WO2009024826A1 - Production d'agrégats secondaires - Google Patents
Production d'agrégats secondaires Download PDFInfo
- Publication number
- WO2009024826A1 WO2009024826A1 PCT/GB2008/050733 GB2008050733W WO2009024826A1 WO 2009024826 A1 WO2009024826 A1 WO 2009024826A1 GB 2008050733 W GB2008050733 W GB 2008050733W WO 2009024826 A1 WO2009024826 A1 WO 2009024826A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- process according
- carbon dioxide
- waste
- materials
- tumbling
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 58
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 29
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 24
- 239000002699 waste material Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000010814 metallic waste Substances 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 8
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims abstract description 4
- 239000007771 core particle Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 30
- 239000011230 binding agent Substances 0.000 claims description 13
- 239000011398 Portland cement Substances 0.000 claims description 9
- 229910001570 bauxite Inorganic materials 0.000 claims description 5
- 239000004568 cement Substances 0.000 claims description 5
- 238000005520 cutting process Methods 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000003723 Smelting Methods 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000000428 dust Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 6
- 239000002184 metal Substances 0.000 abstract description 6
- 238000012545 processing Methods 0.000 abstract description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 239000007795 chemical reaction product Substances 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 abstract description 4
- 238000000605 extraction Methods 0.000 abstract description 2
- 238000010952 in-situ formation Methods 0.000 abstract description 2
- 238000011068 loading method Methods 0.000 abstract description 2
- 150000002736 metal compounds Chemical class 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 239000007858 starting material Substances 0.000 abstract description 2
- -1 and if necessary Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000010804 inert waste Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229940043430 calcium compound Drugs 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011396 hydraulic cement Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000004137 mechanical activation Methods 0.000 description 1
- 239000010852 non-hazardous waste Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/021—Agglomerated materials, e.g. artificial aggregates agglomerated by a mineral binder, e.g. cement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/20—Agglomeration, binding or encapsulation of solid waste
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/20—Agglomeration, binding or encapsulation of solid waste
- B09B3/25—Agglomeration, binding or encapsulation of solid waste using mineral binders or matrix
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Definitions
- This invention relates to the production of secondary aggregates by combined carbonation and tumbling of wastes and residues from metal processing and metal extraction, referred to herein in general terms as 'metallic wastes'.
- the commercially available product Aardelite is manufactured using the pozzolanic properties of residues such as fly-ash.
- a binder for example lime, and processing at a temperature of 90° C, the silica and alumina in the residue are transformed into cementitious minerals.
- the present invention is based on the finding that secondary aggregates can be prepared from metallic wastes, using a combination of accelerated carbonation and tumbling, such that aggregate particles composed of successive layers of solid carbonate-based reaction products form a hard aggregate suitable for use in concrete after only minutes of exposure to carbon dioxide.
- the present invention provides a process for the preparation of aggregates useful in the manufacture of concrete, comprising tumbling C ⁇ 2 -reactive i.e. carbonatable, metallic wastes, or metallic wastes and a C ⁇ 2 -reactive i.e. carbonatable, binder in the presence of moisture and carbon dioxide, such that the carbonatable materials and the carbon dioxide react as the tumbling proceeds to form successive layers of hardened carbonates around core particles.
- further waste and/or binder is added to the system until the aggregate reaches a size which is suitable for its intended use, for example, aggregate for use in preparation of concrete, or aggregate used in road-making.
- a useful carbonatable binder is ordinary Portland cement (OPC).
- the process may be operated by tumbling single loads, or by batchwise addition of materials during the tumbling process, or by continuous feeding of carbonatable materials with continuous removal of aggregated product.
- Figure 1 is a photograph showing untreated bauxite (left); and bauxite which has been tumbled with OPC and carbonated (right);
- Figure 2 is a photograph showing untreated lead-contaminated waste (left); and lead- contaminated waste which has been tumbled with OPC and carbonated (right);
- Figure 3 is a photograph showing untreated oil-drill cuttings (left); and oil-drill cuttings which have been tumbled with OPC and carbonated (right).
