WO2009004937A1 - Method for production of quaternary ammonium hydroxide - Google Patents

Method for production of quaternary ammonium hydroxide Download PDF

Info

Publication number
WO2009004937A1
WO2009004937A1 PCT/JP2008/061335 JP2008061335W WO2009004937A1 WO 2009004937 A1 WO2009004937 A1 WO 2009004937A1 JP 2008061335 W JP2008061335 W JP 2008061335W WO 2009004937 A1 WO2009004937 A1 WO 2009004937A1
Authority
WO
WIPO (PCT)
Prior art keywords
exchange membrane
anion exchange
quaternary ammonium
ammonium hydroxide
membrane
Prior art date
Application number
PCT/JP2008/061335
Other languages
French (fr)
Japanese (ja)
Inventor
Satoshi Kawada
Masayuki Kishino
Hiroyuki Morimoto
Hisahiko Iwamoto
Original Assignee
Tokuyama Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokuyama Corporation filed Critical Tokuyama Corporation
Priority to CN200880016713XA priority Critical patent/CN101680101B/en
Publication of WO2009004937A1 publication Critical patent/WO2009004937A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/24—Halogens or compounds thereof
    • C25B1/26—Chlorine; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/02—Process control or regulation
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms

Abstract

[PROBLEMS] To provide a method in which the deterioration of an anion exchange membrane within a short period can be prevented effectively, and which can produce highly pure quaternary ammonium hydroxide steadily for a long period without the need of replacing the membrane with new one. [MEANS FOR SOLVING PROBLEMS] Disclosed is a method for producing quaternary ammonium hydroxide by arranging an anion exchange membrane and a cation exchange membrane between electrodes and supplying an aqueous solution of a halogenated quaternary ammonium salt to a stock solution chamber facing the side of a cathode of the anion exchange membrane to carry out the electrolysis. In the method, a membrane comprising a base layer (31) and a surface layer (33) formed on one surface of the base layer (31) and having a high crosslinking density is used as the anion exchange membrane, and the anion exchange membrane is so arranged that the surface layer is positioned on the side of an anode (1) to carry out the electrolysis.
PCT/JP2008/061335 2007-07-05 2008-06-20 Method for production of quaternary ammonium hydroxide WO2009004937A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200880016713XA CN101680101B (en) 2007-07-05 2008-06-20 Method for production of quaternary ammonium hydroxide

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-177680 2007-07-05
JP2007177680A JP5100222B2 (en) 2007-07-05 2007-07-05 Method for producing quaternary ammonium hydroxide

Publications (1)

Publication Number Publication Date
WO2009004937A1 true WO2009004937A1 (en) 2009-01-08

Family

ID=40225986

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/061335 WO2009004937A1 (en) 2007-07-05 2008-06-20 Method for production of quaternary ammonium hydroxide

Country Status (5)

Country Link
JP (1) JP5100222B2 (en)
KR (1) KR20100029816A (en)
CN (1) CN101680101B (en)
TW (1) TW200912045A (en)
WO (1) WO2009004937A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024009599A1 (en) * 2022-07-08 2024-01-11 株式会社トクヤマ Electrolysis tank

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103526224B (en) * 2013-09-22 2016-03-09 镇江润晶高纯化工有限公司 A kind of continuous electrolysis prepares the method for high-purity tetraethyl ammonium hydroxide
JP2018057987A (en) 2015-02-19 2018-04-12 富士フイルム株式会社 Composite anion exchange membrane and manufacturing method therefor, ion exchange membrane module, and ion exchange device
JP6244599B2 (en) 2016-04-01 2017-12-13 三菱重工環境・化学エンジニアリング株式会社 Organic electrosynthesis apparatus and organic electrosynthesis method
CN106350832B (en) * 2016-08-26 2018-04-10 肯特催化材料股份有限公司 Molecular Sieves as Template agent high-purity hydrogen aoxidizes the preparation method of the hexamethonium C6 aqueous solution
CN107904618B (en) * 2017-09-06 2020-02-18 肯特催化材料股份有限公司 Method for preparing parallel-connection hydrogen halide acid by four-chamber three-membrane electrolysis of short-chain quaternary ammonium hydroxide
CN109082680B (en) * 2018-09-04 2020-05-05 安庆师范大学 Preparation method of bipyridine ionic liquid
WO2021002235A1 (en) * 2019-07-04 2021-01-07 株式会社トクヤマ Method and device for producing quaternary ammonium hydroxide
CN110669591A (en) * 2019-09-30 2020-01-10 上海新阳半导体材料股份有限公司 non-TMAH alkali cleaning solution used after chemical mechanical polishing and preparation method thereof
CN113620810B (en) * 2021-08-05 2022-04-15 肯特催化材料股份有限公司 Preparation method of quaternary ammonium salt and method for preparing quaternary ammonium base by using quaternary ammonium salt
KR102657799B1 (en) 2021-11-03 2024-04-16 (주)테크윈 Compartmental tank

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5235839A (en) * 1975-09-17 1977-03-18 Furukawa Electric Co Ltd Battery separator
JPS6297610A (en) * 1985-10-25 1987-05-07 Toyo Soda Mfg Co Ltd Method for separating acid and alkali from aqueous solution of salt
JPS6487796A (en) * 1987-05-11 1989-03-31 Tokuyama Soda Kk Production of quaternary ammonium hydroxide
JP2004502786A (en) * 2000-06-13 2004-01-29 ハイドロ−ケベック Crosslinkable bromosulfonated fluoroelastomer based on vinylidene fluoride showing low Tg
JP2006179301A (en) * 2004-12-22 2006-07-06 Japan Atomic Energy Agency High-durability polymer electrolyte membrane for fuel cell with cross-linked structure introduced therein

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6488796A (en) * 1987-09-30 1989-04-03 Toshiba Corp Printing system
JP3542265B2 (en) * 1998-02-12 2004-07-14 株式会社トクヤマ Method for producing quaternary ammonium hydroxide

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5235839A (en) * 1975-09-17 1977-03-18 Furukawa Electric Co Ltd Battery separator
JPS6297610A (en) * 1985-10-25 1987-05-07 Toyo Soda Mfg Co Ltd Method for separating acid and alkali from aqueous solution of salt
JPS6487796A (en) * 1987-05-11 1989-03-31 Tokuyama Soda Kk Production of quaternary ammonium hydroxide
JP2004502786A (en) * 2000-06-13 2004-01-29 ハイドロ−ケベック Crosslinkable bromosulfonated fluoroelastomer based on vinylidene fluoride showing low Tg
JP2006179301A (en) * 2004-12-22 2006-07-06 Japan Atomic Energy Agency High-durability polymer electrolyte membrane for fuel cell with cross-linked structure introduced therein

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024009599A1 (en) * 2022-07-08 2024-01-11 株式会社トクヤマ Electrolysis tank

Also Published As

Publication number Publication date
TW200912045A (en) 2009-03-16
JP2009013477A (en) 2009-01-22
JP5100222B2 (en) 2012-12-19
KR20100029816A (en) 2010-03-17
CN101680101A (en) 2010-03-24
CN101680101B (en) 2011-11-23

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