WO2008038495A1

WO2008038495A1 - Shampoo composition

Info

Publication number: WO2008038495A1
Application number: PCT/JP2007/067170
Authority: WO
Inventors: Atsumi Niinomi; Kenji Matsuda
Original assignee: Lion Corporation
Priority date: 2006-09-26
Filing date: 2007-09-04
Publication date: 2008-04-03
Also published as: HK1134431A1; JP5549076B2; CN101528190A; CN101528190B; JPWO2008038495A1

Abstract

Disclosed is a shampoo composition comprising (A) an anionic surfactant, (B) a polyglycerin fatty acid ester having an HLB value of 12 or greater, (C) polyoxyethylene hydrogenated castor oil, and (D) a cationic polymeric compound. The shampoo composition has an excellent foaming property, can provide a smooth feeling during rinsing, can form a creamy foam, is easy to be rinsed out, and can be discharged from a container easily even at a low temperature.

Description

Specification

Shampoo, composition

Technical field

[0001] The present invention relates to a shampoo composition which has good foam cleanliness, ease of rinsing, and excellent dischargeability from a container at low temperatures, and also has a smooth hair after drying.

Background art

[0002] For the purpose of improving the feeling of use of shampoos, various attempts have been made to combine surfactants and polymer compounds in order to improve the feel when foaming is too easy. In particular, in order to improve the feeling of use of a shampoo composition, in general, the emphasis is on enriching foaming and improving the feel of hair after rinsing and drying (for example, Patent Document 1: JP 2005-232140, Patent Document 2: JP 2001-254095). However, these techniques are not considered for improving the texture such as foam creaminess, ease of rinsing, and discharging from a container at a low temperature. In addition, a composition having a good foaming, foam quality, rinsing property and rinsing feeling has been proposed by using a novel aionic surfactant and a viscous mineral (Patent Document 3: Japanese Patent Laid-Open No. 2001-2001). 17

No. 2669), which uses a special anion activator, uses a general inexpensive anionic surfactant, and also has the ability to discharge the container force. The current situation has never existed before.

[0003] In addition, a shampoo that combines an anionic surfactant with polyoxyethylene hydrogenated castor oil, glycerin fatty acid ester, and cationized cellulose has been proposed! (Patent Document 4: JP-A-2006-8611) (Patent Document 5, Patent Document 5: Japanese Laid-Open Patent Publication No. 2006-52198), the foam has a creamy texture, ease of rinsing, and discharge from a container at a low temperature.

[0004] Based on the above, a shampoo composition is desired which has good foam cleanliness, ease of rinsing, and excellent dischargeability from a container at low temperatures, and also has a smooth hair after drying. It was. In addition, the following is mentioned as a prior art document relevant to this invention. [0005] Patent Document 1: Japanese Patent Application Laid-Open No. 2005-232232

Patent Document 2: Japanese Patent Laid-Open No. 2001-254095

Patent Document 3: Japanese Patent Laid-Open No. 2001-172669

Patent Document 4: Japanese Unexamined Patent Publication No. 2006-8611

Patent Document 5: Japanese Unexamined Patent Publication No. 2006-52198

Disclosure of the invention

Problems to be solved by the invention

[0006] The present invention provides a shampoo composition that has good foam cleanliness, ease of rinsing, and dischargeability from a container at low temperatures, and also has a smooth hair after drying. Objective.

Means for solving the problem

[0007] Generally, by using so-called sarcophagus such as a higher fatty acid salt in a shampoo composition, the ability to improve foam creaminess is excellent. There was a problem. On the other hand, when a shampoo composition mainly composed of an anionic surfactant other than a higher fatty acid salt was used, the foam creaminess was poor! /. Therefore, attempts have been made to add nonionic surfactants and polymer compounds to the shampoo composition in order to improve the foam's creaminess, but these ingredients slightly improve the texture of the foam, While it was possible to impart a feeling of, it was liable to cause problems in terms of ease of rinsing, such as luster during rinsing and poor foaming. In particular, a cationic polymer compound frequently used in a shampoo composition slightly improves the feeling of foam and improves the feeling of rinsing and finishing, but it is easy to rinse. At the same time, there is no product that can satisfy them at the same time. Moreover, even if a surfactant is adjusted to make the foam feel and feel too close, it can become extremely viscous at low temperatures or become non-uniform, for example, and it can be discharged at low temperatures. Was good power. It was difficult to obtain a shampoo composition satisfying these simultaneously.

[0008] The present inventor has (A) an anionic surfactant, (B) a polyglycerol fatty acid ester having an HLB of 12 or more, (C) a polyoxyethylene hydrogenated castor oil, and (D) a cationic polymer compound. In combination, the shampoo composition is excellent in foaming ability, touch feeling at the time of rinsing, creamy consistency of the foam, good rinsing, and excellent discharge from a container at a low temperature. It was found that it can be obtained.

Therefore, the present invention provides

[1] A shampoo containing (A) an anionic surfactant, (B) a polyglycerin fatty acid ester having an HLB of 12 or more, (C) a polyoxyethylene hydrogenated castor oil, and (D) a cationic polymer compound Yarns and synthetics,

[2] A shampoo composition according to [1], further comprising (E) 1-hydroxy-2-pyridones represented by the following general formula (1):

The invention's effect

[0010] According to the present invention, a shampoo composition is obtained which has good foam cleanliness, ease of rinsing, good discharge from a container at low temperature, and good smoothness of hair after drying. This force S is possible.

BEST MODE FOR CARRYING OUT THE INVENTION

[0011] The shampoo composition of the present invention comprises (A) an anionic surfactant, (B) a polyglycerol fatty acid ester having an HLB of 12 or more, (C) a polyoxyethylene hydrogenated castor oil, and (D) a cationic property. A shampoo composition containing a polymer compound, preferably (E) 1-hydroxy 2-pyridones represented by the following general formula (1).

[0012] Examples of the (A) aionic surfactant include the following aionic surfactants (i) to (vii), which can be used alone or in appropriate combination of two or more.

[0013] (i) The following general formula (2)

R ³ SO M ¹ (2)

(In the formula, R ³ is 12 to 16 carbon atoms; α-olefin, 16 to 12 carbon atoms; 16 vinylidene-type olefin, 12 to 12 carbon atoms; 16-aminoolefin, 12 to 16 carbon atoms; hydroxyalkyl group having 16 carbon atoms; Or a linear or branched alkyl group having 10 to 18 carbon atoms, and Μ ¹ is an alkali metal, an alkyl-substituted ammonium, a hydroxyalkyl-substituted ammonium, or a hydrogen atom.)

Or a salt thereof. [0014] Specific examples of the compound represented by the general formula (2) include sodium α-olefin sulfonate (AOS salt), sodium alkyl sulfate, and the like.

