WO2008064038A2 - Appareil pour la liquéfaction du gaz et procédés associés - Google Patents

Appareil pour la liquéfaction du gaz et procédés associés Download PDF

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Publication number
WO2008064038A2
WO2008064038A2 PCT/US2007/084677 US2007084677W WO2008064038A2 WO 2008064038 A2 WO2008064038 A2 WO 2008064038A2 US 2007084677 W US2007084677 W US 2007084677W WO 2008064038 A2 WO2008064038 A2 WO 2008064038A2
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WO
WIPO (PCT)
Prior art keywords
gas
liquid
stream
heat exchanger
flowing
Prior art date
Application number
PCT/US2007/084677
Other languages
English (en)
Other versions
WO2008064038A3 (fr
Inventor
Terry D. Turner
Bruce M. Wilding
Dennis N. Bingham
Michael G. Mckellar
Lisa R. Hoffman
Original Assignee
Battelle Energy Alliance, Llc
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Publication date
Application filed by Battelle Energy Alliance, Llc filed Critical Battelle Energy Alliance, Llc
Publication of WO2008064038A2 publication Critical patent/WO2008064038A2/fr
Publication of WO2008064038A3 publication Critical patent/WO2008064038A3/fr

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
    • F25J1/0037—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work of a return stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0045—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by vaporising a liquid return stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0201—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0201—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration
    • F25J1/0202—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration in a quasi-closed internal refrigeration loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0203—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle
    • F25J1/0204—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle as a single flow SCR cycle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0211—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
    • F25J1/0212—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a single flow MCR cycle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F25J1/0232—Coupling of the liquefaction unit to other units or processes, so-called integrated processes integration within a pressure letdown station of a high pressure pipeline system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0244—Operation; Control and regulation; Instrumentation
    • F25J1/0245—Different modes, i.e. 'runs', of operation; Process control
    • F25J1/0247—Different modes, i.e. 'runs', of operation; Process control start-up of the process
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0244—Operation; Control and regulation; Instrumentation
    • F25J1/0245—Different modes, i.e. 'runs', of operation; Process control
    • F25J1/0251—Intermittent or alternating process, so-called batch process, e.g. "peak-shaving"
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0275—Construction and layout of liquefaction equipments, e.g. valves, machines adapted for special use of the liquefaction unit, e.g. portable or transportable devices
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/08—Separating gaseous impurities from gases or gaseous mixtures or from liquefied gases or liquefied gaseous mixtures
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/20—Processes or apparatus using other separation and/or other processing means using solidification of components
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/60—Processes or apparatus using other separation and/or other processing means using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/84—Processes or apparatus using other separation and/or other processing means using filter
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/06—Splitting of the feed stream, e.g. for treating or cooling in different ways
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00—Processes characterised by the type or other details of the product stream
    • F25J2215/60—Methane
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00—Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/62—Separating low boiling components, e.g. He, H2, N2, Air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00—Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/66—Separating acid gases, e.g. CO2, SO2, H2S or RSH
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00—Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/68—Separating water or hydrates
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/60—Processes or apparatus involving steps for increasing the pressure of gaseous process streams the fluid being hydrocarbons or a mixture of hydrocarbons
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/04—Internal refrigeration with work-producing gas expansion loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2280/00—Control of the process or apparatus
    • F25J2280/02—Control in general, load changes, different modes ("runs"), measurements
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/62—Details of storing a fluid in a tank

Definitions

  • the present invention relates generally to the compression and liquefaction of gases, and more particularly to the liquefaction of a gas, such as natural gas, on a small scale by utilizing a combined refrigerant and expansion process.
  • Natural gas is a known alternative to combustion fuels such as gasoline and diesel. Much effort has gone into the development of natural gas as an alternative combustion fuel in order to combat various drawbacks of gasoline and diesel including production costs and the subsequent emissions created by the use thereof. As is known in the art, natural gas is a cleaner burning fuel than other combustion fuels. Additionally, natural gas is considered to be safer than gasoline or diesel as natural gas will rise in the air and dissipate, rather than settling or accumulating.
  • natural gas also termed “feed gas” herein
  • CNG compressed natural gas
  • LNG liquid natural gas
  • cascade cycle two of the known, basic processes used for the liquefaction of natural gases are referred to as the “cascade cycle” and the “expansion cycle.”
  • the cascade cycle consists of subjecting the feed gas to a series of heat exchanges, each exchange being at successively lower temperatures until the desired liquefaction is accomplished.
  • the levels of refrigeration are obtained with different refrigerants or with the same refrigerant at different evaporating pressures.
  • the cascade cycle is considered Atty. Docket No. BA-087 PCT
  • An additional problem with large facilities is the cost associated with storing large amounts of fuel in anticipation of future use and/or transportation. Not only is there a cost associated with building large storage facilities, but there is also an efficiency issue related therewith as stored LNG will tend to warm and vaporize over time, creating a loss of the LNG fuel product. Further, safety may become an issue when larger amounts of LNG fuel product are stored. In addition to such technical issues, it is noted that significant issues may be associated with siting and licensing of large scale LNG and CNG facilities including obtaining the necessary real estate and approval from numerous levels of government agencies.
  • U.S. Patent 5,505,232 to Barclay, issued April 9, 1996 is directed to a system for producing LNG and/or CNG.
  • the disclosed system is stated to operate on a small scale producing approximately 1,000 gallons a day of liquefied or compressed fuel product.
  • the liquefaction portion of the system itself requires the flow of a "clean" or “purified” gas, meaning that various constituents in the gas such as carbon dioxide, water, or heavy hydrocarbons must be removed before the actual liquefaction process can begin.
  • U.S. Patents 6,085,546 and 6,085,547 both issued July 11, 2000 to Johnston, describe methods and systems of producing LNG.
  • the Johnston patents are both directed to small scale production of LNG, but again, both require “prepurification” of the gas in order to implement the actual liquefaction cycle.
  • the need to provide "clean” or “prepurified” gas to the liquefaction cycle is based on the fact that certain gas components might freeze and plug the system during the liquefaction process because of their relatively higher freezing points as compared to methane which makes up the larger portion of natural gas.
  • the present invention provides apparatuses, systems and methods for the liquefaction of gas including, for example, the liquefaction of natural gas.
  • a method of producing liquid natural gas includes providing a source of unpurified natural gas and flowing a portion of the natural gas from the source.
  • the portion of natural gas is divided into at least a process stream and a cooling stream.
  • the process stream is flowed sequentially through a compressor and a first side of at least one heat exchanger.
  • At least a portion of the process stream is flowed from the at least one heat exchanger through an expansion device and into a liquid-gas separator.
  • the cooling stream is flowed sequentially through an expander and a second side of the at least one heat exchanger.
  • a refrigerant is flowed in a heat exchange relationship with the process stream, the refrigerant being maintained separate from the process stream and the cooling stream.
  • the method may further include forming a slurry within the separator, the slurry comprising at least liquid natural gas and solid carbon dioxide.
  • Forming the slurry may be accomplished by expanding the gas, such as through one or more Joule-Thomson valves.
  • the slurry may be flowed into one or more hydrocyclones by way of one or more pressurized transfer tanks.
  • the transfer tanks may be used alternately or sequentially so as to provide a continuous transfer of slurry to the hydrocyclones.
  • the hydrocyclones substantially separate the solid carbon dioxide and the liquid natural gas.
  • a thickened slush may exit an underflow of the hydrocyclone wherein the thickened slush may include the solid carbon dioxide and a portion of the liquid natural gas. The remaining portion of liquid natural gas is flowed through an overflow of the hydrocyclone.
  • a liquefaction apparatus which may also be termed a "plant,” is provided.
  • the liquefaction plant includes a compressor, a first expansion device, a first heat exchanger, at least a second expansion device and a gas-liquid separator.
  • the liquefaction plant further includes a first flow path configured for sequential delivery of a first stream of gas through the compressor and a first side of the first heat exchanger.
  • a second flow path is defined and configured for sequential delivery of a second stream of gas through the first expansion device and a second side of the first heat exchanger.
  • At least one additional flow path is defined and configured for delivery of at least a Atty. Docket No. BA-087 PCT
  • a refrigerant loop is defined and configured to flow a refrigerant stream in a heat exchange relationship with the first stream, wherein the refrigerant stream remains separate from the first stream and the second stream.
  • the liquefaction plant may include additional components including a plurality of transfer tanks configured to sequentially or alternately fill with slurry and transfer the slurry to one or more hydrocyclones.
