WO2009121093A1 - Traitement des eaux usées - Google Patents

Traitement des eaux usées Download PDF

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Publication number
WO2009121093A1
WO2009121093A1 PCT/AU2009/000329 AU2009000329W WO2009121093A1 WO 2009121093 A1 WO2009121093 A1 WO 2009121093A1 AU 2009000329 W AU2009000329 W AU 2009000329W WO 2009121093 A1 WO2009121093 A1 WO 2009121093A1
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WO
WIPO (PCT)
Prior art keywords
filter
fluid
bed
waste water
inlet
Prior art date
Application number
PCT/AU2009/000329
Other languages
English (en)
Inventor
Konstantinos Athanasiadis
Original Assignee
Ghd Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AU2008901619A external-priority patent/AU2008901619A0/en
Application filed by Ghd Pty Ltd filed Critical Ghd Pty Ltd
Publication of WO2009121093A1 publication Critical patent/WO2009121093A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • B01J20/0229—Compounds of Fe
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/14—Base exchange silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00—Multistage treatment of water, waste water or sewage
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
    • C02F2001/425—Treatment of water, waste water, or sewage by ion-exchange using cation exchangers
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/103—Arsenic compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/105—Phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/16—Nitrogen compounds, e.g. ammonia
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00—General aspects of water treatment
    • C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/16—Regeneration of sorbents, filters

