WO2009057773A1 - Catalyseur de réaction de transestérification, procédé de fabrication d'ester alkylique à l'aide de celui-ci, mélange d'ester alkylique et carburant contenant le mélange d'ester alkylique - Google Patents
Catalyseur de réaction de transestérification, procédé de fabrication d'ester alkylique à l'aide de celui-ci, mélange d'ester alkylique et carburant contenant le mélange d'ester alkylique Download PDFInfo
- Publication number
- WO2009057773A1 WO2009057773A1 PCT/JP2008/069932 JP2008069932W WO2009057773A1 WO 2009057773 A1 WO2009057773 A1 WO 2009057773A1 JP 2008069932 W JP2008069932 W JP 2008069932W WO 2009057773 A1 WO2009057773 A1 WO 2009057773A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- alkyl ester
- transesterification reaction
- reaction catalyst
- ester mixture
- producing
- Prior art date
Links
- 125000005907 alkyl ester group Chemical group 0.000 title abstract 8
- 239000007809 chemical reaction catalyst Substances 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- 238000005809 transesterification reaction Methods 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 239000000446 fuel Substances 0.000 title abstract 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- 125000005910 alkyl carbonate group Chemical group 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- -1 ester compound Chemical class 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 238000010304 firing Methods 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 abstract 1
- 239000000347 magnesium hydroxide Substances 0.000 abstract 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/10—Magnesium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/02—Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C68/00—Preparation of esters of carbonic or haloformic acids
- C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
- C10L1/191—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polyhydroxyalcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
L'invention porte sur un catalyseur de réaction de transestérification facilement manipulable qui permet d'obtenir un ester alkylique comme produit de l'objet avec un rendement élevé sans nécessiter une étape séparée pour l'élimination de la glycérine. L'invention porte également sur un procédé de fabrication d'un ester alkylique utilisant un tel catalyseur de réaction de transestérification, sur un mélange d'ester alkylique ne contenant guère de FAGC, et sur un carburant contenant un tel mélange d'ester alkylique. De façon spécifique, l'invention porte sur un procédé de production d'un ester alkylique dans lequel un ester alkylique d'acide gras est obtenu par réaction d'un triglycéride comme composé ester avec un carbonate d'alkyle en présence d'un catalyseur de réaction de transestérification contenant principalement de la magnésie légèrement cuite qui est obtenue par cuisson d'hydroxyde de magnésium à une température non inférieure à 355°C mais non supérieure à 650°C.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007-286723 | 2007-11-02 | ||
| JP2007-286724 | 2007-11-02 | ||
| JP2007286724 | 2007-11-02 | ||
| JP2007286723 | 2007-11-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2009057773A1 true WO2009057773A1 (fr) | 2009-05-07 |
Family
ID=40591153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2008/069932 WO2009057773A1 (fr) | 2007-11-02 | 2008-10-31 | Catalyseur de réaction de transestérification, procédé de fabrication d'ester alkylique à l'aide de celui-ci, mélange d'ester alkylique et carburant contenant le mélange d'ester alkylique |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO2009057773A1 (fr) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06107601A (ja) * | 1992-09-30 | 1994-04-19 | Nippon Shokubai Co Ltd | ジアルキルカーボネートの製造方法 |
| JPH06279396A (ja) * | 1993-03-25 | 1994-10-04 | Nippon Shokubai Co Ltd | チオール基含有カルボン酸エステル類の製造方法 |
| JP2006515376A (ja) * | 2002-12-12 | 2006-05-25 | ポリメーリ エウローパ ソシエタ ペル アチオニ | 燃料又は溶剤としての脂肪酸のエステルの混合物の使用 |
-
2008
- 2008-10-31 WO PCT/JP2008/069932 patent/WO2009057773A1/fr active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06107601A (ja) * | 1992-09-30 | 1994-04-19 | Nippon Shokubai Co Ltd | ジアルキルカーボネートの製造方法 |
| JPH06279396A (ja) * | 1993-03-25 | 1994-10-04 | Nippon Shokubai Co Ltd | チオール基含有カルボン酸エステル類の製造方法 |
| JP2006515376A (ja) * | 2002-12-12 | 2006-05-25 | ポリメーリ エウローパ ソシエタ ペル アチオニ | 燃料又は溶剤としての脂肪酸のエステルの混合物の使用 |
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