WO2009028280A1 - ピラゾールカルボン酸誘導体及びその製造方法、並びに殺菌剤 - Google Patents

ピラゾールカルボン酸誘導体及びその製造方法、並びに殺菌剤 Download PDF

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WO2009028280A1
WO2009028280A1 PCT/JP2008/063278 JP2008063278W WO2009028280A1 WO 2009028280 A1 WO2009028280 A1 WO 2009028280A1 JP 2008063278 W JP2008063278 W JP 2008063278W WO 2009028280 A1 WO2009028280 A1 WO 2009028280A1
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carbon atoms
alkyl group
bactericide
acid derivative
pyrazolecarboxylic acid
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PCT/JP2008/063278
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English (en)
French (fr)
Inventor
Yutaka Chiba
Toshiyuki Kouno
Chie Shibata
Naofumi Tomura
Tomohisa Akase
Shinichi Banba
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Mitsui Chemicals, Inc.
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Priority to JP2009530023A priority Critical patent/JPWO2009028280A1/ja
Priority to ARP080103727A priority patent/AR068115A1/es
Priority to CL2008002554A priority patent/CL2008002554A1/es
Publication of WO2009028280A1 publication Critical patent/WO2009028280A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/20—N-Aryl derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/16—Halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18—One oxygen or sulfur atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D473/00—Heterocyclic compounds containing purine ring systems
    • C07D473/26—Heterocyclic compounds containing purine ring systems with an oxygen, sulphur, or nitrogen atom directly attached in position 2 or 6, but not in both
    • C07D473/32—Nitrogen atom
    • C07D473/34—Nitrogen atom attached in position 6, e.g. adenine

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

　植物病害防除作用を示すとともに有用作物に対し何ら害を及ぼさないか、またはきわめて害が少ない殺菌剤を提供する。本発明の殺菌剤は、下記一般式（１）で表されるピラゾールカルボン酸誘導体を有効成分として含有する。 ［式中、Ｒ１はアルキル基等を表し、Ｒ２およびＲ３はそれぞれ独立して水素原子、ハロアルキル基等を表す（ただし、Ｒ２およびＲ３の少なくとも１つは炭素数１～６のハロアルキル基である）。Ａは、－ＯＲ４、－ＳＲ５、－ＮＲ６Ｒ７または－ＮＲ８ＮＲ９Ｒ１０を表し、Ｒ４は炭素数３～１２のアルキル基等を、Ｒ５は炭素数１～１２のアルキル基等を、Ｒ６は水素原子等を、Ｒ７は炭素数５～１２のアルキル基等を、Ｒ８、Ｒ９およびＲ１０は炭素数１～１２のアルキル基等をそれぞれ表す。]
PCT/JP2008/063278 2007-08-29 2008-07-24 ピラゾールカルボン酸誘導体及びその製造方法、並びに殺菌剤 WO2009028280A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2009530023A JPWO2009028280A1 (ja) 2007-08-29 2008-07-24 ピラゾールカルボン酸誘導体及びその製造方法、並びに殺菌剤
ARP080103727A AR068115A1 (es) 2007-08-29 2008-08-27 Derivado del acido pirazolcarboxilico metodo de produccion del mismo y fungicida
CL2008002554A CL2008002554A1 (es) 2007-08-29 2008-08-29 Compuestos derivados de pirazol; metodo de produccion de dichos compuestos; y uso de un fungicida que contiene al menos uno de dichos compuestos

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JP2007222384 2007-08-29
JP2007-222384 2007-08-29

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AR (1) AR068115A1 (ja)
CL (1) CL2008002554A1 (ja)
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2253617A1 (de) 2009-05-20 2010-11-24 Bayer CropScience AG Halogen-substituierte Verbindungen als Pestizide
WO2013014204A3 (en) * 2011-07-26 2013-04-04 Sanofi 3-heteroaroylamino-propionic acid derivatives and their use as pharmaceuticals
EP2633756A1 (en) 2012-02-29 2013-09-04 Meiji Seika Pharma Co., Ltd. Pest control composition including novel iminopyridine derivate
WO2014119696A1 (ja) * 2013-01-30 2014-08-07 住友化学株式会社 有害節足動物の防除方法
CN104045634A (zh) * 2014-06-06 2014-09-17 浙江工业大学 含二氟甲基吡唑甲酰胺类化合物及其制备方法和用途
US8987470B2 (en) 2010-10-27 2015-03-24 Solvay Sa Process for the preparation of pyrazole-4-carboxamides
JP2015131789A (ja) * 2013-01-30 2015-07-23 住友化学株式会社 アミド化合物及びその有害節足動物防除用途
CN105601618A (zh) * 2016-01-11 2016-05-25 天津医科大学 芳香族酰亚胺类化合物及其制备方法与应用
US20170015631A1 (en) * 2012-10-16 2017-01-19 Tolero Pharmaceuticals, Inc. Pkm2 modulators and methods for their use
WO2020198067A1 (en) * 2019-03-22 2020-10-01 Sumitomo Dainippon Pharma Oncology, Inc. Pkm2 modulators and methods for their use
US11712433B2 (en) 2019-03-22 2023-08-01 Sumitomo Pharma Oncology, Inc. Compositions comprising PKM2 modulators and methods of treatment using the same
WO2024204842A1 (ja) * 2023-03-31 2024-10-03 日産化学株式会社 ピラゾール化合物及び有害生物防除剤