Definitions

  • the present invention relates to a method and apparatus for treating oil processing waste water, and in particular to a method and apparatus for treating oil processing waste water to remove heavy metal contaminants.
  • Crude oils are typically graded depending on the level of contaminants. Low grade oils containing significant heavy metal contaminants, such as mercury and arsenic, tend to be undesirable to process, primarily as removal of the contaminants results in highly polluted waste water, which poses a significant environmental threat. Consequently environmental protection laws require that the waste water be treated prior to disposal.
  • WOO 105717 describes disposing of mercury-containing wastewater containing mercury- complexing materials by using a strong oxidizing agent in a reaction chamber to produce pretreated wastewater, removing an effluent stream of pretreated wastewater from the reaction chamber and passing the effluent stream of pretreated wastewater through a column packed with a porous resin having immobilized mercury-selective chelating groups bound thereto.
  • a particularly preferred adsorbent material is a crosslinked styrene-divinylbenzene copolymer having immobilized dithiocarbamate groups bound thereto.
  • the present invention provides apparatus for treating oil processing waste water, the apparatus including: a) a first filter for removing a first heavy metal contaminant; and, b) a second filter for removing a second heavy metal contaminant.
  • the first filter is an ion exchange filter.
  • the first filter is for removing positively charged ions.
  • the first filter includes a zeolite filter material.
  • the filter material is clinoptilolite.
  • the filter material includes particles having a size of approximately 1 to 5 mm.
  • the filter material is chemically treated before use.
  • the chemical treatment includes exposing the filter material to a salt solution.
  • the salt solution is a sodium chloride solution.
  • the first filter is for removing a mercury based contaminant.
  • the first filter is for removing at least one of the following cations: a) ammonia nitrogen JVH 4 + - N ; b) copper; c) zinc; d) lead; e) Nickel; f) Cadmium; g) Mercury; h) Chromium; i) Platinum; j) Vanadium; k) Palladium; and,
  • the first filter is an upflow filter.
  • the first filter includes: a) a first filter housing defining a first filter cavity; b) a first filter inlet for receiving the fluid to be filtered; c) a first filter outlet for supplying filtered fluid; and, d) a first filter bed positioned in the first filter cavity, the first filter bed containing a filter material for filtering fluid flowing from the inlet to the outlet.
  • the inlet is positioned below the first filter bed, the first filter bed being is positioned below the first filter outlet so that fluid flows through the first filter bed in an upward direction.
  • the second filter is a sorption filter.
  • the second filter is for removing negatively charged ions.
  • the second filter is for removing residual positively charged ions.
  • the second filter is for removing at least one of: a) Nitrates; and, b) Phosphates.
  • the second filter includes a laterite filter material.
  • the laterite filter material is treated to increase the filter material surface area, before use.
  • the second heavy metal contaminant is an arsenic based contaminant.
  • the second filter is a downflow filter.
  • the second filter includes: a) a second filter housing defining a second filter cavity; b) a second filter inlet for receiving the fluid to be filtered; c) a second filter outlet for supplying filtered fluid; and, d) a second filter bed positioned in the second filter cavity, the second filter bed containing a filter material for filtering fluid flowing from the inlet to the outlet.
  • the filter bed is positioned below the second filter inlet and above the second filter outlet so that fluid flows through the second filter bed in a downward direction.
  • the first filter outlet is coupled to the second filter inlet.
  • the apparatus includes a pre-f ⁇ lter for filtering fluid prior to the fluid being supplied to the first or second filter.
  • the pre-filter is a sand filter.
  • the apparatus includes a pump for pumping fluid through at least one of: a) the pre-filter; b) the first filter; and, c) the second filter.
  • the apparatus is used for polishing oil processing waste water.
  • the present invention provides a method of treating oil processing waste water, the method including: a) using a first filter to remove a first heavy metal contaminant; and, b) using a second filter to remove a second heavy metal contaminant.
  • the second broad form of the invention may be performed using apparatus according to the first broad form of the invention.
  • Figure 1 shows a schematic diagram of an example of a system for treating oil processing waste water
  • Figure 2 shows a flow diagram of a process for treating oil processing waste water
  • Figure 3 shows a flow diagram of a second example of a system for treating oil processing waste water.
  • waste water An example of apparatus for treating oil processing waste water (hereinafter referred to as "waste water”) will now be described with reference to Figure 1.
  • the apparatus includes a first filter 100 coupled to a second filter 110 via a connecting pipe 120.
  • the first filter receives waste water via an inlet pipe 130, supplying filtered waste water to the second filter 110, via the connecting pipe 120. Filtered water is then supplied via an outlet pipe 140.
  • the apparatus may also include an optional pre-filter 150 for pre-filtering the waste water received via a pre-filter inlet pipe 160. In one example, the waste water may be received via a pump 170.
  • the waste water is typically pre-treated using existing techniques for removing solids and other contaminants. Accordingly, in this example, removing the heavy metal contaminants using the process described below is a secondary treatment process generally referred to as polishing.
  • the pre-treatment of water could be performed in any suitable manner and will not therefore be described in further detail.
  • the waste water is optionally pre-f ⁇ ltered, using the pre-filter 150, before being supplied to the first filter 100.
  • the pre-filter can be used for reducing turbidity and/or removing other contaminants such as suspended solids (SS) or the like, to avoid clogging problems downstream.
  • Any suitable pre-filter may be used, and in one example the pre-filter is a pressurised sand filter, although alternatively membrane or cloth filters can be used.
  • the first filter 100 filters the waste water to remove first heavy metal contaminants such as mercury based contaminants, or the like.
  • the first filter 100 is typically an ion exchange filter for removing positively charged ions and in one example is formed from a zeolite, such as clinoptilolite or another similar materials.
  • a filter not only removes mercury based contaminants, but can also remove other positive ionic contaminants such as vanadium, zinc, copper, lead, nickel, cadmium, chromium, platinum, palladium, rhodium, and nutrients such as ammonia nitrogen (JVH/ -N),
  • the second filter 110 filters the waste water to remove a second heavy metal contaminant such as arsenic based contaminants, including arsenate, arsenite, or the like.
  • the second filter is typically a sorption filter for removing at least some negatively charged ions and in one example, is formed from a laterite, or other similar materials.
  • the second filter can also remove other contaminants such as nutrients includes nitrates, phosphates, or the like, other negatively charged ions, or other positively charged ions that have not been removed by the first filter (herein referred to as residual positively charged ions) thereby enhancing the overall performance of the system.
  • nutrients includes nitrates, phosphates, or the like, other negatively charged ions, or other positively charged ions that have not been removed by the first filter (herein referred to as residual positively charged ions) thereby enhancing the overall performance of the system.
  • the ion exchange filter typically it is preferred to remove the positively charged ions using the ion exchange filter first, allowing the majority of these contaminants to be removed, before the second filter removes any negative ions and remaining positive ions. This prevents the sorption filter capacity being exceeded by having the sorption filter attempt to remove all the positively charged ions, which can be adequately removed by the ion exchange filter.