  • the hydrocyclones may be used to separate solids from the liquids. Additionally, filters may be used to further remove solids from the liquids.
  • a sublimation tank may be coupled to the hydrocyclones and configured to receive the solids and sublime them back to a gaseous state.
  • FIG. 1 is a schematic overview of a liquefaction plant according to one embodiment of the present invention
  • FIG. 2 is a process flow diagram depicting a liquefaction cycle according to one embodiment of the present invention
  • FIG. 3 is a process flow diagram depicting a liquefaction cycle according to another embodiment of the present invention.
  • a schematic overview of a portion of a liquefied natural gas (LNG) station 100 is shown according to one embodiment of the present invention. It is noted that, while the present invention is set forth in terms of liquefaction of natural gas, the present invention may be utilized for the liquefaction of other gases as will be appreciated and understood by those of ordinary skill in the art.
  • LNG liquefied natural gas
  • the liquefaction station 100 includes a "small scale" natural gas liquefaction plant 102 which is coupled to a source of natural gas such as a pipeline 104, although other sources, such as a well head, are contemplated as being equally suitable.
  • the term "small scale” is used to differentiate from a larger scale plant having the capacity of producing, for example 70,000 gallons of LNG or more per day.
  • the presently disclosed liquefaction plant may have capacity of producing, for example, approximately 10,000 gallons of LNG a day but may be scaled to produce a different output as needed and is not limited to small scale operations or Atty. Docket No. BA-087 PCT
  • the liquefaction plant 102 of the present invention is considerably smaller in physical size than conventional large-scale plants and may be readily transported from one site to another.
  • One or more pressure regulators 106 may be positioned along the pipeline 104 for controlling the pressure of the gas flowing therethrough.
  • Such a configuration is representative of a pressure letdown station wherein the pressure of the natural gas is reduced from the high transmission pressures at an upstream location to a pressure suitable for distribution to one or more customers at a downstream location.
  • Upstream of the pressure regulators 106 for example, the pressure in the pipeline may be approximately 600 to 800 pounds per square inch gauge (psig) while the pressure downstream of the regulators may be reduced to approximately 470 psig or less.
  • psig pounds per square inch gauge
  • such pressures are merely examples and may vary depending on the particular pipeline 104 and the needs of the downstream customers.
  • the available pressure of the upstream gas in the pipeline 104 is not critical as the pressure thereof may be raised, for example by use of an auxiliary booster pump, compressor, or other appropriate mechanism prior to the gas entering the liquefaction process described herein.
  • the regulators may be positioned near the plant 100 or at some distance therefrom. As will be appreciated by those of ordinary skill in the art, in some embodiments such regulators 106 may be associated with, for example, low pressure lines crossing with high pressure lines or with a different flow circuits.
  • a stream of feed gas 108 Prior to any reduction in pressure along the pipeline 104, a stream of feed gas 108 is split off from the pipeline 104 and fed through a flow meter 110 which measures and records the amount of gas flowing therethrough.
  • the stream of feed gas 108 then enters the small scale liquefaction plant 102 through a plant inlet 112 for processing, as will be detailed hereinbelow.
  • a portion of the feed gas entering the liquefaction plant 102 becomes LNG and exits the plant 102 at a plant outlet 114 for storage in a suitable tank or vessel 116.
  • the vessel 116 is configured to hold at least 10,000 gallons of LNG at a pressure of approximately 35 pounds per square inch absolute (psia) and at temperatures, for example, as low as approximately -240 0 F.
  • psia pounds per square inch absolute
  • a vessel outlet 118 is coupled to a flow meter 120 in association with dispensing the
  • a vessel inlet 122 coupled with a valve/meter set 124 which could include flow and or process measurement devices, enables the venting and/or purging of a Atty. Docket No. BA-087 PCT
  • Piping 126 associated with the vessel 116 and connected with a second plant inlet 128 provides flexibility in controlling the flow of LNG from the liquefaction plant 102 and also enables the flow to be diverted away from the vessel 116, or for drawing vapor from the vessel 116, should conditions ever make such action desirable.
  • the liquefaction plant 102 is also coupled to a downstream section 130 of the pipeline 104 at a second plant outlet 132 for discharging the portion of natural gas not liquefied during the process conducted within liquefaction plant 102 along with other constituents which may be removed during production of the LNG.
  • vent piping 134 may be coupled with piping of liquefaction plant 102 as indicated by interface points 136A and 136B. Such vent piping 134 will similarly carry gas into the downstream section 130 of the pipeline 104.
  • the second plant outlet 132 is shown as being coupled with the pipeline 104, the second plant outlet 132 could actually be configured for discharging into a different pipeline, a different circuit of the same pipeline, or into some other structure if desired.
  • valve/meter set 138 which could include flow and/or process measuring devices, may be used to measure the flow of gas therethrough.
  • the valve/meter sets 124 and 138, as well as the flow meters 110 and 120, may be positioned outside of the plant 102 and/or inside the plant as may be desired.
  • flow meters 110 and 120 when the outputs thereof are compared, help to determine the net amount of feed gas removed from the pipeline 104 as the upstream flow meter 110 measures the gross amount of gas removed and the downstream flow meter 138 measures the amount of gas placed back into the pipeline 104, the difference being the net amount of feed gas removed from pipeline 104.
  • optional flow meters 120 and 124 indicate the discharge of LNG and vapor from the vessel 116.
  • FIG. 2 a process flow diagram is shown, representative of one embodiment of the liquefaction plant 102 schematically depicted in FIG. 1 and as discussed in detail in U.S. Patent Application 11/383,411 filed on May 15, 2006 (one of the applications from which the present application claims priority).
  • a high pressure stream of feed gas 140 i.e., 600 to 800 psia
  • a small portion of feed gas 140 Atty. Docket No. BA-087 PCT
  • liquefaction plant 102 may be split off, passed through a drying filter and utilized as instrument control gas in conjunction with operating and controlling various components in the liquefaction plant 102.
  • a separate source of instrument gas such as, for example, nitrogen, may be provided for controlling various instruments and components within the liquefaction plant 102.
  • instrument controls including, for example, mechanical, electromechanical, or electromagnetic actuation, may likewise be implemented.
  • the feed gas 140 flows through a filter 142 to remove any sizeable objects which might cause damage to, or otherwise obstruct, the flow of gas through the various components of the liquefaction plant 102.
  • the filter 142 may additionally be utilized to remove certain liquid and solid components.
  • the filter 142 may be a coalescing type filter.
  • An example filter is available from Parker Filtration, located in Tewksbury, Massachusetts and is designed to process approximately 5000 standard cubic feet per minute (SCFM) of natural gas at approximately 60 0 F at a pressure of approximately 500 psia.
  • SCFM standard cubic feet per minute
  • Another example of a filter that may be utilized includes a model AKH-0489-DXJ with filter #200-80-DX available from MDA Filtration, Ltd. of Cambridge, Ontario, Canada.
  • the filter 142 may be provided with an optional drain which may discharge, for example, into piping near the plant exit 132 or it may discharge to some other desired location. In one embodiment, the discharge from the filter 142 may ultimately reenter the downstream section 130 of the pipeline 104 (see FIG. 1). Bypass piping may be routed around the filter 142, allowing the filter 142 to be isolated and serviced as may be required without interrupting the flow of gas into the liquefaction plant 102.
  • the feed gas 140 may flow through a compressor 144, if necessary, to raise the pressure of the feed gas 140 to a desired level.
  • a compressor 144 may be used to boost the pressure of the feed gas 140 to the desired pressure. If the pressure of the feed gas 140 entering the inlet 112 is sufficient, the feed gas 140 may be routed around the compressor 144. A water clean-up cycle may be incorporated into the plant 102.
  • a water clean-up cycle may include a source of methanol 146, or some other water absorbing product, which is injected into the feed gas 140, such as, for example, by means of a pump, at a location relatively early in the flow of feed gas 140 through the plant 102.
  • a source of methanol 146 or some other water absorbing product, which is injected into the feed gas 140, such as, for example, by means of a pump, at a location relatively early in the flow of feed gas 140 through the plant 102.
  • a pump or Atty. Docket No. BA-087 PCT
  • variable flow capability to inject methanol into the gas stream such as, for example, by way of at least one of an atomizing or a vaporizing nozzle.
  • multiple types of nozzles may be utilized such that an appropriate nozzle may be selectively utilized depending on the flow characteristics of the feed gas 140 at a given point in time.
