WO2008080453A1 - Ammoniakkonverter - Google Patents
Ammoniakkonverter Download PDFInfo
- Publication number
- WO2008080453A1 WO2008080453A1 PCT/EP2007/010061 EP2007010061W WO2008080453A1 WO 2008080453 A1 WO2008080453 A1 WO 2008080453A1 EP 2007010061 W EP2007010061 W EP 2007010061W WO 2008080453 A1 WO2008080453 A1 WO 2008080453A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- heat exchanger
- ammonia converter
- catalyst
- ammonia
- flow
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/04—Preparation of ammonia by synthesis in the gas phase
- C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
- C01C1/0417—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst characterised by the synthesis reactor, e.g. arrangement of catalyst beds and heat exchangers in the reactor
- C01C1/0423—Cold wall reactors
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/04—Preparation of ammonia by synthesis in the gas phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
- B01J8/0407—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds
- B01J8/0415—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds the beds being superimposed one above the other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0492—Feeding reactive fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0496—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00194—Tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
- B01J2208/00221—Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Definitions
- the invention is directed to an ammonia converter having at least one substantially radially throughflowed catalyst bed, which concentrically surrounds a heat exchanger, wherein outside converter wall and the outer cylinder jacket of the catalyst and / or between the inner cylinder wall of the catalyst and a surrounding the heat exchanger tubes Strömungsleitzylinder an outer or an inner annular space is provided.
- ammonia converters are available in different designs.
- Such reactors for ammonia production are designed with a plurality of catalyst beds, which are flowed through by synthesis gas in succession.
- heat exchangers are provided at each catalyst bed, which transfer the heat of reaction of the gas leaving the catalyst bed to the incoming recycle gas, it being known, depending on the plant configuration, the converters with two catalyst beds and an internal heat exchanger, which is surrounded by the first bed to provide or three catalyst beds, in which case the first two beds surrounded inside the heat exchangers.
- the temperature distribution over the circumference of the catalyst bed can be very nonuniform due to a non-uniform flow against the catalyst during the reduction or preheating phase as well as during normal operation of the ammonia converter, which is particularly in reducing or in the temperature control of the first catalyst bed means
- Cold gas can cause the reduction or reaction proceeds unevenly. Due to the substantially radial flow through the catalyst beds and heat exchangers, this unequal distribution of the temperature is maintained in the downstream catalyst beds, since the incoming recirculation gas is less preheated on the tube side of the downstream heat exchanger and thus this also by the on a peripheral region colder emerging from the catalyst bed gas stream less preheated gas flows into the catalyst bed.
- a further embodiment of the invention is that at least in the inlet region of the flow to the heat exchanger Strömungsleitbleche are provided for generating a spiral flow.
- This type of forced flow can be provided both in catalyst beds whose main flow direction is equipped from outside to inside, or even in catalyst beds which are flowed through from the inside to the outside.
- Fig. 3 is a schematic diagram of static mixers.
- the ammonia converter generally designated 1 in FIG. 1 has a first catalyst bed 2, which is equipped inside a coaxial with a heat exchanger 3, wherein a second Katalyorsatorbett 4 downstream as seen in the flow direction downstream.
- the cycle gas is over a supply nozzle 5 is supplied to the converter 1 and leaves the converter via the outlet pipe 6.
- this process is used during the initial commissioning of the reduction of the catalyst material, gas is fed via a ring manifold 7 in the head of the converter, the first outer annular space 8, between the housing wall 9 of the converter insert and the outer cylinder shell 10 is formed, applied.
- static mixer 9 are provided in this annular space 9, which is indicated in Figs. 1 and 2 by small slanted strokes.
- the gas After flowing through the catalyst 2, the gas enters the annulus designated 14 between the inner cylinder 15 of the first catalyst 2 and the cylindrical Strömungsleit- plate 16, which surrounds the heat exchanger tubes of the heat exchanger 3 substantially.
- static mixers may be provided in this annular space 14, for example in the same or similar design as the guide spirals 11 or Leitspiralabchanginge IIa indicated in FIG. 3.
- the further flow in the ammonia converter 1 is represented in FIG. 1 by small arrows, wherein, if this is necessary, the annular spaces 17 and 18 formed by the second catalyst bed 4 may also be equipped with static mixers. can be equipped, which is not shown in Fig. 1 in detail.
- Fig. 2 shows a modified embodiment insofar as the local ammonia converter Ia is equipped with three catalyst beds, namely once in Fig. 2 upper first catalyst bed 2a, a catalyst bed following this catalyst bed 2b and the then following lower catalyst bed 4a, wherein the two catalyst beds 2a and 2b are provided inside the coaxial heat exchangers, generally designated 3a and 3b.
