059363A1 (en)

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KR1020117012277A KR101687203B1 (ko) 2008-10-30 2009-10-29 황-함유 고리형 지방족 화합물, 그 제조 방법, 이를 포함하는 충전 황-가황성 엘라스토머 조성물 및 그로부터 제조된 물품들
CN200980153394.1A CN102272212B (zh) 2008-10-30 2009-10-29 含硫脂环族化合物、其制备方法、含该化合物的填充的硫可硫化弹性体组合物和由其制造的制品
BRPI0920680A BRPI0920680A2 (pt) 2008-10-30 2009-10-29 composto cicloalifático contendo enxofre, processo para a sua preparação, composição de elastômero com carga vulcanizável com enxofre contendo o mesmo e artigos fabricados a partir dela.
EP09752587.7A EP2342275B1 (en) 2008-10-30 2009-10-29 Sulfur-containing cycloaliphatic compound, process for its preparation, filled sulfur-vulcanizable elastomer composition containing same and articles fabricated therefrom
JP2011534751A JP5681635B2 (ja) 2008-10-30 2009-10-29 硫黄含有脂環式化合物、その調製プロセス、それを含有する充填剤入り硫黄加硫可能エラストマー組成物およびそれらより製造される物品
CA2740170A CA2740170A1 (en) 2008-10-30 2009-10-29 Sulfur-containing cycloaliphatic compound, process for its preparation, filled sulfur-vulcanizable elastomer composition containing same and articles fabricated therefrom

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103649026A (zh) * 2011-07-15 2014-03-19 莫门蒂夫性能材料股份有限公司 三乙烯基环己烷立体异构组合物及其制备方法
US9670379B2 (en) 2015-07-23 2017-06-06 The Boeing Company Composites transmissive to visual and infrared radiation and compositions and methods for making the composites
US10414870B2 (en) 2015-07-23 2019-09-17 The Boeing Company Transparent polymers and methods for making the same
US10494336B2 (en) 2015-05-12 2019-12-03 Continental Reifen Deutschland Gmbh Monomer for copolymerization with alkenes, dienes, vinyl compounds and/or vinylidene compounds, method for the synthesis of a copolymer, copolymer, rubber mixture and use thereof
WO2021216487A1 (en) * 2020-04-21 2021-10-28 Flexsys America L.P. Triazinanes possessing thiosulfonate end-groups and methods of making them

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8329794B2 (en) * 2010-01-07 2012-12-11 Lion Copolymer, Llc Compatibilized silica in nitrile rubber and blends of nitrile rubber and styrene butadiene rubber compositions
CN102633234B (zh) * 2012-04-06 2014-03-19 中国石油大学(华东) 一种不溶性硫磺稳定剂及其制备方法
TWI465470B (zh) * 2012-12-28 2014-12-21 Chi Mei Corp 橡膠組成物與高爾夫球

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080161463A1 (en) * 2006-12-28 2008-07-03 Cruse Richard W Free-flowing filler composition and rubber composition containing same

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3284481A (en) * 1963-10-28 1966-11-08 Dow Chemical Co alpha, alpha'-bis(substituted sulfonylthio)-p-tolyl ethers
US3282976A (en) * 1963-10-28 1966-11-01 Dow Chemical Co alpha, alpha-bis(substituted sulfonylthio)-xylenes
US3462472A (en) * 1967-06-01 1969-08-19 Dow Chemical Co 1,4- and 1,2-bis(substituted sulfonylthiomethyl)cyclohexane
US3732192A (en) * 1971-05-24 1973-05-08 Universal Oil Prod Co Rubber formulations containing thiosulfonate esters
US3786063A (en) * 1971-05-24 1974-01-15 Universal Oil Prod Co Thiazolethiosulfonates
US3869435A (en) * 1971-11-19 1975-03-04 Monsanto Co Method for cross-linking rubber
US4417012A (en) * 1981-07-08 1983-11-22 Monsanto Europe S.A. Organic thiosulphates and thiosulphonates useful as stabilising agents for rubber vulcanisates
US4532080A (en) * 1982-10-21 1985-07-30 Monsanto Europe, S.A. Adhesion promoters
US4508865A (en) * 1983-07-29 1985-04-02 Ciba-Geigy Corporation S-(4-Hydroxyphenyl)thiocarboxylic ester antioxidants
US4810812A (en) * 1986-12-26 1989-03-07 Nippon Shokubai Kagaku Kogyo Co., Ltd. Thiolcarboxylic acid esters
DE59205083D1 (de) * 1991-08-30 1996-02-29 Huels Chemische Werke Ag Verfahren zur Herstellung von Dienkautschuk-Vulkanisaten
DE10129058A1 (de) * 2001-06-15 2002-12-19 Bayer Ag Kieselsäure-, Ruß- und Kautschukgel enthaltende Kautschukmischungen
AU2003200913B2 (en) * 2002-03-25 2006-07-06 Nippon Shokubai Co., Ltd. Thiol carboxylate ester and its stabilization process
US7368490B2 (en) * 2005-11-28 2008-05-06 Momentive Performance Materials Inc. Rubber compositions comprising unsaturated imidoalkoxysilanes
US7968634B2 (en) * 2006-12-28 2011-06-28 Continental Ag Tire compositions and components containing silated core polysulfides

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080161463A1 (en) * 2006-12-28 2008-07-03 Cruse Richard W Free-flowing filler composition and rubber composition containing same

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103649026A (zh) * 2011-07-15 2014-03-19 莫门蒂夫性能材料股份有限公司 三乙烯基环己烷立体异构组合物及其制备方法
CN103649026B (zh) * 2011-07-15 2015-11-25 莫门蒂夫性能材料股份有限公司 三乙烯基环己烷立体异构组合物及其制备方法
US10494336B2 (en) 2015-05-12 2019-12-03 Continental Reifen Deutschland Gmbh Monomer for copolymerization with alkenes, dienes, vinyl compounds and/or vinylidene compounds, method for the synthesis of a copolymer, copolymer, rubber mixture and use thereof
US9670379B2 (en) 2015-07-23 2017-06-06 The Boeing Company Composites transmissive to visual and infrared radiation and compositions and methods for making the composites
US10414870B2 (en) 2015-07-23 2019-09-17 The Boeing Company Transparent polymers and methods for making the same
WO2021216487A1 (en) * 2020-04-21 2021-10-28 Flexsys America L.P. Triazinanes possessing thiosulfonate end-groups and methods of making them

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US20100113681A1 (en) 2010-05-06
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CN102272212A (zh) 2011-12-07
CN102272212B (zh) 2014-04-09
EP2342275A1 (en) 2011-07-13
KR20110081320A (ko) 2011-07-13
KR101687203B1 (ko) 2016-12-16
US8334340B2 (en) 2012-12-18
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EP2342275B1 (en) 2013-05-01
BRPI0920680A2 (pt) 2016-09-27

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