[0015] (ii) The following general formula (3)

R ⁴ -0- (R ⁵ 0)-SO M ² (3)

m 3

Wherein R ⁴ is an alkyl group having 8 to 18 carbon atoms, an alkyl group having 5 to 18 carbon atoms, an alkylphenyl group having an alkyl group having 15 carbon atoms, or an alkylamide group having 8 to 18 carbon atoms, and R ⁵ has 2 carbon atoms. to 3 alkylene group, m 0-6 as the mean, M ² is an alkali metal, alkaline earth metal, alkyl substitution Anmoniumu, hydroxyalkyl-substituted Anmoniumu, § Honoré keno les amide group or a hydrogen atom. )

Or sulfuric acid salt thereof.

Specific examples of the compound represented by the general formula (3) include natural lauryl alcohol polyoxyethylene (m = 3) sulfate, CI 1 to C15 aliphatic alcohol polyoxyethylene (m = 3). Sulfate ester, C12-C13 aliphatic alcohol polyoxyethylene (m = 3) sulfate ester, C12-C13 aliphatic alcohol sulfate ester, polyoxyethylene coconut oil fatty acid amide ether sulfate ester, natural lauryl alcohol polyoxyethylene ( m = 2) The sulfuric acid ester portion of the sulfuric acid ester may be a sodium salt, potassium salt, or an aranolamine salt that is an ammonium salt. Of these, polyoxyethylene alkyl ether sulfates are preferred, and polyoxyethylene ( _m = 2) sodium lauryl ether sulfate, polyoxyethylene coconut oil fatty acid amide ether sodium sulfate, etc. are preferably used. .

[Iii] (iii) The following general formula (4)

[Chemical 1

(Wherein R ⁶ is an alkyl group having 8 to 18 carbon atoms; or an alkylphenyl group having an alkyl group having 5 to 15 carbon atoms; R ⁷ is an alkylene group having 2 to 3 carbon atoms, M ³ and M ⁴ is independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkenyl group having 2 to 4 carbon atoms, an alkali metal, an alkaline earth metal, an alkyl-substituted ammonium, or a hydroxyalkyl-substituted ammonium. It is. )

Or sulfuric acid salt thereof.

[0018] Specific examples of the compound represented by the general formula (4) include N coconut oil fatty acid N—methyl taurine sodium, N coconut oil fatty acid—N methyl taurine magnesium, C 1; Examples include sodium taurine, sodium C12-C13 fatty acid methyl taurate, sodium C12-C13 fatty acid methyl taurate, and the like.

[Iv] (iv) The following general formula (5)

R ⁸ — (R ⁹ 〇) One CH COOM ⁵ (5)

2

(Wherein R ⁸ is an alkyl group having 8 to 18 carbon atoms; an alkyl group having 5 to 18 carbon atoms; an alkylphenyl group having 15 alkyl groups; or an alkylamide group having 8 to 18 carbon atoms; and R ⁹ has 2 carbon atoms. An alkylene group of ˜3, n is an average value of 0 to 9, M ⁵ is an alkali metal, an alkaline earth metal, an alkyl-substituted ammonium, a hydroxyalkyl-substituted ammonium, or a hydrogen atom. Acid or salt thereof.

Specific examples of the compound represented by the general formula (5) include natural lauryl alcohol polyoxyethylene (n = 3) carboxylic acid ester, C 11 to C 15 aliphatic alcohol polyoxyethylene ( _n = 3) Carboxylic acid ester, C12-C13 aliphatic alcohol polyoxyethylene (n = 3) carboxylic acid ester, C12-C13 aliphatic alcohol carboxylic acid ester, polyoxyethylene coconut oil fatty acid amide ether carboxylic acid Examples thereof include those in which the carboxylic acid ester portion of the ester is a carboxylic acid sodium salt, potassium salt, or alanol alcohol salt, or ammonium salt. Among these, polyoxyethylene ( _η = 4 · 5) sodium lauryl ether carboxylate, polyoxyethylene (η = 3) sodium coconut oil fatty acid ether carboxylate, polyoxyethylene (η = 2) sodium lauryl ether carboxylate, etc. Are preferably used.

[0021] (V) The following general formula (6)

[Chemical 2]

M ⁶ OOC-CH ₂ CH ₂ -CH-COOM (6)

1 ⁰ -CN

O II HI (Wherein R ^1Q is a non-aromatic hydrocarbon group having 9 to 17 carbon atoms, M ⁶ and M ⁷ are independently ammonium, alkanolamine, lower (1 to 4 carbon) alkylamine, basic amino acid, Al force Li metal, alkaline earth metal, or hydrogen atom.)

N-acylglutamic acid represented by

[0022] Specific examples of the compound represented by the general formula (6) or a derivative thereof include, for example, N-lauroylglutamic acid, myristoinoregrenoamic acid, N-palmitoylglutamic acid, N-cinoleglutamic acid, and The mixture with these N-acylglutamic acids, and the monoethanolamine salt, sodium salt, potassium salt, etc. of these N-acylglutamic acids can be mentioned. These can be used as an optically active substance or a racemate.

[Vi] (vi) the following general formula (7)

[Chemical 3

(In the formula, R ^U is a hydrogen atom, or a linear or branched alkyl group having 1 to 4 carbon atoms, R ¹² is a non-aromatic hydrocarbon group having 9 to 17 carbon atoms, and M ⁸ is Ammonium, alminolamine, lower alkylamine, basic amino acid, alkali metal, alkaline earth metal, or hydrogen atom, and p is 1 or 2.)

N-acyl-N-alkylamino acids or salts thereof represented by:

[0024] Specific examples of the compound represented by the general formula (7) include, for example, N Lauroileux N ethyl glycine, N Lauroyl mono N isopropyl glycine, N Lauroyl sarcosine, N-myristoyl sarcosine, N-palmitoyl monkey Kosin, N-Lauroinole N Methinole / 3-Alanine, N-Laurourenore N Ethenolay / 3-Alanine, N-Myristoinole β-Alanine, Ν Palmitoylu β-Alanine and mixtures thereof, and their monoethanolamine salts, diethanolamine salts, tri Examples include ethanolamine salt, sodium salt, potassium salt, and magnesium salt.

[Vii] The following general formula (8)

R ¹³ — COOM ⁹ (8)

(In the formula, R ¹³ is a linear hydrocarbon group having 9 to 17 carbon atoms; M ⁹ is an alkali metal or alkaline earth gold. It is a genus or a hydrogen atom. )

Or a salt thereof.

[0026] Specific examples of the compound represented by the general formula (8) include saturated linear fatty acids such as lauric acid, myristic acid, and palmitic acid, and saturated branched fatty acids such as 2-ethylhexanoic acid and isostearic acid. , Oleic acid, linoleic acid and other unsaturated fatty acids, coconut oil, palm oil, palm kernel oil, olive oil, safflower oil, etc. Animal oils and the like, and alkali metal salts such as sodium and potassium, and alkaline earth metal salts.