  • a suitable pump for injecting the methanol may include variable flow control in the range of 0.4 to 2.5 gallons per minute (GPM) at a design pressure of approximately 1000 psia for a water content of approximately 2 to 7 pounds mass per millions of standard cubic feet (lbm/mmscf).
  • the variable flow control may be accomplished through the use of a variable frequency drive coupled to a motor of the pump.
  • GPM gallons per minute
  • one such pump is available from America LEWA located in Holliston, Massachusetts as model number EKM7-2-10MM.
  • methanol When methanol is used, it is mixed with the gas stream to lower the freezing point of any water which may be contained therein.
  • the methanol mixes with the gas stream and binds with the water to prevent the formation of ice in one or more flow paths defined within the liquefaction process.
  • the feed gas 140 is split into two streams, a cooling stream 152 and a process stream 154.
  • the cooling stream 152 enters a turbo expander 156 at a pressure of approximately 840 psig and at a temperature of approximately 60 0 F and is expanded to form an expanded cooling stream 152' exhibiting a lower pressure, for example approximately 50 psig, and a reduced temperature of, for example, approximately -140 0 F.
  • the expanded cooling stream 152' is a cold mass of fluid that provides cooling during the process of producing liquefied gas.
  • the turbo expander 156 is a turbine which expands the gas and extracts power from the expansion process.
  • a rotary compressor 158 may be coupled to the turbo expander 156 by mechanical means, such as through a shaft 160, so as to utilize the power generated by the turbo expander 156 to compress the process stream 154.
  • the reduction of pressure from the transmission line or pipeline 104 to a distribution pressure, effected by the turbo expander 156 provides the majority of the energy used in the plant 102 making it extremely economical to operate the plant 102.
  • the proportion of gas in each of the cooling and process lines 152 and 154 is determined by the power requirements of the compressor 158 as well as the flow and pressure drop across the turbo expander 156. Vane control valves within the turbo expander 156 may be used to control the proportion of gas between the cooling and process lines 152 and 154 as is required according to the above stated parameters. In one embodiment, the feed gas 140 may be proportioned substantially evenly between the cooling and process lines 152 and 154.
  • An example of a turbo expander 156 and compressor 158 system includes a frame size ten (10) system available from GE Rotoflow, Inc., located in Gardona, California.
  • the expander 156 compressor 158 system may be designed to operate at approximately 840 psig at 5,000 pounds mass per hour at about 6O 0 F.
  • the expander/compressor system may also be fitted with gas bearings.
  • gas bearings may be supplied with gas through a supply line 155 which draws a portion of the feed gas therethrough.
  • the portion of gas directed to any such gas bearing is relatively insubstantial as compared to the mass of gas flowing through the cooling and process lines 152 and 154.
  • gas bearings may be supplied by a separate flow of gas such as nitrogen.
  • the expander/compressor system may be fitted with other types of bearings including, for example, magnetic or oil bearings.
  • bypass piping 162 routes the cooling stream 152 around the turbo expander 156.
  • bypass piping 164 routes the process stream 154 around the compressor 158.
  • the bypass piping 162 and 164 may be used during startup of the plant 102 to bring certain components to a steady state condition prior to the processing of LNG within the liquefaction plant 102.
  • the bypass piping 162 and 164 may be used while various components (such as the heat exchanger 166 which will be discussed hereinbelow), are gradually brought to a steady state temperature so as to avoid inducing thermal shock in such components.
  • the pressure of the feed gas 140 is sufficient, the compressor 158 need not be used and the process stream may continue through the bypass piping 164.
  • valves may be opened to recirculate high pressure gas through the bypass piping 164 to the inlet side of the compressor 158.
  • thermal shock might result from the immediate flow of gas from the turbo expander 156 and compressor 154 into certain downstream components.
  • the heat exchanger 166 may be required to bring the system to a thermally steady state condition upon start-up of the liquefaction plant 102.
  • the temperature of the process stream 154 is not increased prior to its introduction into the heat exchanger 166.
  • the cooling stream 152 may pass through an expansion valve, such as a Joule-Thomson (JT) valve 163, allowing the cooling stream to expand thereby reducing its temperature.
  • JT Joule-Thomson
  • the JT valve 163 utilizes the Joule-Thomson principle that expansion of gas will result in an associated cooling of the gas as well.
  • the cooling stream 152 may then be used to incrementally reduce the temperature of the heat exchanger 166.
  • the heat exchanger 166 is a high efficiency heat exchanger made from aluminum. In start-up situations it may be desirable to reduce the temperature of such a heat exchanger 166 by, for example, as much as approximately 1.8°F per minute until a defined temperature limit is achieved. During start-up of the liquefaction plant 102, the temperature of the heat exchanger 166 may be monitored as it incrementally decreases. The JT valve 163 and other valving or instruments may be controlled in order to effect the rate and pressure of flow in the cooling stream 152 and process stream 154' which ultimately controls the cooling rate of heat exchanger 166 and/or other components of the liquefaction plant.
  • the process stream 154 flows through the compressor 158 raising the pressure of the process stream 154.
  • the ratio of the outlet to inlet pressures of a rotary compressor may be approximately 1.5 to 2.0, with an average ratio being around 1.7.
  • the compression process is not thermodynamically ideal and, therefore, adds heat to the process stream 154 as it is compressed.
  • the heat exchanger 166 may include a high efficiency heat exchanger and, in one embodiment, may be formed as a countercurrent flow, plate and fin type heat exchanger. Additionally, the plates and fins may be formed of a highly thermally conductive material such as, for example, aluminum. In one embodiment, the high efficiency heat exchanger 166 may include a multipass, plate and fin heat exchanger such as is available from Chart Industries, Inc. of La Crosse, Wisconsin.
  • the heat exchanger 166 is positioned and configured to efficiently transfer as much heat as possible away from the compressed process stream 154' as it passes therethrough.
  • the liquefaction plant 102 is desirably configured such that temperatures generated within the heat exchanger 166 are never low enough to generate solid CO 2 which may be present in the feed gas 140, and which formation of solid CO 2 might result in blockage in the flow path of the compressed process stream 154'.
  • methanol may be mixed with the feed gas to lower the freezing point of any water which may be contained therein.
  • the methanol mixes with the gas stream and binds with the water to prevent the formation of ice in the cooling stream 152 during expansion in the turbo expander 156.
  • the methanol is present in the process stream 154 and passes therewith through the compressor 158.
  • the compressed process stream 154' is temporarily diverted from the heat exchanger 166 and passed through a separating tank 168 wherein the methanol/water liquid is separated from the compressed process stream 154'.
  • the liquid is discharged through a valve 170A and the gas flows to a coalescing filter 172 to remove an additional amount of the methanol/water mixture.
  • the methanol/water mixture may be discharged from the coalescing filter 172 through a valve 170B while the dried gas reenters the heat exchanger 166 for further cooling and processing.
  • both valves 170A and 170B discharge the removed methanol/water mixture into piping near the plant exit 132 for discharge into the downstream section 130 of the pipeline 104 (see FIG. 1).
  • a coalescing filter 172 used for removing the methanol/water mixture may exhibit an efficiency of removing the methane/water mixture to less than approximately 75 ppm/w.
  • One such filter is available from Parker Filtration, located in Tewksbury, Massachusetts.
  • the liquefaction process shown in FIG. 2 thus provides for efficient production of natural gas by integrating the removal of water during the process without expensive equipment and preprocessing required prior to the liquefaction cycle, and particularly prior to the expansion of the gas through the turbine expander 156.
  • the cooled, compressed process stream 154" (referred to hereinafter as the product stream 154" for purposes of convenience) flows through two expansion valves, such as JT valves 174 and 176 and into a liquid/vapor separator 180.
  • the two valves 174 and 176 are arranged in a parallel flow configuration and work in concert with one another to control the flow of the product stream 154" into the separator 180.
  • the two valves 174 and 176 are of different sizes.
  • the two valves may exhibit different flow coefficients (C v ).
  • one valve 174 may be sized and configured to accommodate approximately 80% of the flow entering into the separator from the product stream 154" while the other valve 176 may be sized and configured to accommodate the remaining approximately 20% of the flow.
  • the larger valve is held at a constant position while the valve carrying the remaining flow is used for the fine control required to maintain a desired flow rate.
  • a Joule-Thomson effect reduces the temperature and pressure from, for example, approximately 1100 psig at approximately -185 0 F to approximately 35 psig and approximately -23O 0 F (which is the saturation temperature and pressure for the liquid).
