WO2010031737A3 - Method of cooling a hydrocarbon stream and an apparatus therefor - Google Patents
Method of cooling a hydrocarbon stream and an apparatus therefor Download PDFInfo
- Publication number
- WO2010031737A3 WO2010031737A3 PCT/EP2009/061793 EP2009061793W WO2010031737A3 WO 2010031737 A3 WO2010031737 A3 WO 2010031737A3 EP 2009061793 W EP2009061793 W EP 2009061793W WO 2010031737 A3 WO2010031737 A3 WO 2010031737A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- flow rate
- stream flow
- hydrocarbon stream
- refrigerant stream
- refrigerant
- Prior art date
Links
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 9
- 229930195733 hydrocarbon Natural products 0.000 title abstract 9
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 9
- 238000001816 cooling Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000003507 refrigerant Substances 0.000 abstract 10
- 230000003247 decreasing effect Effects 0.000 abstract 3
- 230000007423 decrease Effects 0.000 abstract 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0244—Operation; Control and regulation; Instrumentation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
- F25B9/006—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant containing more than one component
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
- F25J1/0055—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream originating from an incorporated cascade
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
- F25J1/0057—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream after expansion of the liquid refrigerant stream with extraction of work
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0211—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
- F25J1/0214—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0211—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
- F25J1/0214—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle
- F25J1/0215—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle
- F25J1/0216—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle using a C3 pre-cooling cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0244—Operation; Control and regulation; Instrumentation
- F25J1/0245—Different modes, i.e. 'runs', of operation; Process control
- F25J1/0248—Stopping of the process, e.g. defrosting or deriming, maintenance; Back-up mode or systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0292—Refrigerant compression by cold or cryogenic suction of the refrigerant gas
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011527298A JP2012511130A (en) | 2008-09-19 | 2009-09-11 | Method and apparatus for cooling a hydrocarbon stream |
AU2009294697A AU2009294697B2 (en) | 2008-09-19 | 2009-09-11 | Method of cooling a hydrocarbon stream and an apparatus therefor |
US13/119,456 US20110168377A1 (en) | 2008-09-19 | 2009-09-11 | Method of cooling a hydrocarbon stream and an apparatus therefor |
EP09782905A EP2324310A2 (en) | 2008-09-19 | 2009-09-11 | Method of cooling a hydrocarbon stream and an apparatus therefor |
RU2011115190/06A RU2525048C2 (en) | 2008-09-19 | 2009-09-11 | Method of cooling hydrocarbon flow and device for its realisation |
AP2011005585A AP2011005585A0 (en) | 2008-09-19 | 2009-09-11 | Method of cooling a hydrocarbon stream and an apparatus thereof. |
CN200980136524.0A CN102265104B (en) | 2008-09-19 | 2009-09-11 | Method of cooling hydrocarbon stream and apparatus therefor |
CA2735884A CA2735884C (en) | 2008-09-19 | 2009-09-11 | Method of cooling a hydrocarbon stream and an apparatus therefor |
BRPI0918663A BRPI0918663A2 (en) | 2008-09-19 | 2009-09-11 | method for cooling a hydrocarbon stream in a heat exchanger; and apparatus for operating a heat exchanger. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08164727.3 | 2008-09-19 | ||
EP08164727 | 2008-09-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010031737A2 WO2010031737A2 (en) | 2010-03-25 |
WO2010031737A3 true WO2010031737A3 (en) | 2015-02-19 |
Family
ID=40626875
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2009/061793 WO2010031737A2 (en) | 2008-09-19 | 2009-09-11 | Method of cooling a hydrocarbon stream and an apparatus therefor |
Country Status (11)
Country | Link |
---|---|
US (1) | US20110168377A1 (en) |
EP (1) | EP2324310A2 (en) |
JP (1) | JP2012511130A (en) |
KR (1) | KR20110061615A (en) |
CN (1) | CN102265104B (en) |
AP (1) | AP2011005585A0 (en) |
BR (1) | BRPI0918663A2 (en) |
CA (1) | CA2735884C (en) |
MY (1) | MY161121A (en) |
RU (1) | RU2525048C2 (en) |
WO (1) | WO2010031737A2 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9527008B2 (en) * | 2012-07-26 | 2016-12-27 | Uop Llc | Apparatus for measurement and calculation of dew point for fractionation column overheads |
CN103148673B (en) * | 2013-01-27 | 2015-01-07 | 南京瑞柯徕姆环保科技有限公司 | Natural gas isobaric liquefaction device |
US11428463B2 (en) * | 2013-03-15 | 2022-08-30 | Chart Energy & Chemicals, Inc. | Mixed refrigerant system and method |
US9696074B2 (en) | 2014-01-03 | 2017-07-04 | Woodward, Inc. | Controlling refrigeration compression systems |
