WO2008136718A1 - Apparatus for treating material comprising pressure vessel with drum rotatably arranged inside - Google Patents

Apparatus for treating material comprising pressure vessel with drum rotatably arranged inside Download PDF

Info

Publication number
WO2008136718A1
WO2008136718A1 PCT/SE2007/050307 SE2007050307W WO2008136718A1 WO 2008136718 A1 WO2008136718 A1 WO 2008136718A1 SE 2007050307 W SE2007050307 W SE 2007050307W WO 2008136718 A1 WO2008136718 A1 WO 2008136718A1
Authority
WO
WIPO (PCT)
Prior art keywords
drum
pressure vessel
opening
inner space
door
Prior art date
Application number
PCT/SE2007/050307
Other languages
French (fr)
Inventor
Per-Arne FRÖDERBERG
Melvin R. Madeley
Anna-Lena Seedhill
Original Assignee
Sanciflex Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanciflex Ab filed Critical Sanciflex Ab
Priority to PCT/SE2007/050307 priority Critical patent/WO2008136718A1/en
Priority to EP07748468.1A priority patent/EP2148739B1/en
Priority to ES07748468.1T priority patent/ES2537316T3/en
Priority to CA2686705A priority patent/CA2686705C/en
Publication of WO2008136718A1 publication Critical patent/WO2008136718A1/en
Priority to US12/613,780 priority patent/US8431085B2/en
Priority to NO20093342A priority patent/NO341539B1/en
Priority to AU2009238262A priority patent/AU2009238262A1/en
Priority to US13/873,027 priority patent/US8747771B2/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/02Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
    • A61L2/04Heat
    • A61L2/06Hot gas
    • A61L2/07Steam
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L11/00Methods specially adapted for refuse
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F29/00Mixers with rotating receptacles
    • B01F29/60Mixers with rotating receptacles rotating about a horizontal or inclined axis, e.g. drum mixers
    • B01F29/63Mixers with rotating receptacles rotating about a horizontal or inclined axis, e.g. drum mixers with fixed bars, i.e. stationary, or fixed on the receptacle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/002Component parts of these vessels not mentioned in B01J3/004, B01J3/006, B01J3/02 - B01J3/08; Measures taken in conjunction with the process to be carried out, e.g. safety measures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/03Pressure vessels, or vacuum vessels, having closure members or seals specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/04Pressure vessels, e.g. autoclaves