[0027] As the anionic surfactant, the above (i) to (vii) can be used singly or in appropriate combination of two or more, among which (i) to (vi) are More preferred is (i), (ii), (v) or (vi), more preferred is (i) or (ii), and particularly preferred is (ii).

[0028] The total amount of component (A) is not particularly limited! /, But 2 to 30% by mass is more preferable with respect to the total amount of the shampoo composition, more preferably 3 to 25% by mass, and even more preferably 5 ~ 20% by weight. Particularly good foaming properties can be obtained within this range.

[0029] (B) The polyglycerol fatty acid ester having an HLB of 12 or more is not particularly limited, and can be used alone or in combination of two or more. Specifically, for example, decaglyceryl monolaurate (HLB15.5), decaglyceryl monooleate (HLB12.0-15.0), decaglyceryl monostearate (HLB15.0), decaglyceryl monoisostearate (HLB14. 9), pentaglyceryl monolaurate (HLB15.6) and the like. Among these, decaglyceryl monolaurate, decaglyceryl monooleate, and pentaglyceryl monolaurate (HLB15.6) are preferable. In addition, those having further increased hydrophilicity due to the polyoxyethylene chain do not have a significant effect of improving the texture of the foam, and therefore those having no polyoxyethylene chain are preferred. If the HLB is less than 12, the interaction between the surfactants will be lost, the foam's creaminess, ease of rinsing, and rinsing feel will be satisfied at the same time. A shampoo composition cannot be obtained. The upper limit of HLB is not particularly limited, but is preferably 22 or less. Polyglycerol fatty acid esters of HLB 12 to 16 are preferred. The HLB here is for Griffin. The calculated value by the method is shown.

[0030] The blending amount of the component (B) is not particularly limited, but is preferably in the range of 0.;! To 10% by mass, more preferably 1 to 7% by mass with respect to the total amount of the shampoo composition. Within this range, it is possible to obtain a greater effect of improving the foam's consistency.

[0031] The (C) polyoxyethylene hydrogenated castor oil is not particularly limited, and can be used singly or in appropriate combination of two or more. Further, as polyoxyethylene hydrogenated castor oil, those having an HLB of less than 15, that is, those having an average number of moles of the added polyoxyethylene chain of 5 to 100, more preferably 10 to 60, more preferably Preferably 20 to 60, particularly preferably 20 to 40. Polyoxyethylene may be abbreviated as POE.

[0032] The blending amount of the component (C) is preferably 0.03 to 10% by mass, more preferably 0.0; to 5% by mass, and still more preferably 0.5 to the total amount of the shampoo composition. ~ 4% by weight. In this range, the ability S to obtain better discharge from the container at low temperature, ease of rinsing, and smoothness of the hair after drying.

[0033] The cationic polymer compound (D) is not particularly limited, and can be used singly or in appropriate combination of two or more. As the cationic polymer compound, a polymer compound used in a normal detergent composition or the like is preferably used. Specifically, cationized cellulose, cationized cellulose derivatives, cationized starch, cationized guar gum, Cationized guar gum derivatives, homopolymers of diallyl quaternary ammonium salts, copolymers of dialkyl diallyl ammonium salts and acrylamide, quaternized polybutylpyrrolidone derivatives, polydaricol polyamine condensates, buriumidazo Copolymers of triumtrichloride and bispyrrolidone, copolymers of hydroxyethylcellulose and dimethyldiarylammonium chloride, copolymers of bispyrrolidone and quaternized dimethylaminoethyl methacrylate, poly Bulpyrrolidone and alkylamino acrylate Copolymer, copolymer of polyvinyl pyrrolidone, alkylamino acrylate and bull force prolatatum, copolymer of bulur pyrrolidone and methacrylamidopropyl trimethylammonium chloride, methacryloylethyltrimethylammonium chloride and N — Copolymer with (2-hydroxyethyl) acrylamide, alkylacrylamide, acrylate and alkylaminoalkylacrylamide Copolymer of polyethylene glycol methacrylate and copolymer of adipic acid and dimethylaminohydroxypropylethylenetriamine (Cartaretin manufactured by Sandos, USA), JP 53-139734, JP 60 — Cationic polymers and the like described in JP 36407. For example, if the copolymer is a copolymer of buriumidazolium trichloride and bulupyrrolidone, it may be referred to as buryumidazolium trichloride / bulupyrrolidone copolymer. As cationized cellulose, a cationic functional group (for example, 0- [2-hydroxy-3- (trimethylammonio) propinole]) is added to cellulose, such as Leoguard series (manufactured by Lion Corporation), etc. Are preferably used. The cationized guar gum is a product obtained by adding a cationic functional group (for example, O- [2-hydroxy-3- (trimethylammonio) propyl]) to guar gum, and the Labor gum series (Dainippon Sumitomo Pharma Co., Ltd.), JAGUAR Series (made by Rhodia Nikka Co., Ltd.) Further, as a copolymer of dialkyl diallyl ammonium salt and acrylamide, Lipoflow series (manufactured by Lion Corporation), Marquat series (manufactured by Ondeco Narco Japan Co., Ltd.) and the like are preferably used. Among these, a copolymer of dialkyl diallyl ammonium salt and acrylamide, cationized cellulose, and cationized guagam are particularly preferable.

[0034] The weight average molecular weight of the cationic polymer compound is usually 20,000 to 50 million, preferably 30,000 to 10 million. The weight average molecular weight is a value measured by the GPC pullulan conversion method.

[0035] The blending amount of the component (D) is preferably 0.0;! To 3 mass%, more preferably 0.05 to; mass%, with respect to the total amount of the shampoo composition. When the blending amount is 0.01% by mass or more, the creamy uniformity of the foam is obtained, and when it is 3% by mass or less, the rinsing is easier and the problem of stickiness after finishing occurs. There is no fear.

