WO2007081011A1 - Exothermic-element folding apparatus - Google Patents

Exothermic-element folding apparatus Download PDF

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Publication number
WO2007081011A1
WO2007081011A1 PCT/JP2007/050438 JP2007050438W WO2007081011A1 WO 2007081011 A1 WO2007081011 A1 WO 2007081011A1 JP 2007050438 W JP2007050438 W JP 2007050438W WO 2007081011 A1 WO2007081011 A1 WO 2007081011A1
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WO
WIPO (PCT)
Prior art keywords
heating element
folding
heating
belt
folded
Prior art date
Application number
PCT/JP2007/050438
Other languages
French (fr)
Japanese (ja)
Inventor
Toshihiro Dodo
Original Assignee
Mycoal Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mycoal Co., Ltd. filed Critical Mycoal Co., Ltd.
Publication of WO2007081011A1 publication Critical patent/WO2007081011A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F7/00Heating or cooling appliances for medical or therapeutic treatment of the human body
    • A61F7/02Compresses or poultices for effecting heating or cooling
    • A61F7/03Compresses or poultices for effecting heating or cooling thermophore, i.e. self-heating, e.g. using a chemical reaction
    • A61F7/032Compresses or poultices for effecting heating or cooling thermophore, i.e. self-heating, e.g. using a chemical reaction using oxygen from the air, e.g. pocket-stoves
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F7/00Heating or cooling appliances for medical or therapeutic treatment of the human body
    • A61F2007/0098Heating or cooling appliances for medical or therapeutic treatment of the human body ways of manufacturing heating or cooling devices for therapy

Definitions

  • the present invention relates to a device for folding a heating element by folding guide means for folding a folding part of the heating element that is conveyed while being stacked on the surface of the conveying means by a folding support means.
  • the exothermic agent accommodating portion is divided by a substantially straight intermediate seal portion formed in the approximate center, and each exothermic agent accommodating portion bulges toward the breathable sheet with respect to the non-breathable sheet.
  • the body of the warmer formed in a protruding shape is provided with a release layer on one side of the packaging sheet, and the packaging sheet is mounted so as to be superimposed on the adhesive layer formed on the release layer.
  • the folding roll is sandwiched between the folding guide plate and the folding transport belt in a state where the folding half is overlapped with the fixed half side, and is pulled downstream with a predetermined tension by the press belt.
  • Patent Document 1 discloses a method of sealing in a bag shape by sealing edges that face each other at the peripheral edge except for the bent portion in a state where the release layer is in close contact with the outside of the adhesive layer. Has been.
  • Patent Document 1 an adhesive layer is formed on the release layer on the side of the packaging sheet, and the body body is attached so as to overlap the adhesive layer.
  • This is a folding device that can be applied only to force iro, and was a folding method.
  • a pressure-sensitive adhesive layer is formed on the side of the body that is generally used, and is attached to a non-breathable packaging sheet, that is, a pressure-sensitive adhesive layer with a separator is attached to an outer bag that is a non-breathable storage bag. The force that cannot be applied to the folding of the heating element provided.
  • Another problem is that the folding finish is unstable and defective products tend to occur.
  • Patent Document 1 Japanese Patent Application Laid-Open No. 2004-344328
  • the present invention has been made to solve the above-described problems, and an object of the present invention is to obtain a heating element folding device that can stably obtain a good folding finished product even at high speed operation.
  • the heating element folding device arranges the molded heating composition adjacent to the substrate and coats it with a coating material, thereby forming the molded heating element.
  • the heating element folding device includes: a belt for transporting the divided heat generating part located on one end side of the heating element; and the divided heating part located on the other end side of the heating element.
  • a folding guide plate is also provided in which the force on the other end side of the belt is curved toward the one end side in the transport direction.
  • the present invention described in claim 2 is the heating element folding apparatus according to claim 1, wherein the heating element folding apparatus includes a gas supply device, and the gas from the gas supply device is guided to the guide. It is characterized by blowing along the inner surface of the plate.
  • the present invention according to claim 3 is the heating element folding device according to claim 2, further comprising a belt for conveying the outer divided heat generating portion on the side of the central belt, The gas of the gas supply device force is also blown out to the belt surface.
  • a magnet is provided along the outer edge side of the outer side of the folding guide plate. It is characterized by that.
  • the molded exothermic composition is disposed adjacent to the substrate and covered with a coating material, and the peripheral portion of the molded exothermic composition is sealed.
  • a heating element folding device for folding a heating element comprising a plurality of segment heating parts containing a heating composition via a sorting part as a seal part by folding the sorting part, wherein the heating element
  • the folding device includes a belt for conveying the divided heat generating portion located on one end side of the heating element and the divided heating portion located on the other end side of the heating element toward the downstream side in the conveying direction.
  • a folding guide base having a curved surface directed from one end side to the other end side of the belt in the transport direction is provided.
  • the invention according to claim 6 is the heating element folding apparatus according to any one of claims 1 to 5, wherein the heating element is in contact with at least one of the folding guide plate and the folding guide base. It is characterized in that a material having slidability is provided on the surface on the side to be processed.
  • the heating element folding device wherein the molded exothermic composition is disposed adjacent to the substrate and covered with a coating material, and the peripheral portion of the molded exothermic composition is covered.
  • a heating element folding device for sealing and heating a heating element comprising a plurality of segmented heating elements containing a heating composition via a partitioning part that is a sealing part, with the partitioning part being folded.
  • the heating element folding device includes a belt for transporting the divided heating section, and includes a roller having a shaft that intersects the belt surface.
  • the present invention according to claim 8 is directed to the heating element folding device according to claim 7.
  • a wrapping sheet supply device is provided between the belt and the conveyor belt for supplying the wrapping sheet.
  • the present invention according to claim 9 is the heating element folding device according to any one of claims 5 to 8, wherein the heating element folding apparatus is external to at least one part selected from the heating element and the packaging sheet. It is provided with an adhesive installation device for providing a temporary adhesive.
  • the heating element according to the present invention, as described in claim 10, is produced by at least one selected from the heating element folding apparatus according to any one of claims 1 to 9, and is folded into two or more. The rare heating element is sealed in a non-breathable storage bag.
  • the heating element according to claim 11 is the heating element according to claim 10, wherein at least a part of the exposed portion of the heating element is temporarily attached to at least a part of the non-breathable storage bag. It is sealed in a bag.
  • the heating element folding device is a device that folds a folded portion of a heating element that is transported while being stacked and maintained on the surface of the conveying means by means of a folding support means and a folding guide means, and a portion of the heating element that is not folded is provided.
  • the folding support means supports the unfolded portion of the heating element, and the folding part of the heating element is folded by the folding supporting means and the folding guide means as the conveying means moves, and the heating element
  • the conveying means, the folding support means, and the folding guide means are arranged so as to have a function of folding, and the conveying means is at least one selected from an endless belt and a packaging material force, and the folding guide means is a folding guide plate.
  • Folding endless belt, packaging material, presser plate, and folding support means Inner base, plate-shaped folding guide base, frame presser roll.
  • at least one selected from magnet magnets is used.
  • the heating element folding device is a device that folds a folded portion of a heating element that is transported while being stacked and maintained on the surface of the conveying means by means of a folding support means and a folding guide means, and a portion of the heating element that is not folded is provided.
  • the folding support means supports the unfolded portion of the heating element, and the folding part of the heating element is folded by the folding supporting means and the folding guide means as the conveying means moves, and heat is generated.
  • the conveying means, the folding support means, and the folding guide means are arranged so as to have a function of folding the body, and the conveying means is at least one selected from an endless belt and a packaging material force, and the folding guide means is the folding guide.
  • At least one selected from the group consisting of a plate, a folded endless belt, a packaging material, and a pressing plate, and the folding support means is a folding guide stand, a plate-shaped folding guide stand, a frame pressing roll, and a magnet force.
  • the endless belt is divided into a center of the width of the central portion of the heating element and an endless belt on both sides thereof, and at least the center of the heating element is supported by folding support means, and the endless belts on both sides Is the minimum length required for scooping up both sides of the heating element, and the center bell It is preferred that the folding support means between the two sides of the belt and clamped by the spacing portion does not act as.
  • the folding device is provided with a gas nozzle and a gas supply device so as to blow gas between the front end portion of the guide means and the transport means.
  • the folding device is provided with a magnet on the back surface portion located on the opposite side of the heating guide of the folding guide means.
  • At least one kind of material selected from the folding guide means and the folding support means is made of a material having a sliding property.
  • the heating element folding device of the present invention is a device that folds the folded portion of the heat generating body that is transported while being stacked and maintained on the surface of the conveying means by the folding support means and the folding guide means, and the conveying means is folded with the folding support means.
  • the heating means stacked on the conveying means has a function of being folded by the guiding means, the conveying means is a packaging material, and the guiding means and the supporting means are a pair of endless belts.
  • the end side of the pair of endless belts is shifted by 90 ° from the entrance side which is one end of the pair of endless belts and the exit side which is the other end. It is preferable that the rotary shafts are parallel to each other, and that one surface of the two endless belts is disposed so as to sandwich the conveying means.
  • the heating element folding device of the present invention is a device that folds the folded portion of the heating element that is transported while being stacked on the surface of the conveying means by the folding support means and the folding guide means.
  • the conveying means is a packaging material
  • the guiding means and the supporting means are composed of two pairs of endless belts consisting of a front folding means and a rear folding means
  • the front folding means is the pair of endless belts.
  • the inlet side which is one end of the endless belt, is shifted by 90 ° from the outlet, which is the other end, and the rotation axis is the same at one end, and the rotation axes are parallel at the other end.
  • One end face of the two endless belts are disposed so as to sandwich the means, and the rear folding means is configured such that the input side which is one end of the pair of endless belts and the output side which is the other end are 90 °. ° Deviation and one end and the other end.
  • the rotation shafts are parallel and that one surface of the two endless belts is disposed so as to face each other so as to sandwich the conveying means. ,.
  • a packaging sheet exists between the conveying surface of the endless belt and the heating element, and the packaging sheet supply device is provided so as to fold and fold the heating element while wrapping the heating element.
  • the folding device includes a heating element provided with an interval, with the heating element containing a heating composition, and a plurality of three or more divided heating parts being separated from each other by a section not containing the heating composition. Preferred to be.
  • the folding device is provided with a magnet along a path along which the heating element is folded, at least one selected from the folding guide plate and the folding guide base.
  • Folding that has been done manually can be done automatically, so it is extremely easy and efficient to enclose an outer bag that is a folded heating element or folded and non-breathable container.
  • the produced heating element can be manufactured.
  • a flexible heating element with multiple section heating parts can be folded continuously, smoothly and easily, improving workability and improving work efficiency, making it extremely easy
  • an automatic supply device that automatically supplies heating elements in accordance with the conveyance of the heating elements to be folded, it is possible to partially automate the folding work of a small amount of heating elements that are created independently. It can be further increased.
  • the width of the endless belt of the heating element folding device is the width of the central part of the heating element, the folding guide plate that folds up by folding up the folding parts on both sides of the heating element does not come into contact with this belt and generates frictional heat. Will not occur.
  • At least one part selected from a heating element and a packaging sheet (such as a non-breathable packaging material) provided with two or more divided heating parts via the dividing part can be provided with an adhesive for temporary wearing.
  • a heating element and a packaging sheet such as a non-breathable packaging material
  • the heating element and the non-breathable packaging material can be folded accurately without causing a deviation, and the yield and production speed can be improved.
  • At least the heating element and the surface material in contact with Z or the packaging material are made of material with excellent slidability, so friction is reduced and the heating element can be folded more smoothly.
  • FIG. 1 shows an example of a heating element folding device of the present invention, in which (a) is a perspective view, (b) is a plan view, and (c) is a side sectional view.
  • FIG. 2 shows another example of the heating element folding device according to the present invention, where (a) is a plan view and (b) is a side sectional view.
  • FIG. 3 shows another example of the heating element folding device of the present invention, where (a) is a plan view and (b) is a side sectional view.
  • FIG. 4 is a side sectional view showing another example of the heating element folding device according to the present invention.
  • FIG. 5 shows another example of the heating element folding device according to the present invention, where (a) is a plan view and (b) is a side cross-sectional view.
  • FIG. 5 shows another example of the heating element folding device according to the present invention, where (a) is a plan view and (b) is a side cross-sectional view.
  • FIG. 6 Another example of the heating element folding device of the present invention is shown, (a) is a plan view, and (b) is a side sectional view.
  • FIG. 7 Another example of the heating element folding device of the present invention is shown, (a) and (b) are perspective views, and (c) are front sectional views.
  • FIG. 8 Another example of the heating element folding device of the present invention is shown, (a) is a plan view, (b) is a perspective view of the folding guide base, and (c) is a perspective view of the folding guide base.
  • FIG. 10 Another example of the heating element folding device of the present invention is shown, (a) is a perspective view, (b) is a perspective view of a folding guide base, (c) is a side view of the folding guide base, (d ) Is a plan view of the folding guide stand.
  • FIGS. 11A and 11B are cross-sectional views showing an example of an automatic filling device of the heating element folding device of the present invention.
  • FIG. 12 shows an example of folding of the heating element folding device of the present invention
  • (a), (e), (h) are plan views
  • (b), (d), (f), (g) are It is explanatory sectional drawing.
  • FIG. 13 is a perspective view showing another example of the heating element folding device according to the present invention.
  • FIG. 14 is a perspective view showing another example of the heating element folding device according to the present invention.
  • FIG. 15 is a plan view showing another example of the heating element folding device according to the present invention.
  • FIG. 16 Another example of the heating element folding device of the present invention is shown, (a) and (b) are perspective views, (c) is a front sectional view, and (d) is a front sectional view.
  • FIG. 17 shows another example of a frame holding roll of the heating element folding device of the present invention, (a) is a perspective view, (b) is a side sectional view, (c) is a plan view, and (d) to (h) ) Is a side cross-sectional view, and (i) is a side view of a pressing plate (having a sliding surface).
  • FIGS. 18A to 18C are perspective views showing another example of the outer bag folding device of the present invention.
  • FIG. 19 is a side cross-sectional view for explaining a manufacturing process of a folded heating element enclosed in an outer bag which is a non-breathable storage bag of the present embodiment.
  • FIG. 20 shows a heating element of the present invention
  • (a), (d), (e), (i), (j) are plan views
  • (b), (c), (f), ( g) and (h) are cross-sectional views.
  • FIG. 21 is a plan view showing a modification of the heating element of the present invention. Explanation of symbols
  • various conveying means, various folding support means, and various folding guide means can be combined in any combination including overlapping.
  • the folding guide means has a function composed of scooping guide, flip-up guide, inward guide and folding plan, and one means may have all functions or a plurality of means. Combine and have all the functions.
  • a folding guide plate and a folding guide bar are formed by continuously providing a scooping guide portion, a flip-up guide portion, an inward guide portion, and a folding guide portion in one means. Also, it may be physically deformed, leaving a function, such as a folding guide plate that folds with a planar object, a folding guide bar that folds with a linear object or a belt-like object, or a folding guide plate or folding A magnet may be provided on the guide bar.
  • the magnet may be provided in an arbitrary region as long as it does not interfere with the folding of the heating element body, either on the side of the folding guide plate or the folding guide bar that does not contact the heating element body or between the side that does not contact the heating guide body.
  • Folding planks and bars may be provided inside the hollow west or on the inner wall. Further, when it is provided on the side in contact with the heating element body, it is preferably embedded in the surface.
  • Examples of the magnet that is the folding support means include an electromagnet and a permanent magnet as long as they have a magnetic force.
  • Examples of installation methods include those that are fixed without contact with the other surface, those that are fixed rotatably, those that are attached to an endless belt, and move with the endless belt.
  • the heating element When the heating element is laminated on the packaging material and folded, at least a part of the exposed part of the heating element is temporarily attached to the packaging material with a weak adhesive or the like! Well ...
  • temporary attachment is for temporarily holding the heating element on the packaging material so that the heating element does not move during movement or folding.
  • a coating device for providing a temporary attachment layer made of an adhesive or the like on the heating element and z or the packaging material is provided.
  • the separator is also treated as a part of the heating element.
  • the heating element of the present invention is not limited as long as it can be folded, but a heating element having two or more section heating sections and one or more section sections is preferable.
  • a heating element having two or more section heating sections and one or more section sections is preferable.
  • a heating element in which a cut is provided in at least a part of the area other than the segment heating part is preferable.
  • a heating element folded at a predetermined section of the heating element and enclosed in an outer bag which is an airtight storage bag is preferable.
  • a heating element is preferred in which at least a part of the exposed part of the heating element is temporarily attached to at least a part of the outer bag which is an airtight storage bag.
  • At least a part of the exposed part of the heating element is temporarily attached to at least a part of the outer bag which is an airtight storage bag, and the temporary attachment is 180 degree peel strength (JIS Z-0287) force. Heating elements that are temporary in the range of 9kg / 25mm are preferred.
  • the incision in the present invention is a through notch, and includes a connecting portion force that is an interval between the incision and the incision.
  • the size (length, width, etc.) and their combinations can be any combination with no restrictions or any repeated combination.
  • the connecting portion is preferably shorter than the cut.
  • the shape of the notch is not limited.
  • At least one end of the cut may or may not be in contact with at least one side of the heating element.
  • a V-notch may be provided at the contact point between the extending direction of at least one section and at least one side of the heating element.
  • At least one end of the cut may or may not be in contact with a notch provided near at least one side of the heating element.
  • the notches in the present invention are alternate notches, alternate notches with V notches, V notches, perforations with V notches (such as perforated perforations with V notches), notches with V notches, and heating elements. Any number may be provided in a region other than the divided heat generation, preferably at an arbitrary position of the dividing portion.
  • a notch is formed between one side of the partitioning part and the other side corresponding thereto in the middle of the partitioning part which is a seal part between the adjacent partitioning heat generating parts.
  • a heating element that enables expansion and contraction.
  • a notch is formed from one side of the segmented portion to the other side corresponding to the middle of the segmented portion which is a seal portion between the adjacent segmented heat generating portions, and each segmented heat generating portion is divided by this notch. It is a heating element that can be (separated).
  • the V notch may be replaced with another notch such as a U notch or an I notch.
  • the installation location and number of the cuts in the heating element of the present invention an arbitrary number other than the divided heat generating portion can be provided.
  • the divided portion is preferable.
  • the notch provided in the heating element having the separator may be a notch that penetrates the separator, or may not be penetrated through the separator! /.
  • the staggered cut of the present invention is a joint that is not cut (or cut) and non-cut.
  • At least one set of cuts in which the arrangement period of the cut portion and the connecting portion is different, at least in one direction.
  • the cuts are arranged at intervals and arranged so that the arrangement cycle of adjacent cuts is different in one direction, and the two rows are combined into one pair, the V difference, the cut and three rows are combined into one set Examples are mutual, different, incision, mutuality, incision, and inconsistency, incision, 5th row, and incision.
  • Examples of preferred, different, and incisions include the following. 1. A plurality of cuts are arranged in a staggered pattern.
  • a plurality of cuts are arranged in different directions (eg, right angles) in one direction of cut (longitudinal direction, etc.).
  • the trajectory connecting the three nearest non-incision center points in the incision direction is non-linear (bending A plurality of incisions with three nearest non-incisions satisfying a straight line having an angle that is not 90 ° with respect to the incision direction.
  • Linear full refers to a compressed portion or a thin portion that does not penetrate.
  • At least one end of the staggered cut may or may not be in contact with at least one side of the heating element.
  • the shape, type and size (length, width, etc.) of each notch, the shape, type, size (length, width, etc.) of each interval, and combinations thereof are limited. Arbitrary combinations and arbitrary repetition combinations can be made.
  • the notches of the above and the other are provided in a direction substantially perpendicular to the direction expanded and contracted.
  • the number of cuts, the number of rows of cuts, and the like can be appropriately selected and used.
  • staggered arrangement means that the notches can be deformed into a mesh shape or the like so that the packaging material such as a non-stretchable material or a non-stretchable material can be stretched and Z or stretched.
  • the joint is integral and the mesh is expanded while only a certain length of cut is inspected. Can be formed.
  • a metal lascaro such as JIS-A5505 can be used as an example.
  • JIS-A5505 JIS-A5505
  • the length, longest diameter or longest side of the notch is not limited, but is preferably 1 to 100 mm, more preferably 1 to 50 mm, and even more preferably 1.5 to 50 mm. More preferably, it is 2-30 mm, More preferably, it is 5-20 mm.
  • the width, the shortest diameter, or the shortest side is not limited, but is preferably more than 0 to 50 mm, more preferably ⁇ to 0.01 to 50 mm, and more preferably ⁇ to 0.01 to 30 mm. More preferably, it is 0.1 to 20 mm, more preferably 0.1 to 20 mm, more preferably 0.1 to 10 mm, and more preferably 0.1 to 5 mm. . It should be noted that the minimum value of the width of the linear notch is not limited. The maximum value is 50 mm or less, more preferably as described above.
  • the length of the connecting portion which is the interval between adjacent cuts in the extension direction of the cut, is not limited, but is preferably 0.01 to 20 mm, more preferably 0.01 to: LOmm, and even more preferable. Or 0.1 to LOmm, more preferably 0.1 to 8 mm, and still more preferably 0.1 to 7 mm. More preferably, it is 0.1-5 mm.
  • the distance between adjacent cuts in the direction perpendicular to the cut extension direction is not limited, but is preferably 0.1 to 20 mm, more preferably 0.1 to 15 mm, and still more preferably 0. l to 10 mm, more preferably 0.1 to 5 mm, and even more preferably 0.5 to 5 mm.
  • the heating element of the present invention is also an extensibility and Z or stretchable heating element in which an arbitrary number of alternating cuts are provided in an arbitrary region other than the section heating unit.
  • the heating element with staggered cuts according to the present invention is a heating element in which at least one part other than the divided heat generating part is provided with a V and a different cut.
  • the extensibility of the heating elements caused by the difference and the incision is different from each other, and at least a part of the exothermic elements preferably extend in the direction at least approximately perpendicular to the extending direction of the notch. If it stretches, The elongation ratio is not limited as long as it exceeds 1, but it is preferably 1.05 to 10, more preferably 1.01 to 10, even more preferably 1. 01 to 5, more preferably 1.01 to 5, more preferably 1.01 to 3, more preferably 1.01 to 2, and even more preferably 1.02 to 2. More preferably, it is 1.03 to 2, more preferably 1.04 to 2, and still more preferably 1.05 to 2.
  • the alternate cut usually has a function of imparting extensibility and stretchability.
  • tensile strength of the stretchable or stretchable heating element of the present invention there is no limitation on the tensile strength of the stretchable or stretchable heating element of the present invention, but a preferable example is 3N / 50 mm or more.
  • the perforated perforation there is a through-cut, and if the hand can be cut, there is no limit, and there is a force that allows any size, any combination, and any repeated combination in the interval between adjacent cuts. As an example.
  • the diameter is preferably 10 ⁇ ⁇ : LOmm ⁇ , more preferably 10 ⁇ ⁇ 5mm ⁇ , more preferably Is 100 ⁇ ⁇ to 5 mm ⁇ , more preferably 500 ⁇ ⁇ to 0.5 mm ⁇ .
  • the length of the through-cut is preferably 10 ⁇ m to 200 mm, more preferably 10 ⁇ m to 50 mm, and even more preferably 10 ⁇ m to 30 mm.
  • the length of the interval (joining part) between the adjacent cuts and the adjacent cuts is not limited, but is preferably 1 ⁇ m to 10 mm, more preferably 1 ⁇ m to 7 mm, even more preferable. 1 / ⁇ ⁇ to 5 ⁇ , more preferably 0. lmn! ⁇ 5mm, more preferably 0
  • the ratio (W1ZW2) between the length of the cut through (W1) and the length of the joint (W2) (W1ZW2) is preferably more than 1, more preferably more than 1 and not more than 50, and still more preferably 1. 01 to 50, more preferably 1.1 to 50, more preferably 1.5 to 50, and still more preferably 1. 5 to 40, more preferably 2 to 30.
  • At least one end of the perforation may or may not be in contact with at least one side of the heating element.
  • Perforated perforations that can be cut by hand may be provided in the area other than the section heating section with any given interval in the vertical, horizontal, vertical and horizontal directions.
  • the perforation at the section of the heating element is one that has been cut intermittently to improve the bendability of the section, or one that has been cut intermittently to allow hand cutting As an example, it is preferable.
  • the perforations may be provided in all the divisions or may be provided partially.
  • the heating element may be temporarily attached to the inner surface of the outer bag, which is a non-breathable storage bag (hereinafter referred to as outer temporary attachment). If the heating element is temporarily attached to the inner surface of the outer bag, it may be temporarily attached to the inner surface of the outer bag before the heating element is folded, or it may be temporarily attached to the inner surface of the outer bag after being folded. May be.
  • outer temporary attachment a non-breathable storage bag
  • the heating element of the present invention is folded and enclosed in an outer bag which is a non-breathable storage bag.
  • the heating element folding device force according to any one of claims 1 to 9 is produced by at least one kind selected, and has two or more divided heating parts and one or more dividing parts.
  • the heating element is folded into a plurality of parts, and at least a part of the exposed portion of the heating element is temporarily attached to at least a part of the non-breathable storage bag and sealed in the non-breathable storage bag.
  • the packaging material used for the outer bag which is a non-breathable storage bag
  • the non-breathable packaging material or the like is used.
  • the adhesive constituting the re-peeling weak adhesive layer used for external temporary attachment ends the folding operation with weak adhesive strength. There is no limit as long as the heating element can be retained in the packaging material.
  • An example of a removable adhesive that can be used is a weak adhesive.
  • hot-melt adhesives there are hot-melt adhesives, emulsion adhesives, solvent-based adhesives, etc.
  • acrylics that have a high glass transition temperature are preferred, and the ratio of acrylic acid components is increased.
  • rubbers those containing a high melting point tack fire are preferred.
  • a hot melt adhesive particularly a hot melt adhesive (polypropylene adhesive, polyethylene adhesive, ethylene propylene copolymer adhesive, etc.) is preferable.
  • an elastomer such as a thermoplastic elastomer
  • a thermoplastic resin is used as a base polymer.
  • the base polymer may be used alone or in combination.
  • the thermoplastic elastomer of the base polymer in the hot melt adhesive include, for example, styrene isoprene styrene block copolymer (SIS), styrene butadiene styrene block copolymer.
  • SBS styrene ethylene-butylene styrene block copolymer
  • SEBS styrene ethylene-butylene styrene block copolymer
  • SEPS styrene-ethylene-propylene-styrene block copolymer
  • SEP styrene-ethylene-propylene block copolymer
  • Elastomer styrenic block copolymer; for example, styrene-containing block copolymer containing 5% by weight or more of styrene
  • polyurethane-based thermoplastic elastomer polyester-based thermoplastic elastomer
  • polypropylene and EPT (ternary ethylene propylene rubber) Polymer Mention may be made of blends based thermoplastic elastomer Chief such trend The
  • thermoplastic resin of the base polymer in the hot-melt pressure-sensitive adhesive includes, for example, polyolefin resin, vinyl acetate resin, polyester resin, styrene resin, acrylic resin, Examples thereof include polyamide-based rosin.
  • polyolefin resin examples include ethylene copolymers (for example, ethylene vinyl acetate copolymer (EVA); ethylene acrylic acid copolymer (EAA), ethylene-methacrylic acid copolymer (EMAA), etc.) Of ethylene unsaturated carboxylic acid copolymer; ionomer; ethylene (meth) acrylic acid ester copolymer such as ethylene acrylate hexyl copolymer, ethylene methyl methacrylate copolymer, ethylene methacrylate methacrylate copolymer Polyethylene (low density polyethylene, linear low density polyethylene, metaguchisen catalyzed polyethylene, medium density polyethylene, high density polyethylene, etc.), polypropylene, a- olefin copolymer, etc.
  • EVA ethylene vinyl acetate copolymer
  • EAA ethylene acrylic acid copolymer
  • EAA ethylene-methacrylic acid copolymer
  • EAA ethylene-methacryl
  • vinyl acetate-based resin examples include poly (vinyl acetate), butyl (meth) acrylate copolymer, vinyl acetate vinyl ester, and vinyl acetate / maleate copolymer. It is done.
  • thermoplastic elastomer particularly, a polyolefin-based thermoplastic elastomer or a styrene-based thermoplastic elastomer
  • examples of adhesives such as emulsion adhesives and solvent-based adhesives include acrylic adhesives, rubber adhesives, polyester adhesives, urethane adhesives, polyamide adhesives, and epoxy adhesives.
  • Adhesives such as bulle alkyl ether adhesives, silicone adhesives, fluorine adhesives, etc., and adhesives of each form (for example, emulsion form, solution form, etc.).
  • the pressure-sensitive adhesive is a cross-linking agent (for example, a polyisocyanate-based cross-linking agent, an alkyl ether base, or the like depending on the type of the pressure-sensitive adhesive).
  • a cross-linking agent for example, a polyisocyanate-based cross-linking agent, an alkyl ether base, or the like depending on the type of the pressure-sensitive adhesive.
  • tackifier for example, rosin derivative resin, polyterpene
  • the adhesive strength is not particularly limited as long as the heating element and the packaging material can be attached until the folding operation is completed, but preferably 180 degree peel strength.
  • JISZ-02 37 is from 0.001 to 0.9 kgZ25 mm, more preferably from 0.001 to 0.5 kg / 25 mm, more preferably ⁇ or 0.001 to 0.1 kg / mm. 25 mm, more preferably 0.005 to 0.1 kgZ25 mm, more preferably 0.1 to: LOOgZ25 mm, more preferably 0.1 to 50 gZ25 mm, more preferably 0.1 to It is 30 gZ25 mm, more preferably 0.1 to 25 gZ25 mm.
  • the coating thickness is not particularly limited, but is preferably 40 m or less, more preferably ⁇ to 0.01 to 40 111, and more preferably [0.1 to 40 / ⁇ ]. ⁇ , more preferably ⁇ to 0.1 to 30 / ⁇ ⁇ , more preferably ⁇ to 1 to 30 / ⁇ ⁇ , more preferably ⁇ to 5 to 30 / zm, more preferably 5-30 / ⁇ ⁇ .
  • a known forming method can be employed. Examples thereof include a hot melt coating method and a solution type coating method. Moreover, it can be in any form such as a whole surface, a partial shape, a solid shape, a net shape, a rod shape, a stripe shape, and a polka dot shape.
  • the external temporary attachment portion (external temporary attachment position) is preferably provided in the vicinity of the opening of the bag, more preferably in parallel with the opening, without any restriction.
  • the separator when a separator is provided on the heating element, it is preferable to provide the separator so that it does not peel off the heating element force.
  • At least the surface of the folding guide table that contacts the heating element and the packaging material is preferably a surface excellent in slidability.
  • Folding support means and folding guide means that use a material having excellent slidability or improve the slidability of the material (providing lubricity and slipperiness) are preferred.
  • Examples of the material having excellent slidability include metals, ceramics, and resin.
  • Preferred examples of resin include thermosetting resin, crystalline thermoplastic engineering plastics, elastomer systems: polyesters and urethanes, and polyolefins (ultra-high molecular weight polyethylene).
  • Thermosetting resin Phenolic resin, polyester, carbon fiber and PTFE, thermosetting engineering plastic (hardened when heated) phenol, urea, melamine, alkyd, unsaturated polyester, epoxy, diallyl butarate, Silicone, polyurethane, etc.
  • Thermoplastic resin Polyacetal (POM), Polyamide (PA), Polytetrafluoroethylene (PTFE), Polyphenylene sulfide (PPS), Elastomer series: Polyester and urethane series, Polyolefin series (Polyethylene, ultra-high molecular weight polyethylene, polypropylene, etc.), polyester, polychlorinated butyl, polysalt vinylidene
  • PA Polyamide
  • POM Polyacetanol
  • PBT Polyprene terephthalate
  • SPS Syndiotacic polystyrene
  • Blended with solid lubricants such as fluorine resin, graphite, molybdenum disulfide, and oil.
  • a matting agent is applied using a curing reaction type resin as a binder.
  • polycarbonate modified polyphenylene ether (mPPE) polysulfone (PSF), polyethersulfone (PES), polyarylene (PAR), polyamideimide (PAI), polyetherimide (PEI), thermoplastic polyimide (PI) Etc.
  • PSF polysulfone
  • PES polyethersulfone
  • PAR polyarylene
  • PAI polyamideimide
  • PEI polyetherimide
  • PI thermoplastic polyimide
  • the static friction coefficient (film table-metal, film table-table, JIS K7125) of the resin is preferably 1.0 or less, more preferably 0.7 or less, and still more preferably 0.5 or less. More preferably 0.4 or less, and still more preferably 0.2 or less.
  • the heating element of the present invention is not limited as long as it is a heating element having at least one foldable portion, but the segment heating part containing the exothermic composition molded body does not contain the exothermic composition molded body.
  • the heating element provided with a gap between the seal sections is particularly preferable, and iron powder, carbon component, reaction accelerator and water are essential components, and the mobile water value is A heat generating composition molded body obtained by molding a moldable excess water exothermic composition having a moldability of 01 or more to less than 14 by molding is laminated on a substrate and further coated with a coating material, and the exothermic composition is formed.
  • It consists of heat-sealing the base material and the covering material at the peripheral edge of the molded body, and has a plurality of divided heat generating portions which are integrally formed heat generating regions having A surface which is one surface and B surface which is the other surface.
  • the length of the heating section is 5mm ⁇ 200mm, the width is more than lmm ⁇ less than 25mm, the height is 0.5mm ⁇ 10 mm, the ratio of (length Z width) is 2.1-30, the width of the section is 1-30 mm, and the plurality of section heating sections are separated from each other, and are striped in at least one direction And at least one of the base material and the covering material is air permeable (oxygen permeable), the surface A is air permeable, and both surfaces A and B are convex segmented heat generating portions. And a heating element formed of a concave (flat) section.
  • the heating element has a minimum bending resistance of 100 mm or less, does not bend easily except in the direction having the lowest bending resistance, and has a direction for ease of bending, and only one direction is bent to the extreme as compared to the other directions. Almost prefer a heating element that has a structure.
  • the base material of the present invention is not limited as long as it functions as a packaging material for a heating element as a packaging material constituting a covering material, a ventilation control material, or a support.
  • non-breathable materials, breathable materials, water-absorbing materials, non-water-absorbing materials, non-stretchable materials, stretchable materials, stretchable materials, non-stretchable materials, foamed materials, non-foamed materials, non-heat examples thereof include a sealing material, a heat sealing material and the like, and can be appropriately used depending on a desired application in a desired form of a composite such as a film, a sheet, a nonwoven fabric, a woven fabric, and a laminate thereof.
  • the base material of the present invention is a packaging material on which the exothermic composition molded body is laminated, and the coating material is a packaging material covering the same, and it does not matter whether it is air permeable or non-breathable.
  • the substrate is made of a non-breathable film or sheet, and the covering material may be a force that can also be a breathable film, sheet, or nonwoven fabric, or both of them may be breathable.
  • the heating element of the present invention is at least partially breathable.
  • the packaging material used for the heating element of the present invention has been disclosed in the past or is commercially available, or any known packaging material used for discarded body warmers or heating elements. You can select and use.
  • the air permeability on the side that contacts the body is preferably lower than the air permeability on the side that does not contact the body.
  • the air permeability of the heat generating part and the section heat generating part is preferably 50gZm2Z24hr to LO, 000gZm2Z24hr, more preferably 100gZm2Z24hr to 5,000gZm2Z24hr, more preferably, in terms of moisture permeability according to the Risshi method (JIS K007129A method). Is 100 gZm2Z 24hr to 600gZm2Z24hr, more preferably 150gZm2Z24hr to 500gZm2Z24hr.
  • the heating element of the present invention is a heating element enclosed in an outer bag which is an airtight storage bag
  • a notch for opening is provided in the seal portion of the outer bag which is an airtight storage bag.
  • the notch is provided in a seal portion of the outer bag that is an airtight storage bag without contacting at least the side of the outer bag that is the airtight storage bag.
  • the notch is provided in a region in the seal portion of the outer bag which is an airtight storage bag and at least touches the side of the outer bag which is an airtight storage bag.
  • the notches of the present invention are not limited, but examples include I notches, V notches, U notches and the like.
  • the seal part of the outer bag which is a non-breathable storage bag, is formed near the outside of the peripheral edge of the heating element, so that the outer bag packaging material and the heating element are in close contact, and the heating element is folded. Combined with packaging in a state, the whole is extremely compact.
  • the heating element Even if the heating element becomes large, the number of members can be reduced compared to the conventional heating element that does not fold, In addition to being able to reduce costs, it has the advantage of being friendly to the global environment, as it reduces the amount of garbage generated during use.
  • a preferable size is as follows.
  • the diameter is preferably about lmm to about 60mm, more preferably 2mn! -50 mm, more preferably 10 mm to 40 mm, and even more preferably 20 mm to 30 mm.
  • the height is preferably 0.1 mm to 20 mm, more preferably 0.3 mm to 20 mm, and even more preferably 0.5 mn! ⁇ 20mm, more preferably lmm ⁇ 20mm, more preferably 1.5mn! ⁇ 10mm, more preferably 3mm ⁇ 9mm, more preferably 4mn! ⁇ 8mm, more preferably 5mn! ⁇ 7mm.
  • the volume is preferably from about 0.0045 cm 3 to about 20 cm 3 , more preferably from about 0.2 cm 3 to about 11 cm 3 .
  • the width is preferably 0.5 mm to 60 mm, more preferably 0.5 mm to 50 mm, and preferably 0.5 mn! ⁇ 50mm, more preferably lmn! ⁇ 50mm, more preferably 3mn! ⁇ 50mm, more preferably 3mm ⁇ 30mm, more preferably 5mn! ⁇ 20mm, more preferably 5mn! ⁇ 15mm, more preferably 5mm ⁇ l Omm to.
  • the height is preferably 0.1 mm to 30 mm, more preferably 0.1 mm! ⁇ 20mm, more preferably 0.1mm ⁇ 10mm, more preferably 0.3mn! ⁇ 10mm, more preferably 0.5mn! ⁇ 10mm, more preferably lmm ⁇ 10mm, more preferably 2mn! ⁇ 1 Omm.
  • the length is preferably 5 mm to 300 mm, more preferably 5 mm to 200 mm, more preferably 5 mm to 100 mm, still more preferably 20 mm to 150 mm, and further preferably 30 mm to: L 00 mm. is there.
  • the surface area is not limited as long as it has a function as a segmented heat generating part, but is preferably about 50 cm 2 or less, more preferably about 40 cm 2 or less, and further preferably less than about 25 cm 2. More preferably, it is less than 20 cm 2 .
  • Volume of volume or exothermic composition molded article of the segment heating portion is preferably 0. 015cm 3 ⁇ 500cm 3, preferably 0. 04cm 3 ⁇ 500cm 3, more preferably 0. 04cm 3 ⁇ 30cm 3 , and still more preferably 0. lcm 3 ⁇ 30cm 3, and more preferably a lcm 3 ⁇ 30c m 3, more preferably 1. 25 cm 3 to 20 cm 3, more preferably 1. 25 cm 3 to 10 cm 3 , more preferably 3 cm 3 to 10 cm 3 .
  • the exothermic composition which is the exothermic composition molded body occupied area when the exothermic composition molded body is accommodated in the segmented exothermic part which is the accommodating area of the exothermic composition molded body.
  • the volume ratio between the volumetric product of the molded body and the volume of the exothermic part that is the exothermic composition storage area is usually 0.6 to 1, preferably 0.7 to 1, and more preferably 0.8 to 1. More preferably, it is 0.9 to 1.
  • the heat generating portions of the present invention be provided in a streak-like manner.
  • “To provide streaks in a spaced manner” means that a plurality of segmented heat-generating portions are provided in a streak-like manner. (In parallel lines). It is preferable that one streak is composed of one section heating part.
  • one streak may be composed of two or more divided heat generating parts and one or more divided parts.
