WO2009152722A1 - Aluminium alloy with high electrical conductivity and high yield strength, worked article and induction plate made of it - Google Patents

Aluminium alloy with high electrical conductivity and high yield strength, worked article and induction plate made of it Download PDF

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Publication number
WO2009152722A1
WO2009152722A1 PCT/CN2009/072022 CN2009072022W WO2009152722A1 WO 2009152722 A1 WO2009152722 A1 WO 2009152722A1 CN 2009072022 W CN2009072022 W CN 2009072022W WO 2009152722 A1 WO2009152722 A1 WO 2009152722A1
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aluminum alloy
weight
content
workpiece
total weight
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PCT/CN2009/072022
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French (fr)
Chinese (zh)
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谢绍俊
陈文�
任运君
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西南铝业(集团)有限责任公司
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Publication of WO2009152722A1 publication Critical patent/WO2009152722A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60LPROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
    • B60L13/00Electric propulsion for monorail vehicles, suspension vehicles or rack railways; Magnetic suspension or levitation for vehicles
    • B60L13/04Magnetic suspension or levitation for vehicles
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60LPROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
    • B60L2200/00Type of vehicles
    • B60L2200/26Rail vehicles

Definitions

  • the present invention relates to an aluminum alloy, particularly an aluminum alloy having high electrical conductivity and high yield strength.
  • the present invention also relates to a method and use for the preparation of the aluminum alloy, as well as a machined part and an induction plate manufactured using the aluminum alloy, particularly an induction plate for a magnetic levitation train track.
  • Aluminium alloys have a range of excellent properties and are used in a wide range of applications including transportation, aerospace, building bridges, packaging containers, electrical and electronics, machinery manufacturing and the energy industry.
  • transportation, aerospace, building bridges, packaging containers, electrical and electronics, machinery manufacturing and the energy industry puts higher demands on the performance of aluminum alloys.
  • the induction plates for magnetic levitation trains require high electrical conductivity and high yield strength.
  • the electrical conductivity can reach above 58% IACS with pure aluminum and a small amount of alloy.
  • the electrical conductivity of some aluminum alloy materials can basically reach the 60% IACS required by the induction plate, the processing state yield strength R P 0. 2 is generally only about 40 N/mm 2 , and the maximum is not more than 60 N/mm. 2 , therefore, the requirements for use are not met.
  • the existing induction plates for magnetic levitation train tracks are mainly composed of copper alloy plates and steel plates. Copper alloys are expensive. If aluminum alloys can be used instead of copper alloys to make induction plates, huge economic benefits will be generated, and the cost of magnetic suspension train construction will be greatly saved, which will facilitate the widespread use of maglev trains.
  • An object of the present invention is to provide an aluminum alloy having high electrical conductivity and high yield strength, characterized in that the aluminum alloy comprises from about 0.40 to about 0.70% by weight of Fe, based on the total weight of the aluminum alloy. 0.20 to about 0.40% by weight of Cu, about 0.01 to about 0.20% by weight of Si and the balance of Al.
  • Another object of the present invention is to provide a method for producing an aluminum alloy having high electrical conductivity and high yield strength according to the present invention, which comprises from about 0.40 to about 0.70 wt% of Fe, respectively, based on the total weight of the aluminum alloy, of about 0.20. ⁇ about 0.40wt% Cu, about 0.01 to about 0.20 wt% of Si and the balance of the A1 batching furnace and smelting step. It is still another object of the present invention to provide an aluminum alloy workpiece made of an aluminum alloy having high electrical conductivity and high yield strength of the present invention.
  • Still another object of the present invention is to provide an aluminum alloy or aluminum alloy workpiece having high electrical conductivity and high yield strength of the present invention for use in the preparation of an induction plate, particularly an induction plate for a magnetic levitation train track.
  • Still another object of the present invention is to provide an induction plate, particularly an induction plate for a magnetic levitation train track, comprising the aluminum alloy or aluminum alloy workpiece of the present invention having high electrical conductivity and high yield strength.
  • the electrical conductivity of the aluminum alloy of the present invention is not less than about 59% IACS, and the yield strength R P of the processed product. 2 can be up to about 90 N/mm 2 or more (increased by at least about 1.5 times compared to the prior art). Therefore, the aluminum alloy and the workpiece thereof of the present invention can be effectively applied to applications requiring high electrical conductivity and high yield strength, for example, aluminum for nuclear reactors, aluminum for electrical equipment, etc., in particular, can replace copper alloys. It is used to manufacture induction boards for magnetic levitation train tracks.
  • the aluminum alloy of the present invention achieves an optimized combination of high electrical conductivity and high yield strength by adding conventional elements Fe, Cu, Si to pure aluminum, which is economical and practical.
  • the aluminum alloy and the workpiece thereof of the present invention have the advantages of low cost, light weight and high strength, and depending on the ratio between the elements, corrosion resistance, good brazability and machinability can be obtained.
  • Advantages, and one or more of the properties can be further improved by adjusting the content of each component within the scope of the present invention according to practical applications (this adjustment can be easily achieved by those skilled in the art using means known in the art) Therefore, an aluminum alloy product excellent in overall performance can be further obtained.
  • the induction plate made of the aluminum alloy or the processed part thereof of the invention is a technical breakthrough in the field of induction plates, and is a huge breakthrough in the field of induction plates for magnetic suspension train tracks, which greatly saves the construction cost of the magnetic suspension train track, and will promote The development of maglev train technology plays an irreplaceable role.
  • the percentages mentioned are by weight unless otherwise indicated.
  • the range of values referred to herein includes endpoint values. Where "not greater than” or “not higher than” is used in the numerical range, including but not limited to the case where the specified composition has a zero content, for example, no more than 0.05 wt% of Zn may include the case where the alloy does not contain Zn. .
  • the word "about” does not exclude the case where the content of the indicated component is slightly larger or slightly smaller than the index value due to the operational error, and it is preferred that the index value fluctuates within an error range of ⁇ 5%.
  • an aluminum alloy having high electrical conductivity and high yield strength, wherein the aluminum alloy comprises 0.40 to 0.70 wt% of Fe, 0.20 to 0.40 wt% based on the total weight of the aluminum alloy % Cu, 0.01 to 0.20 wt% of Si and the balance of Al.
  • the aluminum alloy may contain tolerable impurities.
  • the content of the allowable impurities is not particularly limited as long as the basic properties of the high conductivity, high yield strength aluminum alloy of the present invention are not impaired.
  • the total amount of said tolerable impurities not more than about 0.15wt%, preferably no more than about 0.10wt%, more preferably no more than about 0.05wt% o
  • the content of each of the permissible impurities is no greater than about 0.05 wt%, preferably no greater than about 0.03 wt%, more preferably no greater than about 0.01 wt%.
  • the term "allowable impurities" in the present invention means a component which does not adversely affect the aluminum alloy of the present invention, especially a component which does not significantly adversely affect the high electrical conductivity and high yield strength of the aluminum alloy of the present invention.
  • the allowable impurities may be components which are purposely introduced to improve the properties of the aluminum alloy of the present invention other than electrical conductivity and yield strength, and may also be components which are inevitably introduced due to production conditions.
  • the allowable impurities preferably include one or more of Zn, Ti, Mg, Mn, In, Zr, Cr, M, Sc, V, Hf, Be, Sn, Co, B, and rare earth elements, It preferably includes Zn and Ti.
  • the specific composition of Fe, Cu, Si and A1 as a matrix is the specific composition of Fe, Cu, Si and A1 as a matrix.
  • the role of Fe is to increase the number of compound particles, refine the grain size, increase the recrystallization temperature, and increase the yield strength of the alloy during hot working, without damaging the conductivity or making the conductivity decrease less.
  • the content of Fe in the aluminum alloy of the invention is less than about 0.70% by weight, the yield strength can be increased to a large extent, and the electrical conductivity of the material does not decrease or decrease by ⁇ I; when it is higher than 0.40 wt%, sufficient formation is formed.
  • a large number of AlFeCu compounds phase points, thereby increasing the yield strength of the alloy.
  • the Fe content is from about 0.55 to about 0.70% by weight, preferably from about 0.55 to about 0.65% by weight, more preferably about 0.60% by weight.
  • the role of Cu is to strengthen the matrix and increase the yield strength of the alloy.