[0036] Further, the shampoo composition of the present invention contains (E) 1-hydroxy 2-pyridones represented by the following general formula (1), so that the smoothness of the hair after drying is further increased. Be good

Yes

[0037] [Chemical 4]

Wherein R ¹ is a hydrogen atom; !! an alkyl group having 17 carbon atoms, 2 to; an alkenyl group having 17 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms A cycloalkyl group having 7 to 9 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms and an alkyl group having 1 to 4 carbon atoms (provided that An alkyl group may have some of its hydrogen atoms replaced by !! to an alkyl group having 4 carbon atoms), 6 to; an aryl group having 14 carbon atoms, an aryl group having 6 ~; Having 14 carbon atoms and an alkyl group;! ~~ aralkyl group having 4 carbon atoms, aryl group having 6 ~; having 14 carbon atoms and alkenyl group Strength ¾ ~ 4 An aryl group having 6 carbon atoms, an aryl group of 6 An aryloxy alkyl group or an aryl mercaptoalkyl group, a benzhydryl group, or an alkyl group having 1 to 4 carbon atoms, each having 14 carbon atoms and an alkyl group having 1 to 4 carbon atoms. A sulfonylalkyl group, a furyl group, or an alkenyl group represents a furylalkenyl group having 2 to 4 carbon atoms, provided that the above-mentioned aryl group has some of its hydrogen atoms; An alkyl group having carbon atoms of, !! to 4 may be substituted by an alkoxy group having 4 carbon atoms, a nitro group, a cyano group or a halogen atom R ² is a hydrogen atom; An alkyl group having 2 carbon atoms, an alkenyl group having 2 to 4 carbon atoms, an alkynyl group having 2 to 4 carbon atoms, a halogen atom, a phenyl group, or a benzyl group. ⁺ Represents a hydrogen ion, an organic base, an alkali metal ion, an ammonium ion, or a divalent to tetravalent cation.

Specific examples of the compound represented by the general formula (1) include the following compounds and salts thereof. That is, 1-hydroxy-2-pyridone, 1-hydroxy-1-4-methyl-2-pyridone, 1-hydroxy-1-6-methyl-2-pyridone, 1-hydroxy-4,6-dimethyl 1-hydroxy-4-methyl-6 cyclohexyl — 2-pyridone, 1-hydroxy-1-4-methylenoyl 6- (methyl-cyclo) (Hexyl) 2-pyridone, 1-hydroxy-4-methyl-6- (2 bicyclo [2, 2, 1] heptyl) -2 pyridone and other 6-cyclohexanes; 1-hydroxy mono 4-methyl 6- (4- Methyl monophenyl) 1-2 pyridone, 1-hydroxy 4-methyl-6- [1 (4-12 tropenoxy) -methyl] 2 pyridone, 1-hydroxy-4-methyl 6- (4 cyanphenoxymethyl) 2 -pyridone, 1-hydroxy monomethyl 4 6- (phenylsulfonylmethyl) 2-pyridone, 1-hydroxy tetramethyl 6- (4-bromo monobenzyl) 2-pyridone, etc. Alkenyl-based, 1-hydroxy-4-methyl-6- (2, 4, 4-trimethylpentyl) 2 (IH) - In the formula, such as pyridone monoethanolamine salt (1), R ¹ is; have a ~ 17 carbon atoms! And those in which R ² is an alkyl group having 1 to 4 carbon atoms, and these can be used singly or in appropriate combination of two or more. The 1-hydroxy-2-pyridones represented by the above general formula (1) are not limited to the above specific examples as long as they are represented by the above general formula (1).

[0039] The 1-hydroxy-2 pyridones represented by the general formula (1) can also be used as salts with various organic or organic bases. For example, examples of the organic base include ethanolamine, diethanolamine, Nethylethanolamine, triethanolamine, jetylaminoethanol, low molecular alkanolamines such as 2-amino-2-methyl-propanediol; ethylenediamine, Non-volatile bases such as xamethylenediamine, cyclohexylamine, benzenolamine, N-methylbiperazine; quaternary ammonium hydroxides such as trimethylbenzyl hydroxide; guanidine and its derivatives, and alkylation products thereof Inorganic salts include alkali metal salts such as sodium and potassium; alkaline earth metal salts such as ammonium salt, magnesium and calcium; salts with divalent to tetravalent cations such as zinc, aluminum and zirconium, Non-volatile organic salt among the above salts That is, inorganic salts such as low-molecular alkanolamine, ethylenediamine, and alkali metal salts are preferred.

[0040] The 1-hydroxy-2 pyridones represented by the above general formula (1) include 1-hydroxy- 4 Methyl 6 cyclohexyl 2 Pyridone, 1-Hydroxy mono 4 Methyl 6— (Methylanol cyclohexyl) 2 Pyridone, 1-Hydroxy mono 4 Methyl 6— (2 Bicyclo [2, 2, 1] heptyl) -2 — 6-cyclohexane, such as pyridone, 1-hydroxy-4-methyl-6- (2,4,4-trimethylpentyl) 1-2 (1H) -pyridone monoethanolamine, etc. In general formula (1), R ! ^1; ~ 17 alkyl groups having a carbon atom, R ² particularly is an alkyl group preferably tool having 1-4 carbon atom, 1-hydroxy-4-methyl - 6 - (2, 4 , 4 Trimethylpentyl) 1-2 (1Η) -pyridone monoethanolamine salt is preferred.

[0041] The blending amount of the component (E) is not particularly limited, but from the viewpoint of improving the finished feel, 0.00;! To 2% by mass is preferable to the total amount of the shampoo composition, more preferably 0.00. 05 ~ ;! Mass%. If the amount is too small, (E) is the "become a risk to the addition effect of the component can be obtained and the storage stability at too large for example dissolution is insufficient low temperature some cases force ^s decreases.

[0042] The shampoo composition of the present invention includes, in addition to the essential component, water, a cationic surfactant, an amphoteric surfactant, a noionic surfactant, etc. within the range not impairing the effects of the present invention (A). Surfactants other than ingredients, oils, silicone compounds, alcohols, humectants, thickeners, preservatives, antioxidants, chelating agents, UV absorbers / scattering agents, plant extracts, vitamins, amino acids, pH Add S, adjusters, emulsions (pearling agents), inorganic salts, anti-inflammatory agents such as dipotassium glycyrrhizinate, protein derivatives, animal extracts and pigments as needed.

[0043] Examples of the cationic surfactant include alkyl trimethyl ammonium salts, dialkyl dimethyl ammonium salts, alkyl ammonium salts, benzalkonium salts, benzethonium salts, pyridinium salts, imidazolinium salts, and the like. Examples of counter ions (anions) of these cationic surfactants include halogen ions.

[0044] Examples of amphoteric surfactants include alkylcarboxybetaines, alkylsulfobetaines, alkylhydroxysulfobetaines, alkylamidobetaines, alkylamidoalkylbetaines, imidazolium betaines, and the like.

[0045] Nonionic surfactants include polyoxyethylene alkyl ether, polyoxy Ethylene polyoxypropylene alkyl ether, polyoxyethylene alkyl phenol ether, fatty acid polyglycerin ester less than HLB 12, fatty acid sucrose ester, polyoxyethylene fatty acid alcohol amide, polyoxyethylene fatty acid methyl dalcoside, fatty acid alcohol amide, polyethylene Examples include glycol fatty acid esters, alkylamine oxides, and amidoamine oxides.