  • T is T ⁇ 2S, preferably T ⁇ 2.5S.
  • is ⁇ , preferably ⁇ 0.5 ⁇ .
  • One example is the arrangement of streaks composed of segmented heat generating parts in parallel stripes (vertical stripes, horizontal stripes, diagonal stripes, vertical wave stripes, horizontal wave stripes, diagonal wave stripes, etc.).
  • the width of the section is not limited as long as the section heat generating section can be provided at intervals, but is usually 0.1 lmn! ⁇ 50mm, preferably 0.3mn! ⁇ 50mm, more preferably 0.3mn! ⁇ 50mm, more preferably 0.3mn! ⁇ 40mm, more preferably 0.5mn! ⁇ 30mm, more preferably lmm ⁇ 20mm, Preferably 3mn! ⁇ 10mm.
  • the exothermic composition molded body of the present invention generates heat upon contact with air (oxygen), can be stacked on a substrate, can maintain its shape, is covered with a covering material, and has a peripheral edge of the exothermic composition molded body. If the part can be sealed, there is no limit! /
  • the width is not limited, but it is preferably a heat generating composition molded body which is a sheet-shaped heat generating piece consisting of 1 to 30 mm (the width is not limited, but preferably Is lmn! ⁇ 30mm, preferably lmn! ⁇ 25mm, more preferably lmn! ⁇ 24.5mm.
  • the width of the heat generating sheet is not limited, but is preferably a 0.1 to 50 mm stripe-shaped space with a hole that generates heat upon contact with air (oxygen) and its cutting heat.
  • Exothermic composition molded body is not limited, but is preferably a 0.1 to 50 mm stripe-shaped space with a hole that generates heat upon contact with air (oxygen) and its cutting heat.
  • the width of the sheet-like heating piece is not limited, but preferably has a slit or a 0.1--50 mm stripe-shaped space, and has a holed heating sheet that generates heat in contact with air (oxygen) and Exothermic composition molded body which is the cut product
  • the heat generating sheet is not particularly limited as long as it is a sheet-like material that generates heat upon contact with air (oxygen), but examples thereof include a dispersive heat generating sheet, a papermaking heat generating sheet, and a pressure processing heat generating sheet. .
  • a heat-generating sheet (dispersion type, paper-making type, pressure heating type, etc.), a processed product with holes, a Z-heat generation piece, or the like can be used as the heat-generating composition molded body.
  • the processing method of each heating sheet and the manufacturing method of the heating piece of the present invention described above are processing such as cutting, slitting, punching, punching Z cutting, etc. of the material heating sheet and small width (width is not limited, 1S preferably lmm -30 mm, more preferably width 1 mm to 25 mm, more preferably width lm m to 24.5 mm).
  • Method of manufacturing a sheet-shaped raw material is known of the method of manufacturing force s can be used.
  • WO96 / 11654 ⁇ 2003-102761 ⁇ WO00 / 1362 6 etc. are mentioned as an example.
  • a known method with no restrictions can be used for the installation method of the space (including the slit), and a mechanical cutting method such as a guillotine cutter or a cutting roll or a laser An example is the cutting method using the laser.
  • the dispersive exothermic sheet is not particularly limited as long as the exothermic composition is dispersed and held in a non-woven fabric or other other packaging material and processed into a sheet-like exothermic body.
  • Oxidizable metal powder Carbon component, powder raw material exothermic composition containing water retention agent as essential components is dispersed in the nonwoven fabric, and then an aqueous solution of reaction accelerator such as electrolyte is added, and contact with air (oxygen) generates heat. This is an exothermic sheet.
  • the papermaking exothermic sheet is not limited as long as the exothermic composition is processed into a sheet-like heating element by a papermaking method.
  • an oxidizable metal powder such as iron powder, a carbon component, a water retention agent
  • a paper sheet made from a slurry-like raw material exothermic composition containing fiber and water as essential components by papermaking is dried with hot air at 90 to 200 ° C, and a reaction accelerator such as an electrolyte or an aqueous solution thereof is added to air (oxygen).
  • An example is a heat generating sheet that generates heat upon contact with ().
  • the pressure-processable exothermic sheet is not limited as long as the exothermic composition is processed into a sheet-like heating element by a pressurizing process, but the following 1) and 2) are given as examples. It is done.
  • components of the moldable surplus water exothermic composition can be used.
  • ethanol, propylene glycol, glycerin and the like are preferable as the alcohol.
  • the cross-linking agent causes cross-linking between the water-absorbing polymers, cross-linking between the second polymers, cross-linking between the water-absorbing polymer and the second polymer, and a cross-linking reaction between these polymers.
  • at least one cross-linking agent that promotes cross-linking is preferable among the ones that intervene between these polymers to cause crosslinking. Examples include ethylene glycol diglycidyl ether and methylene bisacrylamide.
  • Oxidizable metal powder such as iron powder, carbon component, reaction accelerator and water are essential components, and 1 to 15% by weight, preferably 3 to 15% by weight, of the formation aid is based on the total amount.
  • the easy water value is An exothermic sheet in which a water-containing exothermic composition of less than 01 is integrated by applying a predetermined pressure.
  • water-absorbing polymers, water retention agents such as wood flour, hydrogen generation inhibitors such as sodium sulfite, pH regulators such as slaked lime, etc. that have been publicly disclosed. Can be appropriately selected and used.
  • a heat-generating sheet, a sheet-shaped heating piece, or a holed mold is used depending on the size of the mold hole, so A piece can be manufactured.
  • the pressure processing method is not limited as long as the exothermic composition is put in a mold and pressed in the mold and the exothermic composition is compressed and molded.
  • the pressure and pressurizing time are not limited as long as they can be formed, but the pressure is preferably 100 to 9000 kgZcm2, and the time is preferably 0.01 to 30 seconds.
  • the exothermic composition is rolled at a predetermined pressure using a roller to obtain a sheet-like heating element.
  • the exothermic composition is placed in a mold hole having a recess or a through hole having a desired shape, and a deformable flexible roll such as a balloon roll or a convex part that can be inserted into the mold hole.
  • the exothermic composition in the mold cavity is pressurized with a pressurizing means such as a roll or belt, and the exothermic composition is compressed and molded.
  • the heat treatment conditions in this case are not limited, but are preferably 50 to 250 ° C. and about 1 second to 20 minutes.
  • each sheet of the present invention is the process such as cutting, slitting, punching, punching Z cutting, etc. of the material heat generating sheet or small width (the width is not limited, but preferably lmn! To 30 mm, more preferably lmm 25 mm, more preferably lmm to 24.5 mm, and the production of a sheet is exemplified, but a known production method can be used as a material sheet, for example, W096 / 11654 is disclosed in JP2003-102761 and WO00. / 13626 Isotropic S—It is listed as Italy.
  • the exothermic composition of the present invention is not limited as long as it can form a exothermic composition molded body and generates heat upon contact with air, but is preferably a carbon component such as iron powder or activated carbon, sodium chloride sodium salt, It contains a reaction accelerator composed of an inorganic electrolyte such as potassium chloride and water as essential components.
  • a moldable surplus water exothermic composition containing surplus water having a water value of 0.01 or more and less than 14 is preferable.
  • the moldable excess water exothermic composition includes water-absorbing polymers such as water retention agents such as wood flour and vermiculite, starch-acrylate graft copolymers, and polyacrylate cross-linked products.
  • water-absorbing polymers such as water retention agents such as wood flour and vermiculite, starch-acrylate graft copolymers, and polyacrylate cross-linked products.
  • Inhibitors of hydrogen generation such as sodium sulfite, pH adjusters such as slaked lime, non-ions such as polyoxyethylene alkyl ether, zwitterion, ion and cationic surfactants, hydrophobic polymers such as polyethylene and polypropylene Compounds, organic silicon compounds such as dimethyl silicone oil, far-infrared radiation materials such as pyroelectric materials and ceramics, negative ion generators such as tourmaline, exothermic aids such as FeCl, silicon and aluminum
  • Metals other than iron such as manganese oxide, metal oxides other than iron oxide, such as manganese dioxide, acidic substances such as hydrochloric acid and maleic acid, acetic acid such as pulp, fertilizer components such as urea, fertilizer components such as urea, glycerin and
  • It may contain at least one selected from an additional component consisting of a humectant such as D-sorbitol, a molding aid, a release agent, an aggregate, a functional substance, or a mixture thereof.
  • any components of the exothermic compositions that have been disclosed in the past, are commercially available, or are used for known disposable warmers and heating elements can be appropriately selected and used. .
  • the mixing ratio of the exothermic composition is not particularly limited, but 1.0 to 50 parts by weight of a carbon component and 1.0 to 50 parts by weight of a reaction accelerator with respect to 100 parts by weight of iron powder.
  • iron powder water retention agent 0.01 to: L0 part by weight, water-absorbing polymer 0.01 to 20 parts by weight, pH adjuster 0.01 to 5 parts by weight, hydrogen generation inhibitor 0. 01 to 12 parts by weight, metal other than iron 1.0 to 50 parts by weight, metal oxide other than iron oxide 1.0 to 50 parts by weight, surfactant 0.01 to 5 parts by weight, hydrophobic polymer compound , Aggregates, fibrous materials, functional substances, organic compounds, pyroelectric substances 0.01 to 10 parts by weight, moisturizers, fertilizer components, and fever aids 0.01 to 10 parts by weight, respectively.
  • the molding aid and mold release agent are 0.001 to 5 parts by weight and 0.01 to 1 part by weight of an acidic substance, respectively. It should be noted that the proportion of the magnetic material that may be further blended may be appropriately determined if desired. This blending ratio can also be applied to a reaction mixture and an exothermic mixture.
  • the mobile water value of the reaction mixture is usually less than 0.01.
  • the blending ratio that may be further blended with the magnetic material may be appropriately determined as desired.
  • the iron powder is not limited! Pig iron iron powder, atomized iron powder, electrolytic iron powder, reduced iron powder, sponge iron powder, iron alloy powder thereof, and the like can be used as examples. In addition, these iron powders may contain carbon or oxygen, or iron containing 50% or more of iron and other metals!
  • the type of metal contained as an alloy is not particularly limited as long as the iron component acts as a component of the heat generating composition, but examples include metals such as aluminum, manganese, copper, and silicon, and semiconductors.
  • the metal of the present invention includes a semiconductor.
  • the content of the metal other than iron is usually 0.01 to 50% by weight, preferably 0.1 to 10% by weight, based on the whole iron powder.
  • the molding aid is a moldability improving agent that improves the moldability of the surplus water heating composition in combination with moisture.
  • the molding aid is not limited as long as it is water-soluble or hydrophilic and improves the moldability of the excess water heating composition, but glucose, fructose, sorbitol, maltose, lactose are not limited. , Sugars such as sucrose, trenorose, pectin, sugar alcohols such as mannitol, sonorebitol, maltitol, erythritol, xylitol, corn starch, wheat starch, rice starch, corn starch, potato starch, dextrin Starch, partially alpha-ized starch, hydroxypropyl starch, carboxymethyl starch, at-cyclodextrin, 13-cyclodextrin, starch of pullulan sugar, crystalline cellulose, carboxymethylcellulose, hydroxypropylcellulose, low substitution Degrees of cellulose such as hydroxypropylcellulose, hydroxypropylmethylcellulose, methinoresenolellose, canoleboxymethylenoresenolose sodium,
  • Polybulurpyrrolidone Polyvinyl alcohol, stearate, sodium polyacrylate, agar, gum arabic, sodium alginate, gelatin, corn syrup, mannitol syrup, carrageenan, tran Togam, Kara gum, Xanthan gum, Dulan gum, Punorerin, Guardlan, Gelatin, Albumin, Casein, Soy protein, Wheat protein, Alappinogalactan, Gua gum, Low power Stobing gum, Tamarind seed gum, Tarra gum, Tragacanth gum, Poly-N-vininorea setamide, Acrylic Acid starch copolymer, microcrystalline cellulose, N-bulacetamide copolymer, bentonite, kaolin, sodium silicate, calcium chloride salt, montmorillonite, aluminum silicate or water-dispersed emulsion such as poly (acetate) Or the use of a combination is mentioned as an example.
  • the aggregate is not limited as long as it is useful as a filler and is useful for making Z or a porous heat-generating composition.
  • Fossil coral coral fossil, weathered reef coral etc.
  • bamboo charcoal Bincho charcoal
  • silica-alumina powder silica-magnesia powder
  • kaolin crystalline cellulose
  • colloidal silica pumice
  • silica gel silica powder
  • my strength powder clay
  • talc Examples include powders and pellets of synthetic resins, foamed synthetic resins such as foamed polyester and polyurethane, algae, alumina, and fiber powder.
  • the release agent is not limited, but is a lubricating oil composed of mineral oil, synthetic oil, animal and vegetable oil, high viscosity lubricating oil such as grease, natural wax, synthetic wax, silicone oil, Examples thereof include silicon rosin, stearic acid, stearates, and the like.
  • the functional substance may be anything as long as it has some function such as medicinal effect and aroma.
  • acidic mucopolysaccharides such as alkaloid compounds; , Anthocyanin, vitamin P, kinka, silanol, terminaria, mayus, etc .; aminophylline, tea echex, caffeine, xanthene derivatives, inosit, dextran sulfate derivatives, cinchio chinoki, escin, anthocyanin, organic Slimming agents such as iodine compounds, hyperic leather, horsetail, mannen wax, ginseng, hyalurochi-dase; indomethacin, dl-camphor, ketoprofen, shoga extract, pepper extract, methyl salicylate, glycosalicylate
  • Analgesics such as lavender; fragrances such as lavender, rosemary, citron, jeper, peppermint,
  • the percutaneously absorbable drug is not particularly limited as long as it is percutaneously absorbable, and examples thereof include skin stimulants, analgesic anti-inflammatory agents such as salicylic acid and indomethacin, and central nervous system agents.
  • skin stimulants such as salicylic acid and indomethacin
  • analgesic anti-inflammatory agents such as salicylic acid and indomethacin
  • central nervous system agents such as central nervous system agents.
  • the mobile water value (0 to: L00) of the moldable excess water exothermic composition of the present invention is preferably 0.01 or more and less than 14, more preferably 0.01-13.5. Yes, more preferably from 0.01 to 13.5, more preferably from 0.1 to 13, more preferably from 0.1 to 12, and even more preferably from 0. It is 01-12, More preferably, it is 1-12, More preferably, it is 2-12, More preferably, it is 2-: L1, More preferably, it is 3-: L1. If it is less than 0.01, the moldability will deteriorate, and if it exceeds 14, the heat generation characteristics will deteriorate.
  • the mobile water value is a value indicating the amount of excess water that can move out of the exothermic composition in the water present in the exothermic composition. This easy water value will be explained.
  • Center point force No. 2 QIS P 3801 (Type 2) with 8 lines radially written at 45 degree intervals) is placed on a stainless steel plate, and the center of the filter paper has an inner diameter of 20 mm and a height of 8 mm.
  • a non-water-absorbing 70 / zm polyethylene film is placed so as to cover the hole, and further, a thickness of 5 mm X a length of 150 mm X Place a stainless steel plate with a width of 150 mm and hold for 5 minutes. Then, the filter paper is taken out, and the soaking locus of water or aqueous solution is read in mm units as the distance from the circumferential portion that is the edge of the hole of the hollow cylinder to the soaking tip along the radial line. Similarly, the distance is read from each line to obtain a total of 8 values.
  • Each of the 8 values read (a , b, c, d, e, f, g, h) are measured moisture values.
  • the arithmetic mean of the 8 measured moisture values is the moisture value (mm) of the sample.
  • the moisture content for measuring the true moisture value is the blended moisture content of the exothermic composition or the like corresponding to the weight of the exothermic composition or the like having an inner diameter of 20 mm and a height of 8 mm, and only water corresponding to the moisture content is used. Measure in the same way with, and calculate the same as the true moisture value (mm).
  • the value obtained by dividing the moisture value by the true moisture value and multiplying by 100 is the easy water value. That is,
  • the moisture content for measuring the true moisture value is determined by determining the moisture content of the exothermic composition from the moisture content measurement using an infrared moisture meter for the exothermic yarn and composition. Based on this, the amount of water necessary for measurement is calculated, and the true water value is measured and calculated from the amount of water.
  • the exothermic composition having a mobile water value (0 to: L00) of 0.01 or more and less than 14 and particularly 0.01 to 13.5 is a non-water-absorbing 70 / zm polyethylene film so as to cover the hole.
  • the exothermic composition of the present invention undergoes an exothermic reaction during measurement, Measurement becomes impossible.
  • Packaging materials such as the base material, the covering material support, and the air conditioning material of the present invention are not limited.
  • the packaging material is a non-breathable material, a breathable material, a water-absorbing material, and a non-water-absorbing material.
  • examples include non-stretchable materials, stretchable materials, stretchable materials, non-stretchable materials, foamed materials, non-foamed materials, non-heat-sealable materials, heat-sealable materials, etc., films, sheets, nonwoven fabrics, etc.
  • a desired form such as a woven fabric or a laminate thereof, it can be appropriately used depending on the desired application.
  • the packaging material used for the heating element according to the present invention may be any packaging material that has been disclosed in the past or is commercially available, or that is used for a well-known disposable body warmer or heating element. It can be appropriately selected and used.
  • the air permeable film for example, a porous film using polyethylene, polypropylene, a polyfluorinated styrene film, or the like is preferably used, and the pore diameter depends on the required air permeability. Is determined.
  • the ventilation rate is designed according to the heat generation agent used, depending on the required heat generation and temperature.
  • the porous film is a film having fine through-holes having a maximum pore diameter of about 0.001 to 20 m by a methanol bubbling method.
  • a through-hole is provided by extending a synthetic resin film.
  • an inorganic fine powder such as calcium carbonate dispersed in melted polyethylene, polypropylene, etc., then extruded into a film, and the resulting film is further stretched to provide through holes, etc. .
  • a packaging material made of non-woven fabric with laminated fibers and thermocompression-bonded to control air permeability can be used after perforating holes in a film or sheet having a non-breathable material such as polyethylene film.
  • the non-breathable material is not limited as long as it does not substantially permeate oxygen.
  • Polyolefin such as polyethylene, polypropylene, and polybutadiene, polychlorinated bur, polysalt vinylidene, polyester Films such as polyethylene, polysulfone, polyamide, etc., and films in which metal compounds such as aluminum and metal oxides such as silicon oxide and aluminum oxide (including metals including semiconductors) are laminated by vapor deposition or sputtering.
  • the metal foil such as a muya sheet, a laminate thereof, aluminum, and the like, and a laminate of the metal foil sandwiched between the films and sheets and a composite material using them.
  • the thickness is not limited, but is preferably about 20 ⁇ m to lmm.
  • the fixing means is not limited as long as it has a fixing ability capable of fixing the heating element to the required portion. Furthermore, the fixing means is preferably removable. Adhesive layers, key hooks, hook buttons, hook-and-loop fasteners such as Velcro (registered trademark), magnets, bands, strings, etc., and combinations thereof, which are generally used as the fixing means, are arbitrarily used. it can. In the case of a band, the adjustment fixing means may be further constituted by a combination of a hook-and-loop fastener and an adhesive layer.
  • the separator may be provided with a cut or the like such as a back split to facilitate its peeling.
  • the fixing means of the present invention has been disclosed in the past, is commercially available, or is publicly known. Fixing means (including removable attachment means) used for disposable warmers and heating elements can be selected and used as appropriate.
  • the pressure-sensitive adhesive constituting the pressure-sensitive adhesive layer is not limited as long as it has an adhesive force necessary to adhere to the skin or clothes.
  • Solvent type aqueous type, emulsion type, hot melt type, reactivity, sensitivity
  • Various forms such as a pressure system, a non-hydrophilic pressure-sensitive adhesive, a mixed pressure-sensitive adhesive, a hydrophilic pressure-sensitive adhesive (Giel etc.) are used.
  • the pressure-sensitive adhesive layer includes a water retention agent, a water-absorbing polymer, a pH adjuster, a surfactant, an organic key compound, a hydrophobic polymer compound, a pyroelectric substance, an antioxidant, an aggregate, a fibrous material, a moisturizing agent, Additional ingredients such as functional substance or mixture thereof may contain at least one selected.
  • a water retention agent e.g., acrylic, urethane, rubber, silicon, polyisoprene, polyisobutene, styrene isoprene, styrene (SIS), styrene isoprene, etc.
  • SIS styrene isoprene
  • One example is a hydrophilic adhesive.
  • the pressure-sensitive adhesive may be a pressure-sensitive adhesive that has been disclosed in the past, is commercially available, or is used for known disposable warmers or heating elements.
  • FIG. 1 (a) is a perspective view showing an example of the heating element folding device of the present invention.
  • Figure 1 (b) is a plan view of the same.
  • FIG. 1 (c) is a side sectional view of the same explanation.
  • the folding guide plate 2 is attached so as to cover the endless belt 12 and will eventually be covered, and fixed magnets are provided in the hollow roll 11 and below the center of the endless belt 12. 50, and the starting point of the folding guide plate 2 is formed on one side of the endless belt 12 so that the surface is horizontal or lower than the surface of the central belt.
  • the folding guide plate 2 gradually lifts the outer side as it goes rearward to become a spring-up guide part, and further bends inward to become an inward guide part. It is formed so as to be folded on a portion supported by the magnet 50.
  • folding guide plates 2 are self-lubricating because the heating element 33 contacts and slides. Therefore, it is preferable to have a slidable surface with a low coefficient of friction, for example, it is desirable to make it with a fluorine-based resin or to coat the surface.
  • the heating element 33 which is conveyed by being stacked on the outer peripheral surface of the endless belt 12 wound around the rotating preceding roll 11, is adsorbed to the endless belt 12 by the fixed magnet 50 in the hollow roll 11, and is folded and guided.
  • the unfolded portion of the heating element that is laminated on the plate 2 and the endless belt 12 is attracted to the surface of the endless belt 12 by the fixed magnet 50 below the center of the endless belt 12, supported, and transported.
  • the folding guide plate 2 has a starting point so that the surface thereof is horizontal or below the surface of the endless belt 12, and the leading edge of the scooping guide portion is formed along the surface of the endless belt 12. Therefore, when the leading edge of the heating element 33 comes to the starting point of the scooping guide portion, the part where the heating element 33 is folded is stacked on the folding guide plate 2.
  • the folding guide plate 2 is formed so as to gradually lift the outside as it goes rearward to become a raising guide part, and further bent inward to become an inward guide part, so that the heating element 33 is an endless belt.
  • the folding part on the right side of the heating element 33 is lifted by the splashing guide part, the inward guide part is folded inward, and the folding guide part is supported by the magnet 50. Fold it over the unfolded part.
  • the folded heating element 33 is pressed by a pressing plate and further conveyed to the next process.
  • FIG. 2 (a) is a plan view showing an example of a three-fold heating element folding device 1 of the present invention.
  • FIG. 2 (b) is a side sectional view of the same explanation.
  • a folding guide plate 2 composed of a scooping guide portion, a lifting guide portion, an inward guide portion and a folding guide portion is attached along the end portion of the endless belt 12, and folded.
  • the starting point of the guide plate 2 is formed on one side of the endless belt 12 so that the surface is horizontal or lower than the surface of the central endless belt 12.
  • the folding guide plate 2 is attached along the endless belt 12 so as to cover it, and a fixed magnet 50 is provided in the hollow roll 11 and below the center of the endless belt 12, and the folding guide plate 2 is moved backward. Raise the outside gradually to become a guide for raising, and further bend inward It is formed as an inward guide part, and further, a folding guide part, and the folded part of the folded heating element is supported by the magnet 50 and folded on the part!
  • a folding guide plate 2 composed of a scooping guide portion, a flip-up guide portion, an inward guide portion and a folding guide portion is attached along the end portion of the endless belt 12 as in the right side. ing.
  • folding guide plates 2 slide in contact with the heating element 33, it is preferable to have a slidable surface with a self-lubricating property and a small friction coefficient, such as a fluorine-based resin. It is desirable to make or coat the surface.
  • the heating element 33 that has been stacked and conveyed on the outer peripheral surface of the endless belt 12 of the rotating front roll 11 is attracted to the endless belt 12 by the fixed magnet 50 in the hollow roll 11, and is connected to the folding guide plate 2 and The unfolded portion of the heating element 33 that is laminated on the endless belt 12 is attracted to the surface of the endless belt 12 by the fixed magnet 50 below the center of the endless belt 12, supported, and transported.
  • the folding guide plate 2 on the right side has a starting point so that the surface thereof is horizontal or lower than the surface of the endless belt 12 at the center, and the leading edge of the guide portion is formed along the surface of the endless belt 12. Therefore, when the leading edge of the heating element 33 comes to the starting point of the scooping guide portion, the part where the heating element is folded is stacked on the folding guide plate 2.
  • the folding guide plate 2 on the right side is formed so that the outer side gradually rises as it goes rearward to become a lifting guide part, and further bent inward to become an inward guide part.
  • the folding part on the right side of the heating element 33 is lifted by the splashing guide part, the inward guide part is folded inward, and the folding guide part is magnetized. Fold it over the unfolded part supported by
  • the left folding guide plate 2 is not folded when the left folding part of the heating element 33 is lifted by the raising guide part, the inward guide part is folded inward, and the folding guide part is supported by the magnet 50. Fold over the part.
  • the folded heating element is pressed by the pressing plate and further conveyed to the next process.
  • the lift-up guide part tilts gently with this spacing force Since it is formed so as to be lifted obliquely and smoothly, the heating element can be lifted up smoothly and easily.
  • FIG. 3 (a) is a plan view showing another example of the three-fold heating element folding device 1 of the present invention.
  • FIG. 3 (b) is a side sectional view of the same explanation.
  • the endless belt 12 is divided into a center, a right side belt, and a left side belt.
  • the endless belt 12 in the center stacks and supports the unfolded portion of the heating element 33, and the other two endless belts 12 up to the right folding guide plate 2 and the left folding guide plate 2, respectively.
  • the heating elements 33 are conveyed, and the heating elements 33 are stacked on the respective folding guide plates 2.
  • the endless hole belt 12 at the center has the same width as that of the unfolded portion of the heating element. The width of the belts on both sides should be wide enough to accommodate the folded part of the heating element.
  • the folding guide plate 2 on the right side lifts the folding part on the left side of the heating element 33, the inside of the splash-up plan is raised, the inward guide part is folded inward, and the folding guide part is supported by the magnet 50. Fold the top and press the heating element 33 with the holding plate folded. Subsequently, the left folding guide plate 2 folds the left folded portion of the heating element 33 and further presses the heating element 33 with the holding plate folded. Further, since the raising guide portion to be conveyed to the next process is formed so as to be lifted smoothly with a gentle slope, the heating element 33 can be lifted up smoothly and easily.
  • FIG. 4 is an explanatory cross-sectional view showing another example in which the gas nozzle 51 of the heating element folding device 1 of the present invention is provided.
  • the tip of the gas nozzle 51 is formed in a horizontally long slit shape (for example, a width of about 15 mm and an opening gap of about 0.5 mm), and is installed so as to inject gas between the outer peripheral surface of the roll 11 and the folding guide plate 2.
  • the gas nozzle 51 is connected to a gas (air etc.) supply device (not shown). Not shown! When gas is supplied to the gas nozzle 51 from the gas supply device and injected (for example, about 10 liters of gas per minute), the gas is placed between the outer peripheral surface of the roll 11 and the folding guide plate 2.
  • FIG. 5 (a) is a plan view showing another example of the heating element folding device 1 of the present invention.
  • FIG. 5 (b) is a side sectional view of the same description.
  • the fixed magnet 50 is not used in the example shown in FIG. 1, and the pressing plate 8 is used as a support means for the heating element 33. It is preferable that the pressing plates 7 and 8 have a surface having an excellent slidability on at least a surface in contact with the heating element 33 or a plate having a rotatable roll 10.
  • FIG. 6 (a) is a plan view showing another example of the heating element folding device 1 of the present invention.
  • FIG. 6 (b) is a side sectional view of the same explanation.
  • This example is an example in which the holding plates 7 and 8 are used as a supporting means for the heating element 33 in the example shown in FIG. It is preferable that the pressing plates 7 and 8 have a surface 7 that has excellent slidability at least on the surface in contact with the heating element, or that have a rotatable roll 10. This is an example in which the heating element 33 is supported by the fixed magnet 50 and the holding plates 7 and 8.
  • FIG. 7 (a) is a perspective view showing another example of the heating element folding device 1 of the present invention.
  • the folding guide 3 has a rotatable roll 10 starting from a substantially vertical plane that is not curved, and the rotatable roll 10 supports a portion of the heating element 33 that is not folded.
  • the entrance side has a substantially vertical surface with a curved cross-sectional shape, but as it moves in the direction of travel, it bends into a curved surface, and further, as it progresses, it has a shape that continuously changes to a flat shape. 3.
  • a magnet 50 is provided on the opposite side (outside) of the folding guide plate 2 that is the folding guide means 2 that contacts the packaging material 41, and the side on which the heating element 33 is folded is folded with a magnetic force during folding. Fold the heating element 33 while pressing it against the material.
  • the magnet 50 provided on the outer surface of the folding guide means is preferably provided along the functions of scooping guide, flip-up guide, inward guide and folding guide.
  • a plurality of rotatable rolls 10 are provided on the lower surface of the folding guide 3 that contacts the unfolded portion of the heating element 33! /.
  • a magnet may be provided along the traveling path in which the heating element 33 of the folding guide plate 2 of the present invention is folded.
  • the magnet may be provided on the inner surface of the hollow folding guide plate 2 or on the inner wall of the outer side of the folding guide plate 2. If it is provided on the outer surface, it is preferably embedded in the outer surface. Rotates under the folding guide stand that supports the unfolded part of the heating element body Let's set up rolls and balls. There may be no resistance to movement of the folded heating element or packaging material. Examples of magnets that can be used are magnets and permanent magnets as long as they have a magnetic force.
  • FIG. 7B is a perspective view showing another example of the folding guide base 3 having a rotatable roll 10 starting from a substantially vertical surface that is not a curved surface.
  • the heating element 33 is composed of a folding guide base 3, a folding guide plate 2 and an endless belt 12 having a rotatable roll 10 starting from a substantially vertical plane that is not a curved surface of the present invention.
  • FIG. 4 is a cross-sectional view showing a folded state.
  • FIG. 8 (a) is a plan view showing another example of the heating element folding device 1 of the present invention.
  • the heating element folding apparatus 1 is provided with a folding guide base 3 having a curved surface on the entrance side in the heating element folding apparatus 1 of the same type as in FIG.
  • FIG. 8 (b) is a perspective view showing another example of the folding guide base 3 of the present invention.
  • the entrance side is a folding guide 3 having a curved surface shape such as a circle or an ellipse, and a shape that continuously changes to a flat shape as it moves in the traveling direction. Further, a plurality of rotatable rolls 10 are provided on the lower surface portion of the heating element 33 that contacts the unfolded portion.
  • FIG. 8 (c) is a perspective view showing an example of the folding guide base 3 of the present invention.
  • the entrance side is a folding guide 3 having a curved surface shape such as a circle or an ellipse, and a shape that continuously changes to a flat shape as it moves in the traveling direction.
  • the lower surface portion in contact with the unfolded portion of the heating element has a surface with excellent slidability.
  • FIGS. 9A to 9J are front sectional views showing an example of folding of the heating element folding device 1 according to the present invention.
  • FIG. 7 shows a schematic diagram. 9A to 9D fold the right side of the heating element 33, and FIGS. 9E to 9H fold the left side of the heating element.
  • FIG. 9 (i) shows the holding plate 7 that holds the heating element 33 folded in three.
  • FIG. 9 (j) shows the heating element 33 folded on three laminated on the endless belt 12. First, it is bent first by the right folding guide plate 2 and the folding guide stand 3 (Fig. 9 (a) to (d)), and then it is bent first by the left folding guide plate 2 and the folding guide stand 3. It is folded so that it overlaps with the part (Fig. 9 (e) to (! 1)), and it is folded in three.
  • the folding guide plate 2 and the folding plan inner base 3 are removed in the above-described three-fold state, and are further transported and discharged while being sandwiched and pressed by the pressing plate 7. Since the pressing plate 7 is pressed elastically and with a Z or constant interval, it can be folded and flattened, and can be easily opened. Instead of the press plate 7, a frame press roll plate 8 may be used.
  • FIG. 10 shows another example of the heating element folding device 1 according to the present invention.
  • (A) is a perspective view
  • (b) is a perspective view of the folding guide base 4
  • (c) is a view of the folding guide base 4.
  • a side view is a plan view of the folding guide 4.
  • FIG. 10 (a) is a two-fold type heating element folding apparatus 1, which is a heating element folding apparatus 1 provided with a folding guide base 4 having a curved surface on the entrance side.
  • FIG. 10 (b) is a perspective view showing another example of the folding guide base 4 of the present invention.
  • the entrance side is a folding guide base 4 having a curved surface shape such as a circle or an ellipse, and a shape that continuously changes to a flat shape as it moves in the traveling direction. That is, it is a folding guide base having a shape that is flattened through at least a circular curved surface shape and an elliptical curved surface shape.
  • a plurality of rotatable rolls 10 are provided on the lower surface of the heating element 33 that contacts the unfolded portion!
  • Figure 10 (c) is a side view of the same.
  • Figure 10 (d) is a plan view.
  • FIGs. 11 (a) and (b) are sectional views showing an example of the automatic supply device 21 of the heating element folding device 1 of the present invention.
  • FIG. 11 (a) shows a state in which an automatic supply device 21 for automatically supplying the heating element before the folding process is attached.
  • the automatic supply device 21 is configured by providing a housing portion 20 in which the heating elements 33 are stacked and accommodated, and an extrusion means is provided at the bottom of the housing portion 20.
  • the extruding means 13 is constituted by an endless belt 12 having an extruding convex portion on the outer peripheral surface, and the drive motor for driving the extruding means 13 is constituted by a step motor or the like that rotates a predetermined amount by one drive. That is, one or more extruding protrusions are used to move the extruding convex portion from the position where the extruding convex portion is hooked to the lowermost heating element 33 to the diagonal position.
  • Form an extrusion of The extruding convex part may be a magnet (extruding magnet) 50.
  • the drive motor is driven by detection of a light projector provided at the entrance on the entry side of the folding means of the folding device 1 and a photoelectric sensor serving as a light receiver. That is, in the photoelectric sensor, it is detected that the mark provided on the transport means passes through a position corresponding to the entrance on the folding side of the folding device 1, and the drive motor is driven by this detection multiple. Like that.
  • the heating element 33 moves to the conveying means and is folded. All are driven in synchronism, and with this configuration, the heating element 33 can be automatically supplied, so that the folding process can be completely automated.
  • FIG. 12 shows an example of folding of the heating element folding device 1 of the present invention.
  • Figs. 12 (a), (d), and (g) are plan views, and Fig. 12 (b) ⁇ (c), (e) (F) is explanatory sectional drawing.
  • the heating element folding apparatus 1 in this example is the heating element folding apparatus 1 using the folding endless belt 24. If only the heating element 33 is inserted, the heating element folding apparatus 1 is configured to fold the heating element 33. If the packaging material 41 laminated with is put in, the heating element folding device 1 for folding the packaging material 41 together with the heating element 33 is obtained.
  • FIGS. 12A to 12C are folded from the “entrance” where the heating element 33 is conveyed. It is a figure which shows the process between "folding completion".
  • FIG. FIG. 12 (h) is a plan view showing the process until the entrance force also changes direction.
  • a pair of endless belts 2 are applied in the direction of travel E of the production line. 4 are arranged so as to face each other. Both endless belts 24 are positioned in a state where they are twisted so that the upstream force in the traveling method and the downstream force are gradually directed and the horizontal force gradually becomes vertical. That is, since the endless belt 24 is twisted by 90 ° so that both side forces also rise, the heating element 33 conveyed on the both endless belts 24 can be folded from both sides.
  • the roll 11 is disposed under the endless belt 24, and the roll 11 is disposed under the endless belt 24.
  • both endless belts are twisted at 90 ° compared to the state at the entrance, so the pair of rolls on the entrance side is also on the exit side after the folding is completed. It is arranged so as to be perpendicular to the pair of rolls 11.
  • the heating element 33 flowing on the endless belt 24 is gradually folded into two, each of the heating element 33 and the heating element 33 1S laminated on the packaging material 41. It will become. Due to the above-described configuration, the pair of rolls 11 on the entrance side, the pair of rolls 11 on the exit side, and the twisted endless belt 24 are used until the process is completed. The heating element 33 is folded together.
  • the heating element 33 and the heating element 33 laminated on the packaging material 41 can be gradually changed in the horizontal direction. And it is conveyed to the next process by a pair of rolls.
  • the heating element 33 is arranged in the vertical direction as shown in FIG. 12 (g). Is kept in a vertical state, the packaging material is sealed, and each sealed heating element 33 is sandwiched between a pair of endless belts 24 twisted at 90 ° to be transported horizontally. It is also possible to set the direction.
  • FIG. 13 is a perspective view showing another example of the heating element folding device 1 of the present invention.
  • the packaging material 41 in which the heating elements 33 supported by the holding rolls are laminated presses the heating element 33 against the folding guide base 3 and advances along the folding guide base 3, and the pressing plate 7 provided downstream is provided. 8 by folding the packaging material 41 and holding it on the unfolded part, Fold the heating element 33.
  • the folding guide base 3 has a curved surface, starts from a circular or elliptical curved surface, has a rotatable tool 10, and the rotatable roll 10 supports the unfolded portion of the heating element 33. . Before the heating element is folded, part of the heating element and part of the packaging sheet are temporarily attached 59 with a weak adhesive.
  • the entrance side is a curved guide shape with a circular or elliptical cross-sectional shape.
  • the folding guide stand has a shape that bends into a curved shape as it moves in the direction of travel, and further changes into a flat shape as it progresses. It is.
  • a plurality of rotatable rolls are provided on the lower surface of the heating element 33 that contacts the unfolded portion.
  • FIG. 14 is a perspective view showing another example of the heating element folding device 1 of the present invention.
  • the wrapping material 41 in which the heating element 33 supported by the holding roll 11A is laminated presses the heating element 33 against the folding guide 3 and advances along the folding guide 3, and the holding plate 7 (framework provided downstream).
  • the heating element 33 is folded by folding the packaging material 41 with the pressing roll plate 8) and pressing it to the unfolded portion. Before the heating element is folded, a part of the heating element and a part of the packaging sheet are temporarily attached 59 with a weak adhesive.
  • the folding guide base 3 has a substantially vertical surface that is not a curved surface, has a rotatable roll, and the rotatable roll 10 supports a portion of the heating element 33 that is not folded.
  • the entrance side has a substantially vertical surface with a curved cross-sectional shape, but as it moves in the direction of travel, it bends into a curved surface, and further, as it progresses, it has a shape that continuously changes to a flat shape. 3.
  • a plurality of rotatable rolls 10 are provided on the lower surface portion of the heating element 33 that contacts the unfolded part!
  • FIG. 15 shows the heating element 33 in which the heating elements 33 are stacked and transported in three rows on the packaging material 41, are slit while being held by the frame holding roll plate 8, and the heating elements 33 are folded for each row.
  • 6 is a plan view showing another example of the heating element folding device 1.
  • FIG. 15 As shown in FIG. 15, the slit cutting roll 53 and the folding means force are also provided.
  • the slit cut roll 53 has a wide packaging material 41 in a state in which a plurality (three) of heating elements are connected in the parallel direction in the conveying direction so as to be continuously one in the parallel direction. It is to be cut and is arranged on the downstream side of the heating element body mounting device 1.
  • the heat element 33 is laminated.
  • the slit cut roll 53 is provided with a circumferential cutting blade at an axial position that divides the packaging material 41 into three equal parts in the width direction, and the packaging material is mounted in the parallel direction by the cutting blade 3
  • Each of the heating elements 33 is continuously cut in the transport direction at the center.
