WO2008087236A1 - Equipo para la fabricación de perfiles tubulares molecularmente biorientados y método correspondiente - Google Patents
Equipo para la fabricación de perfiles tubulares molecularmente biorientados y método correspondiente Download PDFInfo
- Publication number
- WO2008087236A1 WO2008087236A1 PCT/ES2007/070011 ES2007070011W WO2008087236A1 WO 2008087236 A1 WO2008087236 A1 WO 2008087236A1 ES 2007070011 W ES2007070011 W ES 2007070011W WO 2008087236 A1 WO2008087236 A1 WO 2008087236A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mold
- plastic tube
- fluid
- tube
- inlet
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/22—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of tubes
- B29C55/26—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of tubes biaxial
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/28—Blow-moulding apparatus
- B29C49/30—Blow-moulding apparatus having movable moulds or mould parts
- B29C49/36—Blow-moulding apparatus having movable moulds or mould parts rotatable about one axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
- B29C49/4823—Moulds with incorporated heating or cooling means
- B29C2049/4838—Moulds with incorporated heating or cooling means for heating moulds or mould parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
- B29C2049/4856—Mounting, exchanging or centering moulds or parts thereof
- B29C2049/4862—Aligning the mould part position e.g. left half to right half
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
- B29C2049/4879—Moulds characterised by mould configurations
- B29C2049/4882—Mould cavity geometry
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
- B29C2049/4879—Moulds characterised by mould configurations
- B29C2049/4882—Mould cavity geometry
- B29C2049/48825—Asymmetric moulds, i.e. the parison is not in the center of the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
- B29C2049/4879—Moulds characterised by mould configurations
- B29C2049/4894—With at least a part of the mould cavity formed by a cylindrical mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/62—Venting means
- B29C2049/622—Venting means for venting air between preform and cavity, e.g. using venting holes, gaps or patterned moulds
- B29C2049/627—Venting means for venting air between preform and cavity, e.g. using venting holes, gaps or patterned moulds using vacuum means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2791/00—Shaping characteristics in general
- B29C2791/004—Shaping under special conditions
- B29C2791/006—Using vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2791/00—Shaping characteristics in general
- B29C2791/004—Shaping under special conditions
- B29C2791/007—Using fluid under pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/079—Auxiliary parts or inserts
- B29C2949/08—Preforms made of several individual parts, e.g. by welding or gluing parts together
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C49/04—Extrusion blow-moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/56—Opening, closing or clamping means
- B29C49/5611—Tilting movement, e.g. changing angle of the mould parts towards the vertical direction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
- B29K2105/253—Preform
- B29K2105/258—Tubular
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2023/00—Tubular articles
- B29L2023/22—Tubes or pipes, i.e. rigid
Definitions
- the present invention relates to a corresponding equipment and method for the manufacture of molecularly oriented tubular profiles, especially for application in pipes, signaling elements and light structural elements.
- the equipment is based on a mold that incorporates an expansion system, a cooling system and a vacuum system, conveniently synchronized to enable the execution of the method and corresponding obtaining of a molecularly bioriented tube or profile.
- the object of the invention is to be able to form tubular profiles with molecular orientation, in a simple, fast and energy efficient execution process, allowing to reduce costs and times in obtaining tubular profiles with respect to the systems currently used for same purposes, so that the final product will reach the market at a much more competitive price based on the manufacturing that is achieved through the equipment and the method of the invention.
- the field of application is encompassed within the manufacturing processes of molecularly oriented profiles and in particular of discontinuous systems.
- Molecular biorientation is a process by which, by applying a mechanical deformation to a previously extruded tube or proforma under suitable conditions of temperature, pressure, strain rate and deformation radius mainly, a substantial modification of its mechanical properties occurs, mainly The sigma of the material, the resistance to impact, improvement of creep, resistance to the propagation of cracks, improvement of Young's modulus, etc.
- the main characteristics of said method are that the mold is symmetrical and is composed of two concentric bodies that slide into each other, the expansion being carried out in two phases and the contact cooling occurs through the walls of the mold.
- said mold is always kept cold thanks to an external bath of cooling fluid, while the cooling of the already formed plastic tube occurs indirectly through the mold and by contact, which results in an energy-efficient system speaking, and disadvantageous in regard to the process time, since the plastic having a coefficient of expansion greater than that of the metal, a separation between the mold and the plastic occurs almost immediately, making heat transmission by contact very difficult.
- the expansion occurs in at least two phases, being a slow process that is subject to the displacement of the mobile jacket.
- the inlet and outlet of the tubes is hindered by the sliding fittings, being possible the entry and exit of the proforma and tube only by the same end, not allowing a linear process, but with round-trip movements of the material, this aspect being a factor that penalizes the process time and industrial logistics, since the time of extraction and entry of proformas does not allow orientation and both actions cannot be carried out at the same time.
- the thermal efficiency is worsened, since the mold is heated and cooled every time a tube is processed, which implies a high energy expenditure, resulting in low efficiency as in the previous case. , since again the cooling occurs by contact.