Definitions

  • Apparatus for treating material comprising pressure vessel with drum rotatably arranged inside
  • the present invention relates to a material treatment apparatus comprising:
  • the inventive apparatus is particularly intended to be used for treating material in the form of waste by steam at high pressure.
  • waste such as for instance household waste
  • an autoclave in which the waste is subjected to steam at suitable pressure and temperature so as to thereby sterilize the waste and make it safe to handle during the subsequent treatment thereof.
  • the processing of waste in an autoclave will also give other benefits.
  • organic material within the waste is broken down by the treatment in the autoclave to form a mass of small cellulose particles.
  • plastic objects are reduced in size during the processing in the autoclave and labels and printings on packages of metal, glass and plastic are removed.
  • the mass of cellulose particles may be used for different applications and the remaining waste leaving the autoclave can easily be sorted in order to remove recyclable matter.
  • a waste treatment autoclave is previously known from WO 2006/056768 A2.
  • This autoclave comprises a pressure vessel which is rotatable about its longitudinal axis in order to agi- tate waste received inside the pressure vessel.
  • This known autoclave also comprises an internal helix structure projecting from the inner side of the pressure vessel so as to act on waste received in the pressure vessel as the pressure vessel rotates.
  • the object of the present invention is to propose a new and advantageous apparatus for treating material, for instance material in the form of waste, under agitation and at a pressure above or below that of the atmosphere.
  • the inventive apparatus comprises:
  • the agitation means comprises a drum, which is rotatably arranged inside the pressure vessel so as to be rotatable in relation to the pressure vessel and which has an inner space for receiving material that is introduced into the pressure vessel via said opening of the pressure vessel, the drum having a cylindri- cal wall designed to prevent material received in the inner space of the drum from falling into the interspace between the drum and the pressure vessel as the drum rotates in relation to the pressure vessel;
  • the agitation means comprises one or several agitation blades mounted along the inner side of said cylindrical wall of the drum so as to act on material received in the inner space of the drum as the drum rotates in relation to the pressure vessel; and - that the apparatus comprises drive means for rotating the drum in relation to the pressure vessel.
  • the desired agitation of material treated in the pressure vessel is accomplished in an efficient and simple manner without having to rotate the pressure vessel itself.
  • the pressure vessel may consequently be fixed, which offers several advantages as compared to a rotatably arranged pressure vessel. It is for instance much easier to accomplish a secure and pressure tight clamping of a door to a fixed pressure vessel as compared to a rotary pressure vessel, owing to the fact that the clamping means clamping the door to a fixed pressure vessel do not have to be rotatably arranged. This will facilitate the use of robust and reliable clamping means, which for instance may be hydraulically, pneumatically or electrically actuated.
  • the drum has an open end projecting through said opening of the pressure vessel, said door being arranged to close the opening of the pressure vessel as well as the opening at this open end of the drum. Owing to the fact that this open end of the drum extends beyond the associated opening of the pressure vessel, material is prevented from falling down into the interspace between the pressure vessel and the drum when being feed into or discharged out of the inner space of the drum.
  • Fig 1 is a partly cut lateral view of an apparatus according to the present invention, with an inlet arrangement for steam and compressed air shown in a detail enlarge- ment,
  • Fig 2 is a schematic cross-sectional view along the line II-II in Fig 1 ,
  • Fig 3 is a schematic cross-sectional view along the line III-
  • Fig 4 is a schematic cross-sectional view along the line IV-
  • Fig 5 is a schematic lateral view of a part of the apparatus of Fig 1 with closed door
  • Fig 6 is a schematic front view of the apparatus of Fig 1 with closed door
  • Fig 7 is a schematic perspective view of a part of the apparatus of Fig 1 with open door.
  • Fig 1 schematically illustrates an apparatus 1 according to the present invention for treating material, for instance material in the form of waste.
  • the apparatus 1 comprises an elongated pressure vessel 2, which is secured to a support structure 3 in the form of a frame, a base or the similar.
  • the pressure vessel 2 has an opening 4 at one end for feeding material into and dis- charging material out of the pressure vessel.
  • this opening 4 constitutes an inlet opening for material to be treated in the pressure vessel and also an outlet opening for material treated therein.
  • the opening 4 is closable by means of a pressure tight door 5, which in the illustrated example is hingedly mounted to the pressure vessel 2 via a hinge 6.
  • the apparatus comprises hydraulically, pneumatically or electrically actuated clamping means 10 (see Figs 5-7) for clamping the door 5 tightly to the pressure vessel 2 when the door is in its closed position.
  • the clamping means 10 suitably comprises two or more clamping members 1 1 distributed about the opening 4.
  • the respective clamping member 1 1 has the form of a hook, which is connected to the piston 12 of a hydraulic cylinder 13 so as to be displaceable between a locking position (see Fig 5), in which the clamping member 1 1 is in engagement with a pin 7 extending from the door 5 so as to force the rim of the door into pressure tight engagement with the pressure vessel, and an unlocking position, in which the clamping member 11 is out of engagement with the associated pin 7 so as to allow the door 5 to be moved from its closed position (indicated by continuous lines in Fig 5) to its open position (indicated by broken lines in Fig 5).
  • the clamping means 10 could be secured to the pressure vessel 2 or to the support structure 3.
  • the clamping means 10 could of course also be designed in other manners than here M- lustrated.
  • the pressure vessel could be provided with an inlet opening at one end for feeding material into the pressure vessel and an outlet opening at the opposite end for discharging material out of the pressure vessel, with a closable door at the respective opening.
  • the apparatus 1 further comprises agitation means for agitating material received in the pressure vessel 2.
  • the agitation means comprises a drum 20, which is rotatably arranged inside the pressure vessel 2 so as to be rotatable in relation to the pressure vessel.
  • the drum 20 has an inner space 21 for receiving material that is introduced into the pressure vessel via the opening 4 of the pressure vessel.