  • the folding device 1 is a heat generating device in which a plurality of (three) packaging materials 41, each of which is cut in the conveying direction by a slit cut roll 53, are stacked on top of each other.
  • Folding body 33 together with the intermediate seal part of the heating element 33 in the width direction is folded in two, and includes a frame pressing roll plate 8, an endless belt 12, a folding guide base 3, a folding guide plate 2, and a pressing plate 7.
  • the packaging material 41 also serves as the folding guide plate 2.
  • the endless belt 12 conveys the heating element 33 cut in the conveyance direction by the slit cut roll 53 to the stacked roll of the packaging material 41 to the press roll through the press roll 11A, the folding guide stand 3, and the press plate 7. Therefore, it is arranged along the outer surface side of the packaging material 41 (the side on which the heating element body is laminated), that is, along the lower side of the packaging material 41.
  • the endless belt 12 may be arranged along a plurality (three) of the packaging materials 41 in the parallel direction, or a plurality of endless belts 12 may be arranged in parallel so as to correspond to the plurality of packaging materials 41, respectively.
  • the holding roll 11A presses the packaging sheet 41 outside the both ends of the heating element 33, and supplies the heating element 33 and the packaging sheet 41 to the folding guide plate 2 and the folding plan base 3.
  • the folding guide stand 3 is formed in a long shape, and the folding half of the heating element 33 and the packaging material 41 (the half opposite to the fixed half face) is pressed against the folding guide stand 3 so that the fixed half It has a function of receiving a functional surface composed of scooping guide, splash-down guide, inward guide and folding guide in the conveying direction, and the heating element 33 is connected to the packaging material 41. Fold together.
  • the magnet 50 may be provided along the traveling path where the heating element 33 of the folding guide base 3 of the present invention is folded.
  • the magnet 50 may be provided on the outer surface of the folding guide base 3, on the inner side of the hollow folding guide base 3, or on the inner wall. When provided on the outer surface, it is preferably embedded in the outer surface.
  • a rotatable roll, a ball 10 or the like may be provided below the folding guide base 3 that supports the unfolded portion of the heating element 33. Folded heating element 33 and packaging material 41 move There may be no resistance.
  • the magnet 50 may be an electromagnet or a permanent magnet as long as it has a magnetic force.
  • the heating element 33 is laminated with the endless belt 12 in the state where the folded half surface is folded on the fixed half surface side so that the heating element 33 is on the downstream side of the pressing roll 11A. It is passed between the plates 7 and 8 and further conveyed downstream by a press roll on the downstream side of the press plates 7 and 8.
  • the holding plate 7 assists the folding guide base 3 and the packaging material 14 to perform inward guide and folding guidance, and the folding is completed.
  • the press roll consists of a folding guide base 3, a packaging material 41, and a heating element folded in a folded state by a holding plate 33.
  • the laminated packaging material 41 is provided with a certain tension on the upstream side and downstream. It conveys to the side and is provided with a pair of upper and lower rolls.
  • the press roll is not limited as long as the packaging material can be conveyed downstream while applying a certain tension to the upstream side, a balloon roll with a built-in air, a heating roller 33 part with a recessed part, and a packaging material 41 An example of both end sandwiching rolls sandwiching both end portions is given.
  • a pair of upper and lower endless belts 12 may be used instead of the rolls.
  • the heating elements 33 are stacked in the form of a plurality of (three) heating elements each cut by the slit cut roll 53 in the conveying direction.
  • the wrapping material 41 is pulled downstream with a predetermined tension by the press roll while the folding half surface is in contact with the folding guide base 3 surface on the downstream side of the pressing roll 11A.
  • the folding half surface side is raised along the curved portion.
  • the folding half surface side of the heating material 33 laminated packaging material 41 gradually moves from the intermediate seal (folded part) side to the fixed half surface side in the width direction as it moves downstream along the curved surface of the folding guide base 3.
  • the folding guide base 3 is folded in a double-folded state with the entire widthwise direction overlapped with the fixed half surface side on the most downstream side of the folding guide base 3, and is further pressed by the downstream press roll in the folded state and downstream. To the sealing device side.
  • FIG. 16 shows another example of the heating element folding device 1 of the present invention
  • FIG. 16 (a) is a perspective view
  • (b) is a perspective view
  • (c) is a front sectional view
  • (d) is a front sectional view. It is front sectional drawing.
  • the folding device 1 of this example covers and conveys the packaging material 41 of the heating element 33 laminated on the endless belt 12, and, along with the packaging material 41, along the intermediate seal portion of the heating element 33 in the width direction 2 As shown in Fig. 16, it is folded in a folded shape. It is equipped with a pressing endless belt (pressing roll) 12, a plate-shaped folding guide base 3, an endless belt 12, and a support plate 25.
  • heating element 33 By wrapping the heating element 33 on the guide stand 3 with the packaging material 41, sandwiching the plate-shaped folding guide stand 3 with the packaging material 41, and sandwiching it with the presser endless belt (press roll) 12 and the support plate 25
  • the heating element 33 is folded in a folded state, the folding guide base 3 is pulled out, and the heating element 33 and the packaging material 41 are folded in two and conveyed to the next process.
  • the pressless endless belt 12 is positioned on the packaging material 41 and folds the heating element sandwiched between the packaging material 41 and the plate-shaped folding guide base 3 together with the support plate 25 in a folded state.
  • the upstream side of the presser endless belt protrudes perpendicularly to the upstream side of the downstream side, i.e., the surface of the plate-shaped folding guide base, proceeds to the surface of the plate-shaped folding guide base, and is parallel to the surface of the folding guide base. It may be a form that progresses and becomes one.
  • the plate-shaped folding guide base 3 is formed in a long shape so that the side line portion on the fixed half surface side covers the entire heating element 33 including the portion where the heating element 33 is folded on the upstream side.
  • a gentle constriction is formed diagonally so as to approach the intermediate seal part of the heating element 33 from the upstream side to the downstream side, and the folding part such as the intermediate seal part of the heating element 33 after the position where the folding is completed A fold-in guide portion extending along the line.
  • the folding half of the heating element 33 and the packaging material 41 (the half opposite to the fixed half) is guided so that it overlaps the fixed half with the folding guide stand in between.
  • the heating element 33 is folded together with the packaging material 41.
  • the heating element 33 has a function of receiving a functional surface composed of an inward guide and a folding guide.
  • the plate-like folding guide base 3 is supported at the above-mentioned arrangement position via arbitrary support means (not shown).
  • Heating element 33 The laminated packaging material 41 is folded downstream of the holding endless belt 12 with the folding half on the folding half so that the heating element 33 is on the inside and folded on the fixed half side. In this state, the presser endless belt 12 is inserted between the support plate 25 and the support plate 25, and further conveyed downstream by the seal roll 31 on the downstream side of the support plate 25. [0101] The support plate 25 presses the packaging material against the folding guide stand 3, and folds the heating element 33 and the packaging material 41 into two. Use an endless belt 12 instead of the support plate 25.
  • the 0 plane is preferred.
  • FIG. 16 (b) is an explanatory perspective view illustrating a process in which the holding endless belt 12 and the folding guide base 3 having a surface excellent in slidability and the heating element are folded in two.
  • FIG. 16 (c) shows a state in which the heating element 33 and the packaging material 41 are folded using the folding endless belt 12 and the folding guide base 3 and the support base 25 having a surface excellent in slidability.
  • FIG. 16 (d) shows a frame pressing roll plate 8 having a rotatable roll surface, a plate-shaped folding guide base 3 having a rotatable central surface, and a support plate 25 having a rotatable roll surface.
  • FIG. 10 is a cross-sectional view showing another example of a state where the heating element 33 is folded by use.
  • FIG. 17 shows another example of the frame assembly pressing roll 8 of the heating element folding device 1 of the present invention.
  • Fig. 17 (a) the entire heating element 33 is stacked on the inlet side, and a gentle constriction is formed diagonally from the upstream side to the downstream side so as to approach the intermediate seal portion of the heating element 33 body, and the folding is completed. After this position, it becomes a folding guide that extends along the intermediate seal part of the heating element 33, and on the outlet side is a plate-shaped folding guide base that is thin enough to allow the folded heating element 33 to come out smoothly.
  • FIG. A plurality of rotatable rolls are provided on both sides so that the folded heating element 33 and the packaging material 41 are not resistant to movement.
  • Fig. 17 (b) is a cross-sectional view of Z-Z.
  • FIGS. 17C to 17H show another example of the framework roll 54.
  • FIG. It can be used for the plate-shaped folding guide 3, the support plate 25, the lower part of the folding guide, etc.
  • Fig. 17 (c) is a plan view of another example of a frame roll 54 having a plurality of roll forces provided with gap closing plates
  • Fig. 17 (d) is a cross-sectional view taken along line Y-Y in Fig. 17 (c). It is. Even if the roll 10 is replaced with a ball bearing 10 or the like, a frame ball 54 having the same function can be formed.
  • FIG. 17 is a side cross-sectional view of another example of the frame roll 54 shown in FIGS. 17 (e), (f), and (h), and a surface having excellent slidability is provided on the surface opposite to the surface on which the roll 11 is provided. Both sides are exothermic
  • the body 33 and the packaging material 41 have no resistance to movement, and the plurality of rotatable rolls 10 shown in FIG. 17 (b) are provided on both sides and have the same function as the frame roll 54.
  • FIG. 17 (g) is a side view showing another example of the support plate 25 and the pressing plates 7 and 8 (having a slidable surface) having a surface excellent in slidability.
  • FIG. 18 is a perspective view showing another example of the outer bag folding device according to the present invention.
  • FIG. 18 (a) shows the folded heating element 33 in a non-breathable manner.
  • FIG. 11 is a perspective view of another example of the outer bag folding device 55 showing a seal in a double fold when the three-side seal is enclosed in the outer bag as a storage body.
  • “Kannon folding” refers to a folding method in which folding is performed so that it can be opened from the middle to the left and right.
  • FIG. 18 (b) and 18 (c) are perspective views showing another example of the outer bag folding guide base 56.
  • FIG. 18 (b) and 18 (c) are perspective views showing another example of the outer bag folding guide base 56.
  • FIG. 19 is an explanatory view showing an example of the production 26 of the folded heating element enclosed in the outer bag which is the non-breathable storage bag of the present embodiment.
  • Heating element manufacturing device 26 alignment interval changing device 29, temporary wearing adhesive installation device 58, heating element folding device 30, sealing device 31, and cutting device 32 are provided, heating element manufacturing, heating element folding Then, the folded heating element is continuously sealed in the outer bag, and the folded heating element 34 sealed in the outer bag is continuously cut.
  • FIG. 20 (a) shows that the eight divided heat generating portions 38 according to the present invention are provided in stripes at intervals with the divided portions 57 as the seal portions 42, and on the vent surface side, the melt blown portion is provided.
  • FIG. 6 is a plan view showing an example of a pleated rectangular heating element 33 having a mesh (mesh) breathable pressure-sensitive adhesive layer 44 provided by the method before folding.
  • FIG. 20 (b) is a cross-sectional view taken along the line XX, in which the separator is provided on the breathable adhesive material layer 44.
  • FIG. 20 (b) is a cross-sectional view taken along the line XX, in which the separator is provided on the breathable adhesive material layer 44.
  • FIG. 20 (c) is a cross-sectional view showing a state 34 in which a heating element 33 with a separator is folded in two and enclosed in an outer bag 49 which is a non-breathable storage bag.
  • FIG. 20 (d) is a plan view showing a state 34 in which a heating element 33 with a separator is folded in two and enclosed in an outer bag 49 which is a non-breathable storage bag.
  • FIG. 20 (e) shows a section 57 where the two section heat generating sections 38 of the present invention are the seal sections 42.
  • FIG. 20 (f) is a cross-sectional view taken along the line XX, in which the separator 45 is provided on the breathable adhesive material layer 44.
  • FIG. 20 (f) is a cross-sectional view taken along the line XX, in which the separator 45 is provided on the breathable adhesive material layer 44.
  • FIG. 20 (g) is a cross-sectional view showing a state in which the heating element 33 with a separator is folded in two and enclosed in an outer bag 49 which is a non-breathable storage bag.
  • FIG. 20 (h) is a cross-sectional plan view showing another example of the heating element 33 in which the solid adhesive layer 43 with a separator is provided on the non-breathable surface side.
  • FIG. 20 (i) shows that the eight divided heat generating portions 38 of the present invention are provided in stripes with the divided portions 57, which are the seal portions 42, spaced apart, and are provided on the ventilation surface side by the melt blow method.
  • FIG. 4 is a plan view showing an example of a pleated broad bean-shaped heating element 33 having a net-like air-permeable pressure-sensitive adhesive layer 44 before being folded.
  • FIG. 20 (j) shows that the eight divided heat generating portions 38 of the present invention are provided in stripes with the divided portions 57 being the seal portions 42 as an interval, and the heat generating element 33 has a non-breathable surface side.
  • FIG. 6 is a plan view showing an example before folding of a lantern-type heating element 33 having a narrowed pleat-shaped center having solid-type adhesive layers 43 at both ends thereof.

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Abstract

An exothermic-element folding apparatus that even when a high-speed operation is performed, enables stably obtaining of good folding finished articles. There is provided exothermic-element folding apparatus (1) for, with respect to exothermic element (33) having multiple divided exothermic parts (38) containing an exothermic composition arranged via dividing regions (57) being seal portions, produced through arranging of exothermic composition moldings (35) adjacent to each other on base material (40), covering of the same with covering material (39) and sealing of the peripheries of the exothermic composition moldings (35), folding the exothermic element (33) with the use of the dividing regions (57) as folding lines, characterized in that the exothermic-element folding apparatus (1) is equipped with endless belt (12) for delivery of the divided exothermic parts (38) positioned inside and equipped with folding guide plate (2) rising from a lateral outer edge portion of the endless belt (12) and curving along the direction of delivery of the divided exothermic parts (38) gradually toward the side of the endless belt (12).

Description

明 細 書  Specification
発熱体折り畳み装置  Heating element folding device
技術分野  Technical field
[0001] 本発明は、折り畳み支持手段により搬送手段の表面に積層維持されて搬送される 発熱体の折り畳み部を折り畳み案内手段により発熱体を折り畳む装置に関するもの である。  [0001] The present invention relates to a device for folding a heating element by folding guide means for folding a folding part of the heating element that is conveyed while being stacked on the surface of the conveying means by a folding support means.
背景技術  Background art
[0002] 発熱剤収納部が略中央に形成された略直線状の中間シール部により区分され、各 発熱剤収納部が前記非通気性シートに対して前記通気性シート側に膨出する片側 膨出状に形成されたカイロ本体を、包装シートの一面に剥離層を設け、前記剥離層 に重ねて形成した粘着層上に重ねるように装着した包装シートを使用し、前記包装 シートを、押さえロールの下流側で折り畳み半面をその固定半面側に重ね合わせた 状態で折り畳み案内板と折り畳み搬送ベルトとの間に挟み込み、プレスベルトにより 所定の張力で下流側に引っ張り、押さえロールは、その軸方向一端側がカイロ本体 の中間シール部に沿って相対移動し、折り畳み半面側はその中間シール部に沿つ て谷折り状に立ち上げられ、前記カイロ本体の前記中間シール部に沿って折り畳む 前記剥離層を前記粘着層の外側に密着させた状態で、その折り曲げ部を除く周縁 部の互いに対向する縁部同士をシールすることにより袋状に封止する方法が特許文 献 1に開示されている。  [0002] The exothermic agent accommodating portion is divided by a substantially straight intermediate seal portion formed in the approximate center, and each exothermic agent accommodating portion bulges toward the breathable sheet with respect to the non-breathable sheet. The body of the warmer formed in a protruding shape is provided with a release layer on one side of the packaging sheet, and the packaging sheet is mounted so as to be superimposed on the adhesive layer formed on the release layer. The folding roll is sandwiched between the folding guide plate and the folding transport belt in a state where the folding half is overlapped with the fixed half side, and is pulled downstream with a predetermined tension by the press belt. The side moves relative to the intermediate seal part of the body warmer, the folding half surface side rises along the intermediate seal part in a valley fold shape, and folds along the intermediate seal part of the body warmer. Patent Document 1 discloses a method of sealing in a bag shape by sealing edges that face each other at the peripheral edge except for the bent portion in a state where the release layer is in close contact with the outside of the adhesive layer. Has been.
[0003] しかし、特許文献 1では、包装シート側の剥離層に重ねて粘着剤層を形成しておき 、その粘着層に重ねるようにカイロ本体を装着するタイプの 、わゆる外袋一体型の力 イロのみに適用できる折り込み装置であり、折り込み方法であった。  [0003] However, in Patent Document 1, an adhesive layer is formed on the release layer on the side of the packaging sheet, and the body body is attached so as to overlap the adhesive layer. This is a folding device that can be applied only to force iro, and was a folding method.
通常、一般に使用されている、カイロ本体側に粘着剤層を形成して、非通気性の包 装シートに装着する、即ち、非通気性の収納袋である外袋にセパレータ付き粘着剤 層を設けた発熱体の折り込みには適用できな力つた。  Usually, a pressure-sensitive adhesive layer is formed on the side of the body that is generally used, and is attached to a non-breathable packaging sheet, that is, a pressure-sensitive adhesive layer with a separator is attached to an outer bag that is a non-breathable storage bag. The force that cannot be applied to the folding of the heating element provided.
また、外袋に設けられた粘着剤層にカイロが固定されて 、ることが必須条件である ため、外袋に粘着剤層を介して固定されていない発熱体には適用できな力つた。 また、カイロを使用するときのカイロ固定層としての粘着剤層が外袋に設けられ、前 記粘着剤層にカイロが固定されている場合以外で、 3つ以上複数の区分発熱部を有 する発熱体のに場合、各区分発熱部の間で折れ曲がり、押さえロールによるカイロ本 体の中間シール部に沿って谷折り状の立ち上げがうまく起動せず、折り畳みに不具 合が生じた。 In addition, it is an essential condition that the body is fixed to the adhesive layer provided on the outer bag. For this reason, it was difficult to apply to a heating element that is not fixed to the outer bag via an adhesive layer. In addition to the case where the outer bag is provided with a pressure-sensitive adhesive layer as a warmer fixing layer when using a warmer, there are three or more divided heat generating portions except when the warmer is fixed to the pressure-sensitive adhesive layer. In the case of a heating element, it was bent between each section heating part, and the rise of the valley fold did not start well along the intermediate seal part of the body of the warmer by the presser roll, and there was a problem with the folding.
また、折りたたみの仕上がりが不安定で不良品が生じやすいというような問題があつ た。  Another problem is that the folding finish is unstable and defective products tend to occur.
[0004] 特許文献 1:特開 2004— 344328号公報  [0004] Patent Document 1: Japanese Patent Application Laid-Open No. 2004-344328
発明の開示  Disclosure of the invention
発明が解決しょうとする課題  Problems to be solved by the invention
[0005] この発明は上記課題を解消するためになされたもので、高速運転をしても、安定し て良好な折りたたみ仕上がり品が得られる発熱体折りたたみ装置を得ることを目的と する。 [0005] The present invention has been made to solve the above-described problems, and an object of the present invention is to obtain a heating element folding device that can stably obtain a good folding finished product even at high speed operation.
課題を解決するための手段  Means for solving the problem
[0006] 本発明者は、鋭意研究を重ね、前記問題を解決し、本発明を完成した。 [0006] The inventor has conducted intensive research, solved the above problems, and completed the present invention.
即ち、本発明の発熱体折り畳み装置は、請求項 1に記載の通り、成形された発熱組 成物を、基材上に隣接して配置するとともに被覆材により被覆して、前記成形された 発熱組成物の周縁部をシールして、発熱組成物を含む区分発熱部を、シール部で ある区分け部を介して複数備える発熱体を、前記区分け部を折り目にして折り畳むた めの発熱体折り畳み装置であって、前記発熱体折り畳み装置は、前記発熱体の一 端側に位置する前記区分発熱部を搬送するためのベルトと、前記発熱体の他端側 に位置する前記区分発熱部を、前記搬送方向に下流側に向かって支持しながら、前 記発熱体の一端側に重ねるために、前記搬送方向において、前記ベルトの他端側 力も一端側に向かって湾曲する折り畳み案内板を備えることを特徴とする。  That is, the heating element folding device according to the present invention, as described in claim 1, arranges the molded heating composition adjacent to the substrate and coats it with a coating material, thereby forming the molded heating element. A heating element folding apparatus for sealing a peripheral portion of a composition and folding a heating element including a plurality of segmented heating parts containing a heating composition via a partitioning part, which is a sealing part, with the sectioning part being folded. The heating element folding device includes: a belt for transporting the divided heat generating part located on one end side of the heating element; and the divided heating part located on the other end side of the heating element. In order to overlap the one end side of the heating element while supporting it toward the downstream side in the transport direction, a folding guide plate is also provided in which the force on the other end side of the belt is curved toward the one end side in the transport direction. Features.
また、請求項 2に記載の本発明は、請求項 1に記載の発熱体折り畳み装置におい て、前記発熱体折り畳み装置は、ガス供給装置を備え、前記ガス供給装置からのガ スを、前記案内板の内側面に沿って吹き出すようにしたことを特徴とする。 また、請求項 3に記載の本発明は、請求項 2に記載の発熱体折り畳み装置におい て、前記中央ベルトの側方にも、前記外側の区分発熱部を搬送するためのベルトを 備え、前記ベルト表面にも、前記ガス供給装置力 のガスを吹き出すようにしたことを 特徴とする。 Further, the present invention described in claim 2 is the heating element folding apparatus according to claim 1, wherein the heating element folding apparatus includes a gas supply device, and the gas from the gas supply device is guided to the guide. It is characterized by blowing along the inner surface of the plate. Further, the present invention according to claim 3 is the heating element folding device according to claim 2, further comprising a belt for conveying the outer divided heat generating portion on the side of the central belt, The gas of the gas supply device force is also blown out to the belt surface.
また、請求項 4に記載の本発明は、請求項 1乃至 3の何れかに記載の発熱体折り畳 み装置にぉ 、て、前記折り畳み案内板の外側の外縁部側に沿って磁石を設けたこと を特徴とする。  According to a fourth aspect of the present invention, in the heating element folding device according to any one of the first to third aspects, a magnet is provided along the outer edge side of the outer side of the folding guide plate. It is characterized by that.
また、請求項 5に記載の本発明は、成形された発熱組成物を、基材上に隣接して 配置するとともに被覆材により被覆して、前記成形された発熱組成物の周縁部をシ ールして、発熱組成物を含む区分発熱部を、シール部である区分け部を介して複数 備える発熱体を、前記区分け部を折り目にして折り畳むための発熱体折り畳み装置 であって、前記発熱体折り畳み装置は、前記発熱体の一端側に位置する前記区分 発熱部を搬送するためのベルトと、前記発熱体の他端側に位置する前記区分発熱 部を、前記搬送方向に下流側に向かって支持しながら、前記発熱体の一端側に重 ねるために、前記搬送方向において、前記ベルトの他端側から一端側に向力 て曲 面を有する折り畳み案内台を備えることを特徴とする。  Further, according to the present invention of claim 5, the molded exothermic composition is disposed adjacent to the substrate and covered with a coating material, and the peripheral portion of the molded exothermic composition is sealed. A heating element folding device for folding a heating element comprising a plurality of segment heating parts containing a heating composition via a sorting part as a seal part by folding the sorting part, wherein the heating element The folding device includes a belt for conveying the divided heat generating portion located on one end side of the heating element and the divided heating portion located on the other end side of the heating element toward the downstream side in the conveying direction. In order to overlap the one end side of the heating element while supporting, a folding guide base having a curved surface directed from one end side to the other end side of the belt in the transport direction is provided.
また、請求項 6に記載の本発明は、請求項 1乃至 5の何れかに記載の発熱体折り畳 み装置において、前記折り畳み案内板及び前記折り畳み案内台の少なくとも何れか の前記発熱体と接触する側の表面に、摺動性を有する材料を設けたことを特徴とす る。  The invention according to claim 6 is the heating element folding apparatus according to any one of claims 1 to 5, wherein the heating element is in contact with at least one of the folding guide plate and the folding guide base. It is characterized in that a material having slidability is provided on the surface on the side to be processed.
また、請求項 7に記載の発熱体折り畳み装置は、成形された発熱組成物を、基材 上に隣接して配置するとともに被覆材により被覆して、前記成形された発熱組成物の 周縁部をシールして、発熱組成物を含む区分発熱部を、シール部である区分け部を 介して複数備える発熱体を、前記区分け部を折り目にして折り畳むための発熱体折 り畳み装置であって、前記発熱体折り畳み装置は、前記区分発熱部を搬送するため のベルトを備え、前記ベルト面に対して交わる関係にある軸のローラを備えることを特 徴とする。  The heating element folding device according to claim 7, wherein the molded exothermic composition is disposed adjacent to the substrate and covered with a coating material, and the peripheral portion of the molded exothermic composition is covered. A heating element folding device for sealing and heating a heating element comprising a plurality of segmented heating elements containing a heating composition via a partitioning part that is a sealing part, with the partitioning part being folded. The heating element folding device includes a belt for transporting the divided heating section, and includes a roller having a shaft that intersects the belt surface.
また、請求項 8に記載の本発明は、請求項 7に記載の発熱体折り畳み装置におい て、前記ベルトと前記搬送ベルトとの間に、包装シートを供給するため包装シート供 給装置を設けることを特徴とする。 Further, the present invention according to claim 8 is directed to the heating element folding device according to claim 7. A wrapping sheet supply device is provided between the belt and the conveyor belt for supplying the wrapping sheet.
また、請求項 9に記載の本発明は、請求項 5乃至 8の何れかに記載の発熱体折り畳 み装置において、前記発熱体及び前記包装シートから選ばれた少なくとも 1種の一 部に外仮着用の粘着剤を設けるための粘着剤設置装置を備えることを特徴とする。 本発明の発熱体は、請求項 10に記載の通り、請求項 1乃至 9の何れかに記載の発 熱体折り畳み装置から選ばれた少なくとも 1種により製造された、 2つ以上複数に折り 畳まれた発熱体が非通気性収納袋に封入されたことを特徴とする。  Further, the present invention according to claim 9 is the heating element folding device according to any one of claims 5 to 8, wherein the heating element folding apparatus is external to at least one part selected from the heating element and the packaging sheet. It is provided with an adhesive installation device for providing a temporary adhesive. The heating element according to the present invention, as described in claim 10, is produced by at least one selected from the heating element folding apparatus according to any one of claims 1 to 9, and is folded into two or more. The rare heating element is sealed in a non-breathable storage bag.
また、請求項 11に記載の発熱体は、請求項 10に記載の発熱体において前記発熱 体の露出部の少なくとも一部が非通気性収納袋の少なくとも一部に仮着され、非通 気性収納袋に封入されたことを特徴とする。  Further, the heating element according to claim 11 is the heating element according to claim 10, wherein at least a part of the exposed portion of the heating element is temporarily attached to at least a part of the non-breathable storage bag. It is sealed in a bag.
以下に、本発明の好ましい態様を説明する。  Below, the preferable aspect of this invention is demonstrated.
本発明の発熱体折り畳み装置は、搬送手段の表面に積層維持されて搬送される発 熱体の折り畳み部を折り畳み支持手段と折り畳み案内手段により折り畳む装置であ つて、前記発熱体の折り畳まない部分が少なくとも搬送手段上に積層され、前記折り 畳み支持手段が該発熱体の折り畳まない部分を支持し、搬送手段の移動に伴い、 折り畳み支持手段と折り畳み案内手段により発熱体の折り畳み部を折り畳み、発熱 体を折り畳む機能を有するように、搬送手段、折り畳み支持手段、折り畳み案内手段 が配置され、該搬送手段が無端状ベルト、包装材力 選ばれた少なくとも 1種であり、 該折り畳み案内手段が折り畳み案内板、折り畳み無端状ベルト、包装材、押さえ板 の中から選択された少なくとも 1種であり、折り畳み支持手段が折り畳み案内台、板状 折り畳み案内台、枠組み押さえロール。磁石カゝら選ばれた少なくとも 1種であることが 好ましい。  The heating element folding device according to the present invention is a device that folds a folded portion of a heating element that is transported while being stacked and maintained on the surface of the conveying means by means of a folding support means and a folding guide means, and a portion of the heating element that is not folded is provided. At least stacked on the conveying means, the folding support means supports the unfolded portion of the heating element, and the folding part of the heating element is folded by the folding supporting means and the folding guide means as the conveying means moves, and the heating element The conveying means, the folding support means, and the folding guide means are arranged so as to have a function of folding, and the conveying means is at least one selected from an endless belt and a packaging material force, and the folding guide means is a folding guide plate. , Folding endless belt, packaging material, presser plate, and folding support means Inner base, plate-shaped folding guide base, frame presser roll. Preferably, at least one selected from magnet magnets is used.
本発明の発熱体折り畳み装置は、搬送手段の表面に積層維持されて搬送される発 熱体の折り畳み部を折り畳み支持手段と折り畳み案内手段により折り畳む装置であ つて、前記発熱体の折り畳まない部分が少なくとも搬送手段上に積層され、前記折り 畳み支持手段が該発熱体の折り畳まない部分を支持し、搬送手段の移動に伴い、 折り畳み支持手段と折り畳み案内手段により発熱体の折り畳み部を折り畳み、発熱 体を折り畳む機能を有するように、搬送手段、折り畳み支持手段、折り畳み案内手段 が配置され、該搬送手段が無端状ベルト、包装材力 選ばれた少なくとも 1種であり、 該折り畳み案内手段が折り畳み案内板、折り畳み無端状ベルト、包装材、押さえ板 の中から選択された少なくとも 1種であり、折り畳み支持手段が折り畳み案内台、板状 折り畳み案内台、枠組み押さえロール、磁石力 選ばれた少なくとも 1種であり、前記 無端状ベルトを発熱体の中央部分の幅の中央とその両側の無端状ベルトとに三分 割し、少なくとも発熱体の中央部は折り畳み支持手段により支持され、両側の無端状 ベルトは前記発熱体の両側折り畳み部を掬い上げるまでに必要な最小限の長さとし 、前記発熱体の両側張り出し部を掬 ヽ上げる部分を前記中央ベルトと両側のベルトと の間の折り込み支持手段が作用しない間隔部に着設したことが好ましい。 The heating element folding device according to the present invention is a device that folds a folded portion of a heating element that is transported while being stacked and maintained on the surface of the conveying means by means of a folding support means and a folding guide means, and a portion of the heating element that is not folded is provided. At least stacked on the conveying means, the folding support means supports the unfolded portion of the heating element, and the folding part of the heating element is folded by the folding supporting means and the folding guide means as the conveying means moves, and heat is generated. The conveying means, the folding support means, and the folding guide means are arranged so as to have a function of folding the body, and the conveying means is at least one selected from an endless belt and a packaging material force, and the folding guide means is the folding guide. At least one selected from the group consisting of a plate, a folded endless belt, a packaging material, and a pressing plate, and the folding support means is a folding guide stand, a plate-shaped folding guide stand, a frame pressing roll, and a magnet force. The endless belt is divided into a center of the width of the central portion of the heating element and an endless belt on both sides thereof, and at least the center of the heating element is supported by folding support means, and the endless belts on both sides Is the minimum length required for scooping up both sides of the heating element, and the center bell It is preferred that the folding support means between the two sides of the belt and clamped by the spacing portion does not act as.
また、折り畳み装置は、前記案内手段の先端部と前記搬送手段との間にガスを吹 きつけるようにガスノズル及びガス供給装置を設けたことが好ま ヽ。  Further, it is preferable that the folding device is provided with a gas nozzle and a gas supply device so as to blow gas between the front end portion of the guide means and the transport means.
また、折り畳み装置は、前記折り畳み案内手段の発熱体反対側に位置する裏面部 に磁石を設けたことが好まし ヽ。  In addition, it is preferable that the folding device is provided with a magnet on the back surface portion located on the opposite side of the heating guide of the folding guide means.
また、折り畳み装置は、前記折り畳み案内手段及び折り畳み支持手段から選ばれ た少なくとも 1種の少なくとも発熱体側の表面の材質を摺動性を有する素材としたこと が好ましい。  In the folding apparatus, it is preferable that at least one kind of material selected from the folding guide means and the folding support means is made of a material having a sliding property.
本発明の発熱体折り畳み装置は、搬送手段の表面に積層維持されて搬送される発 熱体の折り畳み部を折り畳み支持手段と折り畳み案内手段により折り畳む装置であ つて、搬送手段を折り畳み支持手段と折り畳み案内手段とにより折り畳むことにより、 搬送手段に積層された発熱体を折り畳む機能を有し、該搬送手段が包装材であり、 該案内手段及び支持手段が 2本の無端状ベルトからなる 1対の無端状ベルトとからな り、該 1対の無端状ベルトの一端部である入側と他の一端部である出側が 90° ずれ 、且つ、一端部では回転軸が同じであり、他の一端部では各回転軸が平行であり、 該搬送手段を挟めるように 2つの無端状ベルトの一面が相対して配置されて 、ること が好ましい。  The heating element folding device of the present invention is a device that folds the folded portion of the heat generating body that is transported while being stacked and maintained on the surface of the conveying means by the folding support means and the folding guide means, and the conveying means is folded with the folding support means. The heating means stacked on the conveying means has a function of being folded by the guiding means, the conveying means is a packaging material, and the guiding means and the supporting means are a pair of endless belts. The end side of the pair of endless belts is shifted by 90 ° from the entrance side which is one end of the pair of endless belts and the exit side which is the other end. It is preferable that the rotary shafts are parallel to each other, and that one surface of the two endless belts is disposed so as to sandwich the conveying means.
本発明の発熱体折り畳み装置は、搬送手段の表面に積層維持されて搬送される発 熱体の折り畳み部を折り畳み支持手段と折り畳み案内手段により折り畳む装置であ つて、搬送手段を折り畳み支持手段と折り畳み案内手段とにより折り畳むことにより、 搬送手段に積層された発熱体を折り畳み且つ搬送手段の TD方向軸が折り畳み前と 折り畳み後で、同じである機能を有し、該搬送手段が包装材であり、該案内手段及 び支持手段が前部折り畳み手段と後部折り畳み手段からなる 2組の 1対の無端状べ ルトからなり、前部折り畳み手段は該 1対の無端状ベルトの一端部である入側と他の 一端部である出側が 90° ずれ、且つ、一端部では回転軸が同じであり、他の一端部 では各回転軸が平行であり、該搬送手段を挟めるように 2つの無端状ベルトの一面 が相対して配置されており、後部折り畳み手段は、該 1対の無端状ベルトの一端部で ある入側と他の一端部である出側が 90° ずれ、且つ、一端部と、他の一端部では各 回転軸が平行であり、該搬送手段を挟めるように 2つの無端状ベルトの一面が一端 部と他の一端部との間にお 、て相対するように配置されて 、ることが好ま 、。 The heating element folding device of the present invention is a device that folds the folded portion of the heating element that is transported while being stacked on the surface of the conveying means by the folding support means and the folding guide means. Thus, by folding the transporting means by the folding support means and the folding guide means, the heating element stacked on the transporting means is folded, and the TD direction axis of the transporting means has the same function before and after folding. The conveying means is a packaging material, and the guiding means and the supporting means are composed of two pairs of endless belts consisting of a front folding means and a rear folding means, and the front folding means is the pair of endless belts. The inlet side, which is one end of the endless belt, is shifted by 90 ° from the outlet, which is the other end, and the rotation axis is the same at one end, and the rotation axes are parallel at the other end. One end face of the two endless belts are disposed so as to sandwich the means, and the rear folding means is configured such that the input side which is one end of the pair of endless belts and the output side which is the other end are 90 °. ° Deviation and one end and the other end Then, it is preferable that the rotation shafts are parallel and that one surface of the two endless belts is disposed so as to face each other so as to sandwich the conveying means. ,.
また、折り畳み装置は、前記無端状ベルトの搬送面と発熱体との間に包装シートが 存在し、発熱体を包みながら発熱体を入り畳むように包装シート供給装置が設けられ たことが好ましい。  In the folding device, it is preferable that a packaging sheet exists between the conveying surface of the endless belt and the heating element, and the packaging sheet supply device is provided so as to fold and fold the heating element while wrapping the heating element.
また、折り畳み装置は、前記発熱体が発熱組成物を含有する、 3個以上複数の区 分発熱部が発熱組成物を含有しない区分け部を間隔として、間隔をお!、て設けられ た発熱体であることが好ま 、。  In addition, the folding device includes a heating element provided with an interval, with the heating element containing a heating composition, and a plurality of three or more divided heating parts being separated from each other by a section not containing the heating composition. Preferred to be.
また、折り畳み装置は、前記折り畳み案内板及び折り畳み案内台から選ばれた少 なくとも 1種に、発熱体が折り畳まれる経路に沿って磁石を設けたことが好ましい。 発明の効果  Moreover, it is preferable that the folding device is provided with a magnet along a path along which the heating element is folded, at least one selected from the folding guide plate and the folding guide base. The invention's effect
以上のようにこの発明によれば、  As described above, according to the present invention,
1.これまで手作業で行っていた折り畳みを自動的に行うことができるため、極めて 簡単で且つ効率的に、折り畳まれた発熱体や折り畳まれて非通気性の収納体である 外袋の封入された発熱体を製造することができる。  1. Folding that has been done manually can be done automatically, so it is extremely easy and efficient to enclose an outer bag that is a folded heating element or folded and non-breathable container. The produced heating element can be manufactured.
2.折り畳み案内台を設けることにより、複数の区分発熱部を有する柔軟性の高い 発熱体も連続的に、円滑に、容易に折り畳み作業ができ、作業性を向上し作業効率 を高め、極めて簡単で且つ効率的に、折り畳まれた発熱体や折り畳まれて非通気性 の収納袋である外袋に封入された発熱体を製造することができる。 3.折り畳まれる発熱体の搬送に合わせて発熱体を自動供給する自動供給装置を 設ければ、単独に作成された少量の発熱体の折り畳み作業も部分自動化を図ること ができ、作業'性をより一層高めることができる。 2. By providing a folding guide stand, a flexible heating element with multiple section heating parts can be folded continuously, smoothly and easily, improving workability and improving work efficiency, making it extremely easy In addition, it is possible to efficiently produce a folded heating element or a heating element enclosed in an outer bag which is a folded and non-breathable storage bag. 3. By providing an automatic supply device that automatically supplies heating elements in accordance with the conveyance of the heating elements to be folded, it is possible to partially automate the folding work of a small amount of heating elements that are created independently. It can be further increased.
4.発熱体折りたたみ装置の無端状ベルトの幅を、発熱体の中央部分の幅としたの で、発熱体の両側折り畳み部を掬い上げて折りたたむ折り畳み案内板は、このベルト に接触せず摩擦熱が発生しな ヽ。  4.Because the width of the endless belt of the heating element folding device is the width of the central part of the heating element, the folding guide plate that folds up by folding up the folding parts on both sides of the heating element does not come into contact with this belt and generates frictional heat. Will not occur.
5.ガスノズルにより折り畳み案内板の先端部と無端状ベルトとの間にガスを吹きつ けると、噴出したガスが無端状ベルトと発熱体の片側又は両側の折り畳み部との間に 入り込み、発熱体の折り畳む部分を押し上げるので、発熱体の片側又は両側折り畳 み部の掬い上げが更に円滑になる。  5.When gas is blown between the end of the folding guide plate and the endless belt by the gas nozzle, the ejected gas enters between the endless belt and the folding part on one or both sides of the heating element, and the heating element Since the folding part of the heating element is pushed up, the folding of the folding part on one side or both sides of the heating element becomes even smoother.
