WO2009039674A1 - Desinfektion mit hochdruckreiniger und hydrolysiertem wasser - Google Patents
Desinfektion mit hochdruckreiniger und hydrolysiertem wasser Download PDFInfo
- Publication number
- WO2009039674A1 WO2009039674A1 PCT/CH2008/000393 CH2008000393W WO2009039674A1 WO 2009039674 A1 WO2009039674 A1 WO 2009039674A1 CH 2008000393 W CH2008000393 W CH 2008000393W WO 2009039674 A1 WO2009039674 A1 WO 2009039674A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- water
- pressure
- electrolysis
- materials
- disinfection
- Prior art date
Links
- 229910001868 water Inorganic materials 0.000 title claims abstract description 80
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 79
- 238000004140 cleaning Methods 0.000 title claims abstract description 36
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 19
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 50
- 230000001590 oxidative effect Effects 0.000 claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 23
- 239000000126 substance Substances 0.000 claims abstract description 15
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 9
- 244000005700 microbiome Species 0.000 claims abstract description 7
- 241000894006 Bacteria Species 0.000 claims abstract description 5
- 241000700605 Viruses Species 0.000 claims abstract description 5
- 244000052769 pathogen Species 0.000 claims abstract description 5
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims abstract description 4
- 241000233866 Fungi Species 0.000 claims abstract description 3
- 241000195493 Cryptophyta Species 0.000 claims abstract 2
- 230000003647 oxidation Effects 0.000 claims abstract 2
- 238000007254 oxidation reaction Methods 0.000 claims abstract 2
- 230000008569 process Effects 0.000 claims description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- -1 salt ions Chemical class 0.000 claims description 9
- 229910003460 diamond Inorganic materials 0.000 claims description 8
- 239000010432 diamond Substances 0.000 claims description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 7
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 5
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- 230000010287 polarization Effects 0.000 claims description 4
- 238000003860 storage Methods 0.000 claims description 4
- DNTFEAHNXKUSKQ-RFZPGFLSSA-N (1r,2r)-2-aminocyclopentane-1-sulfonic acid Chemical compound N[C@@H]1CCC[C@H]1S(O)(=O)=O DNTFEAHNXKUSKQ-RFZPGFLSSA-N 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 2
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 claims 1
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 239000000956 alloy Substances 0.000 claims 1
- 230000033228 biological regulation Effects 0.000 claims 1
- 239000001177 diphosphate Substances 0.000 claims 1
- 235000011180 diphosphates Nutrition 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 21
- 235000002639 sodium chloride Nutrition 0.000 description 16
- 210000004027 cell Anatomy 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000011780 sodium chloride Substances 0.000 description 9
- 238000000354 decomposition reaction Methods 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 239000000460 chlorine Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 238000011012 sanitization Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- UAYWVJHJZHQCIE-UHFFFAOYSA-L zinc iodide Chemical compound I[Zn]I UAYWVJHJZHQCIE-UHFFFAOYSA-L 0.000 description 2
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 208000010201 Exanthema Diseases 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000030833 cell death Effects 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001647 drug administration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 201000005884 exanthem Diseases 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 235000021474 generally recognized As safe (food) Nutrition 0.000 description 1
- 235000021473 generally recognized as safe (food ingredients) Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000012432 intermediate storage Methods 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical compound [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229940095696 soap product Drugs 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/02—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
- A61L2/03—Electric current
- A61L2/035—Electrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/02—Cleaning by the force of jets or sprays
- B08B3/026—Cleaning by making use of hand-held spray guns; Fluid preparations therefor
Definitions
- the invention relates to a new chemical and residue-free method for cleaning, Hygienisie ⁇ mg, disinfecting and odor neutralization of surfaces, materials and objects by means of a high-pressure cleaning device using electrolyzed cold or warm water and with the help of oxidative radicals.
- the purpose of the new invention is to demonstrate that by means of a high-pressure cleaning device and the use of electrolyzed water by means of oxidative radicals and ultrafast superoxidation, surfaces, materials and objects can be cleaned, sanitized and disinfected without the costly use of Environmentally polluting and toxic chemicals and energy wasting hot water.
