WO2009135345A1 - Compound hid electric arc tube - Google Patents

Compound hid electric arc tube Download PDF

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Publication number
WO2009135345A1
WO2009135345A1 PCT/CN2008/001304 CN2008001304W WO2009135345A1 WO 2009135345 A1 WO2009135345 A1 WO 2009135345A1 CN 2008001304 W CN2008001304 W CN 2008001304W WO 2009135345 A1 WO2009135345 A1 WO 2009135345A1
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WO
WIPO (PCT)
Prior art keywords
tube
arc tube
quartz glass
arc
glass
Prior art date
Application number
PCT/CN2008/001304
Other languages
French (fr)
Chinese (zh)
Inventor
陈宗烈
Original Assignee
Chen Zonglie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN2008100972277A external-priority patent/CN101373698B/en
Application filed by Chen Zonglie filed Critical Chen Zonglie
Priority to JP2011507771A priority Critical patent/JP5281151B2/en
Priority to EP08783509A priority patent/EP2284861B1/en
Priority to KR1020107027228A priority patent/KR101430289B1/en
Publication of WO2009135345A1 publication Critical patent/WO2009135345A1/en
Priority to US12/910,208 priority patent/US8110972B2/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/30Vessels; Containers
    • H01J61/35Vessels; Containers provided with coatings on the walls thereof; Selection of materials for the coatings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/36Seals between parts of vessels; Seals for leading-in conductors; Leading-in conductors
    • H01J61/366Seals for leading-in conductors

Definitions

  • quartz is used as the material for the HID arc tube. This is because quartz has a strong withstand voltage and can withstand about 200 to 300 atmospheres. On the other hand, an arc tube made of quartz material is easily sealed. However, quartz materials have obvious disadvantages at the same time. On the one hand, the quartz arc tube is formed by hot air melting at the temperature of the outer mold, and the inner cavity is blown into the high pressure air, and the inner cavity size becomes an uncontrollable free working force; When the quartz arc tube is operated at a high temperature, the color rendering property is deteriorated, the luminous efficiency and stability are lowered, and the sodium metal loss in the lamp is severe.
  • quartz arc tubes especially for low-power display lighting lamps, have been replaced by polycrystalline alumina (PCA) ceramic arc tubes, which greatly improve the uniformity and stability of light color.
  • PCA polycrystalline alumina
  • the ceramic arc tube is made by molding or grouting at room temperature, and its geometry is strictly controlled, and the other The reason is that the ceramic arc tube increases the working temperature of the pipe wall: in the case of high wall temperature, a minimum value can be observed on the correlation color temperature and the wall temperature curve, and the ceramic arc tube can fully adapt to this.
  • the lamp has excellent color rendering (Ra > 80) and improved luminous efficiency (> 901m*W-.
  • Another major advantage of the polycrystalline alumina structure is that during the lifetime, the loss of sodium metal in the lamp is greatly reduced, ensuring light The color is more stable than the metal halide lamp products of the traditional quartz arc tube.
  • the Chinese patent No. 98115658. 4 discloses a ceramic shell assembly of a high pressure discharge lamp, a shell structure PCA shell and a specially designed axially layered alumina cermet multilayer structure.
  • the final part of the multi-part end plug is directly sintered to the relevant feedthrough line without any sealing material while maintaining a certain coefficient of thermal expansion. But in fact, due to the high operating temperature of the lamp and the intense corrosion of molten metal halides and vapors, this type of sealing is also difficult to mention. For long-term reliable sealing and long life.
  • a ceramic lamp is also disclosed in US Pat. No. 6,313,582, the discharge tube of which is made of translucent ceramic, and the sealing tube portion is sealed with a sealing material based on Dy 2 0 3 -Al 2 0 3 -Si0 2 . .
  • This kind of arc tube made of ceramic has the disadvantage of PCA's own pressure difference (only about 3-5 atmospheres), the actual package electrode is difficult, and it needs to be filled into the arc in the real state during the exhaust process.
  • Gold halide pellets, mercury injection, filling with various inert gases, and relying on glass solder to achieve a hermetic sealing between the outer leads of the electrodes and the ceramic material is not easy, and often goes to the final step of making the arc tube.
  • the present invention combines the advantages of the two materials and compensates for their respective shortcomings, and proposes a novel arc tube. .
  • the object of the present invention is to provide a composite HID arc tube, the main feature of which is to partially coat a layer of translucent polycrystalline alumina in a quartz tube blown with quartz glass or Vycor quartz glass, and then The high temperature embryo is fired into a fused silica glass and a translucent polycrystalline alumina or a translucent polycrystalline alumina composite HID arc tube.
  • the composite HID arc tube retains the easy sealing of quartz glass and can withstand high pressure work.
  • the inner cover molding grout is used to coat the translucent polycrystalline alumina, so that the inner diameter of the arc tube is strictly controlled, and the inner wall of the arc tube is improved. Operating temperature and effective prevention of sodium penetration.
  • the metal halide lamp produced by the composite HID arc tube can increase the inflation pressure of the lamp in the lamp by 20%-50% than that of the conventional metal halide lamp made of ordinary polycrystalline alumina. Therefore, the light efficiency can be improved by about 25%.
  • the composite HID arc tube technology can be used to fabricate an arc tube of an ultra-high pressure mercury lamp (UHP) light source, which can effectively overcome the existing UHP quartz arc tube due to the inner wall temperature. High recrystallization and devitrification reduce the problem of early failure of compressive strength.
