WO2008020568A1 - Gel-type food and process for producing the same - Google Patents

Gel-type food and process for producing the same Download PDF

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Publication number
WO2008020568A1
WO2008020568A1 PCT/JP2007/065699 JP2007065699W WO2008020568A1 WO 2008020568 A1 WO2008020568 A1 WO 2008020568A1 JP 2007065699 W JP2007065699 W JP 2007065699W WO 2008020568 A1 WO2008020568 A1 WO 2008020568A1
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WO
WIPO (PCT)
Prior art keywords
stage
gel
producing
temperature
treatment liquid
Prior art date
Application number
PCT/JP2007/065699
Other languages
French (fr)
Japanese (ja)
Inventor
Hiroto Itou
Noriaki Matsunaga
Shigeru Aizawa
Original Assignee
Meiji Dairies Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Meiji Dairies Corporation filed Critical Meiji Dairies Corporation
Priority to CN200780034660.XA priority Critical patent/CN101516201B/en
Priority to JP2008529856A priority patent/JP5193868B2/en
Publication of WO2008020568A1 publication Critical patent/WO2008020568A1/en
Priority to HK09109139.4A priority patent/HK1131005A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C21/00Whey; Whey preparations
    • A23C21/04Whey; Whey preparations containing non-milk components as source of fats or proteins
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C19/00Cheese; Cheese preparations; Making thereof
    • A23C19/06Treating cheese curd after whey separation; Products obtained thereby
    • A23C19/068Particular types of cheese
    • A23C19/0684Soft uncured Italian cheeses, e.g. Mozarella, Ricotta, Pasta filata cheese; Other similar stretched cheeses
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C19/00Cheese; Cheese preparations; Making thereof
    • A23C19/06Treating cheese curd after whey separation; Products obtained thereby
    • A23C19/068Particular types of cheese
    • A23C19/0686Cheese from whey, e.g. mysost
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C21/00Whey; Whey preparations
    • A23C21/06Mixtures of whey with milk products or milk components

Definitions

  • the present invention relates to a method for producing a gel-like food product such as whey cheese having a smooth mouthfeel and a smooth mouthfeel and having little water separation and good texture and flavor, and a gel-like food product produced thereby.
  • a gel-like food product such as whey cheese having a smooth mouthfeel and a smooth mouthfeel and having little water separation and good texture and flavor
  • Whey is obtained as a by-product during the production of natural cheese and casein.
  • Whey is well known for its high nutritional value.
  • Whey contains whey protein, lactose, minerals, vitamins, and the like.
  • whey protein is especially useful as a raw material for various nutritional compositions because it has a high nutritional value and is highly efficient in protein utilization.
  • Whey protein is denatured when heat-treated at a temperature of 60 ° C or higher, becomes an acid coagulated product when heat-treated in a low pH solution, and becomes a gel product with excellent water retention when heat-treated in the presence of salts.
  • Non-Patent Document 1 Non-Patent Document 1
  • whey cheese typified by ricotta cheese as a food utilizing the heat coagulation property of whey protein.
  • this whey cheese is prepared by adding whole milk, skim milk, cream, etc. to whey obtained as a by-product during the production of normal natural cheese, and preparing a small amount of this whey. After adding acid (such as lactic acid), etc., it is heated to 85-95 ° C in a large-capacity tank (kettle) to form a card (aggregate) (Non-patent document 2, Non-patent document) Reference 3)
  • Patent Document 2 a whey protein cheese having a smooth texture is obtained by subjecting whey protein to limited decomposition, followed by heat treatment and acid treatment.
  • Patent Document 3 a whey protein is added to raw milk and heated and stirred after pH adjustment, whereby a cottage cheese-like fresh cheese curd excellent in water retention, heat resistance, and storage stability can be obtained in a short time. Get in high yield!
  • the heating time becomes longer, and an overheated portion is generated in the processing liquid due to the structural characteristics of the heating method and the heating apparatus, and the heat history varies depending on the portion of the processing liquid.
  • the card was too hard, and the texture and flavor were not consistent for each part, such as inside the container.
  • an overheated portion is generated in the processing liquid.
  • the processing liquid is heated by indirectly heat (such as a jacket) force of the tank to increase the temperature of the processing liquid, It is assumed as a phenomenon that occurs on the side.
  • a heating element, hot water, water vapor, or the like is injected into the processing liquid, an electrode is brought into contact with the processing liquid to energize it, or an electromagnetic wave (microwave) is irradiated to the processing liquid.
  • microwave electromagnetic wave
  • Patent Document 1 JP-A-1-148148
  • Patent Document 2 JP-A-7-264980
  • Patent Document 3 JP-A-9 299025
  • Non-patent literature l New Food Industry, 25 (3), 33 (1983): Ouegawa Osamu
  • Non-patent document 2 CHEESE Chemistry, Physics and Microbiology-Volume2, Major Cheese Groups: Co-authored by Fox, McSweeney, Cogan, Guinee
  • Patent Document 3 Application of ulrtafiltration in the dairy industry: Co-authored by Renner'Abd
  • the present invention has been made in view of the above-mentioned problems of the prior art, and the texture is brittle.
  • the texture is not starchy, the texture is smooth, the mouthfeel is smooth, and the texture is low. It is an object of the present invention to provide a method for producing a gel-like food product such as whey cheese having good flavor and a gel-like food product such as whey cheese produced thereby.
  • the concentration of whey protein, the mixing ratio of whey protein and fat, pH, volume, etc. are appropriately selected in the treatment solution to be heat-treated, so At the same time, we found the knowledge that hygienic gel-like foods with excellent flavor and long-term storage could be obtained.
  • the present invention is as follows.
  • a treatment solution containing whey protein and fat, the concentration of whey protein being 4 to; 12% by weight, and the weight ratio of fat to whey protein being 5 times or less is heated in two stages.
  • the heating temperature is set to 65 to 75 ° C, and the whole treatment liquid is held at 65 to 75 ° C at a substantially uniform temperature.
  • the heating temperature is 90 ° C or lower and exceeds 75 ° C, and the entire treatment liquid is almost uniform at 90 ° C or lower and 75 ° C. Hold at a temperature exceeding A method for producing a gel food characterized by the above.
  • the pH of the treatment liquid is 5 to 9
  • the treatment liquid contains at least one of an emulsifier, a stabilizer and a gelling agent.
  • a method for producing a gel food characterized in that the material of the container is made of plastic according to (6) or (7) above.
  • the gel food is whey cheese
  • the method for producing a gel food is characterized in that
  • the production of gel-like foods such as whey cheese having a texture and a good taste with a smooth texture and a smooth mouthfeel and low water separation is not starchy, with a brittle tissue and brittle texture.
  • the method and the ability to provide gelled foods such as whey cheese produced by this method is not starchy, with a brittle tissue and brittle texture.
  • the inventors of the present application heat-processed a treatment solution containing whey protein under various heating conditions to produce a gel food such as whey cheese, and attached the gel food. Evaluation and analysis of texture, flavor and physical properties.
  • heat treatment is carried out under various heating conditions to produce prototype food products such as whey cheese. Evaluation and analysis of physical properties.
  • the method for producing a gel food according to the present invention comprises whey protein and fat, the concentration of whey protein is 4 to 12% by weight, and the weight ratio of fat to whey protein is 5 times or less.
  • the treatment liquid is heated under two-stage heating conditions to produce a gel food.
  • the heating temperature is set to 65 to 75 ° C, and the whole processing liquid is held at 65 to 75 ° C at a substantially uniform temperature.
  • the heating temperature is 90 ° C or lower and higher than 75 ° C, and the treatment liquid as a whole is almost uniform at 90 ° C or lower and 75 ° C. The temperature is maintained so that the temperature exceeds.
  • the texture is brittle and the texture is not starchy, the mouthfeel is smooth, the mouthfeel is smooth, and the water release is low.
  • Gel-like foods such as whey cheese having good feeling and flavor can be produced.
  • the whole treatment liquid is held at 65 to 75 ° C at a substantially uniform temperature
  • the whole treatment liquid is 90 ° C or less and 75 ° at a substantially uniform temperature.
  • “Hold at a temperature exceeding C” means that the treatment liquid is subjected to heat treatment so that the temperature of the “part of the treatment liquid that is most difficult to rise” also falls within the predetermined temperature range. It means maintaining the whole temperature.
  • the "part of the processing liquid that is most difficult to raise the temperature” means, for example, when the processing liquid is heated by heating indirectly from the outside of the container containing the processing liquid. This means the part of the processing solution where heat is most difficult to transfer, such as the central part inside the container.
  • the "part of the processing liquid that is most difficult to raise the temperature” means, for example, when the processing liquid is heated by heating indirectly from the outside of the container containing the processing liquid. This means the part of the processing solution where heat is most difficult to transfer, such as the central part inside the container.
  • the heating a treatment liquid by injecting a heating element, hot water, water vapor or the like into the treatment liquid and heating the treatment liquid directly, it is far from the heat generation body, hot water, water vapor or the like. Or a position where it is difficult to change temperature due to physical properties such as viscosity and density.
  • the whey protein used in the present invention is contained in cheese whey, acid whey and the like.
  • Acid whey is obtained as a supernatant when casein is produced by adding acid to milk, utilizing the phenomenon that proteins precipitate near the isoelectric point.
  • the whey protein source (material) used in the present invention specifically includes whey, whey powder, whey protein concentrate (WPC) obtained by treating whey with an ultrafiltration membrane, whey, and the like.
  • WPC whey protein concentrate
  • WPI whey protein isolate
  • the concentration (in water concentration) of the whey protein in the treatment solution is preferably 4 to 12% by weight.
  • the concentration of whey protein in the treatment solution is lower than 4% by weight, the strength of the gel obtained by heat treatment becomes too weak. If the concentration of whey protein is higher than 12% by weight, Since the strength becomes too strong, the gel food is not suitable for food as it is.
  • the concentration of the whey protein in the treatment solution is more preferably 5 to 11% by weight, still more preferably 6 to 10% by weight.
  • the fat content in the treatment solution is preferably 5 times or less by weight ratio to whey protein.
  • the treatment liquid contains an appropriate amount of fat in order to make the mouthfeel and texture of the gel-like food smooth, and to obtain a rich feeling in texture and flavor.
  • the fat content in the treatment liquid exceeds 5 times by weight with respect to whey protein, it is not preferable because the food texture and flavor of the gel food may be felt.
  • the fat content in the treatment liquid is more preferably 0.5 to 4 times, and still more preferably! To 3 times, by weight ratio to the whey protein.
  • Specific examples of the fat source (material) include whole milk, whole fat concentrated milk, whole milk powder, condensed milk, cream, butter, fermented butter, buttermilk, buttermilk powder, vegetable And soy-based foods such as animal oils and fats and soy milk.
  • the treatment liquid described above is heat-treated under two-stage heating conditions.
  • This two-stage heating condition is the first stage, where the heating temperature is 65 to 75 ° C, and the entire treatment liquid is kept at a substantially uniform temperature of 65 to 75 ° C.
  • the heating temperature should be 90 ° C or lower and over 75 ° C, and the whole processing solution should be kept at a uniform temperature of 90 ° C or lower and over 75 ° C. Is.
  • the heating temperature is changed to two stages, and the entire treatment liquid is gelled in a nearly uniform state. A uniform card is formed. As a result, a gel-like food with a good texture and flavor that is less harsh to the mouth and to the touch is produced.
  • the temperature range of 65 to 75 ° C by the first-stage heat treatment (preheating) is a temperature at which the whey protein gradually heat-coagulates, for example, about 70 ° C.
  • the temperature range below 90 ° C and above 75 ° C by the second stage heat treatment (final heating) is the temperature at which the whey protein is completely heat-coagulated, for example, about 80 ° C. is there.
  • the heating temperature in the first stage is preferably set to 65 to 75 ° C, more preferably 70 to 75 ° C, and further preferably 70 to 73 ° C, so that the entire processing liquid is substantially uniform. Hold at a moderate temperature. That is, the temperature of the portion of the processing solution that is most difficult to rise is preferably 65 to 75 ° C, more preferably 70 to 75 ° C, and even more preferably 70 to 73 ° C. A heat treatment is applied to maintain the temperature of the entire processing solution.
