WO2007146453A3 - Fluoride ion electrochemical cell - Google Patents

Fluoride ion electrochemical cell Download PDF

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Publication number
WO2007146453A3
WO2007146453A3 PCT/US2007/063170 US2007063170W WO2007146453A3 WO 2007146453 A3 WO2007146453 A3 WO 2007146453A3 US 2007063170 W US2007063170 W US 2007063170W WO 2007146453 A3 WO2007146453 A3 WO 2007146453A3
Authority
WO
WIPO (PCT)
Prior art keywords
electrochemical cells
present
lithium ion
lithium
cells
Prior art date
Application number
PCT/US2007/063170
Other languages
French (fr)
Other versions
WO2007146453A2 (en
Inventor
Rachid Yazami
Original Assignee
California Inst Of Techn
Centre Nat Rech Scient
Rachid Yazami
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/560,570 external-priority patent/US7794880B2/en
Priority claimed from US11/675,308 external-priority patent/US20070218364A1/en
Priority claimed from US11/677,541 external-priority patent/US8232007B2/en
Application filed by California Inst Of Techn, Centre Nat Rech Scient, Rachid Yazami filed Critical California Inst Of Techn
Priority to JP2008558474A priority Critical patent/JP5615497B2/en
Priority to KR1020147021630A priority patent/KR20140105871A/en
Priority to KR1020087024135A priority patent/KR101503759B1/en
Priority to CN2007800076827A priority patent/CN101467287B/en
Publication of WO2007146453A2 publication Critical patent/WO2007146453A2/en
Publication of WO2007146453A3 publication Critical patent/WO2007146453A3/en

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/604—Polymers containing aliphatic main chain polymers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/20—Graphite
    • C01B32/21—After-treatment
    • C01B32/22—Intercalation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/582—Halogenides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/5835—Comprising fluorine or fluoride salts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/606—Polymers containing aromatic main chain polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/606—Polymers containing aromatic main chain polymers
    • H01M4/608—Polymers containing aromatic main chain polymers containing heterocyclic rings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/04—Cells with aqueous electrolyte
    • H01M6/045—Cells with aqueous electrolyte characterised by aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
    • H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
    • H01M6/166—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte by the solute
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0002—Aqueous electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/04—Cells with aqueous electrolyte
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

The present invention provides electrochemical cells capable of good electronic performance, particularly high specific energies, useful discharge rate capabilities and good cycle life. Electrochemical cells of the present invention are versatile and include primary and secondary cells useful for a range of important applications including use in portable electronic devices. Electrochemical cells of the present invention also exhibit enhanced safety and stability relative to conventional state of the art primary lithium batteries and lithium ion secondary batteries. For example, electrochemical cells of the present invention include secondary electrochemical cells using anion charge carriers capable of accommodation by positive and negative electrodes comprising anion host materials, which entirely eliminate the need for metallic lithium or dissolved lithium ion in these systems.
PCT/US2007/063170 2006-03-03 2007-03-02 Fluoride ion electrochemical cell WO2007146453A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2008558474A JP5615497B2 (en) 2006-03-03 2007-03-02 Fluoride ion electrochemical cell
KR1020147021630A KR20140105871A (en) 2006-03-03 2007-03-02 Fluoride ion electrochemical cell
KR1020087024135A KR101503759B1 (en) 2006-03-03 2007-03-02 fluoride ion electrochemical cell
CN2007800076827A CN101467287B (en) 2006-03-03 2007-03-02 Fluoride ion electrochemical cell

Applications Claiming Priority (12)

Application Number Priority Date Filing Date Title
US77905406P 2006-03-03 2006-03-03
US60/779,054 2006-03-03
US11/560,570 2006-11-16
US11/560,570 US7794880B2 (en) 2005-11-16 2006-11-16 Fluorination of multi-layered carbon nanomaterials
US89731007P 2007-01-25 2007-01-25
US60/897,310 2007-01-25
US90040907P 2007-02-09 2007-02-09
US60/900,409 2007-02-09
US11/675,308 US20070218364A1 (en) 2005-10-05 2007-02-15 Low temperature electrochemical cell
US11/675,308 2007-02-15
US11/677,541 US8232007B2 (en) 2005-10-05 2007-02-21 Electrochemistry of carbon subfluorides
US11/677,541 2007-02-21