  • the content of Cu in the aluminum alloy of the invention is less than 0.40% by weight, the yield strength can be significantly improved without significantly impairing the electrical conductivity of the material; when it is higher than 0.20 wt%, the mass of the AlFeCu phase compound can be increased, and the Cu element can be enlarged in the aluminum.
  • the amount of solid solution in the alloy thereby increasing the yield strength of the alloy.
  • the Cu content is from about 0.20 to about 0.30% by weight, preferably from about 0.22 to about 0.28% by weight, more preferably about 0.25 % by weight.
  • Si is widely present in existing aluminum alloys and is an element that has a large influence on the electrical conductivity of aluminum alloys.
  • the present invention is expected to avoid a large drop in the electrical conductivity of the aluminum alloy by strictly controlling the Si content.
  • the Si content is from about 0.03 to about 0.20% by weight, preferably from about 0.10 to about 0.20% by weight, more preferably about 0.18% by weight.
  • a method of preparing an aluminum alloy having high electrical conductivity and high yield strength comprising from about 0.40 to about 0.70 wt%, respectively, based on the total weight of the aluminum alloy Fe, about 0.20 to about 0.40 wt% of Cu, about 0.01 to about 0.20 wt% of Si and the balance of the A1 batching furnace and smelting step.
  • the process of preparing an aluminum alloy is allowed Impurable impurities are introduced.
  • the allowable impurities may be purposefully introduced to further improve the performance of the aluminum alloy of the present invention other than electrical conductivity and yield strength, or may be inevitably introduced due to production conditions.
  • the allowable impurities preferably include one or more of Zn, Ti, Mg, Mn, In, Zr, Cr, M, Sc, V, Hf, Be, Sn, Co, B, and rare earth elements, It preferably includes Zn and Ti.
  • the total amount of the permissible impurities is not more than about 0.15 wt%, preferably not more than about 0.10 wt%, more preferably based on the total weight of the aluminum alloy. Not more than about 0.05% by weight.
  • the content of each of the permissible impurities is no greater than about 0.05 wt%, preferably no greater than about 0.03 wt%, more preferably no greater than about 0.01 wt% o
  • the content of Fe is from about 0.55 ⁇ about 0.70wt%, preferably from about 0.55 ⁇ about 0.65wt%, more preferably from about 0.60wt% o
  • the content of Cu is from about 0.20 ⁇ about 0.30wt%, preferably from about 0.22 ⁇ about 0.28wt%, more preferably from about 0.25wt% o
  • the Si content is from about 0.03 to about 0.20% by weight, preferably from about 0.10 to about 0.20% by weight, more preferably about 0.18% by weight.
  • an aluminum alloy workpiece produced from an aluminum alloy according to the invention.
  • the aluminum alloy workpiece of the present invention can be formed into a variety of shapes suitable for applications such as sheets, profiles, forgings or other suitable shapes for applications by processing methods known in the art, such as rolling, extrusion or forging. get.
  • the aluminum alloy ingot can be produced by a conventional method known in the art, preferably by, for example, a semi-continuous direct water-cooling casting process.
  • the aluminum alloy workpiece of the present invention can be formed by the following steps:
  • Extrusion processing aluminum alloy ingots of different specifications are fed into the extrusion cylinder (wherein the extrusion cylinder can be preheated to 260 ⁇ 440", preferably 260 ⁇ 360" preheating temperature) for extrusion, aluminum profiles After correction to the finished product.
  • an aluminum alloy or aluminum alloy workpiece according to the invention for the preparation of an induction plate.
  • the sensing plate is preferably an induction plate for a magnetic levitation train track.
  • an induction plate comprising an aluminum alloy or aluminum alloy workpiece according to the invention.
  • the induction plate is a composite plate composed of an aluminum alloy plus a workpiece and a steel plate.
  • the sensing plate is preferably an inductive plate for a magnetic levitation train track.
  • the sensing plate can be formed by methods known in the art such as bridging.
  • aluminum alloy means a general term for an alloy formed by adding other elements on the basis of A1.
  • maglev train includes, but is not limited to, the principle of "same-sex repulsive, opposite-sex attraction,” which causes the traction locomotive motor and the track-sensing plate to generate magnetic force, so that the vehicle body is completely off-track, suspended in the distance track. For example, a train that vacates about 1 cm.
  • induction plate for a magnetic levitation train refers to a track type plate which is used as a traction force to propel the train forward with a magnetic force generated by a magnetic levitation train traction locomotive motor (rotor).
  • rotor a magnetic levitation train traction locomotive motor
  • the weight percentage of each element in the obtained aluminum alloy material is Fe: 0.50%, Cu: 0.20%, Si: 0.014%, Zn: 0.05%, Ti: 0.05%, impurity ⁇ 0.05%, total impurity ⁇ 0.15%, the rest For Al.
  • Extrusion processing The obtained round aluminum ingot is sent to the extrusion cylinder (preheating temperature is 260 ⁇ 360") for extrusion molding, and the aluminum profile is corrected to the finished product.
  • the weight percentage of each element in the obtained aluminum alloy material is Fe: 0.65 %, Cu: 0.4%, Si: 0.18%, Zn: 0.07%, Ti: 0.15 %, impurity ⁇ 0.05%, total impurity ⁇ 0.15%, and the rest For A1. It was obtained in the same manner as in Example 1.
  • the weight percentage of each element in the obtained aluminum alloy material is Fe: 0.40%, Cu: 0.30%, Si: 0.03%, Zn: 0.01%, Ti: 0.01%, impurity single ⁇ 0.05%, total impurity ⁇ 0.15%, and the rest For A1. It was obtained in the same manner as in Example 1.
  • the obtained aluminum alloy material has a weight percentage of Fe: 0.50%, Cu: 0.20%, Si: 0.014%, Zn: 0.01%, Ti: 0.01%, impurity ⁇ 0.05%, and total impurity ⁇ 0.15%.
  • the rest is Al. The same as in the first embodiment The steps are made.
  • the weight percentage of each element in the obtained aluminum alloy material is Fe: 0.65 %, Cu: 0.4%, Si: 0.02%, Zn: 0.005 %, Ti: 0.01%, impurity ⁇ 0.05%, total impurity ⁇ 0.15%, and the rest For A1. It was obtained in the same manner as in Example 1.
  • the weight percentage of each element in the obtained aluminum alloy material is Fe: 0.40%, Cu: 0.30%, Si: 0.10%, Zn: 0.05%, Ti: 0.05%, impurity ⁇ 0.05%, total impurity ⁇ 0.15%, and the rest For A1. It was obtained in the same manner as in Example 1.
  • the weight percentage of each element in the obtained aluminum alloy material is M g : 0.20 % , Fe:
  • the obtained aluminum alloy material has a weight percentage of M g : 0.85 %, Fe: 0.35%, Si: 0.35%, a single impurity of ⁇ 0.05%, a total impurity of ⁇ 0.15%, and the balance being Al. It was obtained in the same manner as in Example 1.
  • Example 1 Mg Fe Cu Si Zn Ti Al Impurity
  • Example 2 - 0.65 0.40 0.18 0.07 0.15 Balance ⁇ 0.15%
  • Example 3 - 0.40 0.30 0.03 0.01 0.01 Balance ⁇ 0.15%
  • Example 4 - 0.50 0.20 0.014 0.01 0.01 Balance ⁇ 0.15%
  • Example 5 - 0.65 0.40 0.02 0.005 0.01 balance ⁇ 0.15%
  • Example 6 - 0.40 0.30 0.10 0.05 0.05 balance ⁇ 0.15% Comparative Example 1 0.30 0.95 - - - - Balance ⁇ 0.15% Comparative Example 2 0.20 0.55 0.25 - - - Balance ⁇ 0.15% Comparative Example 3 0.85 0.35 - 0.35 - - Balance ⁇ 0.15%
  • Test instrument sigmatest2.069 eddy current conductivity meter (made by FOERSTER, Germany)
  • Test block thickness 4.0mm X length 50mm x width 50mm
  • Test temperature room temperature (about 25")
  • Test Example 2 Evaluation of yield strength, tensile strength and elongation
  • Test equipment AG-IS100KN tensile testing machine (manufactured by Shimadzu SHIMADZU Co., Ltd.)
  • Test temperature room temperature (about 25")
  • the conductivity of the aluminum alloy material according to Example 1-6 of the present invention is not less than 59% IACS, and a yield strength R P 0. 2 were 90N / mm 2 or more, clearly superior to Comparative Example 1 -3 aluminum alloy.

