WO2007117037A1

WO2007117037A1 - Apparatus for producing alloy and rare earth element alloy

Info

Publication number: WO2007117037A1
Application number: PCT/JP2007/058124
Authority: WO
Inventors: Hiroshi Hasegawa; Kazuya Ueno; Shinichi Osawa; Shiro Sasaki
Original assignee: Showa Denko K.K.
Priority date: 2006-04-07
Filing date: 2007-04-06
Publication date: 2007-10-18
Also published as: KR101004166B1; EP2026923B1; TW200808981A; RU2008120603A; TWI437103B; RU2389586C2; US7958929B2; EP2026923A4; KR20080070024A; US20090095938A1; EP2026923A1

Abstract

The object of the present invention is to provide an apparatus for producing an alloy, including: a casting device which casts a molten alloy using the strip cast method; a crushing device which crushes the cast alloy after casting; and a heating device which keeps the thin laminas of the cast alloy after crushing at a predetermined temperature or which heats the thin laminas of the cast alloy after crushing, wherein the heating device is equipped with a container and a heater.

Description

DESCRIPTION

APPARATUS FOR PRODUCING ALLOY AND RARE EARTH ELEMENT ALLOY

TECHNICAL FIELD

The present invention relates to an apparatus for producing an alloy. In

particular, the present invention relates to an apparatus for producing a rare earth

element-containing alloy that includes an R-T-B type alloy (wherein R is at least one or

more elements of rare earth elements including Y, T is a metal which always includes Fe,

and B is boron).

This application claims the priority of Japanese Patent Application No.

2006-106793, filed April 7, 2006, and the priority benefit of U.S. Provisional Application

No. 60/792,647, filed on April 18, 2006, the contents of which are incorporated herein by

reference.

BACKGROUNDART

R-T-B type magnets, which have the highest magnetic energy product among

permanent magnets, have been applied to hard disks (HD), MRIs (magnetic resonance

imaging), various types of motors and the like due to their excellent properties. In recent years, their application for motors used in cars has been increased because energy

saving is highly expected and the heat-resistance of the R-T-B type magnets has been

improved.

The R-T-B type magnets mainly contain Nd, Fe, and B, and therefore, they are

generally called an "Nd-Fe-B type" or "R-T-B type" magnet. The R of the R-T-B

type magnet represents mainly those in which a part of Nd is substituted with other rare

earth elements such as Pr, Dy, and Tb, namely at least one of these rare earth elements

including Y. T represents those in which a part of Fe is substituted with metals such as

Co and Ni. B represents Boron in which a part of Boron can be substituted with C or N.

In addition, Cu, Al, Ti, V, Cr, Ga, Mn, Nb, Ta, Mo, W, Ca, Sn, Zr, Hf, etc. may be added

singularly or in combination as additional elements in the R-T-B type magnet.

An R-T-B type alloy, which turns into the R-T-B type magnet, is an alloy

which has a main phase OfR₂T₁₄B, namely a ferromagnetic phase that contributes to

magnetization, and which simultaneously has non-magnetic R-rich phase having a low

melting temperature in which the rare-earth elements are concentrated, and the R— T— B

type alloy is an active metal. Therefore, the R-T-B type alloy has been molten or cast

generally in a vacuum or an inert gas. Also, in order to produce a sintered magnet from

a block of the cast R-T-B type alloy by way of the powdered metal technique, the block

of the alloy is crushed into alloy powder of about 3 μm (measured using a Fisher Sub-Sieve Sizer (FSSS)), then pressed in a magnetic field, and sintered at a high

temperature of about 1000⁰C to 1100⁰C in a sintering furnace. Then, the sintered alloy

is generally subjected to the heating treatment, mechanical processing, and further plated

to improve the erosion resistance, thereby forming a sintered magnet.

The R-rich phase of the R-T-B type sintered magnet has the following

important roles:

1) The R-rich phase has a low melting temperature, becomes a liquid phase when

sintered, and contributes to the densifϊcation of the magnet, namely the improvement of

the magnetization;

2) The R-rich phase eliminates irregularities of the grain boundary, reduces nucleation

sites in the reverse magnetic domain, and enhances the coercive force; and

3) The magnetic R-rich phase magnetically insulates the main phase, and increases the

coercive force.

Consequently, if the state of the dispersion of the R-rich phases in the shaped

magnet is inferior, this causes partial sintering-deficiency and low magnetization, and it

is therefore important that the R-rich phases are uniformly dispersed in the shaped

magnet. The distribution of the R-rich phases is considerably affected by the

organization of the material, namely R-T-B type alloy.

Another problem rises in the casting of the R-T-B type alloy, in which α-Fe generates in the cast alloy. α-Fe has deformability, and therefore, is not crushed and

remains in the crusher. This not only decreases the crushing efficiency of the alloy but

also affects compositional alteration and the particle size distribution before and after

crushing. Moreover, if α-Fe remains in the magnet even after sintering, then the

magnetic property of the magnet will deteriorate. Therefore, it has been considered that

α-Fe should be excluded from the material alloy as much as possible. This is why

α-Fe has been eliminated in conventional alloys by subjecting them to homogenizing

treatment conducted at a high temperature for an extended time where necessary. A

small amount of α— Fe present in the material alloy can be eliminated by way of the

homogenizing treatment. However, the elimination requires the solid phase dispersion

at an extended period because α— Fe is present as peritectic nuclei. Consequently, the

elimination of α-Fe is actually extremely difficult when the ingots have a thickness of

several centimeters and the amount of the rare earth elements is 33% or less.

The strip cast method (abbreviated as "SC method") has been developed and

applied to practical processes, in which a block of the alloy is cast at a more rapid

cooling rate in order to solve the problem in which α-Fe generates in the R-T-B type

alloy.

The SC method is a technique in which a thin lamina of about 0. lmm to 1 mm is

cast by pouring the molten alloy onto a copper roller whose inside is water-cooled, and the alloy is quenched and solidified. In the SC method, because the molten alloy is

extensively cooled to the temperature at which an R₂T₁₄B phase (main phase) generates,

or below this temperature, the RaT₁₄B phase can be generated directly from the molten

alloy and the deposition of α-Fe can be controlled. Furthermore, the crystalline

organization of the alloy becomes refined by way of the SC method, and therefore, an

alloy that has an organization where the R-rich phases are finely dispersed can be

produced. The R-rich phase reacts with hydrogen in a hydrogen atmosphere, expands

and becomes a fragile hydride. By applying this property, fine cracks are incorporated

therein, matching the degree of the dispersion of the R-rich phases. When the alloy is

finely crushed after such a hydrogenation process, a large number of the fine cracks

generated by way of the hydrogenation causes the alloy to break, and the crushability is

very excellent. Thus, as a thin lamina of the alloy cast by way of the SC method has

internal R-rich phases finely dispersed therein, the dispersibility of the R-rich phases in

the crushed and sintered magnet is also excellent, thereby successfully improving the

magnetic property of the magnet (for example, patent document 1).

In addition, the thin lamina of the alloy cast by way of the SC method has

excellent homogeneity of the organization. The homogeneity of the organization can be

compared with respect to particle diameters of the crystals or the state of the dispersion

of the Rich-phases. In the thin lamina of the alloy produced by way of the SC method, although chill crystals sometimes generate on the side of the thin lamina adjacent to the

casting roller (hereinafter, referred as the "casting-roller side"), a properly refined and

homogeneous organization on the whole, which resulted from the rapid-cooling and

solidification, can be obtained.

As explained above, when the R-T-B type alloy cast by way of the SC method

is applied to the production of a sintered magnet, the homogeneity of the R-rich phases in

the produced magnet is enhanced, and the harmful effects to the crushing process and the

magnetization owing to α-Fe can also be prevented. Thus, the block of the R-T-B type

alloy cast by way of the SC method has an excellent organization for producing a

sintered magnet. However, as the properties of the magnet improve, further

improvement of the R-T-B type alloy has been sought.

Patent Document 1: Japanese Unexamined Patent Application, Publication No.

H5-222488

DISCLOSURE OF INVENTION

As described above, the R-T-B type alloy is an alloy that mainly includes an

element "R" in which a part of Nd is substituted with the other rare earth elements such

as Pr, Dy and Tb; an element "T" in which a part of Fe is substituted with metals such as Co and Ni; and "B" (boron). In general, the heat-resistance of the R-T-B type magnet

is evaluated on the basis of the magnitude of its coercive force. The coercive force

increases as the compositional ratios of Dy and Tb in the R-T-B type alloy increase.

However, Dy and Tb are very expensive metals. Therefore, there has been a problem in

which the addition of Dy and Tb to produce an R-T-B type magnet is too costly.

Furthermore, the addition of Dy and Tb indeed improves the coercive force, but

tends to decline the remanent magnetic flux density. This undesirably results in the

decline of the hard magnetic characteristics.

The present invention was accomplished to solve the above problems. The

object of the present invention is to provide an apparatus for producing a rare earth

element-containing alloy, which makes it possible to produce a rare earth magnet that has

a high coercive force.