6.外仮着用の粘着剤を設けるための粘着剤設置装置を備えているために、、 6.Because it has an adhesive installation device for installing an adhesive for temporary wearing outside,
2個以上複数の区分発熱部を区分け部を介して設けた発熱体及び包装シート (非 通気性包装材等)から選ばれた少なくとも一種の一部に外仮着用の粘着剤を設ける ことができ、発熱体を非通気性包装材とともに折り畳む時に、発熱体と非通気性包装 材との間のズレが生ずることがなぐ的確に折り畳めることができ、収率の向上と生産 速度の向上ができる。 At least one part selected from a heating element and a packaging sheet (such as a non-breathable packaging material) provided with two or more divided heating parts via the dividing part can be provided with an adhesive for temporary wearing. When the heating element is folded together with the non-breathable packaging material, the heating element and the non-breathable packaging material can be folded accurately without causing a deviation, and the yield and production speed can be improved.
7.少なくとも前記発熱体及び及び Z又は包装材と接触する表面の材質を摺動性 の優れた素材を採用しているので、摩擦が減り、発熱体の折り畳み作業が更に円滑 になる。  7. At least the heating element and the surface material in contact with Z or the packaging material are made of material with excellent slidability, so friction is reduced and the heating element can be folded more smoothly.
図面の簡単な説明 Brief Description of Drawings
[図 1]本発明の発熱体折り畳み装置の一例を示し、(a)は斜視図、(b)は平面図、 (c) は側面断面図である。 FIG. 1 shows an example of a heating element folding device of the present invention, in which (a) is a perspective view, (b) is a plan view, and (c) is a side sectional view.
[図 2]本発明の発熱体折り畳み装置の他の一例を示し、(a)は平面図、(b)は側面断 面図である。  FIG. 2 shows another example of the heating element folding device according to the present invention, where (a) is a plan view and (b) is a side sectional view.
[図 3]本発明の発熱体折り畳み装置の他の一例を示し、(a)は平面図、(b)は側面断 面図である。  FIG. 3 shows another example of the heating element folding device of the present invention, where (a) is a plan view and (b) is a side sectional view.
[図 4]本発明の発熱体折り畳み装置の他の一例を示す側面断面図である。  FIG. 4 is a side sectional view showing another example of the heating element folding device according to the present invention.
[図 5]本発明の発熱体折り畳み装置の他の一例を示し、(a)は平面図、(b)は側面断 面図、である。 FIG. 5 shows another example of the heating element folding device according to the present invention, where (a) is a plan view and (b) is a side cross-sectional view. FIG.
圆 6]本発明の発熱体折り畳み装置の他の一例を示し、(a)は平面図、(b)は側面断 面図、である。 6] Another example of the heating element folding device of the present invention is shown, (a) is a plan view, and (b) is a side sectional view.
圆 7]本発明の発熱体折り畳み装置の他の一例を示し、(a)、(b)は斜視図、(c)は正 面断面図である。 [7] Another example of the heating element folding device of the present invention is shown, (a) and (b) are perspective views, and (c) are front sectional views.
圆 8]本発明の発熱体折り畳み装置の他の一例を示し、(a)は平面図、(b)は折り畳 み案内台の斜視図、(c)は折り畳み案内台の斜視図である。 8] Another example of the heating element folding device of the present invention is shown, (a) is a plan view, (b) is a perspective view of the folding guide base, and (c) is a perspective view of the folding guide base.
圆 9] (a)〜 (j)本発明の発熱体折り畳み装置の折り畳みの一例を示す、正面断面図 である。 9] (a) to (j) Front sectional views showing an example of folding of the heating element folding device of the present invention.
圆 10]本発明の発熱体折り畳み装置の他の一例を示し、(a)は斜視図、(b)は折り畳 み案内台の斜視図、(c)は折り畳み案内台の側面図、(d)は折り畳み案内台の平面 図である。 圆 10] Another example of the heating element folding device of the present invention is shown, (a) is a perspective view, (b) is a perspective view of a folding guide base, (c) is a side view of the folding guide base, (d ) Is a plan view of the folding guide stand.
[図 11] (a)、(b)本発明の発熱体折り畳み装置の自動充填装置の一例を示す断面図 である。  FIGS. 11A and 11B are cross-sectional views showing an example of an automatic filling device of the heating element folding device of the present invention.
[図 12]本発明の発熱体折り畳み装置の折り畳みの一例を示し、(a)、(e)、(h)は平 面図、(b)、 (d)、 (f)、(g)は説明断面図である。  FIG. 12 shows an example of folding of the heating element folding device of the present invention, (a), (e), (h) are plan views, (b), (d), (f), (g) are It is explanatory sectional drawing.
圆 13]本発明の発熱体折り畳み装置の他の一例を示す斜視図である。 [13] FIG. 13 is a perspective view showing another example of the heating element folding device according to the present invention.
[図 14]本発明の発熱体折り畳み装置の他の一例を示す斜視図である。  FIG. 14 is a perspective view showing another example of the heating element folding device according to the present invention.
[図 15]本発明の発熱体折り畳み装置の他の一例を示す平面図である。  FIG. 15 is a plan view showing another example of the heating element folding device according to the present invention.
圆 16]本発明の発熱体折り畳み装置の他の一例を示し、(a)、(b)は斜視図、(c)は 正面断面図、(d)は正面断面図である。 16] Another example of the heating element folding device of the present invention is shown, (a) and (b) are perspective views, (c) is a front sectional view, and (d) is a front sectional view.
[図 17]本発明の発熱体折り畳み装置の枠組押さえロール他の一例を示し、 (a)は斜 視図、(b)は側面断面図、(c)は平面図、(d)〜(h)は側面断面図、(i)は押さえ板( 摺動性面を有す)の側面図である。  FIG. 17 shows another example of a frame holding roll of the heating element folding device of the present invention, (a) is a perspective view, (b) is a side sectional view, (c) is a plan view, and (d) to (h) ) Is a side cross-sectional view, and (i) is a side view of a pressing plate (having a sliding surface).
[図 18] (a)〜 (c)本発明の外袋折り畳み装置の他の一例を示す斜視図である。 圆 19]本実施の形態の非通気性収納袋である外袋に封入された折り畳み発熱体の 製造工程を説明するための側面断面図である。  FIGS. 18A to 18C are perspective views showing another example of the outer bag folding device of the present invention. FIG. 19 is a side cross-sectional view for explaining a manufacturing process of a folded heating element enclosed in an outer bag which is a non-breathable storage bag of the present embodiment.
[図 20]本発明の発熱体を示し、(a)、(d)、(e)、(i)、(j)は平面図、(b)、(c)、(f)、 ( g)、 (h)は断面図である。 FIG. 20 shows a heating element of the present invention, (a), (d), (e), (i), (j) are plan views, (b), (c), (f), ( g) and (h) are cross-sectional views.
[図 21]本発明の発熱体の変形例を示す平面図である。 符号の説明  FIG. 21 is a plan view showing a modification of the heating element of the present invention. Explanation of symbols
1 折り畳み装置  1 Folding device
2 折り畳み案内板  2 Folding guide plate
3 折り畳み案内台  3 Folding guide
4 折り畳み案内台  4 Folding guide
7 押さえ板 (摺動性面)  7 Holding plate (sliding surface)
8 枠組み押さえロール板  8 Framework holding roll plate
9 枠  9 frame
9A 隙間塞ぎ板  9A gap closing plate
10 回転自在ロール又は回転自在ボール  10 Rotating roll or ball
11 ローノレ  11 Ronore
11A 押さえロール  11A presser roll
12 無端状ベルト  12 Endless belt
13 押し出し手段  13 Extrusion means
20 収納部  20 compartment
21 自動供給装置  21 Automatic feeder
22 押し出し凸部又は押し出し磁石  22 Extrusion convex or magnet
23 底板  23 Bottom plate
24 折り畳み無端状ベルト  24 Folding endless belt
25 支持板  25 Support plate
26 外袋に封入された発熱体発熱体製造装置 26 Heating element heating device manufacturing device enclosed in outer bag
27 発熱体製造装置 27 Heating element manufacturing equipment
28 発熱組成物成形体製造装置  28 Exothermic composition molding production equipment
29 整列間隔変更装置  29 Alignment interval changing device
30 折り畳み装置  30 folding device
31 シール装置 カット装置(カットロール等) 発熱体 31 Sealing device Cutting device (cut roll, etc.)
外袋に封入された発熱体 発熱組成物 Heating element enclosed in outer bag Heating composition
発熱組成物成形体 発熱部 Exothermic composition molded body
区分発熱部 Heating section
被覆材 Coating material
基材 Base material
包装材 Packaging material
シーノレ部 Scenery club
粘着剤層 Adhesive layer
通気性粘着剤層 Breathable adhesive layer
セパレータ Separator
折り畳み部 Folding part
2つに折り畳まれた発熱体 Heating element folded in two
3つに折り畳まれた発熱体 外袋 Heating element folded in three Outer bag
磁石 Magnet
ガスノズル Gas nozzle
押圧手段 Pressing means
スリットカットローノレ 枠糸且みローノレ、枠糸且みボーノレ 外袋折り畳み装置。 Slit-cut ronole Frame thread crease ronole, frame thread crease bonole Outer bag folding device.
外袋折り畳み台 Outer bag folding stand
区分け部 Division
粘着剤設置装置 Adhesive installation device
外仮着 発明を実施するための最良の形態 Temporary clothes BEST MODE FOR CARRYING OUT THE INVENTION
本発明の発熱体折り畳み装置は、各種搬送手段、各種折り畳み支持手段、各種折 り畳み案内手段は、それぞれ、重複を含めて、任意の組み合わせができる。  In the heating element folding apparatus of the present invention, various conveying means, various folding support means, and various folding guide means can be combined in any combination including overlapping.
前記折り畳み案内手段は、掬い案内、はね上げ案内、内寄せ案内及び折込み案 内から構成される機能を有しており、一つの手段が全機能を有していてもよいし、複 数の手段を組み合わせて全機能を有してもょ 、。  The folding guide means has a function composed of scooping guide, flip-up guide, inward guide and folding plan, and one means may have all functions or a plurality of means. Combine and have all the functions.
例えば、折り畳み案内板や折り畳み案内バーは一つの手段の中に、掬い案内部、 はね上げ案内部、内寄せ案内部及び折込み案内部を連続的に設けたものである。 また、面状物で折り畳みを行う折り畳み案内板、線状物又は帯状物で折り畳みを行 う折り畳み案内バーのように機能を残して、物理的に変形してもよいし、折り畳み案内 板や折り畳み案内バーに磁石を設けてもよい。  For example, a folding guide plate and a folding guide bar are formed by continuously providing a scooping guide portion, a flip-up guide portion, an inward guide portion, and a folding guide portion in one means. Also, it may be physically deformed, leaving a function, such as a folding guide plate that folds with a planar object, a folding guide bar that folds with a linear object or a belt-like object, or a folding guide plate or folding A magnet may be provided on the guide bar.
折り畳み案内板や折り畳み案内バーの発熱体本体の折り畳まれる進行路に沿って 磁石を設けることが好ましい。磁石は折り畳み案内板や折り畳み案内バーの発熱体 本体と接触しない側でも、接触しない側と接触する側の間でも、発熱体本体の折り畳 みに支障がなければ任意の領域に設けてよい。折り畳み案板やバーを中空西その 内側、又は内壁に設けてよい。又発熱体本体と接触する側に設ける場合は、前記面 に埋め込むことが好ましい。  It is preferable to provide a magnet along the traveling path of the folding guide plate or the folding guide bar where the heating element body is folded. The magnet may be provided in an arbitrary region as long as it does not interfere with the folding of the heating element body, either on the side of the folding guide plate or the folding guide bar that does not contact the heating element body or between the side that does not contact the heating guide body. Folding planks and bars may be provided inside the hollow west or on the inner wall. Further, when it is provided on the side in contact with the heating element body, it is preferably embedded in the surface.
折り畳み支持手段である磁石は、磁力を有するものであればよぐ電磁石や永久磁 石が一例として挙げられる。  Examples of the magnet that is the folding support means include an electromagnet and a permanent magnet as long as they have a magnetic force.
また、搬送手段である無端状ベルトと折り畳み支持手段である磁石を組み合わせる 場合、磁石は発熱体と接触する面と反対側の他面側設けることが好ま ヽ。  In addition, when combining an endless belt as a conveying means and a magnet as a folding support means, it is preferable to provide the magnet on the other side opposite to the side in contact with the heating element.
設置の方法は制限はなぐ前記他面に接触せず固定されたもの、回転自在に固定 されたもの、無端状ベルトに取り付けられ、無端状ベルトと共に移動するもの等が一 例として挙げられる。  Examples of installation methods include those that are fixed without contact with the other surface, those that are fixed rotatably, those that are attached to an endless belt, and move with the endless belt.
発熱体が包装材に積層されて、折り畳まれる場合は、発熱体の露出部の少なくとも 一部が包装材に弱粘着剤等により仮着されて!、てもよし、仮着されて 、なくてもょ 、。 ここで仮着とは、移動の時や折り畳む時に、発熱体が移動しないように、一時的に 発熱体を包装材に留めておくためのものである。 仮着を場合は、発熱体及び z又は包装材に粘着剤等からなる仮着層を設けるため の塗布装置を設ける。セパレータを有する発熱体の場合は、セパレータも発熱体の 一部として扱う。 When the heating element is laminated on the packaging material and folded, at least a part of the exposed part of the heating element is temporarily attached to the packaging material with a weak adhesive or the like! Well ... Here, temporary attachment is for temporarily holding the heating element on the packaging material so that the heating element does not move during movement or folding. In the case of temporary attachment, a coating device for providing a temporary attachment layer made of an adhesive or the like on the heating element and z or the packaging material is provided. In the case of a heating element having a separator, the separator is also treated as a part of the heating element.
[0012] 本発明の発熱体は折り畳み可能であれば制限はないが、 2個以上の区分発熱部と 1個以上の区分け部を有する発熱体が好ましい。さらに、  [0012] The heating element of the present invention is not limited as long as it can be folded, but a heating element having two or more section heating sections and one or more section sections is preferable. In addition,
1)区分分発熱部以外の領域の少なくとも一部に、切り込みを設けた発熱体が好ま しい。  1) A heating element in which a cut is provided in at least a part of the area other than the segment heating part is preferable.
2)発熱体の所定の区分け部で折り畳まれて、気密性収納袋である外袋に封入され された発熱体が好ましい。  2) A heating element folded at a predetermined section of the heating element and enclosed in an outer bag which is an airtight storage bag is preferable.
3)発熱体の露出部の少なくとも一部が気密性収納袋である外袋の少なくとも一部と 仮着されて ヽる発熱体が好ま ヽ。  3) A heating element is preferred in which at least a part of the exposed part of the heating element is temporarily attached to at least a part of the outer bag which is an airtight storage bag.
4)発熱体の露出部の少なくとも一部が気密性収納袋である外袋の少なくとも一部と 仮着され、該仮着が、 180度ピール強度 (JIS Z— 0287)力 . 001-0. 9kg/25 mmの範囲での仮着である発熱体が好まし 、。  4) At least a part of the exposed part of the heating element is temporarily attached to at least a part of the outer bag which is an airtight storage bag, and the temporary attachment is 180 degree peel strength (JIS Z-0287) force. Heating elements that are temporary in the range of 9kg / 25mm are preferred.
[0013] 本発明における切り込みとは、貫通した切り込みであり、切り込み及び切り込みの 間隔である繋ぎ部力も構成され、形状、種類やサイズ (長さや幅等)や各間隔の形状 、種類やサイズ (長さや幅等)サイズ (長さや幅等)やそれらの組み合わせは、制限は なぐ任意の組み合わせや任意の繰り返し組み合わせをすることができる。繋ぎ部は 、切り込みよりも短いことが好ましい。  [0013] The incision in the present invention is a through notch, and includes a connecting portion force that is an interval between the incision and the incision. The shape, type, and size (length, width, etc.) and the shape, type, and size of each interval ( Length, width, etc.) The size (length, width, etc.) and their combinations can be any combination with no restrictions or any repeated combination. The connecting portion is preferably shorter than the cut.
前記切り込みの形状は制限な 、。  The shape of the notch is not limited.
[0014] 切り込みの少なくとも一つの端部は発熱体の少なくとも一つの辺と接触していてもよ いし、接触していなくてもよい。 [0014] At least one end of the cut may or may not be in contact with at least one side of the heating element.
少なくとも一つの区分け部の延長方向と発熱体の少なくとも一つの辺との接点に V ノッチを設けてもよい。  A V-notch may be provided at the contact point between the extending direction of at least one section and at least one side of the heating element.
また、切り込みの少なくとも一つの端部は発熱体の少なくとも一つの辺付近に設け られたノッチと接触して 、てもよ 、し、接触して 、なくてもょ 、。  Also, at least one end of the cut may or may not be in contact with a notch provided near at least one side of the heating element.
また、切り込みの種類 (形状、配置等)としては、制限はないが、互い違い切り込み 、ミシン目(手切れ可能なミシン目等)、 Vノッチ付き切り込み、 Vノッチ付き互 ヽ違 ヽ 切り込み、 Vノッチ付きミシン目(Vノッチ付き手切れ可能なミシン目等)、各種形状の 切り込み等が一例として挙げられる。 In addition, there are no restrictions on the type of cut (shape, arrangement, etc.), but alternate cuts, perforations (perforated perforations, etc.), V-notched cuts, and V-notched cuts. Examples include notches, perforations with V-notches (perforated perforations with V-notches, etc.), and various shapes of incisions.
好ましくは、本発明における切り込みとは、互い違い切り込み、 Vノッチ付き互い違 V、切り込み、 Vノッチ付きミシン目(Vノッチ付き手切れ可能なミシン目等)、 Vノッチ付 き切り込みであり、発熱体の区分発熱以外の領域に、好ましくは前記区分け部の任 意の箇所に、任意の数で設けてもよい。  Preferably, the notches in the present invention are alternate notches, alternate notches with V notches, V notches, perforations with V notches (such as perforated perforations with V notches), notches with V notches, and heating elements. Any number may be provided in a region other than the divided heat generation, preferably at an arbitrary position of the dividing portion.
また、好ましくは、前記隣接する区分発熱部間のシール部である区分け部の中間 に、区分け部の一辺からそれに対応する他辺まで切り込みを形成し、この切り込みに より前記各区分発熱部間の伸縮 (伸長)を可能にした発熱体である。  Preferably, a notch is formed between one side of the partitioning part and the other side corresponding thereto in the middle of the partitioning part which is a seal part between the adjacent partitioning heat generating parts. A heating element that enables expansion and contraction.
また、好ましくは、前記隣接する区分発熱部間のシール部である区分け部の中間 に、区分け部の一辺からそれに対応する他辺まで切り込みを形成し、この切り込みに より前記各区分発熱部を分割 (分離)可能にした発熱体である。  Preferably, a notch is formed from one side of the segmented portion to the other side corresponding to the middle of the segmented portion which is a seal portion between the adjacent segmented heat generating portions, and each segmented heat generating portion is divided by this notch. It is a heating element that can be (separated).
また、前記 Vノッチを Uノッチ、 Iノッチ等の他のノッチに替えてもよい。  The V notch may be replaced with another notch such as a U notch or an I notch.
[0015] 本発明の発熱体における切り込みの設置場所、数としては、区分発熱部以外の任 意の領域に、任意の数で設けることができるが、設置領域としては、区分け部が好ま しい。 [0015] As the installation location and number of the cuts in the heating element of the present invention, an arbitrary number other than the divided heat generating portion can be provided. However, as the installation region, the divided portion is preferable.
また、セパレータを有する発熱体に設けられた切り込みは、セパレータを貫通する 切り込みでもよ 、し、セパレータを貫通しな 、切り込みでもよ!/、。  In addition, the notch provided in the heating element having the separator may be a notch that penetrates the separator, or may not be penetrated through the separator! /.
[0016] 本発明の互い違い切り込みは、切り込み (又は切り込み部)と非切り込みである繋ぎ  [0016] The staggered cut of the present invention is a joint that is not cut (or cut) and non-cut.
(又は繋ぎ部)とからなり、独立した 1組の 2列以上複数力もな切り込みの中で、少なく とも切り込み部と繋ぎ部との配置周期が異なる 1組の切り込みがあり、少なくとも 1方 向に引っ張ると切り込みが変形し、引っ張り方向の少なくとも 1部が引っ張り方向に伸 長する及び Z又は伸縮することのできる方向を 1個以上有する切り込みの集団であ れば制限はないが、好ましくは複数の切り込みが間隔を置いて配置され、一方向に 対して隣接の切り込みの配置周期が異なるように配置されており、 2列を 1組にした互 Vヽ違 、切り込みや 3列を 1組にした互 、違 、切り込みや 4列を一組にした互 、違 、切 り込みや 5列を一組にした互 ヽ違 、切り込みが一例として挙げられる。  There are at least one set of cuts in which the arrangement period of the cut portion and the connecting portion is different, at least in one direction. There is no limitation as long as it is a group of notches that have one or more directions that at least one part of the pulling direction extends in the pulling direction and can be stretched in the pulling direction or stretched, but preferably a plurality of cuts. The cuts are arranged at intervals and arranged so that the arrangement cycle of adjacent cuts is different in one direction, and the two rows are combined into one pair, the V difference, the cut and three rows are combined into one set Examples are mutual, different, incision, mutuality, incision, and inconsistency, incision, 5th row, and incision.
好ま 、互 、違 、切り込みの一例としては、下記が挙げられる。 1.複数の切り込みが、千鳥足状に配置されている。 Examples of preferred, different, and incisions include the following. 1. A plurality of cuts are arranged in a staggered pattern.
2.複数の切り込みが、切り込みの一方向(長手方向等)が互 、違いに異なる(直角 等)方向に配置されている。  2. A plurality of cuts are arranged in different directions (eg, right angles) in one direction of cut (longitudinal direction, etc.).
3.切り込み方向にお!、て切り込みと切り込みとの間に存在する非切り込みお!/ヽて、 切り込み方向でな 、3個の最隣接の非切り込みの中心点を結ぶ軌跡が非直線 (折れ 線等)である、又は切り込み方向と 90° でない角度を有する直線であることを満足す る、 3個の最隣接の非切り込みを有する複数の切り込み。  3.In the incision direction !, the non-incision between the incision and the incision! / Turn, the trajectory connecting the three nearest non-incision center points in the incision direction is non-linear (bending A plurality of incisions with three nearest non-incisions satisfying a straight line having an angle that is not 90 ° with respect to the incision direction.
4.切り込みの形状として、直線状や楕円状や長方形状等が一例として挙げられる。 また、切り込みのある領域を切り込み部と称する。線状満とは、貫通せず、圧縮部 分や肉薄部分を称する。  4. Examples of the shape of the cut include a straight line, an ellipse, and a rectangle. A region with a cut is called a cut portion. “Linear full” refers to a compressed portion or a thin portion that does not penetrate.
5.互い違い切り込みの少なくとも一つの端部は発熱体の少なくとも一つの辺と接触 していてもよいし、接触していなくてもよい。  5. At least one end of the staggered cut may or may not be in contact with at least one side of the heating element.
6.切り込みや隣接する切り込みとの間隔において、各切り込みの形状、種類やサイ ズ (長さや幅等)や各間隔の形状、種類やサイズ (長さや幅等)やそれらの組み合わ せは、制限はなぐ任意の組み合わせや任意の繰り返し組み合わせをすることができ る。  6.In the notch and the distance between adjacent notches, the shape, type and size (length, width, etc.) of each notch, the shape, type, size (length, width, etc.) of each interval, and combinations thereof are limited. Arbitrary combinations and arbitrary repetition combinations can be made.
[0017] 前記互い違い切り込みは引き延ばされた場合、互い違いに配設した厚さ方向に貫 通する複数の切り込みの形状が変形することにより、伸長及び Z又は伸縮することが できる。  [0017] When the staggered cuts are stretched, the shapes of the plurality of cuts penetrating in the thickness direction that are alternately arranged are deformed, so that the staggered cuts can be stretched and Z or stretched.
前記互 、違 、の切り込みは伸縮させた 、方向と略直交する方向に設けることが好 ましい。切り込みの数、切り込みの列の数等は適宜選択して使用できる。  It is preferable that the notches of the above and the other are provided in a direction substantially perpendicular to the direction expanded and contracted. The number of cuts, the number of rows of cuts, and the like can be appropriately selected and used.
前記互い違いの切り込みを延伸した後の形状に制限はなぐまた、この互い違いの 切り込みを延伸した後の網目形状の寸法は制限はない。  There are no restrictions on the shape after stretching the alternate cuts, and there is no restriction on the dimensions of the mesh shape after stretching the alternate cuts.
[0018] ここで、互い違いに配設するとは、非伸長性材料や非伸縮性材料等の包材でも、 伸長及び Z又は伸縮ができるように、切り込みが網目状等に変形できるように、配設 することを意味し、即ち、どこかで重なりのある互い違いの配置であり、ひも等を綱加 ェしたネットと異なり、接合部分が一体であり、一定の切り込み部長さだけ拡閲しつつ 網目を形成することができる。 [0019] 前記互!、違いに配設した厚さ方向に貫通する複数の切り込み部を形成する場合、 一例として、線状切りこみを例に取ると、一例として JIS— A5505等のメタルラスカロェ に記載されている。この切り込みによって、その長手方向に対して垂直方向に伸縮が 可能となり、形状を自在に変えることが可能な網目状の形状とすることができる。 [0018] Here, staggered arrangement means that the notches can be deformed into a mesh shape or the like so that the packaging material such as a non-stretchable material or a non-stretchable material can be stretched and Z or stretched. In other words, it is a staggered arrangement that overlaps somewhere, and unlike a net that has been laced, the joint is integral and the mesh is expanded while only a certain length of cut is inspected. Can be formed. [0019] In the case of forming a plurality of incisions that penetrate in the thickness direction, which are arranged differently, as an example, taking a linear notch as an example, a metal lascaro such as JIS-A5505 can be used as an example. Are listed. By this cutting, it is possible to expand and contract in the direction perpendicular to the longitudinal direction, and it is possible to obtain a mesh shape whose shape can be freely changed.
[0020] 前記切り込みの寸法は、長さ、最長径又は最長辺は制限はないが、好ましくは 1〜 100mmであり、より好ましくは l〜50mmであり、更に好ましくは 1. 5〜50mmであり 、更に好ましくは 2〜30mmであり、更に好ましくは 5〜20mmである。  [0020] The length, longest diameter or longest side of the notch is not limited, but is preferably 1 to 100 mm, more preferably 1 to 50 mm, and even more preferably 1.5 to 50 mm. More preferably, it is 2-30 mm, More preferably, it is 5-20 mm.
幅又は最短径又は最短辺は制限はないが、好ましくは 0を超えて 50mmであり、よ り好ましく ίま 0. 01〜50mmであり、更【こ好ましく ίま 0. 01〜30mmであり、更【こ好まし く ίま 0. 01〜20mmであり、更に好ましく ίま 0. l〜20mmであり、更に好ましく ίま 0. 1 〜10mmであり、更に好ましくは 0. l〜5mmである。尚、線状の切り込みの幅の最 小値は制限はなぐ切れていればよい。最大値は前記 50mm以下であり、より好まし くは前記記載の通りである。  The width, the shortest diameter, or the shortest side is not limited, but is preferably more than 0 to 50 mm, more preferably ί to 0.01 to 50 mm, and more preferably ί to 0.01 to 30 mm. More preferably, it is 0.1 to 20 mm, more preferably 0.1 to 20 mm, more preferably 0.1 to 10 mm, and more preferably 0.1 to 5 mm. . It should be noted that the minimum value of the width of the linear notch is not limited. The maximum value is 50 mm or less, more preferably as described above.
切り込みの延長方向の隣接する切り込みの間隔である、繋ぎ部の長さは制限はな いが、好ましくは 0. 01〜20mmであり、より好ましくは 0. 01〜: LOmmであり、更に好 ましくは 0. 1〜: LOmmであり、更に好ましくは 0. l〜8mmであり、更に好ましくは 0. 1 〜 7mmである。更に好ましくは 0. 1〜 5mmである。  The length of the connecting portion, which is the interval between adjacent cuts in the extension direction of the cut, is not limited, but is preferably 0.01 to 20 mm, more preferably 0.01 to: LOmm, and even more preferable. Or 0.1 to LOmm, more preferably 0.1 to 8 mm, and still more preferably 0.1 to 7 mm. More preferably, it is 0.1-5 mm.
切り込みの延長方向と直交する方向の隣接する切り込みの間隔である、隣接間隔 は制限はないが、好ましくは 0. l〜20mmであり、より好ましくは 0. l〜15mmであり 、更に好ましくは 0. l〜10mmであり、更に好ましくは 0. l〜5mmであり、更に好ま しくは 0. 5〜5mmである。  The distance between adjacent cuts in the direction perpendicular to the cut extension direction is not limited, but is preferably 0.1 to 20 mm, more preferably 0.1 to 15 mm, and still more preferably 0. l to 10 mm, more preferably 0.1 to 5 mm, and even more preferably 0.5 to 5 mm.
[0021] 本発明の発熱体は、区分発熱部以外の任意の領域に、任意の数の互い違いの切 り込みを設けた伸長性及び Z又は伸縮性のある発熱体でもある。  [0021] The heating element of the present invention is also an extensibility and Z or stretchable heating element in which an arbitrary number of alternating cuts are provided in an arbitrary region other than the section heating unit.
[0022] 本発明の互い違い切り込み付き発熱体は、区分発熱部以外の少なくとも 1部に互 V、違 、切り込みを設けた発熱体である。  The heating element with staggered cuts according to the present invention is a heating element in which at least one part other than the divided heat generating part is provided with a V and a different cut.
互 ヽ違 、切り込みによりもたらされる発熱体の伸長性は、互 、違 、切り込みの延長 方向に対して少なくとも略直交方向に伸長することが好ましぐ少なくとの発熱体の一 部がその方向に伸長すればょ 、。 その伸長率は、 1を越えていれば、制限はないが、用途にもよるが、好ましくは 1. 0 05〜10であり、より好ましくは 1. 01〜10であり、更に好ましくは 1. 01〜5であり、更 に好ましくは 1. 01〜5であり、更に好ましくは 1. 01〜3であり、更に好ましくは 1. 01 〜2であり、更に好ましくは 1. 02〜2であり、更に好ましくは 1. 03〜2であり、更に好 ましくは 1. 04〜2であり、更に好ましくは 1. 05〜2である。 The extensibility of the heating elements caused by the difference and the incision is different from each other, and at least a part of the exothermic elements preferably extend in the direction at least approximately perpendicular to the extending direction of the notch. If it stretches, The elongation ratio is not limited as long as it exceeds 1, but it is preferably 1.05 to 10, more preferably 1.01 to 10, even more preferably 1. 01 to 5, more preferably 1.01 to 5, more preferably 1.01 to 3, more preferably 1.01 to 2, and even more preferably 1.02 to 2. More preferably, it is 1.03 to 2, more preferably 1.04 to 2, and still more preferably 1.05 to 2.
10を超えると、網目の開口部が大きくなりすぎ、引張強度が低下する畏れがある。 互い違い切り込みは、通常、伸長性と伸縮性を付与する機能を有している。  If it exceeds 10, the opening of the mesh becomes too large, and the tensile strength may decrease. The alternate cut usually has a function of imparting extensibility and stretchability.
また、本発明の伸長性又は伸縮性の発熱体の引っ張り強度の制限はないが、好ま しい一例としては、 3N/50mm以上である。  Further, there is no limitation on the tensile strength of the stretchable or stretchable heating element of the present invention, but a preferable example is 3N / 50 mm or more.
前記手切れ可能なミシン目としては、貫通した切り込みであり、手切れができれば 制限はなぐ切り込みと隣接した切り込みとの間隔において、任意のサイズや任意の 組み合わせや任意の繰り返し組み合わせができる力 下記が一例として挙げられる。 As the perforated perforation, there is a through-cut, and if the hand can be cut, there is no limit, and there is a force that allows any size, any combination, and any repeated combination in the interval between adjacent cuts. As an example.
1)手切れ可能なミシン目力 円形状の貫通した切り込みの場合、その口径は、好ま しくは 10 μ ΐη φ〜: LOmm φであり、更に好ましくは 10 μ ΐη φ〜5mm φであり、更に 好ましくは 100 μ ΐη φ〜5mm φであり、更に好ましくは 500 μ ΐη φ〜0. 5mm φであ る。 1) Perforated perforation that can be cut by hand In the case of a circular through-cut, the diameter is preferably 10 μΐηφ ~: LOmmφ, more preferably 10 μΐηφ ~ 5mmφ, more preferably Is 100 μΐη φ to 5 mm φ, more preferably 500 μΐη φ to 0.5 mm φ.
又は円形状以外の貫通した切り込みの場合、貫通した切り込みの長さは、好ましく は 10 μ m〜200mmであり、より好ましくは 10 μ m〜50mmであり、更に好ましくは 1 0 μ m〜30mmであり、更【こ好ましく ίま 10 μ m〜20mmであり、更【こ好ましく ίま 100 πι〜20ππηであり、更【こ好ましく ίま 100 /z m〜: LOmmであり、更【こ好ましく ίま 0. 5m m〜 1 Ommであり、更に好ましくは 1 mn!〜 1 Ommである。  Alternatively, in the case of a through-cut that is not circular, the length of the through-cut is preferably 10 μm to 200 mm, more preferably 10 μm to 50 mm, and even more preferably 10 μm to 30 mm. Yes, more preferably ί 10 μm to 20 mm, more preferably ί 100 πι to 20ππη, more preferably ί 100 / zm ~: LOmm, more preferably ί 0.5 mm to 1 Omm, more preferably 1 mn! ~ 1 Omm.
2)貫通した切り込みと隣接した貫通した切り込みの間隔 (繋ぎ部)の長さは、制限な いが、好ましくは 1 μ m〜10mmであり、より好ましくは 1 μ m〜7mmであり、更に好ま しくは 1 /ζ πι〜5πιπιであり、更に好ましくは 0. lmn!〜 5mmであり、更に好ましくは 0 2) The length of the interval (joining part) between the adjacent cuts and the adjacent cuts is not limited, but is preferably 1 μm to 10 mm, more preferably 1 μm to 7 mm, even more preferable. 1 / ζ πι to 5πιπι, more preferably 0. lmn! ~ 5mm, more preferably 0
. lmm〜2mmで & lmm ~ 2mm &
3)貫通した切り込みの長さ (W1)と繋ぎ部の長さ (W2)との比 (W1ZW2)は好ましく は 1を越える、より好ましくは 1を越えて 50以下であり、更に好ましくは 1. 01〜50であ り、更に好ましくは 1. 1〜50であり、更に好ましくは 1. 5〜50であり、更に好ましくは 1. 5〜40であり、更に好ましくは 2〜30である。 3) The ratio (W1ZW2) between the length of the cut through (W1) and the length of the joint (W2) (W1ZW2) is preferably more than 1, more preferably more than 1 and not more than 50, and still more preferably 1. 01 to 50, more preferably 1.1 to 50, more preferably 1.5 to 50, and still more preferably 1. 5 to 40, more preferably 2 to 30.
4)ミシン目の少なくとも一つの端部は発熱体の少なくとも一つの辺と接触していても よいし、接触していなくてもよい。  4) At least one end of the perforation may or may not be in contact with at least one side of the heating element.
5)手切れかのなミシン目を 2列以上平行させて設けてもょ 、。  5) Make two or more rows of perforated perforations parallel.
6)手切れ可能なミシン目は、区分発熱部以外の領域に縦、横、縦横等に任意に所 定の間隔を有して併設されて ヽてもよ 、。  6) Perforated perforations that can be cut by hand may be provided in the area other than the section heating section with any given interval in the vertical, horizontal, vertical and horizontal directions.
[0024] また、発熱体の区分け部のミシン目とは、区分け部の曲げ性を向上させるために断 続的に切断されたものや、手切れが可能なほどに断続的に切断されたものがー例と して挙げられ、好ましい。シン目はすべての区分け部に設けてもよいし、部分的に設 けてもよい。  [0024] In addition, the perforation at the section of the heating element is one that has been cut intermittently to improve the bendability of the section, or one that has been cut intermittently to allow hand cutting As an example, it is preferable. The perforations may be provided in all the divisions or may be provided partially.
[0025] 発熱体は、非通気性収納袋である外袋の内面と仮着 (以下、外仮着という)されて いてもよい。発熱体が外袋の内面に仮着されている場合、発熱体が折り畳まれる前 に外袋内面に仮着されて ヽてもよ 、し、折り畳まれた後に外袋内面に仮着されて ヽ てもよい。  [0025] The heating element may be temporarily attached to the inner surface of the outer bag, which is a non-breathable storage bag (hereinafter referred to as outer temporary attachment). If the heating element is temporarily attached to the inner surface of the outer bag, it may be temporarily attached to the inner surface of the outer bag before the heating element is folded, or it may be temporarily attached to the inner surface of the outer bag after being folded. May be.
外仮着とは、発熱体と非通気性収納袋とが再剥離製弱粘着剤層を介して、少なくと も一部で接触していることである。これにより、少なくとも発熱体が折り畳まれるまで、 発熱体の外袋の包装材上の移動が防止できる。  Outer temporary attachment means that at least part of the heating element and the non-breathable storage bag are in contact with each other through the weakly peelable adhesive layer. Thereby, the movement of the outer bag of the heating element on the packaging material can be prevented at least until the heating element is folded.
本発明の発熱体は折り畳まれて非通気性収納袋である外袋に封入される。  The heating element of the present invention is folded and enclosed in an outer bag which is a non-breathable storage bag.
好ましくは、請求項 1乃至 9の何れかに記載の発熱体折り畳み装置力 選ばれた少 なくとも 1種により製造された、 2個以上の区分発熱部と 1個以上の区分け部を有す る発熱体が少なくとも 1個以上の区分け部を折り畳み部として 2つ以上複数のに折り 畳まれ、非通気性の収納袋に封入されている発熱体であり、請求項 1乃至 9の何れ かに記載の発熱体折り畳み装置力 選ばれた少なくとも 1種により製造された、 2個 以上の区分発熱部と 1個以上の区分け部を有する発熱体が少なくとも 1個以上の区 分け部を折り畳み部として 2つ以上複数のに折り畳まれ、発熱体の露出部の少なくと も一部は非通気性の収納袋の少なくとも一部に仮着され、非通気性の収納袋に封入 されている発熱体である。  Preferably, the heating element folding device force according to any one of claims 1 to 9 is produced by at least one kind selected, and has two or more divided heating parts and one or more dividing parts. The heating element according to any one of claims 1 to 9, wherein the heating element is a heating element that is folded into two or more by using at least one section as a folding part and enclosed in a non-breathable storage bag. The heating element folding device power of two heating elements that are manufactured by at least one selected type and have two or more section heating sections and one or more section sections, with at least one section as a folding section The heating element is folded into a plurality of parts, and at least a part of the exposed portion of the heating element is temporarily attached to at least a part of the non-breathable storage bag and sealed in the non-breathable storage bag.
[0026] 非通気性収納袋である外袋に使用するの包装材には、前記非通気性包材等が使 用でき、外袋のシール部の縁部及び Z又はシール部の中に(シール部の周縁端部 を含まない、シール部領域内に) 1個以上のノッチ (Iノッチ、 uノッチ、 Vノッチ等)を形 成し、使用者が外袋を容易に引き裂 、て開封できるようにすることが望ま 、。 [0026] As the packaging material used for the outer bag, which is a non-breathable storage bag, the non-breathable packaging material or the like is used. One or more notches (I-notch, u-notch, V-notch) in the edge of the seal part of the outer bag and in the Z or seal part (not including the peripheral edge of the seal part, in the seal part region) Etc.) so that the user can easily tear and open the outer bag.
[0027] 外仮着に使用される再剥離製弱粘着剤層を構成する粘着剤 (以下この粘着剤を「 外仮着型粘着剤」と称する)は、粘着力が弱ぐ折り畳み作業が終わるまで、発熱体 を包装材に保留させることができれば、制限はない。使用可能な再剥離性粘着剤の 一例を挙げるとすれば、弱粘着性接着剤が挙げられる。 [0027] The adhesive constituting the re-peeling weak adhesive layer used for external temporary attachment (hereinafter, this adhesive is referred to as "external temporary adhesive") ends the folding operation with weak adhesive strength. There is no limit as long as the heating element can be retained in the packaging material. An example of a removable adhesive that can be used is a weak adhesive.