  • the drum 20 has a cylindrical wall 22 designed to prevent material received in the inner space 21 of the drum from falling into the interspace 23 between the drum 20 and the pressure vessel 2 as the drum rotates in relation to the pressure vessel.
  • the drum 20 is rotatable about its longitudinal axis and is arranged with its longitudinal axis extending in a horizontal or at least essentially horizontal direction.
  • the drum 20 rests on rollers 24, which are rotatably mounted inside the pressure vessel 2, as illustrated in Figs 1 and 3. In the illustrated example, the rollers 24 are idle rollers arranged in pairs at two or more locations along the drum.
  • the drum 20 is rotated in relation to the pressure vessel 2 by means of suitable drive means 30 (see Figs 1 and 2).
  • the drive means 30 comprises a reversible motor 31 , for instance a hydraulic motor, arranged inside the pressure vessel 2.
  • the motor 31 drives a rotatably mounted gearwheel 32 via a reduction gear 33.
  • the gear wheel 32 en- gages with a gear ring 34, which is fixedly secured to the outer side of the drum 20 and surrounds the drum.
  • the gear ring 34 and thereby the drum 20 is rotated in the desired direction when the gear wheel 32 is put into rotation by the motor 31.
  • the drive means 30 could of course also be designed in other manners than here illustrated.
  • the agitation means further comprises at least one agitation blade 25 mounted along the inner side of the cylindrical wall 22 of the drum so as to act on material received in the inner space 21 of the drum as the drum rotates in relation to the pressure vessel 2.
  • the agitation blade 25 is fixed to the cylindrical wall 22 of the drum so as to rotate together with the drum and it extends in a helical path in the axial direction of said cylindrical wall 22, i.e. in the longitudinal direction of the drum 20, and is suitably a screw-shaped blade.
  • the agitation blade 25 may extend continuously along the cylindrical wall 22 from one end to the other end thereof or be divided into separate parts with intermediate gaps.
  • the agitation blade 25 is arranged to move material received in the inner space 21 of the drum 20 forward away from the opening 4 of the pressure vessel when the drum 20 is rotated by the drive means 30 in a first direction and backward towards said opening 4 when the drum is rotated by the drive means in a second direction opposite said first direction.
  • the drum 20 is to be rotated in said first direction when material is feed into the inner space 21 of the drum via the opening 4 and in the opposite direction when the material is to be discharged out of the opening 4.
  • the drum 20 has an open end 26 projecting through the opening 4 of the pressure vessel 2, as illustrated in Figs 1 and 7.
  • this end 26 of the drum extends beyond the corresponding end of the pressure vessel 2 and material may consequently be feed into and discharged out of the inner space 21 of the drum without falling down onto the bottom of the pressure vessel 2.
  • the door 5 is arranged to close the opening 4 of the pressure vessel as well as the opening
  • a small gap 28 is suitably provided between the rim of the opening 27 and the door 5 when the door is in its closed position so as to allow the drum 20 to rotate freely in relation to the door.
  • a conveyor 40 for instance in the form of a belt conveyor, may be arranged under the pressure vessel 2 below the opening 27 of the drum (see Fig 5) so as to receive material discharged out of the drum and carry this material away for further processing.
  • the apparatus 1 further comprises pressure regulating means 50 for generating a pressure inside the pressure vessel 2 above or below that of the atmosphere.
  • the inner space 21 of the drum 20 is arranged to be in communication with the interspace 23 between the drum and the pressure vessel 2 so as to secure that there is no pressure difference between the inner side and the outer side of the drum.
  • the pressure regulating means 50 may be arranged to generate an overpressure inside the pressure vessel 2 by feeding compressed air and/or compressed steam into the pressure vessel and may be arranged to generate vacuum inside the pressure vessel by exhausting air out of the pressure vessel by suction.
  • the pressure regulating means 50 comprises an air supply conduit 51 extending into the inner space 21 of the drum through a pressure tight lead-through 52 at the closed end of the pressure vessel 2 and through a cen- tral opening 29 at the inner end of the drum 20, as illustrated in the detail enlargement of Fig 1.
  • An air outlet nozzle 53 is provided in the inner space 21 of the drum at the end of the air supply conduit 51.
  • the pressure regulating means 50 could of course also be designed in other manners than here illustrated.
  • the apparatus 1 further comprises steam supply means 60 for supplying steam into the inner space 21 of the drum.
  • the steam supply means 60 comprises a steam supply conduit 61 extending into the inner space 21 of the drum through a pressure tight lead-through 62 at the closed end of the pressure vessel 2 and through the opening 29 at the inner end of the drum 20, as illustrated in the detail enlargement of Fig 1.
  • a steam outlet nozzle 63 is provided in the inner space 21 of the drum at the end of the steam supply conduit 61.
  • the steam sup- ply means 60 could of course also be designed in other manners than here illustrated.
  • One or several steam outlets is/are arranged in the pressure vessel 2 and/or the door 5. In the illustrated example, the door 5 is provided with such an outlet 8.
  • the apparatus 1 further comprises heating means 70 for heating material received in the inner space 21 of the drum.
  • the temperature in the inner space 21 of the drum may be controlled by means of the heating means 70 so as to achieve a desired temperature level suitable for the material treatment.
  • the heating means 70 comprises heating members 71 (see Figs 1 and 4) in the form of interconnected water conduits extending along a part of the drum 20 in the interspace 23 between the drum and the pressure vessel 2. These heating members 71 are connected to a hot water supply (not shown) via a feeding conduit 72 extending through a pressure tight lead- through 73 in the pressure vessel and a return conduit 74 ex- tending through a pressure tight lead-through 75 in the pressure vessel.
  • the heating means 70 could of course also be designed in other manners than here illustrated.
  • the heating means could for instance comprise heating members located on the outside of the pressure vessel.
  • the heating means could also comprise electric heating members or any other suitable type of heating members.
  • the inventive apparatus 1 may with advantage constitute an autoclave, particularly an autoclave for treating material in the form of waste.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)
  • Disintegrating Or Milling (AREA)