- the object of the invention is to provide a new, cost-effective, efficient, environmentally friendly, biological and residue-free method for hygienic treatment of surfaces, materials and objects by means of a high pressure cleaner and the use of electrolysed water by means of oxidative radicals, thanks to ultrafast superoxidation to clean and disinfect.
- the pathogen is compressed, resulting in osmotic or hydrogen overload inside the cell.
- the damaged cell membranes allow increased water transfer between the cell membranes, resulting in hydrogen cell flooding and filling them faster than the cells can dispose of the water. This fact leads to a bursting of the cells, or to cell death by pressure explosion in a few seconds.
- the voltage source causes an electron deficiency in the electrode connected to the positive pole (anode) and an excess of electrons in the other electrode connected to the negative pole (cathode).
- the aqueous solution between the cathode and anode contains electrolytes, which are positively or negatively charged ions.
- the positively charged cations in An electrolytic cell migrates by applying a voltage to the negatively charged cathode (attraction opposite charges). At the cathode, they absorb one or more electrons and are thereby reduced.
- the opposite process takes place.
- the negatively charged anions emit electrons, that is, they are oxidized.
- the number of electrons consumed by the reduction at the cathode corresponds to the electrons picked up by the anode.
- the electrolysis of aqueous saline solution the same volume of hydrogen gas as chlorine gas is produced.
- the electrolysis of water produces twice as much hydrogen gas as oxygen gas, since the two positively charged protons of a water molecule change to the cathode w and have to take up an electron to form hydrogen, whereas the doubly negatively charged oxygen ion at the anode Z ⁇ vei has to give off electrons in order to join the oxygen molecule.
- the voltage which must at least be applied to the electrolyte is known as the deposition potential; in the case of electrolysis of water or in the case of aqueous salt solutions, this is also referred to as the decomposition stress.
- This voltage (or a higher voltage) must be applied so that the electrolysis takes place at all.
- the decomposition voltage the deposition potential can be determined on the basis of the redox potential by means of ions of two or low-boiling molecules. From the redox potential one still receives many other important hints for the electrolysis, for example to the electrolytic
- the cations at the cathode are first reduced after the redox series, which have a more positive (well negative) potential in the redox series (voltage series), ie the potential of the proton-hydrogen electrode voltage get as close as possible.
- the electrolysis of an aqueous saline solution forms at the cathode usually hydrogen and not sodium. Even in the presence of several types of anions that can be oxidized, first those come into play that have in the redox series as close as possible to the voltage zero point, ie a weaker positive redox potential.
- overpotential In addition to your redox potential, the overpotential (overpotential) is also important. Due to the leinetic inhibition of electrodes, one often requires a significantly higher voltage than that from the calculation of the
- Redox potentials calculated.
- the effects of overvoltage can change depending on the nature of the material, including the ORP series, so that other ions are oxidized or reduced than would have been the case for the redox potential.
- Shortly after switching off an electrolysis can be with an ammeter a current rash in the notice other direction.
- the reverse process of electrolysis the formation of a galvanic cell. In this case, power is not consumed for the conversion, but it generates> vir-d current for a short time; This principle is used in fuel cells.
- a galvanic element When a separation of single molecules or bonds is induced by an electrolysis, a galvanic element, the voltage of which counteracts electrolysis, acts simultaneously. This voltage is also called the polarization voltage.
- the electrolysis of water provides two Tetlretressen, which proceed at the two electrodes.
- the electrodes are immersed in water, which is rendered more conductive by the addition of some common salt, and then chlorine is recovered instead of oxygen.
- H 3 O + Positively charged hydronium ions migrate in the electric field to the negatively charged electrode (cathode), where they each receive an electron. Hydrogen atoms are formed, which combine with another H atom formed by reduction to form a " hydrogen molecule.” Remains water molecules
- Each hydroxide ion releases an electron at the positive pole, so that oxygen atoms are formed, which combine to form oxygen molecules.
- NaCl addition to chlorine molecules
- the hydroxide ion is a negatively charged ion that disfigures when bases react with water. Its chemical formula is OH " .