- gas can be fed via the ring line 7a to the upper catalyst bed and via a tube 7b surrounding the centric feed tube 5a for the circulating gas to the underlying catalyst bed 2b.
- corresponding static mixer 11 are indicated in the annular spaces by oblique lines. Incidentally, the flow is reproduced here by small arrows.
- the temperature control of the reactors or converter is, as already mentioned, via the introduction of heating or cooling gas via the lines 7a and 7b, the spaces 19 and 20 serve below the first heat exchanger 3a and below the second heat exchanger 3b the conversion or introduction of the respective gas, the end chamber 20 serves to introduce the incoming gas through the line 5a in the heat exchanger 3b.
- Fig. 3 is illustrative only. The invention is not limited to the directions of flow indicated by the arrows.
- the shell-side gas guide can run in Fig. 3 from bottom left to top right as well as vice versa, ie against the local arrows.
- the Catalyst can be flowed through from the outside to the inside or from the inside to the outside, ie, for example, unlike the arrows 13 indicate this.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007800465280A CN101616730B (zh) | 2006-12-21 | 2007-11-21 | 氨合成塔 |
EP07819880.1A EP2104557B1 (de) | 2006-12-21 | 2007-11-21 | Ammoniakkonverter |
KR1020097011513A KR101388390B1 (ko) | 2006-12-21 | 2007-11-21 | 암모니아 컨버터 |
JP2009541797A JP5680853B2 (ja) | 2006-12-21 | 2007-11-21 | アンモニア転化装置 |
HK10100974.8A HK1137380A1 (en) | 2006-12-21 | 2010-01-29 | Ammonia converter |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006061847.5 | 2006-12-21 | ||
DE102006061847A DE102006061847A1 (de) | 2006-12-21 | 2006-12-21 | Ammoniakkonverter |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008080453A1 true WO2008080453A1 (de) | 2008-07-10 |
Family
ID=39226612
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2007/010061 WO2008080453A1 (de) | 2006-12-21 | 2007-11-21 | Ammoniakkonverter |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP2104557B1 (de) |
JP (1) | JP5680853B2 (de) |
KR (1) | KR101388390B1 (de) |
CN (1) | CN101616730B (de) |
DE (1) | DE102006061847A1 (de) |
HK (1) | HK1137380A1 (de) |
WO (1) | WO2008080453A1 (de) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102015104911A1 (de) * | 2015-03-30 | 2016-10-06 | Thyssenkrupp Ag | Strömungsführung eines Fluids in einem Strömungsbehälter |
DE102015114201A1 (de) | 2015-08-26 | 2017-03-02 | Thyssenkrupp Ag | Reaktor und Verfahren zur katalytischen Umsetzung eines Gasgemisches |
DE102016114711A1 (de) | 2016-08-09 | 2018-02-15 | Thyssenkrupp Ag | Plattenwärmetauscher, Synthesevorrichtung und Verfahren zur Herstellung eines Produkts |
DE102016114710A1 (de) | 2016-08-09 | 2018-02-15 | Thyssenkrupp Ag | Plattenwärmetauscher, Synthesevorrichtung und Verfahren zur Herstellung eines Produkts |
DE102016114713A1 (de) | 2016-08-09 | 2018-02-15 | Thyssenkrupp Ag | Synthesevorrichtung und Verfahren zur Herstellung eines Produkts |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2133249A (en) * | 1933-07-14 | 1938-10-11 | Du Pont | High pressure heat exchanger |
AT287011B (de) * | 1969-03-18 | 1971-01-11 | Chemie Linz Ag | Verfahren zur Gasführung in katalytischen Hochdrucksyntheseanlagen, beispielsweise für die Ammoniaksynthese |
DE1957696A1 (de) * | 1969-11-17 | 1971-05-19 | Lentia Gmbh | Verfahren und Vorrichtung zur Gasfuehrung in katalytischen,zylinderfoermigen Hochdrucksynthesereaktoren |