  • the temperature is set lower than 65 ° C, it takes a long time for the portion where the temperature of the processing liquid is most difficult to reach a predetermined temperature, resulting in poor production efficiency.
  • the heating temperature in the first stage is set higher than 75 ° C, the whey protein will be denatured at once, and the treatment solution will solidify unevenly, resulting in a gel-like texture with a rough mouthfeel and texture. A food product is obtained, which is not preferable.
  • the heating temperature is set appropriately while taking into consideration the production efficiency and quality (texture and flavor) of the gel food.
  • the entire treatment liquid is gelled in a uniform and uniform state, thereby forming a uniform card with less texture and a smooth texture. A simple gel-like food can be obtained.
  • the temperature of the heat treatment is set to 65 ° C to 75 ° C, for example, the temperature is controlled within a range of 65 ° C to 75 ° C at a constant temperature (for example, 70 ° C). Both control and control at varying temperatures (eg 66 ° C to 73 ° C).
  • the heating temperature of the second stage is preferably 90 ° C or less and more than 75 ° C, more preferably 80 ° C to 90 ° C, still more preferably 80 to 85 °.
  • the heating temperature in the second stage is set to 75 ° C or lower, it takes a long time for the most difficult part of the processing liquid to reach the predetermined temperature, resulting in poor production efficiency.
  • the heating temperature is set higher than about 90 ° C, the whey protein is denatured at once, and the treatment liquid is solidified, so that a genore-like food with a rough texture can be obtained. It is not preferable.
  • the temperature of the heat treatment is set to a temperature range of 90 ° C or lower and higher than 75 ° C, for example, within a temperature range of 90 ° C or lower and higher than 75 ° C.
  • Both the first-stage heat treatment and the second-stage heat treatment described above can be performed as indirect heat treatment. Alternatively, both can be direct heat treatment. Furthermore, either one can be indirect heat treatment and the other can be direct heat treatment.
  • Indirect heat treatment involves heat treatment indirectly from the outside of a tank or container that contains the treatment liquid! For example, outside of the tank containing the processing solution (jacket etc.) Indirect heat treatment increases the temperature of the treatment liquid.
  • a cup-shaped plastic container or a retort container filled with a treatment liquid and sealed is introduced into an atmosphere of warm water or steam to raise the temperature of the treatment liquid.
  • a heating element, hot water, water vapor, or the like is injected into the treatment liquid and the heat treatment is performed directly.
  • a heating element, hot water, water vapor, or the like is injected into the processing liquid, an electrode is brought into contact with the processing liquid to energize it, or an electromagnetic wave (microwave) is irradiated to the processing liquid. It processes and raises the temperature of a process liquid.
  • the property of heat denaturation (temperature) of protein is used in a method for producing a gel food, and can be applied to egg white protein in addition to whey protein.
  • the treatment liquid can be emulsified before the treatment liquid is heat-treated.
  • the treatment liquid By emulsifying the treatment liquid, the treatment liquid is mixed in a nearly uniform state, so that the structure of the gel food is also likely to be uniform.
  • the stirring force of the tank When the treatment liquid is not emulsified, the stirring force of the tank, the use of a static mixer, etc. can be used with a force S.
  • a mesh filter, nozzle, homomixer, milder, homogenizer (homogenizer), or the like can be used. These can be used in general operating conditions and operating conditions.
  • the pH of the treatment liquid is 5 to 9.
  • the treatment solution preferably has a pH of 5 to 9, more preferably a pH of 5.55 to 8.5, and further preferably a pH of 6 to 8.
  • the pH adjuster for adjusting the pH of the treatment liquid include lactic acid, acetic acid, sulfuric acid, hydrochloric acid, citrate, lemon juice, sodium hydroxide, and potassium hydroxide.
  • the pH adjustment agent is gradually added gradually while stirring the treatment solution S, and aggregates due to proteins, proteins, etc. are difficult to form.
  • the treatment liquid may contain at least one of an emulsifier, a stabilizer and a gelling agent.
  • emulsifier examples include glycerin fatty acid ester, organic acid monodallylide, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, lecithin, enzymatically decomposed lecithin, polyglycerin fatty acid ester and the like.
  • the stabilizer include locust bin gum, guar gum, xanthan gum, dielan gum, tara gum, and gum arabic.
  • gelling agent examples include agar, pectin, and curdlan.
  • the treatment liquid is a protein, carbohydrate, vitamin, mineral, vegetable or animal that is conventionally known in the production of gel food such as whey cheese.
  • Oil and fat, soy-based foods such as soy milk, fruit-based foods such as fruit juice and pulp, and useful microorganisms such as lactic acid bacteria and bifidobacteria.
  • soy-based foods such as soy milk
  • fruit-based foods such as fruit juice and pulp
  • useful microorganisms such as lactic acid bacteria and bifidobacteria.
  • protein source material
  • specific examples of the protein source include full-fat milk, full-fat concentrated milk, full-fat milk powder, skim milk, skim-fat concentrated milk, skim milk powder, condensed milk, butter milk, butter milk powder , Casein, casein canolecium, sodium caseinate and the like.
  • lipid supply source material
  • examples of the lipid supply source include full-fat milk, full-fat concentrated milk, full-fat powdered milk, condensed milk, cream, butter, and fermented butter.
  • sugar source material
  • lactose lactose
  • glucose glucose
  • vitamin sources include various vitamins such as vitamin C and vitamin E, and fruit foods such as fruit juice and pulp.
  • mineral supply source material
  • various salts such as sodium chloride, magnesium chloride, and calcium carbonate.
  • gel food such as whey cheese other than the above-mentioned additives
  • a conventionally known additive is added to the above-mentioned treatment liquid as necessary, and the force S is used.
  • the additive include salting agent, viscosity adjusting agent, acidulant, sweetener, flavoring agent, acidity adjusting agent, food preservative, cereals, beans, vegetables, meat, seafood,
  • examples thereof include guanidine hydrochloride, urea, ethylene glycol, glycerin, propanol, sodium phosphite, sodium naphthalene sulfonate and sodium laurate sulfonate.
  • salting agent examples include sodium chloride (salt) and potassium chloride.
  • viscosity adjusting agent examples include whole egg, egg yolk, starch, gelatin, and gum.
  • Examples of the acidulant include acetic acid, lactic acid, citrate, tartaric acid, fumaric acid, succinic acid, malic acid, gluconic acid, adipic acid, phytic acid, darcono delta latatane, ascorbic acid and the like.
  • sweeteners include fructose, sucrose, sugar alcohol, mannitol, Sonorbitonore, and multitole.
  • Cocoa mass Cocoa powder, amino acids, nucleic acids and the like.
  • sourness preparation agents include antioxidants, sodium acetate, sodium citrate, sodium malate, sodium tartrate, sodium succinate, and sodium fumarate.
  • Examples of food preservation include coloring agents, sorbic acid, potassium sorbate, sodium sorbate, and ethyl alcohol.
  • both the first stage treatment time and the second stage treatment time be within 30 minutes.
  • the heat treatment time within this range is sufficient to improve the texture and flavor of the two-stage heat treatment of the present invention while maintaining better gel-like foods and production efficiency. It is preferred to be! /, From.
  • the processing time of the first stage and the second stage is! /, And the deviation should be within 30 minutes.
  • S is preferable, more preferably within 20 minutes for both the first stage and the second stage. More preferred The first and second stages are within 15 minutes.
  • the first-stage / second-stage heat treatment time is the treatment liquid to be heat-treated in the first-stage or second-stage heat treatment, or the heat treatment.
  • the capacity of a container such as a tank that contains the processing liquid to be processed, or a part of the container that is filled and sealed with the processing liquid.
  • the entire treatment solution in the first stage, is at a substantially uniform temperature of 65 to 75 ° C, more preferably 70 to 75 ° C, and even more preferably 70 to 73 ° C. keeping.
  • the entire treatment liquid in the second stage, is at a substantially uniform temperature of 90 ° C or lower and higher than 75 ° C, more preferably 80 ° C to 90 ° C, still more preferably 80 to 85 ° C. Holds to ° C.
  • the treatment time for the first stage and the second stage is preferably 30 minutes or less, more preferably 20 minutes or less, and still more preferably 15 minutes or less.
  • Control of these conditions includes, for example, the volume of the processing liquid, the composition of the processing liquid, the volume of the container that holds the processing liquid 'dimension' material, and the volume of the container that is filled and sealed with the processing liquid 'dimension-shape' ⁇ This can be done by adjusting at least one of the materials.
  • the treatment liquid can be heat-treated after being filled in a container and sealed.
  • indirect heating is preferred for both the first stage heat treatment and the second stage heat treatment.
  • heat treatment is performed under two-stage heating conditions, and the entire treatment liquid is maintained at 65 to 75 ° C at a substantially uniform temperature (first stage). Hold the whole liquid at a nearly uniform temperature, 90 ° C or lower and higher than 75 ° C (second stage). That is, when heat treatment is performed under two-stage heating conditions, and the heat treatment liquid is heated indirectly from the outside of the container containing the treatment liquid, the treatment is performed as in the central part inside the container. The temperature of the part of the liquid where heat is most difficult to transfer is within the predetermined temperature range. Thus, the temperature of the entire processing liquid is maintained by applying heat treatment to the processing liquid.
  • the capacity of the container can be 50 ml (milliliter) to 150 ml (milliliter).
  • the volume of the treatment liquid or the container is smaller than 50 ml (milliliter), the effect of improving the texture and flavor by the two-stage heat treatment becomes small.
  • the volume of the processing solution and the container is larger than 150 ml (millilitre)! /, which is preferable because the processing time becomes longer.
  • Specific examples of the shape and form of the container include a cup-shaped container and a bag shape for retort.
  • the material of the container may be made of plastic.
  • the gel food can be used as whey cheese.
  • whey cheese examples include those described in the “Codex standard”.
  • Whey powder (Meiji Dairies Co., Ltd.) 8 ⁇ lg, whey protein isolate (WPI) 5.2 g, raw tarium 13.5 g, tap water 83.2 g dissolved at room temperature while stirring in the tank Later, citrate was added little by little to adjust the pH of the treatment solution to 6.
  • the concentration of whey protein in water was about 6.7% by weight, and the weight ratio of fat to whey protein was about 1.1 times.
  • the final product (gel food) was obtained by cooling to a temperature of 10 ° C or lower.
  • Whey powder (Meiji Dairies Co., Ltd.) 8.0g, whey protein isolate (WPI) 5.4g, fresh tarium 39.2g, tap water 57.5g dissolved in the tank at room temperature Later, citrate was added little by little to adjust the pH of the treatment solution to 6.
  • the concentration of whey protein in water was about 8.5% by weight, and the weight ratio of fat to whey protein was about 2.8 times.
  • 110 g of this treatment solution was filled into a 150 ml plastic cup, it was immersed and held in hot water at a temperature of 75 ° C. for 10 minutes and further in hot water at a temperature of 80 ° C. for 20 minutes.
  • Whey powder (Meiji Dairies Co., Ltd.) 8 ⁇ lg, whey protein isolate (WPI) 5.2 g, raw tarium 13.5 g, tap water 83.2 g dissolved at room temperature while stirring in the tank Later, citrate was added little by little to adjust the pH of the treatment solution to 6.
  • the concentration of whey protein in water was about 6.7% by weight, and the weight ratio of fat to whey protein was about 1.1 times.
  • the product was cooled to a temperature of 10 ° C or lower to obtain a final product (gel food).
  • Example 1 The gel foods obtained in Example 1, Example 2 and Comparative Example 1 were subjected to a sensory test by five specialized panelists.
  • Example 1 and Example 2 in which heat treatment was performed in two stages of preheating at a temperature of 75 ° C and final heating at a temperature of 80 ° C were compared to Comparative Example 1 in which heat treatment was performed in one step at a temperature of 80 ° C Overall it was good! In particular, in terms of texture, Example 1 and Example 2 were clearly better than Comparative Example 1.
  • Example 1 A gel-like food obtained in Example 1 and a commercially available product that is generally sold!
  • Bacterial test (storage test) was conducted on commercial product B.
  • the evaluated items were the viable cell count and anaerobic cell count, and the selective media were standard agar medium (SMA medium) and GAM medium (manufactured by Nissy).