[0046] As oils, castor oil, olive oil, cacao oil, hydrogenated palm oil, coconut oil, coconut oil, kikou sesame, jojoba oil, grape seed oil, apogado oil and the like, and their ester compounds, mink oil , Animal fats such as egg yolk oil, beeswax, whale wax, lanolin, hydrogenated lanolin, carnauba wax, candelillaro and other waxes, liquid paraffin, squalane, microtalister wax, ceresin wax, paraffin wax, petrolatum and other hydrocarbons Natural and synthetic fatty acids such as lauric acid, myristic acid, stearic acid, oleic acid, isostearic acid, behenic acid, glycerol tree 2-ethylhexylate, 2-ethylhexyl stearate, Butyl stearate, isopropyl myristate, isopropyl palmitate, Examples thereof include (B) component such as otatildodecyl myristate, otatildodecyl oleate, and cholesterol oleate, and esters other than (C) component.

[0047] Examples of the silicone compound include dimethylpolysiloxane (including highly polymerized dimethylsilicone and silicone rubber), methylphenylpolysiloxane, cation-modified silicone, polyether-modified silicone, amino-modified silicone, betaine-modified silicone, and alcohol-modified. Silicone, fluorine-modified silicone, epoxy-modified silicone, mercapto-modified silicone, canolepoxy-modified raw silicone, fatty S-acid-modified raw silicone, silicone graft polymer, cyclic silicone, alkyl-modified silicone, trimethylsilyl-terminated dimethylpolysiloxane, Examples thereof include silanol group-terminated dimethylpolysiloxane.

[0048] Examples of alcohols include natural and synthetic alcohols such as lower alcohols such as ethanol and isopropanol, cetyl anoleno cornore, oleino eno eno eno ole, stearino eno eno ole no ole, hexino decano oleore, octyl dodecanol, lauryl alcohol and the like. Examples include higher alcohols.

[0049] As the humectant, urea, 1,3-butanediol, isoprene glycol, 1,2-pentanediol, hexylene glycol, ethylene glycol, propylene glycol, di Ethylene glycol, dipropylene glycol, diethylene glycol monomonorequinolene tenole, polyethylene glycol (200, 300, 400, 600, 1000, 1500), polypropylene glycol, polyethylene glycol, polypropylene glycol, glycerin, diglycerin , Triglycerin, polyglycerin, sorbitol and the like.

[0050] Examples of thickeners include sodium alginate, xanthan gum, aluminum oxalate, Malmo mouth seed extract, tragacanth gum, starch and other natural polymer compounds, methylcellulose, hydroxychetinoresenorelose, hydroxypropinoresenorelose, (D) components such as canolepoxymethinoresenolose, semi-synthetic polymers such as soluble starch, carboxybule polymer, polybulal alcohol, polybulurpyrrolidone, polyacrylic acid, methacryloylethyline 'methacrylic acid ester copolymer Other synthetic polymer compounds.

[0051] Antiseptics include benzoic acid, benzoate, sorbate, dehydroacetate, parabenzoate, 2, 4, 4 'trichloro-2'-hydroxydiphenyl ether, 3, 4, A' Trichlorocarbanilide, benzalkonium chloride, hinokitiol, resorcin, methylchloro isothiazolinone 'methylisothiazolinone solution (trade name: Caisson CG; manufactured by Rohm and Haas' Japan), pentanediol, phenoloxyethanol, ethanol Etc.

[0052] Examples of the antioxidant include α-tocopherol, tocotrienol, dibutylhydroxytonolene, butylhydroxyanisole, and ascorbic acid.

[0053] Examples of the chelating agent include disodium edetate, ethanehydroxydiphosphonic acid, ethylenediamine tetraacetate, hexametaphosphate, darconic acid and the like.

[0054] Examples of the UV absorbing / scattering agent include 2-hydroxy-4-methoxybenzophenone, tert-butylmethoxydibenzoylmethane, octyldimethylparaaminobenzoate, ethylhexylparamethoxycinnamate, titanium oxide, Examples include kaolin and talc.

[0055] As plant extracts, there are Azajak extract, Apogado extract, Amatya extract, Altea root extract, Anoleni force extract, Anoleni force flower extract, Aloe vera extract, Kidachi aloe extract, Tucon extract, Echinashi leaf extract, Ogon extract, Aubata extract, Kihada bark Kiss, Hypericum extract, Cyprus hypericum extract, Orange extract, Orange fruit kiss, Canopus extract, Power walnut extract, Cucumber extract, Cucumber fruit extract, Cuticle Pear, Kumazasa extract, Clara extract, Gentian extract, Gentian extract, Burdock extract, Burdock root extract, Comfrey extract, Salamander extract, Salamander extract, Perilla extract, Peonies extract, Peonies root extract, Cyprus root extract, Crab extract, Crab Saw extract, Crab extract, Sage extract, Citrus extract, Soybean extract, Taisou extract, Jujube fruit extract, Thyme extract, Winored thyme extract, Chii di extract, Capsicum extract, Toki extract , Tokinkin extract, Tokinsen extract, Tonin extract, Peach seed extract, Dokudami extract, Tormentilla extract, Panax ginseng extract, Parsley extract, Parie Talia extract, leopard extract, birch leaf extract, butcher bloom extract, grape leaf extract, safflower extract, capsicum extract, button extract, maronier extract, peach leaf extract, jagnole magic extract, mugwort extract, Examples include mugwort leaf extract, lavender extract and rooibos extract.

As vitamins, vitamin A, vitamin B group, vitamin C, vitamin D, vitamin E, vitamins? Vitamins, vitamin P, vitamin U, carnitine, ferulic acid, γ-oryzanol, a-lipoic acid, orotic acid and derivatives thereof.

[0056] Examples of amino acids include glycine, alanine, norine, leucine, isoleucine, phenylalanine, tryptophan, cystine, cysteine, methionine, proline, hydroxyproline, aspartic acid, glutamic acid, arginine, histidine, lysine, pyrrolidonecarboxylic acid Examples thereof include acids and derivatives thereof.

[0057] Examples of pH adjusters include sodium hydroxide, potassium hydroxide, succinic acid, succinic acid, triethanolamine, aqueous ammonia, triisopropanolamine, phosphoric acid, glycolic acid, and the like. The pH of the shampoo composition Is preferably adjusted to 3.0 to 7.5, preferably ρΗ4.0 to 6.5.

[0058] Examples of the emulsion include ethylene glycol diisostearate, fish scales, mica pieces, and the like. Examples of inorganic salts include sodium chloride, anhydrous sodium sulfate, magnesium sulfate and the like.

[0059] Further, a fragrance and a fragrance composition used in the shampoo composition of the present invention are disclosed in JP 2003-300811 [002; ] To [0035] perfume ingredients, etc. Examples of the perfume solvent are listed. The amount of the perfume solvent used is 0.;! To 99% by mass in the perfume composition, but preferably !! to 50% by mass.

