WO2010013749A1 - Catalyst for methacrylic acid production, process for producing same, and process for producing methacrylic acid - Google Patents

Catalyst for methacrylic acid production, process for producing same, and process for producing methacrylic acid Download PDF

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Publication number
WO2010013749A1
WO2010013749A1 PCT/JP2009/063499 JP2009063499W WO2010013749A1 WO 2010013749 A1 WO2010013749 A1 WO 2010013749A1 JP 2009063499 W JP2009063499 W JP 2009063499W WO 2010013749 A1 WO2010013749 A1 WO 2010013749A1
Authority
WO
WIPO (PCT)
Prior art keywords
methacrylic acid
catalyst
producing
alkali metal
added
Prior art date
Application number
PCT/JP2009/063499
Other languages
French (fr)
Japanese (ja)
Inventor
洋子 篠田
柾　朋博
近藤　正英
内藤　啓幸
雄一 田川
俊雄 長谷川
Original Assignee
三菱レイヨン株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 三菱レイヨン株式会社 filed Critical 三菱レイヨン株式会社
Priority to JP2009537338A priority Critical patent/JP5659490B2/en
Priority to CN200980129513XA priority patent/CN102105223B/en
Publication of WO2010013749A1 publication Critical patent/WO2010013749A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Abstract

Disclosed is a catalyst for methacrylic acid production that can produce methacrylic acid with high selectivity.  Also disclosed are a process for producing the catalyst and a process for producing methacrylic acid using the catalyst.  At least a source of molybdenum and a source of element X are added into water to prepare an aqueous slurry or aqueous solution containing a heteropoly acid.  An alkali metal compound is added to the aqueous slurry or aqueous solution to precipitate a heteropoly acid salt in which at least a part of the heteropoly acid is converted to an alkali metal salt.  A source of phosphorus is then added to produce a catalyst comprising elemental phosphorus, elemental molybdenum, element X (at least one element selected from the group consisting of silicon, titanium, germanium, arsenic, antimony, and cerium), and an alkali metal element.  The catalyst is used in the production of methacrylic acid.
PCT/JP2009/063499 2008-07-29 2009-07-29 Catalyst for methacrylic acid production, process for producing same, and process for producing methacrylic acid WO2010013749A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2009537338A JP5659490B2 (en) 2008-07-29 2009-07-29 Method for producing catalyst for producing methacrylic acid, and method for producing methacrylic acid
CN200980129513XA CN102105223B (en) 2008-07-29 2009-07-29 Catalyst for methacrylic acid production, process for producing same, and process for producing methacrylic acid

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2008194759 2008-07-29
JP2008-194759 2008-07-29
JP2009-119753 2009-05-18
JP2009119753 2009-05-18

Publications (1)

Publication Number Publication Date
WO2010013749A1 true WO2010013749A1 (en) 2010-02-04

Family

ID=41610448

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2009/063499 WO2010013749A1 (en) 2008-07-29 2009-07-29 Catalyst for methacrylic acid production, process for producing same, and process for producing methacrylic acid

Country Status (4)

Country Link
JP (1) JP5659490B2 (en)
KR (1) KR101593723B1 (en)
CN (1) CN102105223B (en)
WO (1) WO2010013749A1 (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011152519A (en) * 2010-01-28 2011-08-11 Mitsubishi Rayon Co Ltd Catalyst for producing methacrylic acid and method for producing the same, and method for producing methacrylic acid
JP2011173114A (en) * 2010-01-28 2011-09-08 Mitsubishi Rayon Co Ltd Catalyst for manufacturing methacrylic acid, manufacturing method of the same, and manufacturing method of methacrylic acid
JP2012232245A (en) * 2011-04-28 2012-11-29 Mitsubishi Rayon Co Ltd Method for producing catalyst for synthesizing unsaturated carboxylic acid
JP2013006162A (en) * 2011-06-27 2013-01-10 Mitsubishi Rayon Co Ltd Method of manufacturing methacrylic acid manufacturing catalyst
JP2013192988A (en) * 2012-03-16 2013-09-30 Mitsubishi Rayon Co Ltd Catalyst for producing methacrylic acid, and method for producing the same
JP2013192989A (en) * 2012-03-16 2013-09-30 Mitsubishi Rayon Co Ltd Method for producing catalyst for producing methacrylic acid
JP2019188268A (en) * 2018-04-18 2019-10-31 三菱ケミカル株式会社 Manufacturing method of catalyst for manufacturing methacrylic acid, and manufacturing method of methacrylic acid
WO2019208715A1 (en) * 2018-04-26 2019-10-31 三菱ケミカル株式会社 Method for producing catalyst for methacrylic-acid production and methods for producing methacrylic acid and methacryic ester
JP2020015043A (en) * 2015-03-09 2020-01-30 日本化薬株式会社 Method fop producing catalyst for producing methacrylic acid

