WO2009000605A1 - Compositions détergentes enzymatiques granulaires - Google Patents

Compositions détergentes enzymatiques granulaires Download PDF

Info

Publication number
WO2009000605A1
WO2009000605A1 PCT/EP2008/056477 EP2008056477W WO2009000605A1 WO 2009000605 A1 WO2009000605 A1 WO 2009000605A1 EP 2008056477 W EP2008056477 W EP 2008056477W WO 2009000605 A1 WO2009000605 A1 WO 2009000605A1
Authority
WO
WIPO (PCT)
Prior art keywords
detergent composition
composition according
weight
sodium
thiosulphate
Prior art date
Application number
PCT/EP2008/056477
Other languages
English (en)
Inventor
Olaf C P Beers
Willem Oldenburg
Ronaldus T L Van Vliet
Original Assignee
Unilever N.V.
Unilever Plc
Hindustan Unilever Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=38670670&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2009000605(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Unilever N.V., Unilever Plc, Hindustan Unilever Limited filed Critical Unilever N.V.
Priority to CN2008800213871A priority Critical patent/CN101688152B/zh
Priority to EP08760075.5A priority patent/EP2162522B1/fr
Priority to BRPI0813386-7A2A priority patent/BRPI0813386A2/pt
Publication of WO2009000605A1 publication Critical patent/WO2009000605A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38672—Granulated or coated enzymes