  • UHP ultra-high pressure mercury lamp
  • the composite HID arc tube according to the present invention comprises a discharge tube and two extraction tubes, characterized in that:
  • the take-up tube is composed of fused silica glass or yoke quartz glass, and a polycrystalline alumina layer is partially coated on both ends of the arcing chamber in the lead-out tube.
  • the arc chamber of the discharge tube is of an olive type or an ellipsoid type.
  • the outlet tube of the composite HID arc tube is sealed in two different ways.
  • the above composite HID arc tube wherein a portion of the extraction tube is coated with polycrystalline alumina, and Al 2 0 3 , Dy 2 0 3 , Si0 2 are used.
  • the mixture is sealed by a main body of glass solder, and the position of the lead-out tube is made of quartz glass, which is heated and sealed by a coal-oxygen fire.
  • the composite HID arc tube according to the present invention wherein the polycrystalline alumina layer is coated by: inserting a liner made of heat-resistant silica gel into the arc chamber of the discharge tube and the extraction tube, and then injecting The pressure of the air makes the silica gel liner a precise inner liner film, and then injects high-purity alumina powder with a small amount of binder, grain production inhibitor, into the gap between the inner liner film and the outer casing.
  • the plasticizer is fully mixed with the ceramic slurry.
  • the present invention is in contrast to the prior art, and its effects are positive and obvious.
  • the composite HID arc tube of the present invention retains both quartz glass in comparison with the disadvantage that the quartz material is not resistant to high temperatures and is prone to loss of sodium metal, and the polycrystalline alumina material is not resistant to high pressure and is difficult to package.
  • the arc tube is easy to form, has good assembly sealing, good pressure resistance, high working pressure, and absorbs the geometrical specification of the translucent polycrystalline alumina (PCA) arc chamber. High temperature, strong resistance to sodium penetration.
  • the composite HID arc tube of the invention can improve the working pressure and temperature, prevent sodium penetration and deformation deformation of the liquid silicon film formed on the electrode surface, and improve the light color stability and light effect of the HID, especially the Li lamp, and prolong The life of the lamp.
  • Figure 1 is a schematic view of a composite HID arc tube of the present invention. detailed description
  • the molybdenum lead 3, the molybdenum foil 4, and the molybdenum outer lead 5 are sequentially connected to the electrode 2, and are respectively disposed in two lead pipes at both ends of the discharge tube 1, wherein the discharge tube 1 is made of fused silica glass or The quartz glass 11 is blown to the outer casing, and is coated with a composite double-layered casing made of translucent polycrystalline alumina (PCA) 12, and two thin and long outlet tubes 14 are disposed on both sides of the arc chamber 13 of the discharge tube 1.
  • PCA translucent polycrystalline alumina
  • One end of the lead-out tube 14 facing the arc chamber 13 is also coated with a translucent polycrystalline alumina layer 12, which is the electrode 2, the molybdenum lead 3, and the molybdenum foil 4 in this order from the arc chamber 13 to the outside.
  • the molybdenum outer lead 5 the position of the lead-out tube 14 corresponding to the molybdenum lead 3 is a portion in which the polycrystalline alumina 12 is coated, and a mixture of Al 2 0 3 , Dy 2 0 3 , and Si0 2 is mainly used.
  • the glass solder 15 is sealed, and the extraction tube 14 corresponding to the molybdenum foil 4 is a single-layer glass tube position composed of quartz glass 11.
  • said discharge vessel 1 there are various metal halides, mercury or mercury alternatives, high purity argon, neon, argon or xenon gas mixture depending on the variety of filling.
  • the composite HID arc tube according to the present invention wherein the arc chamber 13 of the discharge tube is of an olive type or an ellipsoid type, the inner wall of the arc chamber 13 and the outlet tube 14 of about 3 to 8 mm near the ends of the chamber The inner wall is uniformly coated with a thickness of 0.2 to 0.5 by a thick translucent polycrystalline alumina layer 12. Further, according to the composite HID arc tube of the present invention, the electrode 2 is sealed by the first segment and the second segment segment sealing method.
  • the inner wall of the arc chamber 13 of the discharge tube and the inner wall of the extraction tube 14 of about 3 to 8 mm near the ends of the chamber are uniformly coated with the translucent polycrystalline alumina layer 12
  • the liner made of heat-resistant silica gel is inserted into the inner cavity 13 of the discharge tube and the extraction tube 14, and then a certain pressure of air is injected to make the silica gel liner a precise inner liner film.
  • a certain pressure of air is injected to make the silica gel liner a precise inner liner film.
  • a high-purity alumina powder with a small amount of a binder, a crystal production inhibitor, and a plasticizer. Mix well with the ceramic slurry.
  • the arc tube 1 is preferably blown from a high-purity fused silica glass 11 having a hydroxyl content of 10 ppm using an ellipsoidal arc tube casing 11 having a maximum diameter of ⁇ 18.
  • an average wall thickness of 1 8 ⁇ the thinnest part 1. 5mm, the inner layer of the translucent alumina (PCA) layer 12, the average thickness of 0. 2 legs, the thinnest part of the 15 cut, the thickest part 0. 25mm; 2
  • It is made of tantalum tungsten material and has good emission performance.
  • the gold halide filling of the lamp is selected from ScI3- CeI3- lnI3- Til-Nal, so the wall load Ws is about 20W/cm 2 , the beacon Weighing 150W.