Abstract

An apparatus for treating material comprising a pressure vessel (2) and agitation means for agitating material received in the pressure vessel. The agitation means comprises a drum (20), which is rotatably arranged inside the pressure vessel (2) and which has an inner space (21 ) for receiving material that is introduced into the pressure vessel. The agitation means also comprises one or several agitation blades (25) mounted along the inner side of the cylindrical wall (22) of the drum so as to act on material received in the inner space (21 ) of the drum as the drum (20) rotates in relation to the pressure vessel. Drive means (30) is provided for rotating the drum in relation to the pressure vessel.

Description

Apparatus for treating material comprising pressure vessel with drum rotatably arranged inside
FIELD OF THE INVENTION AND PRIOR ART
The present invention relates to a material treatment apparatus comprising:
- a pressure vessel having at least one opening for feeding material into the pressure vessel;
- a door for closing said opening of the pressure vessel; - pressure regulating means for generating a pressure inside the pressure vessel above or below that of the atmosphere; and
- agitation means for agitating material received in the pressure vessel.
The inventive apparatus is particularly intended to be used for treating material in the form of waste by steam at high pressure.
BACKGROUND ART
It is known to process waste, such as for instance household waste, in an autoclave, in which the waste is subjected to steam at suitable pressure and temperature so as to thereby sterilize the waste and make it safe to handle during the subsequent treatment thereof. The processing of waste in an autoclave will also give other benefits. As an example, organic material within the waste is broken down by the treatment in the autoclave to form a mass of small cellulose particles. Furthermore, plastic objects are reduced in size during the processing in the autoclave and labels and printings on packages of metal, glass and plastic are removed. The mass of cellulose particles may be used for different applications and the remaining waste leaving the autoclave can easily be sorted in order to remove recyclable matter.
A waste treatment autoclave is previously known from WO 2006/056768 A2. This autoclave comprises a pressure vessel which is rotatable about its longitudinal axis in order to agi- tate waste received inside the pressure vessel. This known autoclave also comprises an internal helix structure projecting from the inner side of the pressure vessel so as to act on waste received in the pressure vessel as the pressure vessel rotates.
DISCLOSURE OF THE INVENTION
The object of the present invention is to propose a new and advantageous apparatus for treating material, for instance material in the form of waste, under agitation and at a pressure above or below that of the atmosphere.
According to the invention, this object is achieved by an apparatus having the features defined in claim 1.
The inventive apparatus comprises:
- a pressure vessel having at least one opening for feeding material into the pressure vessel;
- a door for closing said opening of the pressure vessel; - pressure regulating means for generating a pressure inside the pressure vessel above or below that of the atmosphere; and
- agitation means for agitating material received in the pressure vessel, and is characterized in: - that the agitation means comprises a drum, which is rotatably arranged inside the pressure vessel so as to be rotatable in relation to the pressure vessel and which has an inner space for receiving material that is introduced into the pressure vessel via said opening of the pressure vessel, the drum having a cylindri- cal wall designed to prevent material received in the inner space of the drum from falling into the interspace between the drum and the pressure vessel as the drum rotates in relation to the pressure vessel;
- that the agitation means comprises one or several agitation blades mounted along the inner side of said cylindrical wall of the drum so as to act on material received in the inner space of the drum as the drum rotates in relation to the pressure vessel; and - that the apparatus comprises drive means for rotating the drum in relation to the pressure vessel.
With the inventive solution, the desired agitation of material treated in the pressure vessel is accomplished in an efficient and simple manner without having to rotate the pressure vessel itself. The pressure vessel may consequently be fixed, which offers several advantages as compared to a rotatably arranged pressure vessel. It is for instance much easier to accomplish a secure and pressure tight clamping of a door to a fixed pressure vessel as compared to a rotary pressure vessel, owing to the fact that the clamping means clamping the door to a fixed pressure vessel do not have to be rotatably arranged. This will facilitate the use of robust and reliable clamping means, which for instance may be hydraulically, pneumatically or electrically actuated. Furthermore, it is easier to mount suitable inlet conduits for steam, compressed air etc in a reliable and pressure tight manner to a fixed pressure vessel as compared to a rotary pressure vessel. The use of a fixed pressure vessel as compared to a rotary pressure vessel will also make it easier to mount suitable heating members to the pressure vessel in order to achieve heating of material received in the pressure vessel.
According to an embodiment of the invention, the drum has an open end projecting through said opening of the pressure vessel, said door being arranged to close the opening of the pressure vessel as well as the opening at this open end of the drum. Owing to the fact that this open end of the drum extends beyond the associated opening of the pressure vessel, material is prevented from falling down into the interspace between the pressure vessel and the drum when being feed into or discharged out of the inner space of the drum.
Further advantageous features of the apparatus according to the invention are indicated in the dependent claims and the following description. BRIEF DESCRIPTION OF THE DRAWINGS
With reference to the appended drawings, a specific description of preferred embodiments of the invention cited as examples fol- lows below. In the drawings:
Fig 1 is a partly cut lateral view of an apparatus according to the present invention, with an inlet arrangement for steam and compressed air shown in a detail enlarge- ment,
Fig 2 is a schematic cross-sectional view along the line II-II in Fig 1 ,
Fig 3 is a schematic cross-sectional view along the line III-
III in Fig 1 ,
Fig 4 is a schematic cross-sectional view along the line IV-
IV in Fig 1 ,
Fig 5 is a schematic lateral view of a part of the apparatus of Fig 1 with closed door,
Fig 6 is a schematic front view of the apparatus of Fig 1 with closed door, and
Fig 7 is a schematic perspective view of a part of the apparatus of Fig 1 with open door.
MODES FOR CARRYING OUT THE INVENTION
Fig 1 schematically illustrates an apparatus 1 according to the present invention for treating material, for instance material in the form of waste. The apparatus 1 comprises an elongated pressure vessel 2, which is secured to a support structure 3 in the form of a frame, a base or the similar. The pressure vessel 2 has an opening 4 at one end for feeding material into and dis- charging material out of the pressure vessel. Thus, this opening 4 constitutes an inlet opening for material to be treated in the pressure vessel and also an outlet opening for material treated therein. The opening 4 is closable by means of a pressure tight door 5, which in the illustrated example is hingedly mounted to the pressure vessel 2 via a hinge 6. The apparatus comprises hydraulically, pneumatically or electrically actuated clamping means 10 (see Figs 5-7) for clamping the door 5 tightly to the pressure vessel 2 when the door is in its closed position. The clamping means 10 suitably comprises two or more clamping members 1 1 distributed about the opening 4. In the illustrated example, the respective clamping member 1 1 has the form of a hook, which is connected to the piston 12 of a hydraulic cylinder 13 so as to be displaceable between a locking position (see Fig 5), in which the clamping member 1 1 is in engagement with a pin 7 extending from the door 5 so as to force the rim of the door into pressure tight engagement with the pressure vessel, and an unlocking position, in which the clamping member 11 is out of engagement with the associated pin 7 so as to allow the door 5 to be moved from its closed position (indicated by continuous lines in Fig 5) to its open position (indicated by broken lines in Fig 5). The clamping means 10 could be secured to the pressure vessel 2 or to the support structure 3. The clamping means 10 could of course also be designed in other manners than here M- lustrated.