具体的には、ホットメルト型粘着剤、ェマルジヨン系粘着剤、溶剤系粘着剤等がある 特に、ガラス転移温度を高くした配合のものが好ましぐアクリル系ではアクリル酸の 成分の比率を高くしたもの、ゴム系では高融点のタツキフアイヤーを配合したもの等 が好ましい。  Specifically, there are hot-melt adhesives, emulsion adhesives, solvent-based adhesives, etc. Especially, acrylics that have a high glass transition temperature are preferred, and the ratio of acrylic acid components is increased. In the case of rubbers, those containing a high melting point tack fire are preferred.
また、ポストイット ZPOSTIT (スリーェム社の商品名)として販売されている着脱型 の付箋紙に使用される粘着剤も使用できる。  In addition, the adhesive used for removable sticky notes sold as Post-it ZPOSTIT (trade name of 3EM) can also be used.
また、ホットメルト型粘着剤、特に、ホットメルト系粘着剤(ポリプロピレン系粘着剤、 ポリエチレン系粘着剤、エチレン プロピレン共重合体系粘着剤等)が好ましい。  Further, a hot melt adhesive, particularly a hot melt adhesive (polypropylene adhesive, polyethylene adhesive, ethylene propylene copolymer adhesive, etc.) is preferable.
[0028] ホットメルト型粘着剤としては、エラストマ一 (熱可塑性エラストマ一等)や熱可塑性 榭脂等をベースポリマーとしている。尚、ベースポリマーは、単独又は混合してもよい ホットメルト型粘着剤におけるベースポリマーの熱可塑性エラストマ一としては、例え ば、スチレン イソプレン スチレンブロック共重合体(SIS)、スチレン ブタジエン スチレンブロック共重合体(SBS)、スチレン エチレンーブチレン スチレンブロ ック共重合体(SEBS)、スチレン一エチレン一プロピレン一スチレンブロック共重合 体(SEPS)、スチレン エチレン プロピレンブロック共重合体(SEP)等のスチレン 系熱可塑性エラストマ一(スチレン系ブロックコポリマー;例えば、スチレン含有 5重量 %以上のスチレン系ブロックコポリマー);ポリウレタン系熱可塑性エラストマ一;ポリエ ステル系熱可塑性エラストマ一;ポリプロピレンと EPT (三元系エチレン プロピレン ゴム)とのポリマーブレンド等のブレンド系熱可塑性エラストマ一等を挙げることができ る。 [0028] As the hot-melt type pressure-sensitive adhesive, an elastomer (such as a thermoplastic elastomer) or a thermoplastic resin is used as a base polymer. The base polymer may be used alone or in combination. Examples of the thermoplastic elastomer of the base polymer in the hot melt adhesive include, for example, styrene isoprene styrene block copolymer (SIS), styrene butadiene styrene block copolymer. (SBS), styrene ethylene-butylene styrene block copolymer (SEBS), styrene-ethylene-propylene-styrene block copolymer (SEPS), styrene-ethylene-propylene block copolymer (SEP), etc. Elastomer (styrenic block copolymer; for example, styrene-containing block copolymer containing 5% by weight or more of styrene); polyurethane-based thermoplastic elastomer; polyester-based thermoplastic elastomer; polypropylene and EPT (ternary ethylene propylene rubber) Polymer Mention may be made of blends based thermoplastic elastomer Chief such trend The
[0029] また、ホットメルト型粘着剤におけるベースポリマーの熱可塑性榭脂としては、例え ば、ポリオレフイン系榭脂、酢酸ビニル系榭脂、ポリエステル系榭脂、スチレン系榭脂 、アクリル系榭脂、ポリアミド系榭脂等が挙げられる。尚、ポリオレフイン系榭脂として は、例えば、エチレン系共重合体 (例えば、エチレン 酢酸ビニル共重合体 (EVA) ;エチレン アクリル酸共重合体(EAA)、エチレンーメタクリル酸共重合体(EMAA )等のエチレン 不飽和カルボン酸共重合体;アイオノマー;エチレン アクリル酸 2 ェチルへキシル共重合体、エチレン メタアクリル酸メチル共重合体、エチレン メタクリル酸ェチル共重合体等のエチレン (メタ)アクリル酸エステル共重合体;ェ チレン ビュルアルコール共重合体等)の他、ポリエチレン (低密度ポリエチレン、線 状低密度ポリエチレン、メタ口セン触媒法ポリエチレン、中密度ポリエチレン、高密度 ポリエチレン等)、ポリプロピレン、 aーォレフイン共重合体(エチレン プロピレン共 重合体、エチレンーブテン一共重合体、プロピレンーブテン共重合体等)等のポリオ レフイン;ポリプロピレン変性榭脂等が挙げられる。また、酢酸ビニル系榭脂としては、 例えば、ポリ酢酸ビュル、酢酸ビュル (メタ)アクリル酸エステル共重合体、酢酸ビ -ル ビニルエステル共重合体、酢酸ビニル マレイン酸エステル共重合体等が挙 げられる。 [0029] The thermoplastic resin of the base polymer in the hot-melt pressure-sensitive adhesive includes, for example, polyolefin resin, vinyl acetate resin, polyester resin, styrene resin, acrylic resin, Examples thereof include polyamide-based rosin. Examples of polyolefin resin include ethylene copolymers (for example, ethylene vinyl acetate copolymer (EVA); ethylene acrylic acid copolymer (EAA), ethylene-methacrylic acid copolymer (EMAA), etc.) Of ethylene unsaturated carboxylic acid copolymer; ionomer; ethylene (meth) acrylic acid ester copolymer such as ethylene acrylate hexyl copolymer, ethylene methyl methacrylate copolymer, ethylene methacrylate methacrylate copolymer Polyethylene (low density polyethylene, linear low density polyethylene, metaguchisen catalyzed polyethylene, medium density polyethylene, high density polyethylene, etc.), polypropylene, a- olefin copolymer, etc. (Ethylene propylene copolymer, ethylene-butene monocopolymer, Renbuten copolymers) such as polio Refuin; polypropylene modified 榭脂 the like. Examples of the vinyl acetate-based resin include poly (vinyl acetate), butyl (meth) acrylate copolymer, vinyl acetate vinyl ester, and vinyl acetate / maleate copolymer. It is done.
[0030] ホットメルト型粘着剤としては、ベースポリマーが熱可塑性エラストマ一(特に、ポリ ォレフィン系熱可塑性エラストマ一やスチレン系熱可塑性エラストマ一)であるホットメ ルト型粘着剤が好適である。  [0030] As the hot-melt pressure-sensitive adhesive, a hot-melt pressure-sensitive adhesive whose base polymer is a thermoplastic elastomer (particularly, a polyolefin-based thermoplastic elastomer or a styrene-based thermoplastic elastomer) is suitable.
[0031] また、ェマルジヨン系粘着剤や溶剤系粘着剤等の粘着剤としては、アクリル系粘着 剤、ゴム系粘着剤、ポリエステル系粘着剤、ウレタン系粘着剤、ポリアミド系粘着剤、 エポキシ系粘着剤、ビュルアルキルエーテル系粘着剤、シリコーン系粘着剤、フッ素 系粘着剤等の粘着剤であって、それぞれの形態 (例えば、ェマルジヨンの形態、溶液 の形態等)の粘着剤が挙げられる。  [0031] In addition, examples of adhesives such as emulsion adhesives and solvent-based adhesives include acrylic adhesives, rubber adhesives, polyester adhesives, urethane adhesives, polyamide adhesives, and epoxy adhesives. , Adhesives such as bulle alkyl ether adhesives, silicone adhesives, fluorine adhesives, etc., and adhesives of each form (for example, emulsion form, solution form, etc.).
[0032] 尚、粘着剤は、粘着性成分 (ベースポリマー)等のポリマー成分の他に、粘着剤の 種類等に応じて、架橋剤(例えば、ポリイソシァネート系架橋剤、アルキルエーテルィ匕 メラミンィ匕合物系架橋剤等)、粘着付与剤 (例えば、ロジン誘導体榭脂、ポリテルペン 榭脂、石油榭脂、フエノール榭脂等)、可塑剤、充填剤、老化防止剤等の適宜添カロ 剤を含んでもよい。 [0032] In addition to the polymer component such as an adhesive component (base polymer), the pressure-sensitive adhesive is a cross-linking agent (for example, a polyisocyanate-based cross-linking agent, an alkyl ether base, or the like depending on the type of the pressure-sensitive adhesive). Melamine compound cross-linking agent, etc.), tackifier (for example, rosin derivative resin, polyterpene) It may contain an appropriate additive such as a resin, a petroleum resin, a phenol resin, a plasticizer, a filler, an anti-aging agent.
[0033] 前記粘着力につ 、ては、折り畳み作業が終わるまで、発熱体と包材とを貼着してお くことができるものであれば制限はないが、好ましくは、 180度ピール強度 (JISZ—02 37)は、 0. 001〜0. 9kgZ25mmであり、より好ましくは、 0. 001〜0. 5kg/25m mであり、更【こ好ましく ίま、 0. 001〜0. lkg/25mmであり、更【こ好ましく ίま、 0. 00 5〜0. lkgZ25mmであり、より好ましくは 0. 1〜: LOOgZ25mmであり、より好ましく は 0. l〜50gZ25mm、より好ましくは 0. l〜30gZ25mmであり、より好ましくは 0. l〜25gZ25mmである。  [0033] The adhesive strength is not particularly limited as long as the heating element and the packaging material can be attached until the folding operation is completed, but preferably 180 degree peel strength. (JISZ-02 37) is from 0.001 to 0.9 kgZ25 mm, more preferably from 0.001 to 0.5 kg / 25 mm, more preferably ί or 0.001 to 0.1 kg / mm. 25 mm, more preferably 0.005 to 0.1 kgZ25 mm, more preferably 0.1 to: LOOgZ25 mm, more preferably 0.1 to 50 gZ25 mm, more preferably 0.1 to It is 30 gZ25 mm, more preferably 0.1 to 25 gZ25 mm.
[0034] また、その塗布厚についても特に制限はないが、好ましくは 40 m以下であり、より 好ましく ίま 0. 01〜40 111でぁり、ょり好ましく【ま0. 1〜40 /ζ πιであり、より好ましく ίま 0. 1〜30 /ζ πιであり、より好ましく ίま 1〜30 /ζ πιであり、より好ましく ίま 5〜30 /z mであ り、更〖こ好ましくは 5〜30 /ζ πιである。  [0034] The coating thickness is not particularly limited, but is preferably 40 m or less, more preferably ί to 0.01 to 40 111, and more preferably [0.1 to 40 / ζ]. πι, more preferably ί to 0.1 to 30 / ζ πι, more preferably ί to 1 to 30 / ζ πι, more preferably ί to 5 to 30 / zm, more preferably 5-30 / ζ πι.
[0035] 塗布乃至形成方法については、公知の形成方法を採用することができる。例えば、 ホットメルト塗工方法や、溶液型塗工方法等が挙げられる。また、全面、部分的、ソリ ッド状、網状、棒状、ストライプ状、水玉状等の任意の形態とすることができる。  As the coating or forming method, a known forming method can be employed. Examples thereof include a hot melt coating method and a solution type coating method. Moreover, it can be in any form such as a whole surface, a partial shape, a solid shape, a net shape, a rod shape, a stripe shape, and a polka dot shape.
[0036] 尚、尚、外仮着部位 (外仮着位置)は、制限はなぐ好ましくは袋の開口部付近、よ り好ましくは、開口に対して平行に設けることが好ましい。  [0036] It should be noted that the external temporary attachment portion (external temporary attachment position) is preferably provided in the vicinity of the opening of the bag, more preferably in parallel with the opening, without any restriction.
また、発熱体にセパレータが設けられている場合には、セパレータが発熱体力 剥 離しな 、ように設けることが好ま U、。  In addition, when a separator is provided on the heating element, it is preferable to provide the separator so that it does not peel off the heating element force.
[0037] 少なくとも、折り畳み案内台の発熱体及び包装材と接触する面は摺動性に優れた 面が好ましい。  [0037] At least the surface of the folding guide table that contacts the heating element and the packaging material is preferably a surface excellent in slidability.
摺動性に優れた素材を使用したり、素材の摺動性を改良 (潤滑性、滑り性の付与) した、折り畳み支持手段や折り畳み案内手段が好ましい。  Folding support means and folding guide means that use a material having excellent slidability or improve the slidability of the material (providing lubricity and slipperiness) are preferred.
摺動性に優れた素材としては、金属、セラミックス、榭脂等が挙げられる。 榭脂としては、熱硬化性榭脂、結晶性熱可塑性エンプラ、エラストマ一系:ポリエス テル系及びウレタン系のもの、ポリオレフイン系(超高分子ポリエチレン)が好ましぐ 好ましい具体例としては、 熱硬化性榭脂:フエノール榭脂、ポリエステル等、カーボン繊維や PTFEを配合、 熱硬化性エンプラ (加熱すると硬化する)フエノール、ユリア、メラミン、アルキッド、不 飽和ポリエステル、エポキシ、ジァリルブタレート、シリコーン、ポリウレタン等 Examples of the material having excellent slidability include metals, ceramics, and resin. Preferred examples of resin include thermosetting resin, crystalline thermoplastic engineering plastics, elastomer systems: polyesters and urethanes, and polyolefins (ultra-high molecular weight polyethylene). Thermosetting resin: Phenolic resin, polyester, carbon fiber and PTFE, thermosetting engineering plastic (hardened when heated) phenol, urea, melamine, alkyd, unsaturated polyester, epoxy, diallyl butarate, Silicone, polyurethane, etc.
熱可塑性榭脂:ポリアセタール (POM)、ポリアミド (PA)、ポリテトラフルォロェチレ ン(PTFE)、ポリフエ-レンサルファイド(PPS)、エラストマ一系:ポリエステル系およ ぴウレタン系のもの、ポリオレフイン系(ポリエチレン、超高分子ポリエチレン、ポリプロ ピレン等)、ポリエステル、ポリ塩化ビュル、ポリ塩ィ匕ビユリデン  Thermoplastic resin: Polyacetal (POM), Polyamide (PA), Polytetrafluoroethylene (PTFE), Polyphenylene sulfide (PPS), Elastomer series: Polyester and urethane series, Polyolefin series (Polyethylene, ultra-high molecular weight polyethylene, polypropylene, etc.), polyester, polychlorinated butyl, polysalt vinylidene
エンプラ:ポリアミド(PA)、ポリアセターノレ (POM)、ポリプレンテレフタレート(PBT) 、ポリェチテレフタレート、シンジォタウチック'ポリスチレン(SPS)  Engineering plastics: Polyamide (PA), Polyacetanol (POM), Polyprene terephthalate (PBT), Polyterephthalate, Syndiotacic polystyrene (SPS)
スーパー:ポリフエ-レンサルファイドく PPS)、ポリエーテルエーテルケトン エンプラ PEEK)、液晶ポリマー(LCP)、フッ素榭脂、ポリ一テル-トリル(PEN) 摺動性の改良 (潤滑性、滑り性の付与)として、  Super: Polyphenylene-sulfide (PPS), Polyetheretherketone engineering plastic (PEEK), Liquid crystal polymer (LCP), Fluororesin, Polyter-tolyl (PEN) Improved sliding properties (providing lubricity and sliding properties) As
1.ふつ素榭脂、黒鉛、二硫ィ匕モリブデン、オイル等の固体潤滑材を配合。  1. Blended with solid lubricants such as fluorine resin, graphite, molybdenum disulfide, and oil.
2.表面の粗化 (表面に凹凸形状を形成して滑り性を付与する)  2.Roughening of the surface (forms unevenness on the surface to give slipperiness)
1)作成時に表面に凹凸形状を賦型する。  1) Form a concavo-convex shape on the surface at the time of creation.
2)サンドブラストにより凹凸形状を形成する。  2) Form irregularities by sandblasting.
3)硬化反応型榭脂ゃ熱可塑性榭脂をバインダーとしてマット剤を塗工する。  3) A matting agent is applied using a curing reaction type resin as a binder.
4)作成時にシリカ、酸ィ匕アルミニウム、炭酸カルシウム、炭酸マグネシウム、硫酸バ リウム等の微粒子力 なるマット剤を繰り込む。  4) Bring in a matting agent with fine particles such as silica, aluminum oxide, calcium carbonate, magnesium carbonate, barium sulfate.
3.表面処理  3.Surface treatment
1)ライニング:テフロン (登録商標)フィルム (PTFE)貼り  1) Lining: Teflon (registered trademark) film (PTFE) pasting
2)二重構造:テフロン (登録商標)(PFA, FEP) +ゴム  2) Double structure: Teflon (registered trademark) (PFA, FEP) + rubber
3)コーティング:テフロン (登録商標)コート,シリコーンコート  3) Coating: Teflon (registered trademark) coat, silicone coat
4表面化学処理:ハロゲン処理  4 Surface chemical treatment: Halogen treatment
等が一例として挙げられる。  Etc. are mentioned as an example.
また、ポリカーボネート、変性ポリフエ-レンエーテル(mPPE)ポリサルホン(PSF) 、ポリエーテルサルホン(PES)、ポリアリレー卜(PAR)、ポリアミドイミド(PAI)、ポリ エーテルイミド (PEI)、熱可塑性ポリイミド (PI)等も条件によっては使用できる。 また、前記樹脂の静摩擦係数 (フィルム表-金属、フィルム表-表、 JIS K7125 )は、好ましくは 1. 0以下であり、より好ましくは 0. 7以下であり、更に好ましくは 0. 5 以下であり、更に好ましくは 0. 4以下であり、更に好ましくは 0. 2以下である。 In addition, polycarbonate, modified polyphenylene ether (mPPE) polysulfone (PSF), polyethersulfone (PES), polyarylene (PAR), polyamideimide (PAI), polyetherimide (PEI), thermoplastic polyimide (PI) Etc. can be used depending on conditions. The static friction coefficient (film table-metal, film table-table, JIS K7125) of the resin is preferably 1.0 or less, more preferably 0.7 or less, and still more preferably 0.5 or less. More preferably 0.4 or less, and still more preferably 0.2 or less.
本発明の発熱体は、折り畳み可能な部分が少なくとも一力所以上有する発熱体で あれば制限はないが、発熱組成物成形体を含有する区分発熱部が発熱組成物成形 体を含有しな 、、シール部である区分け部を間隔として間隔をお 、て設けられた発 熱体が好ましぐ特に鉄粉と、炭素成分と、反応促進剤と水とを必須成分とし、易動水 値が 0. 01以上〜 14未満の成形性含余剰水発熱組成物を型成形により成形した発 熱組成物成形体を、基材上に積層し更にその上を被覆材で被覆し、前記発熱組成 物成形体の周縁部の基材及び被覆材をヒートシールしたことからなり、一面である A 面と他の一面である B面を有する一体成形された発熱領域である複数の区分発熱部 を有し、前記区分発熱部の長さが 5mm〜200mm、幅が lmm以上〜 25mm未満、 高さが 0. 5mm〜10mmであり、(長さ Z幅)の比率が 2. 1〜30であり、区分け部の 幅が l〜30mmであり、前記複数の区分発熱部はそれぞれ離れており、少なくとも 1 方向においてストライプ状に形成され、前記基材及び前記被覆材のうち少なくとも 1 種は通気性 (酸素透過性)を有し、前記 A面は通気性を有し、前記 A、 Bの両面が凸 状区分発熱部と凹状 (平坦状)区分け部とから形成される発熱体が好ましい。  The heating element of the present invention is not limited as long as it is a heating element having at least one foldable portion, but the segment heating part containing the exothermic composition molded body does not contain the exothermic composition molded body. In particular, the heating element provided with a gap between the seal sections is particularly preferable, and iron powder, carbon component, reaction accelerator and water are essential components, and the mobile water value is A heat generating composition molded body obtained by molding a moldable excess water exothermic composition having a moldability of 01 or more to less than 14 by molding is laminated on a substrate and further coated with a coating material, and the exothermic composition is formed. It consists of heat-sealing the base material and the covering material at the peripheral edge of the molded body, and has a plurality of divided heat generating portions which are integrally formed heat generating regions having A surface which is one surface and B surface which is the other surface. The length of the heating section is 5mm ~ 200mm, the width is more than lmm ~ less than 25mm, the height is 0.5mm ~ 10 mm, the ratio of (length Z width) is 2.1-30, the width of the section is 1-30 mm, and the plurality of section heating sections are separated from each other, and are striped in at least one direction And at least one of the base material and the covering material is air permeable (oxygen permeable), the surface A is air permeable, and both surfaces A and B are convex segmented heat generating portions. And a heating element formed of a concave (flat) section.
更に前記発熱体の最低剛軟度が 100mm以下であり、最低剛軟度を有する方向以 外は容易に曲がらず、曲がり安さに方向付けがあり、他方向に比べ一方向のみが極 端に曲がりやす 、構造を有して 、る発熱体が好ま 、。  In addition, the heating element has a minimum bending resistance of 100 mm or less, does not bend easily except in the direction having the lowest bending resistance, and has a direction for ease of bending, and only one direction is bent to the extreme as compared to the other directions. Easily prefer a heating element that has a structure.
本発明の基材ゃ被覆材ゃ通気調整材ゃ支持体を構成する包材としては、発熱体 用の包材として機能すれば制限はない。例えば、包材として非通気性素材、通気性 素材、吸水性素材、非吸水性素材、非伸長性素材、伸長性素材、伸縮性素材、非 伸縮性素材、発泡素材、非発泡素材、非ヒートシール性素材、ヒートシール性素材等 がー例として挙げられ、フィルム、シート、不織布、織布等及びそれらの積層体等の 複合体の所望の形態で、所望の用途により適宜使用できる。  The base material of the present invention is not limited as long as it functions as a packaging material for a heating element as a packaging material constituting a covering material, a ventilation control material, or a support. For example, non-breathable materials, breathable materials, water-absorbing materials, non-water-absorbing materials, non-stretchable materials, stretchable materials, stretchable materials, non-stretchable materials, foamed materials, non-foamed materials, non-heat Examples thereof include a sealing material, a heat sealing material and the like, and can be appropriately used depending on a desired application in a desired form of a composite such as a film, a sheet, a nonwoven fabric, a woven fabric, and a laminate thereof.
本発明の基材とは、発熱組成物成形体が積層される包材であり、被覆材とは、それ を覆う包材であり、通気性である力 非通気性であるかは問わない。 通常、基材は非通気性フィルム又はシートからなり、被覆材は通気性フィルム又は シート又は不織布力もなる力 逆でもかまわなし、双方が通気性を有していてもよい。 本発明の発熱体は少なくとも一部が通気性である。 The base material of the present invention is a packaging material on which the exothermic composition molded body is laminated, and the coating material is a packaging material covering the same, and it does not matter whether it is air permeable or non-breathable. Usually, the substrate is made of a non-breathable film or sheet, and the covering material may be a force that can also be a breathable film, sheet, or nonwoven fabric, or both of them may be breathable. The heating element of the present invention is at least partially breathable.
尚、本発明の発熱発熱体に使用される包材は、従来より開示されている又市販され て 、る又は公知の使 、捨てカイロや発熱体に使用されて 、る如何なる包材をも適宜 選択して使用できる。  The packaging material used for the heating element of the present invention has been disclosed in the past or is commercially available, or any known packaging material used for discarded body warmers or heating elements. You can select and use.
また、発熱体の両面のそれぞれに対する相対的な通気性について制限はないが、 粘着面が通気性、被通気性にかかわらず、発熱体の粘着面が何れの側にあっても In addition, there is no restriction on the relative air permeability of each side of the heating element, but the adhesive face of the heating element is on either side regardless of whether the adhesive face is breathable or breathable.
、身体と接する側の通気性は身体と接しな 、側の通気性より低 、ことが好まし 、。 包材ゃ発熱部や区分発熱部の通気性は、リツシ一法 (JIS K007129A法)による 透湿度で好ましくは 50gZm2Z24hr〜: LO, 000gZm2Z24hrであり、より好ましく は 100gZm2Z24hr〜5, 000gZm2Z24hrであり、更に好ましくは 100gZm2Z 24hr〜600gZm2Z24hrであり、更に好ましくは 150gZm2Z24hr〜500gZm2 Z24hrである。 The air permeability on the side that contacts the body is preferably lower than the air permeability on the side that does not contact the body. The air permeability of the heat generating part and the section heat generating part is preferably 50gZm2Z24hr to LO, 000gZm2Z24hr, more preferably 100gZm2Z24hr to 5,000gZm2Z24hr, more preferably, in terms of moisture permeability according to the Risshi method (JIS K007129A method). Is 100 gZm2Z 24hr to 600gZm2Z24hr, more preferably 150gZm2Z24hr to 500gZm2Z24hr.
これらの範囲より透湿度が低いと、発熱量が不充分になり易ぐ一方、透湿度が高 いと、発熱体の最高温度が高くなりすぎる畏れがある。用途によっては使用できる。 また、本発明の発熱体が気密性収納袋である外袋に封入された発熱体の場合、気 密性収納袋である外袋のシール部に開口用のノッチが設けられることが好ま U、。 また、前記ノッチが少なくとも気密性収納袋である外袋の辺に接触せず、気密性収 納袋である外袋のシール部内に設けられることが好ま 、。  If the moisture permeability is lower than these ranges, the calorific value tends to be insufficient. On the other hand, if the moisture permeability is high, the maximum temperature of the heating element may become too high. It can be used depending on the application. Further, in the case where the heating element of the present invention is a heating element enclosed in an outer bag which is an airtight storage bag, it is preferable that a notch for opening is provided in the seal portion of the outer bag which is an airtight storage bag. . In addition, it is preferable that the notch is provided in a seal portion of the outer bag that is an airtight storage bag without contacting at least the side of the outer bag that is the airtight storage bag.
また、前記ノッチが気密性収納袋である外袋のシール部内の領域に設けられ、少 なくとも気密性収納袋である外袋の辺に接触したけられることが好ま ヽ。  In addition, it is preferable that the notch is provided in a region in the seal portion of the outer bag which is an airtight storage bag and at least touches the side of the outer bag which is an airtight storage bag.
本発明のノッチは制限はないが、 Iノッチ、 Vノッチ、 Uノッチ等が一例として挙げら れる。  The notches of the present invention are not limited, but examples include I notches, V notches, U notches and the like.
非通気性収納袋である外袋のシール部は、発熱体の周縁部の外側近傍に形成さ れているため、外袋用包材と発熱体とが略密着状態となり、発熱体を折り畳んだ状態 で包装していることとも相まって全体が極めてコンパクトになる。  The seal part of the outer bag, which is a non-breathable storage bag, is formed near the outside of the peripheral edge of the heating element, so that the outer bag packaging material and the heating element are in close contact, and the heating element is folded. Combined with packaging in a state, the whole is extremely compact.
発熱体が大きくなつても、折り畳まない従来の発熱体と比べて部材数を少なくでき、 コストを削減できる他、使用時に出るゴミを削減でき、地球環境に優しいという利点も ある。 Even if the heating element becomes large, the number of members can be reduced compared to the conventional heating element that does not fold, In addition to being able to reduce costs, it has the advantage of being friendly to the global environment, as it reduces the amount of garbage generated during use.
前記区分発熱部又は前記発熱組成物成形体のサイズは制限はないが、好ましい サイズは以下の通りである。  Although there is no restriction | limiting in the size of the said division | segmentation exothermic part or the said exothermic composition molded object, A preferable size is as follows.
1)円形状、ディスク形状及びディスク類似形状の場合  1) In the case of circular shape, disc shape and disc-like shape
直径は、好ましくは約 lmm〜約 60mmであり、より好ましくは 2mn!〜 50mmであり 、更に好ましくは 10mm〜40mmであり、更に好ましくは 20mm〜30mmである。 高さは、好ましくは 0. lmm〜20mmであり、より好ましくは 0. 3mm〜20mmであり 、更に好ましくは 0. 5mn!〜 20mmであり、更に好ましくは lmm〜20mmであり、より 好ましくは 1. 5mn!〜 10mmであり、更に好ましく 3mm〜9mmであり、更に好ましく は 4mn!〜 8mmであり、更に好ましくは 5mn!〜 7mmである。  The diameter is preferably about lmm to about 60mm, more preferably 2mn! -50 mm, more preferably 10 mm to 40 mm, and even more preferably 20 mm to 30 mm. The height is preferably 0.1 mm to 20 mm, more preferably 0.3 mm to 20 mm, and even more preferably 0.5 mn! ~ 20mm, more preferably lmm ~ 20mm, more preferably 1.5mn! ~ 10mm, more preferably 3mm ~ 9mm, more preferably 4mn! ~ 8mm, more preferably 5mn! ~ 7mm.
容積は、好ましくは約 0. 0045cm3〜約 20cm3であり、より好ましくは約 0. 2cm3〜 約 11cm3である。 The volume is preferably from about 0.0045 cm 3 to about 20 cm 3 , more preferably from about 0.2 cm 3 to about 11 cm 3 .
2)前記 1)以外の形状 (矩形、矩形類似形状等)である場合  2) When the shape is other than 1) (rectangular, rectangular-like shape, etc.)
幅は、好ましくは 0. 5mm〜60mmであり、より好ましくは 0. 5mm〜50mmであり、 好ましくは 0. 5mn!〜 50mmであり、更に好ましくは lmn!〜 50mmであり、更に好ま しくは 3mn!〜 50mmであり、更に好ましくは 3mm〜30mmであり、更に好ましくは 5 mn!〜 20mmであり、更に好ましくは 5mn!〜 15mmであり、更に好ましくは 5mm〜l Ommで to 。  The width is preferably 0.5 mm to 60 mm, more preferably 0.5 mm to 50 mm, and preferably 0.5 mn! ~ 50mm, more preferably lmn! ~ 50mm, more preferably 3mn! ~ 50mm, more preferably 3mm ~ 30mm, more preferably 5mn! ~ 20mm, more preferably 5mn! ~ 15mm, more preferably 5mm ~ l Omm to.
また、高さは、好ましくは 0. lmm〜30mmであり、より好ましくは 0. lmn!〜 20mm であり、更に好ましくは 0. lmm〜10mmであり、更に好ましくは 0. 3mn!〜 10mmで あり、更に好ましくは 0. 5mn!〜 10mmであり、更に好ましくは lmm〜10mmであり、 更に好ましくは 2mn!〜 1 Ommである。  The height is preferably 0.1 mm to 30 mm, more preferably 0.1 mm! ~ 20mm, more preferably 0.1mm ~ 10mm, more preferably 0.3mn! ~ 10mm, more preferably 0.5mn! ~ 10mm, more preferably lmm ~ 10mm, more preferably 2mn! ~ 1 Omm.
また、長さは、好ましくは 5mm〜300mmであり、より好ましくは 5mm〜200mmで あり、より好ましくは 5mm〜 100mmであり、更に好ましくは 20mm〜150mmであり、 更に好ましくは 30mm〜: L 00mmである。  Further, the length is preferably 5 mm to 300 mm, more preferably 5 mm to 200 mm, more preferably 5 mm to 100 mm, still more preferably 20 mm to 150 mm, and further preferably 30 mm to: L 00 mm. is there.
また、表面積は区分発熱部としての機能を有すれば制限はないが、好ましくは約 5 0cm2以下であり、より好ましくは約 40cm2以下であり、更に好ましくは約 25cm2未満 であり、更に好ましくは 20cm2未満である。 Further, the surface area is not limited as long as it has a function as a segmented heat generating part, but is preferably about 50 cm 2 or less, more preferably about 40 cm 2 or less, and further preferably less than about 25 cm 2. More preferably, it is less than 20 cm 2 .
前記区分発熱部の容積又は発熱組成物成形体の容積は、好ましくは 0. 015cm3 〜500cm3であり、好ましくは 0. 04cm3〜500cm3であり、より好ましくは 0. 04cm3〜 30cm3であり、更に好ましくは 0. lcm3〜30cm3であり、更に好ましくは lcm3〜30c m3であり、更に好ましくは 1. 25cm3〜20cm3であり、更に好ましくは 1. 25cm3〜10 cm3であり、更に好ましくは 3cm3〜 10cm3である。 Volume of volume or exothermic composition molded article of the segment heating portion is preferably 0. 015cm 3 ~500cm 3, preferably 0. 04cm 3 ~500cm 3, more preferably 0. 04cm 3 ~ 30cm 3 , and still more preferably 0. lcm 3 ~30cm 3, and more preferably a lcm 3 ~30c m 3, more preferably 1. 25 cm 3 to 20 cm 3, more preferably 1. 25 cm 3 to 10 cm 3 , more preferably 3 cm 3 to 10 cm 3 .
[0040] 前記区分発熱部にお 、て、発熱組成物成形体の収納領域である区分発熱部に発 熱組成物成形体が収容された時に、発熱組成物成形体占有領域である発熱組成物 成形体の容積積と発熱組成物収納領域である区分発熱部の容積との容積比は通常 0. 6〜1であり、好ましくは 0. 7〜1であり、より好ましくは 0. 8〜1であり、更に好まし くは 0. 9〜1である。 [0040] The exothermic composition which is the exothermic composition molded body occupied area when the exothermic composition molded body is accommodated in the segmented exothermic part which is the accommodating area of the exothermic composition molded body. The volume ratio between the volumetric product of the molded body and the volume of the exothermic part that is the exothermic composition storage area is usually 0.6 to 1, preferably 0.7 to 1, and more preferably 0.8 to 1. More preferably, it is 0.9 to 1.
[0041] 本発明の発熱部は、スジ状に間隔をおいて設けることが好ましぐ「スジ状に間隔を おいて設ける」とは、複数の区分発熱部が、スジ状に間隔をおいて (平行線状に)設 けられたものである。 1本のスジは 1個の区分発熱部により構成されていることが好ま しい。  [0041] It is preferable that the heat generating portions of the present invention be provided in a streak-like manner. "To provide streaks in a spaced manner" means that a plurality of segmented heat-generating portions are provided in a streak-like manner. (In parallel lines). It is preferable that one streak is composed of one section heating part.
また、下記の条件を満たしていれば、 1本のスジは 2個以上の区分発熱部と 1個以 上の区分け部とから構成されて 、てもよ 、。  Also, if the following conditions are satisfied, one streak may be composed of two or more divided heat generating parts and one or more divided parts.
Tは、 T≥2Sであり、好ましくは、 T≥2. 5Sである。  T is T≥2S, preferably T≥2.5S.
Ρは、 Ρ≤Τであり、好ましくは、 Ρ≤0. 5Τである。  Ρ is Ρ≤Τ, preferably Ρ≤0.5Τ.
Τ : 1個の区分発熱部の長さ  Τ: Length of one section heating part
S : 1個の区分発熱部の幅  S: Width of one section heating part
Ρ : 区分け部の長さ  Ρ: Length of the section
平行縞状 (縦縞、横縞、斜め縞、縦波縞、横波縞、斜め波縞等)に区分発熱部から なるスジを配置することが一例として挙げられる。  One example is the arrangement of streaks composed of segmented heat generating parts in parallel stripes (vertical stripes, horizontal stripes, diagonal stripes, vertical wave stripes, horizontal wave stripes, diagonal wave stripes, etc.).
[0042] 前記区分け部の幅は区分発熱部を間隔を置いて設けることができる区分けができ れば制限はないが、通常 0. lmn!〜 50mmであり、好ましくは 0. 3mn!〜 50mmであ り、より好ましくは 0. 3mn!〜 50mmであり、更に好ましくは 0. 3mn!〜 40mmであり、 更に好ましくは 0. 5mn!〜 30mmであり、更に好ましくは lmm〜20mmであり、更に 好ましくは 3mn!〜 10mmである。 [0042] The width of the section is not limited as long as the section heat generating section can be provided at intervals, but is usually 0.1 lmn! ~ 50mm, preferably 0.3mn! ~ 50mm, more preferably 0.3mn! ~ 50mm, more preferably 0.3mn! ~ 40mm, more preferably 0.5mn! ~ 30mm, more preferably lmm ~ 20mm, Preferably 3mn! ~ 10mm.
[0043] 本発明の発熱組成物成形体としては、空気 (酸素)と接触して発熱し、基材上に積 層でき、形状を維持でき、被覆材を被せ、発熱組成物成形体の周縁部をシールする ことができれば制限はな!/、が、 [0043] The exothermic composition molded body of the present invention generates heat upon contact with air (oxygen), can be stacked on a substrate, can maintain its shape, is covered with a covering material, and has a peripheral edge of the exothermic composition molded body. If the part can be sealed, there is no limit! /
1)成形性含余剰水発熱組成物を型成形により成形した発熱組成物成形体、 1) Exothermic composition molded body obtained by molding a moldable excess water exothermic composition by molding,
2)発熱シート及びその切断加工品からなり、幅は制限はないが、好ましくは 1〜30 mmからなるシート状発熱片である発熱組成物成形体 (幅は、制限はないが、好まし くは lmn!〜 30mm、好ましくは lmn!〜 25mm、より好ましくは lmn!〜 24. 5mmで ある。 2) It consists of a heat generating sheet and its cut product, and the width is not limited, but it is preferably a heat generating composition molded body which is a sheet-shaped heat generating piece consisting of 1 to 30 mm (the width is not limited, but preferably Is lmn! ~ 30mm, preferably lmn! ~ 25mm, more preferably lmn! ~ 24.5mm.
3)上記発熱シートの幅は、制限はないが、好ましくは、 0. l〜50mmのストライプ状 の空間を設けた、空気 (酸素)と接触して発熱する孔付き発熱シート及びその切断加 ェ品である発熱組成物成形体、  3) The width of the heat generating sheet is not limited, but is preferably a 0.1 to 50 mm stripe-shaped space with a hole that generates heat upon contact with air (oxygen) and its cutting heat. Exothermic composition molded body,
4)上記シート状発熱片に幅は、制限はないが、好ましくはスリット又は 0. l〜50m mのストライプ状の空間を設けた、空気 (酸素)と接触して発熱する孔付き発熱シート 及びその切断加工品である発熱組成物成形体  4) The width of the sheet-like heating piece is not limited, but preferably has a slit or a 0.1--50 mm stripe-shaped space, and has a holed heating sheet that generates heat in contact with air (oxygen) and Exothermic composition molded body which is the cut product
等が一例として挙げられる。  Etc. are mentioned as an example.
[0044] 発熱シートは空気 (酸素)と接触して発熱するシート状物であれば制限はないが、 分散型発熱シート、抄紙型発熱シート、加圧加工型発熱シート等が一例として挙げら れる。 [0044] The heat generating sheet is not particularly limited as long as it is a sheet-like material that generates heat upon contact with air (oxygen), but examples thereof include a dispersive heat generating sheet, a papermaking heat generating sheet, and a pressure processing heat generating sheet. .
本発明では、発熱組成物成形体として、発熱シート (分散型、抄紙型、加圧加熱型 等)その加工品である孔付き発熱シート及び Z又は発熱片等も使用できる。  In the present invention, a heat-generating sheet (dispersion type, paper-making type, pressure heating type, etc.), a processed product with holes, a Z-heat generation piece, or the like can be used as the heat-generating composition molded body.
上記の本発明の各発熱シートの加工方法や発熱片の製造方法は素材発熱シート の切り出し、スリット、孔あけ、孔あけ Z切り出し等の加工や小幅(幅は、,制限はない 1S 好ましくは lmm〜30mm、より好ましくは幅 lmm〜25mm、より好ましくは幅 lm m〜24. 5mm)シートの製造が好ましい。素材シートの製造方法は公知の製造方法 力 s使用できる。例えば、 WO96/11654^ ^2003- 102761^WO00/1362 6等が一例として挙げられる。また空間部 (含スリット)の設置方法は制限はなぐ公知 の方法が使用でき、ギロチンカッターやカットロール等の機械的なカット方法やレー ザ一 (laser)よるカット方法が一例として挙げられる The processing method of each heating sheet and the manufacturing method of the heating piece of the present invention described above are processing such as cutting, slitting, punching, punching Z cutting, etc. of the material heating sheet and small width (width is not limited, 1S preferably lmm -30 mm, more preferably width 1 mm to 25 mm, more preferably width lm m to 24.5 mm). Method of manufacturing a sheet-shaped raw material is known of the method of manufacturing force s can be used. For example, WO96 / 11654 ^^ 2003-102761 ^ WO00 / 1362 6 etc. are mentioned as an example. In addition, a known method with no restrictions can be used for the installation method of the space (including the slit), and a mechanical cutting method such as a guillotine cutter or a cutting roll or a laser An example is the cutting method using the laser.