  • Example 1 of the product of the present invention live bacteria were below the detection limit value, whereas in the commercial products A and B, live bacteria were detected.
  • the product of the present invention did not show an increase in the number of viable bacteria even after 4 months, and it was proved that the shelf life was longer than that of the commercial products A and B.
  • the shelf life of commercial products A and B was set to 21 days from the date of manufacture.
  • Example 1 The gel-like food obtained in Example 1 and commercially available product A, which is commercially available whey cheese, were photographed with a stereomicroscope (25 times magnification). The images taken are shown in Fig. 1 (invention product) and Fig. 2 (commercial product A). In Example 1 of the product of the present invention, the structure was smooth, whereas in the commercial product A, the structure was rough.
  • the production of gel-like foods such as whey cheese having a texture and a good taste with a smooth texture and a smooth mouthfeel and low water separation is not starchy, and the texture is brittle.
  • a method can be provided.
  • FIG. 1 A photomicrograph of the surface of the product of the present invention taken with a stereomicroscope (25x magnification).
  • FIG. 2 Photomicrograph of the surface of a commercial product taken with a stereomicroscope (25x magnification).

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Abstract

[PROBLEMS] To provide a process for producing a gel-type food such as whey cheese which has a little brittle tissue and a non-sticky and little starchy feeling on the tongue, shows a smooth touch in the mouth and on the tongue, suffers from little dripping and is excellent in texture and taste. [MEANS FOR SOLVING PROBLEMS] A gel-type food is produced by subjecting a solution to be treated, which contains whey proteins and fat components and in which the concentration of the whey proteins is from 4 to 12% by weight and the weight ratio of the fat components to the whey proteins is 5:1 or less, to a heating treatment under two-stage heating conditions. The two-stage heating conditions comprise the first stage wherein the heating temperature is controlled to 65 to 75oC so that the above-described solution to be treated is maintained at an almost uniform temperature of 65 to 75oC as a whole, and the second stage wherein the heating temperature is controlled to not higher than 90OC but higher than 75oC so that the above-described solution to be treated is maintained at an almost uniform temperature of not higher than 90OC but higher than 75oC as a whole.

Description

明 細 書  Specification
ゲル状食品及びその製造方法  Gel-like food and method for producing the same
技術分野  Technical field
[0001] 本発明は、口当たりと舌触りが滑らかで離水が少なぐ食感や風味の良好なホエイ チーズなどのゲル状食品の製造方法及びこれにより製造したゲル状食品に関する。 背景技術  [0001] The present invention relates to a method for producing a gel-like food product such as whey cheese having a smooth mouthfeel and a smooth mouthfeel and having little water separation and good texture and flavor, and a gel-like food product produced thereby. Background art
[0002] ホエイはナチュラルチーズやカゼインの製造時に副産物として得られる。  [0002] Whey is obtained as a by-product during the production of natural cheese and casein.
[0003] ホエイは栄養価の高さで良く知られており、ホエイには、ホエイタンパク質、乳糖、ミ ネラル、ビタミンなどが含まれている。これらホエイの成分中でも、ホエイタンパク質は 特に栄養価の高いことと、タンパク質の利用効率に優れていることから、各種の栄養 組成物などにお!/、て素材として重宝されて!/、る。  [0003] Whey is well known for its high nutritional value. Whey contains whey protein, lactose, minerals, vitamins, and the like. Among these whey components, whey protein is especially useful as a raw material for various nutritional compositions because it has a high nutritional value and is highly efficient in protein utilization.
[0004] ただし、ホエイタンパク質の有効利用は十分とは言えず、さらなる用途開発が望ま れている。 [0004] However, effective use of whey proteins is not sufficient, and further development of applications is desired.
[0005] ホエイタンパク質は、温度 60°C以上で加熱処理すると変性し、低 pHの液中で加熱 処理すると酸凝固物となり、塩類の存在下で加熱処理すると保水性の優れたゲル化 物となる特徴を有してレ、る (非特許文献 1)。  [0005] Whey protein is denatured when heat-treated at a temperature of 60 ° C or higher, becomes an acid coagulated product when heat-treated in a low pH solution, and becomes a gel product with excellent water retention when heat-treated in the presence of salts. (Non-Patent Document 1).
[0006] ホエイタンパク質の加熱凝固性を利用した食品としてリコッタチーズなどに代表され るホエイチーズがある。  [0006] There is whey cheese typified by ricotta cheese as a food utilizing the heat coagulation property of whey protein.
[0007] このホエイチーズは、例えば、通常のナチュラルチーズの製造時に副産物として得 られたホエイに、全脂乳、脱脂乳、クリームなどを添加して処理液を調製し、この処理 液へ少量の酸 (乳酸など)を加える、等した後に、大容量のタンク(釜)で温度 85〜9 5°Cに加熱し、カード (凝集物)を形成させて得られる(非特許文献 2、非特許文献 3) [0007] For example, this whey cheese is prepared by adding whole milk, skim milk, cream, etc. to whey obtained as a by-product during the production of normal natural cheese, and preparing a small amount of this whey. After adding acid (such as lactic acid), etc., it is heated to 85-95 ° C in a large-capacity tank (kettle) to form a card (aggregate) (Non-patent document 2, Non-patent document) Reference 3)
Yes
[0008] まず初めに、カードは大容量のタンク内で、液面付近へ浮上してくるので、その浮 上したカードをザル (網)などで掬い取り回収する。次に、加熱(高温)状態にある処 理液へ少量の酸 (タエン酸など)を加えたりして、さらにカード (凝集物)を形成させる 。これらのカードを合わせて脱水処理し、カップ状の容器などへ充填し密封してホェ ィチーズとするものである。 [0008] First, since the card floats near the liquid level in a large-capacity tank, the floated card is scooped and collected with a colander (net). Next, a small amount of acid (such as taenoic acid) is added to the processing solution in a heated (high temperature) state to further form a card (aggregate). These cards are combined, dehydrated, filled into a cup-shaped container, etc., sealed, and whey. It is supposed to be cheese.
[0009] 一方、ホエイタンパク質を利用したチーズ様食品の製造では幾つかが試みられて いる。例えば、特許文献 1では、ホエイチーズの製造において、高い栄養価を有する ホエイタンパク質濃縮物 (WPC)を主原料に用いて加熱し、レンネットを加えて熟成さ せ、風味と組織の良好なナチュラルチーズ様食品を得て!/、る。 On the other hand, several attempts have been made in the production of cheese-like foods using whey protein. For example, in Patent Document 1, in the production of whey cheese, whey protein concentrate (WPC), which has high nutritional value, is heated as a main ingredient, ripened with rennet, and natural with good flavor and texture. Get cheese-like food!
[0010] 特許文献 2では、ホエイタンパク質を限定的に分解した後に、加熱処理してから酸 処理することにより、滑らかな食感のホエイタンパク質チーズを得ている。 [0010] In Patent Document 2, a whey protein cheese having a smooth texture is obtained by subjecting whey protein to limited decomposition, followed by heat treatment and acid treatment.
[0011] また、特許文献 3では、原料乳にホエイタンパク質を添加し、 pH調整後に加熱撹拌 することにより、保水性、耐熱性、保存性に優れたカッテージチーズ様のフレッシュチ ーズカードを短時間に高収率で得て!/、る。 [0011] Further, in Patent Document 3, a whey protein is added to raw milk and heated and stirred after pH adjustment, whereby a cottage cheese-like fresh cheese curd excellent in water retention, heat resistance, and storage stability can be obtained in a short time. Get in high yield!
[0012] ただし、前記のカードでは、組織が脆かったり、舌触りが糊っぽぐ澱粉っぽかったり[0012] However, in the above card, the tissue is fragile, the touch of the tongue is starchy,
、離水しやすかつたりすることもあり、食感や風味の観点からは不満の残るものもあつ た。 However, there were some things that remained unsatisfactory from the viewpoint of texture and flavor.
[0013] また、前記の製造方法では、加熱時間が長めになること、加熱方法や加熱装置の 構造上の特性により処理液に過加熱な部分が生じ、処理液の部分毎で熱履歴が異 なることなど力、ら、カードが堅くなりすぎたり、容器内などの部分毎で食感や風味が一 定せず、ばらついたりすることもあった。  [0013] In addition, in the manufacturing method described above, the heating time becomes longer, and an overheated portion is generated in the processing liquid due to the structural characteristics of the heating method and the heating apparatus, and the heat history varies depending on the portion of the processing liquid. In some cases, the card was too hard, and the texture and flavor were not consistent for each part, such as inside the container.
[0014] なお、処理液に過加熱な部分が生じるとは、例えば、タンクの外部(ジャケットなど) 力も間接的に加熱処理して処理液を昇温する場合には、タンクの内部における縁周 辺部で起こる現象として想定される。また、処理液へ発熱体、熱水、水蒸気などを注 入したり、処理液へ電極を接触させて通電したり、処理液へ電磁波(マイクロウェイブ )を照射したりすることで直接的に加熱処理して処理液を昇温する場合には、その発 熱体、熱水、水蒸気、電極、照射部分などの付近で起こる現象として想定される。  [0014] Note that an overheated portion is generated in the processing liquid. For example, when the processing liquid is heated by indirectly heat (such as a jacket) force of the tank to increase the temperature of the processing liquid, It is assumed as a phenomenon that occurs on the side. In addition, a heating element, hot water, water vapor, or the like is injected into the processing liquid, an electrode is brought into contact with the processing liquid to energize it, or an electromagnetic wave (microwave) is irradiated to the processing liquid. When the temperature of the processing liquid is increased by processing, it is assumed that the phenomenon occurs in the vicinity of the heating element, hot water, water vapor, electrode, irradiated portion, and the like.
[0015] さらに、このとき、処理液の調製から加熱処理して、容器などへ充填し密封するまで の処理操作が開放系になっていると、衛生上の問題が危惧されることもあった。  [0015] Further, at this time, if the processing operation from preparation of the treatment liquid to heat treatment, filling into a container or the like and sealing is an open system, there may be a concern about sanitary problems.
特許文献 1:特開平 1 - 148148  Patent Document 1: JP-A-1-148148
特許文献 2:特開平 7— 264980  Patent Document 2: JP-A-7-264980
特許文献 3:特開平 9 299025 非特許文献 l : New Food Industry, 25 (3), 33 (1983):上野川修ー Patent Document 3: JP-A-9 299025 Non-patent literature l: New Food Industry, 25 (3), 33 (1983): Ouegawa Osamu
非特許文献 2: CHEESE Chemistry, Physics and Microbiology - Volume2, Major Che ese Groups: Fox · McSweeney · Cogan · Guinee共著  Non-patent document 2: CHEESE Chemistry, Physics and Microbiology-Volume2, Major Cheese Groups: Co-authored by Fox, McSweeney, Cogan, Guinee
^特許文献 3 : Application of ulrtafiltration in the dairy industry : Renner'Abd共著 発明の開示  ^ Patent Document 3: Application of ulrtafiltration in the dairy industry: Co-authored by Renner'Abd
発明が解決しょうとする課題  Problems to be solved by the invention
[0016] 本発明は、上記従来技術の課題点を鑑みてなされたものであり、組織が脆くなぐ 舌触りが糊っぽくなぐ澱粉っぽくない、口当たりと舌触りが滑らかで離水が少なぐ食 感ゃ風味の良好なホエイチーズなどのゲル状食品の製造方法及びこれにより製造さ れたホエイチーズなどのゲル状食品を提供することを目的とする。  [0016] The present invention has been made in view of the above-mentioned problems of the prior art, and the texture is brittle. The texture is not starchy, the texture is smooth, the mouthfeel is smooth, and the texture is low. It is an object of the present invention to provide a method for producing a gel-like food product such as whey cheese having good flavor and a gel-like food product such as whey cheese produced thereby.
課題を解決するための手段  Means for solving the problem
[0017] 本発明者らは、上記課題に鑑み、鋭意研究を重ねた結果、従来のホエイチーズの 製造工程において加熱処理条件を工夫することにより、従来にない食感や風味の優 れたホエイチーズなどのゲル状食品が得られるという知見を見出し、本発明を完成す るに至った。 [0017] As a result of intensive research in view of the above problems, the present inventors have devised heat treatment conditions in the conventional whey cheese manufacturing process, thereby improving whey with an unprecedented texture and flavor. The inventors have found that gel-like foods such as cheese can be obtained, and have completed the present invention.