As an alternative, the pressure vessel could be provided with an inlet opening at one end for feeding material into the pressure vessel and an outlet opening at the opposite end for discharging material out of the pressure vessel, with a closable door at the respective opening.
The apparatus 1 further comprises agitation means for agitating material received in the pressure vessel 2. The agitation means comprises a drum 20, which is rotatably arranged inside the pressure vessel 2 so as to be rotatable in relation to the pressure vessel. The drum 20 has an inner space 21 for receiving material that is introduced into the pressure vessel via the opening 4 of the pressure vessel. The drum 20 has a cylindrical wall 22 designed to prevent material received in the inner space 21 of the drum from falling into the interspace 23 between the drum 20 and the pressure vessel 2 as the drum rotates in relation to the pressure vessel. The drum 20 is rotatable about its longitudinal axis and is arranged with its longitudinal axis extending in a horizontal or at least essentially horizontal direction. The drum 20 rests on rollers 24, which are rotatably mounted inside the pressure vessel 2, as illustrated in Figs 1 and 3. In the illustrated example, the rollers 24 are idle rollers arranged in pairs at two or more locations along the drum.
The drum 20 is rotated in relation to the pressure vessel 2 by means of suitable drive means 30 (see Figs 1 and 2). In the illustrated example, the drive means 30 comprises a reversible motor 31 , for instance a hydraulic motor, arranged inside the pressure vessel 2. The motor 31 drives a rotatably mounted gearwheel 32 via a reduction gear 33. The gear wheel 32 en- gages with a gear ring 34, which is fixedly secured to the outer side of the drum 20 and surrounds the drum. The gear ring 34 and thereby the drum 20 is rotated in the desired direction when the gear wheel 32 is put into rotation by the motor 31. The drive means 30 could of course also be designed in other manners than here illustrated.
The agitation means further comprises at least one agitation blade 25 mounted along the inner side of the cylindrical wall 22 of the drum so as to act on material received in the inner space 21 of the drum as the drum rotates in relation to the pressure vessel 2. The agitation blade 25 is fixed to the cylindrical wall 22 of the drum so as to rotate together with the drum and it extends in a helical path in the axial direction of said cylindrical wall 22, i.e. in the longitudinal direction of the drum 20, and is suitably a screw-shaped blade. The agitation blade 25 may extend continuously along the cylindrical wall 22 from one end to the other end thereof or be divided into separate parts with intermediate gaps. The agitation blade 25 is arranged to move material received in the inner space 21 of the drum 20 forward away from the opening 4 of the pressure vessel when the drum 20 is rotated by the drive means 30 in a first direction and backward towards said opening 4 when the drum is rotated by the drive means in a second direction opposite said first direction. Thus, the drum 20 is to be rotated in said first direction when material is feed into the inner space 21 of the drum via the opening 4 and in the opposite direction when the material is to be discharged out of the opening 4.
The drum 20 has an open end 26 projecting through the opening 4 of the pressure vessel 2, as illustrated in Figs 1 and 7. Thus, this end 26 of the drum extends beyond the corresponding end of the pressure vessel 2 and material may consequently be feed into and discharged out of the inner space 21 of the drum without falling down onto the bottom of the pressure vessel 2. This end
26 of the drum 20 is suitably tapered towards the opening 27 thereof, as illustrated in Figs 1 and 7. The door 5 is arranged to close the opening 4 of the pressure vessel as well as the opening
27 of the drum and has a part 5a arranged to extend into the opening 27 of the drum when the door is in its closed position. A small gap 28 is suitably provided between the rim of the opening 27 and the door 5 when the door is in its closed position so as to allow the drum 20 to rotate freely in relation to the door.
A conveyor 40, for instance in the form of a belt conveyor, may be arranged under the pressure vessel 2 below the opening 27 of the drum (see Fig 5) so as to receive material discharged out of the drum and carry this material away for further processing.
The apparatus 1 further comprises pressure regulating means 50 for generating a pressure inside the pressure vessel 2 above or below that of the atmosphere. The inner space 21 of the drum 20 is arranged to be in communication with the interspace 23 between the drum and the pressure vessel 2 so as to secure that there is no pressure difference between the inner side and the outer side of the drum. The pressure regulating means 50 may be arranged to generate an overpressure inside the pressure vessel 2 by feeding compressed air and/or compressed steam into the pressure vessel and may be arranged to generate vacuum inside the pressure vessel by exhausting air out of the pressure vessel by suction. In the illustrated example, the pressure regulating means 50 comprises an air supply conduit 51 extending into the inner space 21 of the drum through a pressure tight lead-through 52 at the closed end of the pressure vessel 2 and through a cen- tral opening 29 at the inner end of the drum 20, as illustrated in the detail enlargement of Fig 1. An air outlet nozzle 53 is provided in the inner space 21 of the drum at the end of the air supply conduit 51. The pressure regulating means 50 could of course also be designed in other manners than here illustrated.
The apparatus 1 further comprises steam supply means 60 for supplying steam into the inner space 21 of the drum. In the illustrated example, the steam supply means 60 comprises a steam supply conduit 61 extending into the inner space 21 of the drum through a pressure tight lead-through 62 at the closed end of the pressure vessel 2 and through the opening 29 at the inner end of the drum 20, as illustrated in the detail enlargement of Fig 1. A steam outlet nozzle 63 is provided in the inner space 21 of the drum at the end of the steam supply conduit 61. The steam sup- ply means 60 could of course also be designed in other manners than here illustrated. One or several steam outlets is/are arranged in the pressure vessel 2 and/or the door 5. In the illustrated example, the door 5 is provided with such an outlet 8.
The apparatus 1 further comprises heating means 70 for heating material received in the inner space 21 of the drum. The temperature in the inner space 21 of the drum may be controlled by means of the heating means 70 so as to achieve a desired temperature level suitable for the material treatment. In the illus- trated example, the heating means 70 comprises heating members 71 (see Figs 1 and 4) in the form of interconnected water conduits extending along a part of the drum 20 in the interspace 23 between the drum and the pressure vessel 2. These heating members 71 are connected to a hot water supply (not shown) via a feeding conduit 72 extending through a pressure tight lead- through 73 in the pressure vessel and a return conduit 74 ex- tending through a pressure tight lead-through 75 in the pressure vessel. The heating means 70 could of course also be designed in other manners than here illustrated. The heating means could for instance comprise heating members located on the outside of the pressure vessel. The heating means could also comprise electric heating members or any other suitable type of heating members.
The inventive apparatus 1 may with advantage constitute an autoclave, particularly an autoclave for treating material in the form of waste.
The invention is of course not in any way restricted to the embodiments described above. On the contrary, many possibilities to modifications thereof will be apparent to a person with ordi- nary skill in the art without departing from the basic idea of the invention as defined in the appended claims.