- the present invention is a departure from the mixing required to implement the carbonation process of US Patent 5,997,629, in that it involves a tumbling action, typically by use of a rotating drum or tray.
- the mixture when materials that are susceptible to accelerated carbonation are mixed with inert wastes/fines such as quarry or washing fines, the mixture is hardened in a CO 2 -rich gaseous environment, but in a way such that a series of successive layers of hardened material are formed (by the tumbling action) to produce a hard aggregated product, suitable as a replacement for stone, or sintered aggregate in, for example, concrete articles.
- Metallic wastes usable in the invention include metal ore residues, such as bauxite, metal processing wastes, such as aluminium smelting residue (red mud), lead- contaminated waste, iron foundry/steel waste and zinc smelter waste, and oil-drill cuttings.
- metal ore residues such as bauxite
- metal processing wastes such as aluminium smelting residue (red mud), lead- contaminated waste, iron foundry/steel waste and zinc smelter waste, and oil-drill cuttings.
- Carbonatable binders that may be used in this process include cement kiln dust and Portland cement, and CO 2 reactive materials such as quicklime, combustion ashes containing free lime and calcium silicate, or magnesium based minerals.
- Portland cement that is deemed "out-of-date" for concrete manufacture may be used in this invention.
- the residues suitably contain calcium or magnesium compounds, although carbonation can also occur with other metal compounds such as iron compounds.
- Residues containing carbonatable materials may also be supplemented with carbonatable binders, such as OPC, which may be essential if a carbonatable component is absent or minimal in the residue.
- water is added to achieve a weight ratio to solids of not more than 0.5:1 , possibly not more than 0.4:1 or 0.3:1.
- the water to solids ratio is at least 0.01 :1 typically at least 0.1 or 0.2:1.
- the water to solids ratio may be assessed as an overall value for the process. In a continuous process the indicated water to solids ratio is preferably observed for the feed materials throughout the process. Also, in a batchwise process the indicated water to solids ratio is preferably observed for each batch of material added to the tumbler while building up a layer structure for the aggregate.
- the process of the invention is carried out in an atmosphere that has a carbon dioxide content greater than that of natural air, for example containing at least 20%, 30% or 40% by weight carbon dioxide.
- carbon dioxide is the predominant component of the tumbling atmosphere, that is at 50%, 60%, 70% or 80% by weight.
- the atmosphere substantially consists of carbon dioxide, that is at 90%, 95% or 99% by weight. Waste combustion gases with a high content of carbon dioxide may be suitable as the tumbling atmosphere.
- the carbonation step is preferably carried out at or around atmospheric pressure, or up to a pressure not exceeding 30 psi (2 bar).
- the use of a CO 2 atmosphere at higher pressure does not greatly advance the process and requires more complex apparatus.
- the tumbled materials are able to combine with CO 2 in the presence of moisture, at ambient temperature and pressure. It is not usually necessary or desirable to employ heating or cooling during the tumbling.
- the aggregate product does not retain hydraulic properties. Furthermore the product is preferably essentially non-hydrated in that the aggregate layers are formed by non-hydraulic hardening due to reaction with carbon dioxide.
- the carbon dioxide used may be supplied from conventional sources of liquid or pressurised carbon dioxide.
- CO 2 rich gases discharged or recycled from processes such as cement making, or as combustion waste gases may be used with the simultaneous environmental benefits of reducing greenhouse gas emissions.
- the process is carried out by loading the starting materials into a cylindrical drum that is rotatable about an axis that is horizontal or slightly inclined to the horizontal.
- the cylinder may be sealed at both ends so that its interior may be charged with a carbon dioxide atmosphere, or mounted within a larger vessel that holds a carbon dioxide atmosphere.