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Abstract

An aluminum alloy having high electrical conductivity and high yield strength, comprises: iron about 0.40- about 0.70 wt%, copper about 0.20- about 0.40 wt%, silicon about 0.01- about 0.20 wt%, and balance Al. The preparation methods and application of the aluminum alloy are also provided. Worked article which is made of the aluminum alloy, especially induction plate for magnetic suspension train rail, is also provided.

Description

高电导率、 高屈服强度铝合金及其加工件和感应板  High conductivity, high yield strength aluminum alloy and its processed parts and sensor boards
技术领域 Technical field
本发明涉及一种铝合金, 尤其是具有高电导率、 高屈服强度 的铝合金。本发明还涉及该铝合金的制备方法和用途, 以及使用 该铝合金制造的加工件和感应板,尤其是磁悬浮列车轨道用感应 板。  The present invention relates to an aluminum alloy, particularly an aluminum alloy having high electrical conductivity and high yield strength. The present invention also relates to a method and use for the preparation of the aluminum alloy, as well as a machined part and an induction plate manufactured using the aluminum alloy, particularly an induction plate for a magnetic levitation train track.
背景技术 Background technique
铝合金具有一系列优异特性, 广泛应用于交通运输、航空航 天、 建筑桥梁、 包装容器、 电气电子、 机械制造及能源工业等领 域。一些特殊领域的发展对铝合金的性能提出了更高的要求,例 如磁悬浮列车轨道用感应板要求既要有高电导率,又要有高屈服 强度。  Aluminium alloys have a range of excellent properties and are used in a wide range of applications including transportation, aerospace, building bridges, packaging containers, electrical and electronics, machinery manufacturing and the energy industry. The development of some special fields puts higher demands on the performance of aluminum alloys. For example, the induction plates for magnetic levitation trains require high electrical conductivity and high yield strength.
现有铝合金中电导率能达到 58%IACS 以上的有纯铝及少 量的合金。虽然已有一些铝合金材料的电导率基本能够达到感应 板所要求的 60%IACS, 但加工状态屈服强度 RP0.2—般仅为 40 N/mm2左右, 最高不超过 60 N/mm2, 因此达不到使用要求。 In the existing aluminum alloy, the electrical conductivity can reach above 58% IACS with pure aluminum and a small amount of alloy. Although the electrical conductivity of some aluminum alloy materials can basically reach the 60% IACS required by the induction plate, the processing state yield strength R P 0. 2 is generally only about 40 N/mm 2 , and the maximum is not more than 60 N/mm. 2 , therefore, the requirements for use are not met.
现有的磁悬浮列车轨道用感应板主要是由铜合金板和钢板 复合而成的。 而铜合金价格昂贵,如果能够以铝合金代替铜合金 制造感应板, 必将产生巨大的经济效益, 大大节省磁悬浮列车轨 道建设的成本, 从而有利于磁悬浮列车的大范围推广利用。  The existing induction plates for magnetic levitation train tracks are mainly composed of copper alloy plates and steel plates. Copper alloys are expensive. If aluminum alloys can be used instead of copper alloys to make induction plates, huge economic benefits will be generated, and the cost of magnetic suspension train construction will be greatly saved, which will facilitate the widespread use of maglev trains.
发明内容 Summary of the invention
本发明的一个目的是提供一种具有高电导率和高屈服强度 的铝合金, 其特征在于: 基于所述铝合金的总重量, 所述铝合金 包含约 0.40〜约 0.70wt%的 Fe、 约 0.20〜约 0.40wt%的 Cu、 约 0.01〜约 0.20wt%的 Si和余量的 Al。  An object of the present invention is to provide an aluminum alloy having high electrical conductivity and high yield strength, characterized in that the aluminum alloy comprises from about 0.40 to about 0.70% by weight of Fe, based on the total weight of the aluminum alloy. 0.20 to about 0.40% by weight of Cu, about 0.01 to about 0.20% by weight of Si and the balance of Al.
本发明的另一个目的是提供本发明具有高电导率和高屈服 强度的铝合金的制备方法,所述方法包括将基于铝合金的总重量 分别为约 0.40〜约 0.70wt%的 Fe、 约 0.20〜约 0.40wt%的 Cu、 约 0.01〜约 0.20wt%的 Si和余量的 A1配料装炉并熔炼的步骤。 本发明的再一个目的是提供由本发明具有高电导率和高屈 服强度的铝合金制成的铝合金加工件。 Another object of the present invention is to provide a method for producing an aluminum alloy having high electrical conductivity and high yield strength according to the present invention, which comprises from about 0.40 to about 0.70 wt% of Fe, respectively, based on the total weight of the aluminum alloy, of about 0.20. ~ about 0.40wt% Cu, about 0.01 to about 0.20 wt% of Si and the balance of the A1 batching furnace and smelting step. It is still another object of the present invention to provide an aluminum alloy workpiece made of an aluminum alloy having high electrical conductivity and high yield strength of the present invention.
本发明的又一个目的是提供本发明具有高电导率和高屈服 强度的铝合金或铝合金加工件用于制备感应板、尤其是磁悬浮列 车轨道用感应板的用途。  Still another object of the present invention is to provide an aluminum alloy or aluminum alloy workpiece having high electrical conductivity and high yield strength of the present invention for use in the preparation of an induction plate, particularly an induction plate for a magnetic levitation train track.
本发明还有一个目的是提供一种感应板,尤其是磁悬浮列车 轨道用感应板,其包含本发明具有高电导率和高屈服强度的铝合 金或铝合金加工件。  Still another object of the present invention is to provide an induction plate, particularly an induction plate for a magnetic levitation train track, comprising the aluminum alloy or aluminum alloy workpiece of the present invention having high electrical conductivity and high yield strength.
才艮据 IACS ( International Annealed Copper Standard ) ¾ 试, 本发明铝合金的电导率不低于约 59%IACS, 并且加工态产 品屈服强度 RP。.2可达约 90N/mm2以上(与现有技术相比提高了 至少约 1.5倍)。 因此本发明的铝合金及其加工件可以有效地应 用于要求同时具有高电导率和高屈服强度的场合,例如可以用作 核反应堆用铝材、 电气设备用铝材等, 尤其是可以替代铜合金用 于制造磁悬浮列车轨道用感应板。 According to the IACS (International Annealed Copper Standard) 3⁄4 test, the electrical conductivity of the aluminum alloy of the present invention is not less than about 59% IACS, and the yield strength R P of the processed product. 2 can be up to about 90 N/mm 2 or more (increased by at least about 1.5 times compared to the prior art). Therefore, the aluminum alloy and the workpiece thereof of the present invention can be effectively applied to applications requiring high electrical conductivity and high yield strength, for example, aluminum for nuclear reactors, aluminum for electrical equipment, etc., in particular, can replace copper alloys. It is used to manufacture induction boards for magnetic levitation train tracks.
与现有技术中的铝合金相比,本发明的铝合金通过在纯铝中 添加常规元素 Fe、 Cu、 Si而实现了高电导率和高屈服强度的优 化组合, 既经济又实用。 此外, 本发明的铝合金及其加工件还具 有低成本、 轻质高强的优点, 并且取决于各元素之间的比例, 还 可以获得耐腐蚀、 良好的可钎焊性能和易切削性等方面的优点, 并且可以根据实际应用通过在本发明范围内调节各成分的含量 来进一步改善其中的一种或更多种性能(这种调节可以由本领域 技术人员利用本领域已知的手段容易地实现), 因此可以进一步 得到综合性能优异的铝合金产品。  Compared with the aluminum alloy of the prior art, the aluminum alloy of the present invention achieves an optimized combination of high electrical conductivity and high yield strength by adding conventional elements Fe, Cu, Si to pure aluminum, which is economical and practical. In addition, the aluminum alloy and the workpiece thereof of the present invention have the advantages of low cost, light weight and high strength, and depending on the ratio between the elements, corrosion resistance, good brazability and machinability can be obtained. Advantages, and one or more of the properties can be further improved by adjusting the content of each component within the scope of the present invention according to practical applications (this adjustment can be easily achieved by those skilled in the art using means known in the art) Therefore, an aluminum alloy product excellent in overall performance can be further obtained.
