WO2009001632A1 - 水素製造エタノール改質触媒及び水素製造方法 - Google Patents

水素製造エタノール改質触媒及び水素製造方法 Download PDF

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WO2009001632A1
WO2009001632A1 PCT/JP2008/059145 JP2008059145W WO2009001632A1 WO 2009001632 A1 WO2009001632 A1 WO 2009001632A1 JP 2008059145 W JP2008059145 W JP 2008059145W WO 2009001632 A1 WO2009001632 A1 WO 2009001632A1
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hydrogen
reforming catalyst
ethanol
production
reaction
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PCT/JP2008/059145
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English (en)
French (fr)
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Nobuhiko Mori
Toshiyuki Nakamura
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Ngk Insulators, Ltd.
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Publication of WO2009001632A1 publication Critical patent/WO2009001632A1/ja

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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
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    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
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Abstract

　コーキングを抑制しつつ従来よりも低温でエタノールを改質し、効率よく水素を製造するための水素製造エタノール改質触媒、及びそれを用いた水素製造方法を提供する。水素製造エタノール改質触媒は、エタノールを含む炭化水素と水蒸気との反応により、水素、及び一酸化炭素または二酸化炭素を含む混合ガスを生成する改質反応のための水蒸気改質触媒と、一酸化炭素と水蒸気との反応により、水素及び二酸化炭素を生成するシフト反応のためのシフト反応触媒と、を混合して含む。水蒸気改質触媒の活性金属として、Ｃｏ、Ｒｕを用いる。また、担体として、ＺｎＯ、Ｌａ２Ｏ３を用いる。シフト反応触媒は、Ｆｅ２Ｏ３／Ｃｒ２Ｏ３、Ｃｕ／ＺｎＯ、Ｐｔ／ＴｉＯ２等を用いる。
PCT/JP2008/059145 2007-06-25 2008-05-19 水素製造エタノール改質触媒及び水素製造方法 WO2009001632A1 (ja)

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JP2007166656A JP5242086B2 (ja) 2007-06-25 2007-06-25 水素製造エタノール改質触媒及び水素製造方法
JP2007-166656 2007-06-25

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005041749A (ja) * 2003-07-25 2005-02-17 Shikoku Electric Power Co Inc Ｃｏシフト反応の促進方法及びそれを利用した水素ガス又はｃｏ含有率の低減されたガスの製造方法
JP2005131468A (ja) * 2003-10-28 2005-05-26 Research Institute Of Innovative Technology For The Earth エタノール水蒸気改質触媒、その製造方法及び水素の製造方法
JP2005131469A (ja) * 2003-10-28 2005-05-26 Research Institute Of Innovative Technology For The Earth エタノール水蒸気改質触媒、その製造方法及び水素の製造方法
JP2005185890A (ja) * 2003-12-24 2005-07-14 Nissan Motor Co Ltd 水素製造触媒および水素製造方法
JP2007029811A (ja) * 2005-07-25 2007-02-08 Sakai Chem Ind Co Ltd 水性ガスシフト反応触媒とこれを用いる水素ガス中の一酸化炭素ガスを除去する方法
JP2007146051A (ja) * 2005-11-29 2007-06-14 Nippon Oil Corp 炭化水素系燃料の脱硫方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2795339B1 (fr) * 1999-06-24 2001-09-21 Peugeot Citroen Automobiles Sa Catalyseur et procede de reformage de l'ethanol ainsi que systeme de pile a combustible les utilisant
JP2004237239A (ja) * 2003-02-07 2004-08-26 Nissan Motor Co Ltd アルコール改質用触媒
JP2007083197A (ja) * 2005-09-26 2007-04-05 Mitsubishi Gas Chem Co Inc 銅−亜鉛−アルミニウム系触媒の製造方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005041749A (ja) * 2003-07-25 2005-02-17 Shikoku Electric Power Co Inc Ｃｏシフト反応の促進方法及びそれを利用した水素ガス又はｃｏ含有率の低減されたガスの製造方法
JP2005131468A (ja) * 2003-10-28 2005-05-26 Research Institute Of Innovative Technology For The Earth エタノール水蒸気改質触媒、その製造方法及び水素の製造方法
JP2005131469A (ja) * 2003-10-28 2005-05-26 Research Institute Of Innovative Technology For The Earth エタノール水蒸気改質触媒、その製造方法及び水素の製造方法
JP2005185890A (ja) * 2003-12-24 2005-07-14 Nissan Motor Co Ltd 水素製造触媒および水素製造方法
JP2007029811A (ja) * 2005-07-25 2007-02-08 Sakai Chem Ind Co Ltd 水性ガスシフト反応触媒とこれを用いる水素ガス中の一酸化炭素ガスを除去する方法
JP2007146051A (ja) * 2005-11-29 2007-06-14 Nippon Oil Corp 炭化水素系燃料の脱硫方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
LLORCA J. ET AL.: "In situ magnetic characterisation of supported cobalt catalysts under steam-reforming of ethanol", APPL. CATAL. A GEN., vol. 243, 10 April 2003 (2003-04-10), pages 261 - 269 *

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