  • initial light effect 1101111/1 ⁇ 2 average light efficiency 951m/w, color rendering index Ra 85, color temperature 4200K, life 20 , 000 hours, and the consistency of light color during the life of the lamp is much better than that of the quartz sodium lamp.
  • metal molybdenum is used as a lead and a foil for connection to the electrodes for illustrative purposes, but the invention is not limited to metallic molybdenum, and may be replaced with other suitable metals or alloys.
  • Ceramic metal halide lamps can be fabricated using the arc tube of the present invention, typically in a two-terminal or single-ended manner.
  • wires are connected to both ends of the arc tube at both ends of the lamp housing, and the lamp housing is generally available in a cylindrical shape or a conical shape.
  • the wires are only provided at one end of the lamp housing, and the leads at both ends of the arc tube are led out through the wires.
  • the lamp housing is generally available in a spherical or ellipsoidal shape.

Landscapes

  • Vessels And Coating Films For Discharge Lamps (AREA)
  • Manufacture Of Electron Tubes, Discharge Lamp Vessels, Lead-In Wires, And The Like (AREA)

Abstract

A compound HID electric arc tube includes a discharge tube and two lead-out tubes. The discharge tube has an envelope of blown melted quartz glass or Vycor-type quartz glass with a semitranslucent polycrystalline aluminum oxide (PCA) layer applied to the inside surface thus forming a double-layer envelope. The lead-out tubes are made of melted quartz glass or Vycor-type quartz glass and, near the two ends of the arc tube, are partially coated on their inside surfaces with a polycrystalline aluminum oxide (PCA) layer. After high temperature sintering of the electric arc tube, a two-stage method is used to seal the electrodes. A glass solder seal is used in the first section of the lead-out tube having the inner coating of PCA, and a molybdenum foil press seal is used to seal the quartz glass second section.

Description

复合式 HID电弧管 技术领域  Compound HID arc tube
本发明涉及照明设备中使用的电弧管, 特别涉及高压气体放电灯 ( HID) 中所使用的复合式 HID电弧管。 背景技术  This invention relates to arc tubes for use in lighting devices, and more particularly to composite HID arc tubes for use in high pressure gas discharge lamps (HID). Background technique
通常, 选用石英作为 HID电弧管的制作材料, 这是由于石英具有很 强的耐压特性, 可以承受大约 200- 300个大气压; 另一方面, 采用石英 材料制作的电弧管容易封接。 然而, 石英材料同时存在明显的缺点, 一 方面石英电弧管是髙温下热熔靠外模挤压内腔吹入高压风成型, 其内腔 尺寸成了无法控制的自由工差; 另一方面, 石英电弧管工作在高温状态 时, 显色性变差, 发光效率和稳定性降低, 同时灯内钠金属损失严重。  Generally, quartz is used as the material for the HID arc tube. This is because quartz has a strong withstand voltage and can withstand about 200 to 300 atmospheres. On the other hand, an arc tube made of quartz material is easily sealed. However, quartz materials have obvious disadvantages at the same time. On the one hand, the quartz arc tube is formed by hot air melting at the temperature of the outer mold, and the inner cavity is blown into the high pressure air, and the inner cavity size becomes an uncontrollable free working force; When the quartz arc tube is operated at a high temperature, the color rendering property is deteriorated, the luminous efficiency and stability are lowered, and the sodium metal loss in the lamp is severe.
近年来, 特别是小功率陈列照明用灯的石英电弧管, 开始被多晶氧 化铝 (PCA) 陶瓷电弧管所替代, 从而大大提高了光色的均匀度及稳定 性。陶瓷电弧管替代石英电弧管金属卤化物灯(MH)颜色一致性的改善, 其原因之一是由于陶瓷电弧管制作胚胎是在常温下模压或灌浆成型, 其 几何尺寸得到严格控制, 而另一原因是陶瓷电弧管提高了管壁的工作温 度: 在管壁温度很高的情况下, 对其相关色温与管壁温度曲线上可观察 到极小值, 陶瓷电弧管完全能适应于在这一相应色温极小值区域工作 (而对石英电弧管, 这个区域出现在石英玻璃能承受的合理工作温度之 上) , 尤其当灯中填充剂为钠与稀土卤化物时, 更髙的工作温度使灯具 有优良的显色性 (Ra> 80 ) , 并提高了发光效率 (> 901m*W— 。 多晶 氧化铝结构的另一个主要优点是在寿命期间, 灯内钠金属损失大大减 少, 确保光色比传统的石英电弧管的金属卤化物灯产品更稳定。  In recent years, quartz arc tubes, especially for low-power display lighting lamps, have been replaced by polycrystalline alumina (PCA) ceramic arc tubes, which greatly improve the uniformity and stability of light color. One of the reasons for the improvement of the color consistency of the ceramic arc tube instead of the quartz arc tube metal halide lamp (MH) is that the ceramic arc tube is made by molding or grouting at room temperature, and its geometry is strictly controlled, and the other The reason is that the ceramic arc tube increases the working temperature of the pipe wall: in the case of high wall temperature, a minimum value can be observed on the correlation color temperature and the wall temperature curve, and the ceramic arc tube can fully adapt to this. Working in a region of minimum color temperature (for quartz arc tubes, this region appears above the reasonable operating temperature that quartz glass can withstand), especially when the filler in the lamp is sodium and rare earth halides, the more turbulent operating temperature The lamp has excellent color rendering (Ra > 80) and improved luminous efficiency (> 901m*W-. Another major advantage of the polycrystalline alumina structure is that during the lifetime, the loss of sodium metal in the lamp is greatly reduced, ensuring light The color is more stable than the metal halide lamp products of the traditional quartz arc tube.
