WO2007136873A3 - Process for decarboxylation of fatty acids and oils to produce paraffins or olefins - Google Patents

Process for decarboxylation of fatty acids and oils to produce paraffins or olefins Download PDF

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Publication number
WO2007136873A3
WO2007136873A3 PCT/US2007/012226 US2007012226W WO2007136873A3 WO 2007136873 A3 WO2007136873 A3 WO 2007136873A3 US 2007012226 W US2007012226 W US 2007012226W WO 2007136873 A3 WO2007136873 A3 WO 2007136873A3
Authority
WO
WIPO (PCT)
Prior art keywords
oils
decarboxylation
olefins
fatty acids
feedstock
Prior art date
Application number
PCT/US2007/012226
Other languages
French (fr)
Other versions
WO2007136873A2 (en
Inventor
Jeffrey John Scheibel
Randall Thomas Reilman
Original Assignee
Procter & Gamble
Jeffrey John Scheibel
Randall Thomas Reilman
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter & Gamble, Jeffrey John Scheibel, Randall Thomas Reilman filed Critical Procter & Gamble
Priority to EP07809147A priority Critical patent/EP2024467A2/en
Publication of WO2007136873A2 publication Critical patent/WO2007136873A2/en
Publication of WO2007136873A3 publication Critical patent/WO2007136873A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

The invention is directed to a process of decarboxylation of natural fats and oils comprising the use of an activated acidic catalyst essentially free of Group VIII metals. Embodiments of the present process comprise the steps of supplying a feedstock comprising of natural fats, oils and mixtures thereof to a reaction vessel, subjecting the feedstock to an activated acidic catalyst essentially free of Group VIII metals, purging the reaction vessel with an inert gas; and subjecting the feedstock and catalyst to a temperature of from about 250°C to about 500°C.
PCT/US2007/012226 2006-05-19 2007-05-19 Process for decarboxylation of fatty acids and oils to produce paraffins or olefins WO2007136873A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP07809147A EP2024467A2 (en) 2006-05-19 2007-05-19 Process for decarboxylation of fatty acids and oils to produce paraffins or olefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US80205406P 2006-05-19 2006-05-19
US60/802,054 2006-05-19

Publications (2)

Publication Number Publication Date
WO2007136873A2 WO2007136873A2 (en) 2007-11-29
WO2007136873A3 true WO2007136873A3 (en) 2008-04-10

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/012226 WO2007136873A2 (en) 2006-05-19 2007-05-19 Process for decarboxylation of fatty acids and oils to produce paraffins or olefins

Country Status (3)

Country Link
US (1) US20070281875A1 (en)
EP (1) EP2024467A2 (en)
WO (1) WO2007136873A2 (en)

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US7915460B2 (en) * 2007-09-20 2011-03-29 Uop Llc Production of diesel fuel from biorenewable feedstocks with heat integration
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US7982077B2 (en) 2007-09-20 2011-07-19 Uop Llc Production of diesel fuel from biorenewable feedstocks with selective separation of converted oxygen
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US8193399B2 (en) * 2008-03-17 2012-06-05 Uop Llc Production of diesel fuel and aviation fuel from renewable feedstocks
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US8193400B2 (en) * 2008-03-17 2012-06-05 Uop Llc Production of diesel fuel from renewable feedstocks
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US8766025B2 (en) 2008-06-24 2014-07-01 Uop Llc Production of paraffinic fuel from renewable feedstocks
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US8471079B2 (en) * 2008-12-16 2013-06-25 Uop Llc Production of fuel from co-processing multiple renewable feedstocks
US8283506B2 (en) * 2008-12-17 2012-10-09 Uop Llc Production of fuel from renewable feedstocks using a finishing reactor
US8314274B2 (en) * 2008-12-17 2012-11-20 Uop Llc Controlling cold flow properties of transportation fuels from renewable feedstocks
CN101898151B (en) * 2009-05-25 2012-05-30 中国石油化工股份有限公司 Three-crystalline phase composite molecular sieve and preparation method thereof
EP2290045A1 (en) * 2009-07-27 2011-03-02 Total Petrochemicals Research Feluy A process for the production of bio-naphtha from complex mixtures of natural occurring fats and oils
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US8471081B2 (en) 2009-12-28 2013-06-25 Uop Llc Production of diesel fuel from crude tall oil
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US8900443B2 (en) 2011-04-07 2014-12-02 Uop Llc Method for multi-staged hydroprocessing using quench liquid
US8546629B2 (en) 2011-09-23 2013-10-01 Uop Llc Methods for co-production of alkylbenzene and biofuel from natural oils
US8865956B2 (en) 2011-09-23 2014-10-21 Uop Llc Methods for co-production of alkylbenzene and biofuel from natural oils using hydrocracking
US8853479B2 (en) 2011-09-23 2014-10-07 Uop Llc Methods for co-production of alkylbenzene and biofuel from natural oils
US8507741B2 (en) 2011-09-23 2013-08-13 Uop Llc Methods for co-production of alkylbenzene and biofuel from natural oils using hydrocracking
FR2992326B1 (en) * 2012-06-21 2014-06-20 IFP Energies Nouvelles PROCESS FOR THE PRODUCTION OF SURFACTANTS FROM RENEWABLE MATERIALS COMPRISING A HYDROTREATING STEP AND A PROCESSING PROCESS OF SURFACTANT PARAFFINS
US20150225329A1 (en) 2012-09-14 2015-08-13 Bioamber Inc. Alternative pathways to adipic acid by combined fermentation and catalytic methods
US9868679B2 (en) 2013-03-15 2018-01-16 The United States Of America, As Represented By The Secretary Of Agriculture Process for isomerization and decarboxylation of unsaturated organic compounds with a metal catalyst or catalyst precursor
US9079814B2 (en) 2013-06-10 2015-07-14 Uop Llc Linear alkylbenzenes from natural oils and methods of producing
US9080134B2 (en) 2013-06-10 2015-07-14 Uop Llc Linear alkylbenzenes from natural oils and methods of producing
US9079811B2 (en) 2013-06-10 2015-07-14 Uop Llc Linear alkylbenzenes from natural oils and methods of producing
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Also Published As

Publication number Publication date
US20070281875A1 (en) 2007-12-06
EP2024467A2 (en) 2009-02-18
WO2007136873A2 (en) 2007-11-29

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