Claims

1 . An apparatus for treating material, for instance material in the form of waste, the apparatus (1 ) comprising: - a pressure vessel (2) having at least one opening (4) for feeding material into the pressure vessel;
- a door (5) for closing said opening (4) of the pressure vessel
(2);
- pressure regulating means (50) for generating a pressure in- side the pressure vessel (2) above or below that of the atmosphere; and
- agitation means for agitating material received in the pressure vessel (2), characterized in: - that the agitation means comprises a drum (20), which is rotatably arranged inside the pressure vessel (2) so as to be rotatable in relation to the pressure vessel and which has an inner space (21 ) for receiving material that is introduced into the pressure vessel via said opening (4) of the pressure ves- sel, the drum (20) having a cylindrical wall (22) designed to prevent material received in the inner space (21 ) of the drum from falling into the interspace (23) between the drum (20) and the pressure vessel (2) as the drum rotates in relation to the pressure vessel; - that the agitation means comprises one or several agitation blades (25) mounted along the inner side of said cylindrical wall (22) of the drum so as to act on material received in the inner space (21 ) of the drum as the drum (20) rotates in relation to the pressure vessel; and - that the apparatus (1 ) comprises drive means (30) for rotating the drum (20) in relation to the pressure vessel (2).
2. An apparatus according to claim 1 , characterized in that the respective agitation blade (25) extends in a helical path in the axial direction of said cylindrical wall (22) of the drum.
3. An apparatus according to claim 2, characterized in that the respective agitation blade (25) is a screw-shaped blade.
4. An apparatus according to any of claims 1 -3, characterized in that the respective agitation blade (25) is arranged to move material received in the inner space (21 ) of the drum (20) forward away from said opening (4) of the pressure vessel when the drum (20) is rotated by said drive means (30) in a first direction and backward towards said opening (4) of the pres- sure vessel when the drum (20) is rotated by said drive means
(30) in a second direction opposite said first direction.
5. An apparatus according to any of claims 1 -4, characterized in that the drum (20) is arranged with its longitudinal axis ex- tending in a horizontal or at least essentially horizontal direction.
6. An apparatus according to any of claims 1 -5, characterized in that the drum (20) has an open end (26) projecting through said opening (4) of the pressure vessel (2), and that said door
(5) is arranged to close the opening (4) of the pressure vessel as well as the opening (27) at this open end of the drum.
7. An apparatus according to claim 6, characterized in that the door (5) has a part (5a) arranged to extend into the opening
(27) at said open end (26) of the drum when the door is in its closed position.
8. An apparatus according to any of claims 1 -7, characterized in that the apparatus (1 ) comprises hydraulically, pneumatically or electrically actuated clamping means (10) for clamping the door (5) tightly to the pressure vessel (2) when the door is in its closed position.
9. An apparatus according to any of claims 1 -8, characterized in that the apparatus (1 ) comprises heating means (70) for heating material received in the inner space (21 ) of the drum.
10.An apparatus according to claim 9, characterized in that the heating means (70) comprises one or several heating members (71 ), for instance in the form of one or several water conduits, arranged in the interspace (23) between the drum
(20) and the pressure vessel (2).
1 1 .An apparatus according to any of claims 1 -10, characterized in that the apparatus (1 ) comprises steam supply means (60) for supplying steam into the inner space (21 ) of the drum (20).
12.An apparatus according to claim 1 1 , characterized in that the steam supply means (60) comprises a steam supply conduit
(61 ) extending into the inner space (21 ) of the drum through an opening (29) at the end of the drum facing away from said opening (4) of the pressure vessel.
13.An apparatus according to any of claims 1 -12, characterized in that the drum (20) rests on rollers (24), which are rotatably mounted inside the pressure vessel (2).
14.An apparatus according to any of claims 1 -13, characterized in that the apparatus (1 ) constitutes an autoclave.
PCT/SE2007/050307 2007-05-07 2007-05-07 Apparatus for treating material comprising pressure vessel with drum rotatably arranged inside WO2008136718A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
PCT/SE2007/050307 WO2008136718A1 (en) 2007-05-07 2007-05-07 Apparatus for treating material comprising pressure vessel with drum rotatably arranged inside
EP07748468.1A EP2148739B1 (en) 2007-05-07 2007-05-07 Apparatus for treating material comprising pressure vessel with drum rotatably arranged inside
ES07748468.1T ES2537316T3 (en) 2007-05-07 2007-05-07 Material treatment apparatus comprising a pressure vessel with drum rotatably disposed therein
CA2686705A CA2686705C (en) 2007-05-07 2007-05-07 Apparatus for treating material comprising pressure vessel with drum rotatably arranged inside
US12/613,780 US8431085B2 (en) 2007-05-07 2009-11-06 Apparatus for treating material comprising pressure vessel with drum rotatable arranged inside
NO20093342A NO341539B1 (en) 2007-05-07 2009-11-13 Apparatus for treating material comprising a pressure vessel with a drum rotatably arranged therein
AU2009238262A AU2009238262A1 (en) 2007-05-07 2009-11-13 Apparatus for treating material comprising pressure vessel with drum rotatable arranged inside
US13/873,027 US8747771B2 (en) 2007-05-07 2013-04-29 Apparatus for treating material comprising pressure vessel with drum rotatable arranged inside

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/SE2007/050307 WO2008136718A1 (en) 2007-05-07 2007-05-07 Apparatus for treating material comprising pressure vessel with drum rotatably arranged inside

Related Child Applications (3)

Application Number Title Priority Date Filing Date
US12613780 A-371-Of-International 2007-05-07
AU2009238262A Division AU2009238262A1 (en) 2007-05-07 2009-11-13 Apparatus for treating material comprising pressure vessel with drum rotatable arranged inside
US13/873,027 Continuation US8747771B2 (en) 2007-05-07 2013-04-29 Apparatus for treating material comprising pressure vessel with drum rotatable arranged inside

Publications (1)

Publication Number Publication Date
WO2008136718A1 true WO2008136718A1 (en) 2008-11-13