US11874055B2 (en) * | 2014-03-04 | 2024-01-16 | Conocophillips Company | Refrigerant supply to a cooling facility |
DE102014012316A1 (en) * | 2014-08-19 | 2016-02-25 | Linde Aktiengesellschaft | Process for cooling a hydrocarbon-rich fraction |
RU2747919C2 (en) * | 2019-03-06 | 2021-05-17 | Андрей Владиславович Курочкин | Lng production installation |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5791160A (en) * | 1997-07-24 | 1998-08-11 | Air Products And Chemicals, Inc. | Method and apparatus for regulatory control of production and temperature in a mixed refrigerant liquefied natural gas facility |
US6530240B1 (en) * | 2001-12-10 | 2003-03-11 | Gas Technology Institute | Control method for mixed refrigerant based natural gas liquefier |
US20030046953A1 (en) * | 2000-04-25 | 2003-03-13 | Wiveka Jacoba Elion | Controlling the production of a liquefied natural gas product stream |
WO2009013605A2 (en) * | 2007-07-25 | 2009-01-29 | Air Products And Chemicals, Inc. | Controlling liquefaction of natural gas |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2074594B1 (en) * | 1970-01-08 | 1973-02-02 | Technip Cie | |
JPS5869320A (en) * | 1981-10-21 | 1983-04-25 | Hitachi Ltd | Flow rate controlling device |
US4809154A (en) * | 1986-07-10 | 1989-02-28 | Air Products And Chemicals, Inc. | Automated control system for a multicomponent refrigeration system |
US5139548A (en) * | 1991-07-31 | 1992-08-18 | Air Products And Chemicals, Inc. | Gas liquefaction process control system |
JP2945806B2 (en) * | 1992-10-07 | 1999-09-06 | 株式会社神戸製鋼所 | Pre-cooling device for refrigeration load installed in liquefaction refrigeration system |
US5669238A (en) * | 1996-03-26 | 1997-09-23 | Phillips Petroleum Company | Heat exchanger controls for low temperature fluids |
US5724833A (en) * | 1996-12-12 | 1998-03-10 | Phillips Petroleum Company | Control scheme for cryogenic condensation |
DZ2671A1 (en) * | 1997-12-12 | 2003-03-22 | Shell Int Research | Liquefaction process of a gaseous fuel product rich in methane to obtain a liquefied natural gas. |
FR2818365B1 (en) * | 2000-12-18 | 2003-02-07 | Technip Cie | METHOD FOR REFRIGERATION OF A LIQUEFIED GAS, GASES OBTAINED BY THIS PROCESS, AND INSTALLATION USING THE SAME |
US7594414B2 (en) * | 2001-05-04 | 2009-09-29 | Battelle Energy Alliance, Llc | Apparatus for the liquefaction of natural gas and methods relating to same |
JP2004003724A (en) * | 2002-05-31 | 2004-01-08 | Jfe Steel Kk | Cooling method of cryogenic equipment |
TWI314637B (en) * | 2003-01-31 | 2009-09-11 | Shell Int Research | Process of liquefying a gaseous, methane-rich feed to obtain liquefied natural gas |
JP4328278B2 (en) * | 2004-09-14 | 2009-09-09 | 三菱化学株式会社 | Cryogenic control system |
NO345489B1 (en) * | 2006-04-07 | 2021-03-01 | Hamworthy Gas Systems As | Method and device for cooling an LNG flue gas (BOG) stream in a liquid recovery plant |
US8727736B2 (en) * | 2008-12-02 | 2014-05-20 | Kellogg Brown & Root Llc | Multiple electric motors driving a single compressor string |
-
2009
- 2009-09-11 EP EP09782905A patent/EP2324310A2/en not_active Withdrawn
- 2009-09-11 BR BRPI0918663A patent/BRPI0918663A2/en not_active IP Right Cessation
- 2009-09-11 KR KR1020117007997A patent/KR20110061615A/en not_active Application Discontinuation
- 2009-09-11 US US13/119,456 patent/US20110168377A1/en not_active Abandoned
- 2009-09-11 AP AP2011005585A patent/AP2011005585A0/en unknown
- 2009-09-11 CN CN200980136524.0A patent/CN102265104B/en not_active Expired - Fee Related
- 2009-09-11 JP JP2011527298A patent/JP2012511130A/en active Pending
- 2009-09-11 CA CA2735884A patent/CA2735884C/en active Active
- 2009-09-11 MY MYPI2011000844A patent/MY161121A/en unknown
- 2009-09-11 RU RU2011115190/06A patent/RU2525048C2/en active
- 2009-09-11 WO PCT/EP2009/061793 patent/WO2010031737A2/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5791160A (en) * | 1997-07-24 | 1998-08-11 | Air Products And Chemicals, Inc. | Method and apparatus for regulatory control of production and temperature in a mixed refrigerant liquefied natural gas facility |
US20030046953A1 (en) * | 2000-04-25 | 2003-03-13 | Wiveka Jacoba Elion | Controlling the production of a liquefied natural gas product stream |
US6530240B1 (en) * | 2001-12-10 | 2003-03-11 | Gas Technology Institute | Control method for mixed refrigerant based natural gas liquefier |
WO2009013605A2 (en) * | 2007-07-25 | 2009-01-29 | Air Products And Chemicals, Inc. | Controlling liquefaction of natural gas |
Also Published As
Publication number | Publication date |
---|---|
CN102265104A (en) | 2011-11-30 |
JP2012511130A (en) | 2012-05-17 |
RU2525048C2 (en) | 2014-08-10 |
CA2735884A1 (en) | 2010-03-25 |
CN102265104B (en) | 2013-11-06 |
AP2011005585A0 (en) | 2011-02-28 |
KR20110061615A (en) | 2011-06-09 |
MY161121A (en) | 2017-04-14 |
CA2735884C (en) | 2017-01-17 |
WO2010031737A2 (en) | 2010-03-25 |
RU2011115190A (en) | 2012-10-27 |
BRPI0918663A2 (en) | 2015-12-01 |
AU2009294697A1 (en) | 2010-03-25 |
EP2324310A2 (en) | 2011-05-25 |
US20110168377A1 (en) | 2011-07-14 |
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