专利号为 98115658. 4 的中国专利公开了一种高气压放电灯的陶瓷 壳组件, 壳体结构 PCA壳和特殊设计的轴向分层的氧化铝 金属陶瓷多 层结构。 其中多零件端塞的最后零件不用任何密封材料而直接烧结到相 关的穿通线上, 同时保持一定的热膨胀系数。 但事实上, 由于灯的高工 作温度和强烈的熔融金属卤化物及蒸汽的腐蚀, 这种封接方式也很难提 供长期可靠的密封和较长的寿命。 The Chinese patent No. 98115658. 4 discloses a ceramic shell assembly of a high pressure discharge lamp, a shell structure PCA shell and a specially designed axially layered alumina cermet multilayer structure. The final part of the multi-part end plug is directly sintered to the relevant feedthrough line without any sealing material while maintaining a certain coefficient of thermal expansion. But in fact, due to the high operating temperature of the lamp and the intense corrosion of molten metal halides and vapors, this type of sealing is also difficult to mention. For long-term reliable sealing and long life.
美国专利 US 6, 313, 582Β1 也公开了一种陶瓷灯, 其放电管采用半 透明陶瓷制成,密封管部分采用基于 Dy203-Al203-Si02的密封材料进行端 口封接。这种由陶瓷制成的电弧管由于 PCA自身的耐压差(只有大约 3-5 个大气压) 的缺点, 实际封装电极很难, 在排气过程之中的真实状态下 既要往电弧内填充金卤丸、 注汞、 充入各种惰性气体、 又要靠填充玻璃 焊料把电极的外引线与陶瓷材料之间达到气密性封接并非易事, 往往走 到制作电弧管这最后一步而失败, 使前功尽弃, 严重影响了制作陶瓷电 弧管的综合合格率, 不仅使成本高居不下。 而且, 目前的技术也仅仅能 够 150w以下中小功率的电弧管, 对 250W以上至几个 KW的大功率还未 见到有普及商业化应用的范例, 因此, 也使这项先进的制灯技术还未得 到推广与普及。 A ceramic lamp is also disclosed in US Pat. No. 6,313,582, the discharge tube of which is made of translucent ceramic, and the sealing tube portion is sealed with a sealing material based on Dy 2 0 3 -Al 2 0 3 -Si0 2 . . This kind of arc tube made of ceramic has the disadvantage of PCA's own pressure difference (only about 3-5 atmospheres), the actual package electrode is difficult, and it needs to be filled into the arc in the real state during the exhaust process. Gold halide pellets, mercury injection, filling with various inert gases, and relying on glass solder to achieve a hermetic sealing between the outer leads of the electrodes and the ceramic material is not easy, and often goes to the final step of making the arc tube. Failure, the former work was abandoned, which seriously affected the comprehensive qualification rate of ceramic arc tubes, which not only made the cost high. Moreover, the current technology can only be used for medium and small power arc tubes of less than 150w. For high power of 250W or more to several KW, there is no example of popularized commercial applications. Therefore, this advanced lighting technology is also Not promoted and popularized.
上述专利文献公开的技术方案被作为背景技术在此引作参考。 发明内容  The technical solutions disclosed in the above patent documents are hereby incorporated by reference. Summary of the invention
因此, 针对石英材料者半透明多晶氧化铝的优点和不足, 以及封接 方面的问题,本发明将两种材料的优点相结合,同时弥补了各自的缺点, 提出了一种新颖的电弧管。  Therefore, in view of the advantages and disadvantages of translucent polycrystalline alumina in quartz materials, and the problems in sealing, the present invention combines the advantages of the two materials and compensates for their respective shortcomings, and proposes a novel arc tube. .
本发明的目的是提供一种复合式 HID电弧管, 其主要特点是用石英 玻璃或拜可 (Vycor ) 石英玻璃吹制成型的电弧管内部分地涂敷一层半 透明多晶氧化铝, 然后经高温胚烧成型为熔融石英玻璃与半透明多晶氧 化铝或拜可石英玻璃与半透明多晶氧化铝复合式 HID电弧管。 这种复合 式 HID电弧管保留了石英玻璃封接容易, 能够承受高气压工作, 采用内 套成型模灌浆涂敷半透明多晶氧化铝, 使电弧管内腔尺寸受到严格控 制, 提高了电弧管内壁工作温度, 并有效防止了钠渗透现象。 用这种复 合式 HID电弧管制作的金属卤化灯可以将灯内充气压力比普通多晶氧化 铝制作的陶瓷金卤灯的充气压力提高 20%-50%。 因此, 光效可提髙 25% 左右,尤其可以釆用这种复合式 HID电弧管技术去制作超高压汞灯(UHP ) 光源的电弧管, 能有效克服现有 UHP石英电弧管因内壁温度过高重结晶 和失透而降低了耐压强度早期失效的问题。 根据本发明的复合式 HID电弧管, 包括放电管、 两根引出管, 其特 征在于: The object of the present invention is to provide a composite HID arc tube, the main feature of which is to partially coat a layer of translucent polycrystalline alumina in a quartz tube blown with quartz glass or Vycor quartz glass, and then The high temperature embryo is fired into a fused silica glass and a translucent polycrystalline alumina or a translucent polycrystalline alumina composite HID arc tube. The composite HID arc tube retains the easy sealing of quartz glass and can withstand high pressure work. The inner cover molding grout is used to coat the translucent polycrystalline alumina, so that the inner diameter of the arc tube is strictly controlled, and the inner wall of the arc tube is improved. Operating temperature and effective prevention of sodium penetration. The metal halide lamp produced by the composite HID arc tube can increase the inflation pressure of the lamp in the lamp by 20%-50% than that of the conventional metal halide lamp made of ordinary polycrystalline alumina. Therefore, the light efficiency can be improved by about 25%. In particular, the composite HID arc tube technology can be used to fabricate an arc tube of an ultra-high pressure mercury lamp (UHP) light source, which can effectively overcome the existing UHP quartz arc tube due to the inner wall temperature. High recrystallization and devitrification reduce the problem of early failure of compressive strength. The composite HID arc tube according to the present invention comprises a discharge tube and two extraction tubes, characterized in that:
放电管是由熔融石英玻璃或拜可石英玻璃吹制成外壳, 并且内涂敷 半透明多晶氧化铝层构成的复合式双层壳体, 并且  The discharge tube is a composite double-layered shell formed by blowing a fused silica glass or a stellite quartz glass and coated with a translucent polycrystalline alumina layer, and
引出管由熔融石英玻璃或拜可石英玻璃构成, 其中在引出管内靠电 弧腔体的两端, 部分地内涂敷有多晶氧化铝层。  The take-up tube is composed of fused silica glass or yoke quartz glass, and a polycrystalline alumina layer is partially coated on both ends of the arcing chamber in the lead-out tube.