In order to solve the above-described object, the present invention adopts the

following:

[1] An apparatus for producing an alloy, including: a casting device which casts a

molten alloy using the strip cast method; a crushing device which crushes the cast alloy

after casting; and a heating device which keeps the thin laminas of the cast alloy after

crushing at a predetermined temperature or which heats the thin laminas of the cast alloy,

wherein the heating device is equipped with a container and a heater. [2] The apparatus for producing an alloy according to [1], wherein a hopper and the

heating device are disposed below the crushing device.

[3] The apparatus for producing an alloy according to [2], wherein the heater has an

opening part, and an outlet of the hopper is disposed in the opening part.

[4] The apparatus for producing an alloy according to any one of [1] to [3], wherein

the container is equipped with a storage container, and an opening-closing stage disposed

over the storage container; the thin laminas of the cast alloy supplied from the crushing

device are mounted on the opening-closing stage when the opening-closing stage is in a

closed state; and the opening-closing stage releases the thin lamina of the cast alloy to the

storage container when the opening-closing stage is in an opened state.

[5] The apparatus for producing an alloy according to [4], wherein the

opening-closing stage releases the thin laminas of the cast alloy to the storage container

after a predetermined period from the time when the thin laminas of the cast alloy are

mounted on the opening-closing stage.

[6] The apparatus for producing an alloy according to any one of [1] to [5], wherein

the heater keeps the thin laminas of the cast alloy mounted on the opening-closing stage

at a predetermined temperature, or the heater heats the thin laminas of the cast alloy

mounted on the opening-closing stage.

[7] The apparatus for producing an alloy according to any one of [1] to [6], further including a driving device which enables the container to move freely.

[8] The apparatus for producing an alloy according to [7], wherein the container is

equipped with a plurality of the opening-closing stages, and the plurality of the

opening-closing stages is disposed along the moving direction of the container.

[9] The apparatus for producing an alloy according to [8], wherein the thin laminas

of the cast alloy are sequentially mounted on each opening-closing stage by moving the

container in accordance with preparation of the thin laminas of the cast alloy.

[10] The apparatus for producing an alloy according to [8] or [9], wherein the

opening-closing stages sequentially release the thin laminas of the cast alloy to the

storage container after a predetermined period from the time when the thin laminas of the

cast alloy are mounted on the opening-closing stages.

[11] The apparatus for producing an alloy according to any one of [4] to [10],

wherein the opening-closing stage includes a stage plate, and an opening-closing system

which opens and closes the stage plate while the opening-closing system controls the

inclining angle of the stage plate; the opening-closing system mounts the thin laminas of

the cast alloy on the stage plate by adjusting the stage plate at a horizontal position or a

inclining position when the opening-closing stage is in a close state; and the

opening-closing system releases the thin laminas of the cast alloy to the storage container

by making the inclining angle of the stage plate larger when the opening-closing stage is in an open state.

[12] The apparatus for producing an alloy according to [11], wherein the

by making the inclining angle of the stage plate larger after a predetermined period from

the time when the thin laminas of the cast alloy are mounted on the stage plate.

[13] The apparatus for producing an alloy according to any one of [7] to [12],

wherein the heater is disposed between the crushing device and the opening-closing

stages along the moving direction of the container.

[14] The apparatus for producing an alloy according to any one of [1] to [3], wherein

a belt conveyor or a pushing device is disposed between the heater and the container.

[15] The apparatus for producing an alloy according to any one of [1] to [14],

wherein the casting device, the crushing device and the heater are disposed inside a

chamber of an inert gas atmosphere.

[16] The apparatus for producing an alloy according to [15], wherein a cooling

chamber is provided inside the chamber, and the container is able to move to the cooling

chamber.

[17] The apparatus for producing an alloy according to any one of [1] to [16],

wherein the alloy is a rare earth element-containing alloy.

[18] The apparatus for producing an alloy according to [17], wherein the rare earth element-containing alloy includes an R-T-B type alloy where R is at least one element

of rare earth elements including Y; T is a metal which indispensably contains Fe; and B is

boron.

[19] The apparatus for producing an alloy according to any one of [1] to [16],

wherein the alloy is a hydrogen absorbing alloy.

[20] The apparatus for producing an alloy according to any one of [1] to [16],

wherein the alloy is a thermoelectric semiconductor alloy.

[21] An alloy which is produced with the apparatus for producing an alloy according

to any one of [1] to [16].

[22] A rare earth element-containing alloy which is produced with the apparatus for

producing an alloy according to any one of [1] to [16].

[23] A hydrogen absorbing alloy which is produced with the apparatus for producing

an alloy according to any one of [1] to [16].

[24] A thermoelectric semiconductor alloy which is produced with the apparatus for

producing an alloy according to any one of [ 1 ] to [ 16] .

[25] A rare earth magnet, including the rare earth element alloy according to [22].

As described above, according to the apparatus for producing an alloy of the

present invention, the thin laminas of the cast alloy after casting and crushing are

subjected to the temperature-keeping treatment or the heating treatment, so that the properties of the alloy can be improved.

In particular, when the produced alloy is an R-T-B type alloy, its coercive force

can be improved by way of the temperature-keeping treatment, and a rare earth magnet

having excellent coercive force can be produced.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a front view showing one embodiment of the apparatus for producing

an alloy in the present invention;

FIG. 2 is a front view showing a casting device which is provided in the

apparatus for producing an alloy;

FIG. 3 is a front view showing a heating device which is provided in the

apparatus for producing an alloy;

FIG. 4 is a side view showing a heating device which is provided in the

apparatus for producing an alloy;

FIG. 5 is a plan view showing opening-closing stages and a container which are

provided in the apparatus for producing an alloy;

FIG. 6 is a front view illustrating the operation of the apparatus for producing an

alloy;

FIG. 7 is a front view illustrating the operation of the apparatus for producing an alloy;

FIG. 8 is a front view illustrating the operation of the apparatus for producing an

alloy;

FIG. 9 is a front view illustrating the operation of the apparatus for producing an

alloy;

FIG. 10 is side view illustrating the operation of the apparatus for producing an

alloy;

FIG. 11 is a front view showing another example of the heating device which is

provided in the apparatus for producing an alloy;

FIG. 12 is a front view showing another example of the heating device which is

provided in the apparatus for producing an alloy;

FIG. 13 is a front view showing another example of the heating device which is

provided in the apparatus for producing an alloy;

FIG. 14 is a front view showing another example of the heating device which is

provided in the apparatus for producing an alloy;

FIG. 15 is a front view showing another example of the heating device which is

provided in the apparatus for producing an alloy;

FIG. 16 is a front view showing another embodiment of the apparatus for

producing an alloy; .

14

FIG. 17 is a view showing another example of the opening-closing stage; and

FIG. 18 is a graph describing the relationship between the keeping temperature

and the coercive force of the R-T-B type magnets produced in Examples 1 to 3 and

Comparative Example 1.

BEST MODE FOR CARRYING OUT THE INVENTION

Hereinafter, one preferred embodiment of the apparatus for producing an alloy

of the present invention is explained by referring to the figures. However, it should be

understood that the figures are used only for describing the configuration of the

apparatus, and the shown size, width, scales, etc. of each device does not always reflects

those of the actual apparatus for producing an alloy.

[Format of the apparatus for producing an alloy]

FIG. 1 is a front view showing a general configuration of the apparatus for

producing an alloy as one embodiment.

An apparatus for producing an alloy 1 shown in FIG. 1 (hereinafter, shown as

"production apparatus 1") is equipped with a casting device 2, a crushing device 21, and

a heating device 3 in general. The heating device 3 includes a heater 31 and a container

5. The container 5 includes a storage container 4, and the opening-closing stage group

32 provided over the storage container 4. In this configuration, the container 5 (storage container 4) is disposed below the heating device 3. Also, the production apparatus 1 is

equipped with a belt conveyor 51 (driving device) which freely actuates the container 5,

and the container 5 can move to either the right or the left hand driven by the belt

conveyor 51.

Also, the production apparatus 1 shown in FIG. 1 is equipped with a chamber 6.

The chamber 6 includes a casting chamber 6a and a temperature-keeping storage

chamber 6b which is provided below the casting chamber 6a, and which is connected to

the casting chamber 6a. The casting device 2 is installed in the casting chamber 6a, and

the heating device 3 is installed in the temperature-keeping storage chamber 6b. In this

way, the casting device 2 and the heating device 3 are installed inside the chamber 6. In

addition, the heating device 3 is disposed below the casting device 2 in this

configuration.

A gate 6e is provided in the temperature-keeping storage chamber 6b, and the

temperature-keeping storage chamber 6b is closed with the gate 6e except that the

container 5 is conveyed outside the temperature-keeping storage chamber 6b.

The inside of the chamber 6 is in the state of reduced pressure of an inert gas,

and examples of the inert gas include argon.

In addition, a cooling chamber may be provided on the side of the

temperature-keeping storage chamber 6b across the gate 6e. Also, the cooling chamber may be equipped with another gate, and the container 5 may be designed to move outside

the chamber 6 while leaving this gate open.