使用本发明的铝合金或其加工件制成的感应板是感应板领 域的一个技术突破,更是磁悬浮列车轨道用感应板领域的一个巨 大突破, 大大节约磁悬浮列车轨道的建造成本,将对于推动磁悬 浮列车技术的发展起到不可替代的作用。  The induction plate made of the aluminum alloy or the processed part thereof of the invention is a technical breakthrough in the field of induction plates, and is a huge breakthrough in the field of induction plates for magnetic suspension train tracks, which greatly saves the construction cost of the magnetic suspension train track, and will promote The development of maglev train technology plays an irreplaceable role.
具体实施方式 在本发明的上下文中, 除非另有说明, 所提及的百分比均为 重量百分比。 另外, 本文所提及的数值范围均包含端点值。在使 用 "不大于"或 "不高于"表示数值范围时, 包括但不限于所指 的特定组成的含量为零的情况, 例如, 不大于 0.05wt%的 Zn可 包括合金不含有 Zn的情况。 "约" 字表示不排除由于操作误差 而使得所指成分的含量略大于或略小于所指数值的情况,优选所 指数值在 ±5 %的误差范围内浮动。 detailed description In the context of the present invention, the percentages mentioned are by weight unless otherwise indicated. In addition, the range of values referred to herein includes endpoint values. Where "not greater than" or "not higher than" is used in the numerical range, including but not limited to the case where the specified composition has a zero content, for example, no more than 0.05 wt% of Zn may include the case where the alloy does not contain Zn. . The word "about" does not exclude the case where the content of the indicated component is slightly larger or slightly smaller than the index value due to the operational error, and it is preferred that the index value fluctuates within an error range of ± 5%.
在本发明的第一方面,提供一种具有高电导率和高屈服强度 的铝合金, 其中基于所述铝合金的总重量, 所述铝合金包含 0.40~0.70wt%的 Fe、 0.20~0.40wt%的 Cu、 0.01~0.20wt%的 Si 和余量的 Al。  In a first aspect of the invention, there is provided an aluminum alloy having high electrical conductivity and high yield strength, wherein the aluminum alloy comprises 0.40 to 0.70 wt% of Fe, 0.20 to 0.40 wt% based on the total weight of the aluminum alloy % Cu, 0.01 to 0.20 wt% of Si and the balance of Al.
在本发明的一些实施方案中,所述铝合金可以包含可容许的 杂质。所述可容许杂质的含量没有特殊限制,只要不损害本发明 的高电导率、 高屈服强度铝合金的基本性能即可。在一些优选实 施方案中,基于铝合金的总重量, 所述可容许的杂质的总量不大 于约 0.15wt% , 优选不大于约 0.10wt% , 更优选不大于约 0.05wt%o In some embodiments of the invention, the aluminum alloy may contain tolerable impurities. The content of the allowable impurities is not particularly limited as long as the basic properties of the high conductivity, high yield strength aluminum alloy of the present invention are not impaired. In some preferred embodiments, based on total weight of the alloy, the total amount of said tolerable impurities not more than about 0.15wt%, preferably no more than about 0.10wt%, more preferably no more than about 0.05wt% o
在进一步的实施方案中,所述可容许的杂质中每一种杂质的 含量都不大于约 0.05wt%,优选不大于约 0.03wt%,更优选不大 于约 0.01wt%。  In a further embodiment, the content of each of the permissible impurities is no greater than about 0.05 wt%, preferably no greater than about 0.03 wt%, more preferably no greater than about 0.01 wt%.
在本发明中术语 "可容许的杂质"是指不会对本发明的铝合 金产生不利影响的成分,尤其是不会对本发明铝合金的高电导率 和高屈服强度产生显著不利的影响的成分。所述可容许的杂质可 以是为了改善本发明铝合金的除电导率和屈服强度以外的性能 而有目的地引入的成分,也可以是由于生产条件所限而不可避免 地引入的成分。 所述可容许的杂质优选包括 Zn、 Ti、 Mg、 Mn、 In、 Zr、 Cr、 M、 Sc、 V、 Hf、 Be、 Sn、 Co、 B和稀土元素中 的一种或更多种, 更优选包括 Zn和 Ti。  The term "allowable impurities" in the present invention means a component which does not adversely affect the aluminum alloy of the present invention, especially a component which does not significantly adversely affect the high electrical conductivity and high yield strength of the aluminum alloy of the present invention. The allowable impurities may be components which are purposely introduced to improve the properties of the aluminum alloy of the present invention other than electrical conductivity and yield strength, and may also be components which are inevitably introduced due to production conditions. The allowable impurities preferably include one or more of Zn, Ti, Mg, Mn, In, Zr, Cr, M, Sc, V, Hf, Be, Sn, Co, B, and rare earth elements, It preferably includes Zn and Ti.
对本发明铝合金的高电导率和高屈服强度作出贡献的是 Fe、 Cu、 Si和作为基质的 A1的特定组成。 Fe 的作用是增加化合物质点数量、 细化晶粒尺寸, 提高再 结晶温度,提高合金热加工态屈服强度, 并且不会损害电导率或 者使得电导率下降幅度较少。 本发明铝合金中 Fe的含量低于约 0.70wt%时, 可以较大幅度地提高屈服强度, 而材料的电导率不 会下降或者下降幅度 ^I、; 高于 0.40wt%时, 会形成足够多的 AlFeCu化合物相质点, 从而提高合金屈服强度。 在本发明的一 个优选实施方案中, Fe 的含量为约 0.55〜约 0.70wt%、 优选约 0.55〜约 0.65wt%、 更优选约 0.60wt%。 What contributes to the high electrical conductivity and high yield strength of the aluminum alloy of the present invention is the specific composition of Fe, Cu, Si and A1 as a matrix. The role of Fe is to increase the number of compound particles, refine the grain size, increase the recrystallization temperature, and increase the yield strength of the alloy during hot working, without damaging the conductivity or making the conductivity decrease less. When the content of Fe in the aluminum alloy of the invention is less than about 0.70% by weight, the yield strength can be increased to a large extent, and the electrical conductivity of the material does not decrease or decrease by ^I; when it is higher than 0.40 wt%, sufficient formation is formed. A large number of AlFeCu compounds phase points, thereby increasing the yield strength of the alloy. In a preferred embodiment of the invention, the Fe content is from about 0.55 to about 0.70% by weight, preferably from about 0.55 to about 0.65% by weight, more preferably about 0.60% by weight.
Cu的作用是强化基体, 提高合金屈服强度。 本发明铝合金 中 Cu的含量低于 0.40wt%时, 可以显著提高屈服强度, 而不会 明显损害材料的电导率; 高于 0.20wt%时, 可以增加 AlFeCu相 化合物质点, 扩大 Cu元素在铝中的固溶量, 从而提高合金屈服 强度。 在本发明的一个优选实施方案中, Cu 的含量为约 0.20~ 约 0.30wt%、 优选约 0.22〜约 0.28wt%、 更优选约 0.25wt%。  The role of Cu is to strengthen the matrix and increase the yield strength of the alloy. When the content of Cu in the aluminum alloy of the invention is less than 0.40% by weight, the yield strength can be significantly improved without significantly impairing the electrical conductivity of the material; when it is higher than 0.20 wt%, the mass of the AlFeCu phase compound can be increased, and the Cu element can be enlarged in the aluminum. The amount of solid solution in the alloy, thereby increasing the yield strength of the alloy. In a preferred embodiment of the invention, the Cu content is from about 0.20 to about 0.30% by weight, preferably from about 0.22 to about 0.28% by weight, more preferably about 0.25 % by weight.
Si广泛地存在于现有的铝合金中,是对铝合金电导率影响较 大的一种元素。 本发明期望通过严格控制 Si的含量来避免铝合 金电导率的大幅下降。 本发明铝合金中 Si的含量低于 0.20wt% 时, 可以较好地控制电导率下降幅度; 高于 0.01wt%时, 有利于 生产控制, 并且 Si的少量存在也可以对合金强度的改善有所贡 献。 在本发明的一个优选实施方案中, Si 的含量为约 0.03〜约 0.20wt%、 优选约 0.10〜约 0.20wt%、 更优选约 0.18wt%。  Si is widely present in existing aluminum alloys and is an element that has a large influence on the electrical conductivity of aluminum alloys. The present invention is expected to avoid a large drop in the electrical conductivity of the aluminum alloy by strictly controlling the Si content. When the content of Si in the aluminum alloy of the invention is less than 0.20% by weight, the degree of decrease in electrical conductivity can be well controlled; when it is higher than 0.01% by weight, it is advantageous for production control, and the presence of a small amount of Si can also improve the strength of the alloy. Contribution. In a preferred embodiment of the invention, the Si content is from about 0.03 to about 0.20% by weight, preferably from about 0.10 to about 0.20% by weight, more preferably about 0.18% by weight.