- the material resting at the lowest point of the cylinder begin to "climb" the cylinder wall and then tumble back to the lowest level under gravity. Aggregates are formed as coatings on core particles as the tumbling proceeds, and the coatings are hardened by in situ formation of carbonates by reaction with the carbon dioxide.
- the materials to be treated, and optionally water may be added to the drum as a single batch or in more than one portion.
- the load, or each portion is drummed until suitably hardened and, if necessary with addition of another portion, until the desired size is reached for use as an aggregate in concrete manufacture or, for example, as road-stone or gravel substitute.
- the load When the rotational axis is inclined to the horizontal, the load is able to pass down the incline during rotation.
- the angle of inclination and the length of the drum is selected so that the time of travel of a load added at the higher end of the drum is such that it is aggregated to a suitable size as it discharges from the lower end of the drum.
- the materials may be added as a single load, or more preferably as a continuous supply. This process may be carried out in a static CO 2 atmosphere or by circulating a CO 2 rich atmosphere through the drum.
- the process may be carried out using rotating pelletising pans or trays having a circular base and an upstanding peripheral wall around the circumference of the base.
- the base of the tray or pan may be horizontal, or inclined to the horizontal so that a tumbling action is imparted by the movement of the wall, as well as of the base.
- an intermediate scale plant may be based on a tumbler drum of 1.5m diameter x 4.0m length with its main axis at an inclination of 1 -5 degrees from the horizontal. Operating at 1-5 RPM and velocity of 0.08-0.4 m/s, it is anticipated that a continuous feed of 1000-5000 kg/hr is feasible with a process time of 10 to 30 minutes, depending on waste.
- Such an apparatus may be mounted on pairs of rollers or wheels, which support the drum while allowing it to rotate. The drum may be rotated by a motor which drives one or more of the support rollers or wheels.
- This pilot scale plant may be scaled up in conventional manner for larger throughputs on an industrial scale, for example around 100 tonnes/hour.
- the CU 2 -reactive component used may usefully be out-of-date Portland cement.
- cement-kiln dusts, flue dusts and slag can also be used in the process of the invention, in which aggregates are produced using a rotary drum mixer with a tumbling/rolling action charged with carbon dioxide with the internal pressure at around atmospheric.
- the product size range can vary between that of a granular soil-like material (millimetres in diameter) and pellets (millimetres to centimetres in diameter).
- Bauxite aluminium oxide
- Ordinary Portland Cement as an example of a carbonatable binder
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Civil Engineering (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
L'invention concerne des agrégats secondaires qui sont préparés à partir de déchets métalliques, tels que des déchets ou des résidus contenant des composés métalliques résultant d'une extraction de métal ou d'un traitement de métal, utilisant une combinaison de carbonatation accélérée et un culbutage, de telle sorte que des particules agrégées constituées par des couches successives de produits de réaction à base de carbonate solides forment un agrégat dur approprié pour une utilisation dans du béton. Le procédé peut être mis en œuvre par chargement des matériaux de départ, et, si nécessaire, d'eau, dans un tambour cylindrique qui peut tourner autour de son axe horizontal. L'intérieur est chargé d'une atmosphère de dioxyde de carbone, ou le tambour est monté à l'intérieur d'un récipient plus grand qui contient une atmosphère de dioxyde de carbone. Des agrégats sont formés sous la forme de revêtements sur des particules de cœur lorsque le culbutage est conduit, et les revêtements sont durcis par formation in-situ de carbonates par réaction avec le dioxyde de carbone.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0716360.3 | 2007-08-22 | ||
