WO2009001525A1 - 生分解性脂肪族ポリエステル系発泡粒子及びその成形体 - Google Patents

生分解性脂肪族ポリエステル系発泡粒子及びその成形体 Download PDF

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Publication number
WO2009001525A1
WO2009001525A1 PCT/JP2008/001572 JP2008001572W WO2009001525A1 WO 2009001525 A1 WO2009001525 A1 WO 2009001525A1 JP 2008001572 W JP2008001572 W JP 2008001572W WO 2009001525 A1 WO2009001525 A1 WO 2009001525A1
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WIPO (PCT)
Prior art keywords
expanded particle
produced
molded article
resin
aliphatic polyester
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PCT/JP2008/001572
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English (en)
French (fr)
Inventor
Toshio Miyagawa
Tomonori Furukawa
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Kaneka Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Kaneka Corporation filed Critical Kaneka Corporation
Priority to JP2009520322A priority Critical patent/JP5383489B2/ja
Priority to EP08776725.7A priority patent/EP2168993B1/en
Priority to US12/666,756 priority patent/US20100184877A1/en
Publication of WO2009001525A1 publication Critical patent/WO2009001525A1/ja

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/4283Hydroxycarboxylic acid or ester
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0895Manufacture of polymers by continuous processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16Making expandable particles
    • C08J9/18Making expandable particles by impregnating polymer particles with the blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00Manufacture of cellular products
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2230/00Compositions for preparing biodegradable polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2350/00Acoustic or vibration damping material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/02Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/024Preparation or use of a blowing agent concentrate, i.e. masterbatch in a foamable composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/14Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/04Polyesters derived from hydroxy carboxylic acids, e.g. lactones
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/29Compounds containing one or more carbon-to-nitrogen double bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

環境適合性に優れた、植物由来の原料を用いる生分解性脂肪族ポリエステル系樹脂発泡粒子及びその成形体であって、高発泡化しても高剛性を維持し、且つ耐熱性を有する生分解性脂肪族ポリエステル系樹脂発泡粒子及び成形体を提供する。式:[-O-CHR-CH2-CO-](Rは、CnH2n+1で示されるアルキル基を表す。nは1~15の整数を表す。)で示される一種以上の繰り返し単位からなる重合体(ポリ(3-ヒドロキシアルカノエート))及びポリ乳酸系樹脂からなる基材樹脂と、イソシアネート化合物とを溶融混練して得た樹脂組成物を発泡させることで製造された生分解性脂肪族ポリエステル系樹脂発泡粒子。当該樹脂発泡粒子を金型に充填し、次いで加熱成形することで成形体を作製する。
PCT/JP2008/001572 2007-06-27 2008-06-18 生分解性脂肪族ポリエステル系発泡粒子及びその成形体 WO2009001525A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2009520322A JP5383489B2 (ja) 2007-06-27 2008-06-18 生分解性脂肪族ポリエステル系発泡粒子及びその成形体
EP08776725.7A EP2168993B1 (en) 2007-06-27 2008-06-18 Biodegradable aliphatic polyester-based foamed particle and molded product of the same
US12/666,756 US20100184877A1 (en) 2007-06-27 2008-06-18 Biodegradable aliphatic polyester-based foamed particle and molded product of the same

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007-169007 2007-06-27
JP2007169007 2007-06-27
JP2007169008 2007-06-27
JP2007-169008 2007-06-27

Publications (1)

Publication Number Publication Date
WO2009001525A1 true WO2009001525A1 (ja) 2008-12-31

Family

ID=40185352

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Application Number Title Priority Date Filing Date
PCT/JP2008/001572 WO2009001525A1 (ja) 2007-06-27 2008-06-18 生分解性脂肪族ポリエステル系発泡粒子及びその成形体

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Country Link
US (1) US20100184877A1 (ja)
EP (1) EP2168993B1 (ja)
JP (1) JP5383489B2 (ja)
WO (1) WO2009001525A1 (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019146555A1 (ja) * 2018-01-26 2019-08-01 株式会社カネカ ポリ(3-ヒドロキシアルカノエート)系発泡粒子およびポリ(3-ヒドロキシアルカノエート)系発泡成形体

Families Citing this family (11)