Definitions

  • the present invention relates to granular detergent compositions, more in particular to granular detergent compositions comprising alkyl ester, in particular methyl ester fatty acid sulphonate surfactant and enzyme granules,
  • Laundry detergent compositions have for many years contained anionic sulphonate or sulphate surfactant, for example, linear alkylbenzene sulphonate (LAS) or primary alkyl sulphate (PAS) , together with ethoxylated alcohol nonionic surfactants.
  • anionic sulphonate or sulphate surfactant for example, linear alkylbenzene sulphonate (LAS) or primary alkyl sulphate (PAS)
  • ethoxylated alcohol nonionic surfactants used in laundry detergent compositions include typically ethoxylated Cio ⁇ Ci6 alcohols having an average degree of ethoxylation of 3 to 9.
  • MES methyl ester fatty acid sulphonate
  • the IUPAC name for e.g. a so-called C16 MES is Hexadecanoic acid, 2-sulfo-, 1-methylester, sodium salt (C17H33NaO5S) - -
  • Methyl ester sulphonate can be obtained by sulphonation of various renewable oleo-based methyl ester feedstocks derived from eg. coconut (C12-14), palm kernel (C8-18), palm stearin C16-18) or tallow (C16-18).
  • MES is of special interest due to good biodegradability, detergency and calcium hardness tolerance.
  • EP-A-I 634 941 (Lion) or WO-A-01/90284 (Huish) disclose high bulk density granular detergents containing surfactants (including ⁇ -sulpho-fatty acid esters), (bi) carbonate, zeolite and a polymer containing of monoethylenic unsaturated mono- and di-carboxylic acid units.
  • surfactants including ⁇ -sulpho-fatty acid esters
  • carbonate zeolite
  • zeolite a polymer containing of monoethylenic unsaturated mono- and di-carboxylic acid units.
  • the granular detergent composition according to the invention comprising 1 to 30% by weight of an alkyl ester fatty acid sulphonate surfactant and enzyme granules, wherein said composition is substantially free of thiosulphate .
  • a granular detergent composition comprising 1 to 30% by weight of an alkyl ester fatty acid sulphonate surfactant and 0.1 to 10% by weight enzyme granules, wherein said composition is substantially free of thiosulphate.
  • a detergent tablet obtained by compressing the granular detergent composition according to the invention.
  • a process for laundering textile fabrics by machine or hand characterised in that it comprises the step of immersing the fabrics in a wash liquor comprising water in which a granular detergent composition or detergent tablet according to the invention is dissolved or dispersed.
  • a process for manufacturing a granular detergent composition or tablet according to the invention is provided.
  • the granular detergent composition of the invention comprises 1 to 30% by weight of an alkyl ester fatty acid sulphonate surfactant, preferably methyl ester fatty acid sulphonate surfactant, and enzyme granules.
  • an alkyl ester fatty acid sulphonate surfactant preferably methyl ester fatty acid sulphonate surfactant
  • enzyme granules Preferably, the amount of ⁇ -sulpho-fatty acid esters is 1 to 15% by weight, more preferably 3 to 8% by weight.
  • ⁇ -sulfofatty acid esters can be prepared from a variety of sources, including beef tallow, palm kernel oil, palm kernel (olein) oil, palm kernel (stearin) oil, coconut oil, soybean oil, canola oil, cohune - -
  • Suitable fatty acids to make ⁇ -sulfofatty acid esters include, but are not limited to, caprylic (Cs) , capric ( (Cio) , lauric (C12) , myristic (Ci 4 ) , myristoleic (Ci 4 ) , palmitic (Ci ⁇ ) , palmitoleic (Ci ⁇ ) , stearic (Cis) , oleic (Cis) , linoleic (Cis) , linolenic (Cis) , ricinoleic (Cis) , arachidic (C20) , gadolic (C20) , behenic (C22) t and erucic (C22) fatty acids.
  • ⁇ -Sulfofatty acid esters prepared from one or more of these sources are examples of these sources.
  • Samples of alkyl ester fatty acid sulphonate surfactant prepared in dry powder form via above mentioned production processes typically contain about 75-85 % by weight of the desired surfactant.
  • the other components in a typical production sample there is one of specific relevance for the present invention, which is sodium methylsulphate, typically present at (but not restricted to) a level of about 1-10 % based on the weight of the MES as such.
  • the composition may also comprise one or more other surfactants.
  • the other surfactant is present in an amount of from 5 to 40 wt.%, preferably from 7 to 30 wt.%, based on the weight of the total composition.
  • alkylbenzene sulphonates examples include alkylbenzene sulphonates, branched or linear alkyl benzene sulphonates, primary and secondary alcohol sulphates, particularly C8 ⁇ Ci6 primary alcohol sulphates; alkyl ether sulphates, olefin sulphonates, including alpha olefin sulphonates, alkane sulphonates, alkyl xylene sulphonates, dialkyl sulphosuccinates, and alkyl carboxylates . These may be present as sodium, potassium, calcium or magnesium salts or mixtures of these. Sodium salts are generally preferred.
  • the other surfactant is preferably a sulphonate or sulphate anionic surfactant or a combination thereof. More preferably, the anionic surfactant is linear alkylbenzene sulphonate or primary alkyl sulphate. Most preferably the other surfactant is linear alkylbenzene sulphonate.
  • the linear alkyl benzene sulphonate may be present as sodium, potassium, or alkaline earth metal salts, or mixtures of these salts. Sodium salts are generally preferred.
  • the other surfactant may also comprise a nonionic surfactant, preferably an ethoxylated alcohol nonionic surfactant with an average degree of ethoxylation ranging from about 3 to 9, preferably from about 3 to 7.
  • the alcohol may be derived from natural or synthetic feedstock. Preferred alcohol feedstocks are coconut and palm kernel, predominantly C 12 -C 14 , and oxo C 12 -C 15 alcohols.
  • the nonionic surfactant is suitably present in an amount of from 1 to 20 wt %, preferably from 1 to 10, more preferably from 2 to 6 wt %, most preferably from 3 to 5 wt %, based on the weight of the total composition.
  • Additional surfactants or detergent active compounds may comprise other nonionics such as alkylpolyglucosides, polyhydroxyamides (glucamide) , methyl ester ethoxylates and glycerol monoethers .
  • cationic, amphoteric surfactants and/or zwitterionic surfactants may be present.
  • Preferred cationic surfactants are quaternary ammonium salts of the general formula R 1 R 2 R3R 4 N + X-, for example where Ri is a C 12 - Ci 4 alkyl group, R 2 and R3 are methyl groups, R 4 is a
  • 2-hydroxyethyl group, and X- is a chloride ion.
  • This material is available commercially as Praepagen (Trade Mark) HY from Clariant GmbH, in the form of a 40 wt% aqueous solution .
  • Preferred amphoteric surfactants are amine oxides, for example coco dimethyl amine oxide.
  • Preferred zwitterionic surfactants are betaines, and especially amidobetaines .
  • Preferred betaines are C8 to C18 alkyl amidoalkyl betaines, for example coco amido betaine. These may be included as co- surfactants, preferably present in an amount of from 0 to 10 wt %, more preferably 1 to 5 wt %, based on the weight of the total composition.
  • the detergent compositions of the present invention comprise one or more other enzymes, which provide cleaning performance, fabric care and/or sanitation benefits.