[0060] Examples of the fragrance stabilizer include dibutylhydroxytoluene, butylhydroxyanisole, vitamin E and its derivatives, catechin compounds, flavonoid compounds, polyphenol compounds and the like. From 0001 to 10% by mass, preferably from 0.00;! To 5% by mass. Among these, a preferred stabilizer is dibutylhydroxytoluene. The fragrance composition is a mixture comprising the fragrance component, solvent, fragrance stabilizer and the like. In the shampoo composition of the present invention, the strength, the fragrance composition, and the strength of the shampoo composition are mixed in an amount of 0.005 to 40% by mass, preferably 0.01 to 10% by mass.

[0061] The shampoo composition of the present invention is produced by mixing and stirring the above essential components, optional components, and water (the remainder is blended so that the total amount of the shampoo composition is 100% by mass) according to a usual method. The In this case, the component (A) is preferably used as an aqueous solution of a cationic surfactant having a concentration of 20 to 70% by mass previously diluted with purified water or ethanol. In addition, it is preferable that the component (D) is also dispersed and swelled in purified water in advance for easy production. Components (B), (C), (E) and other components may be added as they are, or may be added as an aqueous solution. Oil-soluble components may be dissolved in other oil components. Or you can add it dispersedly.

[0062] Examples of the container of the shampoo composition of the present invention include a dispenser container and a bottle container by mechanical or differential pressure. The bottle material is made of polyethylene, polypropylene, polyethylene terephthalate, polystyrene, polychlorinated butyl, ethylene monobutyl alcohol resin, acrylonitrile 'styrene resin, ABS resin, polyamide, etc. They can be used in combination.

Example

[0063] Hereinafter, the present invention will be specifically described with reference to examples and comparative examples, but the present invention is not limited to the following examples. In the following examples, unless otherwise specified, “%” in the composition indicates mass%, and the amount of each component in the table is an amount converted into a pure component.

[0064] [Examples;! To 12, Comparative examples;! To 4] Shampoo compositions having the compositions shown in Tables! To 3 were prepared and evaluated as follows. The results are also shown in the table.

[0065] (1) Foam creaminess, ease of rinsing, smoothness of hair after drying

As standard samples, sodium polyoxyethylene lauryl ether sulfate (polyoxyethylene average added moles: 2 mol): 15%, polyoxyethylene lauric acid monoethanolamide: 3%, anhydrous sodium sulfate: 1%, cationized cellulose: 0 5%, succinic acid monohydrate: appropriate amount (ρΗ 6.0.0 adjusted amount) and purified water: shampoo composition consisting of the balance was prepared

Yes

The hair is divided into left and right, 3 g of the above standard sample is applied to one side, and 3 g of the test sample is applied to the other side to wash the hair, and `` foam cleanliness '', `` ease of rinsing '', `` smooth hair after drying '' Ten subjects evaluated this item. A result is shown on the following reference | standard.

◎: 8 to 10 subjects who answered that it was better to compare with the standard sample

◯: 5 to 7 subjects who answered that they should be compared to the standard sample

X: 0 to 4 subjects who answered that they should be compared to the standard sample

(2) Emission from containers at low temperatures

Half of the test sample (filled with lOOmU and stored at 5 ° C in a polyethylene container of 200 mL capacity (discharge port diameter 4.5 mm). After storage, tilt the container upright about 120 ° C and push the container body with one hand to test. The time taken for 20 g of the sample to be discharged from the container discharge loca was also measured by the declaration of 10 subjects as follows.

◎: Power that was discharged within 20 seconds ~; 10 people

〇: Power that was discharged within 20 seconds ¾ ~ 7 people

X: Power that was discharged within 20 seconds ~ 3 people

[0066] [Table 1]

Table 2]

Table 3] Comparative example

Composition (%)

1 2 3 4

ΡΟΕ Sodium alkyl ether sulfate 1) 15 15 15 Sodium α-olefin sulfonate 2)

(A)

Sodium alkyl sulfate 3)

Acylmethyl--alanine salt 4)

Decaglycerinole monolaurate HLB 15.5 5) 3 3 3

(B) Decaglycerinole monooleate HLB 14.9 6)

Decaglycerinole monoisostearate HLB 14.9 7)

Glycerinole laurate HLB5.3 9) 3

Hardened castor oil 10) 3 3 3

(O ΡΟΕ Hardened castor oil 1 1)

Hardened castor oil 12)

Cationized cellulose 13) 0.5 0.5 0.5 Cationized guar gum 14)

Dimethyl diallyl ammonium chloride /

(D) Acrylamide copolymer 15)

Methacryloylethyl trimethylammonium chloride

Ν-(2-Hydroxyethyl) acrylamide copolymer liquid

16)

1-hydroxy-4-methyl-6- (2,4,4-trimethyl

(E) Pentinole)-2 (1 Η)-Pyridone

Monoethanolamine salt 17)

Amidopropyl betaine laurate 18) 5 5 5 5 Alkyldimethylamine oxide 19) 1 1 1 1

ΡΟΕ Alkyl ether 20) 0.5 0.5 0.5 0.5

ΡΟΕ Lauric acid monoethanolamide 21) 3 3 3 3 Silicone Emerald / Resistance 22) 1 1 1 1 Silicone Emerald / Resistance 23) 1 1 1 1 Modified silicone 24) 0.5 0.5 0.5 0.5 Sodium sulfate 0.3 0.3 0.3 0.3 Sodium chloride 0.2 0.2 0.2 0.2 Other Sodium benzoate 0.7 0.7 0.7 0.7

Dibutylhydroxytoluene 0.01 0.01 0.01 0.01 Ethanol 0.5 0.5 0.5 0.5 Propylene glycolate 0.2 0.2 0.2 0.2 Hexylene glycolate 0.3 0.3 0.3 0.3 Ethylene glycol distearate 1 1 1 1 Fragrance A 0.5 0.5 0.5 0.5 Refined residue Remainder Remainder Remainder

100.0

Bubble creamy X 0 0 X

Ease of rinsing X 〇 X X Smoothness of hair after drying X X X 〇 Container force at low temperature, evacuation ability 〇 X 〇 X

[0069] From the above results, it can be seen that the shampoo compositions of the present invention all have a foamy, smooth hair after rinsing and immediately drying, and excellent discharge from a container at a low temperature.

[0070] Each of the following shampoo compositions of Examples 13 to 21 was prepared, and the tally properties, ease of rinsing, smoothness of the hair after drying, and discharge at low temperature were evaluated. . Good results were obtained for any of these compositions.