- a general base B reacts with water according to the following scheme:
- Hydroxide ions are also contained in pure water at 20 ° C. in a concentration of 10.sup.- 7 mol.sup.- 1 This is due to the autoprotolysis of the water according to the following reaction equation:
- Electrolysed oxidative water received FDA (USA Food and
- the procedure includes the following technical aids and process steps:
- the preparation of the biocidal oxidative radicals in aqueous, saline solution can be done by 2 different Elcktrolyseclar.
- the first method is implemented with diamond electrolysis using diamond-coated electrodes. This results in a cocktail of oxidative radicals near the "neutral" region with a pH value from 6.4 to 6.8.
- oxidative radicals near the "neutral" region with a pH value from 6.4 to 6.8.
- free chlorine (CI-) are formed at the anode, which together with the hydroxyl groups lead to the formation of hypochlorite HOCL and hypochlorite acid H2OCL, which are organically degraded very rapidly.
- salt is added to the water because of the improved electroconductivity NaCl.
- Molecules such as reducing peroxide-di-sulfate, peroxide-di-phosphate and percarbonate.
- the NaCl salt concentration per liter of water is: preferably 0.5-8 grams NaCl (common salt) or more.
- the second method is implemented with cylinder electrolysis with diaphragm, where the electrolysis cells are separated from each other, consisting of an anode chamber and a cathode chamber.
- the electrolysis cells are separated from each other, consisting of an anode chamber and a cathode chamber.
- the process for chemical and residue free purification, sanitization, disinfection and odor neutralization of surfaces, materials and articles by means of a high pressure cleaning device using electrolyzed cold or warm water and with the help of oxidative radicals shows the way the biocides, in particular the specific properties of the electrolyzed, Oxidath en water, its production, its salt concentration and salt composition, its redox potential, respectively, its concentration in free oxidative radicals and total concentration of oxidative radicals, and its pH and application rate for an efficient injection process of the high-pressure cleaning device.
- the method also shows the technical design and application, with respect to the combination of high-pressure cleaner and electrolysis generator, for the production of oxidative radicals and a water storage tank for deep cleaning and elimination of germs.
- the invention forms an integrated system in which the technical components of oxidative radical production by means of the electrolytic production of oxidative radicals in the water and intermediate storage in the storage tank, with the appropriate application technologies in combination with a high-pressure cleaning device for deep cleaning and disinfection of surfaces, materials and objects are integrated.
- the focus of the innovation is not only in the technical combination of a high-pressure cleaner with an electrolysis plant for the production of oxidative radicals, but also in the new process and application technology of the combined application of High pressure with an aqueous solution of Oxidative Radicals, which thanks to ultrafast superoxidation, can not only cleanse but also disinfect and even be able to dissolve biofilms.
- ID's multi-year trials have determined the optimal levels of oxidative radicals in the water and the specific high pressure and pressure requirements and treatment times to achieve perfect cleaning and disinfection on all types of surfaces, materials and surfaces.
- the invention will be illustrated by an example of a mobile Desin Stammionsanlagc consisting of preferably an electrolysis generator, an intermediate tank and a high-pressure cleaning device including high-pressure spray lance with adjustable nozzle mounted on a mobile rubber wheel equipped trolley chassis.
- a mobile high-pressure disinfection and cleaning system with oxidatively oxidized radicals derived from water for cleaning and sanitizing surfaces, materials and objects consists of the following technical parts:
- Electrolysis generator with 2 single chamber electrolysis cells, parallel connected, boron doped diamond electrodes, stainless steel pump with a capacity of 600 liters per hour and 4 bar pressure, filter with 50 mesh, flow meter up to 900 liters per hour, pressure control with preferably 2 taps and 2 pressure gauges, electric water flow sensor, electronic control unit with time-controlled automatic electrode reversal polarization, redox meter, water supply tank with inlet and outlet tap, water pipes, one-way return valve. Electronic programmable control unit with switch, electronic water level control with electronic inflow valve, on and off button. Timing and switching clock, water supply and discharge to Hocbdruckrciniger. Compare ANNEX 1 B
- the device is connected to the mains 220 V.
- the electrolysis device is then turned on.
- the intermediate tank of 50 liters capacity is filled with normal hardness of poor water and added as needed with 0.5 to 8 grams of cooking salt per liter, i. with up to 400 grams of common salt (NaCl).