Family

ID=39943730

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE2007/050307 WO2008136718A1 (en) 2007-05-07 2007-05-07 Apparatus for treating material comprising pressure vessel with drum rotatably arranged inside

Country Status (6)

Country Link
US (2) US8431085B2 (en)
EP (1) EP2148739B1 (en)
CA (1) CA2686705C (en)
ES (1) ES2537316T3 (en)
NO (1) NO341539B1 (en)
WO (1) WO2008136718A1 (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2148739B1 (en) * 2007-05-07 2015-02-25 Sanciflex AB Apparatus for treating material comprising pressure vessel with drum rotatably arranged inside
GB201001375D0 (en) * 2010-01-28 2010-03-17 Aerothermal Group Plc Apparatus and process for treating municipal solid waste
US8991181B2 (en) 2011-05-02 2015-03-31 Harris Corporation Hybrid imbedded combined cycle
US9038389B2 (en) 2012-06-26 2015-05-26 Harris Corporation Hybrid thermal cycle with independent refrigeration loop
US20140026573A1 (en) * 2012-07-24 2014-01-30 Harris Corporation Hybrid thermal cycle with enhanced efficiency
US9297387B2 (en) 2013-04-09 2016-03-29 Harris Corporation System and method of controlling wrapping flow in a fluid working apparatus
US9574563B2 (en) 2013-04-09 2017-02-21 Harris Corporation System and method of wrapping flow in a fluid working apparatus
US9303514B2 (en) 2013-04-09 2016-04-05 Harris Corporation System and method of utilizing a housing to control wrapping flow in a fluid working apparatus
US9425591B2 (en) * 2013-10-31 2016-08-23 Schneider Electric Industries Sas ARC deflecting and ventilation assembly for electrical enclosures and systems for ARC deflecting and ventilation
CN103690987B (en) * 2013-12-18 2016-01-20 青岛福创环境科技有限公司 A kind of domestic waste mixing deodorizing device
US9303533B2 (en) 2013-12-23 2016-04-05 Harris Corporation Mixing assembly and method for combining at least two working fluids
US11124438B2 (en) 2020-01-20 2021-09-21 Chio Kang Medical, Inc. Alcaligenes faecalis for degrading ethylene oxide
US11085016B1 (en) 2020-01-20 2021-08-10 Chio Kang Medical, Inc. Method for screening bacteria capable of degrading ethylene oxide
US11130939B2 (en) 2020-01-20 2021-09-28 Chio Kang Medical, Inc. Bacteria for degrading ethylene oxide and uses thereof
US11220667B2 (en) 2020-01-20 2022-01-11 Chio Kang Medical, Inc. Bacteria for degrading ethylene oxide and applications thereof
US11103829B1 (en) 2020-03-18 2021-08-31 Chio Kang Medical, Inc. Systems and methods for treating ethylene oxide waste gas
US11130095B1 (en) 2020-03-18 2021-09-28 Chio Kang Medical, Inc. Sterilization exhaust gas treating system and method for treating ethylene oxide-containing sterilization exhaust gas by using the same
US11110390B1 (en) 2020-03-18 2021-09-07 Chio Kang Medical, Inc. Systems and methods for treating sterilization exhaust gas containing ethylene oxide
WO2021184605A1 (en) 2020-03-18 2021-09-23 Qiaokang Biotech (Guangdong) Co., LTD. Microbiological treatment system for ethylene oxide exhaust gas
US11125498B1 (en) 2020-03-18 2021-09-21 Chio Kang Medical, Inc. Gas liquefaction separator, gas liquefaction recovery system, and method for separating and recovering ethylene oxide
US11123680B1 (en) 2020-03-18 2021-09-21 Chio Kang Medical, Inc. Devices, systems, and methods for treating ethylene oxide waste gas
US11129914B1 (en) 2020-03-19 2021-09-28 Chio Kang Medical, Inc. Ethylene oxide adsorption tower and recovery system, and method for recovering ethylene oxide
WO2022000464A1 (en) 2020-07-03 2022-01-06 Qiaokang Biotech (Guangdong) Co., LTD. Mobile pretreatment apparatus and an operating method thereof, and a mobile analysis apparatus and an operating method thereof
WO2022000463A1 (en) * 2020-07-03 2022-01-06 Qiaokang Biotech (Guangdong) Co., LTD. Mobile sterilization system, mobile execution system, and mobile analysis system
CN112792022B (en) * 2020-12-17 2022-11-04 重庆梅安森科技股份有限公司 Dense medium coal washing pretreatment system
CN113865281B (en) * 2021-09-27 2022-08-26 宁波宝工电器有限公司 Unilateral heating circulation constant temperature vehicle room

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4264741A (en) * 1979-06-05 1981-04-28 New Brunswick Scientific Co., Inc. Tiltable fermentor
AT384009B (en) * 1985-12-18 1987-09-25 Voest Alpine Ag Apparatus and process for sanitizing hygienically hazardous material
US5119994A (en) * 1990-10-29 1992-06-09 Placzek Terrance M Method and apparatus for the processing of medical waste materials
EP0575005A1 (en) 1992-06-19 1993-12-22 Fedegari Autoclavi Spa Apparatus for washing and sterilizing rubber plugs or the like which may be used in pharmaceutical containers
US5427650A (en) * 1992-06-25 1995-06-27 Holloway; Clifford C. Apparatus and method for preparation for separation, recovery, and recycling of municipal solid waste and the like
US5746987A (en) * 1995-10-18 1998-05-05 Thermall Corp. Apparatus for physical amd chemical separation and reaction
EP1118706A2 (en) * 2000-01-14 2001-07-25 Georgia-Pacific Corporation Method for removing contaminants from fibers in recycle fiber pulping
WO2006015423A1 (en) * 2004-08-11 2006-02-16 Clifford C Holloway Method and apparatus for collection and treatment of encapsulated waste
WO2006056768A2 (en) 2004-11-23 2006-06-01 Estech Europe Limited Autoclave