  • Suitable enzymes for incorporation in detergent compositions preferably include protease, lipase, amylase, cellulase, mannanase and oxidase, peroxidise, oxidoreductase, beta- glucanase, pectinase and/or pectate lyase. Most preferably, the compositions contain a proteolytic enzyme or protease. - -
  • composition may contain additional enzymes as found in WO-A-01/007681 page 15, line 25 to pagel9, line 29 as well as those found in WO-A-02/02726 page 16 line 21 to page 19 line 16 and those found in WO-A-02/02726 page 33 line 28 to page 39 line 34, the contents of which are herein incorporated by reference. It also may contain maltogenic ⁇ -amylases as described in WO-A-02/02726 page 5, line 14 to page 11 line 29. Commercially available maltogenic ⁇ -amylases are NovamylTM and MaltogenaseTM from Novozymes.
  • composition may also contain a lipase variant of the Humicola lanuginosa lipase with substitutions T231R + N233R, commercially available as LipexTM from Novozymes or another variant as described in WO-A-00/60063.
  • composition may also contain other commercial enzymes not described in any of the previous specifications such as the new enzymes from Novozymes: MannawayTM, NatalaseTM, RenozymeTM, OvozymeTM, CelluCleanTM, PolarzymeTM, StainzymeTM, CoronaseTM, PectaawayTM, PectawashTM, Termamyl UltraTM. And the new enzymes from Genencor: FN-3, FN-4, Purafect PrimeTM, ProperaseTM. - -
  • detergency enzymes are employed in granular form in amounts of from about 0.1 to about 10.0 wt %, preferably from about 0.2 to about 3% by weight, more preferably from about 0.2 to about 1% by weight.
  • the detergent compositions are substantially free of thiosulphate . Since enzyme granules sometimes contain thiosulphate, it was found to be important to use thiosulphate free enzyme granules. Preferably enzyme granules contain less than 3% by weight, more preferably less than 1% by weight, most preferably less than 0.1% by weight of thiosulphate. The amount of thiosulphate in the compositions can be determined using standard analytical techniques. Thiosulphate in the context of this invention means any salt thereof, such as alkalimetal, especially sodium, but also ammonium, Monoethanolamine or Triethanolamine salts.
  • compositions of the invention may contain a detergency builder.
  • the builder is present in an amount of from 1 to less than 80 wt % based on the weight of the total composition. More preferably the amount of builder is from 1 to 60 wt %.
  • Builders are well-known to those skilled in the art. Many suitable builder compounds are available. Examples are zeolites, sodium tripolyphosphate, layered silicate, sodium carbonate, sodium bicarbonate, burkeite, sodium silicate and mixtures thereof. - -
  • compositions may optionally contain other active ingredients to enhance performance and properties.
  • compositions of the invention may contain from 0 to 85 wt % of an inorganic non-builder salt, such as sodium sulphate, sodium sesquicarbonate, sodium chloride, calcium chloride, magnesium chloride and calcite, preferably from 0 to 60 wt %, preferably from 0 to 40 wt %, based on the weight of the total composition.
  • an inorganic non-builder salt such as sodium sulphate, sodium sesquicarbonate, sodium chloride, calcium chloride, magnesium chloride and calcite
  • compositions of the invention may contain a polycarboxylate polymer.
  • polycarboxylate polymer include homopolymers and copolymers of acrylic acid, maleic acid and acrylic/maleic acids.
  • the publication ⁇ Polymeric Dispersing Agents, Sokalan' a printed publication of BASF Aktiengesellschaft, D-6700 Ludwigshaven, Germany describes organic polymers which are useful.
  • the polycarboxylate polymer is selected from the group consisting of sodium polyacrylate, sodium acrylate maleate and mixtures thereof.
  • suitable polymers include Sokalan CP5, ex BASF polyacrylate, namely maleic acid-acrylic acid copolymer, with a sodium salt.
  • the detergent compositions of the invention may comprise one or more optional ingredients selected from soap, peroxyacid and persalt bleaches, bleach activators, air bleach catalysts, sequestrants, cellulose ethers and esters, cellulosic polymers, other antiredeposition agents, sodium bicarbonate, other inorganic salts, fluorescers, photobleaches, polyvinyl pyrrolidone, other dye transfer inhibiting polymers, foam controllers, foam boosters, - -
  • citric acid soil release polymers, silicone, fabric conditioning compounds, coloured speckles such as blue speckles, and perfume. This list is not intended to be exhaustive .
  • compositions of the invention are granular detergent compositions, preferably in powder form, having a mean particle size between 200 and 800 micrometer. Alternatively, the compositions may be in tablet form.
  • the compositions can be formulated for use as hand wash or machine wash detergents .
  • compositions of the invention may be prepared by any suitable process. Powders of low to moderate bulk density may be prepared by spray-drying a slurry, and optionally postdosing (dry-mixing) further ingredients. “Concentrated” or “compact” powders may be prepared by mixing and granulating processes, for example, using a highspeed mixer/granulator, or other non-tower processes.
  • Tablets may be prepared by compacting powders, especially "concentrated" powders.
  • the choice of processing route may be in part dictated by the stability or heat-sensitivity of the surfactants involved, and the form in which they are available. In all cases, all ingredients may be added separately.
  • Sodium LAS sodium C10-C13 alkylbenzene sulphonate (anionic surfactant)
  • Nonionic 7EO C13-C15 fatty alcohol ethoxylated with an average of 7 ethyleneoxide units per mole (nonionic surfactant)
  • Zeolite 4A sodium alumino silicate with Si:Al ratio 1 (ion- exchange builder)
  • Polymer acrylic acid/maleic acid type of polymer (anti- redeposition, anti-ashing or co-builder)
  • SCMC sodium carboxy methyl cellulose (anti-redeposition polymer)
  • Polarzyme 12.0 T protease enzyme granule from Novozymes; granule contains sodium thiosulphate as stabilizer.
  • Savinase 24.0 GTT (12.0 or 24.0 T): protease enzyme granule from Novozymes; granule contains sodium thiosulphate as stabilizer.
  • Stainzyme 12.0 T amylase enzyme granule from Novozymes; granule contains sodium thiosulphate as stabilizer.
  • Termamyl 60 T amylase enzyme granule from Novozymes; granule contains sodium thiosulphate as stabilizer.
  • Properase 100OM protease enzyme granule from Genencor; granule is free of sodium thiosulphate.
  • Purafect 3450M protease enzyme granule from Genencor; granule is free of sodium thiosulphate.
  • Lipex 100 T lipase enzyme granule from Novozymes; granule is free of sodium thiosulphate. - -
  • Savinase pure pure protease enzyme powder from Novozymes; without coating and sodium thiosulphate .
  • Dummy granule granule from Novozymes without enzymes and sodium thiosulphate.
  • BSA Bovine Serum Albumin
  • model protein model protein
  • the malodour molecule generated during storage has been identified via GC/MS headspace analyses to be a dimethyl- sulfide (abbr. DMS), predominantly dimethyl-disulfide, dimethyl-trisulfide and dimethyl-tetrasulfide .
  • DMS dimethyl- sulfide
  • the severity of malodour due to dimethylsulfides can be best assessed olfactively using following intensity scale:
  • Malodour is due to an interaction of MES/MS and thiosulphate (which is present within enzyme-granules of Novozymes) , since - i