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0253775A (ja) * 1988-08-18 1990-02-22 Nissan Chem Ind Ltd ピラゾールカルボキサミド誘導体及び除草剤
JPH02129171A (ja) * 1988-11-08 1990-05-17 Nissan Chem Ind Ltd ピラゾールカルボキサニリド誘導体及び有害生物防除剤
JPH09176124A (ja) * 1995-12-25 1997-07-08 Nissan Chem Ind Ltd ピラゾリン誘導体および植物病害防除剤
JPH09176125A (ja) * 1995-05-31 1997-07-08 Nissan Chem Ind Ltd ５−ピラゾールカルボン酸アミド誘導体および植物病害防除剤
WO2002083647A1 (fr) * 2001-04-06 2002-10-24 Nihon Nohyaku Co., Ltd. Derive de pyrazole-carboxymide, produit intermediaire pour ce derive et agent antiparasitaire contenant ce derive en tant qu'ingredient actif

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0253775A (ja) * 1988-08-18 1990-02-22 Nissan Chem Ind Ltd ピラゾールカルボキサミド誘導体及び除草剤
JPH02129171A (ja) * 1988-11-08 1990-05-17 Nissan Chem Ind Ltd ピラゾールカルボキサニリド誘導体及び有害生物防除剤
JPH09176125A (ja) * 1995-05-31 1997-07-08 Nissan Chem Ind Ltd ５−ピラゾールカルボン酸アミド誘導体および植物病害防除剤
JPH09176124A (ja) * 1995-12-25 1997-07-08 Nissan Chem Ind Ltd ピラゾリン誘導体および植物病害防除剤
WO2002083647A1 (fr) * 2001-04-06 2002-10-24 Nihon Nohyaku Co., Ltd. Derive de pyrazole-carboxymide, produit intermediaire pour ce derive et agent antiparasitaire contenant ce derive en tant qu'ingredient actif

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2253617A1 (de) 2009-05-20 2010-11-24 Bayer CropScience AG Halogen-substituierte Verbindungen als Pestizide
US8987470B2 (en) 2010-10-27 2015-03-24 Solvay Sa Process for the preparation of pyrazole-4-carboxamides
US9751858B2 (en) 2011-07-26 2017-09-05 Sanofi 3-heteroaroylamino-propionic acid derivatives and their use as pharmaceuticals
WO2013014204A3 (en) * 2011-07-26 2013-04-04 Sanofi 3-heteroaroylamino-propionic acid derivatives and their use as pharmaceuticals
US9353068B2 (en) 2011-07-26 2016-05-31 Sanofi 3-heteroaroylamino-propionic acid derivatives and their use as pharmaceuticals
EP3037417A3 (en) * 2011-07-26 2016-10-12 Sanofi 3-heteroaroylamino-propionic acid derivatives and their use as pharmaceuticals
EP2633756A1 (en) 2012-02-29 2013-09-04 Meiji Seika Pharma Co., Ltd. Pest control composition including novel iminopyridine derivate
WO2013129688A1 (en) 2012-02-29 2013-09-06 Meiji Seika Pharma Co., Ltd. Pest control composition including novel iminopyridine derivative
US11771086B2 (en) 2012-02-29 2023-10-03 Mmag Co., Ltd. Pest control composition including novel iminopyridine derivative
US10736319B2 (en) 2012-02-29 2020-08-11 Meiji Seika Pharma Co., Ltd. Pest control composition including novel iminopyridine derivative
US10349655B2 (en) 2012-02-29 2019-07-16 Meiji Seika Pharma Co., Ltd. Pest control composition including novel iminopyridine derivative
US10472328B2 (en) 2012-10-16 2019-11-12 Tolero Pharmaceuticals, Inc. PKM2 modulators and methods for their use
US10766865B2 (en) 2012-10-16 2020-09-08 Sumitomo Dainippon Pharma Oncology, Inc. PKM2 modulators and methods for their use
US20170015631A1 (en) * 2012-10-16 2017-01-19 Tolero Pharmaceuticals, Inc. Pkm2 modulators and methods for their use
US10207996B2 (en) * 2012-10-16 2019-02-19 Tolero Pharmaceuticals, Inc. PKM2 modulators and methods for their use
US9814235B2 (en) 2013-01-30 2017-11-14 Sumitomo Chemical Company, Limited Method for controlling arthropod pest
CN104955332B (zh) * 2013-01-30 2017-03-29 住友化学株式会社 防治节足害虫的方法
WO2014119696A1 (ja) * 2013-01-30 2014-08-07 住友化学株式会社 有害節足動物の防除方法
JP2015131789A (ja) * 2013-01-30 2015-07-23 住友化学株式会社 アミド化合物及びその有害節足動物防除用途
CN104045634A (zh) * 2014-06-06 2014-09-17 浙江工业大学 含二氟甲基吡唑甲酰胺类化合物及其制备方法和用途
CN105601618B (zh) * 2016-01-11 2018-04-27 天津医科大学 芳香族酰亚胺类化合物及其制备方法与应用
CN105601618A (zh) * 2016-01-11 2016-05-25 天津医科大学 芳香族酰亚胺类化合物及其制备方法与应用
WO2020198067A1 (en) * 2019-03-22 2020-10-01 Sumitomo Dainippon Pharma Oncology, Inc. Pkm2 modulators and methods for their use
US11712433B2 (en) 2019-03-22 2023-08-01 Sumitomo Pharma Oncology, Inc. Compositions comprising PKM2 modulators and methods of treatment using the same
WO2024204842A1 (ja) * 2023-03-31 2024-10-03 日産化学株式会社 ピラゾール化合物及び有害生物防除剤

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AR068115A1 (es) 2009-11-04
CL2008002554A1 (es) 2009-01-16
JPWO2009028280A1 (ja) 2010-11-25
JP2009073823A (ja) 2009-04-09
TW200916444A (en) 2009-04-16

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