- the tube is introduced cold, the mold itself serving as a heater and as a mold itself, presenting this numerous holes to allow the evacuation of the fluid that has previously served as heating of the tube, making it more expensive to execute.
- the equipment of the invention comprises a special mold for forming a plastic tube, a mold that acts only as a shaper and at a constant, hot temperature and without the need for thermal exchange between said mold and the tube.
- Said mold is constantly heated with heating elements and at its ends it includes two asymmetric heads that allow the simultaneous introduction and extraction of a pro-forma and oriented tube, with the consequent saving of time in the process, in addition to allowing the use of preheated tubes thanks to The asymmetric geometry of said heads.
- the mold is mounted on a support that allows the rotation and / or tilting of it, to favor the cooling process of the corresponding tubular profiles, complementing the equipment with auxiliary measurement and control systems.
- the production method is based on the following operational phases:
- the equipment of the invention It comprises a mold (1) mounted on a support (2) with characteristics that make it possible to turn and tilt the mold (1), which is externally provided with a plurality of heating elements (3), while at its ends it incorporates two heads asymmetric (4) equipped with a vacuum intake hole (5) whose purpose will be set out later.
- the corresponding plastic tube (6) to be formed is introduced through one of the ends of the mold (1) after removal of the corresponding head (4), the introduction of which is carried out until said plastic tube (6) reaches the head of the opposite end, to then mount that head (4) of the end through which the tube (6) has been introduced and actuate the corresponding fastening means (7) of the tube itself (6) inside the mold (1 ), the plastic tube (6) being supported in correspondence with the lower generatrix of the mold itself (1), as shown in the figure.
- the asymmetric heads (4) allow the tube (6) to be preheated and therefore soft, always supported and in a straight way, facilitating its grip at the ends through the clamping means (7)
- an inlet (8) is provided for the expander and cooler fluid, and an outlet (9) of said fluid, while radially to the wall of the own mold (1) a hole (10) of lubricant flow inlet used in the extraction of the tube (6) is provided once the interior of the mold (1) is formed, the process being carried out by means of an initial empty, through hole (5) which is established in the enclosure limited between the inside of the mold (1) and the outside of the plastic tube (6).
- the proforma and the mold, through the inlet (8) to produce the expansion of the tube (6), and once expanded, and maintaining the pressure inside by means of regulation systems, is applied to the tube itself (6 ) a refrigerant fluid, also through the inlet (8), allowing the escape and drag of the expander fluid from the opposite side or from the same inlet side, through the outlet (9), allowing the continuous flow of said fluid and its direct interaction against the inner walls of the plastic tube (6).
- the mold (1) can perform oscillating and / or rotary movements when mounted on the support (2) provided with these movements, thus ensuring a correct distribution of the temperatures inside.
- pressurized lubricating fluid is applied through the side hole (10), this fluid extending between the mold (1) and the tube (6) and, due to the mattress effect, the extraction forces will be reduced to a high degree, with the particularity that this lubricating fluid must be at the same temperature as the mold (1) to avoid temperature changes.
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BRPI0716313-4A BRPI0716313B1 (pt) | 2007-01-18 | 2007-01-18 | Equipamento para a fabricação de perfis tubulares molecularmente biorientados e método para a fabricação de perfis tubulares molecurlamente biorientados |
EP07704773.6A EP2123424B1 (en) | 2007-01-18 | 2007-01-18 | Equipment for producing molecularly bioriented tubular profiles and corresponding method |
CA2667835A CA2667835C (en) | 2007-01-18 | 2007-01-18 | Equipment for producing molecularly bioriented tubular profiles and corresponding method |
ES07704773T ES2761922T3 (es) | 2007-01-18 | 2007-01-18 | Equipo para la fabricación de perfiles tubulares molecularmente biorientados y método correspondiente |
PT77047736T PT2123424T (pt) | 2007-01-18 | 2007-01-18 | Equipamento para produção de perfis tubulares bi-orientados a nível molecular e método correspondente |
PCT/ES2007/070011 WO2008087236A1 (es) | 2007-01-18 | 2007-01-18 | Equipo para la fabricación de perfiles tubulares molecularmente biorientados y método correspondiente |