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MY190906A (en) * 2016-12-12 2022-05-18 Mitsubishi Chem Corp Method for producing catalyst precursor for producing ?, b-unsaturated carboxylic acid, method for producing catalyst for producing ?, ?-unsaturated carboxylic acid, method for producing ?, ?-unsaturated carboxylic acid, and method for producing ?, ?-unsaturated carboxylic acid ester
CN111545228B (en) * 2020-05-29 2023-05-23 烟台大学 Microwave-assisted aging heteropolyacid salt/cerium oxide composite catalyst and preparation method thereof
CN113893879B (en) * 2021-11-04 2024-02-06 淄博市翔力致高新材料有限责任公司 Heteropoly acid catalyst and preparation method and application thereof
CN114797982A (en) * 2022-05-26 2022-07-29 中国科学技术大学 Catalyst for preparing methacrylic acid by isobutane one-step method, and preparation method and application thereof

Citations (8)

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Publication number Priority date Publication date Assignee Title
JPS5732734A (en) * 1980-08-05 1982-02-22 Standard Oil Co Metachlorine oxidation catalyst and its use
JPH081005A (en) * 1994-06-22 1996-01-09 Sumitomo Chem Co Ltd Production of catalyst for production of mathacrylic acid
JPH09183748A (en) * 1995-10-31 1997-07-15 Sun Co Inc R & M Conversion of alkane to unsaturated carboxylid acid
JP2001104793A (en) * 1999-08-17 2001-04-17 Rohm & Haas Co Heteropoly acid/polyoxomethalate catalyst
JP2001114726A (en) * 1999-10-12 2001-04-24 Nippon Shokubai Co Ltd Production process for methacrylic acid
JP2004008834A (en) * 2002-06-03 2004-01-15 Mitsubishi Rayon Co Ltd Method for producing catalyst for use in manufacturing methacrylic acid
JP2008272626A (en) * 2007-04-26 2008-11-13 Mitsubishi Rayon Co Ltd Catalyst for manufacturing methacrylic acid, manufacturing method thereof and manufacturing method of methacrylic acid
JP2009101251A (en) * 2007-10-19 2009-05-14 Mitsubishi Rayon Co Ltd Catalyst for producing methacrylic acid, method of manufacturing the same, and method of manufacturing methacrylic acid

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0733344B2 (en) 1986-12-06 1995-04-12 旭化成工業株式会社 Method for producing methacrylic acid and / or methacrolein
JPH085820B2 (en) 1988-04-05 1996-01-24 旭化成工業株式会社 Method for producing methacrylic acid and / or methacrolein
JPH047037A (en) 1990-04-23 1992-01-10 Mitsubishi Rayon Co Ltd Preparation of catalyst for manufacturing methacrylic acid