[0071] [Example 13]

[Table 4

Composition Pure% (The same applies to the following examples)

P OE alkyl ether sodium sulfate 1) 1 5

α-Olephine sodium sulfonate 2) 1

^^ / sodium decanoate 2 5) 0.5 alkyl propyl betaine laurate 1 8) 0.5 alkyldimethylamine 1 9) 1

Monolaurate de-glyceryl 4

Hardened castor oil 1 0) 4

ΡΟΕ Alkyl ether 2 0) 0.5

ΡΟΕLauric acid monoethanolamide 2 1) 2

Cationized cellulose 1 3) 0.3 Dimethyldiallyl ammonium chloride ζ allylamide copolymer 1 5) 0.1 Silicone emulsion 2 2) 0.5 Sodium sulfate 1

Sodium benzoate 0.5 Disodium ethylene glycolate 1

Yellow 2 0 3 0.0 Red 1 0 3 0. 0 Fragrance Β 0.5 Residual water balance

Α a 4T 1 0 0. 0

[Example 14]

[Table 5]

Composition%

P OE Sodium alkyl ether sulfate 1) 5

Sodium POE alkyl ether sulfate 2 6) 1 0 Sodium acylyl taurine 2 7) 2

Sodium POE alkylsulfosuccinate 2 8) 3 Pear oil fatty acid amine propyl betaine 2 9) 4 Alkyldimethylamine oxide 1 9) 0. 2

POE hydrogenated castor oil 1 1) 3

POE lauric acid monoethanolamide 2 1) 2 Monooleic acid glyceryl 6) 1 Cationic cellulose 3 0) 0.1 Cationic guar gum 1 4) 0.2 Methacryloylethyl trimethylammonium chloride

N— (2 hydroxyethyl) acrylic amide copolymer f Overnight 1 6) 0. 1 Silicone emulsion 2 3) 0. 3 Sodium sulfate 1 Sodium benzoate ◦. 2 Dibutylhydroxytoluene 0. 0 1 Green 3 No. 0 0 00 4 Fragrance C 0.4 Purified water balance

Total 1 0 0. 0 [Example 15]

[Table 6]

Composition%

Sodium POE alkyl ether sulfate 3 1) 9 Sodium alkyl sulfate 3) 6 Acylmethyl--alanine salt 4) 1 Sodium ether carboxylate 3 2) 1 Alkyl betaine 3 3) 1 Alkyl carboxyethyl doloxetyl imidazolinium

Betaine 3 4) 1 1-Hydroxy 4-Methyl 6— (2, 4, 4 Trimethylpentyl)

-2 (1Η) pyridone monoethanolamine salt 1 7) 0.5

Hardened castor oil 1 0) 0. 0

ΡΟΕ Alkyl ether 2 0) 1

Methyldarcoside ΡΟΕdiolate 3 5) 0.5 Monoglyceryl monoisostearate 7) 7 Cationized cellulose 3 6) 1 Dimethyldiarylammonium chloride, 'acrylamid copolymer 1 5) 0. 2 Sodium chloride 0.5 Sodium benzoate 0.3 Propylene glycol 0.1 Ethylene glycol distearate 0.5 Perfume D 0 3 Purified water balance Total 1 0 0. 0

[Example 16]

[Table 7]

Composition%

ΡΟΕ Sodium alkyl ether sulfate 1) 3 Amidopropyl betaine laurate 1 8) 1 3 Alkyl betaine 3 3) 2 Alkyldimethylamine oxide 1 9) 2 Deglyceryl monolaurate 5) 1 0

Hardened castor oil 1 0) 5

ΡΟΕLauric acid monoethanolamide 2 1) 0.3 Cationic cellulose 1 3) 0.1 Cationic guar gum 3 7) 0.5 Dimethyldiallylammonium chloride / acrylamide copolymer 1 5) 0 1 Modified silicone 2 4) 0.2 Sodium sulfate 0.5 0.5 Sodium benzoate 0.8 Hexylene glycol 0.1 Fragrance Ε 0.5 Purified water Total 1 0 0. 0 [0075] [Example 17]

[Table 8]

Composition%

P OE alkyl ether sodium sulfate 1) 4 α-Sodium olefin sulfonate 2) 5 Acylmethyl-alanin salt 4) 1 0 Sodium alkane sulfonate 2 5) 0.5 Ether ether sodium sulfonate 3 2) 2 Monolauric acid Decaglyceryl 5) 1

Hardened castor oil 1 0) 1 0

ΡΟΕMonolauramide of lauric acid 2 1) 4 Methacryloylethyl trimethylammonium chloride ·

Ν— (2 Hydroxyethyl) acrylic amide copolymer f Overnight 1 6) 0. 0 5 Silicone emulsion 2 2) 1 Modified silicone 2 4) 1

Purified water balance Total 1 0 0.◦

[Example 18]

[Table 9

Composition%

P OE alkyl ether sodium sulfate 3 1) 5 coconut oil fatty acid aminopropyl betaine 2 9) 10 1-hydroxy 4-methyl-6- (2, 4, 4 trimethylpentyl)

-2 (1 H) —pyridone monoethanolamine salt 1 7) 0.3 Alkyldimethylamine oxide 1 9) 7

POE hydrogenated castor oil 1 1) 0.1 Decaglyceryl monoisostearate 7) 0.5 Cationized cellulose 3 0) 0.5 Dimethyldiarylammonium chloride Z acrylic amide copolymer 1 5) 0. 3 Sodium benzoate 0.3 Ethanol 0.1 Ethylene glycol distearate 0.7 Fragrance A 0.4 Purified water balance Total 1 0 0. 0

[0077] [Example 19]

[Table 10] composition

Sodium POE alkyl ether sulfate 26) 1 5 Sodium acylyl taurine 2 7) 1 Lauric acid amide Dolphin pyruvine 1 8) 3

POE hydrogenated castor oil 1 0) 5

POE Azorequinole Itel '20) 1

POE laurate monoethano-monoreami: K 2 1) 1 monolaurate weak glycerinole 5) 3 cationized cellulose 1 3) 0. 2 dimethyldiallyl ammonium chloride 'acrylamide copolymer 1 5) 0.1 Silicone Emma / Resision 2 3) 0.1 Sodium sulfate 0.2 Sodium benzoate 0.5 Propylene darico / 1 0.5 Ethylene glycolate distearate 1 Fragrance B 0.5 Residual water remaining

α mouth t 1 0 0. 0

[Example 20]

[Table 11]

Composition% α-year-old sodium sulfin sulfonate 2) 1 0 Potassium laurate 2 Potassium myristate 1

ΡΟΕ Hardened castor oil 1 0) 1 Deglyceryl monolaurate 5) 0.5 Dimethyl diallyl ammonium chloride Ζ Acrylate amide copolymer 1 5) 0.1 Potassium glycyrrhizinate 0.1 Propylene glycol 0.5 Styrene Copolymer 1 Fragrance C 0.2 Purified water balance Total 1 0 0. 0

[0079] [Example 21]

[Table 12] composition

P OE Sodium alkyl ether sulfate 3 1) 1 2 Lauric acid salt Dolphin pill betaine 1 8) 3 Alkyl betaine 3 3) 1.5 Alkyldimethylamine, Do- 1 9) 2 Monolauric acid penta Glyceryl 8) 6

POE hydrogenated castor oil 1 0) 4.5

POE Lauric acid monoethanolamide 2 1) 0.5 Cationized cellulose 1 3) 0.2 Cationized guar gum 1 4) 0. 6 Dimethyldiarylmonmonyl chloride: um / atalylamide copolymer 1 5 ) 0.4 Modified silicone 2 3) 0. 3 Sodium sulfate 1 Sodium benzoate 0. 9 Hexylene glycolate 0. 3 Fragrance A 0. 5 Yellow 2 ◦ No. 3 0. 00 1 Red 1 No. 06 0. 0 00 5 Green No. 3 0. 00 1 Purified water balance

Each component used in the above example is shown below.