根据本发明的一方面, 在上述复合式 HID电弧管中, 放电管的电弧 腔体呈橄榄型或椭球型。  According to an aspect of the invention, in the above composite HID arc tube, the arc chamber of the discharge tube is of an olive type or an ellipsoid type.
根据本发明的另一方面, 在上述复合式 HID电弧管中, 电弧腔体的 内壁以及靠近腔体两端 3〜8讓引出管的内壁均匀涂敷有 0. 2〜0. 5腿厚 的半透明多晶氧化铝层。  5 厚的的厚。 The second leg of the thickness of the inner wall of the outer layer of the outer wall of the outer tube Translucent polycrystalline alumina layer.
根据本发明的又一方面, 上述复合式 HID电弧管的导出管采用两种 不同方式进行封接。  According to still another aspect of the invention, the outlet tube of the composite HID arc tube is sealed in two different ways.
根据本发明的再一方面, 在上述复合式 HID电弧管中, 其中, 在所 述引出管位置内涂敷有多晶氧化铝的部位,釆用 Al203, Dy203, Si02的混合 物为主体的玻璃焊料封接, 所述引出管由石英玻璃构成的位置, 采用煤 氧火加热后压封。 According to still another aspect of the present invention, in the above composite HID arc tube, wherein a portion of the extraction tube is coated with polycrystalline alumina, and Al 2 0 3 , Dy 2 0 3 , Si0 2 are used. The mixture is sealed by a main body of glass solder, and the position of the lead-out tube is made of quartz glass, which is heated and sealed by a coal-oxygen fire.
另外, 根据本发明的复合式 HID电弧管, 其中, 多晶氧化铝层通过 以下方式涂覆而成: 采用耐热硅胶精密制成的内胆塞入放电管电弧腔体 内及引出管内, 再注入一定压力的空气, 使硅胶内胆成之为一精密的内 衬膜, 再往内衬膜与所述外壳之间的缝隙注入高纯氧化铝粉末与少量粘 接剂、 晶粒生产抑制剂、 增塑剂充分拌匀的陶瓷粉浆, 灌浆成型之后要 经过室温固化、 脱模, 500°C〜600°C低温增压胚烧, 1000Ό中温预烧, 然后加精密氧化铝外模、 内衬模套防止石英玻璃高温变型, 经 180CTC真 空髙温锻烧 3- 4小时, 再迅速将工件移出高温炉强风冷却。  In addition, the composite HID arc tube according to the present invention, wherein the polycrystalline alumina layer is coated by: inserting a liner made of heat-resistant silica gel into the arc chamber of the discharge tube and the extraction tube, and then injecting The pressure of the air makes the silica gel liner a precise inner liner film, and then injects high-purity alumina powder with a small amount of binder, grain production inhibitor, into the gap between the inner liner film and the outer casing. The plasticizer is fully mixed with the ceramic slurry. After grouting, it should be cured at room temperature, demolded, 500 ° C ~ 600 ° C low temperature supercharged embryo, 1000 Ό medium temperature pre-burn, then add precision alumina outer mold, lining The mold sleeve prevents the high temperature deformation of the quartz glass, and is forged for 3 to 4 hours after being vacuumed at 180 CTC, and then the workpiece is quickly removed from the high temperature furnace for strong wind cooling.