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Des problèmes potentiels de mauvaise odeur sont évités par l'utilisation d'une composition détergente granulaire comprenant 1 à 30 % en poids d'un ester alkylique d'un agent tensio-actif alkyle ester sulfonate d'acide gras et des granulés d'enzyme, ladite composition étant sensiblement exempte de thiosulfate.
PCT/EP2008/056477 2007-06-22 2008-05-27 Compositions détergentes enzymatiques granulaires WO2009000605A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN2008800213871A CN101688152B (zh) 2007-06-22 2008-05-27 粒状加酶洗涤剂组合物
EP08760075.5A EP2162522B1 (fr) 2007-06-22 2008-05-27 Compositions détergentes enzymatiques granulaires
BRPI0813386-7A2A BRPI0813386A2 (pt) 2007-06-22 2008-05-27 Composição detergente enzimática granular, tablete detergente, processo para a lavagem de tecidos, e, processo para a sua fabricação.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07110850.0 2007-06-22
EP07110850 2007-06-22

Publications (1)

Publication Number Publication Date
WO2009000605A1 true WO2009000605A1 (fr) 2008-12-31

Family

ID=38670670

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/056477 WO2009000605A1 (fr) 2007-06-22 2008-05-27 Compositions détergentes enzymatiques granulaires

Country Status (7)

Country Link
EP (1) EP2162522B1 (fr)
CN (1) CN101688152B (fr)
AR (1) AR067053A1 (fr)
BR (1) BRPI0813386A2 (fr)
CL (1) CL2008001858A1 (fr)
TR (1) TR201810838T4 (fr)
WO (1) WO2009000605A1 (fr)