The casting device 2 is also equipped with the crushing device 21 that crushes

blocks of the cast alloy formed by way of casting into thin laminas of the cast alloy.

Moreover, a hopper 7 is provided between the casting device 2 and the opening-closing

stage group 32. The hopper 7 directs the thin laminas of the cast alloy onto the

opening-closing stage group 32.

Hereinafter, each of the devices included in the production apparatus 1 is further

described in detail.

[Structure of the casting device]

FIG. 2 is a front view showing the casting device 2 that is provided in the

production apparatus 1.

As shown in FIG. 2, the casting device 2 according to the present embodiment is

a device which prepares thin laminas of the cast alloy by way of crushing after casting

the molten alloy using the strip cast method. In general, the casting device 2 includes a

cooling roll 22 having a diameter of about 60 mm to 80 mm that casts a molten alloy L

into a cast alloy M by way of rapid cooling the molten alloy; a tundish 23 that supplies

the cooling roll 22 with the molten alloy L; and crushing device 21 that crushes the cast

alloy M cast by the cooling roll 22 into thin laminas N of the cast alloy. The molted alloy L is prepared in a high-frequency melting furnace which is

provided outside the chamber 6 (not shown in the figures). In the high-frequency

melting furnace, materials are charged into a refractory pot in a vacuum or in an

atmosphere of an inert gas, and the charged materials are molten by way of the

high-frequency melting method, thereby preparing a molten alloy. The temperature of

the molten alloy L varies with types of alloy contents, but it is adjusted within a range of

1300°C to 1500⁰C. As described in FIG. 2, the prepared molten alloy L is conveyed to

the casting device 2 as it is kept in the refractory pot 24. Then, the molten alloy L is

supplied to from the refractory pot 24 to the tundish 23.

The tundish 23 may be equipped with a flow-adjusting system and/or a

slag-removing system where necessary. Also, the cooling roll 22 has a water-cooling

system inside (not shown in the figures), and the circumferential surface 22a of the

cooling roll 22 is cooled by the water-cooling system. With regard to the material for

the cooling roll 22, a copper or copper alloy is suitable because they have excellent

thermal conductivity, and are easily available. The supplying rate of the molten alloy L

and the revolving speed of the cooling roll 22 are controlled according to the thickness of

the cast alloy M, but it may be suitable that the revolving speed of the cooling roll 22 be

about 0.5 to 3 m/s at a circumferential speed. Depending on the material for the cooling

roll 22 or the condition of the circumferential surface 22a, metals often tend to adhere to the circumferential surface 22a of the cooling roll 22. Therefore, where necessary, a

cleaning unit may be provided therein, so that the quality of the produced R-T-B type

alloy will be stable. The cast alloy M solidified on the cooling roll 22 is separated from

the cooling roll 22 at the side opposite to the tundish 23.

As shown in FIGS 2 and 3, the crushing device 21 , for example, includes a pair

of crushing rolls 21a, and the cast alloy M is inserted between two rotating crushing rolls

21a, such that the cast alloy M is crushed into the thin laminas N of the cast alloy. The

crushed thin laminas N of the cast alloy fall down through the hopper 7, and they are

conveyed to the heating device 3.

[Structure of the heating device]

FIG. 3 is a front view showing a heating device 3 which is provided in the

apparatus for producing an alloy, FIG. 4 is a side view thereof, and FIG. 5 is a plan view

thereof.

As shown in FIGS 3 to 5, a heater 31 included in the heating device 3 has a

heater cover 31 a, and a main body 31b attached blow the heater cover 31a. The heater

cover 3 Ia is provided therein in order to release the heat generated from the main body

3 Ib to the direction of the container 5, and in order to prevent the heat from being

released to the casting chamber 6a. Also, if the heater cover 3 Ia is provided therein,

then it can! prevent the main body 31 from breaking down in the event of a portion of the molten alloy or the cast alloy unexpectedly falling down thereto.

With regard to its heating system, any one of the resistance heating, infrared

heating, and induction heating can be adopted. Also, the main body 31b, for example,

may be any heating element such as metal wires, silicon carbide, and graphite.

The heater 31 has an opening part 31c, and an outlet 7a of the hopper 7 is

disposed in the opening part 31c. Consequently, the thin laminas N of the cast alloy that

falls down from the casting device 2 and that passes through the hopper 7can be supplied

to the opening-closing stage group 32 of the container 5 which is provided below the

heater 31.

Moreover, the heater 31, as shown in FIGS 1 and 3, is disposed along the

longitudinal direction of the belt conveyor 51 (the moving direction of the container 5)

which is provided inside the temperature-keeping storage chamber 6b. This

configuration makes it possible to uniformly keep the temperature of the thin laminas N

of the cast alloy mounted on the opening-closing stage group 32 of the container 5 or to

uniformly heat them even while the container 5 moves inside the temperature-keeping

storage chamber 6b.

The opening-closing stage group 32 included in the heating device 3 is

integrated with the storage container 4 to form the container 5. That is, the container 5

shown in FIGS 3 to 5 is formed with the storage container 4, and the opening-closing stage group 32 which is provided over the container 5

The opening-closing stage group 32 is equipped with a plurality of

opening-closing stages 33. Each opening-closing stage 33 is disposed along the moving

direction of the container 5. The opening-closing stage group 32 shown in FIGS 3 to 5

is equipped with ten opening-closing stages 33. Guide members 52 are provided around

the opening-closing stage group 32, and the guide members 52 prevent the thin laminas

N of the cast alloy that drop through the hopper 7 from scattering into the

temperature-keeping storage chamber 6b.

Each opening-closing stage 33 leaves the thin laminas N of the cast alloy

supplied from the casting device 2 mounted thereon to keep the temperature or to heat

them with the heater 31 at a predetermined period, and drops the thin laminas N of the

cast alloy to the storage container 4 after the temperature-keeping or heating period.

The opening-closing stage 33 is further explained in detail. Each

opening-closing stage 33 is equipped with a stage plate 33 a, and an opening-closing

system 33b which opens or closes the stage plate 33a. Each opening-closing system

33b has a rotating shaft 33bi attached to one side of the stage plate 33a; and a driving

unit (not shown in the figures), which rotates the rotating shaft 3Sb₁. Each driving unit

can freely rotate the rotating shaft 33b_1? such that the inclining angle of each stage plate

33a can be controlled separately. The inclining angle of each stage plate 33a can be set anywhere in the range of 0° (where the stage plate 33a is horizontal (the position shown

in FIG 3 with a dashed line)) to about 90° in the clockwise-direction (where the stage

plate 33a is almost vertical (the position shown in FIG 3 with a continuous line)).

The opening-closing stage 33 is in a closed state when the stage plate 33a is in a

horizontal position (when the inclining angle is about 0°) or when the stage plate 33a is

inclined to such a degree that the thin laminas N of the cast alloy do not fall down from

there. On the other hand, the opening-closing stage 33 is in an opened state from the

condition in which the stage plate 33 a, for example, is slightly inclining to the condition

in which the stage plate 33a is vertical (when the inclining angle is about 90°s). When

the opening-closing stage 33 is in the closed state, the thin laminas N of the cast alloy can

be mounted on the stage plate 33 a. When the opening-closing stage 33 is in an opened

state, the stage plate 33a is in an inclined state, and the thin laminas N of the cast alloy

can fall, thereby enabling them to fall into the storage container 4.

Thus, the opening-closing stage 33 can leave the thin laminas N of the cast alloy

mounted on the stage plate 33a during a predetermined temperature-keeping period by

actuating the opening-closing system 33b, and then, can drop the thin laminas N of the

cast alloy down into the storage container 4 by making the inclining angle of the stage

plate 33a larger.

In addition, the opening-closing stage 33 can function as a cover for the storage container 4. That is, the storage container 4 is closed when the opening-closing stages

33 are in a closed state. This prevents the heat of the heater 31 from transmitting to the

storage container 4, thereby saving the inside of the storage container 4 from heating up.

In this way, the opening-closing stages 33 can block the heat-transmission from the

heater 31 whereby the thin laminas N of the cast alloy stored in the storage container 4

that were already subjected to the heat-keeping treatment are not subjected again to the

temperature-keeping or heating, and the quality of the thin lamina N of the cast alloy is

kept stable.

Next, a plurality of cooling plates 4a is provided inside the storage container 4 as

shown in FIGS 3 and 4. The cooling plates 4a are arranged in their thickness direction

at a fixed interval. When the thin laminas N of the cast alloy after the

temperature-keeping are in contact with the cooling plates 4a, the accumulated heat in the

thin laminas N of the cast alloy is absorbed into the cooling plates 4a, and the

temperature of the thin lamina N of the cast alloy declines.

Various metals such as a stainless steal, iron, hastelloy, and inconel are applied

to the materials for the opening-closing stage 33 and the storage container 4 as long as

they can be used at a high temperature.

As shown in FIGS 3 and 4, the container 5 is mounted on the belt conveyor 51.

The belt conveyor 51 enables the container 5 to move to the left or right side hand of FIG. 3.