Publications (2)

Publication Number Publication Date
WO2007146453A2 WO2007146453A2 (en) 2007-12-21
WO2007146453A3 true WO2007146453A3 (en) 2008-11-13

Family

ID=38832583

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/063170 WO2007146453A2 (en) 2006-03-03 2007-03-02 Fluoride ion electrochemical cell

Country Status (4)

Country Link
JP (1) JP5876848B2 (en)
KR (1) KR20140105871A (en)
CN (1) CN101467287B (en)
WO (1) WO2007146453A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8968921B2 (en) 2005-10-05 2015-03-03 California Institute Of Technology Fluoride ion electrochemical cell

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JP5913114B2 (en) 2009-11-09 2016-04-27 ラトガース，ザ ステート ユニバーシティー オブ ニュージャージー Metal fluoride compositions for self-forming batteries
WO2011072166A1 (en) * 2009-12-11 2011-06-16 Contour Energy Systems, Inc. Fluoride ion battery electrolyte compositions
KR20140025330A (en) * 2010-12-22 2014-03-04 콘투어 에너지 시스템즈, 인크. Fluoride ion battery compositions
WO2012088691A1 (en) * 2010-12-30 2012-07-05 海洋王照明科技股份有限公司 Conductive polymer materials and preparing method and uses thereof
CN102558856B (en) * 2011-12-21 2014-06-04 天津大学 Polyaniline/graphite fluoride composite material and preparation method thereof
JP6087841B2 (en) 2012-04-16 2017-03-01 パナソニック株式会社 Electrochemical energy storage device, active material used therefor, and manufacturing method thereof
US9692039B2 (en) 2012-07-24 2017-06-27 Quantumscape Corporation Nanostructured materials for electrochemical conversion reactions
US9048497B2 (en) 2012-10-05 2015-06-02 Rutgers, The State University Of New Jersey Metal fluoride compositions for self formed batteries
AU2014244131C1 (en) * 2013-03-13 2018-12-13 Nantenergy, Inc. Synergistic additives for electrochemical cells with electrodeposited fuel
DE112014005912T5 (en) 2013-12-18 2016-09-08 Kyoto University A method for producing fluoride ion conductive electrolyte solution and method for manufacturing fluoride ion battery
JP6250879B2 (en) 2013-12-26 2017-12-20 国立大学法人京都大学 Secondary battery
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JP6046655B2 (en) 2014-03-28 2016-12-21 トヨタ自動車株式会社 Electrolyte for fluoride ion battery and fluoride ion battery
JP6285264B2 (en) * 2014-04-17 2018-02-28 トヨタ自動車株式会社 Electrolyte for fluoride ion battery and fluoride ion battery
JP6285263B2 (en) * 2014-04-17 2018-02-28 トヨタ自動車株式会社 Electrolyte for fluoride ion battery and fluoride ion battery
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US11177512B2 (en) 2016-12-15 2021-11-16 Honda Motor Co., Ltd. Barium-doped composite electrode materials for fluoride-ion electrochemical cells
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JP6827232B2 (en) * 2016-03-31 2021-02-10 公立大学法人大阪 Water-based secondary battery
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8968921B2 (en) 2005-10-05 2015-03-03 California Institute Of Technology Fluoride ion electrochemical cell

Also Published As

Publication number Publication date
CN101467287A (en) 2009-06-24
KR20140105871A (en) 2014-09-02
JP5876848B2 (en) 2016-03-02
JP2013145758A (en) 2013-07-25
CN101467287B (en) 2012-09-05
WO2007146453A2 (en) 2007-12-21

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