Cited By (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011134809A1 (fr) 2010-04-26 2011-11-03 Novozymes A/S Granules enzymatiques
US8110703B2 (en) 2008-05-30 2012-02-07 Anhui Medical University Retinoid derivative and pharmaceutical composition and use thereof
WO2012175401A2 (fr) 2011-06-20 2012-12-27 Novozymes A/S Composition particulaire
WO2012175708A2 (fr) 2011-06-24 2012-12-27 Novozymes A/S Polypeptides ayant une activité de protéase et polynucléotides les codant
WO2013001087A2 (fr) 2011-06-30 2013-01-03 Novozymes A/S Procédé de criblage d'alpha-amylases
WO2013007594A1 (fr) 2011-07-12 2013-01-17 Novozymes A/S Granulés enzymatiques stables au stockage
WO2013024021A1 (fr) 2011-08-15 2013-02-21 Novozymes A/S Polypeptides ayant une activité cellulase et polynucléotides codant pour ceux-ci
EP2569406A1 (fr) * 2010-05-14 2013-03-20 The Sun Products Corporation Compositions nettoyantes contenant des polymères et procédés de production et d'utilisation associés
WO2013041689A1 (fr) 2011-09-22 2013-03-28 Novozymes A/S Polypeptides ayant une activité protéase et polynucléotides codant pour ceux-ci
WO2013076269A1 (fr) 2011-11-25 2013-05-30 Novozymes A/S Variants de subtilase et polynucléotides codants pour ceux-ci
WO2013092635A1 (fr) 2011-12-20 2013-06-27 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
WO2013110766A1 (fr) 2012-01-26 2013-08-01 Novozymes A/S Utilisation de polypeptides à activité protéasique dans les aliments pour animaux et les détergents
WO2013120948A1 (fr) 2012-02-17 2013-08-22 Novozymes A/S Variants de subtilisine et polynucléotides codant ces derniers
WO2013131964A1 (fr) 2012-03-07 2013-09-12 Novozymes A/S Composition détergente et substitution d'azurants optiques dans des compositions détergentes
WO2013167581A1 (fr) 2012-05-07 2013-11-14 Novozymes A/S Polypeptides ayant une activité de décomposition du xanthane et polynucléotides codant pour ceux-ci
WO2013189972A2 (fr) 2012-06-20 2013-12-27 Novozymes A/S Utilisation de polypeptides ayant une activité protéase dans des aliments pour animaux et des détergents
WO2014096259A1 (fr) 2012-12-21 2014-06-26 Novozymes A/S Polypeptides possédant une activité protéasique et polynucléotides codant pour ceux-ci
WO2014183921A1 (fr) 2013-05-17 2014-11-20 Novozymes A/S Polypeptides présentant une activité alpha-amylase
WO2014207227A1 (fr) 2013-06-27 2014-12-31 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
WO2014207224A1 (fr) 2013-06-27 2014-12-31 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
WO2015001017A2 (fr) 2013-07-04 2015-01-08 Novozymes A/S Polypeptides présentant un effet anti-redéposition et polynucléotides codant pour ceux-ci
EP2832853A1 (fr) 2013-07-29 2015-02-04 Henkel AG&Co. KGAA Composition détergente comprenant des variantes de protéases
WO2015049370A1 (fr) 2013-10-03 2015-04-09 Novozymes A/S Composition détergente et utilisation de celle-ci
WO2015134729A1 (fr) 2014-03-05 2015-09-11 Novozymes A/S Compositions et procédés destinés à améliorer les propriétés de matériaux textiles non-cellulosiques par l'utilisation d'endo-xyloglucane transférase
WO2015134737A1 (fr) 2014-03-05 2015-09-11 Novozymes A/S Compositions et procédés pour améliorer les propriétés de matières textiles cellulosiques avec une xyloglucane endotransglycosylase
WO2015150457A1 (fr) 2014-04-01 2015-10-08 Novozymes A/S Polypeptides présentant une activité alpha-amylase
WO2015189371A1 (fr) 2014-06-12 2015-12-17 Novozymes A/S Variants d'alpha-amylase et polynucléotides codant pour ces derniers
WO2016079305A1 (fr) 2014-11-20 2016-05-26 Novozymes A/S Variants de alicyclobacillus et polynucléotides codant pour ceux-ci
EP3106508A1 (fr) 2015-06-18 2016-12-21 Henkel AG & Co. KGaA Composition détergente comprenant des variantes de subtilase
WO2017064269A1 (fr) 2015-10-14 2017-04-20 Novozymes A/S Variants polypeptidiques
WO2017064253A1 (fr) 2015-10-14 2017-04-20 Novozymes A/S Polypeptides ayant une activité de protéase et polynucléotides codant pour ceux-ci
WO2017207762A1 (fr) 2016-06-03 2017-12-07 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
WO2018011277A1 (fr) 2016-07-13 2018-01-18 Novozymes A/S Variants dnases de bacillus cibi
EP3309249A1 (fr) 2013-07-29 2018-04-18 Novozymes A/S Variants de protéases et polynuclétides les codant
EP3321360A2 (fr) 2013-01-03 2018-05-16 Novozymes A/S Variants d'alpha-amylase et polynucléotides les codant
EP3453757A1 (fr) 2013-12-20 2019-03-13 Novozymes A/S Polypeptides a activite de protease et polynucleotides les codant
WO2019081721A1 (fr) 2017-10-27 2019-05-02 Novozymes A/S Variants de la dnase
WO2019084349A1 (fr) 2017-10-27 2019-05-02 The Procter & Gamble Company Compositions détergentes comprenant des variants polypeptidiques
WO2019201793A1 (fr) 2018-04-17 2019-10-24 Novozymes A/S Polypeptides ayant une activité de liaison des hydrates de carbone dans des compositions détergentes et leur utilisation pour réduire les plis de textiles ou de tissus
EP3608403A2 (fr) 2014-12-15 2020-02-12 Henkel AG & Co. KGaA Composition détergente comprenant des variantes de subtilase
EP3611260A1 (fr) 2013-07-29 2020-02-19 Novozymes A/S Variants de protéase et polynucléotides les codants
US20200181542A1 (en) * 2017-06-30 2020-06-11 Novozymes A/S Enzyme Slurry Composition
EP3690037A1 (fr) 2014-12-04 2020-08-05 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
WO2020188095A1 (fr) 2019-03-21 2020-09-24 Novozymes A/S Variants d'alpha-amylase et polynucléotides codant pour ceux-ci
WO2020207944A1 (fr) 2019-04-10 2020-10-15 Novozymes A/S Variants polypeptidiques
EP3739029A1 (fr) 2014-07-04 2020-11-18 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP3786269A1 (fr) 2013-06-06 2021-03-03 Novozymes A/S Variants d'alpha-amylase et polynucléotides les codant
WO2021037895A1 (fr) 2019-08-27 2021-03-04 Novozymes A/S Composition détergente
WO2021053127A1 (fr) 2019-09-19 2021-03-25 Novozymes A/S Composition détergente
WO2021064068A1 (fr) 2019-10-03 2021-04-08 Novozymes A/S Polypeptides comprenant au moins deux domaines de liaison aux hydrates de carbone
EP3872175A1 (fr) 2015-06-18 2021-09-01 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP3878960A1 (fr) 2014-07-04 2021-09-15 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP3892708A1 (fr) 2020-04-06 2021-10-13 Henkel AG & Co. KGaA Compositions de nettoyage comprenant des variantes de dispersine
WO2022074037A2 (fr) 2020-10-07 2022-04-14 Novozymes A/S Variants d'alpha-amylase
WO2022171780A2 (fr) 2021-02-12 2022-08-18 Novozymes A/S Variants d'alpha-amylase
WO2022268885A1 (fr) 2021-06-23 2022-12-29 Novozymes A/S Polypeptides d'alpha-amylase
WO2024131880A2 (fr) 2022-12-23 2024-06-27 Novozymes A/S Composition détergente comprenant une catalase et une amylase