[0045] 分散型発熱シートとは、発熱組成物を不織布等の他空隙率の包装材中に分散、保 持し、シート状の発熱体に加工したものであれば制限はないが、鉄粉等の被酸化性 金属粉末炭素成分、保水剤を必須成分とした粉末原料発熱組成物を不織布中に分 散させた後に電解質等の反応促進剤水溶液を加え、空気 (酸素)と接触して発熱す る発熱シートである。 [0045] The dispersive exothermic sheet is not particularly limited as long as the exothermic composition is dispersed and held in a non-woven fabric or other other packaging material and processed into a sheet-like exothermic body. Oxidizable metal powder Carbon component, powder raw material exothermic composition containing water retention agent as essential components is dispersed in the nonwoven fabric, and then an aqueous solution of reaction accelerator such as electrolyte is added, and contact with air (oxygen) generates heat. This is an exothermic sheet.
[0046] 抄紙型発熱シートとは、発熱組成物を抄紙法によりシート状の発熱体に加工したも のであれば制限はないが、鉄粉等の被酸化性金属粉末、炭素成分、保水剤、繊維 状物及び水を必須成分としたスラリー状原料発熱組成物を抄紙により製造した抄紙 シートを 90〜200°Cの熱風乾燥し、電解質等の反応促進剤又はその水溶液を加え て、空気 (酸素)と接触して発熱する発熱シートが一例として挙げられる。  [0046] The papermaking exothermic sheet is not limited as long as the exothermic composition is processed into a sheet-like heating element by a papermaking method. However, an oxidizable metal powder such as iron powder, a carbon component, a water retention agent, A paper sheet made from a slurry-like raw material exothermic composition containing fiber and water as essential components by papermaking is dried with hot air at 90 to 200 ° C, and a reaction accelerator such as an electrolyte or an aqueous solution thereof is added to air (oxygen). An example is a heat generating sheet that generates heat upon contact with ().
[0047] 加圧加工型発熱シートとは、発熱組成物を加圧加工法によりシート状の発熱体に 加工したものであれば制限はないが、下記の 1)及び 2)がー例として挙げられる。 [0047] The pressure-processable exothermic sheet is not limited as long as the exothermic composition is processed into a sheet-like heating element by a pressurizing process, but the following 1) and 2) are given as examples. It is done.
1)鉄粉等の被酸化性金属粉末、炭素成分、反応促進剤及び水を必須成分とした発 熱組成物と、吸水性ポリマー及び Z又は吸水性ポリマー以外の第 2のポリマーとの混 合物に、アルコール、架橋剤若しくは可塑剤のいずれかを添加した発熱組成物を、 所定の圧力を加えて一体化した発熱シート。 1) Mixing of heat-generating composition containing oxidizable metal powder such as iron powder, carbon component, reaction accelerator and water as essential components with water-absorbing polymer and second polymer other than Z or water-absorbing polymer An exothermic sheet in which an exothermic composition obtained by adding any of alcohol, a crosslinking agent, and a plasticizer to a product is integrated by applying a predetermined pressure.
前記発熱組成物としては、前記成型性合余剰水発熱組成物の成分を使用できる。 アルコールには、一価ないし多価の液体のアルコールを用いることが好ましぐ例え ば、エタノール、プロピレングリコール、グリセリン等が好ましい。  As the exothermic composition, components of the moldable surplus water exothermic composition can be used. For example, ethanol, propylene glycol, glycerin and the like are preferable as the alcohol.
前記架橋剤は、前記吸水性ポリマー間の架橋、前記第 2のポリマー間の架橋、及 び前記吸水性ポリマーと前記第 2のポリマーとの間の架橋、これらのポリマー間で架 橋反応を起こさせるものの他、自らがこれらポリマー間に介在して橋かけを起こさせる ものの内、少なくとも一つの架橋を促進する架橋剤が好ましい。エチレングリコールジ グリシジルエーテル、メチレンビスアクリルアミド等が一例として挙げられる。  The cross-linking agent causes cross-linking between the water-absorbing polymers, cross-linking between the second polymers, cross-linking between the water-absorbing polymer and the second polymer, and a cross-linking reaction between these polymers. In addition to the above-described ones, at least one cross-linking agent that promotes cross-linking is preferable among the ones that intervene between these polymers to cause crosslinking. Examples include ethylene glycol diglycidyl ether and methylene bisacrylamide.
2)鉄粉等の被酸化性金属粉末、炭素成分、反応促進剤及び水を必須成分とし、成 形助剤を全体量に対して 1〜15重量%、好ましくは 3〜15重量%を含有し、易動水 値が 0. 01未満の含水発熱組成物を、所定の圧力を加えて一体化した発熱シート。 尚、吸水性ポリマー、木粉等の保水剤、亜硫酸ナトリウム等の水素発生抑制剤、消 石灰等の pH調整剤等の従来公開されて ヽる使 ヽ捨てカイロや発熱体用発熱組成 物の成分が適宜選択して使用できる。 2) Oxidizable metal powder such as iron powder, carbon component, reaction accelerator and water are essential components, and 1 to 15% by weight, preferably 3 to 15% by weight, of the formation aid is based on the total amount. The easy water value is An exothermic sheet in which a water-containing exothermic composition of less than 01 is integrated by applying a predetermined pressure. In addition, water-absorbing polymers, water retention agents such as wood flour, hydrogen generation inhibitors such as sodium sulfite, pH regulators such as slaked lime, etc. that have been publicly disclosed. Can be appropriately selected and used.
加圧加工型発熱シートは、加圧加工法によりシート化するときに、型孔の大小により 発熱シート、シート状発熱片、孔付き型を使用することにより、孔付き発熱シート、孔 付き状発熱片が製造できる。  When a pressure-processed heat generating sheet is made into a sheet by the pressure processing method, a heat-generating sheet, a sheet-shaped heating piece, or a holed mold is used depending on the size of the mold hole, so A piece can be manufactured.
ここで、加圧加工法とは、型内に発熱組成物を入れ型内で加圧して、発熱組成物 を圧縮して成形する方法であれば、制限はな!/ヽが、  Here, the pressure processing method is not limited as long as the exothermic composition is put in a mold and pressed in the mold and the exothermic composition is compressed and molded.
1)発熱組成物を円筒形の金型に入れて、加圧して成形する。圧力と加圧時間は成 形できれば制限はないが、圧力は、好ましくは 100〜9000kgZcm2であり、時間は 、、好ましくは、 0. 01〜30秒である。  1) Put the exothermic composition in a cylindrical mold and press to mold. The pressure and pressurizing time are not limited as long as they can be formed, but the pressure is preferably 100 to 9000 kgZcm2, and the time is preferably 0.01 to 30 seconds.
2)発熱組成物をローラーを用いて所定の圧力で圧延し、 .シート状の発熱体とする。 2) The exothermic composition is rolled at a predetermined pressure using a roller to obtain a sheet-like heating element.
3)所望の形状からなる凹部や貫通孔を有する型の型孔に発熱組成物を入れ、バル ーンゃゴム性ロール等の変形可能な柔軟なロールや型孔に挿入可能な凸部を有す るロールやベルト等の加圧手段で、型孔内の発熱組成物を加圧して、発熱組成物を 圧縮して成形する。 3) The exothermic composition is placed in a mold hole having a recess or a through hole having a desired shape, and a deformable flexible roll such as a balloon roll or a convex part that can be inserted into the mold hole. The exothermic composition in the mold cavity is pressurized with a pressurizing means such as a roll or belt, and the exothermic composition is compressed and molded.
また、作製した発熱体を熱処理してもよい。この場合の熱処理条件は制限はないが 、好ましくは 50〜250°C、 1秒〜 20分程度である。  Moreover, you may heat-process the produced heat generating body. The heat treatment conditions in this case are not limited, but are preferably 50 to 250 ° C. and about 1 second to 20 minutes.
上記の本発明の各シートの製造方法は素材発熱シートの切り出し、スリット、孔あけ 、孔あけ Z切り出し等の加工や小幅(幅は制限はないが、好ましくは lmn!〜 30mm 、より好ましくは lmm〜25mm、より好ましくは lmm〜24. 5mmである。シートの製 造が挙げられるが、素材シートの製造方法は公知の製造方法が使用できる。例えば 、 W096/11654ゃ特開 2003— 102761や WO00/13626等力 S—伊として挙げ、 られる。  The manufacturing method of each sheet of the present invention described above is the process such as cutting, slitting, punching, punching Z cutting, etc. of the material heat generating sheet or small width (the width is not limited, but preferably lmn! To 30 mm, more preferably lmm 25 mm, more preferably lmm to 24.5 mm, and the production of a sheet is exemplified, but a known production method can be used as a material sheet, for example, W096 / 11654 is disclosed in JP2003-102761 and WO00. / 13626 Isotropic S—It is listed as Italy.
本発明の発熱組成物は、発熱組成物成形体が形成でき、空気と接触して発熱する ものであれば制限はないが、好ましくは、鉄粉、活性炭等の炭素成分、塩ィ匕ナトリウム 、塩化カリウム等の無機電解質等からなる反応促進剤及び水を必須成分とし、易動 水値が 0. 01以上 14未満の余剰水を含有する成形性含余剰水発熱組成物がこのま しい。 The exothermic composition of the present invention is not limited as long as it can form a exothermic composition molded body and generates heat upon contact with air, but is preferably a carbon component such as iron powder or activated carbon, sodium chloride sodium salt, It contains a reaction accelerator composed of an inorganic electrolyte such as potassium chloride and water as essential components. A moldable surplus water exothermic composition containing surplus water having a water value of 0.01 or more and less than 14 is preferable.
また、前記成形性含余剰水発熱組成物は、上記成分の他に、木粉、バーミキユラィ ト等の保水剤、デンプンーアクリル酸塩グラフト共重合体、ポリアクリル酸塩架橋物等 の吸水性ポリマー、亜硫酸ナトリウム等の水素発生抑制剤、消石灰等の pH調整剤、 ポリオキシエチレンアルキルエーテル等のノ-オン、両性イオン、ァ-オン、カチオン の界面活性剤、ポリエチレンやポリプロピレン等の疎水性高分子化合物、ジメチルシ リコーンオイル等の有機ケィ素化合物、焦電物質、セラミック等の遠赤外線放射物質 、トルマリン等のマイナスイオン発生剤、 FeCl等の発熱助剤、ケィ素やアルミニウム  In addition to the above-mentioned components, the moldable excess water exothermic composition includes water-absorbing polymers such as water retention agents such as wood flour and vermiculite, starch-acrylate graft copolymers, and polyacrylate cross-linked products. Inhibitors of hydrogen generation such as sodium sulfite, pH adjusters such as slaked lime, non-ions such as polyoxyethylene alkyl ether, zwitterion, ion and cationic surfactants, hydrophobic polymers such as polyethylene and polypropylene Compounds, organic silicon compounds such as dimethyl silicone oil, far-infrared radiation materials such as pyroelectric materials and ceramics, negative ion generators such as tourmaline, exothermic aids such as FeCl, silicon and aluminum
2  2
等の鉄以外の金属、二酸化マンガン等の酸化鉄以外の金属酸化物、塩酸やマレイ ン酸ゃ酢酸等の酸性物質、パルプ等の繊維状物、尿素等の肥料成分、グリセリンやMetals other than iron, such as manganese oxide, metal oxides other than iron oxide, such as manganese dioxide, acidic substances such as hydrochloric acid and maleic acid, acetic acid such as pulp, fertilizer components such as urea, fertilizer components such as urea, glycerin and
D—ソルビトール等の保湿剤、成形助剤、離型剤、骨材、機能性物質、又はこれらの 混合物からなる付加的な成分カゝら選ばれた少なくとも一種を含有してもよい。 It may contain at least one selected from an additional component consisting of a humectant such as D-sorbitol, a molding aid, a release agent, an aggregate, a functional substance, or a mixture thereof.
尚、本発明の発熱組成物の成分は、従来より開示されている又市販されている又 は公知の使い捨てカイロや発熱体に使用される発熱組成物の如何なる成分をも適宜 選択して使用できる。  As the components of the exothermic composition of the present invention, any components of the exothermic compositions that have been disclosed in the past, are commercially available, or are used for known disposable warmers and heating elements can be appropriately selected and used. .
前記発熱組成物は、その配合割合は特に限定されるものではな 、が、鉄粉 100重 量部に対して、炭素成分 1. 0〜50重量部、反応促進剤 1. 0〜50重量部、水 1. 0〜 60重量部を必須成分とする混合物である。  The mixing ratio of the exothermic composition is not particularly limited, but 1.0 to 50 parts by weight of a carbon component and 1.0 to 50 parts by weight of a reaction accelerator with respect to 100 parts by weight of iron powder. A mixture containing 1.0 to 60 parts by weight of water as an essential component.
更に、前記発熱組成物に下記のものを下記の配合割合で加えてもょ 、。  Further, the following may be added to the exothermic composition at the following blending ratio:
即ち、鉄粉 100重量部に対して、保水剤 0. 01〜: L0重量部、吸水性ポリマー 0. 01 〜20重量部、 pH調整剤 0. 01〜5重量部、水素発生抑制剤 0. 01〜12重量部、鉄 以外の金属 1. 0〜50重量部、酸化鉄以外の金属酸化物 1. 0〜50重量部、界面活 性剤 0. 01〜5重量部、疎水性高分子化合物、骨材、繊維状物、機能性物質、有機 ケィ素化合物、焦電物質はそれぞれ 0. 01〜10重量部、保湿剤、肥料成分、発熱助 剤はそれぞれ 0. 01〜: L0重量部、成形助剤、離型剤はそれぞれ 0. 001〜5重量部 、酸性物質 0. 01〜1重量部である。尚、磁性体を更に配合するようにしてもよぐ配 合割合は所望により適宜決めればよい。 尚、この配合割合は、反応混合物、発熱混合物にも適用することができる。また、反 応混合物の易動水値は通常 0. 01未満である。 That is, with respect to 100 parts by weight of iron powder, water retention agent 0.01 to: L0 part by weight, water-absorbing polymer 0.01 to 20 parts by weight, pH adjuster 0.01 to 5 parts by weight, hydrogen generation inhibitor 0. 01 to 12 parts by weight, metal other than iron 1.0 to 50 parts by weight, metal oxide other than iron oxide 1.0 to 50 parts by weight, surfactant 0.01 to 5 parts by weight, hydrophobic polymer compound , Aggregates, fibrous materials, functional substances, organic compounds, pyroelectric substances 0.01 to 10 parts by weight, moisturizers, fertilizer components, and fever aids 0.01 to 10 parts by weight, respectively. The molding aid and mold release agent are 0.001 to 5 parts by weight and 0.01 to 1 part by weight of an acidic substance, respectively. It should be noted that the proportion of the magnetic material that may be further blended may be appropriately determined if desired. This blending ratio can also be applied to a reaction mixture and an exothermic mixture. The mobile water value of the reaction mixture is usually less than 0.01.
また、磁性体を更に配合するようにしてもよぐ配合割合は所望により適宜決めれば よい。  Further, the blending ratio that may be further blended with the magnetic material may be appropriately determined as desired.
[0050] 前記鉄粉は、限定はされな!、が、铸鉄鉄粉、アトマイズ鉄粉、電解鉄粉、還元鉄粉 、スポンジ鉄粉及びそれらの鉄合金粉等が一例として使用できる。更に、これら鉄粉 が炭素や酸素を含有していてもよぐまた、鉄を 50%以上含む鉄で、他の金属を含 んで!、てもよ!/ヽ。合金等として含まれる金属の種類は鉄成分が発熱組成物の成分と して働けば特に制限はないが、アルミニウム、マンガン、銅、ケィ素等の金属、半導体 がー例として挙げられる。本発明の金属には半導体も含める。  [0050] The iron powder is not limited! Pig iron iron powder, atomized iron powder, electrolytic iron powder, reduced iron powder, sponge iron powder, iron alloy powder thereof, and the like can be used as examples. In addition, these iron powders may contain carbon or oxygen, or iron containing 50% or more of iron and other metals! The type of metal contained as an alloy is not particularly limited as long as the iron component acts as a component of the heat generating composition, but examples include metals such as aluminum, manganese, copper, and silicon, and semiconductors. The metal of the present invention includes a semiconductor.
本発明の鉄粉において、前記鉄以外の金属の含有量は、鉄粉全体に対して通常 0 . 01〜50重量%であり、好ましくは 0. 1〜10重量%である。  In the iron powder of the present invention, the content of the metal other than iron is usually 0.01 to 50% by weight, preferably 0.1 to 10% by weight, based on the whole iron powder.
[0051] 成形助剤とは、水分との組み合わせにより、含余剰水発熱組成物の成形性を改善 する成形性改善剤である。  [0051] The molding aid is a moldability improving agent that improves the moldability of the surplus water heating composition in combination with moisture.
[0052] 成形助剤としては、水溶性又は親水性があり、含余剰水発熱組成物の成形性を改 善するものであれば制限はないが、ブドウ糖、果糖、ソルビトール、マルトース、ラクト ース、サッカロース、トレノヽロース、ぺクチン等の糖類、マン-トール、ソノレビトーノレ、マ ルチトール、エリスリトール、キシリトール等の糖アルコール類、トウモロコシデンプン、 コムギデンプン、コメデンプン、コーンスターチ、バレイショデンプン、デキストリン、了 ルファー化デンプン、部分アルファ一化デンプン、ヒドロキシプロピルスターチ、カル ボキシルメチルスターチ、 at—シクロデキストリン、 13—シクロデキストリン、プルラン糖 のデンプン類、結晶セルロース、カルボキシメチルセルロース、ヒドロキシプロピルセ ルロース、低置換度ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロー ス、メチノレセノレロース、カノレボキシメチノレセノレロースナトリウム、カノレメロース、力ノレメロ ースカルシウム、カルメロースナトリウム、クロスカルメロースナトリウム、酢酸ェチルセ ルロース、ヒドロキシメチルセルロース等のセルロース類、ポリビュルピロリドン、ポリビ -ルアルコール、ステアリン酸塩、ポリアクリル酸ナトリウム、寒天、アラビアゴム、アル ギン酸ナトリウム、ゼラチン、コーンシロップ、マンニットシロップ、カラギーナン、トラン トガム、カラャガム、キサンタンガム、ジュランガム、プノレラン、ガードラン、ゼラチン、ァ ルブミン、カゼイン、大豆蛋白質、小麦蛋白質、ァラピノガラクタン、グァガム、ロー力 ストビーンガム、タマリンドシードガム、タラガム、トラガカントゴム、ポリ N ビニノレア セトアミド、アクリル酸 デンプン共重合体、微晶質セルロース、 N—ビュルァセトアミ ド共重合体、ベントナイト、カオリン、珪酸ソーダ、塩ィ匕カルシウム、モンモリロナイト、 珪酸アルミニウム又はポリ酢酸ビュルェマルジヨン等の水分散ェマルジヨン等の単独 又は組み合わせの使用が一例として挙げられる。 [0052] The molding aid is not limited as long as it is water-soluble or hydrophilic and improves the moldability of the excess water heating composition, but glucose, fructose, sorbitol, maltose, lactose are not limited. , Sugars such as sucrose, trenorose, pectin, sugar alcohols such as mannitol, sonorebitol, maltitol, erythritol, xylitol, corn starch, wheat starch, rice starch, corn starch, potato starch, dextrin Starch, partially alpha-ized starch, hydroxypropyl starch, carboxymethyl starch, at-cyclodextrin, 13-cyclodextrin, starch of pullulan sugar, crystalline cellulose, carboxymethylcellulose, hydroxypropylcellulose, low substitution Degrees of cellulose such as hydroxypropylcellulose, hydroxypropylmethylcellulose, methinoresenolellose, canoleboxymethylenoresenolose sodium, canolemellose, strong noremose calcium, carmellose sodium, croscarmellose sodium, ethyl acetate cellulose, hydroxymethylcellulose, etc. , Polybulurpyrrolidone, polyvinyl alcohol, stearate, sodium polyacrylate, agar, gum arabic, sodium alginate, gelatin, corn syrup, mannitol syrup, carrageenan, tran Togam, Kara gum, Xanthan gum, Dulan gum, Punorerin, Guardlan, Gelatin, Albumin, Casein, Soy protein, Wheat protein, Alappinogalactan, Gua gum, Low power Stobing gum, Tamarind seed gum, Tarra gum, Tragacanth gum, Poly-N-vininorea setamide, Acrylic Acid starch copolymer, microcrystalline cellulose, N-bulacetamide copolymer, bentonite, kaolin, sodium silicate, calcium chloride salt, montmorillonite, aluminum silicate or water-dispersed emulsion such as poly (acetate) Or the use of a combination is mentioned as an example.
[0053] 前記骨材としては、充填剤として有用であり、及び Z又は、発熱組成物の多孔質化 に有用であれば制限はない。化石サンゴ (サンゴ化石、風化造礁サンゴ等)、竹炭、 備長炭、シリカ—アルミナ粉、シリカ—マグネシア粉、カオリン、結晶セルロース、コロ ィダルシリカ、軽石、シリカゲル、シリカ粉、マイ力粉、クレー、タルク、合成樹脂の粉 末やペレット、発泡ポリエステル及びポリウレタンのような発泡合成樹脂、藻土、アルミ ナ、繊維素粉末等が一例として挙げられる。 [0053] The aggregate is not limited as long as it is useful as a filler and is useful for making Z or a porous heat-generating composition. Fossil coral (coral fossil, weathered reef coral etc.), bamboo charcoal, Bincho charcoal, silica-alumina powder, silica-magnesia powder, kaolin, crystalline cellulose, colloidal silica, pumice, silica gel, silica powder, my strength powder, clay, talc Examples include powders and pellets of synthetic resins, foamed synthetic resins such as foamed polyester and polyurethane, algae, alumina, and fiber powder.
[0054] 前記離型剤としては、制限はないが、鉱物油、合成油、動植物油等で構成される潤 滑油、グリース、天然ワックス、合成ワックス等の高粘性潤滑油、シリコーンオイル、フ ッ素榭脂、ステアリン酸、ステアリン酸塩類等が一例として挙げられる。  [0054] The release agent is not limited, but is a lubricating oil composed of mineral oil, synthetic oil, animal and vegetable oil, high viscosity lubricating oil such as grease, natural wax, synthetic wax, silicone oil, Examples thereof include silicon rosin, stearic acid, stearates, and the like.
[0055] 前記機能性物質としては、薬効、芳香等の何らかの機能を有して 、れば 、かなるも のでもよい。香料、薬草、ハーブ、漢方薬、経皮吸収性薬物、医薬活性物質、芳香剤 、化粧水、乳液、湿布剤、防カビ剤、抗菌剤、殺菌剤、消臭剤又は脱臭剤、磁気体 等が一例として挙げられる。  [0055] The functional substance may be anything as long as it has some function such as medicinal effect and aroma. Perfumes, herbs, herbs, herbal medicines, transdermal drugs, pharmaceutically active substances, fragrances, lotions, emulsions, poultices, fungicides, antibacterial agents, bactericides, deodorants or deodorants, magnetic substances, etc. As an example.
更に、機能性物質としては、具体的に一例を挙げれば、酸性ムコポリサッカライド、 力ミツレ、カテキン、セィヨウトチノキ、ビタミン E、ニコチン酸誘導体、アルカロイドィ匕合 物等の血行促進剤;セィヨウトチンキ、フラボン誘導体、アントシァ-ジン、ビタミン P、 きんせんか、シラノール、テルミナリア、マユス等のむくみ改善剤;アミノフィリン、茶ェ キス、カフェイン、キサンテン誘導体、イノシット、デキストラン硫酸誘導体、セィヨウト チノキ、エスシン、アントシァ-ジン、有機ヨウ素化合物、オトギリ革、スギナ、マンネン ロウ、朝鮮人参、ヒアルゥ口-ダーゼ等のスリム化剤;インドメタシン、 dl—カンフル、ケ トプロフェン、ショーガエキス、トウガラシエキス、サリチル酸メチル、サリチル酸グリコ ール等の鎮痛剤;ラベンダー、ローズマリー、シトロン、ジェ-パー、ペパーミント、ュ 一カリ、ローズウッド、オレンジ等の香料等が挙げられ、一種以上を用いることができ る。 Furthermore, as specific examples of functional substances, acidic mucopolysaccharides, strength mitsules, catechins, cytobinoids, vitamin E, nicotinic acid derivatives, blood circulation promoters such as alkaloid compounds; , Anthocyanin, vitamin P, kinka, silanol, terminaria, mayus, etc .; aminophylline, tea echex, caffeine, xanthene derivatives, inosit, dextran sulfate derivatives, cinchio chinoki, escin, anthocyanin, organic Slimming agents such as iodine compounds, hyperic leather, horsetail, mannen wax, ginseng, hyalurochi-dase; indomethacin, dl-camphor, ketoprofen, shoga extract, pepper extract, methyl salicylate, glycosalicylate Analgesics such as lavender; fragrances such as lavender, rosemary, citron, jeper, peppermint, eucalyptus, rosewood, orange and the like, and one or more can be used.
[0056] 前記経皮吸収性薬物としては、経皮吸収性のものであれば特に限定されるもので はないが、例えば、皮膚刺激剤、サリチル酸やインドメタシン等の沈痛消炎剤、中枢 神経作用剤 (睡眠鎮静剤、抗てんかん剤、精神神経用剤)、利尿剤、血圧降下剤、 蓮血管拡張剤、鎮咳去疾剤、抗ヒスタミン剤、不整脈用剤、強心剤、副腎皮質ホルモ ン剤、局所麻酔剤等が挙げられる。これら薬剤は、一種又は必要に応じて二種以上 配合されて用いられる。  [0056] The percutaneously absorbable drug is not particularly limited as long as it is percutaneously absorbable, and examples thereof include skin stimulants, analgesic anti-inflammatory agents such as salicylic acid and indomethacin, and central nervous system agents. (Sleep sedatives, antiepileptics, neuropsychiatric agents), diuretics, antihypertensives, lotus vasodilators, antitussives, antihistamines, arrhythmic agents, cardiotonic agents, corticosteroids, local anesthetics, etc. Is mentioned. These drugs are used alone or in combination of two or more as required.
[0057] 本発明の成形性含余剰水発熱組成物の易動水値 (0〜: L00)は、好ましくは 0. 01 以上〜 14未満であり、更に好ましくは 0. 01-13. 5であり、より好ましくは 0. 01〜1 3. 5であり、更【こ好ましく ίま 0. 01〜13であり、更【こ好ましく ίま 0. 01〜12であり、更 に好ましくは 0. 01〜12であり、更に好ましくは 1〜 12であり、更に好ましくは 2〜12 であり、更に好ましくは 2〜: L 1であり、更に好ましくは 3〜: L 1である。 0. 01以下である と成形性が落ち、 14を越えると発熱特性が悪くなる。  The mobile water value (0 to: L00) of the moldable excess water exothermic composition of the present invention is preferably 0.01 or more and less than 14, more preferably 0.01-13.5. Yes, more preferably from 0.01 to 13.5, more preferably from 0.1 to 13, more preferably from 0.1 to 12, and even more preferably from 0. It is 01-12, More preferably, it is 1-12, More preferably, it is 2-12, More preferably, it is 2-: L1, More preferably, it is 3-: L1. If it is less than 0.01, the moldability will deteriorate, and if it exceeds 14, the heat generation characteristics will deteriorate.
[0058] 易動水値とは、発熱組成物中に存在する水分の中で発熱組成物外へ移動できる 余剰水分の量を示す値である。この易動水値にっ 、て説明する。  [0058] The mobile water value is a value indicating the amount of excess water that can move out of the exothermic composition in the water present in the exothermic composition. This easy water value will be explained.
中心点力 放射状に 45度間隔で 8本の線が書かれた No. 2 QIS P 3801 2種) の濾紙を、ステンレス板上に置き、前記濾紙の中心に、内径 20mm X高さ 8mmの中 空円筒状の穴を持つ長さ 150mm X幅 100mmの型板を置き、その中空円筒状の穴 付近に試料を置き、押し込み板を型板上に沿って動かし、試料を押し込みながら中 空円筒状の穴へ入れ、型板面に沿って、試料を擦り切る (型押し込み成形)。  Center point force No. 2 QIS P 3801 (Type 2) with 8 lines radially written at 45 degree intervals) is placed on a stainless steel plate, and the center of the filter paper has an inner diameter of 20 mm and a height of 8 mm. Place a template with a hollow cylindrical hole length 150mm X width 100mm, place a sample near the hollow cylindrical hole, move the push plate along the mold plate, and push the sample into the hollow cylindrical shape Into the hole and scrape the sample along the mold surface (indentation molding).
次に、測定中に発熱反応が起こらないようにするために、前記穴を覆うように非吸 水性の 70 /z mポリエチレンフィルムを置き、更に、その上に、厚さ 5mm X長さ 150m m X幅 150mmのステンレス製平板を置き、 5分間保持する。その後、濾紙を取り出し 、放射状に書かれた線に沿って、水又は水溶液の浸みだし軌跡を中空円筒の穴の 縁である円周部から浸みだし先端までの距離として、 mm単位で読み取る。同様にし て、各線上からその距離を読み取り、合計 8個の値を得る。読み取った 8個の各値 (a , b, c, d, e, f, g, h)を測定水分値とする。その 8個の測定水分値を算術平均したも のをその試料の水分値 (mm)とする。また、真の水分値を測定するための水分量は 内径 20mm X高さ 8mmの前記発熱組成物等の重量に相当する前記発熱組成物等 の配合水分量とし、その水分量に相当する水のみで同様に測定し、同様に算出した ものを真の水分値 (mm)とする。水分値を真の水分値で除したものに 100をかけた 値が易勤水値である。即ち、 Next, in order to prevent an exothermic reaction during the measurement, a non-water-absorbing 70 / zm polyethylene film is placed so as to cover the hole, and further, a thickness of 5 mm X a length of 150 mm X Place a stainless steel plate with a width of 150 mm and hold for 5 minutes. Then, the filter paper is taken out, and the soaking locus of water or aqueous solution is read in mm units as the distance from the circumferential portion that is the edge of the hole of the hollow cylinder to the soaking tip along the radial line. Similarly, the distance is read from each line to obtain a total of 8 values. Each of the 8 values read (a , b, c, d, e, f, g, h) are measured moisture values. The arithmetic mean of the 8 measured moisture values is the moisture value (mm) of the sample. In addition, the moisture content for measuring the true moisture value is the blended moisture content of the exothermic composition or the like corresponding to the weight of the exothermic composition or the like having an inner diameter of 20 mm and a height of 8 mm, and only water corresponding to the moisture content is used. Measure in the same way with, and calculate the same as the true moisture value (mm). The value obtained by dividing the moisture value by the true moisture value and multiplying by 100 is the easy water value. That is,
易動水値 = [水分値 (mm) Z真の水分値 (mm) ] X 100  Easy water value = [moisture value (mm) Z true water value (mm)] X 100
同一試料に対して、 5点測定し、その 5個の易勤水値を平均し、その平均値をその 試料の易勤水値とする。また、発熱体中の発熱組成物の易動水値を測定する場合、 真の水分値を測定する水分量は発熱糸且成物の赤外線水分計による水分量測定から 発熱組成物の含水率を算出し、それを基に、測定に必要な水分量を算出し、前記水 分量により真の水分値を測定算出する。  Measure five points on the same sample, average the five commuting water values, and use the average value as the commuting water value of the sample. In addition, when measuring the mobile water value of the exothermic composition in the heating element, the moisture content for measuring the true moisture value is determined by determining the moisture content of the exothermic composition from the moisture content measurement using an infrared moisture meter for the exothermic yarn and composition. Based on this, the amount of water necessary for measurement is calculated, and the true water value is measured and calculated from the amount of water.
また、易動水値 (0〜: L00)が 0. 01以上〜 14未満、特に 0. 01-13. 5の発熱組成 物は、前記穴を覆うように非吸水性の 70 /z mポリエチレンフィルムを置き、更に、その 上に、厚さ 5mm X長さ 150mm X幅 150mmのステンレス製平板を置く代わりに、風 防を被せた場合は本発明の発熱組成物は測定中に発熱反応が起こり、測定不能に なる。  In addition, the exothermic composition having a mobile water value (0 to: L00) of 0.01 or more and less than 14 and particularly 0.01 to 13.5 is a non-water-absorbing 70 / zm polyethylene film so as to cover the hole. In addition, instead of placing a stainless steel flat plate with a thickness of 5 mm x length 150 mm x width 150 mm on it, the exothermic composition of the present invention undergoes an exothermic reaction during measurement, Measurement becomes impossible.
[0059] 本発明の基材、被覆材支持体、通気調整材等の包装材としては、制限はなぐ例 えば、包材として非通気性素材、通気性素材、吸水性素材、非吸水性素材、非伸長 性素材、伸長性素材、伸縮性素材、非伸縮性素材、発泡素材、非発泡素材、非ヒー トシール性素材、ヒートシール性素材等が一例として挙げられ、フィルム、シート、不 織布、織布等及びそれらの積層体等の所望の形態で、所望の用途により適宜使用 できる。  [0059] Packaging materials such as the base material, the covering material support, and the air conditioning material of the present invention are not limited. For example, the packaging material is a non-breathable material, a breathable material, a water-absorbing material, and a non-water-absorbing material. Examples include non-stretchable materials, stretchable materials, stretchable materials, non-stretchable materials, foamed materials, non-foamed materials, non-heat-sealable materials, heat-sealable materials, etc., films, sheets, nonwoven fabrics, etc. In a desired form such as a woven fabric or a laminate thereof, it can be appropriately used depending on the desired application.
尚、本発明の発熱発熱体に使用される包装材は、従来より開示されている又市販さ れて ヽる又は公知の使 ヽ捨てカイロや発熱体に使用されて ヽる如何なる包装材をも 適宜選択して使用できる。  The packaging material used for the heating element according to the present invention may be any packaging material that has been disclosed in the past or is commercially available, or that is used for a well-known disposable body warmer or heating element. It can be appropriately selected and used.
[0060] 前記通気性フィルムは、例えば、ポリエチレン、ポリプロピレン、ポリフッ化工チレン フィルム等を使用した多孔質フィルムが好適に用いられ、必要通気量に応じて孔径 が定められる。通気量は必要発熱量、温度に応じて、用いる発熱剤に関連して設計 される。 [0060] As the air permeable film, for example, a porous film using polyethylene, polypropylene, a polyfluorinated styrene film, or the like is preferably used, and the pore diameter depends on the required air permeability. Is determined. The ventilation rate is designed according to the heat generation agent used, depending on the required heat generation and temperature.
前記多孔質フィルムとは、メタノールバブリング法による最大孔径が 0. 001〜20 m程度の微細な貫通孔を有するフィルムであり、例えば、合成樹脂フィルムをこ軸延 伸することによって貫通孔を設けたもの、或いは、溶融したポリエチレン、ポリプロピレ ン等に炭酸カルシウム等の無機系微細粉末を分散させた後、フィルム状に押出し、 得られたフィルムを更に延伸させて、貫通孔を設けたもの等である。  The porous film is a film having fine through-holes having a maximum pore diameter of about 0.001 to 20 m by a methanol bubbling method. For example, a through-hole is provided by extending a synthetic resin film. Or an inorganic fine powder such as calcium carbonate dispersed in melted polyethylene, polypropylene, etc., then extruded into a film, and the resulting film is further stretched to provide through holes, etc. .
また、繊維が積層され熱圧着されて通気性を制御された不織布よりなる包装材ゃポ リエチレンフィルム等非通気性素材力 なるフィルムやシートに穿孔により孔を開けた ちのち使用でさる。  In addition, a packaging material made of non-woven fabric with laminated fibers and thermocompression-bonded to control air permeability can be used after perforating holes in a film or sheet having a non-breathable material such as polyethylene film.
[0061] 前記非通気性素材としては、実質的に酸素を透過しな 、素材であれば、制限はな く、ポリエチレン、ポリプロピレン、ポリブタジエン等のポリオレフイン、ポリ塩化ビュル、 ポリ塩ィ匕ビユリデン、ポリエステル、ポリエーテル、ポリスルフォン、ポリアミド等のフィ ルムゃシートやそれらにアルミニウム等の金属や酸化ケィ素や酸化アルミニウムと等 の金属化合物 (金属には半導体も含む)を蒸着やスパッタリング等で積層したフィル ムゃシートやそれらの積層体やアルミニウム等の金属箔ゃ該金属箔を前記フィルム やシートでは挟み積層したものやそれらを使った複合素材が一例として挙げられる。 厚さは制限はないが、 20 μ m〜 lmm程度のものが好ましい。  [0061] The non-breathable material is not limited as long as it does not substantially permeate oxygen. Polyolefin such as polyethylene, polypropylene, and polybutadiene, polychlorinated bur, polysalt vinylidene, polyester Films such as polyethylene, polysulfone, polyamide, etc., and films in which metal compounds such as aluminum and metal oxides such as silicon oxide and aluminum oxide (including metals including semiconductors) are laminated by vapor deposition or sputtering. Examples of the metal foil such as a muya sheet, a laminate thereof, aluminum, and the like, and a laminate of the metal foil sandwiched between the films and sheets and a composite material using them. The thickness is not limited, but is preferably about 20 μm to lmm.
[0062] 固定手段としては、発熱体を所要部に固定できる固定能力を有するものであれば 制限はない。更に、固定手段は取り外しができることが好ましい。前記固定手段とし て一般的に採用されている、粘着剤層、鍵ホック、ホックボタン、マジックテープ (登録 商標)等の面ファスナー、マグネット、バンド、ひも等及びそれらを組み合わせたもの を任意に使用できる。尚、バンドの場合、面ファスナーと粘着剤層との組み合わせで 調整用固定手段を更に構成しても構わない。 [0062] The fixing means is not limited as long as it has a fixing ability capable of fixing the heating element to the required portion. Furthermore, the fixing means is preferably removable. Adhesive layers, key hooks, hook buttons, hook-and-loop fasteners such as Velcro (registered trademark), magnets, bands, strings, etc., and combinations thereof, which are generally used as the fixing means, are arbitrarily used. it can. In the case of a band, the adjustment fixing means may be further constituted by a combination of a hook-and-loop fastener and an adhesive layer.
また、使用されるまでの間の保護としてセパレータを固定手段に付与してもよい。前 記セパレータには背割り等の切り込み等を設けてその剥離が容易となるようにしても よい。  Moreover, you may provide a separator to a fixing means as protection until it is used. The separator may be provided with a cut or the like such as a back split to facilitate its peeling.
尚、本発明の固定手段は、従来より開示されている又市販されている又は公知の 使い捨てカイロや発熱体に使用される固定手段 (含取り外しできる取り付け手段等) を適宜選択して使用できる。 The fixing means of the present invention has been disclosed in the past, is commercially available, or is publicly known. Fixing means (including removable attachment means) used for disposable warmers and heating elements can be selected and used as appropriate.
前記粘着剤層を構成する粘着剤としては、皮膚や衣服に付着するに必要な粘着力 を有するものであれば、制限はなぐ溶剤系、水性系、ェマルジヨン型、ホットメルト型 、反応性、感圧系、或いは、非親水性粘着剤、混合粘着剤、親水性粘着剤 (ジエル 等)等の各種形態が用いられる。  The pressure-sensitive adhesive constituting the pressure-sensitive adhesive layer is not limited as long as it has an adhesive force necessary to adhere to the skin or clothes. Solvent type, aqueous type, emulsion type, hot melt type, reactivity, sensitivity Various forms such as a pressure system, a non-hydrophilic pressure-sensitive adhesive, a mixed pressure-sensitive adhesive, a hydrophilic pressure-sensitive adhesive (Giel etc.) are used.