GB0716360A GB0716360D0 (en) | 2007-08-22 | 2007-08-22 | Production of secondary aggregates |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009024826A1 true WO2009024826A1 (fr) | 2009-02-26 |
Family
ID=38599069
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2008/050733 WO2009024826A1 (fr) | 2007-08-22 | 2008-08-21 | Production d'agrégats secondaires |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB0716360D0 (fr) |
WO (1) | WO2009024826A1 (fr) |
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2461622A (en) * | 2008-05-29 | 2010-01-13 | Calera Corp | Rocks and aggregate, and methods of making and using the same |
US7744761B2 (en) | 2007-06-28 | 2010-06-29 | Calera Corporation | Desalination methods and systems that include carbonate compound precipitation |
US7749476B2 (en) | 2007-12-28 | 2010-07-06 | Calera Corporation | Production of carbonate-containing compositions from material comprising metal silicates |
US7754169B2 (en) | 2007-12-28 | 2010-07-13 | Calera Corporation | Methods and systems for utilizing waste sources of metal oxides |
US7753618B2 (en) | 2007-06-28 | 2010-07-13 | Calera Corporation | Rocks and aggregate, and methods of making and using the same |
US7771684B2 (en) | 2008-09-30 | 2010-08-10 | Calera Corporation | CO2-sequestering formed building materials |
US7790012B2 (en) | 2008-12-23 | 2010-09-07 | Calera Corporation | Low energy electrochemical hydroxide system and method |
US7815880B2 (en) | 2008-09-30 | 2010-10-19 | Calera Corporation | Reduced-carbon footprint concrete compositions |
US7829053B2 (en) | 2008-10-31 | 2010-11-09 | Calera Corporation | Non-cementitious compositions comprising CO2 sequestering additives |
US7875163B2 (en) | 2008-07-16 | 2011-01-25 | Calera Corporation | Low energy 4-cell electrochemical system with carbon dioxide gas |
US7887694B2 (en) | 2007-12-28 | 2011-02-15 | Calera Corporation | Methods of sequestering CO2 |
WO2011020927A2 (fr) | 2009-08-21 | 2011-02-24 | Recoval Belgium | Procédé de traitement d'une matière granulaire alcaline apte à être carbonatée |
US7939336B2 (en) | 2008-09-30 | 2011-05-10 | Calera Corporation | Compositions and methods using substances containing carbon |
US7966250B2 (en) | 2008-09-11 | 2011-06-21 | Calera Corporation | CO2 commodity trading system and method |
US7993511B2 (en) | 2009-07-15 | 2011-08-09 | Calera Corporation | Electrochemical production of an alkaline solution using CO2 |
US7993500B2 (en) | 2008-07-16 | 2011-08-09 | Calera Corporation | Gas diffusion anode and CO2 cathode electrolyte system |
US8137444B2 (en) | 2009-03-10 | 2012-03-20 | Calera Corporation | Systems and methods for processing CO2 |
ITVE20110041A1 (it) * | 2011-05-31 | 2012-12-01 | Veneta Depuratori E Affini S Ve D A Soc | Procedimento di trattamento di ceneri pesanti o scorie in genere.- |
US8357270B2 (en) | 2008-07-16 | 2013-01-22 | Calera Corporation | CO2 utilization in electrochemical systems |
WO2013060870A1 (fr) | 2011-10-26 | 2013-05-02 | Carbstone Innovation | Procédé pour la production d'un article lié comprenant un matériau granulaire carbonaté moulé par pressage |
US8491858B2 (en) | 2009-03-02 | 2013-07-23 | Calera Corporation | Gas stream multi-pollutants control systems and methods |
EP2708520A1 (fr) * | 2012-09-14 | 2014-03-19 | Cemex Research Group AG | Procédé de fabrication de supplément et de carbonate de calcium à partir d'un agrégat de béton et dispositif de réalisation du procédé |