* Cited by examiner, † Cited by third party
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US20120007267A1 (en) 2010-07-07 2012-01-12 Lifoam Industries Method of Producing Compostable or Biobased Foams
MX2012003108A (es) * 2011-07-07 2013-02-07 Lifoam Ind Proceso para activar la expansion secundaria de perlas expandibles.
WO2014001119A1 (de) 2012-06-26 2014-01-03 Basf Se Verfahren zur herstellung von expandierbaren polymilchsäurehaltigen granulaten
US9682805B2 (en) 2012-10-26 2017-06-20 Berry Plastics Corporation Closure for container
WO2014153060A1 (en) * 2013-03-14 2014-09-25 Berry Plastics Corporation Stack shoulders for insulated container
CA2983334C (en) 2015-04-30 2023-09-26 Berry Plastics Corporation Container closure
CN106398183B (zh) * 2016-08-31 2018-12-07 上海分尚网络科技有限公司 一种插花装置的制备方法
WO2018125895A1 (en) * 2016-12-28 2018-07-05 Swimc, Llc Packaging coating resins derived from reactions of phenols with polyolefinic terpenes
WO2018134810A1 (en) * 2017-01-23 2018-07-26 Kal-Kar Ein Carmel Ltd Biodegradable seedling containers prepared from expandable polymeric beads
CN112759906A (zh) * 2020-12-23 2021-05-07 青岛润兴塑料新材料有限公司 一种用于海洋的全生物降解聚乳酸吸油发泡材料
WO2022230746A1 (ja) * 2021-04-28 2022-11-03 株式会社カネカ ポリ(3-ヒドロキシアルカノエート)系発泡粒子、およびポリ(3-ヒドロキシアルカノエート)系発泡成形体

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05170966A (ja) 1991-12-24 1993-07-09 Mitsui Toatsu Chem Inc 分解性ポリマーの発泡性粒子
JP2001026658A (ja) 1999-07-13 2001-01-30 Mitsui Chemicals Inc ポリ乳酸系樹脂組成物及びその製造方法
JP2003301068A (ja) 2002-04-10 2003-10-21 Kanebo Ltd ポリ乳酸発泡粒子よりなる成形物及びその製造方法
JP2005060689A (ja) * 2003-07-31 2005-03-10 Toray Ind Inc 発泡体およびその製造方法
JP2006022242A (ja) 2004-07-09 2006-01-26 Kaneka Corp ポリ乳酸系樹脂発泡粒子およびその成形体
WO2006112287A1 (ja) * 2005-04-14 2006-10-26 Kaneka Corporation ポリヒドロキシアルカノエート樹脂発泡粒子、およびその成形体と該樹脂発泡粒子の製造方法

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US6808795B2 (en) * 2001-03-27 2004-10-26 The Procter & Gamble Company Polyhydroxyalkanoate copolymer and polylactic acid polymer compositions for laminates and films
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Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05170966A (ja) 1991-12-24 1993-07-09 Mitsui Toatsu Chem Inc 分解性ポリマーの発泡性粒子
JP2001026658A (ja) 1999-07-13 2001-01-30 Mitsui Chemicals Inc ポリ乳酸系樹脂組成物及びその製造方法
JP2003301068A (ja) 2002-04-10 2003-10-21 Kanebo Ltd ポリ乳酸発泡粒子よりなる成形物及びその製造方法
JP2005060689A (ja) * 2003-07-31 2005-03-10 Toray Ind Inc 発泡体およびその製造方法
JP2006022242A (ja) 2004-07-09 2006-01-26 Kaneka Corp ポリ乳酸系樹脂発泡粒子およびその成形体
WO2006112287A1 (ja) * 2005-04-14 2006-10-26 Kaneka Corporation ポリヒドロキシアルカノエート樹脂発泡粒子、およびその成形体と該樹脂発泡粒子の製造方法

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* Cited by examiner, † Cited by third party
Title
See also references of EP2168993A4

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019146555A1 (ja) * 2018-01-26 2019-08-01 株式会社カネカ ポリ(3-ヒドロキシアルカノエート)系発泡粒子およびポリ(3-ヒドロキシアルカノエート)系発泡成形体
JPWO2019146555A1 (ja) * 2018-01-26 2021-01-07 株式会社カネカ ポリ(3−ヒドロキシアルカノエート)系発泡粒子およびポリ(3−ヒドロキシアルカノエート)系発泡成形体
JP7123980B2 (ja) 2018-01-26 2022-08-23 株式会社カネカ ポリ(3-ヒドロキシアルカノエート)系発泡粒子およびポリ(3-ヒドロキシアルカノエート)系発泡成形体

Also Published As

Publication number Publication date
EP2168993A1 (en) 2010-03-31
JP5383489B2 (ja) 2014-01-08
EP2168993B1 (en) 2016-10-19
JPWO2009001525A1 (ja) 2010-08-26
US20100184877A1 (en) 2010-07-22
EP2168993A4 (en) 2011-12-14

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