  • This pressure drop also precipitates solid CO 2 .
  • the three phase (gas, liquid, and solid CO2) mixture exiting the valves is collected in the separator tank 180.
  • An accumulator 177 may be coupled with the product stream 154" at a location upstream from the valves 174 Atty. Docket No. BA-087 PCT
  • a pressure sense line 178 may extend between the accumulator and the product stream 154" and may be buffered by a restrictive valve 179. Additionally, the accumulator 177 may be directly coupled to the product stream 154".
  • the stream follows a constant enthalpy pressure drop that changes from a high pressure, single phase mixture at a high pressure and low temperature (e.g., approximately 1,100 psig and approximately -200 0 F) to three phases (solid, liquid and gas) with approximately 10% to 28% mass flow being vapor, at a reduced pressure of, for example, 35 psig.
  • the solid component includes solid CO 2
  • the vapor component from the separator 180 is collected and removed therefrom through piping 182 and is routed back to the heat exchanger 166 to provide additional cooling by way of a compressor 186. While shown to be located on the warm side of the heat exchanger 166, the compressor 186 could be positioned on the cold side of the heat exchanger 166, although such positioning might require the compressor to be configured as a cryogenic compressor. In one embodiment, the compressor 186 may be powered by an internal combustion engine driven by a portion of the natural gas flowing through the plant 102. In another embodiment, the compressor 186 may be powered by electricity or other means as will be appreciated by those of ordinary skill in the art.
  • an ejector or an eductor might be utilized in place of the compressor 186 in another embodiment.
  • the compressor 186 may be used to recompress the excess gas from the separator 180 to pressures suitable, for example, for introduction of the gas into the heat exchanger 166.
  • the compressor 186 may be used to increase the pressure of the gas from approximately 35 psig to approximately 50 psig.
  • the compressor 186 may also be coupled to a vent line associated with the storage tank 116 to likewise help maintain the pressure within storage tank 116 at substantially the same pressure as that of the separator 180.
  • a make up line 187 having a regulator 188 may be routed around the compressor 186 to prevent flow surges as may be the case when gas flow from the separator 180 and or storage tank 116 is relatively low.
  • the pressure of such a regulator may be set at a level that is just under the desired saturation pressure for the separator 180.
  • a floating ball check valve may also be installed in the suction line of the compressor 186 to prevent a sudden surge of liquid. If the compressor 186 is located on the cold side of the heat exchanger 166, the floating ball check valve may also be used to prevent any accumulated liquid from entering the Atty. Docket No. BA-087 PCT
  • a back-pressure regulator may be located in the vapor piping 182 to also help control the pressure within the separator 180.
  • the back pressure regulator 184 may be configured with set-point of approximately 35 psig so as to create a saturation pressure of the liquid that is below a desired transfer pressure (i.e., the pressure used to transfer liquid from the separator 180 to other components within the plant 102).
  • the storage tank 116 may be maintained at substantially the same pressure as that of the separator 180.
  • the liquid saturation pressure below associated transfer pressures, the liquid is prevented from boiling when the liquid experiences a pressure drop such as will occur when the liquid flows through piping, valves and other equipment as it is transferred from the separator 180.
  • the pressure difference between the separator 180 e.g., approximately 35 psig
  • a transfer pressure may be specified such that it is sufficient to ensure that any and all line pressure drops encountered en route to the storage tank 116 are accounted for.
  • the liquid will then arrive at the storage tank 116 at saturation pressure, minimizing loss and flow complications that might otherwise occur due to boiling of the liquid during the transfer thereof.
  • solid CO 2 mostly forms as small crystals in the liquid as it exits the JT valves 174 and 176. With the appropriate resident time in the liquid, the CO 2 becomes a sub-cooled solid particle. In the sub-cooled state the particles are less likely to clump together. Keeping the particles suspended in the liquid provides more effective and efficient transfer and separation of the solids from the liquid component. If allowed to settle, the particles have a tendency to clump or stick together.
  • gas bubbles may be introduced into the bottom of the separator 180. Introduction of the gas bubbles helps to agitate the CO 2 solids within the liquid and keep the particles continually moving within the liquid. While not specifically shown in FIG.
  • gas may be drawn from, for example, a location subsequent the coalescing filter 172, to provide the bubbling and agitation of the solids within the separator.
  • the level may be monitored by appropriate sensors.
  • the level of the liquid/solid within the separator 180 may be desirably monitored and controlled in order to provide desired resident times for the CO 2 and thereby ensure that the CO2 particles are subcooled.
  • the liquid/solid slurry will be transferred to at least one of a plurality of transfer tanks 190A and 190B.
  • the transfer tanks 190A and 190B are used alternately.
  • the transfer tanks 190A and 190B are utilized to transfer the slurry from the separator 180 to one of a plurality of hydrocyclones 192A and 192B.
  • transfer tanks 190A and 190B provides improved control over the transfer of the slurry (including transfer of the slurry to the hydrocyclones 192 A and 192B and subsequent transfer of the liquid from the hydrocyclones 192 A and 192B to downstream components such as the storage tank 116), and ensures that adequate transfer pressures are maintained during such transfer. If pressures are not properly maintained during transfer of the slurry, the liquid may boil due to pressure losses associated with piping and other components.
  • the separator 180 When the separator 180 has reached its specified maximum level, two valves will open allowing the fluid to move into one of the transfer tanks (e.g., transfer tank 190A for purposes of the present discussion).
  • the first valve 220A allows the transfer of liquid/CO 2 slurry, while the second valve 222A vents the transfer tank 190A back to the separator 180 enabling the captured gases in the transfer tank 190A to escape as it is being filled with the slurry.
  • bubbler locations may be added to the bottom of the pipe to prevent the CO 2 from settling during the transfer of the slurry (similar to that which has been previously described with respect to the separator 180). It is noted that a single valve may be utilized instead of multiple valves if the single valve is properly located (e.g., physically below the separator 180).
  • the valves 220A and 222 A to the transfer tank 190A close.
  • the liquid CO 2 transfer alternates between the two transfer tanks 190A and 190B associated with the separator tank 180.
  • the valves connecting the separator 180 and transfer tank are closed the liquid/CO 2 mixture is ready to be transferred to the hydrocyclone separator.
  • the pressure sensitive hydrocyclone separates the CO 2 from the liquid by cyclonic action.
  • the transfer tank is pressurized to the Atty. Docket No. BA-087 PCT
  • the transfer pressure is approximately 20 psi higher than the saturation pressure of the liquid. This pressure head provides the motive force for the liquid/CO 2 mixture, prevents the liquid from boiling as pressure drops are realized, and prevents the formation of additional CO 2 that could occur if the pressure were to drop below saturation pressure.
  • transfer tanks 190A and 190B By alternating the filling of the two (or more) transfer tanks 190A and 190B, a constant flow of slurry to a selected hydrocyclone (e.g., 192A) may be easily maintained.
  • the alternating use of transfer tanks 190A and 190B also improves the efficiency and effectiveness of the separation process performed by the hydrocyclones 192A and 192B. It is noted that, if the rate at which liquid is produced (i.e., within the separator 180) falls behind with respect to a desired separation rate of a hydrocyclone 192A, the flow to the hydrocyclone 192A may be suspended while the separator 180 and transfer tanks 190A and 190B fill to a desired level.
  • the transfer tanks 190A and 190B and hydrocyclones 192 A and 192B may be oversized to prevent the possibility of producing liquid in the separator 180 faster than the transfer/separation capabilities of the hydrocyclones 192 A and 192B.
  • the transfer tank (considering tank 190A as an example) is pressurized by use of a pressure regulator 224 which is set at a desired transfer pressure. If the feed line to the transfer tank 190A is sufficient and the regulator 224 is large enough, a regulator 224 can be mounted directly on the transfer tank 190A. This would require one regulator for each tank. However, in another embodiment, both transfer tanks 190A and 190B could be maintained with a smaller feed line and a single regulator 224 as shown in FIG. 2. Use of a single regulator may require the use of storage or accumulator tanks (e.g., 226A) to ensure that the proper volume of gas is used so as to maintain a constant pressure during the complete transfer process. It is noted that the gas used to transfer the liquid will be warmer than the liquid/solid slurry being transferred. As such, any heat transfer effects are accounted for in configuring and sizing the regulator(s) 224 and accumulator tank(s) 226A.
  • the liquid/solid slurry is transferred to, and processed by, one of the hydrocyclones 192A and 192B.