  • zeolites are hydrated aluminosilicate minerals that have a micro-porous structure, represented by the chemical formula:
  • zeolites are complex, crystalline inorganic polymers based on an infinitely extending three dimensional, four connected framework of AIO 4 and S1O 4 tetrahedra linked to each other by the sharing of oxygen ions.
  • AIO 4 tetrahedra bears a net negative charge
  • zeolites typically naturally include positive exchangeable ions, such as sodium TVa + , K + , Ca 2+ , and Mg 2+ ions, embedded within the micro-porous structure.
  • zeolites such as clinoptilolite are naturally occurring and can be mined using open pit techniques in many regions. Consequently, zeolites, and particularly clinoptilolite, are cheap and readily available, thereby making them practical for use as a filter material for the first filter.
  • Zeolites are typically mined as large rocks, which are therefore unsuitable for use in a filter bed. Accordingly, the zeolite material is typically crushed or ground into smaller fragments of desired particle diameter such as between ⁇ -5mm. This increases the available surface area, thereby enhancing the filtering process, and reduces gaps between adjacent fragments, thereby ensuring that all the filter bed contains material.
  • the actual size used can depend on a number of parameters, such as the flow rate of the oil processing waste water, the relative expected level of contaminants, or the like. Thus, for example, a high concentration of contaminants would generally require a greater surface area to ensure adequate filtering, and accordingly a smaller particle size would be preferred. However, with low contaminant concentration but a high flow rate, less filtering is required, whilst a higher throughput is preferred, thereby making a larger particle size, say 3 -5mm, more appropriate. However, it will be appreciated that the examples quoted are for the purpose of illustration only and that in practice any suitable particle size may be used.
  • the grinding process generates dust that can clog pores of the clinoptilolite, resulting to lower sorption capacity due to the reduced available ion exchange surface. Whilst washing with water can reduce this clogging, typically washing with water alone is unable to remove all the dust from the clogged pores.
  • the effectiveness of the crushed zeolites is enhanced using chemical conditioning, which involves exposing the zeolite to a high concentration of salt water solution. This can be performed by washing the grinded zeolite in a sodium chloride solution.
  • the high concentration of Na + ions causes any other ions present, such as more positively charged Calcium Ca 2+ ions to be displaced, thereby maximising the effectiveness of the ion exchange process.
  • Arsenic contaminants such as arsenate and arsenite, typically form negative ions in solution, such as As 3' , and consequently are not suited for removal using ion exchange in the zeolite filter. Accordingly, the second filter typically uses a laterite based sorption filter.
  • Laterites are formed by leaching of and enrichment with aluminium and iron oxides of silica based rocks. Laterites typically include minerals such as kaolinite, goethite, hematite and gibbsite, and therefore contain in various ratios. Laterites can include soft porous material, as well as hard, dense rocks, depending on the nature of the parent rock and the weathering that has occurred.
  • Porous laterites have a high surface area, and in use the arsenic ions bind to the surface of the laterite, becoming embedded therein.
  • the filtering ability is therefore directly related to the surface area of the laterite. Accordingly, a porous laterite is preferred, and the absorption capabilities can be enhanced by treating the laterite with 0.01 M HNO 3 , which increases the specific surface area.
  • this is not essential, and it will be appreciated that laterite can be used without pre-treatment, thereby helping to minimise costs for the filtering apparatus.
  • the need for the pre-f ⁇ lter will depend on the typical purity of the waste water, and accordingly in some instances this may not be required, although reducing clogging downstream can significantly extend the life and improve the efficiency of the downstream filter processes, thereby making the use of the pre-filter advantageous. Additionally, as the pre-filter can generally be cleaned by backwashing, there is little expense involved in the use of the pre-filter. As such filter materials are cheap and readily available, this allows for low cost treatment of oil processing waste water, which in turn allows for the refining of previously marginally economic crude oil.
  • the first filter is an upflow filter
  • the second filter is a downflow filter. This allows the filters to be used in sequence, as will now be described with reference to Figure 3.
  • the first filter 100 includes a first filter housing 300 defining a first filter cavity 301 having a first filter bed 302 provided therein.
  • the first filter bed 302 typically is formed from a mesh screen having filter material, such as the clinoptilolite, provided thereon, as will be appreciated by persons skilled in the art.
  • the first filter housing 300 includes a first filter inlet 303 coupled to the inlet pipe 130, and a first filter outlet 304 coupled to the connecting pipe 120.
  • the first filter inlet 303 is positioned in the first filter housing 300 below the first filter bed 302, which is in turn positioned below the first filter outlet 304.
  • the second filter 110 includes a second filter housing 310 defining a second filter cavity 311 having a second filter bed 312 provided therein.
  • the second filter bed 312 typically is formed from a mesh screen having filter material, such as the laterite, provided thereon, as will be appreciated by persons skilled in the art.
  • the second filter housing 310 includes a second filter inlet 313 coupled to the coupled to the connecting pipe 120, and a second filter outlet 314 coupled to the outlet pipe 140.
  • the second filter inlet 313 is positioned in the housing above the second filter bed 312, which is in turn positioned above the second filter outlet 314.
  • the second filter inlet 313 is also coupled to a second filter pipe 315 that includes a number of apertures or nozzles 316 therein.
  • waste water when waste water is pumped into the first filter cavity 301 via the inlet pipe 130, waste water will fill the first filter cavity 301. As waste water passes through the first filter bed 302, the water undergoes an ion exchange filter process, thereby removing any positive charged heavy metal based contaminants such as mercury.
  • the water level continues to rise until it reaches the level of the outlet 304, allowing filtered waste water to exit the first filter 100, through the connecting pipe 120, thereby entering the second filter pipe 315.
  • the rate of inflow and the size of the apertures is selected to allow the second filter pipe 315 to contain a sufficient level of waste water to allow waste water to flow through all of the apertures 316, thereby allowing the waste water to be dispersed evenly over the second filter bed 312.
  • the waste water is then filtered to remove the arsenic based contaminants as it drains through the second filter bed 312, before being supplied via the second filter outlet 314 to the outlet pipe 140.
  • This arrangement allows a pressurised sand filter to be used to drive the entire process.
  • the pressurised output from the pre-filter 160 allows the first filter cavity 301 to be filled with waste water, whilst natural drainage from the first filter 100 allows the second filter 110 to operate.
  • This arrangement also has the further benefit that filters such as clinoptilolites tend to work best in an upflow mode, whilst laterite filters tend to work best under conditions of down flow, which is satisfied by the above described arrangement, whilst still only requiring the use of a pressurised sand filter to drive the system.
  • a pressurised filter is not essential in this configuration and alternatively the system can be driven using other suitable pumps.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Abstract