在本发明的第二方面,提供一种制备根据本发明的具有高电 导率和高屈服强度的铝合金的方法,所述方法包括将基于铝合金 的总重量分别为约 0.40〜约 0.70wt%的 Fe、 约 0.20〜约 0.40wt% 的 Cu、 约 0.01〜约 0.20wt%的 Si和余量的 A1配料装炉并熔炼 的步骤。  In a second aspect of the invention, there is provided a method of preparing an aluminum alloy having high electrical conductivity and high yield strength according to the present invention, the method comprising from about 0.40 to about 0.70 wt%, respectively, based on the total weight of the aluminum alloy Fe, about 0.20 to about 0.40 wt% of Cu, about 0.01 to about 0.20 wt% of Si and the balance of the A1 batching furnace and smelting step.
在本发明的铝合金制备方法中的具体工艺步骤和工艺条件 没有特殊限制,并且可以由本领域技术人员根据本领域的公知常 识和参考本领域已知的任何常规铝合金制备工艺进行确定,只要 能够生产出本发明范围内的铝合金即可。  The specific process steps and process conditions in the aluminum alloy preparation method of the present invention are not particularly limited, and can be determined by those skilled in the art according to common knowledge in the art and any conventional aluminum alloy preparation process known in the art, as long as It is sufficient to produce an aluminum alloy within the scope of the present invention.
在本发明的一些实施方案中,允许在制备铝合金的工艺过程 中引入可容许的杂质。所述可容许的杂质可以有目的地引入,从 而进一步改善本发明铝合金的除电导率和屈服强度以外的性能, 也可以是由于生产条件所限而不可避免地引入的。所述可容许的 杂质优选包括 Zn、 Ti、 Mg、 Mn、 In、 Zr、 Cr、 M、 Sc、 V、 Hf、 Be、 Sn、 Co、 B和稀土元素中的一种或更多种, 更优选包 括 Zn和 Ti。 In some embodiments of the invention, the process of preparing an aluminum alloy is allowed Impurable impurities are introduced. The allowable impurities may be purposefully introduced to further improve the performance of the aluminum alloy of the present invention other than electrical conductivity and yield strength, or may be inevitably introduced due to production conditions. The allowable impurities preferably include one or more of Zn, Ti, Mg, Mn, In, Zr, Cr, M, Sc, V, Hf, Be, Sn, Co, B, and rare earth elements, It preferably includes Zn and Ti.
在一个优选实施方案中, 在根据本发明方法制备的铝合金 中, 所述可容许的杂质的总量基于铝合金的总重量不大于约 0.15wt%, 优选不大于约 0.10wt%, 更优选不大于约 0.05wt%。 在进一步的实施方案中,所述可容许的杂质中每一种杂质的含量 都不大于约 0.05wt%,优选不大于约 0.03wt%,更优选不大于约 0.01wt%o In a preferred embodiment, in the aluminum alloy prepared according to the method of the present invention, the total amount of the permissible impurities is not more than about 0.15 wt%, preferably not more than about 0.10 wt%, more preferably based on the total weight of the aluminum alloy. Not more than about 0.05% by weight. In a further embodiment, the content of each of the permissible impurities is no greater than about 0.05 wt%, preferably no greater than about 0.03 wt%, more preferably no greater than about 0.01 wt% o
优选地, 在根据本发明方法制备的铝合金中, Fe 的含量为 约 0.55〜约 0.70wt%、 优选约 0.55〜约 0.65wt%、 更优选约 0.60wt%o Preferably, in the aluminum alloy prepared by the process according to the present invention, the content of Fe is from about 0.55~ about 0.70wt%, preferably from about 0.55~ about 0.65wt%, more preferably from about 0.60wt% o
优选地, 在根据本发明方法制备的铝合金中, Cu的含量为 约 0.20〜约 0.30wt%、 优选约 0.22〜约 0.28wt%、 更优选约 0.25wt%o Preferably, in the aluminum alloy prepared by the process according to the present invention, the content of Cu is from about 0.20~ about 0.30wt%, preferably from about 0.22~ about 0.28wt%, more preferably from about 0.25wt% o
优选地,在根据本发明方法制备的铝合金中, Si的含量为约 0.03〜约 0.20wt%、优选约 0.10〜约 0.20wt%、更优选约 0.18wt%。  Preferably, in the aluminum alloy prepared according to the method of the present invention, the Si content is from about 0.03 to about 0.20% by weight, preferably from about 0.10 to about 0.20% by weight, more preferably about 0.18% by weight.
在本发明的第三方面,提供一种由根据本发明的铝合金制成 的铝合金加工件。  In a third aspect of the invention, there is provided an aluminum alloy workpiece produced from an aluminum alloy according to the invention.
本发明的铝合金加工件可以通过本领域已知的加工方法,例 如轧制、挤压或锻压,将铝合金铸锭加工成型为例如板材、型材、 锻件或其它适合于应用的各种形状而得到。所述铝合金铸锭可以 利用本领域已知的传统方法制得,优选通过例如半连续直接水冷 铸造法制得。  The aluminum alloy workpiece of the present invention can be formed into a variety of shapes suitable for applications such as sheets, profiles, forgings or other suitable shapes for applications by processing methods known in the art, such as rolling, extrusion or forging. get. The aluminum alloy ingot can be produced by a conventional method known in the art, preferably by, for example, a semi-continuous direct water-cooling casting process.
例如, 在一个制备本发明的铝合金加工件的具体实施方案 中, 本发明的铝合金加工件可以通过以下步骤成型:  For example, in a specific embodiment for preparing the aluminum alloy workpiece of the present invention, the aluminum alloy workpiece of the present invention can be formed by the following steps:
a) 熔炼: 将原铝锭及其他含所需合金元素的母合金或纯金 属装入熔炼炉内,升温熔化(例如,在约 900 " 以上、优选约 900 。C ~约 1050 " 、 更优选约 900 " ~约 950 " 的炉膛温度下加热至 熔化, 所得铝液保持在约 715" ~约 740" , 优选约 725" ~约 735 更优选约 730 " ); 待熔池内炉料充分熔化后, 进行扒渣 搅拌; 调整熔体成分; 再将铝合金熔体转移至静置炉内静置, 并 精炼净化熔体。 a) Smelting: Raw aluminum ingots and other master alloys or pure gold containing the required alloying elements It is charged into the smelting furnace and heated to melt (for example, at a temperature of about 900 Å or more, preferably about 900 ° C to about 1050 Å, more preferably about 900 ~ to about 950 Å), and the obtained aluminum liquid is kept at the temperature. About 715" ~ about 740", preferably about 725" ~ about 735 is more preferably about 730 "); after the furnace material in the molten pool is fully melted, the slag is stirred; the melt composition is adjusted; and the aluminum alloy melt is transferred to the stationary furnace. The interior is allowed to stand and refined to purify the melt.
b)铸造: 静置炉内铝合金熔体经过滤系统过滤后, 流入结 晶器, 直接水冷铸造成不同规格的铝合金铸锭。  b) Casting: After the aluminum alloy melt in the static furnace is filtered by the filtration system, it flows into the crystallizer and is directly water-cooled into aluminum alloy ingots of different specifications.
c) 挤压加工: 不同规格的铝合金铸锭, 送入挤压筒 (其中 挤压筒可以预先加热至 260 ~ 440" 、 优选 260 ~ 360 " 的预热温 度)进行挤压成型, 铝型材经矫直至成品。  c) Extrusion processing: aluminum alloy ingots of different specifications are fed into the extrusion cylinder (wherein the extrusion cylinder can be preheated to 260 ~ 440", preferably 260 ~ 360" preheating temperature) for extrusion, aluminum profiles After correction to the finished product.