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2010299607B2 (en) * 2009-09-25 2016-07-28 Tonix Medicines, Inc. Formulations comprising triptan compounds
CN102277238B (zh) * 2011-07-13 2012-10-03 杭州迪康生物技术有限公司 一种颗粒状含mes组合物
CN106221952A (zh) * 2016-07-26 2016-12-14 紫罗兰家纺科技股份有限公司 一种益生菌防螨家用纺织品洗涤剂及其洗涤方法
US11499124B2 (en) 2020-03-13 2022-11-15 YFY Consumer Products, Co. Solid granules used for cleaning agents
US11767495B2 (en) 2020-03-13 2023-09-26 YFY Consumer Products, Co. Systems and methods for manufacturing solid granules

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4194986A (en) * 1977-02-02 1980-03-25 Union Generale De Savonnerie Powdered or flaked washing compositions adapted to automatic laundry machines

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2134978A1 (fr) * 1992-05-08 1993-11-25 Ann M. Wolff Compositions granulaires de detergent contenant de la lipase
CA2176697C (fr) * 1993-12-21 2000-01-11 Michael Alan John Moss Composition detergente contenant du percarbonate et de l'amylase

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4194986A (en) * 1977-02-02 1980-03-25 Union Generale De Savonnerie Powdered or flaked washing compositions adapted to automatic laundry machines