  • the hydrocyclones 192A and 192B act as separators to remove the solid CO 2 from the slurry allowing the LNG or other liquid product to be collected and stored.
  • the hydrocyclones 192A and 192B may be configured to be substantially identical to one another. As such, only a single hydrocyclone 192 A is referenced with respect to the particular details thereof.
  • the hydrocyclone 192 A may be designed, for example, to operate at a pressure of approximately 125 psia at a temperature of approximately - Atty. Docket No. BA-087 PCT
  • the hydrocyclone 192A uses a pressure drop to create a centrifugal force which separates the solids from the liquid.
  • a thickened slush formed of a portion of the liquid natural gas with the solid CO 2 , exits the hydrocyclone 192A through an underflow 194A.
  • the remainder of the liquid natural gas is passed through an overflow 196A for additional filtering.
  • a slight pressure differential for example, between approximately -0.5 psid and 1.5 psid, exists between the underflow 194A and the overflow 196A of the hydrocyclone 192A.
  • the pressure in the hydrocyclone 192A is provided and maintained by the transfer tank (190A or 190B).
  • a control valve 240A may be positioned at the overflow 196A of the hydrocyclone 192A to assist in controlling the pressure differential developed within the hydrocyclone 192A.
  • the underflow pressure may be controlled by the mid-system pressure as may be maintained by the suction side of a recompression compressor 228 (if one is being used) or by the distribution line pressure at the plant outlet 132.
  • a suitable hydrocyclone 192A is available, for example, from Krebs Engineering of Arlington, AZ.
  • the hydrocyclone 192A may be configured to operate at design pressures of up to approximately 125 psi within a temperature range of approximately 100 0 F to -300 0 F.
  • the hydrocyclone 192A may desirably include an interior surface which exhibits a specified surface finish.
  • hydrocyclones 192 A and 192B are selectively coupled with each of the transfer tanks 190A and 190B through appropriate valving and piping such that each of the transfer tanks 190A and 190B may selectively flow slurry to either of the hydrocyclones 192 A and 192B.
  • the use of two hydrocyclones 192A and 192B provides redundancy in the system so that if one hydrocyclone becomes plugged (or partially plugged), the other hydrocyclone may be used while appropriate maintenance is performed on the first.
  • warm gas may be routed from another location in the plant 102 to assist in unplugging a hydrocyclone such as by melting or sublimation of solid CO 2 that may be the source of any such plugging.
  • the selection and control of the transfer tanks 190A and 190B and hydrocyclones 192 A and 192B will be further discussed hereinbelow with respect to the control and operation of the plant 102.
  • the liquid natural gas flows through the overflow 196A of the hydrocyclone 192A and may flow through one of a plurality of filters 200A and 200B placed in a parallel flow configuration.
  • the filters 200A and 200B capture any remaining solid CO 2 which may not have been separated out in the hydrocyclone 192A.
  • the filters 200A and 200B may be configured such as substantially described in the priority patent applications and patents that have been incorporated by reference. Generally, in one embodiment, such filters 200A and Atty. Docket No. BA-087 PCT
  • the filters 200A and 200B may include a first filter screen of coarse stainless steel mesh, a second conical shaped filter screen of stainless steel mesh less coarse than the first filter screen, and a third filter screen formed of fine stainless steel mesh. In another embodiment, all three filter screens may be formed of the same grade of mesh.
  • the filters 200A and 200B may, from time to time, become clogged or plugged with solid CO 2 captured therein.
  • the other filter i.e., 200B
  • the other filter may be purged of CO 2 by passing a relatively high temperature natural gas therethrough in a counter flowing fashion. For example, gas may be drawn from a relatively warmer gas stream, as indicated at interface points 202B (or 202 A for filter 200A) and 202C to flow through and clean the filter 200B.
  • the cleaning gas may be discharged to a downstream location within the plant 102 adjacent the plant outlet 132 as indicated by interface connections 136E (136D for filter 202A) and 136A.
  • Appropriate valving and piping including, for example, three way valves 204 A and 204B, which may be used to enable the filters 200A and 200B to be switched and isolated from one another as may be required.
  • Other methods of removing CO 2 solids (or other solids) that have accumulated in the filters 200A and 200B are readily known by those of ordinary skill in the art.
  • the filters 200A and 200B may be configured to include a floating bed that traps solid CO 2 while permitting fluid to pass therethrough. As the floating bed becomes filled with CO 2 , the trapped CO 2 settles to the bottom. When the filter (e.g., 200A) is filled with CO 2 , an elevated pressure differential develops indicating that the filter 200A needs to be cleaned and flow can be switched to the redundant filter (e.g., 200B). The first filter 200A may then be cleaned in a manner similar to that which has been described hereinabove. The filtered liquid passes from the filter 200A (or 200B) to a diversion tank 206.
  • Liquid in the diversion tank 206 may be selectively passed to the storage tank 116, utilized for additional cooling within the liquefaction 102, or both.
  • the liquid in the diversion tank 206 may be routed back to the heat exchanger 166, such as through stream 208 and by use of an appropriate pump 210 (referred to herein as a diversion pump).
  • the diversion pump 210 may also be used to elevate the pressure of the liquid such that it may be subsequently recirculated through the liquefaction plant 102 or reintroduced into the pipeline 104.
  • a positive displacement pump may be used to pump liquid out of the diversion tank 208 to the heat exchanger 166 while increasing the pressure of the liquid to, for example, approximately 495 psig if the liquid is going to be passed back to the pipeline 104 (or Atty. Docket No. BA-087 PCT
  • the diversion tank 206 may also be supplied with liquid by way of a make-up pump
  • the make-up pump 212 may be used to supply the needed liquid.
  • the pump 212 will start and fill the tank 206 back to a desired level.
  • a supply of liquid may be maintained in the diversion tank 206 which may be pumped into the heat exchanger 166 to assist in preparing the plant 102 for the liquid production process.
  • the cryogenic liquid in the diversion tank 206 may be used provide cooling during in the final stages of the heat exchanger 166 in order to reduce the temperature of what becomes the compressed product stream 154" to temperatures required for liquid production.
  • the flow of liquid from the diversion tank 206 to the heat exchanger may be controlled based on the temperature of the product stream 154".
  • the pump 210 may provide additional flow of liquid from the diversion tank 206 to the heat exchanger 166.
  • the pump 210 may be controlled to reduce the amount of liquid being provided to the heat exchanger 166.
  • the pump 210 may be configured as a variable flow pump and controlled, for example, by a proportional, integral, derivative (PID) controller.
  • PID proportional, integral, derivative
  • the thickened slush formed in the hydrocyclone exits the underflow 194A and passes through piping 213A to a sublimation tank 214.
  • the sublimation tank 214 may include, for example, a heat exchanger configured to convert the solid CO 2 to a gaseous state.
  • the sublimation tank 214 may include a tube-in-shell heat exchanger such as that which is disclosed in the priority applications and patents previously incorporated by reference.
  • the slush may enter such a heat exchanger on the tube side thereof.
  • the slush entering the sublimation tank 214 will include approximately 10% solid CO 2 by mass in a liquid carrier.
  • Warm gas for example, gas at a temperature of approximately 100 0 F, may flow through the sublimation tank 214 by way of a Atty. Docket No. BA-087 PCT
  • the liquid carrier violently flashes to a gas which, in addition to transferring heat to the solid CO 2 , provides a positive motive flow for the solid CO 2 .
  • the CO 2 constantly interacts with the tube walls as it progresses through the tubes. Additionally, the tube walls become progressively warmer along the flow path of the CO 2 . Once all of the liquid has flashed to a gas and warmed to approximately -8O 0 F, the CO 2 will start to sublime, aided by the relatively warm tube walls and the warmed gases.
  • the sublimation tank 214 may be configured such that the warm gas from stream 216 will warm all areas of the shell (when configured as a tube-in-shell heat exchanger) to a temperature above the sublimation temperature of the CO2. In this manner, the sublimation tank becomes "self -thawing" in the case of any potential plugs caused by the solid CO 2 passing through the tube side thereof.
  • the gas leaving the sublimation tank (including both the warming gas and the sublimed CO 2 ) may be routed back to the expanded cooling stream 152' to assist in cooling the compressed process stream 154' in heat exchanger 166.
  • the plant 102 may include a recompression compressor 228.
  • the recompression compressor 228 may be used to recompress gas to a desired pressure prior to reintroduction of the gas into the pipeline 104 (or other receiving station or system) or prior to the recirculation of gases into the plant 102 for reprocessing thereof.