在本发明的第四方面,提供根据本发明的铝合金或铝合金加 工件用于制备感应板的用途。所述感应板优选为磁悬浮列车轨道 用感应板。  In a fourth aspect of the invention, there is provided the use of an aluminum alloy or aluminum alloy workpiece according to the invention for the preparation of an induction plate. The sensing plate is preferably an induction plate for a magnetic levitation train track.
在本发明的第五方面,提供一种感应板, 所述感应板包含根 据本发明的铝合金或铝合金加工件。  In a fifth aspect of the invention, there is provided an induction plate comprising an aluminum alloy or aluminum alloy workpiece according to the invention.
在本发明的一个优选实施方案中,所述感应板是由铝合金加 工件和钢板构成的复合板。所述感应板优选为磁悬浮列车轨道用 感应板。 所述感应板可以通过本领域已知的方法例如桥压法制 成。  In a preferred embodiment of the invention, the induction plate is a composite plate composed of an aluminum alloy plus a workpiece and a steel plate. The sensing plate is preferably an inductive plate for a magnetic levitation train track. The sensing plate can be formed by methods known in the art such as bridging.
在本发明中, 术语 "铝合金" 是指以 A1为基通过添加其他 元素而形成的合金的总称。  In the present invention, the term "aluminum alloy" means a general term for an alloy formed by adding other elements on the basis of A1.
在本发明中, 术语 "磁悬浮列车" 包括但不限于利用"同性 相斥, 异性相吸,,的原理, 让牵引机车电机与轨道感应板产生磁 力,使车体完全脱离轨道, 悬浮在距离轨道例如约 1厘米处腾空 行驶的列车。  In the present invention, the term "maglev train" includes, but is not limited to, the principle of "same-sex repulsive, opposite-sex attraction," which causes the traction locomotive motor and the track-sensing plate to generate magnetic force, so that the vehicle body is completely off-track, suspended in the distance track. For example, a train that vacates about 1 cm.
在本发明中, 术语 "磁悬浮列车用感应板"是指与磁悬浮列 车牵引机车电机(转子)所产生的磁力作为牵引力, 推动列车前 进的一种轨道型板。 下面结合具体实施例对本发明作进一步说明,以助于理解本 发明的内容, 但本发明不限于此。 In the present invention, the term "induction plate for a magnetic levitation train" refers to a track type plate which is used as a traction force to propel the train forward with a magnetic force generated by a magnetic levitation train traction locomotive motor (rotor). The present invention will be further described in conjunction with the specific embodiments to facilitate the understanding of the present invention, but the invention is not limited thereto.
实施例 1  Example 1
所得铝合金材料中各元素重量百分含量为 Fe: 0.50 % , Cu: 0.20 % , Si: 0.014 % , Zn: 0.05 % , Ti: 0.05 % ,杂质单个 < 0.05%, 杂质总和<0.15%, 其余为 Al。  The weight percentage of each element in the obtained aluminum alloy material is Fe: 0.50%, Cu: 0.20%, Si: 0.014%, Zn: 0.05%, Ti: 0.05%, impurity < 0.05%, total impurity < 0.15%, the rest For Al.
本实施例的具有高导电率和高屈服强度的铝合金材料通过 下列步骤制备:  The aluminum alloy material of the present embodiment having high electrical conductivity and high yield strength is prepared by the following steps:
a) 熔炼: 将原铝锭及其他含所需合金元素的母合金或纯金 属装入熔炼炉内, 在 900" 左右的炉膛温度下加热至熔化, 得到 温度保持在 730" 左右的铝液; 待熔池内炉料充分熔化后, 进行 扒渣搅拌; 根据上述合金元素比例, 调整熔体成分; 再将铝合金 熔体转移至静置炉内静置, 并精炼净化熔体。  a) Smelting: The original aluminum ingot and other master alloys or pure metals containing the required alloying elements are placed in a melting furnace, heated to a melting temperature at a furnace temperature of about 900" to obtain an aluminum liquid having a temperature of about 730"; After the furnace material in the molten pool is fully melted, the slag slag is stirred; the melt composition is adjusted according to the proportion of the above alloying elements; the aluminum alloy melt is transferred to a static furnace for standing, and the melt is refined and purified.
b)铸造: 静置炉内铝合金熔体经过滤系统过滤后, 流入结 晶器, 直接水冷铸造成 Φ127的圆铝锭。  b) Casting: After the aluminum alloy melt in the static furnace is filtered by the filtration system, it flows into the crystallizer and is directly water-cooled into a round aluminum ingot of Φ127.
c) 挤压加工: 所得到的圆铝锭送入挤压筒 (预热温度为 260 ~ 360 " )进行挤压成型, 铝型材经矫直至成品。  c) Extrusion processing: The obtained round aluminum ingot is sent to the extrusion cylinder (preheating temperature is 260 ~ 360") for extrusion molding, and the aluminum profile is corrected to the finished product.
实施例 2  Example 2
所得铝合金材料中各元素重量百分含量为 Fe: 0.65 % , Cu: 0.4%, Si: 0.18%, Zn: 0.07%, Ti: 0.15 % , 杂质单个< 0.05%, 杂质总和< 0.15%,其余为 A1。以与实施例 1中相同的步骤制得。  The weight percentage of each element in the obtained aluminum alloy material is Fe: 0.65 %, Cu: 0.4%, Si: 0.18%, Zn: 0.07%, Ti: 0.15 %, impurity < 0.05%, total impurity < 0.15%, and the rest For A1. It was obtained in the same manner as in Example 1.
实施例 3  Example 3
所得铝合金材料中各元素重量百分含量为 Fe: 0.40 % , Cu: 0.30%, Si: 0.03%, Zn: 0.01 % , Ti: 0.01 % ,杂质单个< 0.05%, 杂质总和< 0.15%,其余为 A1。以与实施例 1中相同的步骤制得。  The weight percentage of each element in the obtained aluminum alloy material is Fe: 0.40%, Cu: 0.30%, Si: 0.03%, Zn: 0.01%, Ti: 0.01%, impurity single < 0.05%, total impurity < 0.15%, and the rest For A1. It was obtained in the same manner as in Example 1.
实施例 4  Example 4
所得得的铝合金材料中各元素重量百分含量为 Fe: 0.50 % , Cu: 0.20 % , Si: 0.014 % , Zn: 0.01 % , Ti: 0.01 % , 杂质单个 <0.05%, 杂质总和 <0.15%, 其余为 Al。 以与实施例 1中相同 的步骤制得。 The obtained aluminum alloy material has a weight percentage of Fe: 0.50%, Cu: 0.20%, Si: 0.014%, Zn: 0.01%, Ti: 0.01%, impurity <0.05%, and total impurity <0.15%. The rest is Al. The same as in the first embodiment The steps are made.
实施例 5  Example 5
所得铝合金材料中各元素重量百分含量为 Fe: 0.65 % , Cu: 0.4%, Si: 0.02%, Zn: 0.005 % , Ti: 0.01 % ,杂质单个< 0.05%, 杂质总和< 0.15%,其余为 A1。以与实施例 1中相同的步骤制得。  The weight percentage of each element in the obtained aluminum alloy material is Fe: 0.65 %, Cu: 0.4%, Si: 0.02%, Zn: 0.005 %, Ti: 0.01%, impurity < 0.05%, total impurity < 0.15%, and the rest For A1. It was obtained in the same manner as in Example 1.
实施例 6  Example 6
所得铝合金材料中各元素重量百分含量为 Fe: 0.40 % , Cu: 0.30%, Si: 0.10%, Zn: 0.05%, Ti: 0.05%,杂质单个< 0.05%, 杂质总和< 0.15%,其余为 A1。以与实施例 1中相同的步骤制得。  The weight percentage of each element in the obtained aluminum alloy material is Fe: 0.40%, Cu: 0.30%, Si: 0.10%, Zn: 0.05%, Ti: 0.05%, impurity < 0.05%, total impurity < 0.15%, and the rest For A1. It was obtained in the same manner as in Example 1.
对比例 1  Comparative example 1
所得铝合金材料中各元素重量百分含量为 Mg: 0.30 % , Fe: 0.95%, 杂质单个<0.05%, 杂质总和<0.15%, 其余为 Al。 以 与实施例 1中相同的步骤制得。 The resulting aluminum alloy material of the elements in weight percentage of M g: 0.30%, Fe: 0.95%, the single impurities <0.05%, total impurity content of <0.15%, the rest is Al. It was obtained in the same manner as in Example 1.