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2955305A (en) * 1957-04-12 1960-10-11 Co Bartlett & Snow Co Sprue cleaning mill
FR1394779A (en) * 1964-01-03 1965-04-09 France Ministre Des Armees Continuous cellulose nitration process
US3991779A (en) * 1974-04-19 1976-11-16 Del Tek, Inc. Medical equipment cleaning system
US4974781A (en) * 1989-03-09 1990-12-04 The Placzek Family Trust Method and apparatus for preparing paper-containing and plastic-containing waste materials for component fraction separation
SE9901403D0 (en) * 1999-04-20 1999-04-20 Electrolux Ab Apparatus for cleaning textile articles with a densified liquid processing gas
DE19922195A1 (en) * 1999-05-12 2000-11-16 Linde Tech Gase Gmbh Cleaning arrangement has pressure container contg. at least one cleaning container and arrangement for moving cleaning container, which can be displaced and/or rotated
NL1013284C2 (en) * 1999-10-13 2001-04-17 Michael Adrianus Maria Wyrwas Autoclave for sterilizing packaged liquid products.
FR2804327A1 (en) * 2000-02-01 2001-08-03 Frans Vandenhove PROCESS FOR PASTEURIZING AND / OR STERILIZING CULTURE MEDIA FOR PLANTS AND MUSHROOMS AND APPARATUS FOR CARRYING OUT SAID METHOD
US7745208B2 (en) * 2006-02-15 2010-06-29 Noll Anthony P Angled reaction vessel
EP2148739B1 (en) * 2007-05-07 2015-02-25 Sanciflex AB Apparatus for treating material comprising pressure vessel with drum rotatably arranged inside

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4264741A (en) * 1979-06-05 1981-04-28 New Brunswick Scientific Co., Inc. Tiltable fermentor
AT384009B (en) * 1985-12-18 1987-09-25 Voest Alpine Ag Apparatus and process for sanitizing hygienically hazardous material
US5119994A (en) * 1990-10-29 1992-06-09 Placzek Terrance M Method and apparatus for the processing of medical waste materials
EP0575005A1 (en) 1992-06-19 1993-12-22 Fedegari Autoclavi Spa Apparatus for washing and sterilizing rubber plugs or the like which may be used in pharmaceutical containers
US5427650A (en) * 1992-06-25 1995-06-27 Holloway; Clifford C. Apparatus and method for preparation for separation, recovery, and recycling of municipal solid waste and the like
US5746987A (en) * 1995-10-18 1998-05-05 Thermall Corp. Apparatus for physical amd chemical separation and reaction
EP1118706A2 (en) * 2000-01-14 2001-07-25 Georgia-Pacific Corporation Method for removing contaminants from fibers in recycle fiber pulping
WO2006015423A1 (en) * 2004-08-11 2006-02-16 Clifford C Holloway Method and apparatus for collection and treatment of encapsulated waste
WO2006056768A2 (en) 2004-11-23 2006-06-01 Estech Europe Limited Autoclave

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2148739A4

Also Published As

Publication number Publication date
NO341539B1 (en) 2017-12-04
US20130243662A1 (en) 2013-09-19
EP2148739A1 (en) 2010-02-03
CA2686705C (en) 2015-11-24
US8747771B2 (en) 2014-06-10
EP2148739A4 (en) 2013-01-02
US20100055010A1 (en) 2010-03-04
CA2686705A1 (en) 2008-11-13
EP2148739B1 (en) 2015-02-25
NO20093342L (en) 2010-02-01
ES2537316T3 (en) 2015-06-05
US8431085B2 (en) 2013-04-30

Similar Documents

Publication Publication Date Title
EP2148739B1 (en) Apparatus for treating material comprising pressure vessel with drum rotatably arranged inside
CN100421896C (en) Apparatus for processing thermoplastic synthetic plastic material
JP2009045075A (en) Device for massaging products
US20110243808A1 (en) Autoclave
JP2010516454A (en) Organic substance drying equipment
HU185319B (en) Device particularly for processing foodstuffs as well as working method for operating rolling-drum processing apparatuses
US10703062B2 (en) Screw press for compressing and dewatering a suspension
EP2519362B1 (en) Device and procedure for continuous treatment of waste
WO2019181811A1 (en) Washing device and barrel polishing system
KR101701463B1 (en) Food waste drying and sterilizing apparatus
EP2999544B1 (en) A substance fragmenting device
CN111747048A (en) Mobile medical waste treatment equipment
KR102023702B1 (en) Grain steaming and extruding apparatus
KR200456089Y1 (en) Peeling and washing device of gink go nuts
CN212768162U (en) Mobile medical waste treatment equipment
AU2009238262A1 (en) Apparatus for treating material comprising pressure vessel with drum rotatable arranged inside
PT2125352E (en) Screw press for compacting solid waste
CN210119071U (en) Dry-method high-temperature anaerobic generating device for kitchen slurry after being dried by pressing
CN215143293U (en) Drying, preparing and processing all-in-one machine for livestock and poultry died of diseases
CN215676190U (en) Overturning structure of drying machine for bio-organic fertilizer production line
CN220174439U (en) Sterilizing equipment is used in production of thick slurry of bursting beads
CN215557063U (en) Dry casting machine capable of preventing blockage
KR100913813B1 (en) River snail peeling apparatus
KR101506021B1 (en) soap pulverizer
CN212894613U (en) Dregs steaming equipment for oil pressing

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 07748468

Country of ref document: EP

Kind code of ref document: A1

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2686705

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2007748468

Country of ref document: EP

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)