  • Gas from the separator 180 and from the storage tank 116 may be used, for example, as fuel for a combustion engine that drives the recompression compressor 228.
  • valves may be placed throughout the liquefaction plant 102 for various purposes such as facilitating physical assembly and startup of the plant 102, maintenance activities, or for collecting of material samples at desired locations throughout the plant 102 as will be appreciated by those of ordinary skill in the art.
  • the plant 102 may be configured as a relatively compact structure such as described in the applications and patents previously incorporated by reference. Atty. Docket No. BA-087 PCT
  • the plant 102 may be constructed on one or more skids for simple transportation and erection of the plant 102.
  • the plant 102 may further include controls such that minimal operator input is required for the operation of the plant 102. Indeed, it may be desirable that the plant be able to function without an on-site operator. Thus, with proper programming and control design, the plant may be accessed through remote telemetry for monitoring and/or adjusting the operations of the plant. Similarly, various alarms may be built into such controls so as to alert a remote operator or to shut down the plant in an upset condition.
  • One suitable controller for example, may be a DL405 series programmable logic controller (PLC) commercially available from Automation Direct of Cumming, GA.
  • PLC DL405 series programmable logic controller
  • the JT valves 174 and 176 are closed such that the product stream 154" is diverted back into the heat exchanger 166 after passing through a JT valve 230.
  • the expander 156/compressor 158 will be manually accelerated at a rate that corresponds with approximately 2 0 F per minute temperature reduction in the heat exchanger 166. This acceleration may stop when the pressure of the compressed process stream 154' builds to approximately 800 psig. If the pressure of the pipeline 104 or other source is running at a pressure of approximately 800 psig, use of the compressor 158 may not be necessary. However, the compressor 158 may be started to provide a desired boost in pressure to the process stream 154.
  • the diversion tank 206 Prior to closing the JT valve 230 in the cooling stream and opening valves 174 and 176, the diversion tank 206 may be filled with liquid from the storage tank 116. The flow may simply fill the diversion tank 206 or it may recirculate back into the storage tank 116. When the temperature of the product stream 154" reaches a desired temperature, the flow of product stream 154" is routed to the separator 180. At this time the diversion tank pump 210 will start pumping liquid from the diversion tank 206 to the heat exchanger 166 to aid in the final and rapid cooling of the compressed process stream 154'. Switching the flow of the product stream 154" into the separator 180 will prevent
  • CO 2 from building up in the heat exchanger 166. It is noted that CO 2 formation begins when the pressure drops from approximately 800 psig at approximately -16O 0 F to a pressure of approximately 35 psig at a temperature of approximately -22O 0 F.
  • the separator 180 will flash the small amount of liquid and CO 2 to a gas, as the temperature of the product stream 154" decreases. Decreased temperatures in the product stream 154" result in the production of additional liquid. The liquid quality will also improve as the temperature drops and the CO 2 will be suspended in the liquid as the tank of the separator 180 cools to a point at which the liquid remains.
  • the separator 180 may be flushed. Flushing the cold liquid into the warm transfer tanks 190A and 190B will boil off most of the liquid and any remaining liquid may be used to continue cooling off various components of the plant 102. As the temperature of the product stream 154" reaches a desired range of, for example, approximately -18O 0 F to approximately -200 0 F, the expander 156 will have been accelerated to a desired operational speed.
  • the back-end flow loop generally refers to the flow of fluid through the liquid handling components of the plant and particularly the flow through the valve or valves (e.g., valves 174 and 176) leading into the gas-liquid separator 180.
  • the cooling loop refers generally to flow of fluid that provides cooling via the heat exchanger 166 during normal operating conditions and particularly includes the flow of liquid from the diversion tank 206. Further details regarding the control of the plant 102 are set forth in the various U.S. Patents and U.S. Patent Applications previously incorporated by reference including, for example, U.S. Patent Application No. 11/383,411 filed on May 15, 2006 previously incorporated by reference.
  • FIG. 3 a process flow diagram is shown which is representative of another embodiment of a liquefaction plant 102'.
  • the plant 102' is similar to the plant 102 previously discussed herein with respect to FIG. 2 and similar components and flow paths are identified using similar reference numerals.
  • the plant 102 discussed with respect to FIG. 2 utilizes a substantial portion of the gas for cooling of the process/product streams.
  • a plant 102 might produce between approximately 6,000 to approximately 40,000 volumetric gallons of liquid product per day. This output may represent a production rate of approximately 6% to approximately 20% of the gas that is introduced into the plant 102.
  • the balance of the gas entering the plant 102 Atty. Docket No. BA-087 PCT
  • liquefied product is used primarily for refrigeration of the liquefied product.
  • gas being used as a refrigerant, up to approximately 40% may be liquefied with approximately 20% being returned to the plant 102 for use in the cooling required to convert the gas to a liquid and, therefore, is not available to be utilized as liquid product.
  • approximately half of the total liquid produced by the plant may be required for refrigeration purposes and is discharged to the receiver (e.g., pipeline, reservoir or other receiving station).
  • the receiver e.g., pipeline, reservoir or other receiving station.
  • Such a configuration can pose limits on the amount of liquid a plant 102 is able to produce.
  • Such a configuration may also be limited by the size of receiver (e.g., pipeline, reservoir or other receiving station) that receives gas (also referred to as tail gas) from the outlet 132 of the plant 102.
  • the plant 102' shown and described with respect to FIG. 3 reduces the amount of gas required for refrigerant purposes, resulting in higher liquefied product volumes, and provides additional flexibility in site location of the plant 102', including the ability to install and operate the plant 102' at a location where tail gas reservoirs or receivers are limited or smaller than desired for operating previously described plants (e.g., plant 102).
  • the feed gas 140 may flow through a filter 142 such as previously discussed. After the feed gas 140 flows through the filter 142, it may flow through a compressor 144, if necessary, to raise the pressure of the feed gas 140 to a desired level. If the pressure of the feed gas 140 entering the inlet 112 is sufficient, the feed gas 140 may be routed around the compressor 144.
  • a water clean-up cycle may again be incorporated into the plant 102.
  • a water clean-up cycle may include a source of methanol 146, or some other water absorbing product, which is injected into the feed gas 140, such as, for example, by means of a pump, at a location relatively early in the flow of feed gas 140 through the plant 102.
  • Other possible water clean-up methods are also contemplated as will be appreciated by those of ordinary skill in the art.
  • the feed gas 140 is split into a cooling stream 152 and a process stream 154.
  • the cooling stream 152 enters a turbo expander 156 at a pressure of approximately 840 psig and at a temperature of approximately 60 0 F and is expanded to form an expanded cooling stream 152' exhibiting a lower pressure, for example approximately 50 psig, and a reduced temperature of, for example, Atty. Docket No. BA-087 PCT
  • the expanded cooling stream 152' is a cold mass of fluid that provides cooling during the process of producing liquefied gas.
  • the turbo expander 156 is a turbine which expands the gas and extracts power from the expansion process.
  • a rotary compressor 158 may be coupled to the turbo expander 156 by mechanical means, such as through a shaft 160, so as to utilize the power generated by the turbo expander 156 to compress the process stream 154.
  • the reduction of pressure from the transmission line or pipeline 104 to a distribution pressure, effected by the turbo expander 156 provides the majority of the energy used in the plant 102 making it extremely economical to operate the plant 102.
  • a larger volume of produced liquid will be realized.
  • elevated pressures help to keep any CO 2 contained within the process stream 154 from plugging the various downstream flow paths.
  • the proportion of gas in each of the cooling and process lines 152 and 154 may be determined by the power requirements of the compressor 158 as well as the flow and pressure drop across the turbo expander 156. Vane control valves within the turbo expander 156 may be used, to a certain extent, to control the proportion of gas between the cooling and process lines 152 and 154. Additionally, some flow adjustments through the compressor 156 and expander 158 may be effected by altering the downstream pressure through adjustment of the JT valves 174 and 176. For example, adjusting the valves 174 and 176 to increase the pressure within the product stream 154" results in a reduced flow through the compressor 156. In one embodiment, the feed gas 140 may be proportioned substantially evenly between the cooling and process lines 152 and 154.
  • the expander/compressor system may also be fitted with gas bearings.
  • gas bearings may be supplied with gas through a supply line 155 which draws a portion of the feed gas therethrough.
  • the portion of gas directed to any such gas bearing is relatively insubstantial as compared to the mass of gas flowing through the cooling and process lines 152 and 154.