对比例 2  Comparative example 2
所得铝合金材料中各元素重量百分含量为 Mg: 0.20 % , Fe:The weight percentage of each element in the obtained aluminum alloy material is M g : 0.20 % , Fe:
0.55 % , Cu: 0.25%, 杂质单个 <0.05%, 杂质总和 <0.15%, 其余为 Al。 以与实施例 1中相同的步骤制得。 0.55 %, Cu: 0.25%, impurity <0.05%, total impurity <0.15%, and the balance is Al. It was obtained in the same manner as in Example 1.
对比例 3  Comparative example 3
所得铝合金材料中各元素重量百分含量为 Mg: 0.85 % , Fe: 0.35%, Si: 0.35%, 杂质单个<0.05%, 杂质总和<0.15%, 其 余为 Al。 以与实施例 1中相同的步骤制得。 The obtained aluminum alloy material has a weight percentage of M g : 0.85 %, Fe: 0.35%, Si: 0.35%, a single impurity of <0.05%, a total impurity of <0.15%, and the balance being Al. It was obtained in the same manner as in Example 1.
为比较起见, 以表 1列出实施例 1-6和对比例 1-3中制备的 铝合金材料的具体组成。
Figure imgf000009_0001
For the sake of comparison, the specific compositions of the aluminum alloy materials prepared in Examples 1-6 and Comparative Examples 1-3 are listed in Table 1.
Figure imgf000009_0001
合金中各元素的百分含量, wt%  Percentage of each element in the alloy, wt%
编号  Numbering
Mg Fe Cu Si Zn Ti Al 杂质 实施例 1 - 0.50 0.20 0.014 0.05 0.05 余量 < 0.15% 实施例 2 - 0.65 0.40 0.18 0.07 0.15 余量 < 0.15% 实施例 3 - 0.40 0.30 0.03 0.01 0.01 余量 < 0.15% 实施例 4 - 0.50 0.20 0.014 0.01 0.01 余量 < 0.15% 实施例 5 - 0.65 0.40 0.02 0.005 0.01 余量 < 0.15% 实施例 6 - 0.40 0.30 0.10 0.05 0.05 余量 < 0.15% 对比例 1 0.30 0.95 - - - - 余量 < 0.15% 对比例 2 0.20 0.55 0.25 - - - 余量 < 0.15% 对比例 3 0.85 0.35 - 0.35 - - 余量 < 0.15% Mg Fe Cu Si Zn Ti Al Impurity Example 1 - 0.50 0.20 0.014 0.05 0.05 Balance < 0.15% Example 2 - 0.65 0.40 0.18 0.07 0.15 Balance < 0.15% Example 3 - 0.40 0.30 0.03 0.01 0.01 Balance < 0.15% Example 4 - 0.50 0.20 0.014 0.01 0.01 Balance < 0.15% Example 5 - 0.65 0.40 0.02 0.005 0.01 balance < 0.15% Example 6 - 0.40 0.30 0.10 0.05 0.05 balance < 0.15% Comparative Example 1 0.30 0.95 - - - - Balance < 0.15% Comparative Example 2 0.20 0.55 0.25 - - - Balance < 0.15% Comparative Example 3 0.85 0.35 - 0.35 - - Balance < 0.15%
测试例 1: 评价电导率 Test Example 1: Evaluation of Conductivity
釆用 《YS/T478-200铜及铜合金导电率涡流检测方法》对上 述实施例 1-6和对比例 1-3中制备的铝合金材料进行电导率的检 测。  The electrical conductivity of the aluminum alloy materials prepared in the above Examples 1-6 and Comparative Examples 1-3 was examined using "YS/T478-200 Copper and Copper Alloy Conductivity Eddy Current Testing Method".
测试仪器: sigmatest2.069涡流电导仪 (由德国 FOERSTER 公司制造)  Test instrument: sigmatest2.069 eddy current conductivity meter (made by FOERSTER, Germany)
测试频率: 60KHZ  Test frequency: 60KHZ
标准块: 539  Standard block: 539
测试块: 厚 4.0mm X长 50mm x宽 50mm  Test block: thickness 4.0mm X length 50mm x width 50mm
测试温度: 室温(约 25" )  Test temperature: room temperature (about 25")
测试例 2: 评价屈服强度、 抗拉强度和延伸率 Test Example 2: Evaluation of yield strength, tensile strength and elongation
釆用 《GB/T228-2002金属材料室温拉伸试验方法》对上述 实施例 1-6和对比例 1-3中制备的铝合金材料进行屈服强度、 抗 拉强度和延伸率的检测。  The yield strength, tensile strength and elongation of the aluminum alloy materials prepared in the above Examples 1-6 and Comparative Examples 1-3 were examined by "GB/T228-2002 Metallic Material Tensile Test Method".
测试仪器: AG-IS100KN拉伸试验机(由岛津 SHIMADZU 公司制造)  Test equipment: AG-IS100KN tensile testing machine (manufactured by Shimadzu SHIMADZU Co., Ltd.)
加工性能试样: 2.5mm宽哑铃型试样  Processing performance sample: 2.5mm wide dumbbell type specimen
测试温度: 室温(约 25" )  Test temperature: room temperature (about 25")
拉伸速度: 5mm/min 下表 2列出了实施例 1-6和对比例 1-3中制备的铝合金材料 的性能测试结果。 Stretching speed: 5mm/min Table 2 below lists the performance test results of the aluminum alloy materials prepared in Examples 1-6 and Comparative Examples 1-3.
表 2  Table 2
Figure imgf000011_0001
由表 2可见, 本发明的实施例 1-6的铝合金材料的电导率均 不低于 59%IACS, 并且屈服强度 RP0.2均在 90N/mm2以上, 显 然优于对比例 1-3的铝合金。
Figure imgf000011_0001
Seen from Table 2, the conductivity of the aluminum alloy material according to Example 1-6 of the present invention is not less than 59% IACS, and a yield strength R P 0. 2 were 90N / mm 2 or more, clearly superior to Comparative Example 1 -3 aluminum alloy.
如上所述, 已经通过本发明的优选实施方案例示了本发明, 但是不应将本发明限于这些实施方案。根据本文的教导,本领域 技术人员可以对这些实施方案进行各种替代、 变化和 /或修改, 这些经过替代、 变化和 /或修改的实施方案只要不与本发明的教 导相互矛盾, 都应落入本发明的保护范围内。  As described above, the invention has been exemplified by the preferred embodiments of the invention, but the invention should not be limited to the embodiments. Numerous alternatives, variations, and/or modifications of these embodiments can be made by those skilled in the art in light of the teachings herein. These alternative, modified and/or modified embodiments should fall apart from the teachings of the present invention. Within the scope of protection of the present invention.

Claims

权 利 要 求 Rights request
1、一种具有高电导率和高屈服强度的铝合金,其特征在于: 基于铝合金的总重量,所述铝合金包含约 0.40〜约 0.70wt%的 Fe、 约 0.20〜约 0.40wt%的 Cu、 约 0.01〜约 0.20wt%的 Si和余量的 Al。 What is claimed is: 1. An aluminum alloy having high electrical conductivity and high yield strength, characterized in that the aluminum alloy comprises from about 0.40 to about 0.70% by weight of Fe, from about 0.20 to about 0.40% by weight, based on the total weight of the aluminum alloy. Cu, about 0.01 to about 0.20% by weight of Si and the balance of Al.
2、 根据权利要求 1所述的铝合金, 其中所述铝合金包含可 容许的杂质, 并且基于铝合金的总重量, 所述可容许的杂质的总 量不大于约 0.15wt%,优选不大于约 0.10wt%,更优选不大于约 0.05wt%o 2. The aluminum alloy according to claim 1, wherein the aluminum alloy contains allowable impurities, and based on the total weight of the aluminum alloy, the total amount of the allowable impurities is not more than about 0.15 wt%, preferably not more than About 0.10% by weight, more preferably no more than about 0.05% by weight o
3、 根据权利要求 2所述的铝合金, 其中基于铝合金的总重 量, 所述可容许的杂质中每一种杂质的含量都不大于约 0.05wt%, 优选不大于约 0.03wt%, 更优选不大于约 0.01wt%。  3. The aluminum alloy according to claim 2, wherein the content of each of the allowable impurities is not more than about 0.05% by weight, preferably not more than about 0.03% by weight, based on the total weight of the aluminum alloy. It is preferably no more than about 0.01% by weight.