[The operation of the apparatus for producing an alloy]

Next, the operation of the above-described production apparatus 1 will be

explained. All FIGS 6 to 9 are front views illustrating the operation of the apparatus for

producing an alloy.

As shown in FIG. 6, the container 5 is moved to where an opening-closing stage

33 A (present at the left edge of the opening-closing stage group 32) locates directly under

the outlet 7a of the hopper 7. Also, all opening-closing stages 33 are set in a closed

state.

Then, thin laminas N of the cast alloy are prepared by actuating the casting

device 2. In reference to FIG. 2, a molten alloy L is prepared in a melting device (not

shown in the figures). The molten alloy L is supplied to the tundish 23, and further

supplied from the tundish 23 to the cooling roll 22, whereby the molten alloy L is

solidified to produce a cast alloy M. After that, the cast alloy M is displaced from the

cooling roll 22, and passes through crushing rolls 21a, such that the cast alloy M is

crushed into thin laminas N of the cast alloy.

The composition of the molten alloy L is represented, for example, by the

general formula R-T-B. "R" represents mainly those in which a part of Nd is

substituted with the other rare earth elements such as Pr, Dy and Tb, namely at least one of the rare earth elements including Y. "T" represents those in which a part of Fe is

substituted with metals such as Co and Ni. "B" represents boron in which a part of

boron can be substituted with C or N. In addition, Cu, Al, Ti, V, Cr₅ Ga, Mn, Nb, Ta₅

Mo, W₅ Ca, Sn, Zr, Hf, etc. may be added singularly or in combination as additional

elements. The composition ratios of R and B are 28 to 33% and 0.9 to 1.3% by mass

respectively, and the balance is T. A part of R may be substituted with 15% by mass of

Dy and/or 15% by mass of Tb. However, the composition of the molten alloy applied to

the production apparatus 1 of the present invention is not limited to the above-described

range, and any composition for R-T-B type alloys can be applied.

It is preferable that the average cooling speed of the molten alloy on the cooling

roll 22 be 300⁰C to 3000⁰C per second. When the cooling speed is 300⁰C per second or

more, sufficient cooling speed can prevent the deposition of α-Fe, and can prevent

organizations such as an R-rich phase and R₂Tπ-phase from being coarse. When the

cooling speed is 3000⁰C per second or less, its cooling rate does not grow excessive

whereby the thin laminas of the cast alloy can be supplied to the heating device 3 at a

proper temperature. Also, there is a merit that the thin laminas of the cast alloy are not

excessively cooled, and therefore, it is unnecessary for them to be heated again, hi

addition, the average cooling speed can be calculated by dividing the difference between

the temperatures of the molten alloy directly before touching the cooling roll and when separating from the cooling roll by the time that the molten alloy touches the cooling roll.

Furthermore, the average temperature of the cast alloy M when separating from

the cooling roll will slightly vary depending on a slight change in the condition of

touching the cooling roll 22, changes of the thickness, among others. For example, the

surface of the alloy is scanned in the cross direction with a radiation thermometer from

when casting begins to when casting ends whereby the average temperature of the cast

alloy M when separating from the cooling roll can be calculated by averaging the

measured values.

It is preferable that the average temperature of the cast alloy M when separating

from the cooling roll 22 be lower by 100 to 500°C than the solidifying temperature of the

molten alloy in the equilibrium state of the I^T^B-phase, and it is more preferably lower

by 100 to 400⁰C. The melting temperature of the R₂T₁₄B-phase is around 115O⁰C in the

ternary system of Nd-Fe-B. However, the melting temperature varies according to the

substitution of Nd to the other rare earth elements, the substitution of Fe to the other

transition elements, and types or amounts of the other additional elements. If the

difference between the average temperature of the cast alloy M when separating from the

cooling roll 22, and the solidifying temperature of the cast alloy M in the equilibrium

state of the F^T^B-phase is less than 100°C, the cooling speed is insufficient. On the

other hand, if the difference is over 500⁰C, the cooling speed is too fast, and the cooling of the molten alloy becomes excessive. The degree of such excessive cooling is not

uniform inside the alloy, and it varies depending on the condition of touching the cooling

roll, and the distance from the site contacting with the cooling roll.

Next, as shown in FIG. 6, the crushed thin laminas N of the cast alloy pass

through the hopper 7, and pile (mount) on the opening-closing stage 33 A which is

positioned directly under the outlet 7a of the hopper 7. During this time, the heater 31 is

switched on, the thin laminas N of the cast alloy are kept at a predetermined temperature

or heated by the heater 31 directly after they are piled on the opening-closing stage 33 A.

The amount of the thin laminas N of the cast alloy piled on the opening-closing

stage 33A may be properly adjusted according to the area of the stage plate 33a.

However, the thin laminas N of the cast alloy are continuously supplied from the casting

device 2, they will overflow from the opening-closing stage 33 A in time although it also

depends on the supplying speed.

Therefore, in the production apparatus 1 of the present embodiment, the

container 5 is moved to the left side hand as shown in FIG. 7 when the piling amount of

the thin laminas N of the cast alloy reaches a predetermined value with respect to the

opening-closing stage 33A Then, another opening-closing stage 33B next to the

opening-closing stage 33 A on the right side is positioned directly under the outlet 7a of

the hopper 7, followed by the thin laminas N of the cast alloy being piled on the opening-closing stage 33B. After that, in the same way, the container 5 is moved in

accordance with the preparation of the thin laminas N of the cast alloy, and the thin

laminas N of the cast alloy are piled sequentially on the opening-closing stages 33 C to

33 E. Specifically, in the present invention, the preparation of the thin laminas N of the

cast alloy refers to the supplying rate of the thin laminas N of the cast alloy thereto, or

production rate thereof.

The piling amount of the thin laminas N of the cast alloy with respect to each of

the opening-closing stages 33 A to 33E may be monitored with their mass by providing

each stage plate 33a with a mass-detecting system, or may be controlled by adjusting the

piling period with respect to each stage plate 33a based on the production amount of the

thin laminas N of the cast alloy per time that is calculated from the casting or crushing

speed of the casting device 2.

During this time, the thin laminas N of the cast alloy piled on each of the

opening-closing stages 33 A to 33E are kept at a predetermined temperature or heated

with the heater 31. It is preferable that the keeping temperature be lower than the

temperature of the thin lamina N when separating from the cooling roll (separating

temperature), and for example, it is preferably within a range of (the separating

temperature - 100°C) to the separating temperature, and it is more preferably within a

range of (the separating temperature - 50°C) to the separating temperature. More specifically, the keeping temperature is preferably within a range of 600°C to 900⁰C.

Also, when the separating temperature declines for any reason, the thin laminas N of the

cast alloy can be heated and kept at a predetermined temperature by setting the keeping

temperature higher than the separating temperature. It is preferable that the heating

range be within 100⁰C, and more preferably within 5O⁰C. If the heating range is too

large, the yield will decline.

Furthermore, the period of the temperature-keeping is preferably 30 seconds or

more, more preferably 30 seconds to about several hours, and most preferably 30 seconds

to 30 minutes. The coercive force of the R-T-B type alloy can be enhanced by way of

subjecting the thin laminas N of the cast alloy to the temperature-keeping treatment.

When the keeping temperature is 600⁰C or more, the coercive force can be sufficiently

enhanced. Also, when the coercive force is 900⁰C or less, the deposition of α-Fe can

be prevented, and the organizations such as the R-rich phase and the RiTπ-phase can be

prevented from being coarse. If the temperature-keeping time is 30 seconds or more,

then the coercive force can be sufficiently enhanced. That is, the thin laminas of the

cast alloy may be subjected to the temperature-keeping treatment for several hours, but

the temperature-keeping time is preferably 30 minutes or less in terms of the yielding

efficiency.

In addition, if they are kept at 1000⁰C, the coercive force can be improved. However, such a temperature makes organizations coarse. Furthermore, the particle

distribution or the fluidity of the fine powder when they are finely crushed, and the

sintering temperature may unfavorably change. When they are kept at 1000⁰C, it is

required to consider its influence to subsequent processes.

Next, as shown in FIG. 8, the container 5 is further moved with respect to the

rest of the opening-closing stages 33F to 33J in accordance with the preparation of the '

thin laminas N of the cast alloy in the same way whereby the thin laminas N of the cast

alloy are successively piled on each of the opening-closing stages 33F to 33H.

With regard to the thin laminas N of the cast alloy piled on the opening-closing

stages 33 A to 33E, they are successively dropped into the storage container 4 by making

each opening-closing stage in an opened state as shown in FIG. 9 when the predetermined

temperature-keeping time or heating time passes. Once the thin laminas N of the cast

alloy are dropped into the storage container 4, the heat of the heater 31 no longer

transmits to the thin laminas N of the cast alloy so that the temperature-keeping treatment

is finished.