本发明与已有技术相对照, 其效果是积极和明显的。 具体地说, 相 比较石英材料的不耐高温, 而且容易产生钠金属损失, 以及多晶氧化铝 材料不耐高压而造成不易封装的缺点来说, 本发明的复合 HID电弧管既 保留了石英玻璃的电弧管容易成型, 好装配封口, 耐压特性好, 工作气 压高, 又吸收了半透明多晶氧化铝(PCA)电弧腔体内几何尺寸规范, 耐 高温, 抗钠渗透性强的优点。 因此, 本发明的复合式 HID电弧管可以提 高工作气压和温度, 防止钠渗透以及电极表面液态硅膜形成的变形损 坏, 提髙了 HID, 尤其是丽灯的光色稳定性和光效, 并延长了灯的使用 寿命。 The present invention is in contrast to the prior art, and its effects are positive and obvious. Specifically, the composite HID arc tube of the present invention retains both quartz glass in comparison with the disadvantage that the quartz material is not resistant to high temperatures and is prone to loss of sodium metal, and the polycrystalline alumina material is not resistant to high pressure and is difficult to package. The arc tube is easy to form, has good assembly sealing, good pressure resistance, high working pressure, and absorbs the geometrical specification of the translucent polycrystalline alumina (PCA) arc chamber. High temperature, strong resistance to sodium penetration. Therefore, the composite HID arc tube of the invention can improve the working pressure and temperature, prevent sodium penetration and deformation deformation of the liquid silicon film formed on the electrode surface, and improve the light color stability and light effect of the HID, especially the Li lamp, and prolong The life of the lamp.
本发明的目的、 特征及优点将通过实施例并结合附图进行详细说 明。 附图说明  The objects, features, and advantages of the invention will be described in detail by the embodiments and the accompanying drawings. DRAWINGS
图 1是本发明一种复合式 HID电弧管示意图。 具体实施方式  BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic view of a composite HID arc tube of the present invention. detailed description
下面, 将参考附图对本发明进行具体描述。  Hereinafter, the present invention will be specifically described with reference to the accompanying drawings.
如图 1所示, 本发明的一种复合式 HID电弧管, 具有放电管 1、 电 极 2、 钼引线 3、 钼箔 4、 钼外引线 5, 电极 2设置在所述的放电管 1的 电弧腔体 13内, 钼引线 3、 钼箔 4、 钼外引线 5依次与电极 2连接, 并 分别设置在放电管 1两端的两根引出管 中, 其中, 放电管 1 由熔融 石英玻璃或拜可石英玻璃 11吹制外壳, 内涂敷半透明多晶氧化铝(PCA) 12构成的复合式双层壳体, 放电管 1的电弧腔体 13两边设置有两根细 而长的引出管 14,引出管 14内靠电弧腔体 13的一端也分别涂敷有半透 明多晶氧化铝层 12, 由所述的电弧腔体内 13向外依次是所述的电极 2、 钼引线 3、 钼箔 4和钼外引线 5, 与所述的钼引线 3对应的引出管 14位 置是内涂敷有多晶氧化铝 12的部位, 采用 Al203, Dy203, Si02的混合物为 主体的玻璃焊料 15封接, 与钼箔 4相对应的引出管 14是石英玻璃 11 构成的单层玻管位置, 采用煤氧火加热后压封, 所述的放电管 1根据不 同的品种充填有各种不同的金属卤化物, 汞或汞的替代物, 高纯氩气, 氩氖混合气或氙气。 As shown in FIG. 1, a composite HID arc tube of the present invention has a discharge tube 1, an electrode 2, a molybdenum lead 3, a molybdenum foil 4, a molybdenum outer lead 5, and an electrode 2 is disposed on the arc of the discharge tube 1. In the cavity 13, the molybdenum lead 3, the molybdenum foil 4, and the molybdenum outer lead 5 are sequentially connected to the electrode 2, and are respectively disposed in two lead pipes at both ends of the discharge tube 1, wherein the discharge tube 1 is made of fused silica glass or The quartz glass 11 is blown to the outer casing, and is coated with a composite double-layered casing made of translucent polycrystalline alumina (PCA) 12, and two thin and long outlet tubes 14 are disposed on both sides of the arc chamber 13 of the discharge tube 1. One end of the lead-out tube 14 facing the arc chamber 13 is also coated with a translucent polycrystalline alumina layer 12, which is the electrode 2, the molybdenum lead 3, and the molybdenum foil 4 in this order from the arc chamber 13 to the outside. And the molybdenum outer lead 5, the position of the lead-out tube 14 corresponding to the molybdenum lead 3 is a portion in which the polycrystalline alumina 12 is coated, and a mixture of Al 2 0 3 , Dy 2 0 3 , and Si0 2 is mainly used. The glass solder 15 is sealed, and the extraction tube 14 corresponding to the molybdenum foil 4 is a single-layer glass tube position composed of quartz glass 11. After the fire coal and oxygen using heat and pressure seal, said discharge vessel 1 there are various metal halides, mercury or mercury alternatives, high purity argon, neon, argon or xenon gas mixture depending on the variety of filling.
进一步的, 根据本发明的复合式 HID电弧管, 其中, 放电管的电弧 腔体 13呈橄榄型或椭球型,电弧腔体 13的内壁以及靠近腔体两端约 3〜 8mm引出管 14的内壁均匀涂敷有 0. 2〜 0. 5讓厚的半透明多晶氧化铝层 12。 进一步的, 根据本发明的复合式 HID电弧管, 其中釆用第一段和第 二段分段封接的方法对电极 2进行封接。 Further, the composite HID arc tube according to the present invention, wherein the arc chamber 13 of the discharge tube is of an olive type or an ellipsoid type, the inner wall of the arc chamber 13 and the outlet tube 14 of about 3 to 8 mm near the ends of the chamber The inner wall is uniformly coated with a thickness of 0.2 to 0.5 by a thick translucent polycrystalline alumina layer 12. Further, according to the composite HID arc tube of the present invention, the electrode 2 is sealed by the first segment and the second segment segment sealing method.