4、 根据权利要求 2或 3所述的铝合金, 其中所述可容许的 杂质包括 Zn、 Ti、 Mg、 Mn、 In、 Zr、 Cr、 M、 Sc、 V、 Hf、 Be、 Sn、 Co、 B和稀土元素中的一种或更多种。  4. The aluminum alloy according to claim 2 or 3, wherein the allowable impurities include Zn, Ti, Mg, Mn, In, Zr, Cr, M, Sc, V, Hf, Be, Sn, Co, One or more of B and rare earth elements.
5、 根据权利要求 4所述的铝合金, 其中所述可容许的杂质 包括 Zn和 Ti。  5. The aluminum alloy according to claim 4, wherein the allowable impurities include Zn and Ti.
6、 根据权利要求 1-3中任一项所述的铝合金, 其中基于铝 合金的总重量, Fe的含量为约 0.55〜约 0.70wt%、 优选约 0.55~ 约 0.65wt%、 更优选约 0.60wt%。  The aluminum alloy according to any one of claims 1 to 3, wherein the Fe content is from about 0.55 to about 0.70% by weight, preferably from about 0.55 to about 0.65% by weight, more preferably, based on the total weight of the aluminum alloy. 0.60 wt%.
7、 根据权利要求 1-3 中任一项所述的铝合金, 其中基于铝 合金的总重量, Cu的含量为约 0.20〜约 0.30wt%、 优选约 0.22~ 约 0.28wt%、 更优选约 0.25wt%。  The aluminum alloy according to any one of claims 1 to 3, wherein the content of Cu is from about 0.20 to about 0.30% by weight, preferably from about 0.22 to about 0.28% by weight, more preferably, based on the total weight of the aluminum alloy. 0.25 wt%.
8、 根据权利要求 1-3 中任一项所述的铝合金, 其中基于铝 合金的总重量, Si的含量为约 0.03〜约 0.20wt%、 优选约 0.10~ 约 0.20wt%、 更优选约 0.18wt%。  The aluminum alloy according to any one of claims 1 to 3, wherein the content of Si is from about 0.03 to about 0.20% by weight, preferably from about 0.10 to about 0.20% by weight, more preferably, based on the total weight of the aluminum alloy. 0.18 wt%.
9、 一种制备根据权利要求 1所述的铝合金的方法, 所述方 法包括将基于铝合金的总重量分别为约 0.40〜约 0.70wt%的 Fe、 约 0.20〜约 0.40wt%的 Cu、 约 0.01〜约 0.20wt%的 Si和余量的9. A method of preparing an aluminum alloy according to claim 1, the method comprising, respectively, from about 0.40 to about 0.70 wt% of Fe, based on the total weight of the aluminum alloy, From about 0.20 to about 0.40% by weight of Cu, from about 0.01 to about 0.20% by weight of Si and the balance
A1配料装炉并熔炼的步骤。 The step of preparing and melting the A1 ingredients.
10、根据权利要求 9所述的方法, 其中允许在所述铝合金制 备过程中引入可容许的杂质, 并且基于铝合金的总重量, 所述可 容许的杂质的总量不大于约 0.15wt% , 优选不大于约 0.10wt% , 更优选不大于约 0.05wt%。  10. The method according to claim 9, wherein an allowable impurity is introduced during the preparation of the aluminum alloy, and the total amount of the allowable impurities is not more than about 0.15 wt% based on the total weight of the aluminum alloy. Preferably, it is no more than about 0.10% by weight, more preferably no more than about 0.05% by weight.
11、 根据权利要求 10所述的方法, 其中基于铝合金的总重 量, 所述可容许的杂质中每一种杂质的含量都不大于约 0.05wt% , 优选不大于约 0.03wt% , 更优选不大于约 0.01wt%。  11. The method according to claim 10, wherein the content of each of the allowable impurities is not more than about 0.05% by weight, preferably not more than about 0.03% by weight, more preferably based on the total weight of the aluminum alloy. Not more than about 0.01% by weight.
12、根据权利要求 10或 11所述的方法, 其中所述可容许的 杂质包括 Zn、 Ti、 Mg、 Mn、 In、 Zr、 Cr、 M、 Sc、 V、 Hf、 Be、 Sn、 Co、 B和稀土元素中的一种或更多种。  The method according to claim 10 or 11, wherein the allowable impurities include Zn, Ti, Mg, Mn, In, Zr, Cr, M, Sc, V, Hf, Be, Sn, Co, B And one or more of rare earth elements.
13、 根据权利要求 12所述的方法, 其中所述可容许的杂质 包括 Zn和 Ti。  13. The method of claim 12, wherein the tolerable impurities comprise Zn and Ti.
14、 根据权利要求 9-11 中任一项所述的方法, 其中基于铝 合金的总重量, Fe的含量为约 0.55〜约 0.70wt%、 优选约 0.55~ 约 0.65wt%、 更优选约 0.60wt%。  The method according to any one of claims 9 to 11, wherein the Fe content is from about 0.55 to about 0.70 wt%, preferably from about 0.55 to about 0.65 wt%, more preferably about 0.60, based on the total weight of the aluminum alloy. Wt%.
15、 根据权利要求 9-11 中任一项所述的方法, 其中基于铝 合金的总重量, Cu的含量为约 0.20〜约 0.30wt%、 优选约 0.22~ 约 0.28wt%、 更优选约 0.25wt%。  The method according to any one of claims 9 to 11, wherein the content of Cu is from about 0.20 to about 0.30% by weight, preferably from about 0.22 to about 0.28% by weight, more preferably about 0.25, based on the total weight of the aluminum alloy. Wt%.
16、 根据权利要求 9-11 中任一项所述的方法, 其中基于铝 合金的总重量, Si的含量为约 0.03〜约 0.20wt%、 优选约 0.10~ 约 0.20wt%、 更优选约 0.18wt%。  The method according to any one of claims 9 to 11, wherein the content of Si is from about 0.03 to about 0.20% by weight, preferably from about 0.10 to about 0.20% by weight, more preferably about 0.18, based on the total weight of the aluminum alloy. Wt%.
17、一种由根据权利要求 1-8中任一项的铝合金制成的铝合 金加工件。  17. An aluminum alloy workpiece produced from an aluminum alloy according to any one of claims 1-8.
18、 根据权利要求 17所述的铝合金加工件, 其中所述铝合 金加工件为板材、型材、锻件或其它适合于应用的各种形状的加 工件。  18. The aluminum alloy workpiece of claim 17, wherein the aluminum alloy workpiece is a sheet, profile, forging or other workpiece of various shapes suitable for the application.
19、根据权利要求 17或 18所述的铝合金加工件,其中所述 铝合金加工件通过轧制、 挤压或锻压铝合金铸锭而制得。 The aluminum alloy workpiece according to claim 17 or 18, wherein said The aluminum alloy workpiece is produced by rolling, extruding or forging an aluminum alloy ingot.
20、根据权利要求 1-8中任一项所述的铝合金或根据权利要 求 17-19中任一项所述的铝合金加工件用于制备感应板的用途。  Use of an aluminum alloy according to any one of claims 1-8 or an aluminum alloy workpiece according to any one of claims 17-19 for the preparation of an induction plate.
21、 根据权利要求 20的用途, 其中所述感应板是磁悬浮列 车轨道用感应板。  The use according to claim 20, wherein said sensing plate is an inductive plate for a magnetic levitation train track.
22、一种感应板,其特征在于所述感应板包含根据权利要求 1-8中任一项所述的铝合金或根据权利要求 17-19中任一项所述 的铝合金加工件。  An induction plate, characterized in that the induction plate comprises the aluminum alloy according to any one of claims 1-8 or the aluminum alloy workpiece according to any one of claims 17-19.
23、 根据权利要求 22所述的感应板, 其中所述感应板是由 铝合金加工件和钢板构成的复合板。  The induction plate according to claim 22, wherein the induction plate is a composite plate composed of an aluminum alloy workpiece and a steel plate.
24、根据权利要求 22或 23所述的感应板, 其中所述感应板 是磁悬浮列车轨道用感应板。  The sensor board according to claim 22 or 23, wherein the sensor board is an induction board for a magnetic levitation train track.
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CN2907065Y (en) * 2006-05-09 2007-05-30 中铁电气化局集团宝鸡器材厂 Induction plate for linear motor system
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