[0018] また、このとき、加熱処理を施す処理液にお!/、てホエイタンパク質の濃度や、ホエイ タンパク質と脂肪の混合比、 pH、容量などを適宜選択することにより、従来にない食 感ゃ風味に優れ、かつ長期の保存が可能で衛生的なゲル状食品が得られるという知 見を同時に見出した。  [0018] Further, at this time, the concentration of whey protein, the mixing ratio of whey protein and fat, pH, volume, etc. are appropriately selected in the treatment solution to be heat-treated, so At the same time, we found the knowledge that hygienic gel-like foods with excellent flavor and long-term storage could be obtained.
[0019] すなわち、本発明は、以下の通りのものである。  That is, the present invention is as follows.
[0020] (1)ホエイタンパク質と脂肪分とを含み、ホエイタンパク質の濃度が 4〜; 12重量%、脂 肪分のホエイタンパク質に対する重量比が 5倍以下である処理液を、二段階の加熱 条件により加熱処理してゲル状食品を製造する方法であって、  [0020] (1) A treatment solution containing whey protein and fat, the concentration of whey protein being 4 to; 12% by weight, and the weight ratio of fat to whey protein being 5 times or less is heated in two stages. A method for producing a gel food by heat treatment according to conditions,
二段階の加熱条件の一段階目では、加熱温度を 65〜75°Cとして前記処理液の全 体がほぼ均一な温度で 65〜75°Cになるように保持し、  In the first stage of the two-stage heating conditions, the heating temperature is set to 65 to 75 ° C, and the whole treatment liquid is held at 65 to 75 ° C at a substantially uniform temperature.
二段階の加熱条件の二段階目では、加熱温度を 90°C以下であって 75°Cを超える 温度として前記処理液の全体がほぼ均一な温度で 90°C以下であって 75°Cを超える 温度になるように保持する ことを特徴とするゲル状食品の製造方法。 In the second stage of the two-stage heating conditions, the heating temperature is 90 ° C or lower and exceeds 75 ° C, and the entire treatment liquid is almost uniform at 90 ° C or lower and 75 ° C. Hold at a temperature exceeding A method for producing a gel food characterized by the above.
[0021] (2)前記の(1)において、前記処理液に対して加熱処理する前に前記処理液を乳化 処理することを特徴とするゲル状食品の製造方法。 [0021] (2) In the above (1), a method for producing a gel-like food, wherein the treatment liquid is emulsified before heat-treating the treatment liquid.
[0022] (3)前記の(1)又は(2)において、前記処理液の pHが 5〜9であることを特徴とする ゲル状食品の製造方法 [0022] (3) In the method (1) or (2), the pH of the treatment liquid is 5 to 9,
(4)前記の(1)乃至(3)のいずれかにおいて、前記処理液は乳化剤、安定剤、ゲル 化剤の少なくとも一つ以上を含むことを特徴とするゲル状食品の製造方法。  (4) In any one of the above (1) to (3), the treatment liquid contains at least one of an emulsifier, a stabilizer and a gelling agent.
[0023] (5)前記の(1)乃至(4)の!/、ずれかにお!/、て、一段階目の加熱処理時間及び二段 階目の加熱処理時間カ^、ずれも 30分以内であることを特徴とするゲル状食品の製 造方法。 [0023] (5) The above-mentioned (1) to (4)! /, Or even the deviation! /, The heat treatment time for the first stage and the heat treatment time for the second stage, and the deviation is 30. A method for producing a gel food characterized by being within minutes.
[0024] (6)前記の(1)乃至(5)のいずれかにおいて、前記処理液を容器に充填し密封した 後に加熱処理することを特徴とするゲル状食品の製造方法。  [0024] (6) A method for producing a gel-like food according to any one of (1) to (5), wherein the treatment liquid is filled in a container and sealed, followed by heat treatment.
[0025] (7)前記の(6)において、前記容器の容量が 50ml (ミリリットル)乃至 150ml (ミリリット ノレ)であることを特徴とする請求項 6記載のゲル状食品の製造方法。 [0025] (7) The method for producing a gel food according to (6) above, wherein the container has a capacity of 50 ml (milliliter) to 150 ml (milliliter).
[0026] (8)前記の(6)又は(7)にお!/、て、前記容器の材質がプラスチック製であることを特 徴とするゲル状食品の製造方法。 [0026] (8) A method for producing a gel food characterized in that the material of the container is made of plastic according to (6) or (7) above.
[0027] (9)前記の(1)乃至(8)のいずれかにおいて、前記ゲル状食品がホエイチーズであ ることを特徴とするゲル状食品の製造方法。 [0027] (9) In any one of (1) to (8), the gel food is whey cheese, and the method for producing a gel food is characterized in that
[0028] (10)前記の(1)乃至(8)のいずれかの製造方法を用いて製造したゲル状食品。 [0028] (10) A gel-like food produced using the production method of any one of (1) to (8) above.
[0029] (11 )前記の(1)乃至(8)のいずれかの製造方法を用いて製造したホエイチーズ。 [0029] (11) Whey cheese produced using the production method of any one of (1) to (8) above.
発明の効果  The invention's effect
[0030] 本発明によれば、組織が脆くなぐ舌触りが糊っぽくなぐ澱粉っぽくない、 口当たり と舌触りが滑らかで離水が少なぐ食感や風味の良好なホエイチーズなどのゲル状 食品の製造方法及びこれにより製造されたホエイチーズなどのゲル状食品を提供す ること力 Sでさる。  [0030] According to the present invention, the production of gel-like foods such as whey cheese having a texture and a good taste with a smooth texture and a smooth mouthfeel and low water separation, is not starchy, with a brittle tissue and brittle texture. The method and the ability to provide gelled foods such as whey cheese produced by this method.
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0031] 本願の発明者らは、ホエイタンパク質を含む処理液に対して様々な加熱条件により 加熱処理してホエイチーズなどのゲル状食品を試作し、それらのゲル状食品につい て食感や風味、物性などを評価 '解析した。また、ホエイタンパク質を含む処理液を カップ状の容器へ充填し密封した後に、様々な加熱条件により加熱処理してホエイ チーズなどのゲル状食品を試作し、それらのゲル状食品について食感や風味、物性 などを評価 '解析した。 [0031] The inventors of the present application heat-processed a treatment solution containing whey protein under various heating conditions to produce a gel food such as whey cheese, and attached the gel food. Evaluation and analysis of texture, flavor and physical properties. In addition, after filling a cup-shaped container with a treatment solution containing whey protein and sealing it, heat treatment is carried out under various heating conditions to produce prototype food products such as whey cheese. Evaluation and analysis of physical properties.
[0032] このとき、食感や風味の評価には官能検査を用い、物性の評価には細菌検査ゃ顕 微鏡の写真撮影などを用いた。これら食感や風味と物性を同時に評価 ·解析すること により、食感や風味の良好なゲル状食品の製造方法およびこれにより製造したゲル 状食品を見出した。  At this time, a sensory test was used to evaluate the texture and flavor, and a bacterial test was used to take a microscopic photograph to evaluate the physical properties. By simultaneously evaluating and analyzing the texture, flavor and physical properties, a method for producing a gel-like food having a good texture and flavor and a gel-like food produced thereby were found.
[0033] 本発明のゲル状食品の製造方法は、ホエイタンパク質と脂肪分とを含み、ホェイタ ンパク質の濃度が 4〜; 12重量%、脂肪分のホエイタンパク質に対する重量比が 5倍 以下である処理液を、二段階の加熱条件により加熱処理してゲル状食品を製造する ものである。  [0033] The method for producing a gel food according to the present invention comprises whey protein and fat, the concentration of whey protein is 4 to 12% by weight, and the weight ratio of fat to whey protein is 5 times or less. The treatment liquid is heated under two-stage heating conditions to produce a gel food.
[0034] ここで、二段階の加熱条件の一段階目では、加熱温度を 65〜75°Cとして前記処 理液の全体がほぼ均一な温度で 65〜75°Cになるように保持し、二段階の加熱条件 の二段階目では、加熱温度を 90°C以下であって 75°Cを超える温度として前記処理 液の全体がほぼ均一な温度で 90°C以下であって 75°Cを超える温度になるように保 持するものである。  [0034] Here, in the first stage of the two-stage heating conditions, the heating temperature is set to 65 to 75 ° C, and the whole processing liquid is held at 65 to 75 ° C at a substantially uniform temperature. In the second stage of the two-stage heating conditions, the heating temperature is 90 ° C or lower and higher than 75 ° C, and the treatment liquid as a whole is almost uniform at 90 ° C or lower and 75 ° C. The temperature is maintained so that the temperature exceeds.
[0035] 前記の処理液を、前述した二段階の加熱条件で加熱処理することにより、組織が脆 くなぐ舌触りが糊っぽくなぐ澱粉っぽくない、口当たりと舌触りが滑らかで離水が少 なぐ食感や風味の良好なホエイチーズなどのゲル状食品を製造することができる。  [0035] By subjecting the treatment liquid to heat treatment under the two-stage heating conditions described above, the texture is brittle and the texture is not starchy, the mouthfeel is smooth, the mouthfeel is smooth, and the water release is low. Gel-like foods such as whey cheese having good feeling and flavor can be produced.
[0036] 本発明において「処理液の全体がほぼ均一な温度で 65〜75°Cになるように保持 する」、「処理液の全体がほぼ均一な温度で 90°C以下であって 75°Cを超える温度に なるように保持する」とは、「処理液の最も昇温しにくい部分」の温度もが前記の所定 の温度範囲になるように、処理液に加熱処理を加えて処理液全体の温度を保持する ことをいう。  [0036] In the present invention, "the whole treatment liquid is held at 65 to 75 ° C at a substantially uniform temperature", "the whole treatment liquid is 90 ° C or less and 75 ° at a substantially uniform temperature. “Hold at a temperature exceeding C” means that the treatment liquid is subjected to heat treatment so that the temperature of the “part of the treatment liquid that is most difficult to rise” also falls within the predetermined temperature range. It means maintaining the whole temperature.
[0037] なお、ここで、「処理液の最も昇温しにくい部分」とは、例えば、処理液を収容してい る容器の外部から間接的に加熱処理して処理液を加熱する場合には、容器の内部 における中心部のように、処理液の中で最も熱が伝わりにくい部分を意味する。 [0038] また、処理液へ発熱体、熱水、水蒸気などを注入して直接的に加熱処理して処理 液を加熱する場合には、その発熱体、熱水、水蒸気などから距離的に遠かったり、粘 度や密度などの物性的に温度変化しにくかったりする位置を意味する。 [0037] Here, the "part of the processing liquid that is most difficult to raise the temperature" means, for example, when the processing liquid is heated by heating indirectly from the outside of the container containing the processing liquid. This means the part of the processing solution where heat is most difficult to transfer, such as the central part inside the container. [0038] In addition, when heating a treatment liquid by injecting a heating element, hot water, water vapor or the like into the treatment liquid and heating the treatment liquid directly, it is far from the heat generation body, hot water, water vapor or the like. Or a position where it is difficult to change temperature due to physical properties such as viscosity and density.
[0039] 本発明で用いるホエイタンパク質は、チーズホエイや、酸ホエイなどに含まれている [0039] The whey protein used in the present invention is contained in cheese whey, acid whey and the like.
Yes
[0040] チーズホエイは、乳からナチュラルチーズを製造する時に副産物として得られる。  [0040] Cheese whey is obtained as a by-product when producing natural cheese from milk.
酸ホエイは、タンパク質が等電点の付近で沈殿する現象を利用し、乳に酸を加えて カゼインを製造する時に上清として得られる。  Acid whey is obtained as a supernatant when casein is produced by adding acid to milk, utilizing the phenomenon that proteins precipitate near the isoelectric point.