  • gas bearings may be supplied by a separate flow of gas such as nitrogen.
  • the expander/compressor system may be fitted with other types of bearings including, for example, magnetic or oil bearings.
  • Bypass piping 162 routes the cooling stream 152 around the turbo expander 156.
  • bypass piping 164 routes the process stream 154 around the compressor 158.
  • the bypass piping 162 and 164 may be used during startup of the plant 102 to bring certain components to a steady state condition prior to the processing of LNG within the liquefaction Atty. Docket No. BA-087 PCT
  • the heat exchanger 166 is a high efficiency heat exchanger made from aluminum. In start-up situations it may be desirable to reduce the temperature of such a heat exchanger 166 by, for example, as much as approximately 1.8°F per minute until a defined temperature limit is achieved. During start-up of the liquefaction plant 102, the temperature of the heat exchanger 166 may be monitored as it incrementally decreases.
  • the JT valve 163 and other valving or instruments may be controlled in order to effect the rate and pressure of flow in the cooling stream 152 and process stream 154' which ultimately controls the cooling rate of heat exchanger 166 and/or other components of the liquefaction plant. Additionally, during start-up, it may be desirable to have an amount of LNG already present in the tank 116 (FIG. 1). Some of the LNG may be cycled through the system in order to cool various components if so desired or deemed necessary. Also, as will become apparent upon reading the additional description below, other cooling devices, including additional JT valves, located in various "loops" or flow streams may likewise be controlled during start-up in order to cool down the heat exchanger 166 or other components of the liquefaction plant 102.
  • the process stream 154 flows through the compressor 158 raising the pressure of the process stream 154.
  • the compression process is not thermodynamically ideal and, therefore, adds heat to the process stream 154 as it is compressed.
  • the compressed process stream is subjected to one or more cooling processes including, for example, a heat exchange process carried out in heat exchanger 166. It is noted that, if the heat of compression is too high, the gas may be precooled, for example, by an ambient heat exchanger prior to its entry into the heat exchanger 166.
  • the heat exchanger 166 may include a high efficiency heat exchanger and, in one embodiment, may be formed as a countercurrent flow, plate and fin type heat exchanger.
  • the plates and fins may be formed of a highly thermally conductive material such as, for example, aluminum.
  • the high efficiency heat exchanger 166 may include a multipass, plate and fin heat exchanger such as is available from Chart Industries, Inc. of La Crosse, Wisconsin. Atty. Docket No. BA-087 PCT
  • the methanol and water may be removed from the flow at a location about midway through the heat exchange process as previously described herein.
  • the cooled, compressed process stream 154" (referred to hereinafter as the product stream 154" for purposes of convenience) flows through a second heat exchanger 300 that is associated with a refrigeration system 302.
  • the refrigeration system includes a refrigerant loop 304 that maintains the refrigerant separate and independent from the flow of any gas within the plant 102'.
  • the refrigerant being used in the refrigerant loop 304 does not include any of the gas introduced into the plant 102' through the inlet 112.
  • the refrigerant in the refrigerant loop 304 does not come into physical contact with, or otherwise intermix with the various gas or liquid streams of the plant 102' (i.e., cooling stream 152, expanded cooling stream 152', process stream 154, compressed process stream 154', product stream 154", the liquid streams flowing from the hydrocyclones 192A and 192B through the filters 200A and 200B to the storage tank 116, or the slush streams flowing from the hydrocyclones 192 A and 192B to the sublimation tank 214).
  • Various types of refrigerants and refrigeration components may be utilized depending on cooling requirements of the plant 102' as will be recognized by those of ordinary skill in the art.
  • refrigerants such as propane, ethane, methane, or nitrogen may be used. Cycles such as mixed refrigerant or cascade cycles may also be employed.
  • the combination of the high efficiency heat exchanger 166 and the second heat exchanger serve to remove heat from the compressed process stream 154', to a very low temperature, for example between approximately -185°F and approximately -200 0 F at a pressure, for example, of approximately 1,100 psig.
  • the heat exchangers 166 and 300 are positioned and configured to efficiently transfer as much heat as possible away from the compressed process stream 154' and product stream 154" as it passes through such heat exchangers 166 and 300.
  • the liquefaction plant 102' is desirably configured such that temperatures generated within the heat exchangers 166 and 300 are never low enough to generate solid CO 2 which may be present in the feed gas 140, and which formation of solid CO 2 might result in blockage in the flow path of the compressed process stream 154' or product stream 154".
  • the portion may be flowed Atty. Docket No. BA-087 PCT
  • the portion of gas may be split from the product stream 154" at a location prior to the second heat exchanger 300 (such as shown by dashed lines) or at a location subsequent the second heat exchanger 300.
  • the product stream 154" flows through two expansion valves, such as JT valves 174 and 176 and into a liquid/vapor separator 180 (although a different number of valves may be utilized).
  • the two valves 174 and 176 may be arranged in a parallel flow configuration and work in concert with one another to control the flow of the product stream 154" into the separator 180.
  • a Joule-Thomson effect reduces the temperature and pressure from, for example, approximately 1100 psig at approximately -185 0 F to approximately 35 psig and approximately -23O 0 F (which is the saturation temperature and pressure for the liquid).
  • This pressure drop also precipitates solid CO 2 .
  • the three phase (gas, liquid, and solid CO2) mixture exiting the valves is collected in the separator tank 180 wherein a liquid/solid slurry is formed and the gas or vapor is separated from the liquid/solid slurry.
  • An accumulator 177 may be coupled with the product stream 154" at a location upstream from the valves 174 and 176 to further dampen flow pulses that may be introduced into the stream 154" by the valves 174 and 176.
  • a pressure sense line 178 may extend between the accumulator 177 and the product stream 154" and may be buffered by a restrictive valve 179. Additionally, the accumulator 177 may be directly coupled to the product stream 154".
  • the stream follows a constant enthalpy pressure drop that changes from a high pressure, single phase mixture at a high pressure and low temperature (e.g., approximately 1,100 psig and approximately -200 0 F) to three phases (solid, liquid and gas) with approximately 10% to 28% mass flow being vapor, at a reduced pressure of, for example, 35 psig.
  • the solid component includes solid CO 2
  • the vapor component from the separator 180 is collected and removed therefrom through piping 182 and is routed back to the heat exchanger 166 to provide additional cooling by way of a compressor 186.
  • the compressor 186 While shown to be located on the warm side of the heat exchanger 166, the compressor 186 could be positioned on the cold side of the heat exchanger 166, although such positioning might require the compressor to be configured as a cryogenic compressor. In one embodiment, the compressor 186 may be powered by an internal combustion engine driven by a portion of the natural gas flowing through the plant 102. In Atty. Docket No. BA-087 PCT
  • the compressor 186 may be powered by electricity or other means as will be appreciated by those of ordinary skill in the art. It is further noted that an ejector or an eductor might be utilized in place of the compressor 186 in other embodiments.
  • the compressor 186 may be used to recompress the excess gas from the separator 180 to pressures suitable, for example, for introduction of the gas into the heat exchanger 166.
  • the compressor 186 may be used to increase the pressure of the gas from approximately 35 psig to approximately 50 psig.
  • the compressor 186 may also be coupled to a vent line associated with the storage tank 116 to likewise help maintain the pressure within storage tank 116 at substantially the same pressure as that of the separator 180.
  • a make up line 187 having a regulator 188 may be routed around the compressor 186 to prevent flow surges as may be the case when gas flow from the separator 180 and or storage tank 116 is relatively low.
  • the pressure of such a regulator may be set at a level that is just under the desired saturation pressure for the separator 180.
  • a floating ball check valve may also be installed in the suction line of the compressor 186 to prevent a sudden surge of liquid. If the compressor 186 is located on the cold side of the heat exchanger 166, the floating ball check valve may also be used to prevent any accumulated liquid from entering the suction side of the pump. It is noted that if the compressor 186 is located on the warm side of the heat exchanger 166, no liquid will be present at the suction side of the compressor 186 under normal operating conditions.
  • a back-pressure regulator may be located in the vapor piping 182 to also help control the pressure within the separator 180.
  • the back pressure regulator 184 may be configured with set-point of approximately 35 psig so as to create a saturation pressure of the liquid that is below a desired transfer pressure (i.e., the pressure used to transfer liquid from the separator 180 to other components within the plant 102).
  • the storage tank 116 may be maintained at substantially the same pressure as that of the separator 180.