Cited By (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8110703B2 (en) 2008-05-30 2012-02-07 Anhui Medical University Retinoid derivative and pharmaceutical composition and use thereof
EP2840134A1 (fr) 2010-04-26 2015-02-25 Novozymes A/S Granules enzymatiques
WO2011134809A1 (fr) 2010-04-26 2011-11-03 Novozymes A/S Granules enzymatiques
EP2569406A1 (fr) * 2010-05-14 2013-03-20 The Sun Products Corporation Compositions nettoyantes contenant des polymères et procédés de production et d'utilisation associés
EP2569406A4 (fr) * 2010-05-14 2013-11-13 Sun Products Corp Compositions nettoyantes contenant des polymères et procédés de production et d'utilisation associés
US9464261B2 (en) 2010-05-14 2016-10-11 The Sun Products Corporation Polymer-containing cleaning compositions and methods of production and use thereof
WO2012175401A2 (fr) 2011-06-20 2012-12-27 Novozymes A/S Composition particulaire
WO2012175708A2 (fr) 2011-06-24 2012-12-27 Novozymes A/S Polypeptides ayant une activité de protéase et polynucléotides les codant
EP4026901A2 (fr) 2011-06-30 2022-07-13 Novozymes A/S Procédé de criblage d'alpha-amylases
WO2013001087A2 (fr) 2011-06-30 2013-01-03 Novozymes A/S Procédé de criblage d'alpha-amylases
EP3543333A2 (fr) 2011-06-30 2019-09-25 Novozymes A/S Procédé de criblage d'alpha-amylases
WO2013007594A1 (fr) 2011-07-12 2013-01-17 Novozymes A/S Granulés enzymatiques stables au stockage
WO2013024021A1 (fr) 2011-08-15 2013-02-21 Novozymes A/S Polypeptides ayant une activité cellulase et polynucléotides codant pour ceux-ci
WO2013041689A1 (fr) 2011-09-22 2013-03-28 Novozymes A/S Polypeptides ayant une activité protéase et polynucléotides codant pour ceux-ci
WO2013076269A1 (fr) 2011-11-25 2013-05-30 Novozymes A/S Variants de subtilase et polynucléotides codants pour ceux-ci
WO2013092635A1 (fr) 2011-12-20 2013-06-27 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
WO2013110766A1 (fr) 2012-01-26 2013-08-01 Novozymes A/S Utilisation de polypeptides à activité protéasique dans les aliments pour animaux et les détergents
WO2013120948A1 (fr) 2012-02-17 2013-08-22 Novozymes A/S Variants de subtilisine et polynucléotides codant ces derniers
WO2013131964A1 (fr) 2012-03-07 2013-09-12 Novozymes A/S Composition détergente et substitution d'azurants optiques dans des compositions détergentes
WO2013167581A1 (fr) 2012-05-07 2013-11-14 Novozymes A/S Polypeptides ayant une activité de décomposition du xanthane et polynucléotides codant pour ceux-ci
WO2013189972A2 (fr) 2012-06-20 2013-12-27 Novozymes A/S Utilisation de polypeptides ayant une activité protéase dans des aliments pour animaux et des détergents
WO2014096259A1 (fr) 2012-12-21 2014-06-26 Novozymes A/S Polypeptides possédant une activité protéasique et polynucléotides codant pour ceux-ci
EP3321360A2 (fr) 2013-01-03 2018-05-16 Novozymes A/S Variants d'alpha-amylase et polynucléotides les codant
WO2014183921A1 (fr) 2013-05-17 2014-11-20 Novozymes A/S Polypeptides présentant une activité alpha-amylase
EP3786269A1 (fr) 2013-06-06 2021-03-03 Novozymes A/S Variants d'alpha-amylase et polynucléotides les codant
WO2014207227A1 (fr) 2013-06-27 2014-12-31 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
WO2014207224A1 (fr) 2013-06-27 2014-12-31 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
WO2015001017A2 (fr) 2013-07-04 2015-01-08 Novozymes A/S Polypeptides présentant un effet anti-redéposition et polynucléotides codant pour ceux-ci
EP3611260A1 (fr) 2013-07-29 2020-02-19 Novozymes A/S Variants de protéase et polynucléotides les codants
EP3613853A1 (fr) 2013-07-29 2020-02-26 Novozymes A/S Variants de protéase et polynucléotides les codants
EP2832853A1 (fr) 2013-07-29 2015-02-04 Henkel AG&Co. KGAA Composition détergente comprenant des variantes de protéases
EP3339436A1 (fr) 2013-07-29 2018-06-27 Henkel AG & Co. KGaA Composition détergente comprenant des variantes de protéases
EP3309249A1 (fr) 2013-07-29 2018-04-18 Novozymes A/S Variants de protéases et polynuclétides les codant
WO2015049370A1 (fr) 2013-10-03 2015-04-09 Novozymes A/S Composition détergente et utilisation de celle-ci
EP3453757A1 (fr) 2013-12-20 2019-03-13 Novozymes A/S Polypeptides a activite de protease et polynucleotides les codant
WO2015134737A1 (fr) 2014-03-05 2015-09-11 Novozymes A/S Compositions et procédés pour améliorer les propriétés de matières textiles cellulosiques avec une xyloglucane endotransglycosylase
WO2015134729A1 (fr) 2014-03-05 2015-09-11 Novozymes A/S Compositions et procédés destinés à améliorer les propriétés de matériaux textiles non-cellulosiques par l'utilisation d'endo-xyloglucane transférase
WO2015150457A1 (fr) 2014-04-01 2015-10-08 Novozymes A/S Polypeptides présentant une activité alpha-amylase
WO2015189371A1 (fr) 2014-06-12 2015-12-17 Novozymes A/S Variants d'alpha-amylase et polynucléotides codant pour ces derniers
EP3739029A1 (fr) 2014-07-04 2020-11-18 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP3878960A1 (fr) 2014-07-04 2021-09-15 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
WO2016079305A1 (fr) 2014-11-20 2016-05-26 Novozymes A/S Variants de alicyclobacillus et polynucléotides codant pour ceux-ci
EP3690037A1 (fr) 2014-12-04 2020-08-05 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
US10760036B2 (en) 2014-12-15 2020-09-01 Henkel Ag & Co. Kgaa Detergent composition comprising subtilase variants
EP3608403A2 (fr) 2014-12-15 2020-02-12 Henkel AG & Co. KGaA Composition détergente comprenant des variantes de subtilase
EP4071244A1 (fr) 2015-06-18 2022-10-12 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP3106508A1 (fr) 2015-06-18 2016-12-21 Henkel AG & Co. KGaA Composition détergente comprenant des variantes de subtilase
EP3872175A1 (fr) 2015-06-18 2021-09-01 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP4324919A2 (fr) 2015-10-14 2024-02-21 Novozymes A/S Variants polypeptidiques
WO2017064269A1 (fr) 2015-10-14 2017-04-20 Novozymes A/S Variants polypeptidiques
WO2017064253A1 (fr) 2015-10-14 2017-04-20 Novozymes A/S Polypeptides ayant une activité de protéase et polynucléotides codant pour ceux-ci
WO2017207762A1 (fr) 2016-06-03 2017-12-07 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP3950941A2 (fr) 2016-07-13 2022-02-09 Novozymes A/S Variants polypeptidiques de la dnase
WO2018011277A1 (fr) 2016-07-13 2018-01-18 Novozymes A/S Variants dnases de bacillus cibi
WO2018011276A1 (fr) 2016-07-13 2018-01-18 The Procter & Gamble Company Variants dnase de bacillus cibi et leurs utilisations
US20200181542A1 (en) * 2017-06-30 2020-06-11 Novozymes A/S Enzyme Slurry Composition
WO2019081724A1 (fr) 2017-10-27 2019-05-02 Novozymes A/S Variants de dnase
WO2019084349A1 (fr) 2017-10-27 2019-05-02 The Procter & Gamble Company Compositions détergentes comprenant des variants polypeptidiques
WO2019081721A1 (fr) 2017-10-27 2019-05-02 Novozymes A/S Variants de la dnase
WO2019201793A1 (fr) 2018-04-17 2019-10-24 Novozymes A/S Polypeptides ayant une activité de liaison des hydrates de carbone dans des compositions détergentes et leur utilisation pour réduire les plis de textiles ou de tissus
WO2020188095A1 (fr) 2019-03-21 2020-09-24 Novozymes A/S Variants d'alpha-amylase et polynucléotides codant pour ceux-ci
WO2020207944A1 (fr) 2019-04-10 2020-10-15 Novozymes A/S Variants polypeptidiques
WO2021037895A1 (fr) 2019-08-27 2021-03-04 Novozymes A/S Composition détergente
WO2021053127A1 (fr) 2019-09-19 2021-03-25 Novozymes A/S Composition détergente
WO2021064068A1 (fr) 2019-10-03 2021-04-08 Novozymes A/S Polypeptides comprenant au moins deux domaines de liaison aux hydrates de carbone
EP3892708A1 (fr) 2020-04-06 2021-10-13 Henkel AG & Co. KGaA Compositions de nettoyage comprenant des variantes de dispersine
WO2022074037A2 (fr) 2020-10-07 2022-04-14 Novozymes A/S Variants d'alpha-amylase
WO2022171780A2 (fr) 2021-02-12 2022-08-18 Novozymes A/S Variants d'alpha-amylase
WO2022268885A1 (fr) 2021-06-23 2022-12-29 Novozymes A/S Polypeptides d'alpha-amylase
WO2024131880A2 (fr) 2022-12-23 2024-06-27 Novozymes A/S Composition détergente comprenant une catalase et une amylase