As described above by referring to FIG. 7, thin laminas N of the cast alloy are

successively mounted on each opening-closing stage, and the different opening-closing

stages consequently have time-differences in the starting point to start the

temperature-keeping treatment with respect to the thin laminas N of the cast alloy on the opening-closing stages. Therefore, it is preferable that the thin laminas N of the cast

alloy are successively dropped into the storage container 4 by successively switching

each opening-closing stage to in an opened state in order to fix the temperature-keeping

time with respect to thin laminas N of the cast alloy on each opening-closing stage.

The thin laminas N of the cast alloy that dropped into the storage container 4 are

in contact with the cooling plate 4a whereby the heat is absorbed into the cooling plate 4a,

and the thin laminas N of the cast alloy are consequently cooled down.

FIGS 9 and 10 show a state in which all opening-closing stages 33 are in an

opened state, and the thin laminas N of the cast alloy are stored in the storage container 4.

If the casting and crushing processes by the casting device 2 are subsequently

conducted after that, the container 5 can be moved to the right hand in the figures while

all opening-closing stages 33 are made in a closed state, and the thin laminas N of the

cast alloy are successively mounted on each opening-closing stage 33 in accordance with

the preparation of the thin laminas N of the cast alloy.

To the contrary, if the casting and crushing processes by the casting device 2 are

terminated, all opening-closing stages 33 are switched to in a closed state to prevent the

heat of the heater 31 from reaching the storage container 4. Then, the gate 6e of the

temperature-keeping storage chamber 6b is opened, and the container 5 is conveyed

outside the chamber 6. W 2

31

Also, if a cooling chamber is provided in the chamber, the gate 6e of the

temperature-keeping storage chamber 6b is opened, the container 5 is conveyed to the

cooling chamber, and the thin laminas N of the cast alloy inside the container 5 are

allowed to stand in order to cool. When the cooling is completed, the gate of the

cooling chamber is opened, and the container 5 may be carried outside the chamber 6.

As explained above, because the production apparatus 1 is equipped with the

heating device 3 that keeps the thin laminas N of the cast alloy at a predetermined

temperature or that heats them, the coercive force of the thin laminas N of the cast alloy

made of the R-T-B type alloy can be improved whereby an R-T-B type magnet having

excellent heat-resistance can be produced.

Also, the production apparatus 1 is equipped with the opening-closing stages 33

on which the thin laminas N of the cast alloy supplied from the casting device are

mounted when they are in a closed state, and that drops the thin laminas N of the cast

alloy into the storage container 4 when they are in an opened state; and the heater 31 that

keeps the thin laminas N of the cast alloy mounted on the opening-closing stages 33 at a

predetermined temperature or that heats them. This is why the temperature-keeping

time for the thin laminas N of the cast alloy can be controlled by adjusting the opening or

closing period of the opening-closing stages 33 without switching the heater 31 on or off,

and this also results in miniaturization of the apparatus. Also, according to the above production apparatus 1, the opening-closing stages

33 release the thin laminas N of the cast alloy to the storage container 4 when a

predetermined temperature-keeping time passes after the thin laminas N of the alloy are

mounted thereon whereby the coercive force of thin laminas N of the cast alloy can be

greatly improved.

Also, according to the production apparatus 1, the heating device 3 is disposed

below the casting device 2 whereby the thin laminas N of the cast alloy can be easily

moved between two or three of the devices only by way of dropping them. Therefore, it

is unnecessary to provide another system for delivering the thin laminas N of the cast

alloy, and this can result in the miniaturization or space-saving for the production

apparatus 1.

Also, according to the production apparatus I₅ the storage container 4 and the

opening-closing stages 33 are integrated to form the container 5 whereby the total thin

laminas N of the cast alloy after the temperature-keeping treatment can be released to the

storage container 4 without loss thereof. Also, because the storage container 4 and the

opening-closing stages 33 are integrated to form one body, the miniaturization or

space-saving for the production apparatus 1 can be achieved. Furthermore, the belt

conveyor 51 which freely moves the container 5 is provided therein whereby the thin

laminas N of the cast alloy after the temperature-keeping treatment can be quickly delivered out from the production apparatus 1.

Also, according to the production apparatus 1, the container 5 is equipped with a

plurality of the opening-closing stages 33, and each opening-closing stage 33 is disposed

along the moving-direction of the container 5 whereby thin laminas N of the cast alloy

can be successively mounted on each opening-closing stage 33 by moving the container 5

even if thin laminas N of the cast alloy are continuously supplied from the casting device

2. Consequently, the thin laminas N of the cast alloy will not overflow from each

opening-closing stage 33.

Also, according to the production apparatus 1, the thin laminas N of the cast

alloy are successively released to the storage container 4 when a predetermined

temperature-keeping time passes after the thin laminas N of the cast alloy are mounted on

each opening-closing stage 33 whereby the temperature-keeping time can be fixed and

the quality of the thin laminas N of the cast alloy can be consequently kept uniform.

Also, according to the production apparatus 1, the heater 31 is disposed between

the casting device 2 and the opening-closing stages 33 along the moving direction of the

container 5 whereby the distance between the thin laminas N of the cast alloy on each

opening-closing stage 33 and the heater 31 can be fixed even while the container 5

moves. Consequently, the thin laminas N of the cast alloy can always be kept at a

predetermined temperature in the same conditions. Also, according to the production apparatus 1, the storage container 4 is

equipped with the cooling plate 4a that cools the thin laminas N of the cast alloy whereby

the thin laminas N of the cast alloy after the temperature-keeping treatment can be

quickly cooled. Consequently, the temperature-keeping time will not be substantially

extended, and the quality of the thin laminas N of the cast alloy can be improved.

Also, according to the production apparatus 1, the casting device 2 is equipped

with the crushing device 21 whereby blocks of the cast alloy can be easily crushed into

thin laminas N of the cast alloy, and this consequently makes it easier to treat the cast

alloy in the heating device 3 or the storage container 4.

Also, according to the production apparatus 1, the hopper 7 that directs the thin

laminas N of the cast alloy onto the opening-closing stages 33 is provided between the

crushing device 21 and the opening-closing stages 33 whereby the thin laminas N of the

cast alloy will not scatter inside the temperature-keeping storage chamber 6b, and the

entire amount of the thin laminas N of the alloy can be delivered to the opening-closing

stages 33 without loss thereof.

Also, according to the production apparatus 1, the heater 31 has the opening part

31c, and the outlet 7a of the hopper 7 is disposed in the opening part 31c whereby the

outlet 7a of the hopper 7 faces the opening-closing stage 33 of the container 5, and the

entire amount of the thin laminas N of the alloy can be therefore delivered to the opening-closing stages 33 without loss thereof as well as miniaturization and

space-saving for the production apparatus 1 can be achieved.

Also, according to the production apparatus 1, the casting device 2 and the

heating device 3 are provided inside the chamber 6 of an atmosphere of an inert gas

whereby the R-T-B type alloy can be prevented from deteriorating.

Also, according to the production apparatus 1, a cooling chamber is provided

inside the chamber 6, and the container 5 can be moved to the cooling chamber whereby

the thin laminas N of the cast alloy stored in the container 5 that have already subjected

to the temperature-keeping treatment can be delivered from the temperature-keeping

storage chamber 5b, and they can be cooled. Consequently, the yield can be improved.

Also, according to the production apparatus 1, the rare earth element-containing

alloy is an R-T-B type alloy whereby a magnet having high coercive force and excellent

heat resistance can be produced.

The R-T-B type alloy is an alloy that mainly includes an element "R" where a

part of Nd is substituted with the other rare earth elements such as Pr, Dy and Tb; an

element "T" where a part of Fe is substituted with metals such as Co and Ni; and "B"

(boron). The coercive force of the R-T-B type magnet formed of such an alloy

generally increases as the composition ratios of Dy and Tb in the R-T-B type alloy

increase, but the remanent magnetic flux density tends to decline on the contrary. According to the production apparatus 1, the R-T-B type alloy can be subjected

to the temperature-keeping treatment because the heating device 3 is provided therein

whereby the coercive force of the magnet formed of the R-T-B type alloy can be

improved. Consequently, the composition ratios of Dy and Tb in the alloy can be

reduced. In addition, when the composition ratios of Dy and Tb in the alloy are

reduced, the remanent magnetic flux density can also be improved.

The heating device is not limited to the above-described embodiment, and

embodiments shown in FIGS 11 to 14 may be applied.

FIG. 11 shows another embodiment for the heating device. The difference

between a heating device 103 shown in FIG. 11 and the heating device 3 shown in FIG. 1

and FIGS 3 to 5 is that a heater 131 is equipped with a protective cover 131c.

That is, the heater 131 shown in FIG. 11 includes a heater cover 131 a; a main

body 13 Ib provided below the heater cover 131a; and the protective cover 131c that is

attached to the heater cover 131 a to protect the main body 131 b. The heater cover 131a

is provided in order to release the heat generated from the main body 13 Ib in the

direction of the container 5 and in order to prevent the heat from the main body 131b

from emitting to the casting chamber 6a. Also, the heater cover 131a can protect the

main body 131b from breaking down even if a portion of the molten alloy or the cast

alloy drops from the casting device 2 thereto. Also, the protective cover 131c is disposed between the main body 131b and the

container 5. When the thin laminas N of the cast alloy fall down to the opening-closing

stages 33 of the container, the thin laminas N of the cast alloy may strike against the main

body 131b because they rebound on the opening-closing stages 33. However, the

protective cover 131c can protect the main body 131b from the thin laminas N of the cast

alloy. In addition, the heater emitted from the main body 13 Ib is radiated onto the thin

laminas N of the cast alloy on the opening-closing stages 33 through the protective cover

131c.

