WO2009082546A3 - Films de polyéthylène et procédé pour leur production - Google Patents

Films de polyéthylène et procédé pour leur production Download PDF

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Publication number
WO2009082546A3
WO2009082546A3 PCT/US2008/082049 US2008082049W WO2009082546A3 WO 2009082546 A3 WO2009082546 A3 WO 2009082546A3 US 2008082049 W US2008082049 W US 2008082049W WO 2009082546 A3 WO2009082546 A3 WO 2009082546A3
Authority
WO
WIPO (PCT)
Prior art keywords
production
polyethylene films
micron
elmendorf tear
mpa
Prior art date
Application number
PCT/US2008/082049
Other languages
English (en)
Other versions
WO2009082546A2 (fr
Inventor
David M. Fiscus
Danny Van Hoyweghen
X. Christina Lu
Alan A. Galuska
Original Assignee
Exxonmobil Chemical Patents Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/959,078 external-priority patent/US20090156764A1/en
Priority claimed from US12/130,135 external-priority patent/US20090297810A1/en
Application filed by Exxonmobil Chemical Patents Inc. filed Critical Exxonmobil Chemical Patents Inc.
Publication of WO2009082546A2 publication Critical patent/WO2009082546A2/fr
Publication of WO2009082546A3 publication Critical patent/WO2009082546A3/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • B32B2250/242All polymers belonging to those covered by group B32B27/32
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51Elastic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558Impact strength, toughness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/582Tearability
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/72Density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/732Dimensional properties
    • B32B2307/734Dimensional stability
    • B32B2307/736Shrinkable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/02Open containers
    • B32B2439/06Bags, sacks, sachets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/70Food packaging
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2535/00Medical equipment, e.g. bandage, prostheses, catheter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2553/00Packaging equipment or accessories not otherwise provided for
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2555/00Personal care
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2555/00Personal care
    • B32B2555/02Diapers or napkins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

La présente invention concerne un film de polyéthylène ayant un module sécant à 1 % MD de 220 MPa ou plus et une résistance à la déchirure Elmendorf MD de Y g/micron, où Y ³ -0,4515 (Dart Drop en g/micron) + 33,3 g/micron, où la résistance à la déchirure Elmendorf MD est d'au moins 11,8 g/micron.
PCT/US2008/082049 2007-12-18 2008-10-31 Films de polyéthylène et procédé pour leur production WO2009082546A2 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US11/959,078 2007-12-18
US11/959,078 US20090156764A1 (en) 2007-12-18 2007-12-18 Ethylene-Based Polymers and Articles Made Therefrom
US12/130,135 2008-05-30
US12/130,135 US20090297810A1 (en) 2008-05-30 2008-05-30 Polyethylene Films and Process for Production Thereof

Publications (2)

Publication Number Publication Date
WO2009082546A2 WO2009082546A2 (fr) 2009-07-02
WO2009082546A3 true WO2009082546A3 (fr) 2013-07-04

Family

ID=40801738

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2008/082049 WO2009082546A2 (fr) 2007-12-18 2008-10-31 Films de polyéthylène et procédé pour leur production

Country Status (1)

Country Link
WO (1) WO2009082546A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107073905A (zh) * 2014-08-12 2017-08-18 陶氏环球技术有限责任公司 基于聚乙烯的复合膜和由其制造的物件

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009139851A1 (fr) * 2008-05-15 2009-11-19 Univation Technologies, Llc Compositions de polyoléfine et procédés de traitement de celles-ci à l'aide de sels métalliques
EP2915826B1 (fr) * 2010-10-21 2024-02-28 Univation Technologies, LLC Polyéthylène et son procédé de fabrication
CN104822716B (zh) 2012-12-21 2017-11-14 埃克森美孚化学专利公司 具有改进的加工性的支化聚乙烯及由其制成的高抗撕裂性膜
RU2015143678A (ru) * 2013-03-15 2017-04-21 Юнивэйшн Текнолоджис, Ллк Полиэтиленовые пленки, катализируемые гафноценом, имеющие быстрое развитие клейкости
TWI600694B (zh) * 2014-11-26 2017-10-01 柏列利斯股份公司 膜層
EP3433305B1 (fr) 2016-03-25 2021-07-21 ExxonMobil Chemical Patents Inc. Films de polyéthylène
WO2019027524A1 (fr) * 2017-08-02 2019-02-07 Exxonmobil Chemical Patents Inc. Films multicouches et procédés de fabrication
US20230097375A1 (en) * 2020-03-12 2023-03-30 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved bending stiffness and high md tear resistance