[0041] 本発明で用いるホエイタンパク質の供給源(素材)としては、具体的には、ホエイ、 ホエイパウダー、ホエイを限外濾過膜などで処理して得られるホエイタンパク質濃縮 物 (WPC)、ホエイをイオン交換樹脂などで処理して得られるホエイタンパク質分離 物(WPI)などを例示できる。  [0041] The whey protein source (material) used in the present invention specifically includes whey, whey powder, whey protein concentrate (WPC) obtained by treating whey with an ultrafiltration membrane, whey, and the like. Examples thereof include a whey protein isolate (WPI) obtained by treating the protein with an ion exchange resin.
[0042] 前記の処理液におけるホエイタンパク質の濃度(水中濃度)は、好ましくは 4〜; 12重 量%である。 [0042] The concentration (in water concentration) of the whey protein in the treatment solution is preferably 4 to 12% by weight.
[0043] 前記の処理液におけるホエイタンパク質の濃度が 4重量%より低いと、加熱処理に より得られるゲルの強度が弱くなりすぎてしまい、ホエイタンパク質の濃度が 12重量% より高いと、ゲルの強度が強くなりすぎてしまうため、そのままではゲル状食品として 食用には適さないこととなる。  [0043] If the concentration of whey protein in the treatment solution is lower than 4% by weight, the strength of the gel obtained by heat treatment becomes too weak. If the concentration of whey protein is higher than 12% by weight, Since the strength becomes too strong, the gel food is not suitable for food as it is.
[0044] なお、かかる観点から、前記の処理液におけるホエイタンパク質の濃度は、より好ま しくは 5〜 11重量%、さらに好ましくは 6〜; 10重量%である。  [0044] From this viewpoint, the concentration of the whey protein in the treatment solution is more preferably 5 to 11% by weight, still more preferably 6 to 10% by weight.
[0045] 前記の処理液における脂肪分は、ホエイタンパク質に対する重量比で 5倍以下で あることが望ましい。  [0045] The fat content in the treatment solution is preferably 5 times or less by weight ratio to whey protein.
[0046] 前記の処理液には脂肪分が適当量で含まれていることが、ゲル状食品の口当たり と舌触りを滑らにし、食感や風味に濃厚感などを得る上で好ましい。しかし、処理液 における脂肪分がホエイタンパク質に対する重量比で 5倍を超えると、ゲル状食品の 食感や風味に脂っぽさなどを感じることもあるので好ましくない。  [0046] It is preferable that the treatment liquid contains an appropriate amount of fat in order to make the mouthfeel and texture of the gel-like food smooth, and to obtain a rich feeling in texture and flavor. However, if the fat content in the treatment liquid exceeds 5 times by weight with respect to whey protein, it is not preferable because the food texture and flavor of the gel food may be felt.
[0047] なお、かかる観点から、前記の処理液における脂肪分は、ホエイタンパク質に対す る重量比で、より好ましくは 0. 5〜4倍、さらに好ましくは;!〜 3倍である。 [0048] 前記の脂肪分の供給源 (素材)として具体的には、全脂乳、全脂濃縮乳、全脂粉乳 、練乳、クリーム、バター、発酵バター、バターミルク、バターミルク粉、植物性や動物 性の油脂、豆乳などの大豆系の食品などが例示できる。 [0047] From this point of view, the fat content in the treatment liquid is more preferably 0.5 to 4 times, and still more preferably! To 3 times, by weight ratio to the whey protein. [0048] Specific examples of the fat source (material) include whole milk, whole fat concentrated milk, whole milk powder, condensed milk, cream, butter, fermented butter, buttermilk, buttermilk powder, vegetable And soy-based foods such as animal oils and fats and soy milk.
[0049] 本発明では、前記で説明した処理液を、二段階の加熱条件により加熱処理する。  [0049] In the present invention, the treatment liquid described above is heat-treated under two-stage heating conditions.
[0050] この二段階の加熱条件は、一段階目で、加熱温度を 65〜75°Cとして前記処理液 の全体がほぼ均一な温度で 65〜75°Cになるように保持し、二段階目で、加熱温度 を 90°C以下であって 75°Cを超える温度として前記処理液の全体がほぼ均一な温度 で 90°C以下であって 75°Cを超える温度になるように保持するものである。  [0050] This two-stage heating condition is the first stage, where the heating temperature is 65 to 75 ° C, and the entire treatment liquid is kept at a substantially uniform temperature of 65 to 75 ° C. Visually, the heating temperature should be 90 ° C or lower and over 75 ° C, and the whole processing solution should be kept at a uniform temperature of 90 ° C or lower and over 75 ° C. Is.
[0051] 一段階目の加熱処理 (予備加熱)と二段階目の加熱処理 (最終加熱)とで、加熱温 度を二段階に変えて、処理液の全体を均一に近い状態でゲル化させ、均一なカード を形成させるものである。これにより、口当たりや舌触りにザラつきの少ない、食感や 風味の良好なゲル状食品を製造するものである。  [0051] In the first stage heat treatment (preliminary heating) and the second stage heat treatment (final heating), the heating temperature is changed to two stages, and the entire treatment liquid is gelled in a nearly uniform state. A uniform card is formed. As a result, a gel-like food with a good texture and flavor that is less harsh to the mouth and to the touch is produced.
[0052] 一段階目の加熱処理(予備加熱)による 65〜75°Cの温度範囲は、例えば、約 70 °Cのように、ホエイタンパク質が徐々に熱凝固する温度である。  [0052] The temperature range of 65 to 75 ° C by the first-stage heat treatment (preheating) is a temperature at which the whey protein gradually heat-coagulates, for example, about 70 ° C.
[0053] 二段階目の加熱処理 (最終加熱)による 90°C以下であって 75°Cを超える温度範囲 は、例えば、約 80°Cのように、ホエイタンパク質が完全に熱凝固する温度である。  [0053] The temperature range below 90 ° C and above 75 ° C by the second stage heat treatment (final heating) is the temperature at which the whey protein is completely heat-coagulated, for example, about 80 ° C. is there.
[0054] 本発明では、一段階目の加熱温度を好ましくは 65〜75°C、より好ましくは 70〜75 °C、さらに好ましくは 70〜73°Cに設定し、処理液の全体をほぼ均一な温度で保持す る。すなわち、前述した処理液の最も昇温しにくい部分の温度が好ましくは 65〜75 °C、より好ましくは 70〜75°C、さらに好ましくは 70〜73°Cになるように、処理液に加 熱処理を加えて処理液全体の温度を保持する。  [0054] In the present invention, the heating temperature in the first stage is preferably set to 65 to 75 ° C, more preferably 70 to 75 ° C, and further preferably 70 to 73 ° C, so that the entire processing liquid is substantially uniform. Hold at a moderate temperature. That is, the temperature of the portion of the processing solution that is most difficult to rise is preferably 65 to 75 ° C, more preferably 70 to 75 ° C, and even more preferably 70 to 73 ° C. A heat treatment is applied to maintain the temperature of the entire processing solution.
[0055] 65°Cよりも低く設定すると、処理液の最も昇温しにくい部分が所定の温度に到達す るために長時間を必要とし、生産効率などが悪くなる。  [0055] If the temperature is set lower than 65 ° C, it takes a long time for the portion where the temperature of the processing liquid is most difficult to reach a predetermined temperature, resulting in poor production efficiency.
[0056] 一方、一段階目の加熱温度を 75°Cよりも高く設定すると、ホエイタンパク質が一気 に変性してしまい、処理液が不均一に凝固するため、口当たりや舌触りにザラつきの あるゲル状食品が得られることとなり好ましくない。  [0056] On the other hand, if the heating temperature in the first stage is set higher than 75 ° C, the whey protein will be denatured at once, and the treatment solution will solidify unevenly, resulting in a gel-like texture with a rough mouthfeel and texture. A food product is obtained, which is not preferable.
[0057] つまり、加熱温度はゲル状食品の生産効率と品質 (食感や風味)を勘案しつつ、適 切に設定することが好ましい。 [0058] 一段階目の加熱処理 (予備加熱)により、処理液の全体をムラなく均一に近い状態 でゲル化させることにより、均一なカードを形成し、ザラつきが少なく食感や風味の滑 らかなゲル状食品を得ることができる。 That is, it is preferable to set the heating temperature appropriately while taking into consideration the production efficiency and quality (texture and flavor) of the gel food. [0058] By the first stage of heat treatment (preheating), the entire treatment liquid is gelled in a uniform and uniform state, thereby forming a uniform card with less texture and a smooth texture. A simple gel-like food can be obtained.
[0059] なお、加熱処理の温度を 65°C〜75°Cに設定するとは、例えば、温度を 65°C〜75 °Cの範囲内で、一定の温度(例えば、 70°C)で制御することと、変動する温度(例え ば、 66°C〜73°C)で制御することの両者を意味するものである。  [0059] The temperature of the heat treatment is set to 65 ° C to 75 ° C, for example, the temperature is controlled within a range of 65 ° C to 75 ° C at a constant temperature (for example, 70 ° C). Both control and control at varying temperatures (eg 66 ° C to 73 ° C).
[0060] 本発明では、二段階目の加熱温度を好ましくは 90°C以下であって 75°Cを超える温 度範囲、より好ましくは 80°C〜90°C、さらに好ましくは 80〜85°Cに設定し、処理液の 全体をほぼ均一な温度で保持する。すなわち、前述した処理液の最も昇温しにくい 部分の温度が好ましくは 90°C以下であって 75°Cを超える温度範囲、より好ましくは 8 0°C〜90°C、さらに好ましくは 80〜85°Cになるように、処理液に加熱処理を加えて処 理液全体の温度を保持する。  [0060] In the present invention, the heating temperature of the second stage is preferably 90 ° C or less and more than 75 ° C, more preferably 80 ° C to 90 ° C, still more preferably 80 to 85 °. Set to C to keep the entire processing solution at a nearly uniform temperature. That is, the temperature of the portion of the processing liquid that is most difficult to raise is preferably 90 ° C or less and more than 75 ° C, more preferably 80 ° C to 90 ° C, and still more preferably 80 to 90 ° C. Heat the treatment solution to 85 ° C to maintain the temperature of the whole treatment solution.
[0061] 二段階目の加熱温度を 75°C以下に設定すると、処理液の最も昇温しにくい部分が 所定の温度に到達するために長時間を必要とし、生産効率などが悪くなる。  [0061] If the heating temperature in the second stage is set to 75 ° C or lower, it takes a long time for the most difficult part of the processing liquid to reach the predetermined temperature, resulting in poor production efficiency.
[0062] 一方、加熱温度を 90°C前後よりも高く設定すると、ホエイタンパク質が一気に変性 してしまい、処理液が強固に凝固するため、口当たりや舌触りにザラつきのあるゲノレ 状食品が得られることとなり好ましくない。  [0062] On the other hand, if the heating temperature is set higher than about 90 ° C, the whey protein is denatured at once, and the treatment liquid is solidified, so that a genore-like food with a rough texture can be obtained. It is not preferable.
[0063] つまり、二段階目でも加熱温度はゲル状食品の生産効率と品質を勘案しつつ、適 切に設定することが好ましい。  [0063] That is, it is preferable to set the heating temperature appropriately in the second stage while taking into consideration the production efficiency and quality of the gel food.
[0064] なお、加熱処理の温度を 90°C以下であって 75°Cを超える温度範囲に設定すると は、例えば、温度を 90°C以下であって 75°Cを超える温度範囲内で、一定の温度(例 えば、 80°C)で制御することと、変動する温度(例えば、 76°C〜88°C)で制御すること の両者を意味するものである。  [0064] Note that, when the temperature of the heat treatment is set to a temperature range of 90 ° C or lower and higher than 75 ° C, for example, within a temperature range of 90 ° C or lower and higher than 75 ° C, This means both controlling at a constant temperature (for example, 80 ° C) and controlling at a fluctuating temperature (for example, 76 ° C to 88 ° C).
[0065] 前述した一段階目の加熱処理、二段階目の加熱処理とも、間接的加熱処理とする こと力 Sできる。あるいは、いずれとも直接的加熱処理とすることもできる。さらに、どちら か一方を間接的加熱処理とし、他方を直接的加熱処理とすることもできる。  [0065] Both the first-stage heat treatment and the second-stage heat treatment described above can be performed as indirect heat treatment. Alternatively, both can be direct heat treatment. Furthermore, either one can be indirect heat treatment and the other can be direct heat treatment.