- the pre-programmed electrolysis unit is now switched on.
- the corrosion resistant pump 600 liters per hour
- the corrosion resistant pump now pumps the water at 10 liters per minute through the electrolysis cells.
- the water is cleaved by the diamond electrodes (anode / cathode), resulting in oxidative radicals that cause ultrafast superoxidation on surfaces leading to complete disinfection and killing of microorganisms.
- the water is electrolyzed until the desired concentration is established.
- the programmed REDOX Monitor device automatically turns on and off, or a timer controls the electrolyzer.
- the high-pressure cleaner can be switched on.
- the high pressure spray process can now be triggered and the surfaces to be cleaned treated with the high pressure water jet.
- the reducing water acts like a soap product and not only removes dirt and bacterial dirt bio-films, but also disinfects by killing 99.9% of all microorganisms such as viruses, gram positive and gram negative bacteria, yeasts, protozoa, etc. seconds.
- the oxidative water has a prolonged action time, which favors the disinfection intensity.
- the cleaning is perfect and it There are no toxic residues.
- the method can thus also be used in CIP applications (Clean in Place).
- the high pressure, oxidative radical cleaning process is cheaper than any other chemical cleaning process.
- the energy consumption is only 600 W / h for the production of 600 liters of disinfectant solution.
Landscapes
- Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NZ584139A NZ584139A (en) | 2007-09-25 | 2008-09-23 | Disinfection using a high-pressure cleaning device and hydrolyzed water, featuring use of a diamond electrode |
BRPI0817975-1A2A BRPI0817975A2 (pt) | 2007-09-25 | 2008-09-23 | Método e execução técnica para limpeza de superfícies por meio de equipamento de limpeza a alta pressão sob utilização de água eletrolizada com radicais oxidativos. |
CA2700868A CA2700868A1 (en) | 2007-09-25 | 2008-09-23 | Disinfection using a high-pressure cleaning device and hydrolyzed water |
US12/679,880 US20100192987A1 (en) | 2007-09-25 | 2008-09-23 | Method and technical embodiment for the cleaning of surfaces by means of a high-pressure cleaning device using electrolyzed water by using oxidative free radicals |
AU2008302995A AU2008302995A1 (en) | 2007-09-25 | 2008-09-23 | Disinfection using a high-pressure cleaning device and hydrolyzed water |
CN2008801085599A CN102056632A (zh) | 2007-09-25 | 2008-09-23 | 用高压清洁器和经水解的水进行消毒 |
EP08800439A EP2192929A1 (de) | 2007-09-25 | 2008-09-23 | Desinfektion mit hochdruckreiniger und hydrolysiertem wasser |
ZA2010/02877A ZA201002877B (en) | 2007-09-25 | 2010-04-23 | Disinfection using a high-pressure cleaning device and hydrolyzed water |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH1483/07 | 2007-09-25 | ||
CH01483/07A CH704952B1 (de) | 2007-09-25 | 2007-09-25 | Verfahren und technische Ausführung zur Reinigung von Oberflächen, mittels eines Hochdruck-Reinigungs-Gerätes unter Verwendung von elektrolysiertem kaltem oder warmem Wasser mit Oxidativen Radikalen. |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009039674A1 true WO2009039674A1 (de) | 2009-04-02 |
Family
ID=40276000
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CH2008/000393 WO2009039674A1 (de) | 2007-09-25 | 2008-09-23 | Desinfektion mit hochdruckreiniger und hydrolysiertem wasser |
Country Status (10)
Country | Link |
---|---|
US (1) | US20100192987A1 (de) |
EP (1) | EP2192929A1 (de) |
CN (1) | CN102056632A (de) |
AU (1) | AU2008302995A1 (de) |
BR (1) | BRPI0817975A2 (de) |
CA (1) | CA2700868A1 (de) |