1) Shin Nippon Rika Co., Ltd. Sinoline SPE— 1250 (C12, 2Ε. Ο. (Oxyethylene))

2) LipoLan LB—440 (C14) manufactured by Lion Corporation

3) Sanno Nore manufactured by Rai Sen Co., Ltd .: LM-1130 (C12, 14, 16)

4) Enadicol L—30ANT (C12, triethananolamine salt) manufactured by Lion Corporation

5) Sunsoft M—12J

6) Taiyo Kagaku Sunsoft Q—17Y

7) Taiyo Kagaku Sunsoft Q—19Y

8) Taiyo Chemical Co., Ltd. Sunsoft A— 12E

9) Sunsoft Co., Ltd. Sunsoft No. 750 HLB5.3

10) Aoki Yushi Co., Ltd. Braunon CW-20 (20E. 0.)

11) Nikkol HCO-60 (60E. 0.) manufactured by Nikko Chemicals Co., Ltd.

12) Emalex HC—100 (100E. 0.) manufactured by Enomoto Emarujion Co., Ltd.

13) Lion Corporation Leo Guard GP (Molecular weight 200,000-500,000) Cationic group: O- [2 Hydroxy-3 (trimethylammonio) propyl] 4) Jaguar EXCEL (Molecular weight 2 million) manufactured by Rhodia Nihon Japan Co., Ltd. Cationic group: O- [2 Hydroxy-3 (trimethylammonio) propyl] 5) Riboflow MN manufactured by Lion Corporation (Molecular weight 5 million)

6) Diasleek C 801 manufactured by Mitsubishi Chemical Corporation

8) Enagicol L—30B, manufactured by Lion Corporation

9) Lion Corporation Alomottas DM12D—W (C)

0) emalex C—20, manufactured by Nippon Emulsion Co., Ltd.

1) Kawaken Fine Chemical Co., Ltd. Amidette 2L

2) One company oil and fat industry Co., Ltd. Silicone emulsion (6)

3) SM8904 manufactured by Toray Dow Cowing. Silicone Co., Ltd.

4) SH3775M manufactured by Toray Dow Cowing, Silicone Co., Ltd.

5) Clariant Japan Co., Ltd. Hostapur SAS 30

6) Shinno Rika Co., Ltd. Sinoline SPE— 1150

7) Nippon Oil & Fats Co., Ltd. Diabon

8) Nippon Shokuhin Co., Ltd. Softanore MES-3

9) Enajicol C 30B manufactured by Lion Corporation

0) Lion Corp. Leo Guard MLP

Cationic group: O— [2 Hydroxy-3 (trimethylammonio) propyl] 1) Ticapol NE1230 (C10 ～; 14, 3E. O.) manufactured by Tika Corporation

2) Energycol EC—A manufactured by Lion Co., Ltd.

3) Genagen B 1566 manufactured by Clariant Japan

4) Energic CNS manufactured by Lion Corporation

5) Gamacamate DOE—120 made by Amacor

6) Lion Corporation Leo Guard MGP

Cationic group: O— [2 Hydroxy-3 (trimethylammonio) propyl] 7) Dainippon Sumitomo Pharma Co., Ltd. Labor gum CG— M8M Cationic group: O- [2-hydroxy-3- (trimethylammonio) propyl] Fragrance A: Fragrance A according to JP-A-2006-63044, Tables 5 to 10

Perfume B: Perfume B described in JP-A-2006-63044, Tables 5 to 10

Perfume C: Perfume C described in JP-A-2006-63044, Tables 5 to 10

Perfume D: Perfume D described in JP-A-2006-63044, Tables 5 to 10

Perfume E: Perfume E described in JP-A-2003-267841 Tables 2 to 16

Yellow No. 203: Quinoline Yellow WS— G (Chuo Synthetic Chemical Co., Ltd.)

Red 106: Red 106 (Made by Kasei Kasei Co., Ltd.)

Green No. 3: Green No. 3 (Made by Kasei Kasei Co., Ltd.)

Claims

The scope of the claims

[1] A shampoo composition comprising (A) an anionic surfactant, (B) a polyglycerol fatty acid ester having an HLB of 12 or more, (C) a polyoxyethylene hydrogenated castor oil, and (D) a cationic polymer compound .

[2] Further, (E) the following general formula (1)

[Chemical 1]

Wherein R ¹ is a hydrogen atom; !! an alkyl group having 17 carbon atoms, 2 to; an alkenyl group having 17 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms A cycloalkyl group having 7 to 9 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms and an alkyl group having 1 to 4 carbon atoms (provided that An alkyl group may have some of its hydrogen atoms replaced by !! to an alkyl group having 4 carbon atoms), 6 to; an aryl group having 14 carbon atoms, an aryl group having 6 ~; Having 14 carbon atoms and an alkyl group;! ~~ an aralkyl group having 4 carbon atoms, an aryl group 6 ~; having 14 carbon atoms and an alkenyl group 2-4 Allyl alkenyl groups having 6 carbon atoms, An aryloxy alkyl group or an aryl mercaptoalkyl group, a benzhydryl group, or an alkyl group having 1 to 4 carbon atoms, each having 14 carbon atoms and an alkyl group having 1 to 4 carbon atoms. A sulfonylalkyl group, a furyl group, or an alkenyl group represents a furylalkenyl group having 2 to 4 carbon atoms, provided that the above-mentioned aryl group has some of its hydrogen atoms; An alkyl group having carbon atoms of, !! to 4 may be substituted by an alkoxy group having 4 carbon atoms, a nitro group, a cyano group or a halogen atom R ² is a hydrogen atom; An alkyl group having 2 carbon atoms, 2 to An alkenyl group having 4 carbon atoms, an alkynyl group having 2 to 4 carbon atoms, a halogen atom, a phenyl group or a benzyl group. X ⁺ represents a hydrogen ion, an organic base, an alkali metal ion, an ammonium ion or a divalent to tetravalent cation. )

The shampoo composition according to claim 1, comprising 1-hydroxy-2-pyridone represented by the formula: