WO2009073062A3 - Electrolytic cell for producing alkali alcoholates - Google Patents
Electrolytic cell for producing alkali alcoholates Download PDFInfo
- Publication number
- WO2009073062A3 WO2009073062A3 PCT/US2008/011382 US2008011382W WO2009073062A3 WO 2009073062 A3 WO2009073062 A3 WO 2009073062A3 US 2008011382 W US2008011382 W US 2008011382W WO 2009073062 A3 WO2009073062 A3 WO 2009073062A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- alkali
- compartment
- alcohol
- catholyte
- solution
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/25—Reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Alkali alcoholates are produced from alkali metal salt solutions and alcohol using a three-compartment electrolyte cell (I0) that includes an anolyte compartment (22) configured with an anode (26), a buffer compartment (24), and a catholyte compartment (20) configured with a cathode (28) First and second separators (14 and 16), permeable to alkali ions, are positioned between the anolyte compartment (22) and the catholyte compartment (20) to define a buffer compartment (24) They may be fabπcated of the same or different matenals including, but not limited to, an alkali ion conducting solid electrolyte configured to selectively transport alkali ions, a porous ceramic, or a porous polymer separator mateπal The catholyte solution may include an alkali alcoholate and alcohol The anolyte solution may include at least one alkali salt The buffer compartment solution may include a soluble alkali salt and an alkali alcoholate in alcohol.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08857374A EP2209931A4 (en) | 2007-10-01 | 2008-10-01 | Electrolytic cell for producing alkali alcoholates |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/865,361 US20080173540A1 (en) | 2003-12-11 | 2007-10-01 | Electrolytic Cell for Producing Alkali Alcoholates |
US11/865,361 | 2007-10-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2009073062A2 WO2009073062A2 (en) | 2009-06-11 |
WO2009073062A3 true WO2009073062A3 (en) | 2009-12-23 |
Family
ID=40718405
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2008/011382 WO2009073062A2 (en) | 2007-10-01 | 2008-10-01 | Electrolytic cell for producing alkali alcoholates |
Country Status (3)
Country | Link |
---|---|
US (1) | US20080173540A1 (en) |
EP (1) | EP2209931A4 (en) |
WO (1) | WO2009073062A2 (en) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5314246B2 (en) | 2003-12-11 | 2013-10-16 | アメリカン パシフィック コーポレイション | Electrolytic method for producing alkali alcoholates using solid membranes of ion-conducting ceramics |
US8075758B2 (en) | 2003-12-11 | 2011-12-13 | Ceramatec, Inc. | Electrolytic method to make alkali alcoholates using ion conducting alkali electrolyte/separator |
US7824536B2 (en) | 2003-12-11 | 2010-11-02 | Ceramatec, Inc. | Electrolytic method to make alkali alcoholates using ceramic ion conducting solid membranes |
US8268159B2 (en) | 2005-12-20 | 2012-09-18 | Ceramatec, Inc. | Electrolytic process to produce sodium hypochlorite using sodium ion conductive ceramic membranes |
US8262872B2 (en) * | 2005-12-20 | 2012-09-11 | Ceramatec, Inc. | Cleansing agent generator and dispenser |
US20080245671A1 (en) * | 2007-04-03 | 2008-10-09 | Shekar Balagopal | Electrochemical Process to Recycle Aqueous Alkali Chemicals Using Ceramic Ion Conducting Solid Membranes |
US8192609B2 (en) * | 2009-12-01 | 2012-06-05 | Wisconsin Alumni Research Foundation | Cobalt oxyfluoride catalysts for electrolytic dissociation of water |
EP2507411A4 (en) * | 2009-12-01 | 2015-07-29 | Wisconsin Alumni Res Found | Buffered cobalt oxide catalysts |
US8444846B2 (en) * | 2009-12-07 | 2013-05-21 | Battelle Energy Alliance, Llc | Method and system for producing hydrogen using sodium ion separation membranes |
WO2012097167A2 (en) * | 2011-01-12 | 2012-07-19 | Ceramatec, Inc. | Electrochemical production of hydrogen |
US11769906B2 (en) | 2017-09-14 | 2023-09-26 | Ampcera Inc. | Systems and methods for selectively extracting alkaline metals from metal-rich solutions using solid state ionic conductive electrolyte membrane |
US11177498B1 (en) | 2018-10-15 | 2021-11-16 | Ampcera Inc. | Redox flow batteries, components for redox flow batteries and methods for manufacture thereof |
US11819806B1 (en) | 2018-10-15 | 2023-11-21 | Ampcera Inc. | Methods for manufacturing a solid state ionic conductive membrane on a macro porous support scaffold |
US11600853B1 (en) | 2019-05-14 | 2023-03-07 | Ampcera Inc. | Systems and methods for storing, transporting, and handling of solid-state electrolytes |
ES2955404T3 (en) * | 2020-03-24 | 2023-11-30 | Evonik Operations Gmbh | Procedure for the production of alkali metal alcoholates in a three-chamber electrolytic cell |
EP3885471B1 (en) * | 2020-03-24 | 2023-07-19 | Evonik Operations GmbH | Improved method for the preparation of sodium alcoholates |
ES2958263T3 (en) | 2021-02-11 | 2024-02-06 | Evonik Operations Gmbh | Alkali metal alcoholate production procedure in a three-chamber electrolytic cell |
KR102543734B1 (en) * | 2021-06-16 | 2023-06-13 | 울산과학기술원 | Desalting apparatus for resource recovery from seawater concentrate |
EP4112780B1 (en) * | 2021-06-29 | 2023-08-02 | Evonik Operations GmbH | Three-chamber electrolysis cell for the production of alkali metal alcoholate |
PL4112778T3 (en) * | 2021-06-29 | 2024-05-13 | Evonik Operations Gmbh | Three-chamber electrolysis cell for the production of alkali metal alcoholate |
HUE064033T2 (en) * | 2021-06-29 | 2024-02-28 | Evonik Operations Gmbh | Three-chamber electrolysis cell for the production of alkali metal alcoholate |
EP4124677A1 (en) | 2021-07-29 | 2023-02-01 | Evonik Functional Solutions GmbH | Fracture-stable partition comprising solid electrolyte ceramics for electrolytic cells |
WO2023006490A1 (en) | 2021-07-29 | 2023-02-02 | Evonik Functional Solutions Gmbh | Break-resistant partition wall comprising solid electrolyte ceramics for electrolytic cells |
EP4134472A1 (en) * | 2021-08-13 | 2023-02-15 | Evonik Functional Solutions GmbH | Method for producing alkaline metal alcaholates in an electrolysis cell |
EP4144889A1 (en) * | 2021-09-06 | 2023-03-08 | Evonik Functional Solutions GmbH | Method for producing alkaline metal alcaholates in an electrolysis cell |
EP4144888A1 (en) * | 2021-09-06 | 2023-03-08 | Evonik Functional Solutions GmbH | Method for producing alkaline metal alcaholates in an electrolysis cell |
EP4144890A1 (en) * | 2021-09-06 | 2023-03-08 | Evonik Functional Solutions GmbH | Method for producing alkaline metal alcaholates in an electrolysis cell |
WO2023193940A1 (en) * | 2022-04-04 | 2023-10-12 | Evonik Operations Gmbh | Improved method for depolymerising polyethylene terephthalate |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5425856A (en) * | 1994-04-26 | 1995-06-20 | Occidental Chemical Corporation | Method of making alkali metal alcoholates |
US20060226022A1 (en) * | 2003-12-11 | 2006-10-12 | Ceramatec, Inc. | Electrolytic method to make alkali alcoholates using ceramic ion conducting solid membranes |
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US3197392A (en) * | 1961-11-30 | 1965-07-27 | Du Pont | Process for preparing organometal compounds |
GB1307581A (en) * | 1970-05-05 | 1973-02-21 | Monsanto Chemicals | Production of alkoxides |
AT324352B (en) * | 1972-10-05 | 1975-08-25 | Studiengesellschaft Kohle Mbh | PROCESS FOR THE PRODUCTION OF ORGANIC METAL COMPOUNDS BY ELECTROCHEMICAL REPRODUCTION OF METALS AND H-ACIDEN COMPOUNDS |
US4217184A (en) * | 1979-03-26 | 1980-08-12 | Stauffer Chemical Company | Continuous process for preparing metal alkoxides |
US4250000A (en) * | 1979-03-26 | 1981-02-10 | Stauffer Chemical Company | Electrochemical process for metal alkoxides |
DE3702052C1 (en) * | 1987-01-24 | 1988-07-14 | Degussa | Process for the production of high purity sodium alcoholate from the filtration residue of crude sodium obtained by melt electrolysis |
US4990413A (en) * | 1989-01-18 | 1991-02-05 | Mhb Joint Venture | Composite solid electrolytes and electrochemical devices employing the same |
DE4009410A1 (en) * | 1990-03-23 | 1991-09-26 | Basf Ag | METHOD FOR ELECTROCHEMICAL CLIPPING OF ALKALI SULPHATES |
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US5290405A (en) * | 1991-05-24 | 1994-03-01 | Ceramatec, Inc. | NaOH production from ceramic electrolytic cell |
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US5286354A (en) * | 1992-11-30 | 1994-02-15 | Sachem, Inc. | Method for preparing organic and inorganic hydroxides and alkoxides by electrolysis |
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CA2234552C (en) * | 1997-04-11 | 2001-03-06 | Arthur Yelon | Composite inorganic-polymer thin film cation-selective membrane, method of fabricating same and applications |
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DE19940069A1 (en) * | 1999-08-24 | 2001-03-08 | Basf Ag | Process for the electrochemical production of an alkali metal from an aqueous solution |
DE19962102A1 (en) * | 1999-12-22 | 2001-06-28 | Basf Ag | Process for the electrochemical oxidation of organic compounds |
EP1312700A3 (en) * | 2001-11-02 | 2003-05-28 | Degussa AG | Process for the production of alkali metal alcoholates |
WO2005021697A1 (en) * | 2003-08-29 | 2005-03-10 | Nippon Shokubai Co., Ltd. | Method of production of fatty acid alkyl esters and/or glycerine and fatty acid alkyl ester-containing composition |
US20080173551A1 (en) * | 2003-12-11 | 2008-07-24 | Joshi Ashok V | Electrolytic Method to Make Alkali Alcoholates |
JP5314246B2 (en) * | 2003-12-11 | 2013-10-16 | アメリカン パシフィック コーポレイション | Electrolytic method for producing alkali alcoholates using solid membranes of ion-conducting ceramics |
US8075758B2 (en) * | 2003-12-11 | 2011-12-13 | Ceramatec, Inc. | Electrolytic method to make alkali alcoholates using ion conducting alkali electrolyte/separator |
US20090057162A1 (en) * | 2007-01-11 | 2009-03-05 | Shekar Balagopal | Electrolytic Process to Separate Alkali Metal Ions from Alkali Salts of Glycerine |
US20080245671A1 (en) * | 2007-04-03 | 2008-10-09 | Shekar Balagopal | Electrochemical Process to Recycle Aqueous Alkali Chemicals Using Ceramic Ion Conducting Solid Membranes |
WO2009005767A1 (en) * | 2007-06-29 | 2009-01-08 | Archer-Daniels-Midland Company | Process for desalting glycerol solutions and recovery of chemicals |
WO2009032312A1 (en) * | 2007-09-05 | 2009-03-12 | Ceramatec, Inc | Apparatus and methods for producing biodiesel using an alkali ion donating catalyst |
-
2007
- 2007-10-01 US US11/865,361 patent/US20080173540A1/en not_active Abandoned
-
2008
- 2008-10-01 EP EP08857374A patent/EP2209931A4/en not_active Withdrawn
- 2008-10-01 WO PCT/US2008/011382 patent/WO2009073062A2/en active Application Filing
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5425856A (en) * | 1994-04-26 | 1995-06-20 | Occidental Chemical Corporation | Method of making alkali metal alcoholates |
US20060226022A1 (en) * | 2003-12-11 | 2006-10-12 | Ceramatec, Inc. | Electrolytic method to make alkali alcoholates using ceramic ion conducting solid membranes |
Also Published As
Publication number | Publication date |
---|---|
US20080173540A1 (en) | 2008-07-24 |
EP2209931A4 (en) | 2010-12-29 |
WO2009073062A2 (en) | 2009-06-11 |
EP2209931A2 (en) | 2010-07-28 |
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