前記粘着剤層は、保水剤、吸水性ポリマー、 pH調整剤、界面活性剤、有機ケィ素 化合物、疎水性高分子化合物、焦電物質、酸化防止剤、骨材、繊維状物、保湿剤、 機能性物質又はこれらの混合物力 なる付加的な成分力 選ばれた少なくとも 1種を 含有してもよい。例えば、アクリル系、ウレタン系、ゴム系、シリコン系、ポリイソプレン 系、ポリイソブテレン系、スチレン イソプレン スチレン(SIS)系、スチレン イソプ レン系等の粘着剤や親水性ポリマーや水溶性ポリマーを主成分とする親水性粘着剤 してが一例として挙げられる。  The pressure-sensitive adhesive layer includes a water retention agent, a water-absorbing polymer, a pH adjuster, a surfactant, an organic key compound, a hydrophobic polymer compound, a pyroelectric substance, an antioxidant, an aggregate, a fibrous material, a moisturizing agent, Additional ingredients such as functional substance or mixture thereof may contain at least one selected. For example, acrylic, urethane, rubber, silicon, polyisoprene, polyisobutene, styrene isoprene, styrene (SIS), styrene isoprene, etc. One example is a hydrophilic adhesive.
尚、前記粘着剤は、従来より開示されている又市販されている又は公知の使い捨て カイロや発熱体に使用される粘着剤が使用できる。  The pressure-sensitive adhesive may be a pressure-sensitive adhesive that has been disclosed in the past, is commercially available, or is used for known disposable warmers or heating elements.
つぎに、本発明の実施の形態を図面に基づき説明する。  Next, embodiments of the present invention will be described with reference to the drawings.
図 1 (a)は、本発明の発熱体折り畳み装置の一例を示す斜視図である。  FIG. 1 (a) is a perspective view showing an example of the heating element folding device of the present invention.
図 1 (b)は、同平面図である。  Figure 1 (b) is a plan view of the same.
図 1 (c)は、同説明側面断面図である。  FIG. 1 (c) is a side sectional view of the same explanation.
無端状ベルト 12の側方に沿って、折り畳み案内板 2が無端状ベルト 12沿い、やが て覆うようにに取り付けられ、中空ロール 11内と無端状ベルト 12の中央部の下には 固定磁石 50が設けられ、折り畳み案内板 2の始点は、無端状ベルト 12の片側で、表 面が中央ベルトの表面と水平又はより下になるように形成されている。また、折り畳み 案内板 2は後方へ行くに従って外側を次第に持ち上げてはね上げ案内部となり、更 に、内側へ折り曲げて内寄せ案内部となり、更に、折込み案内部となり、折り曲げれ た発熱体の折り畳み部を磁石 50に支持されている部分の上に折り畳むように形成さ れている。  Along the side of the endless belt 12, the folding guide plate 2 is attached so as to cover the endless belt 12 and will eventually be covered, and fixed magnets are provided in the hollow roll 11 and below the center of the endless belt 12. 50, and the starting point of the folding guide plate 2 is formed on one side of the endless belt 12 so that the surface is horizontal or lower than the surface of the central belt. In addition, the folding guide plate 2 gradually lifts the outer side as it goes rearward to become a spring-up guide part, and further bends inward to become an inward guide part. It is formed so as to be folded on a portion supported by the magnet 50.
これらの折り畳み案内板 2は発熱体 33が接触して摺動するので、自己潤滑性があ つて摩擦係数が小さい摺動性のある面を有することが好ましぐ例えば、フッ素系榭 脂等で作るとか表面を被覆するとかすることが望ましい。 These folding guide plates 2 are self-lubricating because the heating element 33 contacts and slides. Therefore, it is preferable to have a slidable surface with a low coefficient of friction, for example, it is desirable to make it with a fluorine-based resin or to coat the surface.
[0064] 次に、動作について説明する。  Next, the operation will be described.
回転する前段ロール 11に卷回された無端状ベルト 12の外周面に積層されて搬送 されてきた発熱体 33は、中空ロール 11内の固定磁石 50により無端状ベルト 12に吸 着され、折り畳み案内板 2と前記無端状ベルト 12に積層され、発熱体の折り畳まれな い部分は無端状ベルト 12の中央部下の固定磁石 50により無端状ベルト 12の表面に 吸着され、支持され、搬送される。折り畳み案内板 2は、表面が無端状ベルト 12の表 面と水平又は下になるようにして始点があり、掬い案内部の先端縁は無端状ベルト 1 2の面に沿うように形成されているので、発熱体 33の先端縁が掬い案内部の始点に くると、発熱体 33の折り畳まれる部分は折り畳み案内板 2上に積層される。  The heating element 33, which is conveyed by being stacked on the outer peripheral surface of the endless belt 12 wound around the rotating preceding roll 11, is adsorbed to the endless belt 12 by the fixed magnet 50 in the hollow roll 11, and is folded and guided. The unfolded portion of the heating element that is laminated on the plate 2 and the endless belt 12 is attracted to the surface of the endless belt 12 by the fixed magnet 50 below the center of the endless belt 12, supported, and transported. The folding guide plate 2 has a starting point so that the surface thereof is horizontal or below the surface of the endless belt 12, and the leading edge of the scooping guide portion is formed along the surface of the endless belt 12. Therefore, when the leading edge of the heating element 33 comes to the starting point of the scooping guide portion, the part where the heating element 33 is folded is stacked on the folding guide plate 2.
また、折り畳み案内板 2は、後方へ行くに従って外側を次第に持ち上げてはね上げ 案内部となり、更に、内側へ折り曲げて内寄せ案内部となるように形成されているの で、発熱体 33が無端状ベルト 12の上に吸着、積層されて搬送されるにともない、発 熱体 33の右側の折り畳み部を、はね上げ案内部が持ち上げ、内寄せ案内部が内側 に折り曲げ、折込み案内部が磁石 50に支持された折り畳まれない部分の上に折り畳 む。折り畳まれた発熱体 33は押さえ板により押さえられ、更に、次工程に搬送される  In addition, the folding guide plate 2 is formed so as to gradually lift the outside as it goes rearward to become a raising guide part, and further bent inward to become an inward guide part, so that the heating element 33 is an endless belt. As it is attracted, stacked and transported on 12, the folding part on the right side of the heating element 33 is lifted by the splashing guide part, the inward guide part is folded inward, and the folding guide part is supported by the magnet 50. Fold it over the unfolded part. The folded heating element 33 is pressed by a pressing plate and further conveyed to the next process.
[0065] 図 2 (a)は、本発明の 3つ折り畳みの発熱体折り畳み装置 1の一例を示す平面図で ある。 FIG. 2 (a) is a plan view showing an example of a three-fold heating element folding device 1 of the present invention.
図 2 (b)は、同説明側面断面図である。  FIG. 2 (b) is a side sectional view of the same explanation.
無端状ベルト 12の右側には、掬い案内部、はね上げ案内部,内寄せ案内部及び 折込み案内部から構成される折り畳み案内板 2が無端状ベルト 12の端部に沿って取 り付けられ、折り畳み案内板 2の始点は、無端状ベルト 12の片側で、表面が中央の 無端状ベルト 12の表面と水平又はより下になるように形成されている。折り畳み案内 板 2が無端状ベルト 12沿い、やがて覆うようにに取り付けられ、中空ロール 11内と無 端状ベルト 12の中央部下には固定磁石 50が設けられ、折り畳み案内板 2は後方へ 行くに従って外側を次第に持ち上げてはね上げ案内部となり、更に、内側へ折り曲 げて内寄せ案内部となり、更に、折込み案内部となり、折り曲げれた発熱体の折り畳 み部を磁石 50に支持されて 、る部分の上に折り畳むように形成されて!、る。 On the right side of the endless belt 12, a folding guide plate 2 composed of a scooping guide portion, a lifting guide portion, an inward guide portion and a folding guide portion is attached along the end portion of the endless belt 12, and folded. The starting point of the guide plate 2 is formed on one side of the endless belt 12 so that the surface is horizontal or lower than the surface of the central endless belt 12. The folding guide plate 2 is attached along the endless belt 12 so as to cover it, and a fixed magnet 50 is provided in the hollow roll 11 and below the center of the endless belt 12, and the folding guide plate 2 is moved backward. Raise the outside gradually to become a guide for raising, and further bend inward It is formed as an inward guide part, and further, a folding guide part, and the folded part of the folded heating element is supported by the magnet 50 and folded on the part!
無端状ベルト 12の左側には、掬い案内部,はね上げ案内部,内寄せ案内部及び 折込み案内部から構成される折り畳み案内板 2が右側と同様に無端状ベルト 12の端 部に沿って取り付けられている。  On the left side of the endless belt 12, a folding guide plate 2 composed of a scooping guide portion, a flip-up guide portion, an inward guide portion and a folding guide portion is attached along the end portion of the endless belt 12 as in the right side. ing.
これらの折り畳み案内板 2は発熱体 33が接触して摺動するので、自己潤滑性があ つて摩擦係数が小さい摺動性のある面を有することが好ましぐ例えば、フッ素系榭 脂等で作るとか表面を被覆するとかすることが望ましい。  Since these folding guide plates 2 slide in contact with the heating element 33, it is preferable to have a slidable surface with a self-lubricating property and a small friction coefficient, such as a fluorine-based resin. It is desirable to make or coat the surface.
次に、動作について説明する。  Next, the operation will be described.
回転する前段ロール 11の無端状ベルト 12の外周面に積層されて搬送されてきた 発熱体 33は、中空ロール 11内の固定磁石 50により無端状ベルト 12に吸着され、折 り畳み案内板 2と前記無端状ベルト 12に積層され、発熱体 33の折り畳まれない部分 は無端状ベルト 12の中央部下の固定磁石 50により無端状ベルト 12の表面に吸着さ れ、支持され、搬送される。  The heating element 33 that has been stacked and conveyed on the outer peripheral surface of the endless belt 12 of the rotating front roll 11 is attracted to the endless belt 12 by the fixed magnet 50 in the hollow roll 11, and is connected to the folding guide plate 2 and The unfolded portion of the heating element 33 that is laminated on the endless belt 12 is attracted to the surface of the endless belt 12 by the fixed magnet 50 below the center of the endless belt 12, supported, and transported.
右側の折り畳み案内板 2は、表面が中央の無端状ベルト 12の表面と水平又は下に なるようにして始点があり、掬 、案内部の先端縁は無端状ベルト 12の面に沿うように 形成されているので、発熱体 33の先端縁が掬い案内部の始点にくると、発熱体の折 り畳まれる部分は折り畳み案内板 2上に積層される。  The folding guide plate 2 on the right side has a starting point so that the surface thereof is horizontal or lower than the surface of the endless belt 12 at the center, and the leading edge of the guide portion is formed along the surface of the endless belt 12. Therefore, when the leading edge of the heating element 33 comes to the starting point of the scooping guide portion, the part where the heating element is folded is stacked on the folding guide plate 2.
また、右側の折り畳み案内板 2は、後方へ行くに従って外側を次第に持ち上げては ね上げ案内部となり、更に、内側へ折り曲げて内寄せ案内部となるように形成されて いるので、発熱体 33が無端状ベルト 112の上に吸着、積層されて搬送されるにとも ない、発熱体 33の右側の折り畳み部を、はね上げ案内部が持ち上げ、内寄せ案内 部が内側に折り曲げ、折込み案内部が磁石 50に支持された折り畳まれない部分の 上に折り畳む。  Further, the folding guide plate 2 on the right side is formed so that the outer side gradually rises as it goes rearward to become a lifting guide part, and further bent inward to become an inward guide part. As it is attracted, stacked and conveyed on the endless belt 112, the folding part on the right side of the heating element 33 is lifted by the splashing guide part, the inward guide part is folded inward, and the folding guide part is magnetized. Fold it over the unfolded part supported by
続いて、左側の折り畳み案内板 2は、発熱体 33の左側の折り畳み部を、はね上げ 案内部が持ち上げ、内寄せ案内部が内側に折り曲げ、折込み案内部が磁石 50に支 持された折り畳まれない部分の上に折り畳む。折り畳まれた発熱体は押さえ板により 押さえられ、更に、次工程に搬送される。はね上げ案内部はこの間隔部力も緩い傾 斜で滑らかに持ち上がるように形成されているので、円滑に、容易に発熱体を掬い上 げることができる。 Subsequently, the left folding guide plate 2 is not folded when the left folding part of the heating element 33 is lifted by the raising guide part, the inward guide part is folded inward, and the folding guide part is supported by the magnet 50. Fold over the part. The folded heating element is pressed by the pressing plate and further conveyed to the next process. The lift-up guide part tilts gently with this spacing force Since it is formed so as to be lifted obliquely and smoothly, the heating element can be lifted up smoothly and easily.
[0067] 図 3 (a)は、本発明の 3つ折り畳みの発熱体折り畳み装置 1の他の一例を示す平面 図である。図 3 (b)は、同説明側面断面図である。  FIG. 3 (a) is a plan view showing another example of the three-fold heating element folding device 1 of the present invention. FIG. 3 (b) is a side sectional view of the same explanation.
本例は無端状ベルト 12を中央と右側ベルトと左側ベルトとに三分割して 、る。中央 の無端状ベルト 12が発熱体 33の折り畳まれない部分を積層、支持し、他の 2本の無 端状ベルト 12はそれぞれ右側の折り畳み案内板 2まで、左側の折り畳み案内板 2ま で、発熱体 33を搬送し、それぞれの折り畳み案内板 2に発熱体 33を積層する。中央 の無端状孔ベルト 12は、幅が発熱体の折り畳まれない部分の幅と同じである。両側 のベルトの幅は、発熱体の折り畳み部を乗せることができる幅があればょ 、。  In this example, the endless belt 12 is divided into a center, a right side belt, and a left side belt. The endless belt 12 in the center stacks and supports the unfolded portion of the heating element 33, and the other two endless belts 12 up to the right folding guide plate 2 and the left folding guide plate 2, respectively. The heating elements 33 are conveyed, and the heating elements 33 are stacked on the respective folding guide plates 2. The endless hole belt 12 at the center has the same width as that of the unfolded portion of the heating element. The width of the belts on both sides should be wide enough to accommodate the folded part of the heating element.
続いて、右側の折り畳み案内板 2が発熱体 33の左側の折り畳み部を、はね上げ案 内部が持ち上げ、内寄せ案内部が内側に折り曲げ、折込み案内部が磁石 50に支持 された折り畳まれない部分の上に折り畳み、更に押さえ板が折り畳まれた発熱体 33 を押える。続いて、左側の折り畳み案内板 2が発熱体 33の左側の折り畳み部を、折り 畳み、更に押さえ板が折り畳まれた発熱体 33を押える。そして、次工程に搬送される はね上げ案内部はこの間隔部力 緩い傾斜で滑らかに持ち上がるように形成され ているので、円滑に、容易に発熱体 33を掬い上げることができる。  Next, the folding guide plate 2 on the right side lifts the folding part on the left side of the heating element 33, the inside of the splash-up plan is raised, the inward guide part is folded inward, and the folding guide part is supported by the magnet 50. Fold the top and press the heating element 33 with the holding plate folded. Subsequently, the left folding guide plate 2 folds the left folded portion of the heating element 33 and further presses the heating element 33 with the holding plate folded. Further, since the raising guide portion to be conveyed to the next process is formed so as to be lifted smoothly with a gentle slope, the heating element 33 can be lifted up smoothly and easily.
[0068] 図 4は、本発明の発熱体折り畳み装置 1のガスノズル 51を設けた他の一例を示す 説明断面図である。 FIG. 4 is an explanatory cross-sectional view showing another example in which the gas nozzle 51 of the heating element folding device 1 of the present invention is provided.
ガスノズル 51の先端は横長スリット状 (例えば、幅約 15mm,開口隙間約 0. 5mm) に形成され、ロール 11の外周面と折り畳み案内板 2との間にガスを噴射するように設 置されて!ヽる。ガスノズル 51は図示しな 、ガス (空気等)供給装置に連結されて ヽる。 図示しな!、ガス供給装置カゝらガスノズル 51に、ガスを供給して噴射させると (例えば、 毎分約 10リットルのガス)、ガスはロール 11の外周面と折り畳み案内板 2との間に入り 、折り畳み案内板 2の先端縁とロール 11の外周面との隙間から噴出し、この噴出する ガスは、この部分に搬送されてくる発熱体 33の折り畳み部を浮き上がらせて、折り畳 み案内板 2の先端縁による掬い上げを円滑にする。 [0069] 図 5 (a)は、本発明の発熱体折り畳み装置 1の他の一例を示す平面図である。 図 5 (b)は、同説明側面断面図である。 The tip of the gas nozzle 51 is formed in a horizontally long slit shape (for example, a width of about 15 mm and an opening gap of about 0.5 mm), and is installed so as to inject gas between the outer peripheral surface of the roll 11 and the folding guide plate 2. ! The gas nozzle 51 is connected to a gas (air etc.) supply device (not shown). Not shown! When gas is supplied to the gas nozzle 51 from the gas supply device and injected (for example, about 10 liters of gas per minute), the gas is placed between the outer peripheral surface of the roll 11 and the folding guide plate 2. Enters the gap between the leading edge of the folding guide plate 2 and the outer peripheral surface of the roll 11, and the gas that is blown up floats the folding part of the heating element 33 conveyed to this part. Smooth the scooping by the leading edge of the guide plate 2. FIG. 5 (a) is a plan view showing another example of the heating element folding device 1 of the present invention. FIG. 5 (b) is a side sectional view of the same description.
本例は図 1に示した例において固定磁石 50を使用せず、押さえ板 8を発熱体 33の 支持手段に使用した例である。押さえ板 7、 8は少なくとも発熱体 33と接触する面に おいて、摺動性に優れた表面を有するもの力、又は、回転自在のロール 10を有する ものが好ましい。  In this example, the fixed magnet 50 is not used in the example shown in FIG. 1, and the pressing plate 8 is used as a support means for the heating element 33. It is preferable that the pressing plates 7 and 8 have a surface having an excellent slidability on at least a surface in contact with the heating element 33 or a plate having a rotatable roll 10.
[0070] 図 6 (a)は、本発明の発熱体折り畳み装置 1の他の一例を示す平面図である。  FIG. 6 (a) is a plan view showing another example of the heating element folding device 1 of the present invention.
図 6 (b)は、同説明側面断面図である。  FIG. 6 (b) is a side sectional view of the same explanation.
本例は図 1に示した例において、押さえ板 7、 8を発熱体 33の支持手段に使用した 例である。押さえ板 7、 8は少なくとも発熱体と接触する面において、摺動性に優れた 表面を有するもの 7か、又は、回転自在のロール 10を有するものが好ましい。固定磁 石 50と押さえ板 7、 8により発熱体 33を支持した一例である。  This example is an example in which the holding plates 7 and 8 are used as a supporting means for the heating element 33 in the example shown in FIG. It is preferable that the pressing plates 7 and 8 have a surface 7 that has excellent slidability at least on the surface in contact with the heating element, or that have a rotatable roll 10. This is an example in which the heating element 33 is supported by the fixed magnet 50 and the holding plates 7 and 8.
[0071] 図 7 (a)は、本発明の発熱体折り畳み装置 1の他の一例を示す斜視図である。 FIG. 7 (a) is a perspective view showing another example of the heating element folding device 1 of the present invention.
折り畳み案内台 3が曲面ではなぐほぼ垂直な面を始点とし、回転自在のロール 10 を有し、回転自在のロール 10が発熱体 33の折り畳まれな 、部分を支持して 、る。 入り側は断面形状が曲面形状出なぐほぼ垂直な面をして 、るが進行方向に移る に従い、曲面状に曲がり、更に進行に従い、扁平形状に連続的に変化する形状を有 した折り畳み案内台 3である。折り畳み案内手段である折り畳み案内板 2の包装材 41 と接触する側と反対側 (外側)の面に磁石 50が設けられ、折り畳みの際に、発熱体 3 3の折り畳まれる側を磁力で、包装材へ押しつけながら発熱体 33を折り畳む。  The folding guide 3 has a rotatable roll 10 starting from a substantially vertical plane that is not curved, and the rotatable roll 10 supports a portion of the heating element 33 that is not folded. The entrance side has a substantially vertical surface with a curved cross-sectional shape, but as it moves in the direction of travel, it bends into a curved surface, and further, as it progresses, it has a shape that continuously changes to a flat shape. 3. A magnet 50 is provided on the opposite side (outside) of the folding guide plate 2 that is the folding guide means 2 that contacts the packaging material 41, and the side on which the heating element 33 is folded is folded with a magnetic force during folding. Fold the heating element 33 while pressing it against the material.
折り畳み案内手段の外側の面に設けられる磁石 50は、掬い案内、はね上げ案内、 内寄せ案内及び折込み案内の機能に沿って設けられることが好ましい。  The magnet 50 provided on the outer surface of the folding guide means is preferably provided along the functions of scooping guide, flip-up guide, inward guide and folding guide.
折り畳み案内台 3の、発熱体 33の折り畳まない部分と接触する下面部には、複数 の回転自在のロール 10が設けられて!/、る。  A plurality of rotatable rolls 10 are provided on the lower surface of the folding guide 3 that contacts the unfolded portion of the heating element 33! /.
また、本発明の折り畳み案内板 2の発熱体 33の折り畳まれる進行路に沿って磁石 を設けてもよい。磁石は折り畳み案内板 2の外面でも、中空の折り畳み案内板 2の内 側、又は内壁に設けてよい。又外面に設ける場合は、外面に埋め込むことが好ましい 。 発熱体本体の折り畳まれない部分を支持する折り畳み案内台の下側に回転自在 のロールやボール等を設けてもょ 、。折り畳まれた発熱体や包装材が移動するの抵 抗がないようにしてもよい。磁石は、磁力を有するものであればよぐ電磁石や永久磁 石が一例として挙げられる。 Further, a magnet may be provided along the traveling path in which the heating element 33 of the folding guide plate 2 of the present invention is folded. The magnet may be provided on the inner surface of the hollow folding guide plate 2 or on the inner wall of the outer side of the folding guide plate 2. If it is provided on the outer surface, it is preferably embedded in the outer surface. Rotates under the folding guide stand that supports the unfolded part of the heating element body Let's set up rolls and balls. There may be no resistance to movement of the folded heating element or packaging material. Examples of magnets that can be used are magnets and permanent magnets as long as they have a magnetic force.
図 7 (b)は、曲面ではなぐほぼ垂直な面を始点とし、回転自在のロール 10を有す る折り畳み案内台 3の他の一例を示す斜視図である。  FIG. 7B is a perspective view showing another example of the folding guide base 3 having a rotatable roll 10 starting from a substantially vertical surface that is not a curved surface.
図 7 (c)は、本発明の曲面ではなぐほぼ垂直な面を始点とし、回転自在のロール 1 0を有する折り畳み案内台 3と折り畳み案内板 2と無端状ベルト 12とより、発熱体 33を 折り畳んで!/、る状態を示す断面図である。  In FIG. 7 (c), the heating element 33 is composed of a folding guide base 3, a folding guide plate 2 and an endless belt 12 having a rotatable roll 10 starting from a substantially vertical plane that is not a curved surface of the present invention. FIG. 4 is a cross-sectional view showing a folded state.
[0072] 図 8 (a)は、本発明の発熱体折り畳み装置 1の他の一例を示す平面図である。 FIG. 8 (a) is a plan view showing another example of the heating element folding device 1 of the present invention.
図 2と同型の発熱体折り畳み装置 1に、入り側が曲面状の面を有する折り畳み案内 台 3を設けた発熱体折り畳み装置 1である。  The heating element folding apparatus 1 is provided with a folding guide base 3 having a curved surface on the entrance side in the heating element folding apparatus 1 of the same type as in FIG.
図 8 (b)は、本発明の折り畳み案内台 3の他の一例を示す斜視図である。 入り側は断面形状が円、楕円等の曲面形状をして 、るが進行方向に移るに従 、扁 平形状に連続的に変化する形状を有した折り畳み案内台 3である。更に、発熱体 33 の折り畳まない部分と接触する下面部には、複数の回転自在のロール 10が設けられ ている。  FIG. 8 (b) is a perspective view showing another example of the folding guide base 3 of the present invention. The entrance side is a folding guide 3 having a curved surface shape such as a circle or an ellipse, and a shape that continuously changes to a flat shape as it moves in the traveling direction. Further, a plurality of rotatable rolls 10 are provided on the lower surface portion of the heating element 33 that contacts the unfolded portion.
図 8 (c)は、本発明の折り畳み案内台 3を示の一例を示す斜視図である。 入り側は断面形状が円、楕円等の曲面形状をして 、るが進行方向に移るに従 、扁 平形状に連続的に変化する形状を有した折り畳み案内台 3である。  FIG. 8 (c) is a perspective view showing an example of the folding guide base 3 of the present invention. The entrance side is a folding guide 3 having a curved surface shape such as a circle or an ellipse, and a shape that continuously changes to a flat shape as it moves in the traveling direction.
発熱体の折り畳まない部分と接触する下面部は、摺動性の優れた面担っている。  The lower surface portion in contact with the unfolded portion of the heating element has a surface with excellent slidability.
[0073] 図 9 (a)〜 (j)は、本発明の発熱体折り畳み装置 1の折り畳みの一例を示す正面断 面図である。 [0073] FIGS. 9A to 9J are front sectional views showing an example of folding of the heating element folding device 1 according to the present invention.
畳み案内板 2と折り畳み案内台 3と無端状ベルト 12により、搬送方向に搬送された 発熱体 33は搬送に従って発熱体の両側部は畳み案内板 2と相対摺動し、徐々に立 ち上げられ折り返されてゆく。  The heating element 33 conveyed in the conveying direction by the folding guide plate 2, the folding guide base 3 and the endless belt 12 is gradually lifted up as the both sides of the heating element slide relative to the folding guide plate 2 as it is conveyed. It will be folded.
模式的に示すと図 7に示したようになる。即ち、図 9 (a)〜(d)は発熱体 33の右側を 折り畳み、図 9 (e)〜 (h)は発熱体の左側を折り畳む。  Figure 7 shows a schematic diagram. 9A to 9D fold the right side of the heating element 33, and FIGS. 9E to 9H fold the left side of the heating element.
図 9 (i)は押さえ板 7で、 3つに折り畳まれた発熱体 33を押さえる。 図 9 (j)は無端状ベルト 12上に積層された 3つに折り畳まれた発熱体 33を示す。 まず右側の折り畳み案内板 2と折り畳み案内台 3とによって先に折曲され(図 9 (a) 〜(d) )、続いて左側の折り畳み案内板 2と折り畳み案内台 3とによって先に折曲した 部分の上に重なるように折曲され(図 9 (e)〜(! 1) )、三つ折り状態となる。 Fig. 9 (i) shows the holding plate 7 that holds the heating element 33 folded in three. FIG. 9 (j) shows the heating element 33 folded on three laminated on the endless belt 12. First, it is bent first by the right folding guide plate 2 and the folding guide stand 3 (Fig. 9 (a) to (d)), and then it is bent first by the left folding guide plate 2 and the folding guide stand 3. It is folded so that it overlaps with the part (Fig. 9 (e) to (! 1)), and it is folded in three.
搬送手段の後段部において、上記三つ折り状態で折り畳み案内板 2と折り畳み案 内台 3から抜けるとともに、押さえ板 7に挟まれ押さえられながら更に搬送され、排出 される。押さえ板 7では、弾力的に及び Z又は一定間隔を保持して押圧されるので、 折り畳まれて平らになった状態を得ることができるとともに、開くことの容易性も得られ る。押さえ板 7の代わりに枠組み押さえロール板 8を使用してもよ 、。  At the rear stage of the transport means, the folding guide plate 2 and the folding plan inner base 3 are removed in the above-described three-fold state, and are further transported and discharged while being sandwiched and pressed by the pressing plate 7. Since the pressing plate 7 is pressed elastically and with a Z or constant interval, it can be folded and flattened, and can be easily opened. Instead of the press plate 7, a frame press roll plate 8 may be used.
[0074] 図 10は、本発明の発熱体折り畳み装置 1の他の一例を示し、 (a)は斜視図、 (b)は 折り畳み案内台 4の斜視図、(c)は折り畳み案内台 4の側面図、(c)は折り畳み案内 台 4の平面図である。 FIG. 10 shows another example of the heating element folding device 1 according to the present invention. (A) is a perspective view, (b) is a perspective view of the folding guide base 4, and (c) is a view of the folding guide base 4. A side view, (c) is a plan view of the folding guide 4.
図 10 (a)は、 2つ折り畳み型の発熱体折り畳み装置 1であり、入り側が曲面状の面 を有する折り畳み案内台 4を設けた発熱体折り畳み装置 1である。  FIG. 10 (a) is a two-fold type heating element folding apparatus 1, which is a heating element folding apparatus 1 provided with a folding guide base 4 having a curved surface on the entrance side.
図 10 (b)は、本発明の折り畳み案内台 4の他の一例を示す斜視図である。 入り側は断面形状が円、楕円等の曲面形状をして 、るが進行方向に移るに従 、扁 平形状に連続的に変化する形状を有した折り畳み案内台 4である。即ち、少なくとも 円の曲面形状、楕円の曲面形状を経て扁平形状になる形状を有する折り畳み案内 台である。更に、発熱体 33の折り畳まない部分と接触する下面部には、複数の回転 自在のロール 10が設けられて!/、る。  FIG. 10 (b) is a perspective view showing another example of the folding guide base 4 of the present invention. The entrance side is a folding guide base 4 having a curved surface shape such as a circle or an ellipse, and a shape that continuously changes to a flat shape as it moves in the traveling direction. That is, it is a folding guide base having a shape that is flattened through at least a circular curved surface shape and an elliptical curved surface shape. In addition, a plurality of rotatable rolls 10 are provided on the lower surface of the heating element 33 that contacts the unfolded portion!
図 10 (c)は、同側面図である。図 10 (d)は、平面図である。  Figure 10 (c) is a side view of the same. Figure 10 (d) is a plan view.
[0075] 図 11 (a)、(b)本発明の発熱体折り畳み装置 1の自動供給装置 21の一例を示す断 面図である。 [0075] Figs. 11 (a) and (b) are sectional views showing an example of the automatic supply device 21 of the heating element folding device 1 of the present invention.
図 11 (a)は、折り畳み処理前の発熱体を自動的に供給するための自動供給装置 2 1を取り付けた状態を示している。この自動供給装置 21は、発熱体 33を積層して収 容する収容部 20を設け、前記収容部 20の底部に、押出し手段を設けて構成してい る。  FIG. 11 (a) shows a state in which an automatic supply device 21 for automatically supplying the heating element before the folding process is attached. The automatic supply device 21 is configured by providing a housing portion 20 in which the heating elements 33 are stacked and accommodated, and an extrusion means is provided at the bottom of the housing portion 20.
[0076] 収容部 20の前面に発熱体 33を一枚抜き出せる隙間を形成している。底板 22の後 部は切欠いて、この切欠部に前記押出し手段 13を備えている。押出し手段 13は、押 出し凸部を外周面に有した無端状ベルト 12で構成し、この押出し手段 13を駆動する 駆動モータは、一回の駆動で所定量回転するステップモータ等で構成する。つまり 押出し凸部を一番下の発熱体 33に引っ掛力る位置から、その押出し凸部がその対 角線上の位置まで移動するようにして、 1つ以上の押出し凸部で、発熱体 33の押し 出しを形成して 、る。押し出し凸部は磁石 (押し出し磁石) 50でもよ 、。 A gap is formed in the front surface of the housing portion 20 so that one heating element 33 can be extracted. After bottom plate 22 The part is notched, and the pushing means 13 is provided in the notch. The extruding means 13 is constituted by an endless belt 12 having an extruding convex portion on the outer peripheral surface, and the drive motor for driving the extruding means 13 is constituted by a step motor or the like that rotates a predetermined amount by one drive. That is, one or more extruding protrusions are used to move the extruding convex portion from the position where the extruding convex portion is hooked to the lowermost heating element 33 to the diagonal position. Form an extrusion of The extruding convex part may be a magnet (extruding magnet) 50.
[0077] 駆動モータの駆動は、図示しないが、折り畳み装置 1の折り畳み手段の入り側ある 入り口に設けた投光器と受光器力 なる光電センサの検知により行う。即ち光電セン サでは搬送手段に設けられた目印が、折り畳み装置 1の折り畳み手段の入り側ある 入り口に対応する位置を通過することを検知して、この検知倍号により駆動モータの 駆動が行われるようにする。  [0077] Although not shown, the drive motor is driven by detection of a light projector provided at the entrance on the entry side of the folding means of the folding device 1 and a photoelectric sensor serving as a light receiver. That is, in the photoelectric sensor, it is detected that the mark provided on the transport means passes through a position corresponding to the entrance on the folding side of the folding device 1, and the drive motor is driven by this detection multiple. Like that.
[0078] 駆動モータが駆動して発熱体 33が押し出されると、発熱体 33は搬送手段へ移動し 、折り畳みがなされる。すべてが同調して駆動されており、このように構成すると、発 熱体 33の供給が自動的に行えるので、折り畳み処理の完全な自動化を図ることがで きる。  When the drive motor is driven and the heating element 33 is pushed out, the heating element 33 moves to the conveying means and is folded. All are driven in synchronism, and with this configuration, the heating element 33 can be automatically supplied, so that the folding process can be completely automated.
[0079] 図 12本発明の発熱体折り畳み装置 1の折り畳みの一例を示し、図 12 (a)、(d)、(g )は平面図、図 12 (b)ゝ (c)、(e)、(f)は説明断面図である。  [0079] Fig. 12 shows an example of folding of the heating element folding device 1 of the present invention. Figs. 12 (a), (d), and (g) are plan views, and Fig. 12 (b) ゝ (c), (e) (F) is explanatory sectional drawing.
本例の発熱体折り畳み装置 1は、折り畳み無端状ベルト 24による発熱体折り畳み 装置 1であり、発熱体 33のみを投入すれば、発熱体 33を折り畳む発熱体折り畳み装 置 1であり、発熱体 33を積層した包装材 41を投入すれば、包装材 41を発熱体 33と 共に折り畳む発熱体折り畳み装置 1になる。  The heating element folding apparatus 1 in this example is the heating element folding apparatus 1 using the folding endless belt 24. If only the heating element 33 is inserted, the heating element folding apparatus 1 is configured to fold the heating element 33. If the packaging material 41 laminated with is put in, the heating element folding device 1 for folding the packaging material 41 together with the heating element 33 is obtained.
次に、折り畳み無端状ベルト 24による発熱体 33の折り曲げ工程について説明する 図 12 (a)〜 (c)は、折り畳まれて 、な 、発熱体 33が搬送されてくる"入り口 "から"折 り畳み完了"間での工程を示す図である。  Next, the folding process of the heating element 33 by the folding endless belt 24 will be described. FIGS. 12A to 12C are folded from the “entrance” where the heating element 33 is conveyed. It is a figure which shows the process between "folding completion".
図 12 (c!)〜 (f)は、折り畳まれた発熱体 33の方向転換の工程を示す図である。 図 12 (h)は、入り口力も方向転換後までの工程を示す平面図である。  12 (c!) To (f) are diagrams showing a process of changing the direction of the folded heating element 33. FIG. FIG. 12 (h) is a plan view showing the process until the entrance force also changes direction.
[0080] 図 12 (a)に示すように、製造ラインの進行方向 Eに向力つて、一対の無端状ベルト 2 4が対向するようにして配置されている。この両無端状ベルト 24は、進行方法の上流 力も下流に向力つて漸次水平力も垂直になるように捻った状態で位置付けられてい る。即ち、無端状ベルト 24が両側力も起き上がるようにして 90° 捻られているので、 この両無端状ベルト 24上を搬送される発熱体 33は、両側から折り畳まれるようになる [0080] As shown in FIG. 12 (a), a pair of endless belts 2 are applied in the direction of travel E of the production line. 4 are arranged so as to face each other. Both endless belts 24 are positioned in a state where they are twisted so that the upstream force in the traveling method and the downstream force are gradually directed and the horizontal force gradually becomes vertical. That is, since the endless belt 24 is twisted by 90 ° so that both side forces also rise, the heating element 33 conveyed on the both endless belts 24 can be folded from both sides.
[0081] 即ち、折り畳みの入り口においては、無端状ベルト 24の下にロール 11が配され、 無端状ベルト 24の下にロール 11が配されている。そして、折り畳み完了後の出口に おいては、入り口における状態と比較して両無端状ベルトが 90° になるように捻られ ているので、入り口側の一対のロールも折り畳み完了後の出口側の一対のロール 11 に対して直角となるように配されて 、る。無端状ベルト 24の上を流れる発熱体 33は、 図 12 (b) (c)に示されるように、発熱体 33及び包装材 41上に積層された発熱体 33 1S それぞれ、徐々に 2つ折り状態となっていく。以上のような構成となっていることか ら、当前記工程が終了するまでの間に、入り口側の一対のロール 11、出口側の一対 のロール 11と、捻られた無端状ベルト 24とにより、発熱体 33が、一体的に折り畳まれ る。 That is, at the folding entrance, the roll 11 is disposed under the endless belt 24, and the roll 11 is disposed under the endless belt 24. At the exit after the folding is completed, both endless belts are twisted at 90 ° compared to the state at the entrance, so the pair of rolls on the entrance side is also on the exit side after the folding is completed. It is arranged so as to be perpendicular to the pair of rolls 11. As shown in FIGS. 12 (b) and 12 (c), the heating element 33 flowing on the endless belt 24 is gradually folded into two, each of the heating element 33 and the heating element 33 1S laminated on the packaging material 41. It will become. Due to the above-described configuration, the pair of rolls 11 on the entrance side, the pair of rolls 11 on the exit side, and the twisted endless belt 24 are used until the process is completed. The heating element 33 is folded together.
[0082] 図 12 (d)に示すような工程を経ることにより、前記折り畳まれた発熱体は、図 12 (e)  [0082] Through the process shown in Fig. 12 (d), the folded heating element is transformed into Fig. 12 (e).
(f)に示すように、発熱体 33及び包装材 41上に積層された発熱体 33が、それぞれ、 徐々に水平方向に向きを変えられる。そして、一対のロールにより次工程へと搬送さ れる。  As shown in (f), the heating element 33 and the heating element 33 laminated on the packaging material 41 can be gradually changed in the horizontal direction. And it is conveyed to the next process by a pair of rolls.
[0083] 尚、包装材に積層した発熱体 33の場合、このような方向転換工程を設けずに、図 1 2 (g)に示すように、シール装置 31を垂直方向に配置して発熱体を垂直状態のまま にし、包装材をシールし、シールされた個々の発熱体 33を 90° に捻られた一対の無 端状ベルト 24に挟んで搬送することにより、封入された発熱体を水平方向にすること も可能である。  In the case of the heating element 33 laminated on the packaging material, without providing such a direction changing step, the heating element 33 is arranged in the vertical direction as shown in FIG. 12 (g). Is kept in a vertical state, the packaging material is sealed, and each sealed heating element 33 is sandwiched between a pair of endless belts 24 twisted at 90 ° to be transported horizontally. It is also possible to set the direction.
[0084] 図 13は本発明の発熱体折り畳み装置 1の他の一例を示す斜視図である。  FIG. 13 is a perspective view showing another example of the heating element folding device 1 of the present invention.
押さえロールに支持された発熱体 33を積層した包装材 41が折り畳み案内台 3に発 熱体 33を押しつけながら、折り畳み案内台 3に沿って、進行し、下流に設けられた押 さえ板 7、 8により、包装材 41を折り畳み、折り畳まれない部分へ押さえることにより、 発熱体 33を折り畳む。 The packaging material 41 in which the heating elements 33 supported by the holding rolls are laminated presses the heating element 33 against the folding guide base 3 and advances along the folding guide base 3, and the pressing plate 7 provided downstream is provided. 8 by folding the packaging material 41 and holding it on the unfolded part, Fold the heating element 33.