CH (1) | CH704952B1 (de) |
NZ (1) | NZ584139A (de) |
WO (1) | WO2009039674A1 (de) |
ZA (1) | ZA201002877B (de) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7891046B2 (en) | 2006-02-10 | 2011-02-22 | Tennant Company | Apparatus for generating sparged, electrochemically activated liquid |
US8007654B2 (en) | 2006-02-10 | 2011-08-30 | Tennant Company | Electrochemically activated anolyte and catholyte liquid |
US8012339B2 (en) | 2006-02-10 | 2011-09-06 | Tennant Company | Hand-held spray bottle having an electrolyzer and method therefor |
US8012340B2 (en) | 2006-02-10 | 2011-09-06 | Tennant Company | Method for generating electrochemically activated cleaning liquid |
US8016996B2 (en) | 2006-02-10 | 2011-09-13 | Tennant Company | Method of producing a sparged cleaning liquid onboard a mobile surface cleaner |
US8025786B2 (en) | 2006-02-10 | 2011-09-27 | Tennant Company | Method of generating sparged, electrochemically activated liquid |
US8025787B2 (en) | 2006-02-10 | 2011-09-27 | Tennant Company | Method and apparatus for generating, applying and neutralizing an electrochemically activated liquid |
US8046867B2 (en) | 2006-02-10 | 2011-11-01 | Tennant Company | Mobile surface cleaner having a sparging device |
US8236147B2 (en) | 2008-06-19 | 2012-08-07 | Tennant Company | Tubular electrolysis cell and corresponding method |
US8319654B2 (en) | 2008-06-19 | 2012-11-27 | Tennant Company | Apparatus having electrolysis cell and indicator light illuminating through liquid |
US8337690B2 (en) | 2007-10-04 | 2012-12-25 | Tennant Company | Method and apparatus for neutralizing electrochemically activated liquids |
US8485140B2 (en) | 2008-06-05 | 2013-07-16 | Global Patent Investment Group, LLC | Fuel combustion method and system |
DE102012105961A1 (de) | 2012-07-04 | 2014-01-09 | Vorwerk & Co. Interholding Gmbh | Spendegerät und Verfahren zur Reinigung mittels einer eine Ionenkonzentration aufweisenden Reinigungsflüssigkeit |
US9162904B2 (en) | 2011-03-04 | 2015-10-20 | Tennant Company | Cleaning solution generator |
DE102015112466A1 (de) | 2015-07-30 | 2017-02-02 | Alfred Kärcher Gmbh & Co. Kg | Bodenreinigungsmaschine und Verfahren zum Betreiben einer Bodenreinigungsmaschine |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2291246A2 (de) * | 2008-06-10 | 2011-03-09 | Tennant Company | Elektrolysierte flüssigkeit verwendender dampfreiniger und verfahren dafür |
US20090311137A1 (en) * | 2008-06-11 | 2009-12-17 | Tennant Company | Atomizer using electrolyzed liquid and method therefor |
US20100089419A1 (en) * | 2008-09-02 | 2010-04-15 | Tennant Company | Electrochemically-activated liquid for cosmetic removal |
US20100147700A1 (en) * | 2008-12-17 | 2010-06-17 | Tennant Company | Method and apparatus for applying electrical charge through a liquid having enhanced suspension properties |
US20110219555A1 (en) * | 2010-03-10 | 2011-09-15 | Tennant Company | Cleaning head and mobile floor cleaner |
CN103987664B (zh) | 2011-12-06 | 2017-03-08 | 德尔塔阀门公司 | 龙头中的臭氧分配 |
AT512689A1 (de) * | 2012-03-29 | 2013-10-15 | Pro Aqua Diamantelektroden Produktion Gmbh & Co Kg | Flüssigkeit auf der Basis von Wasser zur Verwendung als Reinigungs- und/oder Desinfektionsmittel, Substanz zur Auflösung in Wasser zur Herstellung eines Reinigungs- und/oder Desinfektionsmittels und Verfahren zur Herstellung eines Reinigungs- und/oder Desinfektionsmittels |
GB2533281B (en) * | 2014-12-09 | 2019-08-28 | Ozo Innovations Ltd | Electrolyzed water composition |
WO2017011506A1 (en) | 2015-07-13 | 2017-01-19 | Delta Faucet Company | Electrode for an ozone generator |