AU2007344397A AU2007344397B2 (en) | 2007-01-18 | 2007-01-18 | Equipment for producing molecularly bioriented tubular profiles and corresponding method |
US12/447,655 US8636499B2 (en) | 2007-01-18 | 2007-01-18 | Equipment for producing molecularly bioriented tubular profiles and corresponding method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/ES2007/070011 WO2008087236A1 (es) | 2007-01-18 | 2007-01-18 | Equipo para la fabricación de perfiles tubulares molecularmente biorientados y método correspondiente |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008087236A1 true WO2008087236A1 (es) | 2008-07-24 |
Family
ID=39635683
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/ES2007/070011 WO2008087236A1 (es) | 2007-01-18 | 2007-01-18 | Equipo para la fabricación de perfiles tubulares molecularmente biorientados y método correspondiente |
Country Status (8)
Country | Link |
---|---|
US (1) | US8636499B2 (es) |
EP (1) | EP2123424B1 (es) |
AU (1) | AU2007344397B2 (es) |
BR (1) | BRPI0716313B1 (es) |
CA (1) | CA2667835C (es) |
ES (1) | ES2761922T3 (es) |
PT (1) | PT2123424T (es) |
WO (1) | WO2008087236A1 (es) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4240344A (en) | 1979-09-06 | 1980-12-23 | Equipment Technology Incorporated | High speed unit printer and inker therefor |
ES8105621A1 (es) * | 1979-09-15 | 1981-06-16 | Yorkshire Imperial Plastics | Perfeccionamientos en aparatos para la fabricacion de tube- ria de material termoplastico |
US4499045A (en) | 1981-08-06 | 1985-02-12 | Solvay & Cie (Societe Anonyme) | Process for the production of tubes of a molecularly oriented plastic |
EP0434276A1 (en) * | 1989-12-15 | 1991-06-26 | CarnaudMetalbox plc | Heatsetting of thermoplastic tubular articles |
WO1998013190A1 (fr) | 1996-09-26 | 1998-04-02 | Alphacan | Procede et installation de fabrication de tubes en matiere plastique avec etirage bi-axial, et tube en matiere plastique ainsi obtenu |
WO2002009926A1 (en) * | 2000-08-02 | 2002-02-07 | Wavin B.V. | Methods and devices for the production of a pipe from biaxially oriented thermoplastic material having an integrated socket |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU35737A1 (es) * | 1957-01-30 | |||
US5055024A (en) * | 1988-10-04 | 1991-10-08 | Cordis Corporation | Apparatus for manufacturing balloons for medical devices |
JPH02131917A (ja) * | 1988-11-12 | 1990-05-21 | Toyota Motor Corp | セイフティパッドの製造方法 |
US5112561A (en) * | 1990-10-19 | 1992-05-12 | Edward S. Robbins, III | Blow-molding methods for fabricating hollow articles from an open-ended tubular body of thermoplastic material |
JP2904384B2 (ja) * | 1992-12-11 | 1999-06-14 | 宇部興産株式会社 | ブロー成形機 |
-
2007
- 2007-01-18 PT PT77047736T patent/PT2123424T/pt unknown
- 2007-01-18 ES ES07704773T patent/ES2761922T3/es active Active
- 2007-01-18 WO PCT/ES2007/070011 patent/WO2008087236A1/es active Application Filing
- 2007-01-18 CA CA2667835A patent/CA2667835C/en active Active
- 2007-01-18 AU AU2007344397A patent/AU2007344397B2/en active Active
- 2007-01-18 US US12/447,655 patent/US8636499B2/en active Active
- 2007-01-18 BR BRPI0716313-4A patent/BRPI0716313B1/pt active IP Right Grant
- 2007-01-18 EP EP07704773.6A patent/EP2123424B1/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4240344A (en) | 1979-09-06 | 1980-12-23 | Equipment Technology Incorporated | High speed unit printer and inker therefor |
ES8105621A1 (es) * | 1979-09-15 | 1981-06-16 | Yorkshire Imperial Plastics | Perfeccionamientos en aparatos para la fabricacion de tube- ria de material termoplastico |
US4499045A (en) | 1981-08-06 | 1985-02-12 | Solvay & Cie (Societe Anonyme) | Process for the production of tubes of a molecularly oriented plastic |
EP0434276A1 (en) * | 1989-12-15 | 1991-06-26 | CarnaudMetalbox plc | Heatsetting of thermoplastic tubular articles |
WO1998013190A1 (fr) | 1996-09-26 | 1998-04-02 | Alphacan | Procede et installation de fabrication de tubes en matiere plastique avec etirage bi-axial, et tube en matiere plastique ainsi obtenu |
WO2002009926A1 (en) * | 2000-08-02 | 2002-02-07 | Wavin B.V. | Methods and devices for the production of a pipe from biaxially oriented thermoplastic material having an integrated socket |
Non-Patent Citations (1)
Title |
---|
See also references of EP2123424A4 |
Also Published As
Publication number | Publication date |
---|---|
EP2123424A4 (en) | 2019-01-23 |
US20100189833A1 (en) | 2010-07-29 |
AU2007344397A1 (en) | 2008-07-24 |
CA2667835A1 (en) | 2008-07-24 |
ES2761922T8 (es) | 2020-06-05 |
BRPI0716313A2 (pt) | 2013-01-01 |
EP2123424B1 (en) | 2019-09-18 |
PT2123424T (pt) | 2019-10-17 |
BRPI0716313B1 (pt) | 2018-05-29 |
AU2007344397B2 (en) | 2011-05-26 |
ES2761922T3 (es) | 2020-05-21 |
EP2123424A1 (en) | 2009-11-25 |
CA2667835C (en) | 2014-05-20 |
US8636499B2 (en) | 2014-01-28 |
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