[0066] 間接的加熱処理は、処理液を収容して!/、るタンクや容器の外部から間接的に加熱 処理するものである。例えば、処理液を収容しているタンクの外部(ジャケットなど)か ら間接的に加熱処理して処理液の温度を上昇させるものである。あるいは処理液が 充填されて密封されているカップ状のプラスチック製の容器やレトルトの容器などを 温水中や水蒸気の雰囲気中へ投入して処理液の温度を上昇させるものである。 [0066] Indirect heat treatment involves heat treatment indirectly from the outside of a tank or container that contains the treatment liquid! For example, outside of the tank containing the processing solution (jacket etc.) Indirect heat treatment increases the temperature of the treatment liquid. Alternatively, a cup-shaped plastic container or a retort container filled with a treatment liquid and sealed is introduced into an atmosphere of warm water or steam to raise the temperature of the treatment liquid.
[0067] 直接的加熱処理は、処理液へ発熱体、熱水、水蒸気などを注入して直接的に加熱 処理するものである。例えば、処理液へ発熱体、熱水、水蒸気などを注入したり、処 理液へ電極を接触させて通電したり、処理液へ電磁波(マイクロウェイブ)を照射した りすることで直接的に加熱処理して処理液の温度を上昇させるものである。  [0067] In the direct heat treatment, a heating element, hot water, water vapor, or the like is injected into the treatment liquid and the heat treatment is performed directly. For example, a heating element, hot water, water vapor, or the like is injected into the processing liquid, an electrode is brought into contact with the processing liquid to energize it, or an electromagnetic wave (microwave) is irradiated to the processing liquid. It processes and raises the temperature of a process liquid.
[0068] なお、本発明は、タンパク質の加熱変性(温度)の特性を、ゲル状食品の製造方法 に利用しており、ホエイタンパク質の他に卵白タンパク質などへも適用できる。  [0068] In the present invention, the property of heat denaturation (temperature) of protein is used in a method for producing a gel food, and can be applied to egg white protein in addition to whey protein.
[0069] 本発明のゲル状食品の製造方法においては、前記処理液に対して加熱処理する 前に前記処理液を乳化処理することができる。  [0069] In the method for producing a gel food of the present invention, the treatment liquid can be emulsified before the treatment liquid is heat-treated.
[0070] 処理液を乳化処理することにより、処理液が均一に近い状態で混合されるため、ゲ ル状食品の組織も均一になりやすく好ましい。  [0070] By emulsifying the treatment liquid, the treatment liquid is mixed in a nearly uniform state, so that the structure of the gel food is also likely to be uniform.
[0071] 処理液を乳化処理しない場合には、タンクの撹拌、スタティックミキサーなどを利用 すること力 Sでさる。  [0071] When the treatment liquid is not emulsified, the stirring force of the tank, the use of a static mixer, etc. can be used with a force S.
[0072] 処理液を乳化処理する場合には、メッシュフィルター、ノズル、ホモミキサー、マイル ダー、均質機 (ホモゲナイザー)などを利用することができる。そして、これらは一般的 な操作条件や運転条件などで利用すれば良い。  [0072] When the treatment liquid is emulsified, a mesh filter, nozzle, homomixer, milder, homogenizer (homogenizer), or the like can be used. These can be used in general operating conditions and operating conditions.
[0073] 本発明のゲル状食品の製造方法においては、前記の処理液の pHが 5〜9であるこ とが望ましい。  [0073] In the method for producing a gel food according to the present invention, it is desirable that the pH of the treatment liquid is 5 to 9.
[0074] 処理液の pHがこの範囲にあると、タンパク質の変性が安定して進行するため、ゲル 状食品の組織も均一になりやすく好ましい。  [0074] When the pH of the treatment liquid is within this range, the denaturation of the protein proceeds stably, and thus the structure of the gel food is likely to be uniform.
[0075] かかる観点から、処理液の好ましい pHは 5〜9、より好ましい pHは 5· 55〜8. 5、さ らに好ましい pHは 6〜8である。  [0075] From this viewpoint, the treatment solution preferably has a pH of 5 to 9, more preferably a pH of 5.55 to 8.5, and further preferably a pH of 6 to 8.
[0076] 処理液の pHを調整する pH調整剤として具体的には、乳酸、酢酸、硫酸、塩酸、ク ェン酸、レモン汁、水酸化ナトリウム、水酸化カリウムなどを例示できる。 pH調整剤を 処理液と混合する際には、処理液を撹拌などしながら、 pH調整剤を少しずつ徐々に 添加するの力 S、タンパク質などによる凝集物が生成しにくく好ましい。 [0077] 本発明のゲル状食品の製造方法にお!/、ては、前記処理液は乳化剤、安定剤、ゲ ル化剤の少なくとも一つ以上を含むものとすることができる。 [0076] Specific examples of the pH adjuster for adjusting the pH of the treatment liquid include lactic acid, acetic acid, sulfuric acid, hydrochloric acid, citrate, lemon juice, sodium hydroxide, and potassium hydroxide. When mixing the pH adjusting agent with the treatment solution, it is preferable that the pH adjustment agent is gradually added gradually while stirring the treatment solution S, and aggregates due to proteins, proteins, etc. are difficult to form. [0077] In the method for producing a gel food of the present invention, the treatment liquid may contain at least one of an emulsifier, a stabilizer and a gelling agent.
[0078] 処理液へ乳化剤、安定剤、ゲル化剤などを添加することにより、油相と水相が分離 したり、沈殿が生じたりせず、処理液が均一に近い状態で安定化されるため、ゲル状 食品の組織も均一になりやすく好ましい。  [0078] By adding an emulsifier, a stabilizer, a gelling agent, or the like to the treatment liquid, the oil and water phases are not separated or precipitated, and the treatment liquid is stabilized in a nearly uniform state. Therefore, the structure of the gel food is preferable because it tends to be uniform.
[0079] 乳化剤として具体的には、グリセリン脂肪酸エステル、有機酸モノダリセライド、ショ 糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステ ル、レシチン、酵素分解レシチン、ポリグリセリン脂肪酸エステルなどが例示できる。  [0079] Specific examples of the emulsifier include glycerin fatty acid ester, organic acid monodallylide, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, lecithin, enzymatically decomposed lecithin, polyglycerin fatty acid ester and the like.
[0080] 安定剤として具体的には、ローカストビンガム、グァーガム、キサンタンガム、ジエラ ンガム、タラガム、アラビアガムなどが例示できる。  [0080] Specific examples of the stabilizer include locust bin gum, guar gum, xanthan gum, dielan gum, tara gum, and gum arabic.
[0081] ゲル化剤として具体的には、寒天、ぺクチン、カードランなどが例示できる。  [0081] Specific examples of the gelling agent include agar, pectin, and curdlan.
[0082] 本発明のゲル状食品の製造方法において、前記の処理液は、ホエイチーズなどの ゲル状食品の製造において従来から知られているタンパク質、糖質、ビタミン、ミネラ ル、植物性や動物性の油脂、豆乳などの大豆系の食品、果汁や果肉などの果実系 の食品、乳酸菌やビフィズス菌などの有用な微生物などを、さらに含むものとすること ができる。これらは、前記の処理液に対して添加'混合することにより前記の処理液に 含ませること力 Sできる。  [0082] In the method for producing a gel food according to the present invention, the treatment liquid is a protein, carbohydrate, vitamin, mineral, vegetable or animal that is conventionally known in the production of gel food such as whey cheese. Oil and fat, soy-based foods such as soy milk, fruit-based foods such as fruit juice and pulp, and useful microorganisms such as lactic acid bacteria and bifidobacteria. These can be added to the treatment liquid and mixed with the treatment liquid to be included in the treatment liquid.
[0083] 前記において、タンパク質の供給源 (素材)として具体的には、全脂乳、全脂濃縮 乳、全脂粉乳、脱脂乳、脱脂濃縮乳、脱脂粉乳、練乳、バターミルク、バターミルク粉 、カゼイン、カゼインカノレシゥム、カゼインナトリウムなどが例示できる。  [0083] In the above, specific examples of the protein source (material) include full-fat milk, full-fat concentrated milk, full-fat milk powder, skim milk, skim-fat concentrated milk, skim milk powder, condensed milk, butter milk, butter milk powder , Casein, casein canolecium, sodium caseinate and the like.
[0084] 脂質の供給源 (素材)として具体的には、全脂乳、全脂濃縮乳、全脂粉乳、練乳、 クリーム、バター、発酵バターなどが例示できる。  [0084] Specific examples of the lipid supply source (material) include full-fat milk, full-fat concentrated milk, full-fat powdered milk, condensed milk, cream, butter, and fermented butter.
[0085] 糖質の供給源 (素材)として具体的には、乳糖、ブドウ糖などが例示できる。  [0085] Specific examples of the sugar source (material) include lactose and glucose.
[0086] ビタミンの供給源(素材)として具体的には、ビタミン Cやビタミン Eなどの各種のビタ ミン類、果汁や果肉などの果実系の食品などが例示できる。  [0086] Specific examples of vitamin sources (materials) include various vitamins such as vitamin C and vitamin E, and fruit foods such as fruit juice and pulp.
[0087] ミネラルの供給源(素材)として具体的には、塩化ナトリウム、塩化マグネシウム、炭 酸カルシウムなどの各種の塩類などが例示できる。  [0087] Specific examples of the mineral supply source (material) include various salts such as sodium chloride, magnesium chloride, and calcium carbonate.
[0088] 本発明では、上記した添加物以外のものであってホエイチーズなどのゲル状食品 の製造において従来から知られている添加物を必要に応じて前記の処理液に配合 すること力 Sでさる。 [0088] In the present invention, gel food such as whey cheese other than the above-mentioned additives In the production of the above, a conventionally known additive is added to the above-mentioned treatment liquid as necessary, and the force S is used.
[0089] その添加物として具体的には、塩味剤、粘度調製剤、酸味料、甘味料、呈味料、酸 味調製剤、食品保存剤、穀類、豆類、野菜類、肉類、魚介類、グァニジン塩酸塩、尿 素、エチレングリコール、グリセリン、プロパノール、亜リン酸ナトリウム、ナフタレンスノレ ホン酸ナトリウム、ラウリンスルホン酸ナトリウムなどが例示できる。  [0089] Specific examples of the additive include salting agent, viscosity adjusting agent, acidulant, sweetener, flavoring agent, acidity adjusting agent, food preservative, cereals, beans, vegetables, meat, seafood, Examples thereof include guanidine hydrochloride, urea, ethylene glycol, glycerin, propanol, sodium phosphite, sodium naphthalene sulfonate and sodium laurate sulfonate.
[0090] 塩味剤としては、塩化ナトリウム (食塩)や塩化カリウムなどを例示できる。 [0090] Examples of the salting agent include sodium chloride (salt) and potassium chloride.
[0091] 粘度調製剤としては、全卵、卵黄、澱粉、ゼラチン、ガム質などを例示できる。 [0091] Examples of the viscosity adjusting agent include whole egg, egg yolk, starch, gelatin, and gum.
[0092] 酸味料としては、酢酸、乳酸、クェン酸、酒石酸、フマル酸、コハク酸、リンゴ酸、グ ルコン酸、アジピン酸、フィチン酸、ダルコノデルタラタトン、ァスコルビン酸などを例 示できる。 [0092] Examples of the acidulant include acetic acid, lactic acid, citrate, tartaric acid, fumaric acid, succinic acid, malic acid, gluconic acid, adipic acid, phytic acid, darcono delta latatane, ascorbic acid and the like.
[0093] 甘味料としては、果糖、ショ糖、糖アルコール、マンニット、ソノレビトーノレ、マルチトー ルなどを例示できる。  [0093] Examples of sweeteners include fructose, sucrose, sugar alcohol, mannitol, Sonorbitonore, and multitole.
[0094] 呈味料としては、コーヒー、抹茶、ピーナッツペースト、アーモンドペースト、香辛料 [0094] As flavoring agents, coffee, green tea, peanut paste, almond paste, spices
、カカオマス、ココアパウダー、アミノ酸、核酸などを例示できる。 , Cocoa mass, cocoa powder, amino acids, nucleic acids and the like.