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5732734A (en) * 1980-08-05 1982-02-22 Standard Oil Co Metachlorine oxidation catalyst and its use
JPH081005A (en) * 1994-06-22 1996-01-09 Sumitomo Chem Co Ltd Production of catalyst for production of mathacrylic acid
JPH09183748A (en) * 1995-10-31 1997-07-15 Sun Co Inc R & M Conversion of alkane to unsaturated carboxylid acid
JP2001104793A (en) * 1999-08-17 2001-04-17 Rohm & Haas Co Heteropoly acid/polyoxomethalate catalyst
JP2001114726A (en) * 1999-10-12 2001-04-24 Nippon Shokubai Co Ltd Production process for methacrylic acid
JP2004008834A (en) * 2002-06-03 2004-01-15 Mitsubishi Rayon Co Ltd Method for producing catalyst for use in manufacturing methacrylic acid
JP2008272626A (en) * 2007-04-26 2008-11-13 Mitsubishi Rayon Co Ltd Catalyst for manufacturing methacrylic acid, manufacturing method thereof and manufacturing method of methacrylic acid
JP2009101251A (en) * 2007-10-19 2009-05-14 Mitsubishi Rayon Co Ltd Catalyst for producing methacrylic acid, method of manufacturing the same, and method of manufacturing methacrylic acid

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011173114A (en) * 2010-01-28 2011-09-08 Mitsubishi Rayon Co Ltd Catalyst for manufacturing methacrylic acid, manufacturing method of the same, and manufacturing method of methacrylic acid
JP2011152519A (en) * 2010-01-28 2011-08-11 Mitsubishi Rayon Co Ltd Catalyst for producing methacrylic acid and method for producing the same, and method for producing methacrylic acid
JP2012232245A (en) * 2011-04-28 2012-11-29 Mitsubishi Rayon Co Ltd Method for producing catalyst for synthesizing unsaturated carboxylic acid
JP2013006162A (en) * 2011-06-27 2013-01-10 Mitsubishi Rayon Co Ltd Method of manufacturing methacrylic acid manufacturing catalyst
JP2013192988A (en) * 2012-03-16 2013-09-30 Mitsubishi Rayon Co Ltd Catalyst for producing methacrylic acid, and method for producing the same
JP2013192989A (en) * 2012-03-16 2013-09-30 Mitsubishi Rayon Co Ltd Method for producing catalyst for producing methacrylic acid
JP2020015043A (en) * 2015-03-09 2020-01-30 日本化薬株式会社 Method fop producing catalyst for producing methacrylic acid
JP2019188268A (en) * 2018-04-18 2019-10-31 三菱ケミカル株式会社 Manufacturing method of catalyst for manufacturing methacrylic acid, and manufacturing method of methacrylic acid
JP7006477B2 (en) 2018-04-18 2022-02-10 三菱ケミカル株式会社 A method for producing a catalyst for producing methacrylic acid, and a method for producing methacrylic acid.
WO2019208715A1 (en) * 2018-04-26 2019-10-31 三菱ケミカル株式会社 Method for producing catalyst for methacrylic-acid production and methods for producing methacrylic acid and methacryic ester
CN112004597A (en) * 2018-04-26 2020-11-27 三菱化学株式会社 Method for producing catalyst for methacrylic acid production, and method for producing methacrylic acid and methacrylic acid ester
KR20210002576A (en) 2018-04-26 2021-01-08 미쯔비시 케미컬 주식회사 Method for producing a catalyst for producing methacrylic acid, and a method for producing methacrylic acid and methacrylic acid ester
JPWO2019208715A1 (en) * 2018-04-26 2021-05-20 三菱ケミカル株式会社 A method for producing a catalyst for producing methacrylic acid, and a method for producing methacrylic acid and a methacrylic acid ester.
JP7031737B2 (en) 2018-04-26 2022-03-08 三菱ケミカル株式会社 A method for producing a catalyst for producing methacrylic acid, and a method for producing methacrylic acid and a methacrylic acid ester.

Also Published As

Publication number Publication date
CN102105223B (en) 2013-07-10
KR101593723B1 (en) 2016-02-12
KR20110044266A (en) 2011-04-28
CN102105223A (en) 2011-06-22
JP5659490B2 (en) 2015-01-28
JPWO2010013749A1 (en) 2012-01-12

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