  • the liquid saturation pressure below associated transfer pressures, the liquid is prevented from boiling when the liquid experiences a pressure drop such as will occur when the liquid flows through piping, valves and other equipment as it is transferred from the separator 180.
  • the pressure difference between the separator 180 e.g., approximately 35 psig
  • a transfer pressure may be specified such that it is sufficient to ensure that any and all line pressure drops encountered en route to the storage tank 116 are accounted for.
  • the liquid will then arrive at the storage tank 116 at saturation pressure, Atty. Docket No. BA-087 PCT
  • solid CO 2 mostly forms as small crystals in the liquid as it exits the JT valves 174 and 176. With the appropriate resident time in the liquid, the CO 2 becomes a sub-cooled solid particle. In the sub-cooled state the particles are less likely to clump together. Keeping the particles suspended in the liquid provides more effective and efficient transfer and separation of the solids from the liquid component.
  • gas bubbles may be introduced into the bottom of the separator 180 in a manner similar to that previously described. As the separator 180 is filled, the level may be monitored by appropriate sensors.
  • the level of the liquid/solid within the separator 180 may be desirably monitored and controlled in order to provide desired resident times for the CO 2 and thereby ensure that the CO 2 particles are subcooled.
  • the liquid/solid slurry will be transferred to at least one of a plurality of transfer tanks 190A and 190B such as previously described.
  • the separator 180 When the separator 180 has reached its specified maximum level, two valves will open allowing the fluid to move into one of the transfer tanks (e.g., transfer tank 190A for purposes of the present discussion).
  • the first valve 220A allows the transfer of liquid/CO 2 slurry, while the second valve 222A vents the transfer tank 190A back to the separator 180 enabling the captured gases in the transfer tank 190A to escape as it is being filled with the slurry.
  • bubbler locations may be added to the bottom of the pipe to prevent the CO 2 from settling during the transfer of the slurry (similar to that which has been previously described with respect to the separator 180). It is noted that a single valve may be utilized instead of multiple valves if the single valve is properly located (e.g., physically below the separator 180).
  • the valves 220A and 222A to the transfer tank 190A close.
  • the liquid CO 2 transfer alternates between the two transfer tanks associated with the SGL tank. Once the valves connecting the separator 180 and transfer tank 190A are closed the liquid/CO 2 mixture is ready to be transferred to the hydrocyclone separator.
  • the pressure sensitive hydrocyclone separates the CO 2 from the liquid by cyclonic action.
  • the transfer tank is pressurized to the desired pressure and the transfer valve is opened.
  • the transfer pressure is approximately 20 psi higher than the saturation pressure of the liquid. This pressure head provides the motive force for the Atty. Docket No. BA-087 PCT
  • liquid/CO 2 mixture prevents the liquid from boiling as pressure drops are realized, and prevents the formation of additional CO 2 that could occur if the pressure were to drop below saturation pressure.
  • the transfer tank (considering tank 190A as an example) is pressurized by use of a pressure regulator 224 which is set at a desired transfer pressure. If the feed line to the transfer tank 190A is sufficient and the regulator 224 is large enough, a regulator 224 can be mounted directly on the transfer tank 192 A. This would require one regulator for each tank. However, in another embodiment, both transfer tanks 190A and 190B could be maintained with a smaller feed line and a single regulator 224 as shown in FIG. 3. Use of a single regulator may require the use of storage or accumulator tanks (e.g., 226A) to ensure that the proper volume of gas is used so as to maintain a constant pressure during the complete transfer process.
  • storage or accumulator tanks e.g., 226A
  • the gas used to transfer the liquid will be warmer than the liquid/solid slurry being transferred. As such, any heat transfer effects are accounted for in configuring and sizing the regulator(s) 224A and accumulator tank(s) 226A.
  • the liquid/solid slurry is transferred to, and processed by, one of the hydrocyclones 192A and 192B.
  • the hydrocyclones 192A and 192B act as separators to remove the solid CO 2 from the slurry allowing the LNG or other liquid product to be collected and stored in a manner similar to that previously described herein in association with other embodiments.
  • the liquid natural gas flows through the overflow 196A of the hydrocyclone 192 A and may flow through one of a plurality of filters 200A and 200B placed in a parallel flow configuration.
  • the filters 200A and 200B capture any remaining solid CO 2 which may not have been separated out in the hydrocyclone 192 A.
  • the filters 200A and 200B may be configured such as substantially described in the priority patent applications and patents that have been incorporated by reference.
  • the filters 200A and 200B may, from time to time, become clogged or plugged with solid CO 2 captured therein.
  • the other filter i.e., 200B
  • gas may be drawn from a relatively warmer gas stream, as indicated at interface points 202B (or 202A for filter 200A) and 202C to flow through and clean the filter 200B as has been previously described.
  • the filtered liquid passes from the filter 200A (or 200B) to the storage tank.
  • the plant 102' does not include a diversion tank (e.g., diversion tank 206 in FIG. 2) or a make-up pump (e.g., make-up pump 210 in FIG. 2) since none of the liquid produced by the plant 102' is being returned or recycled to act as a refrigerant. Rather, the refrigeration system 302 described above is configured to provide adequate cooling such that all of the liquid produced by the plant 102' may be collected as a product.
  • a diversion tank e.g., diversion tank 206 in FIG. 2
  • a make-up pump e.g., make-up pump 210 in FIG. 2
  • the thickened slush formed in the hydrocyclone exits the underflow 194 A and passes through piping 213A to a sublimation tank 214 in a manner similar to that which has been previously described herein.
  • the gas leaving the sublimation tank (including both the warming gas and the sublimed CO 2 ) may be routed back to the expanded cooling stream 152' to assist in cooling the compressed process stream 154' in heat exchanger 166.
  • the plant 102' may include a recompression compressor 228.
  • the recompression compressor 228 may be used to recompress gas to a desired pressure prior to reintroduction of the gas into the pipeline 104 (or other receiving station, reservoir or system) or prior to the recirculation of gases into the plant 102 for reprocessing thereof.
  • Gas from the separator 180 and from the storage tank 116 may be used, for example, as fuel for a combustion engine that drives the recompression compressor 228.
  • valves may be placed throughout the liquefaction plant 102' for various purposes such as facilitating physical assembly and startup of the plant 102', maintenance activities, or for collecting of material samples at desired locations throughout the plant 102' as will be appreciated by those of ordinary skill in the art.
  • the plant 102' may also be configured as a relatively compact structure such as described in the applications and patents previously incorporated by reference. Generally, the plant 102' may be constructed on one or more skids for simple transportation and erection of the plant 102'.
  • the plant 102' may include a variety of controls for effective and efficient operation thereof. Examples of various control schemes are described in association with other embodiments set forth in the present application as well as the various patents and patent applications that have been incorporated by reference herein.
  • the present invention is not limited to the liquefaction of natural gas and the removal of CO 2 therefrom. It is also noted that various teachings set forth in the documents incorporated by reference herein may be combined with one or more of the embodiments described herein and that the described embodiments are not limited by their specific examples.

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  • Separation By Low-Temperature Treatments (AREA)

Abstract

L'invention concerne un appareil, un système et un procédé permettant de produire un gaz liquéfié. Une usine de liquéfaction peut être couplée, par exemple, à une source de gaz naturel non purifié, telle qu'une canalisation d'amenée de gaz naturel dans une station de régulation de pression. Une partie du gaz est aspirée et divisée en un flux de traitement et un flux de refroidissement. Le flux de refroidissement peut passer à travers une vanne de détente. Le flux de traitement compressé est refroidi, ou par un procédé d'échange de chaleur utilisant le flux de refroidissement dilaté, ou par un échangeur de chaleur utilisant un réfrigérant indépendant et séparé, ou par les deux. Le flux de traitement compressé, refroidi est dilaté de façon à liquéfier le gaz naturel. Un séparateur de gaz/liquide sépare la vapeur du gaz naturel liquide. Une partie du gaz liquide peut être utilisée pour un refroidissement supplémentaire ou sensiblement la totalité du gaz liq uide peut être recueillie sous forme de produit.
PCT/US2007/084677 2006-11-16 2007-11-14 Appareil pour la liquéfaction du gaz et procédés associés WO2008064038A2 (fr)

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US11/560,682 US20070107465A1 (en) 2001-05-04 2006-11-16 Apparatus for the liquefaction of gas and methods relating to same
US11/560,682 2006-11-16

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WO2008064038A2 true WO2008064038A2 (fr) 2008-05-29
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