[0095] 酸味調製剤としては、酸化防止剤、酢酸ナトリウム、クェン酸ナトリウム、リンゴ酸ナト リウム、酒石酸ナトリウム、コハク酸ナトリウム、フマル酸ナトリウムなどを例示できる。 [0095] Examples of sourness preparation agents include antioxidants, sodium acetate, sodium citrate, sodium malate, sodium tartrate, sodium succinate, and sodium fumarate.
[0096] 食品保存としては、色素剤、ソルビン酸、ソルビン酸カリウム、ソルビン酸ナトリウム、 エチルアルコールなどを例示できる。 [0096] Examples of food preservation include coloring agents, sorbic acid, potassium sorbate, sodium sorbate, and ethyl alcohol.
[0097] これらを単独もしくは混合して、本発明の目的に反しない範囲内で配合することが できる。 [0097] These may be used alone or in admixture within a range not departing from the object of the present invention.
[0098] 本発明のゲル状食品の製造方法にお!/、ては、一段階目の処理時間及び二段階目 の処理時間がいずれも 30分以内であることが望ましい。本発明の二段階の加熱処 理による食感や風味の改善効果を十分に発揮させ、その一方で、ゲル状食品のより 良!/、生産効率を維持する上で、この範囲の加熱処理時間であることが好まし!/、から である。  [0098] In the method for producing a gel food according to the present invention, it is desirable that both the first stage treatment time and the second stage treatment time be within 30 minutes. The heat treatment time within this range is sufficient to improve the texture and flavor of the two-stage heat treatment of the present invention while maintaining better gel-like foods and production efficiency. It is preferred to be! /, From.
[0099] なお、かかる観点より、一段階目及び二段階目の処理時間は!/、ずれも 30分以内で あること力 S好ましく、より好ましくは一段階目 ·二段階目とも 20分以内、さらに好ましく は一段階目 ·二段階目とも 15分以内である。 [0099] From this point of view, the processing time of the first stage and the second stage is! /, And the deviation should be within 30 minutes. S is preferable, more preferably within 20 minutes for both the first stage and the second stage. More preferred The first and second stages are within 15 minutes.
[0100] なお、本発明にお!/、て、一段階目 ·二段階目の加熱処理時間とは、一段階目や二 段階目の加熱処理において、加熱処理される処理液や、加熱処理される処理液が 収容されているタンクなどの収容容器や、処理液が充填 '密封されている容器の一部 力 当該加熱処理において目標としている所定の温度に達してからの経過時間のこ とをいう。 [0100] In the present invention, the first-stage / second-stage heat treatment time is the treatment liquid to be heat-treated in the first-stage or second-stage heat treatment, or the heat treatment. The capacity of a container such as a tank that contains the processing liquid to be processed, or a part of the container that is filled and sealed with the processing liquid. The elapsed time after the target temperature is reached in the heat treatment. Say.
[0101] 本発明においては、一段階目では、処理液の全体がほぼ均一な温度で 65〜75°C 、より好ましくは 70〜75°C、さらに好ましくは 70〜73°Cになるように保持している。ま た、二段階目では、処理液の全体がほぼ均一な温度で 90°C以下であって 75°Cを超 える温度、より好ましくは 80°C〜90°C、さらに好ましくは 80〜85°Cになるように保持 している。そして、一段階目及び二段階目の処理時間を好ましくは、いずれも 30分 以内、より好ましくは、いずれも 20分以内、さらに好ましくは、いずれも 15分以内にし ている。これらの条件の制御は、例えば、処理液の容量、処理液の組成、処理液を 収容する容器の容量'寸法 '形状'材質、処理液が充填、密封される容器の容量 '寸 法-形状 ·材質などの中の少なくとも 1つ以上を調整することにより行うことができる。  [0101] In the present invention, in the first stage, the entire treatment solution is at a substantially uniform temperature of 65 to 75 ° C, more preferably 70 to 75 ° C, and even more preferably 70 to 73 ° C. keeping. In the second stage, the entire treatment liquid is at a substantially uniform temperature of 90 ° C or lower and higher than 75 ° C, more preferably 80 ° C to 90 ° C, still more preferably 80 to 85 ° C. Holds to ° C. The treatment time for the first stage and the second stage is preferably 30 minutes or less, more preferably 20 minutes or less, and still more preferably 15 minutes or less. Control of these conditions includes, for example, the volume of the processing liquid, the composition of the processing liquid, the volume of the container that holds the processing liquid 'dimension' material, and the volume of the container that is filled and sealed with the processing liquid 'dimension-shape' · This can be done by adjusting at least one of the materials.
[0102] 本発明のゲル状食品の製造方法においては、処理液を容器に充填し密封した後 に加熱処理することができる。  [0102] In the method for producing a gel food of the present invention, the treatment liquid can be heat-treated after being filled in a container and sealed.
[0103] この場合には、一段階目の加熱処理、二段階目の加熱処理とも間接加熱が好まし い。  [0103] In this case, indirect heating is preferred for both the first stage heat treatment and the second stage heat treatment.
[0104] 処理液を容器などへ充填し密封した後に、容器の外部から間接的に加熱処理する ことにより、品質の経時的な劣化が少なぐ賞味期限が比較的長ぐ長期の保存が可 能で衛生的なゲル状食品を得ることができる。  [0104] After the treatment liquid is filled into a container and sealed, heat treatment is performed indirectly from the outside of the container, so that the shelf life is relatively long and the shelf life is relatively long. A hygienic gel food can be obtained.
[0105] 本発明によれば、二段階の加熱条件で加熱処理し、また、処理液の全体がほぼ均 一な温度で 65〜75°Cになるように保持し(一段階目)、処理液の全体がほぼ均一な 温度で 90°C以下であって 75°Cを超える温度になるように保持して!/、る(二段階目 )。 すなわち、二段階の加熱条件で加熱処理し、処理液を収容している容器の外部から 間接的に加熱処理して処理液を加熱する場合には、容器の内部における中心部の ように、処理液の中で最も熱が伝わりにくい部分の温度が前記の所定の温度範囲に なるように、処理液に加熱処理を加えて処理液全体の温度を保持している。 [0105] According to the present invention, heat treatment is performed under two-stage heating conditions, and the entire treatment liquid is maintained at 65 to 75 ° C at a substantially uniform temperature (first stage). Hold the whole liquid at a nearly uniform temperature, 90 ° C or lower and higher than 75 ° C (second stage). That is, when heat treatment is performed under two-stage heating conditions, and the heat treatment liquid is heated indirectly from the outside of the container containing the treatment liquid, the treatment is performed as in the central part inside the container. The temperature of the part of the liquid where heat is most difficult to transfer is within the predetermined temperature range. Thus, the temperature of the entire processing liquid is maintained by applying heat treatment to the processing liquid.
[0106] そこで、処理液を容器に充填し密封した後に、容器の外部から間接的に加熱処理 しても、容器の内部における中心部と縁周辺部とが均一に近い食感や風味となるゲ ル状食品を得ることができる。 [0106] Therefore, even if the processing liquid is filled in the container and sealed, and then indirectly heated from the outside of the container, the center and the peripheral edge of the inside of the container have a nearly uniform texture and flavor. Gel-like food can be obtained.
[0107] 前記のように、処理液を容器に充填し密封した後に加熱処理する場合には、前記 容器の容量は 50ml (ミリリットル)乃至 150ml (ミリリットル)にすることができる。 [0107] As described above, when the heat treatment is performed after filling the container with the treatment liquid and sealing, the capacity of the container can be 50 ml (milliliter) to 150 ml (milliliter).
[0108] 処理液や容器の容量が 50ml (ミリリットル)よりも小さいと、二段階の加熱処理による 食感や風味の改善効果が小さくなる。一方、処理液や容器の容量が 150ml (ミリリット ノレ)よりも大き!/、と、処理時間が長めになるので好ましくなレ、。 [0108] If the volume of the treatment liquid or the container is smaller than 50 ml (milliliter), the effect of improving the texture and flavor by the two-stage heat treatment becomes small. On the other hand, the volume of the processing solution and the container is larger than 150 ml (millilitre)! /, Which is preferable because the processing time becomes longer.
[0109] なお、容器の形状 ·形態として、具体的には、カップ状の容器や、レトルト用の袋状 などを例示できる。 [0109] Specific examples of the shape and form of the container include a cup-shaped container and a bag shape for retort.
[0110] また、この場合、前記容器の材質はプラスチック製とすることができる。  [0110] In this case, the material of the container may be made of plastic.
[0111] 本発明のゲル状食品の製造方法において、前記のゲル状食品はホエイチーズとす ること力 Sできる。ホエイチーズは「Codex規格」に記載されたものなどが例示できる。  [0111] In the method for producing a gel food of the present invention, the gel food can be used as whey cheese. Examples of whey cheese include those described in the “Codex standard”.
[0112] 以下、本発明に関して実施例を挙げて説明するが、本発明は、これにより限定され るものではない。 Hereinafter, the present invention will be described with reference to examples, but the present invention is not limited thereto.
実施例 1  Example 1
[0113] (ホエイチーズの製造 1) [0113] (Manufacture of whey cheese 1)
ホエイパウダー(明治乳業 (株)製) 8· lg、ホエイタンパク分離物 (WPI) 5. 2g、生タリ ーム 13. 5g、水道水 83. 2gをタンク内で撹拌しながら、常温で溶解した後に、クェン 酸を少しずつ添加し、処理液の pHを 6に調整した。  Whey powder (Meiji Dairies Co., Ltd.) 8 · lg, whey protein isolate (WPI) 5.2 g, raw tarium 13.5 g, tap water 83.2 g dissolved at room temperature while stirring in the tank Later, citrate was added little by little to adjust the pH of the treatment solution to 6.
[0114] この処理液では、ホエイタンパク質の水中濃度は約 6. 7重量%、ホエイタンパク質 に対する脂肪の重量比は約 1. 1倍であった。 [0114] In this treatment solution, the concentration of whey protein in water was about 6.7% by weight, and the weight ratio of fat to whey protein was about 1.1 times.
[0115] この処理液 110gを容量 150mlのプラスチック製のカップへ充填した後に、温度 75[0115] After filling 110 g of this processing solution into a 150 ml capacity plastic cup, the temperature is 75.
°Cの熱水に 10分間、さらに温度 80°Cの熱水に 20分間、それぞれ浸漬して保持した Immerse and hold in hot water at ° C for 10 minutes and further in hot water at 80 ° C for 20 minutes.
[0116] そして、温度 10°C以下に冷却して最終製品(ゲル状食品)を得た。 [0116] The final product (gel food) was obtained by cooling to a temperature of 10 ° C or lower.
実施例 2 [0117] (ホエイチーズの製造 2) Example 2 [0117] (Manufacture of whey cheese 2)
ホエイパウダー(明治乳業 (株)製) 8· 0g、ホエイタンパク分離物 (WPI) 5. 4g、生タリ ーム 39. 2g、水道水 57. 5gをタンク内で撹拌しながら、常温で溶解した後に、クェン 酸を少しずつ添加し、処理液の pHを 6に調整した。  Whey powder (Meiji Dairies Co., Ltd.) 8.0g, whey protein isolate (WPI) 5.4g, fresh tarium 39.2g, tap water 57.5g dissolved in the tank at room temperature Later, citrate was added little by little to adjust the pH of the treatment solution to 6.
[0118] この処理液では、ホエイタンパク質の水中濃度は約 8. 5重量%、ホエイタンパク質 に対する脂肪の重量比は約 2. 8倍であった。この処理液 110gを容量 150mlのプラ スチック製のカップへ充填した後に、温度 75°Cの熱水に 10分間、さらに温度 80°Cの 熱水に 20分間、それぞれ浸漬して保持した。 [0118] In this treatment solution, the concentration of whey protein in water was about 8.5% by weight, and the weight ratio of fat to whey protein was about 2.8 times. After 110 g of this treatment solution was filled into a 150 ml plastic cup, it was immersed and held in hot water at a temperature of 75 ° C. for 10 minutes and further in hot water at a temperature of 80 ° C. for 20 minutes.
[0119] そして、温度 10°C以下に冷却して最終製品(ゲル状食品)を得た。 [0119] Then, it was cooled to a temperature of 10 ° C or lower to obtain a final product (gel food).
