WO2009048132A1 - Compound having 1,2,3,5,6,7-hexahydro-s-indacene skeleton, silicon-silicon double bond-containing compound, and fluorescent material - Google Patents

Compound having 1,2,3,5,6,7-hexahydro-s-indacene skeleton, silicon-silicon double bond-containing compound, and fluorescent material Download PDF

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Publication number
WO2009048132A1
WO2009048132A1 PCT/JP2008/068444 JP2008068444W WO2009048132A1 WO 2009048132 A1 WO2009048132 A1 WO 2009048132A1 JP 2008068444 W JP2008068444 W JP 2008068444W WO 2009048132 A1 WO2009048132 A1 WO 2009048132A1
Authority
WO
WIPO (PCT)
Prior art keywords
silicon
compound
atom
hexahydro
double bond
Prior art date
Application number
PCT/JP2008/068444
Other languages
French (fr)
Japanese (ja)
Inventor
Kohei Tamao
Tsukasa Matsuo
Tomohide Fukawa
Katsunori Suzuki
Original Assignee
Riken
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2007265855A external-priority patent/JP2009091332A/en
Priority claimed from JP2007265886A external-priority patent/JP2009091333A/en
Application filed by Riken filed Critical Riken
Publication of WO2009048132A1 publication Critical patent/WO2009048132A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/18—Polycyclic aromatic halogenated hydrocarbons
    • C07C25/22—Polycyclic aromatic halogenated hydrocarbons with condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/54—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
    • C07C13/547—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered
    • C07C13/553—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered with an indacene or hydrogenated indacene ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C07C17/12—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms in the ring of aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/16—Preparation of halogenated hydrocarbons by replacement by halogens of hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/272—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions
    • C07C17/275—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions of hydrocarbons and halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C22/00—Cyclic compounds containing halogen atoms bound to an acyclic carbon atom
    • C07C22/02—Cyclic compounds containing halogen atoms bound to an acyclic carbon atom having unsaturation in the rings
    • C07C22/04—Cyclic compounds containing halogen atoms bound to an acyclic carbon atom having unsaturation in the rings containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/02—Monocyclic aromatic halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/0805—Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
    • C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings

Abstract

Disclosed is a compound represented by the following general formula (I). (I) In the formula (I), A and B independently represent a hydrogen atom, a halogen atom, a lithium atom, a monovalent group represented by -MgX (wherein X represents a chlorine atom, a bromine atom or an iodine atom) or a silyl group; and R1-R8 independently represent a saturated or unsaturated hydrocarbon group having 1-20 carbon atoms. In this connection, R1-R8 are not methyl groups at the same time, or they are not ethyl groups at the same time. Consequently, there can be provided a novel compound which is useful for organic synthetic chemistry.
PCT/JP2008/068444 2007-10-11 2008-10-10 Compound having 1,2,3,5,6,7-hexahydro-s-indacene skeleton, silicon-silicon double bond-containing compound, and fluorescent material WO2009048132A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007265855A JP2009091332A (en) 2007-10-11 2007-10-11 Compound having 1,2,3,5,6,7-hexahydro-s-indacene skeleton
JP2007265886A JP2009091333A (en) 2007-10-11 2007-10-11 Silicon-silicon double bond-containing compound and fluorescent material
JP2007-265855 2007-10-11
JP2007-265886 2007-10-11

Publications (1)

Publication Number Publication Date
WO2009048132A1 true WO2009048132A1 (en) 2009-04-16

Family

ID=40549275

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/068444 WO2009048132A1 (en) 2007-10-11 2008-10-10 Compound having 1,2,3,5,6,7-hexahydro-s-indacene skeleton, silicon-silicon double bond-containing compound, and fluorescent material

Country Status (1)

Country Link
WO (1) WO2009048132A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024061948A1 (en) * 2022-09-22 2024-03-28 Merck Patent Gmbh Nitrogen-containing hetreocycles for organic electroluminescent devices
WO2024061942A1 (en) * 2022-09-22 2024-03-28 Merck Patent Gmbh Nitrogen-containing compounds for organic electroluminescent devices

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2768982A (en) * 1953-12-21 1956-10-30 California Research Corp Fused ring hydrocarbon production
JPS5412359A (en) * 1977-06-30 1979-01-30 Int Flavors & Fragrances Inc Production of bicyclic compound

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2768982A (en) * 1953-12-21 1956-10-30 California Research Corp Fused ring hydrocarbon production
JPS5412359A (en) * 1977-06-30 1979-01-30 Int Flavors & Fragrances Inc Production of bicyclic compound

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
BRUNTON G. ET AL.: "Kinetic applications of electron paramagnetic resonance spectroscopy. 32. Further studies of quantum-mechanical tunneling in the isomerization of sterically hindered aryl radicals", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 100, no. 13, 1978, pages 4197 - 200 *
FUKAZAWA A. ET AL.: "Coplanar Oligo (p-phenylenedisilenylene)s Based on the Octaethyl-Substituted s-Hydrindacenyl Groups", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 129, no. 46, 27 October 2007 (2007-10-27), pages 14164 - 14165 *
FUKAZAWA A. ET AL.: "Synthesis and Photophysical Properties of Extended n-Conjugated System Containing Si=Si Double Bonds with a New Fused-Type Bulky Ligand", SYMP ORGANOMET CHEM JPN, vol. 54, 12 October 2007 (2007-10-12), pages 3 *
KOBAYASHI M. ET AL.: "Ferrocenyl-ki o Yusuru Shinki na Teihaii Silicon Kagobutsu no Gosei Kenkyu", CSJ: THE CHEMICAL SOCIETY OF JAPAN KOEN YOKOSHU, vol. 85, no. 2, 11 March 2005 (2005-03-11), pages 1004 *
SUGIYAMA Y. ET AL.: "Kasa Takai Chikanki o Yusuru Antei na Dihydro Disilene no Gosei", CSJ: THE CHEMICAL SOCIETY OF JAPAN KOEN YOKOSHU, vol. 85, no. 1, 11 March 2005 (2005-03-11), pages 126 *
SUZUKI K. ET AL.: "Shukukangata Rittai Hogoki o Yusuru Disilene Kyoekikei Oligomer no Gosei", CSJ: THE CHEMICAL SOCIETY OF JAPAN KOEN YOKOSHU, vol. 88, no. 1, 12 March 2008 (2008-03-12), pages 336 *
TOKITO N.: "Rittai Hogo o Katsuyo shita Ko Hannosei Ko Shuki 14 Zoku Genso Kagobutsu no Anteika (Monbusho S)", KASSEI IJO BUNSHI - GOSEI TO HANNO SEIGYO HEISEI 7 NENDO MONBU KAGAKUSHO KENKYUHI HOJOKIN SOGO KENKYU (A) KENKYU SEIKA HOKOKUSHO, March 1996 (1996-03-01), pages 87 - 89 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024061948A1 (en) * 2022-09-22 2024-03-28 Merck Patent Gmbh Nitrogen-containing hetreocycles for organic electroluminescent devices
WO2024061942A1 (en) * 2022-09-22 2024-03-28 Merck Patent Gmbh Nitrogen-containing compounds for organic electroluminescent devices

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