The protective cover 131c may be a plate-shaped or mesh-like structure. If the

protective cover 131 c is plate-shaped, the use of a material that has excellent thermal

conductivity and heat-radiation efficiency is preferable in order to sufficiently radiate the

heat to the thin laminas N of the cast alloy. If it is mesh-like, it is preferable to use

those which have pore sizes where the thin laminas N of the cast alloy cannot pass

through the protective cover.

Next, FIG. 12 shows yet another embodiment for the heating device. The

difference between a heating device 203 shown in FIG. 12 and the heating device 3

shown in FIG. 1 and FIGS 3 to 5 is that partition panels 134 are provided between the

opening-closing stages 133 of the opening-closing stage group 132.

That is, the opening-closing stage group 132 illustrated in FIG. 12 has a plurality of the opening-closing stages 133, and the each opening-closing stage 133 is arranged

along the moving-direction of the container 5. The opening-closing stage group 132

shown in FIG. 12 has ten opening-closing stages 133. Also, guide members 52 are

provided around the opening-closing stage group 132, and the guide members 52 prevent

the thin laminas N of the cast alloy that has dropped through the hopper 7 from scattering

into the temperature-keeping storage chamber 6b.

Moreover, the partition panels 134 are provided on the boundary of each

opening-closing stage 133. Each partition panel 134 is set to stand facing the direction

of the heater 31.

When the thin laminas N of the cast alloy fall down to the opening-closing

stages 133, the thin laminas N of the cast alloy rebound on the opening-closing stage

133, and may scatter into adjacent opening-closing stages 133. However, the partition

panel 134 can prevent the thin laminas N of the cast alloy from scattering.

Furthermore, the partition panel 134 can prevent the thin laminas N of the cast

alloy from piling around a boundary part of the opening-closing stage 133, and the all

thin laminas N can be dropped into the storage container 4 without leaving them thereon.

In addition, the partition panel 134 may include an auxiliary heater in order to

assist temperature-keeping for the thin laminas N of the cast alloy on the opening-closing

stage 133. The use of the auxiliary heater can uniformly keep the temperature of the W 2

39

thin laminas N of the cast alloy.

Next, FIG. 13 illustrates yet another embodiment for the heating device. The

difference between a heating device 303 shown in FIG. 13 and the heating device 3

shown in FIG. 1 and FIGS 3 to 5 is that a belt conveyor 306 is provided between a heater

331 and a container 305 instead of the opening-closing stage group 132.

That is, the heating device 303 shown in FIG. 13 includes the heater 331; the

container 305; and the belt conveyor 306 provided between the heater 331 and the

container 305. The belt conveyor 306 carries the thin laminas N of the cast alloy to the

container 305 while keeping them at a predetermined temperature supplied from the

casting device. Also, the container 305 is equipped with a cooling plate 305a.

The heater 331 includes a heater cover 331a and a main body 331b provided

under the heater cover 331a. The function, the material, etc. of the heater cover 331a

and the main body 33 Ib are arranged in the same manner as the above-described heater

31.

Moreover, an outlet 7a of the hopper 7 is provided at the left side of the heater

331 whereby the thin laminas N of the cast alloy which have dropped from the casting

device 2 through the hopper 7 can be delivered out to the belt conveyor 306.

Furthermore, the heater 331 is disposed along the longitudinal direction of the

belt conveyor 306 at a regular distance from each other as shown in FIG. 13. This configuration can achieve the uniform temperature-keeping of thin laminas N of the cast

alloy that are conveyed by the belt conveyor 306.

In addition, in the heating device 303 shown in FIG. 13, another heater may be

provided between the belt conveyor 306 and the container 305 in order to heat the belt of

the belt conveyor 306.

Next, the belt conveyor 306 is disposed such that the end part 306a is arranged

directly under the outlet 7a of the hopper 7 and the end part 306b is arranged directly

over the container 305. The belt conveyor 306 extends from the end part 306a to the

end part 306b along the heater 331. Also, the distance between the belt conveyor 306

and the heater 331 is almost fixed.

According to the above-described configuration, the thin laminas N of the cast

alloy that has dropped from the casting device 2 through the hopper 7 can be subjected to

the temperature-keeping by the heater 331 while being delivered by the belt conveyor

306. Then, the thin laminas N of the cast alloy can be released from the end part 306b

of the belt conveyor 306 to the container 305. With regard to the temperature-keeping

time, the starting point refers to when the thin laminas N of the cast alloy reach the belt

conveyor 306, and the ending point refers to when they are sent from the end part 306b

of the belt conveyor 306 to the container 305. Consequently, the temperature-keeping

time can be adjusted by way of adjusting the driving speed of the belt conveyor 306. Thus, according to the heating device 303 shown in FIG. 13, the thin laminas N

of the cast alloy that are continuously supplied can be kept at a predetermined

temperature or heated, and the period for the temperature-keeping or heating can be

fixed.

In addition, the container 305 is provided on another belt conveyor 51 , and the

container 305 can be moved to either the left or the right side hand of the figure.

According to this structure, the relative position of the container 305 to the end part 306b

of the belt conveyor 306 can be freely adjustable whereby the thin laminas N of the cast

alloy can be prevented from piling at the same position of the container 305.

Next, FIG. 14 shows yet another embodiment for the heating device. The

difference between a heating device 403 shown in FIG. 14 and the heating device 303

shown in FIG. 13 is that a pushing device 406 is disposed between a heater 331 and a

container 305 instead of the belt conveyor 306.

That is, the heating device 403 includes a heater 331; a container 305; the

pushing device 406 disposed between the heater 331 and the container 305. The

pushing device 406 delivers the thin laminas N of the cast alloy, which are supplied from

the casting device, to the container 305 while they are kept at a predetermined

temperature. In addition, the container 305 is equipped with a cooling plate 305a.

A heater 331 includes a heater cover 33 Ia; a main body 33 Ib provided under the heater cover 331a. The function, material, etc. of the heater cover 331a and the main

body 331b are arranged in the same manner as the above-described heater 31.

Also, an outlet 7a of a hopper 7 is disposed at the left side of the heater 331

whereby the thin laminas N of the cast alloy that have been dropped the casting device 2

passing through the hopper 7 can be released to the pushing device 406.

Moreover, the heater 331, as shown in FIG. 14, is disposed along the

longitudinal direction of the pushing device 406. This configuration can achieve

uniform temperature-keeping of the thin laminas N of the cast alloy that are conveyed by

the pushing device 406.

In addition, in a heating device 403 shown in FIG. 14, another heater may be

provided between a base plate 406a and the container 305 in order to heat the base plate

406a.

Next, the pushing device 406 includes the base plate 406a; and a pushing

member 406b that slides on the base plate 406a. The base plate 406a is disposed such

that the end part 40Oa₁ is arranged directly under the outlet 7a of the hopper 7 and

another end part 406a₂ is arranged directly over the container 305. The base plate 406a

extends from the end part 40Oa₁ to the end part 406a₂ along the heater 331. Also, the

distance between the base plate 406a and the heater 331 is almost fixed. The pushing

member 406b moves from the end part 406ai of the base plate 406a toward the end part 406a₂ while being in contact with the base plate 406a. To the contrary, the pushing

member 406b moves back from the end part 406a₂ to the end part 40Oa₁ while separating

from the base plate 406a.

According to the above-described configuration, the thin laminas N of the cast

alloy that have been dropped from the casting device 2 passing from the hopper 7 are

piled on the base plate 406a, and the thin laminas N of the cast alloy are kept at a

predetermined temperature by the heater 331 while the pushing member 406b delivers

them to the end part 406a₂ of the base plate by way of pushing. Then, the thin laminas

N of the cast alloy are released from the end part 406a₂ of the base plate 406a to the

container 305. With regard to the temperature-keeping time, the starting point refers to

when the thin laminas N of the cast alloy reach the base plate 406a, and the ending point

refers to when they are sent from the end part 406a₂ of the base plate 406a to the

container 305. Consequently, the period for the temperature-keeping can be adjusted by

way of controlling the driving speed of the pushing member 406b.

Thus, according to the heating device 403 shown in FIG. 14, the thin laminas N

of the cast alloy that are continuously supplied can be kept at a predetermined

fixed.

In the same manner as FIG. 13, the container 305 is provided on a belt conveyor 51, and the container 305 can move to either left or right side hand of the figure.

According to this structure, the relative position of the container 305 to the end part

406a₂ of the base plate 406a of the pushing device 406 is freely adjustable whereby the

thin laminas N of the cast alloy can be prevented from piling at the same position of the

container 305.