[0120] (比較例 1) (ホエイチーズの試作 1) [0120] (Comparative Example 1) (Prototype of whey cheese 1)
ホエイパウダー(明治乳業 (株)製) 8· lg、ホエイタンパク分離物 (WPI) 5. 2g、生タリ ーム 13. 5g、水道水 83. 2gをタンク内で撹拌しながら、常温で溶解した後に、クェン 酸を少しずつ添加し、処理液の pHを 6に調整した。  Whey powder (Meiji Dairies Co., Ltd.) 8 · lg, whey protein isolate (WPI) 5.2 g, raw tarium 13.5 g, tap water 83.2 g dissolved at room temperature while stirring in the tank Later, citrate was added little by little to adjust the pH of the treatment solution to 6.
[0121] この処理液では、ホエイタンパク質の水中濃度は約 6. 7重量%、ホエイタンパク質 に対する脂肪の重量比は約 1. 1倍であった。 [0121] In this treatment solution, the concentration of whey protein in water was about 6.7% by weight, and the weight ratio of fat to whey protein was about 1.1 times.
[0122] この処理液 110gを容量 150mlのプラスチック製のカップへ充填した後に、温度 80[0122] After 110 g of this treatment solution was filled into a 150 ml plastic cup, the temperature was 80
°Cの熱水に 30分間、浸漬して保持した。 It was immersed and kept in hot water at ° C for 30 minutes.
[0123] そして、温度 10°C以下に冷却して最終製品(ゲル状食品)を得た。 [0123] Then, the product was cooled to a temperature of 10 ° C or lower to obtain a final product (gel food).
[0124] (評価 1) (官能検査) [0124] (Evaluation 1) (Sensory test)
実施例 1、実施例 2、比較例 1で得たゲル状食品について、専門パネラーの 5名に より官能検査を実施した。評価した項目は表 1に示した通り、離水、外観、食感、風味 とした。各項目は評点法により評価し、「良い」 = 5点、「やや良い」 =4点、「普通」 = 3 点、「やや悪い」 = 2点、「悪い」 = 1点の 5段階とした。  The gel foods obtained in Example 1, Example 2 and Comparative Example 1 were subjected to a sensory test by five specialized panelists. The items evaluated were water separation, appearance, texture and flavor as shown in Table 1. Each item is evaluated by a scoring method, with 5 levels of “good” = 5 points, “slightly good” = 4 points, “normal” = 3 points, “slightly bad” = 2 points, and “bad” = 1 point. .
[0125] 温度 75°Cの予備加熱と温度 80°Cの最終加熱の二段階で加熱処理した実施例 1と 実施例 2が、温度 80°Cの一段階で加熱処理した比較例 1よりも全体的に良!/、評価で あった。特に食感の項目では、実施例 1と実施例 2が比較例 1よりも明らかに良い評 価であった。 [0125] Example 1 and Example 2 in which heat treatment was performed in two stages of preheating at a temperature of 75 ° C and final heating at a temperature of 80 ° C were compared to Comparative Example 1 in which heat treatment was performed in one step at a temperature of 80 ° C Overall it was good! In particular, in terms of texture, Example 1 and Example 2 were clearly better than Comparative Example 1.
[表 1] 官能検査結果 [table 1] Sensory test results
項目 離水 外観 食感 風味  Item Water separation Appearance Texture Flavor
実施例 1 3.8 3.6 4.2 3.8  Example 1 3.8 3.6 4.2 3.8
実施例 2 4.0 3.6 4.4 4.4  Example 2 4.0 3.6 4.4 4.4
比較例 1 3.8 3.4 2.4 3.4  Comparative Example 1 3.8 3.4 2.4 3.4
[0126] (評価 2) (細菌検査) [0126] (Evaluation 2) (Bacteria test)
実施例 1で得たゲル状食品と、一般に販売されて!、るホエイチーズである市販品 A A gel-like food obtained in Example 1 and a commercially available product that is generally sold!
、市販品 Bについて、細菌検査 (保存試験)を実施した。 Bacterial test (storage test) was conducted on commercial product B.
[0127] 評価した項目は表 2に示した通り、生菌数、嫌気性菌数とし、それぞれの選択培地 は標準寒天培地(SMA培地)と GAM培地(二ッスィ社製)とした。 [0127] As shown in Table 2, the evaluated items were the viable cell count and anaerobic cell count, and the selective media were standard agar medium (SMA medium) and GAM medium (manufactured by Nissy).
[0128] 本発明品の実施例 1では生菌が検出限界値以下であつたのに対し、巿販品 Aゃ巿 販品 Bでは生菌が検出された。 [0128] In Example 1 of the product of the present invention, live bacteria were below the detection limit value, whereas in the commercial products A and B, live bacteria were detected.
[0129] 本発明品は製造ョ力、ら 4ヶ月を経過しても生菌数の増加は見られず、市販品 Aや 市販品 Bよりも賞味期限の長いことが実証された。なお、市販品 Aや市販品 Bの賞味 期限は製造日から 21日間に設定されていた。 [0129] The product of the present invention did not show an increase in the number of viable bacteria even after 4 months, and it was proved that the shelf life was longer than that of the commercial products A and B. The shelf life of commercial products A and B was set to 21 days from the date of manufacture.
[表 2]  [Table 2]
表 2. 細菌検査結果  Table 2. Bacteria test results
項目 (検査条件) 生菌数 嫌気性菌数 実施例 1 (製造日から 12()曰後) く 10 < 10  Item (Test conditions) Viable count Anaerobic count Example 1 (after 12 () after production date) 10 <10
市販品 A (製造日から 10日後) 1.0 10Γ) 4.4 X 104 市販品 B (製造日から 8曰後) 3.6 105 1.2 X 10 ' Commercial product A (10 days after production date) 1.0 10 Γ) 4.4 X 10 4 Commercial product B (8 days after production date) 3.6 10 5 1.2 X 10 '
[0130] (評価 3) (顕微鏡の写真撮影) [0130] (Evaluation 3) (Microscope photography)
実施例 1で得たゲル状食品と、一般に販売されて!、るホエイチーズである市販品 A について、実体顕微鏡 (倍率 25倍)による写真撮影を実施した。写真撮影した映像 は図 1 (本発明品)と図 2 (市販品 A)に示した通りである。本発明品の実施例 1では滑 らかな組織であつたのに対し、市販品 Aではザラつ!/、た組織であった。  The gel-like food obtained in Example 1 and commercially available product A, which is commercially available whey cheese, were photographed with a stereomicroscope (25 times magnification). The images taken are shown in Fig. 1 (invention product) and Fig. 2 (commercial product A). In Example 1 of the product of the present invention, the structure was smooth, whereas in the commercial product A, the structure was rough.
産業上の利用可能性 [0131] 本発明によれば、組織が脆くなぐ舌触りが糊っぽくなぐ澱粉っぽくない、 口当たり と舌触りが滑らかで離水が少なぐ食感や風味の良好なホエイチーズなどのゲル状 食品の製造方法を提供することができる。 Industrial applicability [0131] According to the present invention, the production of gel-like foods such as whey cheese having a texture and a good taste with a smooth texture and a smooth mouthfeel and low water separation, is not starchy, and the texture is brittle. A method can be provided.
[0132] また、処理液をカップ状の容器などへ充填し密封した後に、容器の外部から間接的 に加熱処理しても、容器の内部における中心部と縁周辺部とが均一に近い食感や風 味となるゲル状食品の製造方法を提供することができる。 [0132] In addition, even when the treatment liquid is filled into a cup-shaped container and sealed and then heat-treated indirectly from the outside of the container, the central portion and the peripheral edge of the inside of the container are almost uniform in texture. It is possible to provide a method for producing a gel-like food that can be used as a flavor.
図面の簡単な説明  Brief Description of Drawings
[0133] [図 1]本発明品の表面を実体顕微鏡で写真撮影した顕微鏡写真 (倍率 25倍)。  [0133] [FIG. 1] A photomicrograph of the surface of the product of the present invention taken with a stereomicroscope (25x magnification).
[図 2]市販品の表面を実体顕微鏡で写真撮影した顕微鏡写真 (倍率 25倍)。  [Fig. 2] Photomicrograph of the surface of a commercial product taken with a stereomicroscope (25x magnification).

Claims

請求の範囲 The scope of the claims
[1] ホエイタンパク質と脂肪分とを含み、ホエイタンパク質の濃度が 4〜; 12重量%、脂肪 分のホエイタンパク質に対する重量比が 5倍以下である処理液を、二段階の加熱条 件により加熱処理してゲル状食品を製造する方法であって、  [1] A treatment solution containing whey protein and fat, with a whey protein concentration of 4 to; 12% by weight and a weight ratio of fat to whey protein of 5 times or less is heated under two-stage heating conditions. A method for producing a gel food by processing,
二段階の加熱条件の一段階目では、加熱温度を 65〜75°Cとして前記処理液の全 体がほぼ均一な温度で 65〜75°Cになるように保持し、  In the first stage of the two-stage heating conditions, the heating temperature is set to 65 to 75 ° C, and the whole treatment liquid is held at 65 to 75 ° C at a substantially uniform temperature.
二段階の加熱条件の二段階目では、加熱温度を 90°C以下であって 75°Cを超える 温度として前記処理液の全体がほぼ均一な温度で 90°C以下であって 75°Cを超える 温度になるように保持する  In the second stage of the two-stage heating conditions, the heating temperature is 90 ° C or lower and exceeds 75 ° C, and the entire treatment liquid is almost uniform at 90 ° C or lower and 75 ° C. Hold at a temperature exceeding
ことを特徴とするゲル状食品の製造方法。  A method for producing a gel food characterized by the above.
[2] 前記処理液に対して加熱処理する前に前記処理液を乳化処理することを特徴とす る請求項 1記載のゲル状食品の製造方法。 [2] The method for producing a gelled food according to claim 1, wherein the treatment liquid is emulsified before the treatment liquid is heat-treated.
[3] 前記処理液の pHが 5〜9であることを特徴とする請求項 1又は 2記載のゲル状食品 の製造方法。 [3] The method for producing a gelled food according to claim 1 or 2, wherein the pH of the treatment liquid is 5 to 9.
[4] 前記処理液は乳化剤、安定剤、ゲル化剤の少なくとも一つ以上を含むことを特徴と する請求項 1乃至 3のいずれか一項記載のゲル状食品の製造方法。  [4] The method for producing a gelled food according to any one of [1] to [3], wherein the treatment liquid contains at least one of an emulsifier, a stabilizer, and a gelling agent.
[5] 一段階目の加熱処理時間及び二段階目の加熱処理時間が!/、ずれも 30分以内で あることを特徴とする請求項 1乃至 4のいずれか一項記載のゲル状食品の製造方法 [5] The heat treatment time of the first stage and the heat treatment time of the second stage are! /, And the deviation is within 30 minutes, The gel food according to any one of claims 1 to 4, Production method
Yes
[6] 前記処理液を容器に充填し密封した後に加熱処理することを特徴とする請求項 1 乃至 5のいずれか一項記載のゲル状食品の製造方法。  [6] The method for producing a gel food according to any one of [1] to [5], wherein the container is filled with the treatment liquid and sealed, followed by heat treatment.
[7] 前記容器の容量が 50ml乃至 150mlであることを特徴とする請求項 6記載のゲル状 食品の製造方法。 7. The method for producing a gel food according to claim 6, wherein the container has a capacity of 50 ml to 150 ml.
[8] 前記容器の材質がプラスチック製であることを特徴とする請求項 6又は 7記載のゲ ル状食品の製造方法。  [8] The method for producing a gel food according to claim 6 or 7, wherein the container is made of plastic.
[9] 前記ゲル状食品がホエイチーズであることを特徴とする請求項 1乃至 8のいずれか 一項記載のゲル状食品の製造方法。  [9] The method for producing a gel food according to any one of claims 1 to 8, wherein the gel food is whey cheese.
[10] 請求項 1〜8のいずれか一項に記載の製造方法を用いて製造したゲル状食品。 [11] 請求項 1〜8のいずれか一項に記載の製造方法を用いて製造したホエイチーズ。 [10] A gel-like food produced using the production method according to any one of claims 1 to 8. [11] Whey cheese manufactured using the manufacturing method according to any one of claims 1 to 8.
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