折り畳み案内台 3が曲面を有し、円形又は楕円形の曲面を始点とし、回転自在の口 ール 10を有し、回転自在のロール 10が発熱体 33の折り畳まれない部分を支持して いる。発熱体が折り畳まれる前に発熱体の一部と包装シートの一部は弱粘着剤によ り外仮着 59されている。  The folding guide base 3 has a curved surface, starts from a circular or elliptical curved surface, has a rotatable tool 10, and the rotatable roll 10 supports the unfolded portion of the heating element 33. . Before the heating element is folded, part of the heating element and part of the packaging sheet are temporarily attached 59 with a weak adhesive.
入り側は断面形状が円形又は楕円形の曲面形状であり、進行方向に移るに従 、、 曲面状に曲がり、更に進行に従い、扁平形状に連続的に変化する形状を有した折り 畳み案内台 3である。発熱体 33の折り畳まない部分と接触する下面部には、複数の 回転自在のロールが設けられて 、る。  The entrance side is a curved guide shape with a circular or elliptical cross-sectional shape. The folding guide stand has a shape that bends into a curved shape as it moves in the direction of travel, and further changes into a flat shape as it progresses. It is. A plurality of rotatable rolls are provided on the lower surface of the heating element 33 that contacts the unfolded portion.
[0085] 図 14は、本発明の発熱体折り畳み装置 1の他の一例を示す斜視図である。 FIG. 14 is a perspective view showing another example of the heating element folding device 1 of the present invention.
押さえロール 11Aに支持された発熱体 33を積層した包装材 41が折り畳み案内台 3 に発熱体 33を押しつけながら、折り畳み案内台 3に沿って、進行し、下流に設けられ た押さえ板 7 (枠組み押さえロール板 8)により、包装材 41を折り畳み、折り畳まれない 部分へ押さえることにより、発熱体 33を折り畳む。発熱体が折り畳まれる前に発熱体 の一部と包装シートの一部は弱粘着剤により外仮着 59されている。  The wrapping material 41 in which the heating element 33 supported by the holding roll 11A is laminated presses the heating element 33 against the folding guide 3 and advances along the folding guide 3, and the holding plate 7 (framework provided downstream). The heating element 33 is folded by folding the packaging material 41 with the pressing roll plate 8) and pressing it to the unfolded portion. Before the heating element is folded, a part of the heating element and a part of the packaging sheet are temporarily attached 59 with a weak adhesive.
折り畳み案内台 3が曲面ではなぐほぼ垂直な面を始点とし、回転自在のロールを 有し、回転自在のロール 10が発熱体 33の折り畳まれな 、部分を支持して 、る。 入り側は断面形状が曲面形状出なぐほぼ垂直な面をして 、るが進行方向に移る に従い、曲面状に曲がり、更に進行に従い、扁平形状に連続的に変化する形状を有 した折り畳み案内台 3である。発熱体 33の折り畳まない部分と接触する下面部には、 複数の回転自在のロール 10がが設けられて!/、る。  The folding guide base 3 has a substantially vertical surface that is not a curved surface, has a rotatable roll, and the rotatable roll 10 supports a portion of the heating element 33 that is not folded. The entrance side has a substantially vertical surface with a curved cross-sectional shape, but as it moves in the direction of travel, it bends into a curved surface, and further, as it progresses, it has a shape that continuously changes to a flat shape. 3. A plurality of rotatable rolls 10 are provided on the lower surface portion of the heating element 33 that contacts the unfolded part!
[0086] 図 15は、発熱体 33が 3列に包装材 41上に積層され搬送され、枠組み押さえロー ル板 8に押さえられながら、スリットされ、一列毎に発熱体 33が折り畳まれる本発明の 発熱体折り畳み装置 1の他の一例を示す平面図である。図 15に示すように、スリット カットロール 53と折り畳み手段力もなる。 [0086] FIG. 15 shows the heating element 33 in which the heating elements 33 are stacked and transported in three rows on the packaging material 41, are slit while being held by the frame holding roll plate 8, and the heating elements 33 are folded for each row. 6 is a plan view showing another example of the heating element folding device 1. FIG. As shown in FIG. 15, the slit cutting roll 53 and the folding means force are also provided.
[0087] スリットカットロール 53は、並列方向に発熱体の複数個(3個)分が繋がった状態と なっている幅広状の包装材 41を、並列方向 1個分ずっとなるように搬送方向にカット するもので、発熱体本体装着装置 1の下流側に配置され、包装材 41上の一部に、発 熱体 33が積層されている。 [0087] The slit cut roll 53 has a wide packaging material 41 in a state in which a plurality (three) of heating elements are connected in the parallel direction in the conveying direction so as to be continuously one in the parallel direction. It is to be cut and is arranged on the downstream side of the heating element body mounting device 1. The heat element 33 is laminated.
[0088] スリットカットロール 53は、包装材 41を幅方向に 3等分する軸方向位置に周方向の 切り刃を備えており、包装材は、この切り刃により、並列方向に装着された 3個の発熱 体 33の間の夫々中央で搬送方向に連続的にカットされる。  [0088] The slit cut roll 53 is provided with a circumferential cutting blade at an axial position that divides the packaging material 41 into three equal parts in the width direction, and the packaging material is mounted in the parallel direction by the cutting blade 3 Each of the heating elements 33 is continuously cut in the transport direction at the center.
[0089] 折り畳み装置 1は、スリットカットロール 53により搬送方向にカットされて発熱体 1個 分ずつの複数本 (3本)の列状となった包装材 41を、その上に積層された発熱体 33 と共にその発熱体 33の中間シール部に沿って幅方向 2つ折り状に折り畳むもので、 枠組み押さえロール板 8、無端状ベルト 12、折り畳み案内台 3、折り畳み案内板 2、 押さえ板 7を備え、包装材 41が、折り畳み案内板 2を兼ねている。  [0089] The folding device 1 is a heat generating device in which a plurality of (three) packaging materials 41, each of which is cut in the conveying direction by a slit cut roll 53, are stacked on top of each other. Folding body 33 together with the intermediate seal part of the heating element 33 in the width direction is folded in two, and includes a frame pressing roll plate 8, an endless belt 12, a folding guide base 3, a folding guide plate 2, and a pressing plate 7. The packaging material 41 also serves as the folding guide plate 2.
[0090] 無端状ベルト 12は、スリットカットロール 53で搬送方向にカットされた発熱体 33積 層済みの包装材 41を、押さえロール 11A、折り畳み案内台 3、押さえ板 7を経てプレ スロールまで搬送するもので、包装材 41の外面側 (発熱体本体が積層されて ヽな ヽ 側)、即ち、包装材 41の下側に沿って配置されている。尚、無端状ベルト 12は、並列 方向の複数本 (3本)の包装材 41に沿って配置してもよいし、それら複数本の包装材 41に夫々対応するように複数本並列に配置してもよ!/ヽ。  [0090] The endless belt 12 conveys the heating element 33 cut in the conveyance direction by the slit cut roll 53 to the stacked roll of the packaging material 41 to the press roll through the press roll 11A, the folding guide stand 3, and the press plate 7. Therefore, it is arranged along the outer surface side of the packaging material 41 (the side on which the heating element body is laminated), that is, along the lower side of the packaging material 41. The endless belt 12 may be arranged along a plurality (three) of the packaging materials 41 in the parallel direction, or a plurality of endless belts 12 may be arranged in parallel so as to correspond to the plurality of packaging materials 41, respectively. Anyway!
[0091] 押さえロール 11Aは、発熱体 33の両端部より外側の包装シート 41を押さえ、折り畳 み案内板 2、折り畳み案台 3へ発熱体 33と包装シート 41を供給する。  The holding roll 11A presses the packaging sheet 41 outside the both ends of the heating element 33, and supplies the heating element 33 and the packaging sheet 41 to the folding guide plate 2 and the folding plan base 3.
[0092] 折り畳み案内台 3は、長い形状に形成され、発熱体 33及び包装材 41の折り畳み半 面(固定半面と反対側の半面)を、折り畳み案内台 3に押しつけるようにして、固定半 面側に重ね合わせるように案内するもので、搬送方向に、掬い案内、はね下げ案内 、内寄せ案内及び折込み案内から構成される機能面を受け取る機能を有し、発熱体 33を包装材 41と共同して折り畳む。  [0092] The folding guide stand 3 is formed in a long shape, and the folding half of the heating element 33 and the packaging material 41 (the half opposite to the fixed half face) is pressed against the folding guide stand 3 so that the fixed half It has a function of receiving a functional surface composed of scooping guide, splash-down guide, inward guide and folding guide in the conveying direction, and the heating element 33 is connected to the packaging material 41. Fold together.
本発明の折り畳み案内台 3の発熱体 33の折り畳まれる進行路に沿って磁石 50を 設けてもよい。磁石 50は折り畳み案内台 3の外面でも、中空の折り畳み案内台 3の内 側、又は内壁に設けてよい。又外面に設ける場合は、外面に埋め込むことが好ましい 発熱体 33の折り畳まれない部分を支持する折り畳み案内台 3の下側に回転自在の ロールやボール 10等を設けてもよい。折り畳まれた発熱体 33や包装材 41が移動す るの抵抗がないようにしてもよい。磁石 50は、磁力を有するものであればよぐ電磁石 や永久磁石が一例として挙げられる。 The magnet 50 may be provided along the traveling path where the heating element 33 of the folding guide base 3 of the present invention is folded. The magnet 50 may be provided on the outer surface of the folding guide base 3, on the inner side of the hollow folding guide base 3, or on the inner wall. When provided on the outer surface, it is preferably embedded in the outer surface. A rotatable roll, a ball 10 or the like may be provided below the folding guide base 3 that supports the unfolded portion of the heating element 33. Folded heating element 33 and packaging material 41 move There may be no resistance. The magnet 50 may be an electromagnet or a permanent magnet as long as it has a magnetic force.
[0093] 発熱体 33積層済みの包装材 41は、押さえロール 11Aの下流側で、折り畳み半面 を発熱体 33が内側となるように固定半面側に折り重ねた状態で、無端状ベルト 12と 押さえ板 7、 8との間に揷通され、更に押さえ板 7、 8の下流側のプレスロールにより下 流側に搬送される。 [0093] The heating element 33 is laminated with the endless belt 12 in the state where the folded half surface is folded on the fixed half surface side so that the heating element 33 is on the downstream side of the pressing roll 11A. It is passed between the plates 7 and 8 and further conveyed downstream by a press roll on the downstream side of the press plates 7 and 8.
[0094] 押さえ板 7は、発熱体 33積層済みの包装材 41を覆いながら、折り畳み案内台 3と 包装材 14を補助し内寄せ案内及び折込み案内を行い、折り畳みが完了する。  [0094] While holding the heating element 33 and the laminated packaging material 41, the holding plate 7 assists the folding guide base 3 and the packaging material 14 to perform inward guide and folding guidance, and the folding is completed.
[0095] プレスロールは、折り畳み案内台 3と包装材 41と押さえ板で 2つ折り状態に折り畳ま れた発熱体 33積層済みの包装材 41を、その上流側に一定のテンションを付与しつ つ下流側に搬送するもので、上下一対のロールを備えている。プレスロールは包装 材を上流側に一定のテンションを付与しつつ下流側に搬送できれば制限はなく、空 気を内蔵したバルーンロール、発熱体 33部分に部分を抜いた凹部付きロール、包装 材 41の両端部を挟んだ両端部挟みロール等が一例として挙げられる。又ロールの代 わりに上下一対の無端状ベルト 12を使用してもよい。  [0095] The press roll consists of a folding guide base 3, a packaging material 41, and a heating element folded in a folded state by a holding plate 33. The laminated packaging material 41 is provided with a certain tension on the upstream side and downstream. It conveys to the side and is provided with a pair of upper and lower rolls. The press roll is not limited as long as the packaging material can be conveyed downstream while applying a certain tension to the upstream side, a balloon roll with a built-in air, a heating roller 33 part with a recessed part, and a packaging material 41 An example of both end sandwiching rolls sandwiching both end portions is given. A pair of upper and lower endless belts 12 may be used instead of the rolls.
[0096] 以上のような折り畳み装置 1によれば、スリットカットロール 53により搬送方向にカツ トされて発熱体 1個分ずつの複数本 (3本)の列状となった発熱体 33積層済みの包装 材 41は、押さえロール 11Aの下流側で折り畳み半面を折り畳み案内台 3面に接触し ながらプレスロールにより所定の張力で下流側に引っ張られる。このとき、折り畳み案 内台 3は、その表面が発熱体 33の中間シール部に沿って湾曲しているため、折り畳 み半面側はその湾曲部に沿って立ち上げあられる。その後、発熱体 33積層済みの 包装材 41の折り畳み半面側は、折り畳み案内台 3の曲面に沿って、下流側へ移動 するにつれて中間シール (折り曲げ部)側から幅方向に徐々に固定半面側に折り重 ねられ、折り畳み案内台 3の最下流側では幅方向の全面が固定半面側に重なった 2 つ折り状態となり、更にその下流側のプレスロールでその 2つ折り状態のままで押圧 されて下流側の封止装置側に送られる。  [0096] According to the folding device 1 as described above, the heating elements 33 are stacked in the form of a plurality of (three) heating elements each cut by the slit cut roll 53 in the conveying direction. The wrapping material 41 is pulled downstream with a predetermined tension by the press roll while the folding half surface is in contact with the folding guide base 3 surface on the downstream side of the pressing roll 11A. At this time, since the surface of the folding plan inner base 3 is curved along the intermediate seal portion of the heating element 33, the folding half surface side is raised along the curved portion. After that, the folding half surface side of the heating material 33 laminated packaging material 41 gradually moves from the intermediate seal (folded part) side to the fixed half surface side in the width direction as it moves downstream along the curved surface of the folding guide base 3. The folding guide base 3 is folded in a double-folded state with the entire widthwise direction overlapped with the fixed half surface side on the most downstream side of the folding guide base 3, and is further pressed by the downstream press roll in the folded state and downstream. To the sealing device side.
[0097] 図 16は、本発明の発熱体折り畳み装置 1の他の一例を示し、図 16 (a)は斜視図、 ( b)は斜視図、(c)は正面断面図、(d)は正面断面図である。 本例の折り畳み装置 1は、無端状ベルト 12の上に積層された発熱体 33の包装材 4 1を被せ、搬送し、包装材 41と共にその発熱体 33の中間シール部に沿って幅方向 2 つ折り状に折り畳むもので、図 16に示すように、押さえ無端状ベルト (押さえロール) 12、板状の折り畳み案内台 3、無端状ベルト 12、支持板 25を備えて、板状の折り畳 み案内台 3上の、発熱体 33を包装材 41で包み込み、板状折り畳み案内台 3を挟ん で、包装材 41で包み込み、押さえ無端状ベルト (押さえロール) 12と支持板 25で挟 むことにより発熱体 33を 2つ折り状態に折り畳み、折り畳み案内台 3を抜き、発熱体 3 3と包装材 41を 2つ折りにしたまま、次工程へ搬送する。 FIG. 16 shows another example of the heating element folding device 1 of the present invention, FIG. 16 (a) is a perspective view, (b) is a perspective view, (c) is a front sectional view, and (d) is a front sectional view. It is front sectional drawing. The folding device 1 of this example covers and conveys the packaging material 41 of the heating element 33 laminated on the endless belt 12, and, along with the packaging material 41, along the intermediate seal portion of the heating element 33 in the width direction 2 As shown in Fig. 16, it is folded in a folded shape. It is equipped with a pressing endless belt (pressing roll) 12, a plate-shaped folding guide base 3, an endless belt 12, and a support plate 25. By wrapping the heating element 33 on the guide stand 3 with the packaging material 41, sandwiching the plate-shaped folding guide stand 3 with the packaging material 41, and sandwiching it with the presser endless belt (press roll) 12 and the support plate 25 The heating element 33 is folded in a folded state, the folding guide base 3 is pulled out, and the heating element 33 and the packaging material 41 are folded in two and conveyed to the next process.
[0098] 押さえ無端状ベルト 12は、包装材 41の上に位置し、包装材 41と板状折り畳み案内 台 3に挟まれた発熱体を支持板 25と共に 2つ折り状態に折り畳む。 The pressless endless belt 12 is positioned on the packaging material 41 and folds the heating element sandwiched between the packaging material 41 and the plate-shaped folding guide base 3 together with the support plate 25 in a folded state.
押さえ無端状ベルトの上流側が、下流側の上流側、即ち、板状の折り畳み案内台 の面の垂直方向に突出して板状の折り畳み案内台の面に進行して、折り畳み案内 台の面と平行になって進行して 1ヽく形態でもよ ヽ。  The upstream side of the presser endless belt protrudes perpendicularly to the upstream side of the downstream side, i.e., the surface of the plate-shaped folding guide base, proceeds to the surface of the plate-shaped folding guide base, and is parallel to the surface of the folding guide base. It may be a form that progresses and becomes one.
[0099] 板状折り畳み案内台 3は、長い形状に形成され、その固定半面側の側線部が、上 流側では発熱体 33の折り畳む部分も含め、折り畳み案内台が発熱体 33全体を覆う ように配し、上流側から下流側に発熱体 33の中間シール部に近づくように斜めに穏 やかなくびれが形成され、折り畳みが完了する位置以降は発熱体 33の中間シール 部等の折り畳み部に沿って、延びた折り込み案内部となっている。 [0099] The plate-shaped folding guide base 3 is formed in a long shape so that the side line portion on the fixed half surface side covers the entire heating element 33 including the portion where the heating element 33 is folded on the upstream side. A gentle constriction is formed diagonally so as to approach the intermediate seal part of the heating element 33 from the upstream side to the downstream side, and the folding part such as the intermediate seal part of the heating element 33 after the position where the folding is completed A fold-in guide portion extending along the line.
発熱体 33及び包装材 41の折り畳み半面(固定半面と反対側の半面)を、折り畳み 案内台を挟み固定半面側に重ね合わせるように案内するもので、搬送方向に、掬い 案内、はね下げ案内、内寄せ案内及び折込み案内から構成される機能面を受け取 る機能を有し、発熱体 33を包装材 41と共同して折り畳む。  The folding half of the heating element 33 and the packaging material 41 (the half opposite to the fixed half) is guided so that it overlaps the fixed half with the folding guide stand in between. The heating element 33 is folded together with the packaging material 41. The heating element 33 has a function of receiving a functional surface composed of an inward guide and a folding guide.
尚、板状折り畳み案内台 3は、任意の支持手段 (図示省略)を介して上記配置位置 に支持されている。  The plate-like folding guide base 3 is supported at the above-mentioned arrangement position via arbitrary support means (not shown).
[0100] 発熱体 33積層済みの包装材 41は、押さえ無端状ベルト 12の下流側で、折り畳み 半面を発熱体 33が内側となるように折り畳み案内台を挟んで、固定半面側に折り重 ねた状態で、押さえ無端状ベルト 12と支持板 25との間に挿通され、更に支持板 25 の下流側のシールロール 31により下流側に搬送される。 [0101] 支持板板 25は、包装材を折り畳み案内台 3へ押し付け、発熱体 33と包装材 41を 2 つに折り畳む。支持板 25の代わりに無端状ベルト 12を使用してもょ 、。 [0100] Heating element 33 The laminated packaging material 41 is folded downstream of the holding endless belt 12 with the folding half on the folding half so that the heating element 33 is on the inside and folded on the fixed half side. In this state, the presser endless belt 12 is inserted between the support plate 25 and the support plate 25, and further conveyed downstream by the seal roll 31 on the downstream side of the support plate 25. [0101] The support plate 25 presses the packaging material against the folding guide stand 3, and folds the heating element 33 and the packaging material 41 into two. Use an endless belt 12 instead of the support plate 25.
[0102] 折り畳み案内台 3と支持板 25の表面、少なくとも発熱体 33及び Z又は包装材 41と 接触する面は、摺動性の優れた面や回転自在のロール 10面や回転自在のボール 1[0102] The surface of the folding guide 3 and the support plate 25, at least the surface that contacts the heating element 33 and Z or the packaging material 41, is a surface with excellent slidability, 10 rotatable rolls, and a rotatable ball 1
0面であることが好ましい。 The 0 plane is preferred.
[0103] 図 16 (b)は、押さえ無端状ベルト 12と摺動性に優れた表面を有する折り畳み案内 台 3及び発熱体が 2つに折り畳まれていく過程を説明した説明斜視図である。 FIG. 16 (b) is an explanatory perspective view illustrating a process in which the holding endless belt 12 and the folding guide base 3 having a surface excellent in slidability and the heating element are folded in two.
[0104] 図 16 (c)は、押さえ無端状ベルト 12と摺動性に優れた表面を有する折り畳み案内 台 3及び支持台 25を使用して発熱体 33と包装材 41を折り畳んだ状態を示す断面図 である。 [0104] Fig. 16 (c) shows a state in which the heating element 33 and the packaging material 41 are folded using the folding endless belt 12 and the folding guide base 3 and the support base 25 having a surface excellent in slidability. FIG.
[0105] 図 16 (d)は、回転自在のロール面を有する枠組み押さえロール板 8、回転自在の口 一ル面を有する板状折り畳み案内台 3及び回転自在のロール面を有する支持板 25 を使用して発熱体 33を折り畳んだ状態の他の一例をを示す断面図である。  FIG. 16 (d) shows a frame pressing roll plate 8 having a rotatable roll surface, a plate-shaped folding guide base 3 having a rotatable central surface, and a support plate 25 having a rotatable roll surface. FIG. 10 is a cross-sectional view showing another example of a state where the heating element 33 is folded by use.
[0106] 図 17は、本発明の発熱体折り畳み装置 1の枠組押さえロール 8他の一例を示す。 FIG. 17 shows another example of the frame assembly pressing roll 8 of the heating element folding device 1 of the present invention.
[0107] 図 17 (a)は、入り口側が発熱体 33全体を積層し、上流側から下流側に発熱体 33 本体の中間シール部に近づくように斜めに穏やかなくびれが形成され、折り畳みが 完了する位置以降は発熱体 33の中間シール部に沿って、延びた折り込み案内部と なり、出口側は折り畳まれた発熱体 33がスムースに抜けるように厚みが薄くなつてい る板状折り畳み案内台 3を示す斜視図である。複数の回転自在のロールが両面に設 けられ、折り畳まれた発熱体 33や包装材 41が移動するの抵抗がな 、ようにされて ヽ る。図 17 (b)は、同 Z— Zの断面図である。 [0107] In Fig. 17 (a), the entire heating element 33 is stacked on the inlet side, and a gentle constriction is formed diagonally from the upstream side to the downstream side so as to approach the intermediate seal portion of the heating element 33 body, and the folding is completed. After this position, it becomes a folding guide that extends along the intermediate seal part of the heating element 33, and on the outlet side is a plate-shaped folding guide base that is thin enough to allow the folded heating element 33 to come out smoothly. FIG. A plurality of rotatable rolls are provided on both sides so that the folded heating element 33 and the packaging material 41 are not resistant to movement. Fig. 17 (b) is a cross-sectional view of Z-Z.
図 17 (c)〜(h)は、枠組みロール 54の他の一例を示す。板状折り畳み案内台 3、 支持板 25、折り込み案内台の下側部等に使用できる。  FIGS. 17C to 17H show another example of the framework roll 54. FIG. It can be used for the plate-shaped folding guide 3, the support plate 25, the lower part of the folding guide, etc.
図 17 (c)は隙間塞ぎ板を設けた複数のロール力もなる枠組みロール 54の他の一 例の平面図であり、図 17 (d)は、図 17 (c)の Y— Yの断面図である。ロール 10をボー ルベアリング等のボール 10代えても同じ機能の枠組みボール 54ができる。  Fig. 17 (c) is a plan view of another example of a frame roll 54 having a plurality of roll forces provided with gap closing plates, and Fig. 17 (d) is a cross-sectional view taken along line Y-Y in Fig. 17 (c). It is. Even if the roll 10 is replaced with a ball bearing 10 or the like, a frame ball 54 having the same function can be formed.
図 17 (e) (f) (h)に示した枠組みロール 54の他の一例の側面断面図であり、ロール 11が設けられた面と反対側の面に摺動性の優れた表面を設けたものは両面が発熱 体 33や包装材 41が移動するの抵抗がない面となり、図 17 (b)に示した同複数の回 転自在のロール 10が両面に設けられ枠組みロール 54と同じ機能を有する。 17 is a side cross-sectional view of another example of the frame roll 54 shown in FIGS. 17 (e), (f), and (h), and a surface having excellent slidability is provided on the surface opposite to the surface on which the roll 11 is provided. Both sides are exothermic The body 33 and the packaging material 41 have no resistance to movement, and the plurality of rotatable rolls 10 shown in FIG. 17 (b) are provided on both sides and have the same function as the frame roll 54.
図 17 (g)は、摺動性に優れた表面を有する支持板 25、押さえ板 7、 8 (摺動性面を 有す)の他の一例を示す側面図である。  FIG. 17 (g) is a side view showing another example of the support plate 25 and the pressing plates 7 and 8 (having a slidable surface) having a surface excellent in slidability.
[0108] 図 18は、(a)〜(c)は本発明の外袋折り畳み装置の他の一例を示す斜視図である 図 18 (a)は、折り畳まれた発熱体 33を非通気性の収納体である外袋に 3方シール で封入するときの観音折りでのシールを示す外袋折り畳み装置 55の他の一例の斜 視図である。本明細書において、「観音折り」とは、真ん中から左右に観音開きできる ように折り畳む折り畳み方を 、う。 FIG. 18 is a perspective view showing another example of the outer bag folding device according to the present invention. FIG. 18 (a) shows the folded heating element 33 in a non-breathable manner. FIG. 11 is a perspective view of another example of the outer bag folding device 55 showing a seal in a double fold when the three-side seal is enclosed in the outer bag as a storage body. In this specification, “Kannon folding” refers to a folding method in which folding is performed so that it can be opened from the middle to the left and right.
図 18 (b) (c)は、外袋折り畳み案内台 56の他の一例を示す斜視図である。  18 (b) and 18 (c) are perspective views showing another example of the outer bag folding guide base 56. FIG.
図 19は、本実施の形態の非通気性収納袋である外袋に封入された折り畳み発熱 体の製造 26の一例を示す説明図である。  FIG. 19 is an explanatory view showing an example of the production 26 of the folded heating element enclosed in the outer bag which is the non-breathable storage bag of the present embodiment.
発熱体の製造装置 26、整列間隔変更装置 29、外仮着用の粘着剤設置装置 58、 発熱体の折り畳み装置 30、シール装置 31、カット装置 32が設けられ、発熱体の製造 、発熱体の折り畳み、折り畳まれた発熱体の外袋への封入、外袋に封入された折り 畳み発熱体 34へのカットが連続的に行われる。  Heating element manufacturing device 26, alignment interval changing device 29, temporary wearing adhesive installation device 58, heating element folding device 30, sealing device 31, and cutting device 32 are provided, heating element manufacturing, heating element folding Then, the folded heating element is continuously sealed in the outer bag, and the folded heating element 34 sealed in the outer bag is continuously cut.
[0109] 図 20 (a)は、本発明の 8個の区分発熱部 38がシール部 42である区分け部 57を間 隔として、間隔をおいてストライプ状に設けられ、通気面側に、メルトブロー法により設 けられた網 (目)状の通気性粘着剤層 44を有するプリーツ型長方形形状の発熱体 3 3の折り畳まれる前の一例を示す平面図である。 [0109] Fig. 20 (a) shows that the eight divided heat generating portions 38 according to the present invention are provided in stripes at intervals with the divided portions 57 as the seal portions 42, and on the vent surface side, the melt blown portion is provided. FIG. 6 is a plan view showing an example of a pleated rectangular heating element 33 having a mesh (mesh) breathable pressure-sensitive adhesive layer 44 provided by the method before folding.
図 20 (b)は、同 X— Xの断面図で、セパレータが通気性粘着材層 44の上に設けら れている。  FIG. 20 (b) is a cross-sectional view taken along the line XX, in which the separator is provided on the breathable adhesive material layer 44. FIG.
図 20 (c)は、セパレータ付きの発熱体 33が 2つに折り畳まれて非通気性の収納袋 である外袋 49に封入された 34状態を示す断面図である。  FIG. 20 (c) is a cross-sectional view showing a state 34 in which a heating element 33 with a separator is folded in two and enclosed in an outer bag 49 which is a non-breathable storage bag.
図 20 (d)は、セパレータ付きの発熱体 33が 2つに折り畳まれて非通気性の収納袋 である外袋 49に封入された 34状態を示す平面図である。  FIG. 20 (d) is a plan view showing a state 34 in which a heating element 33 with a separator is folded in two and enclosed in an outer bag 49 which is a non-breathable storage bag.
図 20 (e)は、本発明の 2個の区分発熱部 38がシール部 42である区分け部 57を間 隔として、間隔をおいて設けられ、通気面側に、ストライプ状に粘着剤層 43が設けら れた通気性粘着剤層 44を有する長方形形状の発熱体 33の折り畳まれる前の一例 を示す平面図である。 FIG. 20 (e) shows a section 57 where the two section heat generating sections 38 of the present invention are the seal sections 42. A plane showing an example before folding of a rectangular heating element 33 having a breathable pressure-sensitive adhesive layer 44 provided at intervals as a gap and having a pressure-sensitive adhesive layer 43 provided in a stripe shape on the ventilation surface side. FIG.
図 20 (f)は、同 X— Xの断面図で、セパレータ 45が通気性粘着材層 44の上に設け られている。  FIG. 20 (f) is a cross-sectional view taken along the line XX, in which the separator 45 is provided on the breathable adhesive material layer 44. FIG.
図 20 (g)は、セパレータ付きの同発熱体 33が 2つに折り畳まれて非通気性の収納 袋である外袋 49に封入された状態を示す断面図である。  FIG. 20 (g) is a cross-sectional view showing a state in which the heating element 33 with a separator is folded in two and enclosed in an outer bag 49 which is a non-breathable storage bag.
図 20 (h)は、セパレータ付きソリッドタイプの粘着剤層 43が非通気性面側に設けら れた発熱体 33の他の一例を示す断面図平面図である。  FIG. 20 (h) is a cross-sectional plan view showing another example of the heating element 33 in which the solid adhesive layer 43 with a separator is provided on the non-breathable surface side.
図 20 (i)は、本発明の 8個の区分発熱部 38がシール部 42である区分け部 57を間 隔として、間隔をおいてストライプ状に設けられ、通気面側に、メルトブロー法により設 けられた網 (目)状の通気性粘着剤層 44を有するプリーツ型そら豆形形状の発熱体 33の折り畳まれる前の一例を示す平面図である。  FIG. 20 (i) shows that the eight divided heat generating portions 38 of the present invention are provided in stripes with the divided portions 57, which are the seal portions 42, spaced apart, and are provided on the ventilation surface side by the melt blow method. FIG. 4 is a plan view showing an example of a pleated broad bean-shaped heating element 33 having a net-like air-permeable pressure-sensitive adhesive layer 44 before being folded.
図 20 (j)は、本発明の 8個の区分発熱部 38がシール部 42である区分け部 57を間 隔として、間隔をおいてストライプ状に設けられ、発熱体 33の非通気性面側の両端 部にソリッド型の粘着剤層 43を有するプリーツ型の中央がくびれた提灯型発熱体 33 の折り畳まれる前の一例を示す平面図である。  FIG. 20 (j) shows that the eight divided heat generating portions 38 of the present invention are provided in stripes with the divided portions 57 being the seal portions 42 as an interval, and the heat generating element 33 has a non-breathable surface side. FIG. 6 is a plan view showing an example before folding of a lantern-type heating element 33 having a narrowed pleat-shaped center having solid-type adhesive layers 43 at both ends thereof.

Claims

請求の範囲 The scope of the claims
[1] 成形された発熱組成物を、基材上に隣接して配置するとともに被覆材により被覆し て、前記成形された発熱組成物の周縁部をシールして、発熱組成物を含む区分発 熱部を、シール部である区分け部を介して複数備える発熱体を、前記区分け部を折 り目にして折り畳むための発熱体折り畳み装置であって、前記発熱体折り畳み装置 は、前記発熱体の一端側に位置する前記区分発熱部を搬送するためのベルトと、前 記発熱体の他端側に位置する前記区分発熱部を、前記搬送方向に下流側に向力つ て支持しながら、前記発熱体の一端側に重ねるために、前記搬送方向において、前 記ベルトの他端側から一端側に向かって湾曲する折り畳み案内板を備えることを特 徴とする発熱体折り畳み装置。  [1] The molded exothermic composition is placed adjacent to the substrate and covered with a coating material, and the peripheral edge of the molded exothermic composition is sealed, so that the segmentation containing the exothermic composition is performed. A heating element folding device for folding a heating element having a plurality of heating parts via a partitioning part, which is a seal part, by folding the partitioning part, wherein the heating element folding device comprises: While supporting the belt for conveying the divided heat generating part located on one end side and the divided heat generating part located on the other end side of the heating element by force toward the downstream side in the conveying direction, A heating element folding apparatus, comprising: a folding guide plate that is curved toward the one end side from the other end side of the belt in the transport direction so as to overlap with one end side of the heating element.
[2] 前記発熱体折り畳み装置は、ガス供給装置を備え、前記ガス供給装置からのガス を、前記案内板の内側面に沿って吹き出すようにしたことを特徴とする請求項 1に記 載の発熱体折り畳み装置。  [2] The heating element folding device includes a gas supply device, and the gas from the gas supply device is blown out along an inner surface of the guide plate. Heating element folding device.
[3] 前記中央ベルトの側方にも、前記外側の区分発熱部を搬送するためのベルトを備 え、前記ベルト表面にも、前記ガス供給装置力 のガスを吹き出すようにしたことを特 徴とする請求項 2に記載の発熱体折り畳み装置。  [3] A belt for conveying the outer divided heat generating part is also provided on the side of the central belt, and the gas of the gas supply device is blown out to the belt surface. The heating element folding device according to claim 2.
[4] 前記折り畳み案内板の外側の外縁部側に沿って磁石を設けたことを特徴とする請 求項 1乃至 3の何れかに記載の発熱体折り畳み装置。  [4] The heating element folding device according to any one of claims 1 to 3, wherein a magnet is provided along an outer edge side of the folding guide plate.
[5] 成形された発熱組成物を、基材上に隣接して配置するとともに被覆材により被覆し て、前記成形された発熱組成物の周縁部をシールして、発熱組成物を含む区分発 熱部を、シール部である区分け部を介して複数備える発熱体を、前記区分け部を折 り目にして折り畳むための発熱体折り畳み装置であって、前記発熱体折り畳み装置 は、前記発熱体の一端側に位置する前記区分発熱部を搬送するためのベルトと、前 記発熱体の他端側に位置する前記区分発熱部を、前記搬送方向に下流側に向力つ て支持しながら、前記発熱体の一端側に重ねるために、前記搬送方向において、前 記ベルトの他端側から一端側に向かって曲面を有する折り畳み案内台を備えること を特徴とする発熱体折り畳み装置。  [5] The molded exothermic composition is disposed adjacent to the substrate and covered with a coating material, and the peripheral edge of the molded exothermic composition is sealed, so that the segmentation containing the exothermic composition is performed. A heating element folding device for folding a heating element having a plurality of heating parts via a partitioning part, which is a seal part, by folding the partitioning part, wherein the heating element folding device comprises: While supporting the belt for conveying the divided heat generating part located on one end side and the divided heat generating part located on the other end side of the heating element by force toward the downstream side in the conveying direction, A heating element folding apparatus, comprising: a folding guide base having a curved surface from the other end side of the belt toward the one end side in the conveying direction so as to overlap with one end side of the heating element.
[6] 前記折り畳み案内板及び前記折り畳み案内台の少なくとも何れかの前記発熱体と 接触する側の表面に、摺動性を有する材料を設けたことを特徴とする請求項 1乃至 5 の何れかに記載の発熱体折り畳み装置。 [6] The heating element of at least one of the folding guide plate and the folding guide base; 6. The heating element folding device according to claim 1, wherein a material having sliding property is provided on a surface on a contact side.
[7] 成形された発熱組成物を、基材上に隣接して配置するとともに被覆材により被覆し て、前記成形された発熱組成物の周縁部をシールして、発熱組成物を含む区分発 熱部を、シール部である区分け部を介して複数備える発熱体を、前記区分け部を折 り目にして折り畳むための発熱体折り畳み装置であって、前記発熱体折り畳み装置 は、前記区分発熱部を搬送するためのベルトを備え、前記ベルト面に対して交わる 関係にある軸のローラを備えることを特徴とする発熱体折り畳み装置。 [7] The molded exothermic composition is placed adjacent to the substrate and covered with a coating material, and the peripheral edge of the molded exothermic composition is sealed, so that the segmentation containing the exothermic composition is performed. A heating element folding device for folding a heating element comprising a plurality of heating parts via a sorting part, which is a seal part, by folding the sorting part, wherein the heating element folding device comprises the sorting heating part A heating element folding device, comprising: a belt for conveying the belt, and a roller having a shaft that intersects the belt surface.
[8] 前記ベルトと前記搬送ベルトとの間に、包装シートを供給するため包装シート供給 装置を設けることを特徴とする請求項 7に記載の発熱体折り畳み装置。 8. The heating element folding device according to claim 7, wherein a packaging sheet supply device is provided between the belt and the conveyor belt to supply a packaging sheet.
[9] 前記発熱体及び前記包装シートから選ばれた少なくとも 1種の一部に外仮着用の 粘着剤を設けるための粘着剤設置装置を備えることを特徴とする請求項 5乃至 8の何 れかに記載の発熱体折り畳み装置。 [9] Any one of claims 5 to 8, further comprising an adhesive installation device for providing an adhesive for external temporary wear to at least one part selected from the heating element and the packaging sheet. The heating element folding device according to claim 1.
[10] 請求項 1乃至 9の何れかに記載の発熱体折り畳み装置力 選ばれた少なくとも 1種 により製造された、 2つ以上複数に折り畳まれた発熱体が非通気性収納袋に封入さ れたことを特徴とする発熱体。 [10] The heating element folding device force according to any one of claims 1 to 9, wherein two or more heating elements manufactured by at least one selected type are enclosed in a non-breathable storage bag. A heating element characterized by that.
[11] 前記発熱体の露出部の少なくとも一部が非通気性収納袋の少なくとも一部に仮着 され、非通気性収納袋に封入されたことを特徴とする請求項 10に記載の発熱体。 11. The heating element according to claim 10, wherein at least a part of the exposed portion of the heating element is temporarily attached to at least a part of the non-breathable storage bag and sealed in the non-breathable storage bag. .
PCT/JP2007/050438 2006-01-13 2007-01-15 Exothermic-element folding apparatus WO2007081011A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006-006808 2006-01-13
JP2006006808A JP2009082155A (en) 2006-01-13 2006-01-13 Heating element folding apparatus

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Publication number Priority date Publication date Assignee Title
US9162403B2 (en) 2013-03-15 2015-10-20 Davis-Standard, Llc Apparatus for manufacturing and processing pre-stretch films having strips of increased thickness

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JPS5519524A (en) * 1978-07-27 1980-02-12 Sekisui Plastics Preparation of bag by foaming sheet
JPH0538894A (en) * 1990-02-09 1993-02-19 Deyupuro Seiko Kk Device for continuous production of letter with overlay
JPH0475966A (en) * 1990-07-13 1992-03-10 Nippon Shokubai Co Ltd Edge bending device
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3053551A4 (en) * 2013-09-30 2017-05-31 Kobayashi Pharmaceutical Co., Ltd. Disposable body warmer
US10195074B2 (en) 2013-09-30 2019-02-05 Kobayashi Pharmaceutical Co., Ltd. Disposable body warmer

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