WO2008015323A3 - Catalyseur a base d' un support hybride organique - inorganique et son utilisation en hydroraffinage et hydroconversion - Google Patents

Catalyseur a base d' un support hybride organique - inorganique et son utilisation en hydroraffinage et hydroconversion Download PDF

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Publication number
WO2008015323A3
WO2008015323A3 PCT/FR2007/001169 FR2007001169W WO2008015323A3 WO 2008015323 A3 WO2008015323 A3 WO 2008015323A3 FR 2007001169 W FR2007001169 W FR 2007001169W WO 2008015323 A3 WO2008015323 A3 WO 2008015323A3
Authority
WO
WIPO (PCT)
Prior art keywords
organic
hydrorefining
inorganic hybrid
group
hydroconversion
Prior art date
Application number
PCT/FR2007/001169
Other languages
English (en)
Other versions
WO2008015323A2 (fr
Inventor
Alexandra Chaumonnot
Denis Guillaume
Benoit Fremon
Karin Marchand
Renaud Revel
Original Assignee
I F P
Alexandra Chaumonnot
Denis Guillaume
Benoit Fremon
Karin Marchand
Renaud Revel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by I F P, Alexandra Chaumonnot, Denis Guillaume, Benoit Fremon, Karin Marchand, Renaud Revel filed Critical I F P
Priority to US12/375,757 priority Critical patent/US8435912B2/en
Publication of WO2008015323A2 publication Critical patent/WO2008015323A2/fr
Publication of WO2008015323A3 publication Critical patent/WO2008015323A3/fr

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255Phosphorus containing compounds
    • B01J31/0269Phosphorus containing compounds on mineral substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20Vanadium, niobium or tantalum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/882Molybdenum and cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12Silica and alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20Sulfiding

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

On décrit un catalyseur supporté et sulfuré comprenant : - un support poreux constitué d'un matériau hybride organique-inorganique pour lequel la liaison covalente entre les phases organique et inorganique répond à la formule M-O-Z-R où M représente au moins un métal constitutif de la phase inorganique, Z au moins un hétéroélément parmi le phosphore et le silicium et R un fragment organique, - au moins un métal du groupe VIB et/ou du groupe VB et/ou du groupe VIII. L'invention porte également sur l'utilisation de ce catalyseur pour l'hydroraffinage e l'hydroconversion de charges hydrocarbonées telles que les coupes pétrolières, les coupe issues du charbon ou de la biomasse ou les hydrocarbures produits à partir du gaz naturel.
PCT/FR2007/001169 2006-07-31 2007-07-06 Catalyseur a base d' un support hybride organique - inorganique et son utilisation en hydroraffinage et hydroconversion WO2008015323A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/375,757 US8435912B2 (en) 2006-07-31 2007-07-06 Catalyst based on an organic-inorganic hybrid support and its use in hydrorefining and hydroconversion

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0607048 2006-07-31
FR0607048A FR2904243B1 (fr) 2006-07-31 2006-07-31 Catalyseur a base d'un support hybride organique - inorganique et son utilisation en hydroraffinage et hydroconversion

Publications (2)

Publication Number Publication Date
WO2008015323A2 WO2008015323A2 (fr) 2008-02-07
WO2008015323A3 true WO2008015323A3 (fr) 2008-03-13

Family

ID=37794473

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2007/001169 WO2008015323A2 (fr) 2006-07-31 2007-07-06 Catalyseur a base d' un support hybride organique - inorganique et son utilisation en hydroraffinage et hydroconversion

Country Status (3)

Country Link
US (1) US8435912B2 (fr)
FR (1) FR2904243B1 (fr)
WO (1) WO2008015323A2 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2931475B1 (fr) * 2008-05-23 2010-06-04 Inst Francais Du Petrole Procede de craquage d'ethers alkyl tertiaires utilisant un materiau hybride organique-inorganique mesostructure.
RU2495082C2 (ru) * 2008-09-10 2013-10-10 Хальдор Топсеэ А/С Способ и катализатор гидропереработки
US8940660B2 (en) * 2008-12-04 2015-01-27 Uop Llc Simultaneous warm gas desulfurization and complete CO-shift for improved syngas cleanup
KR20120082697A (ko) * 2011-01-14 2012-07-24 삼성전자주식회사 Co2 개질용 촉매 조성물
FR2977890B1 (fr) * 2011-07-15 2013-07-19 IFP Energies Nouvelles Procede de metathese des olefines utilisant un catalyseur a base d'un materiau spherique comprenant des particules metalliques oxydes piegees dans une matrice mesostructuree
US9567265B2 (en) * 2012-11-30 2017-02-14 Iowa State University Research Foundation, Inc. Catalysts and methods of using the same
US9556088B2 (en) 2012-11-30 2017-01-31 Iowa State University Research Foundation, Inc. Adsorbent catalytic nanoparticles and methods of using the same
CN114433120B (zh) * 2022-02-28 2024-06-28 中国刑事警察学院 一种脱硫催化剂及其制备方法和应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4064154A (en) * 1975-11-06 1977-12-20 Dow Corning Corporation Catalysts and carriers therefor
EP0848992A1 (fr) * 1996-12-17 1998-06-24 Institut Francais Du Petrole Catalyseur contenant du bore et du silicium et son utilisation en hydrotraitement de charges hydrocarbonées
EP1579909A1 (fr) * 2004-03-23 2005-09-28 Institut Français du Pétrole Catalyseur supporté de forme shpérique dopé et procédé d'hydrotraitement et d'hydroconversion de fractions pétrolières contenant des métaux
DE102004039277A1 (de) * 2004-08-13 2006-02-23 Merck Patent Gmbh Am Zentralatom substituierte, immoblisierbare Ruthenium(II)-Katalysatoren, Verfahren zu deren Herstellung und Verwendung

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5856609A (en) * 1996-09-12 1999-01-05 Phillips Petroleum Company Aromatic hydrodealkylation process with sulfur oxide containing catalyst
DE10201241A1 (de) * 2002-01-15 2003-07-24 Bayer Ag Katalysator

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4064154A (en) * 1975-11-06 1977-12-20 Dow Corning Corporation Catalysts and carriers therefor
EP0848992A1 (fr) * 1996-12-17 1998-06-24 Institut Francais Du Petrole Catalyseur contenant du bore et du silicium et son utilisation en hydrotraitement de charges hydrocarbonées
EP1579909A1 (fr) * 2004-03-23 2005-09-28 Institut Français du Pétrole Catalyseur supporté de forme shpérique dopé et procédé d'hydrotraitement et d'hydroconversion de fractions pétrolières contenant des métaux
DE102004039277A1 (de) * 2004-08-13 2006-02-23 Merck Patent Gmbh Am Zentralatom substituierte, immoblisierbare Ruthenium(II)-Katalysatoren, Verfahren zu deren Herstellung und Verwendung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
FRANTZ R ET AL: "Triisopropoxysilyl-functionalized oxide nanoparticles using a di-tert-butyl phosphonate ester as the surface grafting agent", TETRAHEDRON LETTERS, ELSEVIER, AMSTERDAM, NL, vol. 45, no. 14, 29 March 2004 (2004-03-29), pages 2935 - 2937, XP004495683, ISSN: 0040-4039 *

Also Published As

Publication number Publication date
WO2008015323A2 (fr) 2008-02-07
FR2904243B1 (fr) 2008-10-31
US8435912B2 (en) 2013-05-07
FR2904243A1 (fr) 2008-02-01
US20100133147A1 (en) 2010-06-03

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