US9792748B2 (en) | 2015-10-06 | 2017-10-17 | Alfonso Campalans | Neutral atmosphere and sanitization storage apparatus, method and system |
CA2946465C (en) | 2015-11-12 | 2022-03-29 | Delta Faucet Company | Ozone generator for a faucet |
CA3007437C (en) | 2015-12-21 | 2021-09-28 | Delta Faucet Company | Fluid delivery system including a disinfectant device |
US10757944B2 (en) | 2016-04-26 | 2020-09-01 | WillowPure, LLC | Ozone treatment for elimination of pathogens |
US9986753B2 (en) | 2016-10-06 | 2018-06-05 | Alfonso Campalans | Quad apparatus, method and system |
US10143763B2 (en) | 2016-10-06 | 2018-12-04 | Alfonso Campalans | Neutral atmosphere and sanitization storage apparatus, method and system |
EP3323380B1 (de) * | 2016-11-18 | 2020-01-08 | Markus Schlee | Behandlungssystem zur reinigung eines mit biofilmverunreinigten bauteils, insbesondere eines implantat-teils |
CN107549195A (zh) * | 2017-10-10 | 2018-01-09 | 南通市新丝路蚕业有限公司 | 一种用于蚕室消毒的电解氧化水及其消毒方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3819329A (en) * | 1971-05-11 | 1974-06-25 | Morton Norwich Products Inc | Spray sanitizing system with electrolytic generator |
ZA996573B (en) * | 1998-10-23 | 2000-04-19 | Radcial Waters Ip Pty Ltd | The treatment of Bio-Film on ocean-based seismographic equipment. |
US20020032141A1 (en) * | 2000-09-08 | 2002-03-14 | Gene Harkins | System and method to clean and disinfect hard surfaces using electrolyzed acidic water produced from a solution of NaCl |
US20030062267A1 (en) * | 2001-05-25 | 2003-04-03 | Shinichi Nakamura | Method for generating sterilizing wash water and a portable apparatus thereof |
US20070186957A1 (en) * | 2006-02-10 | 2007-08-16 | Tennant Company | Method and apparatus for producing humanly-perceptable indicator of electrochemical properties of an output cleaning liquid |
WO2007117351A2 (en) * | 2006-02-10 | 2007-10-18 | Tennant Company | Mobile surface cleaner having a sparging device, and method of producing a sparged cleaning liquid onboard a mobile surface cleaner |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE339390T1 (de) * | 2003-04-15 | 2006-10-15 | Permelec Electrode Ltd | Diamantelektrode für die elektrolyse |
-
2007
- 2007-09-25 CH CH01483/07A patent/CH704952B1/de not_active IP Right Cessation
-
2008
- 2008-09-23 NZ NZ584139A patent/NZ584139A/en not_active IP Right Cessation
- 2008-09-23 WO PCT/CH2008/000393 patent/WO2009039674A1/de active Application Filing
- 2008-09-23 US US12/679,880 patent/US20100192987A1/en not_active Abandoned
- 2008-09-23 CA CA2700868A patent/CA2700868A1/en not_active Abandoned
- 2008-09-23 EP EP08800439A patent/EP2192929A1/de not_active Withdrawn
- 2008-09-23 CN CN2008801085599A patent/CN102056632A/zh active Pending
- 2008-09-23 AU AU2008302995A patent/AU2008302995A1/en not_active Abandoned
- 2008-09-23 BR BRPI0817975-1A2A patent/BRPI0817975A2/pt not_active Application Discontinuation
-
2010
- 2010-04-23 ZA ZA2010/02877A patent/ZA201002877B/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3819329A (en) * | 1971-05-11 | 1974-06-25 | Morton Norwich Products Inc | Spray sanitizing system with electrolytic generator |
ZA996573B (en) * | 1998-10-23 | 2000-04-19 | Radcial Waters Ip Pty Ltd | The treatment of Bio-Film on ocean-based seismographic equipment. |
US20020032141A1 (en) * | 2000-09-08 | 2002-03-14 | Gene Harkins | System and method to clean and disinfect hard surfaces using electrolyzed acidic water produced from a solution of NaCl |
US20030062267A1 (en) * | 2001-05-25 | 2003-04-03 | Shinichi Nakamura | Method for generating sterilizing wash water and a portable apparatus thereof |