进一步的, 根据本发明的复合式 HID电弧管, 其中, 放电管的电弧 腔体 13的内壁及靠近腔体两端约 3〜8mm引出管 14的内壁均匀涂敷半 透明多晶氧化铝层 12,涂敷时釆用耐热硅胶精密制成的内胆塞入放电管 内腔 13及引出管 14内, 再注入一定压力的空气, 使所述的硅胶内胆成 之为一精密的内衬膜, 再往内衬膜与所述的放电管 1的熔融石英玻璃或 拜可石英玻璃外壳 11 之间的缝隙注入高纯氧化铝粉末与少量粘接剂、 晶粒生产抑制剂、 增塑剂充分拌匀的陶瓷粉浆。  Further, according to the composite HID arc tube of the present invention, the inner wall of the arc chamber 13 of the discharge tube and the inner wall of the extraction tube 14 of about 3 to 8 mm near the ends of the chamber are uniformly coated with the translucent polycrystalline alumina layer 12 When coating, the liner made of heat-resistant silica gel is inserted into the inner cavity 13 of the discharge tube and the extraction tube 14, and then a certain pressure of air is injected to make the silica gel liner a precise inner liner film. And further filling the gap between the inner liner film and the fused silica glass or the quartz glass outer casing 11 of the discharge tube 1 into a high-purity alumina powder with a small amount of a binder, a crystal production inhibitor, and a plasticizer. Mix well with the ceramic slurry.
进一步的, 根据本发明的复合式 HID 电弧管, 其中, 电弧腔体 13 的内壁靠近腔体两端约 3〜8mm引出管 14的内壁均匀半透明多晶氧化铝 层 12, 灌浆成型之后要经过室温固化、 脱模, 500Ό〜600Ό低温增压胚 烧, 100CTC中温预烧, 然后加精密氧化铝外模、 内衬模套防止石英玻璃 11高温变型, 经 1800°C真空高温锻烧 3-4小时, 再迅速将工件移出高 温炉强风冷却, 以防止石英外壳 11失透。  Further, the composite HID arc tube according to the present invention, wherein the inner wall of the arc chamber 13 is adjacent to the ends of the chamber by about 3 to 8 mm, and the inner wall of the outlet tube 14 is uniformly translucent polycrystalline alumina layer 12, which is passed after the grouting Room temperature curing, demoulding, 500Ό~600Ό low temperature supercharged embryo burning, 100CTC medium temperature pre-burning, then adding precision alumina outer mold, inner liner mold sleeve to prevent high temperature deformation of quartz glass 11, 1800 °C vacuum high temperature calcination 3-4 After hours, the workpiece is quickly removed from the high temperature furnace and cooled by strong wind to prevent the quartz casing 11 from being devitrified.
进一步的, 根据本发明的复合式 HID电弧管, 其中, 电极 2采用第 一段和第二段分段封接的方法, 其中, 在靠近电弧管电弧腔体 13 两端 距离约 3〜8讓引出管 14的一段为第一段,由此段再往外延伸 10〜20匪 的引出管 称之为第二段, 第一段引出管 14内壁与电弧腔体 13内壁 一样涂敷有半透明多晶氧化铝层 12, 封接时采用以 Al203, Dy20:i, Si02的 混合物为主体的玻璃焊料 15 封接, 第二段是石英玻璃或改进型石英玻 璃 11, 如拜可石英玻璃, 钼阻玻璃, 采用钼箔 4非匹配性封接, 或直接 用钼杆匹配性封接, 以增加灯工作在超高气压, 如 100〜200atm时的气 密性。 Further, according to the composite HID arc tube of the present invention, the electrode 2 is sealed by the first stage and the second stage, wherein the distance between the ends of the arc chamber 13 adjacent to the arc tube is about 3 to 8 The section of the outlet pipe 14 is the first section, and the outlet pipe extending from the section to the outside by 10 to 20 inches is referred to as the second section. The inner wall of the first section of the outlet pipe 14 is coated with the translucent layer as the inner wall of the arc chamber 13 The crystalline aluminum oxide layer 12 is sealed by a glass solder 15 mainly composed of a mixture of Al 2 0 3 , Dy 2 0 : i , and Si0 2 , and the second stage is quartz glass or modified quartz glass 11 . Quartz glass, molybdenum-resistant glass, non-matching sealing with molybdenum foil 4, or direct sealing with molybdenum rods to increase the airtightness of the lamp operating at ultra-high pressure, such as 100~200atm.
在图 1所示的实例中, 电弧管 1优选采用椭球型电弧管外壳 11 由 羟基含量 10ppm 的高纯熔融石英玻璃 11 吹制而成, 最大直径为 Φ 18. 5醒, 平均壁厚 1. 8mra, 最薄的地方 1. 5mm, 内涂敷并烧结而成的半 透明氧化铝 (PCA) 层 12, 平均厚 0. 2腿, 最薄处 15删, 最厚处 0. 25mm; 电极 2采用钍钨材料制作, 有良好的发射性能, 灯的金卤充填 物选取 ScI3- CeI3- lnI3- Til- Nal, 因此管壁负载 Ws约为 20W/cm2, 灯标 称功率 150W。 In the example shown in Fig. 1, the arc tube 1 is preferably blown from a high-purity fused silica glass 11 having a hydroxyl content of 10 ppm using an ellipsoidal arc tube casing 11 having a maximum diameter of Φ 18. 5 awake, an average wall thickness of 1 8毫米, the thinnest part 1. 5mm, the inner layer of the translucent alumina (PCA) layer 12, the average thickness of 0. 2 legs, the thinnest part of the 15 cut, the thickest part 0. 25mm; 2 It is made of tantalum tungsten material and has good emission performance. The gold halide filling of the lamp is selected from ScI3- CeI3- lnI3- Til-Nal, so the wall load Ws is about 20W/cm 2 , the beacon Weighing 150W.