Also Published As

Publication number Publication date
TR201810838T4 (tr) 2018-08-27
CN101688152B (zh) 2012-06-27
BRPI0813386A2 (pt) 2014-12-30
CN101688152A (zh) 2010-03-31
CL2008001858A1 (es) 2009-03-06
EP2162522A1 (fr) 2010-03-17
AR067053A1 (es) 2009-09-30
EP2162522B1 (fr) 2018-07-04

Similar Documents

Publication Publication Date Title
EP2162522B1 (fr) Compositions détergentes enzymatiques granulaires
US20040110656A1 (en) Detergent compositions
JPH09509204A (ja) 無定形ケイ酸塩ビルダー物質を含む洗剤
ZA200501217B (en) Detergent compositions
CA2445045C (fr) Composition detergente de blanchisserie, en particules, contenant des zeolites
CA2402332C (fr) Composition de detergent a lessive particulaire contenant deux composants granulaires ayant des densites apparentes distinctes
US5958871A (en) Detergent composition based on zeolite-bicarbonate builder mixture
GB2287948A (en) Laundry detergent composition
EP1436378B1 (fr) Compositions detergentes contenant du carbonate de potassium et leur procede de preparation
EP1527155B2 (fr) Compositions detergentes
GB2303858A (en) Detergent composition
GB2296919A (en) Detergent composition
US20030114347A1 (en) Detergent compositions
WO2004027004A1 (fr) Compositions de detergents
BRPI0813386B1 (pt) Granular detergent composition, process for washing textile tissues through machine or manually and process for the manufacture of a granular detergent composition
WO1997012025A1 (fr) Composition detergente comprenant un melange d'adjuvant bicarbonate-zeolite
EP0859824A1 (fr) Composition detergente
EP0880578A1 (fr) Composition detergente comportant de la zeolite et une enzyme proteolytique
MXPA98002408A (en) Deterge composition
MXPA98002501A (en) Detergent composition containing a zeolite detergent improvement and a lubricant for elmi

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880021387.1

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08760075

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 2008760075

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2208/MUMNP/2009

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 12009502344

Country of ref document: PH

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: PI0813386

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20091218