WO2008078479A1 - ジフルオロ酢酸エステルの製造方法 - Google Patents

ジフルオロ酢酸エステルの製造方法 Download PDF

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Publication number
WO2008078479A1
WO2008078479A1 PCT/JP2007/072503 JP2007072503W WO2008078479A1 WO 2008078479 A1 WO2008078479 A1 WO 2008078479A1 JP 2007072503 W JP2007072503 W JP 2007072503W WO 2008078479 A1 WO2008078479 A1 WO 2008078479A1
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WO
WIPO (PCT)
Prior art keywords
difluoroacetic acid
acid ester
carbon atoms
hcf2cf2or1
reacting
Prior art date
Application number
PCT/JP2007/072503
Other languages
English (en)
French (fr)
Inventor
Takayuki Nishimiya
Akihiro Fukui
Satoru Okamoto
Satoshi Yoshikawa
Yasuo Hibino
Original Assignee
Central Glass Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Central Glass Company, Limited filed Critical Central Glass Company, Limited
Publication of WO2008078479A1 publication Critical patent/WO2008078479A1/ja

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

以下の式 【化５】 HCF2CF2OR1 で表される１－アルコキシ－１，１，２，２－テトラフルオロエタン［式中、Ｒ1 は炭素数１～２０の直鎖または分岐鎖のアルキル基を示す。］を、炭素数１～２０のアルコール、及び金属水酸化物もしくは金属アルコキシドと反応させてジフルオロ酢酸金属塩を得、得られたジフルオロ酢酸金属塩を、酸の存在下、炭素数１～１０のアルコールと反応させ、ジフルオロ酢酸エステルを得る。この方法によれば、従来技術と比べて短工程で、簡便かつ工業的規模で製造できる。
PCT/JP2007/072503 2006-12-27 2007-11-21 ジフルオロ酢酸エステルの製造方法 WO2008078479A1 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006351155A JP2008162902A (ja) 2006-12-27 2006-12-27 ジフルオロ酢酸エステルの製造方法
JP2006-351155 2006-12-27

Publications (1)

Publication Number Publication Date
WO2008078479A1 true WO2008078479A1 (ja) 2008-07-03

Family

ID=39562272

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/072503 WO2008078479A1 (ja) 2006-12-27 2007-11-21 ジフルオロ酢酸エステルの製造方法

Country Status (2)

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JP (1) JP2008162902A (ja)
WO (1) WO2008078479A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011184316A (ja) * 2010-03-05 2011-09-22 Central Glass Co Ltd ジフルオロ酢酸エステルの製造方法
WO2012011524A1 (ja) * 2010-07-23 2012-01-26 ダイキン工業株式会社 ジフルオロ酢酸エステルの製造方法
FR2996147A1 (fr) * 2012-10-03 2014-04-04 Rhodia Operations Procede de traitement d'acide fluore

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5217927B2 (ja) * 2008-11-12 2013-06-19 セントラル硝子株式会社 ジフルオロ酢酸エステルの製造方法
WO2012062602A1 (en) 2010-11-08 2012-05-18 Solvay Specialty Polymers Italy S.P.A. Process for the preparation of difluoroacetic acid
CN103113220B (zh) * 2013-01-29 2015-03-18 巨化集团技术中心 一种二氟乙酸酯的合成方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002521033A (ja) * 1998-07-24 2002-07-16 サムスン ファイン ケミカルズ カンパニー リミテッド 光学的に純粋な（ｓ）−３，４−ジヒドロキシ酪酸誘導体の連続的な製造方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002521033A (ja) * 1998-07-24 2002-07-16 サムスン ファイン ケミカルズ カンパニー リミテッド 光学的に純粋な（ｓ）−３，４−ジヒドロキシ酪酸誘導体の連続的な製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
YOUNG J.A. AND TARRANT P.: "A New Method of Preparation of Esters of Difluoroacetic Acid", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 72, 1950, pages 1860 - 1861, XP002581355 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011184316A (ja) * 2010-03-05 2011-09-22 Central Glass Co Ltd ジフルオロ酢酸エステルの製造方法
WO2012011524A1 (ja) * 2010-07-23 2012-01-26 ダイキン工業株式会社 ジフルオロ酢酸エステルの製造方法
JP2012025697A (ja) * 2010-07-23 2012-02-09 Daikin Industries Ltd ジフルオロ酢酸エステルの製造方法
FR2996147A1 (fr) * 2012-10-03 2014-04-04 Rhodia Operations Procede de traitement d'acide fluore
WO2014053312A1 (fr) * 2012-10-03 2014-04-10 Rhodia Operations Procede de traitement d'acide fluore
US9394225B2 (en) 2012-10-03 2016-07-19 Rhodia Operations Method for processing fluoric acid

Also Published As

Publication number Publication date
JP2008162902A (ja) 2008-07-17

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