Next, FIG. 15 further shows still another embodiment for the heating device.

The difference between a heating device shown in FIG. 15 and the heating device 303

shown in FIG. 13 is that a vertical furnace 451 and a table feeder are provided therein

instead of the heater 331 and the belt conveyor 306.

The vertical furnace 451 shown in FIG. 15 includes a thin lamina-path 452; an

outside heater 453 provided in the circumference of the thin lamina-path 452. Also, a

hopper 7 through which the thin laminas N of the cast alloy supplied from the casting

device 2 is disposed on the entrance-side of the thin lamina-path 452. The table feeder

461 is disposed on the exit-side of the thin lamina-path 452. The container 305 is

disposed under the table feeder 461. The table feeder 461 includes a table 462; a

rotating blade 463 provided on the table 462; a driving member 464 disposed beneath the

table 462 which rotates the rotating blade 463.

When the thin laminas N of the cast alloy are supplied to the above-described

vertical furnace 451, the inside of the thin lamina-path 452 is filled with the thin laminas N of the cast alloy, and the thin laminas N of the cast alloy are successively pushed out

from the thin lamina-path 452. The pushed out thin laminas N of the cast alloy are

mounted on the table 462 of the table feeder 461, but they are further pushed out to the

circumference of the table 462 when the rotating blade 463 rotates, and they are dropped

into the container 305. The thin laminas N of the cast alloy are kept at a predetermined

temperature or heated with the outside heater 453 while they pass through the thin

lamina-path 452. The temperature-keeping time can be adjusted by controlling the

balance between the supplying rate of the thin laminas N of the cast alloy to the vertical

furnace 451, and the discharging rate of the thin laminas N of the cast alloy at the table

feeder 461.

Thus, according to the heating device shown in FIG. 15, the successively

supplied thin laminas N of the cast alloy can be kept at a predetermined temperature or

heated, and the period for the temperature-keeping or heating can be also fixed.

Next, another embodiment of the apparatus for producing an alloy is further

described, wherein a vibrating feeder equipped with a heater is provided between a

casting device and a heating device in order to uniformly keep the temperature of the thin

laminas N of the cast alloy directly uniform after crushing. The structure is shown in

FIG. 16.

In the production apparatus shown in FIG. 16, a vibrating feeder 501 equipped with a heater is disposed between the casting device and the heating device. In brief,

the vibrating feeder 501 equipped with a heater includes a thin lamina-path 502 having

an inclined plane 502a; a vibration-generating device 503 that vibrates the inclined plane

502a; and heater 504 disposed over the thin lamina-path 502.

A hopper 502b which is a path- way for the thin laminas of the cast alloy crushed

by a crushing device 21 is disposed at the upstream of the thin lamina-path 502. Also,

the inclined plane 502a has an outlet 502c at the downstream of the thin lamina-path 502,

and a metal net 502d is attached to the outlet 502c. A retrieving outlet 502e is provided

at the downstream from the outlet 502c to retrieve the thin laminas of the cast alloy

having large particle sizes that could not pass through the metal net 502d_s and a

retrieving plate 502f is provided under the retrieving outlet 502e.

In addition, projections may be provided on the inclined plane 502a to entirely

spread the sliding thin laminas of the cast alloy in the cross direction of the inclined plane

502a.

When the thin laminas of the cast alloy are supplied to the vibrating feeder 501

equipped with a heater, the thin laminas of the cast alloy slide off on the inclined plane

502a which is vibrated by the vibration-generating device 503. Then, the thin laminas

of the cast alloy having small particles sizes pass through the metal net 502d, and drop

from the hopper 7 into the heating device 3. On the other hand, the thin laminas of the cast alloy having large particle sizes further slide down onto the metal net 502d, and they

are retrieved in the retrieving plate 502f from the retrieving outlet 502e. The thin

laminas of the cast alloy are kept at a predetermined temperature or heated by the heater

504 while they slide down on the thin lamina-path 502. Accordingly, the temperature of

the thin laminas of the cast alloy directly after crushing can be made uniform.

In addition, the present invention is limited to the above-described embodiment,

and additions, omissions, substitutions, and other modifications can be made without

departing from the spirit or scope of the present invention. For example, the

configuration of the opening-closing stages 33 is not limited to the above-described

embodiment. For example, the opening-closing stages 33 shown in FIG. 11 may be

applied.

FIG. 17A shows an embodiment in which a rotating shaft 52 is provided at the

center of a stage plate 51. In this embodiment, the motion of opening and closing can

be achieved by rotating the rotating shaft 52 in one direction.

Also, FIG. 17B shows another embodiment in which slightly inclined stage

plates 61 having a rotating shaft 62 are provided, and a fixing member 64 having an

inclined plane 63 is set to face the stage plate 61 to form an opening-closing stage. In

this embodiment, the stage plate 61 is faced to the fixing member 64 to form a groove 65,

the thin laminas of the cast alloy are piled in the groove 65, and therefore, thin laminas are prevented from scattering around.

As an example of a driving member for the container 5, a belt conveyor 51 is

shown. However, for example, the container 5 may be equipped with a truck having

wheels to form a vehicle-type container, and the truck may be designed to run on a

railroad which is built in the apparatus.

Furthermore, the following embodiments can be applied instead of installing the

cooling plate inside the container.

One example is a storage container wherein a stainless steel net is provided

parallel to the bottom of the container so as to form a space between the stainless steel

net and the bottom of the container, and an inert cooling gas is injected thereto. In this

device, the thin laminas of the cast alloy can be cooled by injecting a cooling gas thereto

directly after they are dropped and retrieved therein, and the cooling rate for the thin

laminas of the cast alloy can be further modulated by adjusting the volume of the cooling

gas injected thereto.

In the above-described example, they are cooled by way of the gas-phase

cooling with a gas flowing between the piles. Therefore, if a large amount of the thin

laminas of the cast alloy is piled, and the container is large, then the piles also tend to be

large, and their cooling rate may be accidentally limited, or they may be ununiformly

cooled depending on the position of the container. Such problems may be solved by applying another example, wherein the inside

of the storage container is partitioned with a plurality of hollow partition panels, a

cooling medium flows inside the hollow partition panels, and the cooling rate of the thin

laminas of the cast alloy can be sped up by way of the contact cooling between the

hollow partition panels and the thin laminas of the cast alloy. According to this

technique, the cooling medium does not have direct contact with the thin laminas of the

cast alloy. Therefore, a gas such as air other than inert gases, or a liquid such as water

can be used as a cooling medium.

Yet another embodiment can be mentioned. This embodiment utilizes the

technique in which vents holes are made at the bottom parts of the above-described

hollow partition panels, and a part of the inert gas that is injected into the panels is

released from the vent holes to the inside of the storage container to cool the thin laminas

of the cast alloy. In general, it is effective to cool the thin laminas of the cast alloy as

rapidly as possible with regard to cooling after the organizations inside the alloy are

solidified. In particular, such rapid cooling is preferable when casting is continuously

conducted.

Another heater can be provided on the down side of the stage plate 33 a of the

opening-closing stage 33, and the stage plate 33a may be heated by this heater. This

heater may be used in combination with the heater 31. In addition, this embodiment may be applied to the above-described heating device 103 or 203.

Also, a heat-insulated structure may be provided on the down side of the stage

plate 33a of the opening-closing stage 33 in order to prevent the heat generated from the

heater 31 from transmitting to the inside of the container 5. In this case, as examples of

such a heat-insulated structure, blocks or fibrous boards made of ceramics such as

alumina and zirconia may be disposed on the down side of the stage plate 33a, or a

plurality of thin metal plates are piled on the down side of the stage plate 33 a while

having a space between them. With regard to the materials for the thin metal plate,

those having a melting temperature lower than the temperature of the thin laminas of the

cast alloy can be used, and iron or stainless steel, for example, may be used, hi

addition, this embodiment can be applied to the above-described heating device 103 or

203.

Also, a heater may be provided in hopper 7 to prevent the thin laminas of the

cast alloy from being cooled.

Also, the production apparatuses of the present invention can be applied to

produce a thermoelectric semiconductor alloy or hydrogen absorbing alloy other than R—

T-B type alloy.

The thermoelectric semiconductor alloys, for example, include alloys

represented by the general formula A₃-_XB_XC (wherein A and B represent at least one element of transition metals such as Fe, Co, Ni, Ti, V, Cr, Zr, Hf, Nb, Mo, Ta and W; and

C represents at least one element of Group 13 or 14 such as Al, Ga, In, Si, Ge, and Sn).

Also, the thermoelectric semiconductor alloys can includes, for example, alloys

represented by the general formula ABC (A and B represent at least one element of

transition metals such as Fe, Co, Ni₅ Ti, V₅ Cr₅ Zr, Hf, Nb, Mo, Ta and W; and C

represents at least one element of Group 13 or 14 such as Al, Ga, In, Si, Ge₅ and Sn).