L'invention concerne un appareil de traitement des eaux usées issues du traitement des hydrocarbures, l'appareil comportant un premier filtre destiné à éliminer un premier contaminant de type métal lourd et un second filtre destiné à éliminer un second contaminant de type métal lourd.
PCT/AU2009/000329 2008-04-04 2009-03-20 Traitement des eaux usées WO2009121093A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AU2008901619A AU2008901619A0 (en) 2008-04-04 Waste water treatment
AU2008901619 2008-04-04

Publications (1)

Publication Number Publication Date
WO2009121093A1 true WO2009121093A1 (fr) 2009-10-08

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010088718A1 (fr) * 2009-02-05 2010-08-12 Ghd Pty Ltd Traitement de l'eau
CN102642991A (zh) * 2012-04-28 2012-08-22 南京大学 一种电镀废水高效组合深度处理方法
CN103241803A (zh) * 2013-05-14 2013-08-14 广东新大禹环境工程有限公司 电镀废水分离工艺
US9371408B2 (en) 2011-07-12 2016-06-21 General Electric Company Polymer and method for using the same
CN111807635A (zh) * 2020-07-23 2020-10-23 河北林江环境科技发展有限公司 污水、饮用水重金属去除工艺
WO2020245801A1 (fr) * 2019-06-06 2020-12-10 M.A.R.S. Bio-Med Processes Inc. Systèmes et procédés de traitement de l'eau

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5227071A (en) * 1992-01-17 1993-07-13 Madison Chemical Company, Inc. Method and apparatus for processing oily wastewater
US5622627A (en) * 1993-09-03 1997-04-22 Advanced Waste Reduction, Inc. Parts washer system
US5942107A (en) * 1994-11-01 1999-08-24 Busch, Jr.; Joseph B. Apparatus for the treatment of hazardous waste water
US20050207955A1 (en) * 2004-03-17 2005-09-22 Bo Wang Mercury adsorbent composition, process of making same and method of separating mercury from fluids

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5227071A (en) * 1992-01-17 1993-07-13 Madison Chemical Company, Inc. Method and apparatus for processing oily wastewater
US5622627A (en) * 1993-09-03 1997-04-22 Advanced Waste Reduction, Inc. Parts washer system
US5942107A (en) * 1994-11-01 1999-08-24 Busch, Jr.; Joseph B. Apparatus for the treatment of hazardous waste water
US20050207955A1 (en) * 2004-03-17 2005-09-22 Bo Wang Mercury adsorbent composition, process of making same and method of separating mercury from fluids

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010088718A1 (fr) * 2009-02-05 2010-08-12 Ghd Pty Ltd Traitement de l'eau
US8758607B2 (en) 2009-02-05 2014-06-24 Ghd Pty Ltd. Water treatment
US9371408B2 (en) 2011-07-12 2016-06-21 General Electric Company Polymer and method for using the same
CN102642991A (zh) * 2012-04-28 2012-08-22 南京大学 一种电镀废水高效组合深度处理方法
CN102642991B (zh) * 2012-04-28 2013-12-04 南京大学 一种电镀废水高效组合深度处理方法
CN103241803A (zh) * 2013-05-14 2013-08-14 广东新大禹环境工程有限公司 电镀废水分离工艺
WO2020245801A1 (fr) * 2019-06-06 2020-12-10 M.A.R.S. Bio-Med Processes Inc. Systèmes et procédés de traitement de l'eau
CN111807635A (zh) * 2020-07-23 2020-10-23 河北林江环境科技发展有限公司 污水、饮用水重金属去除工艺

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