在灯管匹配高频方波电流、 电压及衡功率输出的电子镇流器情况下 测试: 初始光效 1101111/½, 平均的光效 951m/w,显色指数 Ra 85,色温 4200K, 寿命 20, 000小时, 而且灯寿命期间内的光色的一致性比石英钪 钠灯有很大的改善。  Tested in the case of an electronic ballast with a lamp matching high frequency square wave current, voltage and balanced power output: initial light effect 1101111/1⁄2, average light efficiency 951m/w, color rendering index Ra 85, color temperature 4200K, life 20 , 000 hours, and the consistency of light color during the life of the lamp is much better than that of the quartz sodium lamp.
根据本发明的实施例, 为了说明的目的, 釆取了金属钼作为引线以 及箔片来与电极连接, 但是本发明并不限于金属钼, 也可以采用其他适 合的金属或者合金来替换。  In accordance with an embodiment of the present invention, metal molybdenum is used as a lead and a foil for connection to the electrodes for illustrative purposes, but the invention is not limited to metallic molybdenum, and may be replaced with other suitable metals or alloys.
可以利用本发明的电弧管来制作陶瓷金属卤化物灯, 一般采用双端 或者单端方式来制作。 双端方式是在灯外壳的两端设置有导线连接到电 弧管的两端, 灯外壳一般可选用圆柱型或者圆锥型等。 而单端方式是只 在灯外壳的一端设置导线, 电弧管两端的引线都通过这个导线引出, 灯 外壳一般可选用球型或椭球型等。  Ceramic metal halide lamps can be fabricated using the arc tube of the present invention, typically in a two-terminal or single-ended manner. In the double-end mode, wires are connected to both ends of the arc tube at both ends of the lamp housing, and the lamp housing is generally available in a cylindrical shape or a conical shape. In the single-ended mode, the wires are only provided at one end of the lamp housing, and the leads at both ends of the arc tube are led out through the wires. The lamp housing is generally available in a spherical or ellipsoidal shape.
以上引用的所有专利均以全文复制的方式引入本文以供参考。 虽然 为了有助于说明本发明的各个方面, 上文详细描述了本发明的具体实 例, 但是应当理解, 这并不旨在将本发明限制于实例中所给出的具体内 容。 相反, 其目的在于涵盖附带的权利要求书中限定的本发明的精神和 范围内的所有修改形式、 实施例和替代实施例。  All patents cited above are hereby incorporated by reference in their entirety herein in their entirety. While the invention has been described in detail with reference to the preferred embodiments of the present invention, it is understood that the invention is not intended to limit the invention. Rather, the invention is to cover all modifications, embodiments and alternative embodiments within the spirit and scope of the invention as defined in the appended claims.

Claims

权利要求 Rights request
1. 一种复合式 HID电弧管, 包括放电管 (1 ) 、 两根引出管 (14 ) , 其特征在于: A composite HID arc tube comprising a discharge tube (1) and two extraction tubes (14), characterized in that:
所述放电管是由熔融石英玻璃或拜可石英玻璃吹制成外壳 (11 ) , 并且内涂敷半透明多晶氧化铝层 (12 ) 构成的复合式双层壳体, 并且 所述引出管由熔融石英玻璃或拜可石英玻璃构成, 其中在所述引出 管内靠电弧腔体的两端, 部分地内涂敷有多晶氧化铝层。  The discharge tube is a composite double-layer casing formed by blowing a fused silica glass or a stellite glass into a casing (11) and coated with a translucent polycrystalline alumina layer (12), and the extraction tube It is composed of fused silica glass or baiqu quartz glass, and a polycrystalline alumina layer is partially coated in the outlet tube at both ends of the arc chamber.
2. 如权利要求 1所述的复合式 HID电弧管, 其特征在于: 所述电 弧腔体的内壁以及靠近腔体两端 3〜8mm 引出管的内壁均匀涂敷有 0. 2〜0. 5mm厚的半透明多晶氧化铝层。 0. 5mm. 5mm. 5mm. 5mm. 5mm. A thick translucent polycrystalline alumina layer.
3. 如权利要求 1或 所述的复合式 HID电弧管, 其特征在于: 所 述放电管的电弧腔体呈橄榄型或椭球型。 3. The composite HID arc tube according to claim 1 or 2, wherein the arc chamber of the discharge tube is of an olive type or an ellipsoid type.
4. 如权利要求 1或 2所述的复合式 HID电弧管, 其特征在于: 所 述导出管采用两种不同方式进行封接。 4. The composite HID arc tube of claim 1 or 2, wherein: the outlet tube is sealed in two different ways.
5. 如权利要求 3所述的复合式 HID 电弧管, 其特征在于: 所述导 出管釆用两种不同方式进行封接。 5. The composite HID arc tube of claim 3 wherein: said outlet tube is sealed in two different ways.
PCT/CN2008/001304 2007-08-21 2008-07-11 Compound hid electric arc tube WO2009135345A1 (en)

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EP2284861A1 (en) 2011-02-16
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JP5281151B2 (en) 2013-09-04
EP2284861B1 (en) 2012-10-31
KR20110021846A (en) 2011-03-04

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