DE2306516A1 (de) * | 1973-02-09 | 1974-08-15 | Lentia Gmbh | Vorrichtung zur erzielung einer gleichmaessigen gasverteilung in radialdurchstroemten katalysatorlagen in reaktoren fuer katalytische, exotherme hochdrucksynthesen, vorzugsweise der ammoniaksynthese |
DE8334218U1 (de) * | 1983-11-29 | 1986-09-18 | Uhde Gmbh, 4600 Dortmund | Vorrichtung zur Durchführung exothermer, katalytischer Gasreaktionen für die Ammoniak- oder Methanol-Synthese |
EP0282699A2 (de) * | 1987-03-18 | 1988-09-21 | Uhde GmbH | Zweistufiger Ammoniakkonverter mit wenigstens einem Katalysatorbett mit in dessen Inneren angeordneten Wärmetauscher |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE754531A (fr) * | 1969-08-07 | 1971-02-08 | Chemie Linz Ag | Procede et dispositif pour le guidage du gaz dans les reacteursde synthese catalytique a haute pression |
JPS5912294A (ja) * | 1982-07-12 | 1984-01-21 | Kamui Sangyo Kk | 多管式熱交換器の製造方法 |
JPH0652135B2 (ja) * | 1989-05-31 | 1994-07-06 | ネポン株式会社 | 整流筒の整流板の形成方法 |
JPH03196831A (ja) * | 1989-12-27 | 1991-08-28 | Chiyoda Corp | ガス反応器 |
DE19540537C1 (de) * | 1995-10-31 | 1997-06-26 | Uhde Gmbh | Vorrichtung zur Beaufschlagung einer Festkörperschüttung |
US5814129A (en) * | 1997-04-11 | 1998-09-29 | Air Products And Chemical, Inc. | Radial flow adsorption vessel |
CN2562864Y (zh) * | 2002-07-05 | 2003-07-30 | 中国石化集团巴陵石油化工有限责任公司 | 一种聚合釜 |
JP4002195B2 (ja) * | 2003-02-13 | 2007-10-31 | メトロ電気工業株式会社 | 流体加熱用ヒータ |
-
2006
- 2006-12-21 DE DE102006061847A patent/DE102006061847A1/de not_active Ceased
-
2007
- 2007-11-21 KR KR1020097011513A patent/KR101388390B1/ko active IP Right Grant
- 2007-11-21 CN CN2007800465280A patent/CN101616730B/zh not_active Expired - Fee Related
- 2007-11-21 WO PCT/EP2007/010061 patent/WO2008080453A1/de active Application Filing
- 2007-11-21 JP JP2009541797A patent/JP5680853B2/ja not_active Expired - Fee Related
- 2007-11-21 EP EP07819880.1A patent/EP2104557B1/de active Active
-
2010
- 2010-01-29 HK HK10100974.8A patent/HK1137380A1/xx not_active IP Right Cessation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2133249A (en) * | 1933-07-14 | 1938-10-11 | Du Pont | High pressure heat exchanger |
AT287011B (de) * | 1969-03-18 | 1971-01-11 | Chemie Linz Ag | Verfahren zur Gasführung in katalytischen Hochdrucksyntheseanlagen, beispielsweise für die Ammoniaksynthese |
DE1957696A1 (de) * | 1969-11-17 | 1971-05-19 | Lentia Gmbh | Verfahren und Vorrichtung zur Gasfuehrung in katalytischen,zylinderfoermigen Hochdrucksynthesereaktoren |
DE2306516A1 (de) * | 1973-02-09 | 1974-08-15 | Lentia Gmbh | Vorrichtung zur erzielung einer gleichmaessigen gasverteilung in radialdurchstroemten katalysatorlagen in reaktoren fuer katalytische, exotherme hochdrucksynthesen, vorzugsweise der ammoniaksynthese |
DE8334218U1 (de) * | 1983-11-29 | 1986-09-18 | Uhde Gmbh, 4600 Dortmund | Vorrichtung zur Durchführung exothermer, katalytischer Gasreaktionen für die Ammoniak- oder Methanol-Synthese |
EP0282699A2 (de) * | 1987-03-18 | 1988-09-21 | Uhde GmbH | Zweistufiger Ammoniakkonverter mit wenigstens einem Katalysatorbett mit in dessen Inneren angeordneten Wärmetauscher |
Also Published As
Publication number | Publication date |
---|---|
JP2010513194A (ja) | 2010-04-30 |
HK1137380A1 (en) | 2010-07-30 |
EP2104557B1 (de) | 2015-01-07 |
KR20090101170A (ko) | 2009-09-24 |
CN101616730A (zh) | 2009-12-30 |
DE102006061847A1 (de) | 2008-06-26 |
JP5680853B2 (ja) | 2015-03-04 |
DE102006061847A8 (de) | 2008-11-27 |
KR101388390B1 (ko) | 2014-04-22 |
EP2104557A1 (de) | 2009-09-30 |
CN101616730B (zh) | 2012-10-10 |
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