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5998017A (en) * 1996-03-12 1999-12-07 Tenneco Packaging Stretch wrap films
US6093480A (en) * 1997-05-21 2000-07-25 Tenneco Packaging Stretch wrap films
US20010016632A1 (en) * 1999-07-09 2001-08-23 Nova Chemicals (International) S.A. Heavy duty packaging film
WO2001098409A1 (fr) * 2000-06-22 2001-12-27 Exxonmobil Chemical Patents Inc. Mélange de polyéthylène très basse densité et de polyéthylène haute densité
US20040053022A1 (en) * 2002-09-05 2004-03-18 Ohlsson Stefan Bertil Shrink film
US20050058847A1 (en) * 2001-07-19 2005-03-17 Szul John F. High tear films from hafnocene catalyzed polyethylenes
US20050159300A1 (en) * 2004-01-21 2005-07-21 Jensen Michael D. Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
US6956088B2 (en) * 2001-07-19 2005-10-18 Univation Technologies, Llc Polyethylene films with improved physical properties
WO2007130277A1 (fr) * 2006-05-05 2007-11-15 Exxonmobil Chemical Patents Inc. Mélanges de polymères basse densité linéaires et articles fabriqués à partir de ces mélanges

Family Cites Families (11)

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Publication number Priority date Publication date Assignee Title
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5008204A (en) 1988-02-02 1991-04-16 Exxon Chemical Patents Inc. Method for determining the compositional distribution of a crystalline copolymer
JPH06509528A (ja) 1991-07-18 1994-10-27 エクソン・ケミカル・パテンツ・インク ヒートシール製品
ES2108861T3 (es) 1991-11-25 1998-01-01 Exxon Chemical Patents Inc Composiciones cataliticas polionicas de metales de transicion.
US5643847A (en) 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
EP0775707B1 (fr) 1995-06-08 2001-11-28 Showa Denko Kabushiki Kaisha Composés ioniques et catalyseurs destinés à polymeriser les olefines au moyen de ces composés
EP0824112B1 (fr) 1996-08-13 2006-05-10 Basell Polyolefine GmbH Composé chimique supporté
US6242545B1 (en) 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US6040261A (en) 1999-04-15 2000-03-21 Equistar Chemicals, Lp Supported single-site catalyst and olefin polymerization process
US7157531B2 (en) 2004-06-21 2007-01-02 Univation Technologies, Llc Methods for producing polymers with control over composition distribution
US8247065B2 (en) 2006-05-31 2012-08-21 Exxonmobil Chemical Patents Inc. Linear polymers, polymer blends, and articles made therefrom

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5998017A (en) * 1996-03-12 1999-12-07 Tenneco Packaging Stretch wrap films
US6093480A (en) * 1997-05-21 2000-07-25 Tenneco Packaging Stretch wrap films
US20010016632A1 (en) * 1999-07-09 2001-08-23 Nova Chemicals (International) S.A. Heavy duty packaging film
WO2001098409A1 (fr) * 2000-06-22 2001-12-27 Exxonmobil Chemical Patents Inc. Mélange de polyéthylène très basse densité et de polyéthylène haute densité
US20050058847A1 (en) * 2001-07-19 2005-03-17 Szul John F. High tear films from hafnocene catalyzed polyethylenes
US6956088B2 (en) * 2001-07-19 2005-10-18 Univation Technologies, Llc Polyethylene films with improved physical properties
US20040053022A1 (en) * 2002-09-05 2004-03-18 Ohlsson Stefan Bertil Shrink film
US20050159300A1 (en) * 2004-01-21 2005-07-21 Jensen Michael D. Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
WO2007130277A1 (fr) * 2006-05-05 2007-11-15 Exxonmobil Chemical Patents Inc. Mélanges de polymères basse densité linéaires et articles fabriqués à partir de ces mélanges

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107073905A (zh) * 2014-08-12 2017-08-18 陶氏环球技术有限责任公司 基于聚乙烯的复合膜和由其制造的物件

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Publication number Publication date
WO2009082546A2 (fr) 2009-07-02

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