Moreover, rare earth alloys represented by the general formula

RE_x(Fe₁-yMy)4Sbi2 (wherein RE represents at least one element of La and Ce; and M

represents at least one element selected from the group consisting of Ti₅ Zr, Sn₅ and Pb

where 0 < x < 1 and 0 < y < 1 ) can be also mentioned.

Furthermore, rare earth alloys represented by the general formula

(wherein RE represents at least one element of La and Ce; and M

represents at least one element selected from the group consisting of Ti, Zr, Sn, Cu, Zn,

Mn and Pb where 0 < x < 1 and 0 < y < 1) can be also mentioned.

As examples of the hydrogen absorbing alloy, AB₂-type alloys (those using a

base material of a transition element alloy such as Ti, Mn, Zr and Ni) or AB₅-type alloys

(those using a base material of an alloy containing 5 parts of a catalytic transition element

(Ni, Co, Al or the like) with respect to 1 part of a rare earth element, Nb, and/or Zr) can

be mentioned. Examples

The material mixture of neodymium metal, dysprosium metal, ferroboron,

cobalt, aluminum, copper, and iron (where the alloy composition ratio becomes 22% of

Nd, 9.5% of Dy, 0.96% of B, 1.0% of Co, 10.15% of Al, 0.10% of Cu, and the balance

being Fe) was molten in the atmosphere of an argon gas at 1 arm pressure in the

high-frequency melting furnace using an alumina crucible in order to prepare a molten

alloy.

Then, this molten alloy was supplied to the casting device of the production

apparatus shown in FIG. 1, this was cast by way of the SC method, and crushed to

produce thin laminas of the cast alloy.

In addition, the diameter of the cooling roll was 600 mm, the material of the

cooling roll was an alloy in which a small amount of Cr and Zr is mixed with copper.

The inside of the cooling roll was water-cooled, and the circumferential speed of the roll

was 1.3 m/s when casting. The average temperature of the cast alloy M when

separating from the cooling roll was measured with a radiation thermometer, and it was

found 89O⁰C. Furthermore, with regards to the measured values, the difference between

the maximum temperature and the minimum temperature was 35°C. The melting

temperature of the R₂T₁₄B-phase of the produced alloy was about 1170°C. Therefore,

the difference between the melting temperature and the average temperature was 28O⁰C. In addition, the average cooling rate of the blocks of the cast alloy on the cooling roll was

980°C/second, and the average thickness was 0.29 mm.

The produced thin laminas of the cast alloy were allowed to pass through the

hopper 7 of the production apparatus shown in FIG. 1, and they were piled on the

opening-closing stages. Then, they were subjected to the temperature-keeping

treatment where they were kept at 700⁰C to 900°C for one minute (700°C in Example 1;

800°C in Example 2; and 900⁰C in Example 3). In this way, thin laminas of the cast

alloy formed by Examples 1 to 3 that were formed of the rare earth alloys were prepared.

On the other hand, thin laminas of the cast alloy of Comparative Example 1

were produced in the same manner as Examples 1 to 3 except that the

temperature-keeping treatment was not conducted.

Then, each of thin laminas of the cast alloy was pressed with a molding machine

in an atmosphere of 100% nitrogen and in the transverse magnetic field. The molding

pressure was set 0.8 1 / cm² and the magnetic field of 15 kOe was generated in the mold

cavity. The obtained compact was kept in a vacuum of 1.33 x 10^"5 hPa at 500⁰C for one

hour, then kept in a vacuum of 1.33 x 10^"5 hPa at 800⁰C for two hours, and further kept

in a vacuum of 1.33 * 10^'5 hPa at 1030⁰C for two hours whereby the compact was

sintered. Their sintered densities ranged from 7.67 to 7.69 g/cm³ or more, and they had

sufficient densities. These sintered products were further heated in an atmosphere of argon at 530⁰C for one hour whereby R-T-B type magnets of Examples 1 to 3 and

Comparative Example 1 were produced.

The magnetic properties of the obtained R-T-B type magnets were measured

with a pulse-type B-H curve tracer. The result is shown in FIG. 18. FIG. 18 shows a

relationship between the temperature for the temperature-keeping treatment, and the

coercive force of the R-T-B type magnets with respect to Examples 1 to 3 and

Comparative Examples 1.

As shown in FIG. 18, it was revealed that the coercive forces of the R-T-B type

magnets of Examples 1 to 3 that were subjected to the temperature-keeping treatment

were improved by about 3% with respect to Comparative Example 1 that was not

subjected to the temperature-keeping treatment.

INDUSTRIAL APPLICABILITY

According to the present invention, the apparatus for producing an alloy can

produce an R-T-B type magnet having high coercive force as well as reducing the cost

with regard to the material used therein. The produced R-T-B type magnets can be

applied to industrial products such as hard disks, MRI apparatuses and motors.

Furthermore, the production apparatus of the present invention can be applied to the

production of a thermoelectric semiconductor alloy or hydrogen absorbing alloy other 2

55

than the R-T-B type alloy. Therefore, the apparatus for producing an alloy of the

present invention has high industrial applicability.

Claims

1. An apparatus for producing an alloy, comprising:

a casting device which casts a molten alloy using the strip cast method;

a crushing device which crushes the cast alloy after casting; and

a heating device which keeps the thin laminas of the cast alloy after crushing at a

predetermined temperature, or which heats the thin laminas of the cast alloy after

crushing, wherein

the heating device is equipped with a container and a heater.

2. The apparatus for producing an alloy according to claim 1, wherein a hopper and

the heating device are disposed below the crushing device.

3. The apparatus for producing an alloy according to claim 2, wherein the heater

has an opening part, and an outlet of the hopper is disposed in the opening part.

4. The apparatus for producing an alloy according to claim 3, wherein the container

is equipped with a storage container, and an opening-closing stage disposed over the

storage container; the thin laminas of the cast alloy supplied from the crushing device are mounted on the opening-closing stage when the opening-closing stage is in a closed

state; and the opening-closing stage releases the thin lamina of the cast alloy to the

storage container when the opening-closing stage is in an opened state.

5. The apparatus for producing an alloy according to claim 4, wherein the

mounted on the opening-closing stage.

6. The apparatus for producing an alloy according to claim 5, wherein the heater

keeps the thin laminas of the cast alloy mounted on the opening-closing stage at a

predetermined temperature, or the heater heats the thin laminas of the cast alloy mounted

on the opening-closing stage.

7. The apparatus for producing an alloy according to claim 6, further comprising a

driving device which enables the container to move freely.

8. The apparatus for producing an alloy according to claim 7, wherein the container

is equipped with a plurality of the opening-closing stages, and the plurality of the W

58

opening-closing stages is disposed along the moving direction of the container.

9. The apparatus for producing an alloy according to claim 8, wherein the thin

laminas of the cast alloy are sequentially mounted on each opening-closing stage by

moving the container in accordance with preparation of the thin laminas of the cast alloy.

10. The apparatus for producing an alloy according to claim 8 or 9, wherein the

cast alloy are mounted on the opening-closing stages.

11. The apparatus for producing an alloy according to claim 10, wherein the

opening-closing stage includes a stage plate, and an opening-closing system which opens

and closes the stage plate while the opening-closing system controls the inclining angle

of the stage plate; the opening-closing system mounts the thin laminas of the cast alloy

on the stage plate by adjusting the stage plate at a horizontal position or a inclining

position when the opening-closing stage is in a close state; and the opening-closing

system releases the thin laminas of the cast alloy to the storage container by making the

inclining angle of the stage plate larger when the opening-closing stage is in an open state.

12. The apparatus for producing an alloy according to claim 11 , wherein the

13. The apparatus for producing an alloy according to claim 12, wherein the heater

is disposed between the crushing device and the opening-closing stages along the moving

direction of the container.

14. The apparatus for producing an alloy according to claim 3, wherein a belt

conveyor or a pushing device is disposed between the heater and the container.

15. The apparatus for producing an alloy according to claim 1 , wherein the casting

device, the crushing device and the heater are disposed inside a chamber of an inert gas

atmosphere.

16. The apparatus for producing an alloy according to claim 15, wherein a cooling W 2

60

chamber.

17. The apparatus for producing an alloy according to claim 1 , wherein the alloy is a

rare earth element-containing alloy.

18. The apparatus for producing an alloy according to claim 17, wherein the rare

earth element-containing alloy comprises an R-T-B type alloy where R is at least one

element of rare earth elements including Y; T is a metal which indispensably contains Fe;

and B is boron.

19. The apparatus for producing an alloy according to claim 1, wherein the alloy is

a hydrogen absorbing alloy.

20. The apparatus for producing an alloy according to claim 1 , wherein the alloy is a

thermoelectric semiconductor alloy.

21. An alloy which is produced with the apparatus for producing an alloy according

to claim 1.

22. A rare earth element-containing alloy which is produced with the apparatus for

producing an alloy according to claim 1.

23. A hydrogen absorbing alloy which is produced with the apparatus for producing

an alloy according to claim 1.

24. A thermoelectric semiconductor alloy which is produced with the apparatus for

producing an alloy according to claim 1.

25. A rare earth magnet, comprising the rare earth element alloy according to claim

22.