US20070186957A1 (en) * | 2006-02-10 | 2007-08-16 | Tennant Company | Method and apparatus for producing humanly-perceptable indicator of electrochemical properties of an output cleaning liquid |
WO2007117351A2 (en) * | 2006-02-10 | 2007-10-18 | Tennant Company | Mobile surface cleaner having a sparging device, and method of producing a sparged cleaning liquid onboard a mobile surface cleaner |
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8156608B2 (en) | 2006-02-10 | 2012-04-17 | Tennant Company | Cleaning apparatus having a functional generator for producing electrochemically activated cleaning liquid |
US8603320B2 (en) | 2006-02-10 | 2013-12-10 | Tennant Company | Mobile surface cleaner and method for generating and applying an electrochemically activated sanitizing liquid having O3 molecules |
US7891046B2 (en) | 2006-02-10 | 2011-02-22 | Tennant Company | Apparatus for generating sparged, electrochemically activated liquid |
US8012340B2 (en) | 2006-02-10 | 2011-09-06 | Tennant Company | Method for generating electrochemically activated cleaning liquid |
US8016996B2 (en) | 2006-02-10 | 2011-09-13 | Tennant Company | Method of producing a sparged cleaning liquid onboard a mobile surface cleaner |
US8025786B2 (en) | 2006-02-10 | 2011-09-27 | Tennant Company | Method of generating sparged, electrochemically activated liquid |
US8025787B2 (en) | 2006-02-10 | 2011-09-27 | Tennant Company | Method and apparatus for generating, applying and neutralizing an electrochemically activated liquid |
US8046867B2 (en) | 2006-02-10 | 2011-11-01 | Tennant Company | Mobile surface cleaner having a sparging device |
US8012339B2 (en) | 2006-02-10 | 2011-09-06 | Tennant Company | Hand-held spray bottle having an electrolyzer and method therefor |
US8719999B2 (en) | 2006-02-10 | 2014-05-13 | Tennant Company | Method and apparatus for cleaning surfaces with high pressure electrolyzed fluid |
US8007654B2 (en) | 2006-02-10 | 2011-08-30 | Tennant Company | Electrochemically activated anolyte and catholyte liquid |
US8337690B2 (en) | 2007-10-04 | 2012-12-25 | Tennant Company | Method and apparatus for neutralizing electrochemically activated liquids |
US8485140B2 (en) | 2008-06-05 | 2013-07-16 | Global Patent Investment Group, LLC | Fuel combustion method and system |
US8319654B2 (en) | 2008-06-19 | 2012-11-27 | Tennant Company | Apparatus having electrolysis cell and indicator light illuminating through liquid |
US8236147B2 (en) | 2008-06-19 | 2012-08-07 | Tennant Company | Tubular electrolysis cell and corresponding method |
US9162904B2 (en) | 2011-03-04 | 2015-10-20 | Tennant Company | Cleaning solution generator |
DE102012105961A1 (de) | 2012-07-04 | 2014-01-09 | Vorwerk & Co. Interholding Gmbh | Spendegerät und Verfahren zur Reinigung mittels einer eine Ionenkonzentration aufweisenden Reinigungsflüssigkeit |
DE102015112466B4 (de) | 2015-07-30 | 2022-08-11 | Alfred Kärcher SE & Co. KG | Bodenreinigungsmaschine und Verfahren zum Betreiben einer Bodenreinigungsmaschine |
DE102015112466A1 (de) | 2015-07-30 | 2017-02-02 | Alfred Kärcher Gmbh & Co. Kg | Bodenreinigungsmaschine und Verfahren zum Betreiben einer Bodenreinigungsmaschine |
Also Published As
Publication number | Publication date |
---|---|
AU2008302995A1 (en) | 2009-04-02 |
CN102056632A (zh) | 2011-05-11 |
US20100192987A1 (en) | 2010-08-05 |
CA2700868A1 (en) | 2009-04-02 |
ZA201002877B (en) | 2011-07-27 |
BRPI0817975A2 (pt) | 2014-10-14 |
EP2192929A1 (de) | 2010-06-09 |
NZ584139A (en) | 2011-08-26 |
CH704952B1 (de) | 2012-11-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2009039674A1 (de) | Desinfektion mit hochdruckreiniger und hydrolysiertem wasser | |