US8834688B2 (en) | 2009-02-10 | 2014-09-16 | Calera Corporation | Low-voltage alkaline production using hydrogen and electrocatalytic electrodes |
US8869477B2 (en) | 2008-09-30 | 2014-10-28 | Calera Corporation | Formed building materials |
US9133581B2 (en) | 2008-10-31 | 2015-09-15 | Calera Corporation | Non-cementitious compositions comprising vaterite and methods thereof |
US9260314B2 (en) | 2007-12-28 | 2016-02-16 | Calera Corporation | Methods and systems for utilizing waste sources of metal oxides |
WO2020260568A1 (fr) | 2019-06-26 | 2020-12-30 | Orbix Productions | Procédé de production d'un article compacté à liaison carbonate |
Citations (5)
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EP0367914A1 (fr) * | 1988-10-15 | 1990-05-16 | Hubert Eirich | Procédé pour la fabrication d'agglomérats resistant au lessivage |
FR2732910A1 (fr) * | 1995-04-13 | 1996-10-18 | Viafrance Sa | Procede de traitement des machefers d'incineration en vue de les valoriser |
WO1997013735A1 (fr) * | 1995-10-06 | 1997-04-17 | Imperial College Of Science, Technology & Medicine | Traitement de matieres dangereuses |
WO2002057008A1 (fr) * | 2001-01-17 | 2002-07-25 | Forkers Limited | Traitement d'un materiau solide avec un fluide |
WO2007096671A1 (fr) * | 2006-02-21 | 2007-08-30 | University Of Greenwich | Fabrication d'agregats secondaires |
-
2007
- 2007-08-22 GB GB0716360A patent/GB0716360D0/en not_active Ceased
-
2008
- 2008-08-21 WO PCT/GB2008/050733 patent/WO2009024826A1/fr active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0367914A1 (fr) * | 1988-10-15 | 1990-05-16 | Hubert Eirich | Procédé pour la fabrication d'agglomérats resistant au lessivage |
FR2732910A1 (fr) * | 1995-04-13 | 1996-10-18 | Viafrance Sa | Procede de traitement des machefers d'incineration en vue de les valoriser |
WO1997013735A1 (fr) * | 1995-10-06 | 1997-04-17 | Imperial College Of Science, Technology & Medicine | Traitement de matieres dangereuses |
WO2002057008A1 (fr) * | 2001-01-17 | 2002-07-25 | Forkers Limited | Traitement d'un materiau solide avec un fluide |
WO2007096671A1 (fr) * | 2006-02-21 | 2007-08-30 | University Of Greenwich | Fabrication d'agregats secondaires |
Cited By (41)
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US7914685B2 (en) | 2007-06-28 | 2011-03-29 | Calera Corporation | Rocks and aggregate, and methods of making and using the same |
US7744761B2 (en) | 2007-06-28 | 2010-06-29 | Calera Corporation | Desalination methods and systems that include carbonate compound precipitation |
US7931809B2 (en) | 2007-06-28 | 2011-04-26 | Calera Corporation | Desalination methods and systems that include carbonate compound precipitation |
US7753618B2 (en) | 2007-06-28 | 2010-07-13 | Calera Corporation | Rocks and aggregate, and methods of making and using the same |
US7887694B2 (en) | 2007-12-28 | 2011-02-15 | Calera Corporation | Methods of sequestering CO2 |
US7749476B2 (en) | 2007-12-28 | 2010-07-06 | Calera Corporation | Production of carbonate-containing compositions from material comprising metal silicates |
US7754169B2 (en) | 2007-12-28 | 2010-07-13 | Calera Corporation | Methods and systems for utilizing waste sources of metal oxides |
US8333944B2 (en) | 2007-12-28 | 2012-12-18 | Calera Corporation | Methods of sequestering CO2 |
US9260314B2 (en) | 2007-12-28 | 2016-02-16 | Calera Corporation | Methods and systems for utilizing waste sources of metal oxides |
GB2461622A (en) * | 2008-05-29 | 2010-01-13 | Calera Corp | Rocks and aggregate, and methods of making and using the same |
GB2461622B (en) * | 2008-05-29 | 2011-04-13 | Calera Corp | Rocks and aggregate, and methods of making and using the same |
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