EP2219684B1 (de) | Vorrichtung zur reinigung von boden-oberflächen mit elektrolysiertem wasser mittels oxidativer radikale, erzeugt durch diamant-elektroden | |
EP2214723A2 (de) | Desinfektion von händen, körperteilen und agrarprodukten mit elektrolysiertem wasser und elektrostatischer düse | |
EP2152324B1 (de) | Pflanzenschutzverfahren und -vorrichtung zur kontrolle und elimination von pflanzenschädlingen mittels elektrolytisch hergestellten oxidativen radikalen, uvc-licht, und luft unterstützter elektrostatischer sprühtechnologie | |
US20040037737A1 (en) | Method of and equipment for washing, disinfecting and/or sterilizing health care devices | |
RU2602110C2 (ru) | Способ и устройство для очистки воды | |
WO2013166614A2 (de) | Systemisches pflanzenschutz-verfahren zur kontrolle von mykosen, bakteriosen und virosen mittels injektor-technologie und neutralem elektrolysierten mineralwasser als biozid | |
CN103435131B (zh) | 一种制取酸性电解水的装置 | |
CN206127025U (zh) | 净水器 | |
US20140302168A1 (en) | Microbiocidal Solution with Ozone and Methods | |
DE19717579A1 (de) | Verfahren zum Bereitstellen von desinfiziertem Wasser in einem Vorratstank | |
CN205873972U (zh) | 酸性氧化电位水生成器 | |
CN101638262A (zh) | 酸性氧化电位水的生产工艺及瓶装 | |
CN113215596B (zh) | 一种适用于工业化生产次氯酸消毒水的系统 | |
DE202011105738U1 (de) | Online-Desinfektion mittels Diamant-Elektrolyse von Dialyse-Geräten | |
EP1380543A1 (de) | Wasseraufbereitungsanlage zur Erzeugung von trinkbarem Wasser | |
CN2892883Y (zh) | 一种农用电解水发生装置 | |
JP3535451B2 (ja) | 硫酸イオンを含む酸性水及び硫酸イオンを含むアルカリ水の製造方法、硫酸イオンを含む酸性水及び硫酸イオンを含むアルカリ水の製造装置、硫酸イオンを含む酸性水及び硫酸イオンを含むアルカリ水 | |
CH704481A2 (de) | Batteriebetriebenes Handsprühgerät mit integrierter Elektrolysezelle mit Volldiamant-Elektroden zur Produktion von Neutralem Elektrolysewasser zur Reinigung und Desinfektion von Oberflächen. | |
DE102010044315B4 (de) | Elektrolysezelle in kompakter Form | |
CH703701A2 (de) | Kulturverfahren für Sprossen, Baby Leafs und Meristem-Kulturen im sterilen Kulturraum auf Netz mittels Brumisation mit Elektrolysewasser, gelösten Nährstoffen und Kunstlicht. | |
KR20190005554A (ko) | 아연전극을 이용한 저농도 과산화수소 수용액에 의한 살균 및 탈취장치 | |
CH710413A2 (de) | Verfahren und Gerät zur verbesserten sterilen Blatt-Düngung von Pflanzen mit Nährstoffen enthaltendem, mikroclusterisiertem Wasser, hergestellt mittels Bor-dotierter Diamant-Elektroden-Elektrolyse. | |
CN104094970A (zh) | 一种即用型次氯酸钠复合消毒剂的配制方法 | |
CN212609730U (zh) | 电解盐氯消毒系统 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200880108559.9 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 08800439 Country of ref document: EP Kind code of ref document: A1 |
|
DPE1 | Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101) | ||
DPE1 | Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101) | ||
WWE | Wipo information: entry into national phase |
Ref document number: 584139 Country of ref document: NZ |
|
WWE | Wipo information: entry into national phase |
Ref document number: 12679880 Country of ref document: US |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2700868 Country of ref document: CA Ref document number: 2096/DELNP/2010 Country of ref document: IN |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008800439 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008302995 Country of ref document: AU |
|
ENP | Entry into the national phase |
Ref document number: 2008302995 Country of ref document: AU Date of ref document: 20080923 Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: PI0817975 Country of ref document: BR Kind code of ref document: A2 Effective date: 20100325 |