WO2007004396A1 - Method for manufacturing electrophoretic display medium, and electrophoretic display medium - Google Patents

Method for manufacturing electrophoretic display medium, and electrophoretic display medium Download PDF

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Publication number
WO2007004396A1
WO2007004396A1 PCT/JP2006/311923 JP2006311923W WO2007004396A1 WO 2007004396 A1 WO2007004396 A1 WO 2007004396A1 JP 2006311923 W JP2006311923 W JP 2006311923W WO 2007004396 A1 WO2007004396 A1 WO 2007004396A1
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WO
WIPO (PCT)
Prior art keywords
substrate
display medium
electrophoretic display
substrates
pair
Prior art date
Application number
PCT/JP2006/311923
Other languages
French (fr)
Japanese (ja)
Inventor
Yoshito Toyoda
Original Assignee
Brother Kogyo Kabushiki Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Brother Kogyo Kabushiki Kaisha filed Critical Brother Kogyo Kabushiki Kaisha
Publication of WO2007004396A1 publication Critical patent/WO2007004396A1/en

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/165Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
    • G02F1/166Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect
    • G02F1/167Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect by electrophoresis
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1341Filling or closing of cells
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1339Gaskets; Spacers; Sealing of cells
    • G02F1/13394Gaskets; Spacers; Sealing of cells spacers regularly patterned on the cell subtrate, e.g. walls, pillars

Definitions

  • the present invention relates to an electrophoretic display medium manufacturing method and an electrophoretic display medium.
  • an electrophoretic display medium is known as a medium for displaying an image.
  • an electric field is applied to charged particles filled between a pair of substrates that are paired with a substrate serving as a display surface and a substrate serving as a display surface. Can be moved to. Such control is performed, and the charged particles are moved to the display surface, whereby the color of the charged particles is displayed on the display surface. Thereby, an image can be displayed.
  • Patent Document 1 Japanese Patent No. 3189958 has two substrates each having a partition member for partitioning a space between substrates into a plurality of partition chambers.
  • An electrophoretic display medium is disclosed in which each substrate is disposed in a direction in which the respective partition members face each other, and a gap is provided between the facing partition members so that charged particles can freely pass therethrough. ing.
  • the present invention has been made to solve the above-described problems, and provides an electrophoretic display medium manufacturing method and an electrophoretic display medium that do not cause display image unevenness and display quality is good.
  • the purpose is to do.
  • an electrophoretic display medium manufacturing method includes a pair of substrates each including a first substrate and a second substrate, and at least a partition portion on the first substrate.
  • a method for producing an electrophoretic display medium in which a liquid chamber provided with a material and filled with a display liquid composed of charged particles and a dispersion medium for dispersing the charged particles in a liquid chamber partitioned by the pair of substrates and the partition member A first opposing surface of the partition member provided on the first substrate facing the second substrate or the partition member provided on the second substrate, and provided on the second substrate or the second substrate.
  • a display liquid disposition that disposes the display liquid on at least the first substrate in a state in which a gap between the partition member and the second facing surface facing the first facing surface is separated from a predetermined distance.
  • the charged particles are substantially spherical, and the predetermined distance of the gap is five times the average particle diameter of the charged particles in the substrate arranging step.
  • the pair of substrates is arranged as follows.
  • an electrode is provided on at least one of the first opposing surface and the precursor second opposing surface, and the gap is disposed in the substrate arranging step.
  • the force applied to the charged particles in the liquid chamber from the electric field generated by the voltage applied to the electrode even if the charged particles exist between the first facing surface and the second facing surface.
  • the pair of substrates are arranged so that the distances are substantially the same.
  • the charged particles are substantially spherical, and the predetermined distance of the gap is one time the average particle diameter of the charged particles in the substrate arranging step. As described above, the pair of substrates is arranged.
  • the display liquid is filled between the pair of substrates in a state where the pair of substrates are opposed to each other in the display liquid arranging step. This is the special number.
  • a contact member is provided at least on the partition member or the first substrate provided on the first substrate, and the substrate arranging step The contact body is in contact with a second substrate or a partition member provided on the second substrate.
  • the partition member protrudes from the first substrate or the second substrate, and the first facing surface or the second facing surface is defined.
  • An end surface, and the contact body is provided on an end surface of the partition member and has an end surface protruding from the end surface of the partition member, and the end surface of the contact body is smaller than the end surface of the partition member, It is characterized by that.
  • the method for manufacturing an electrophoretic display medium according to claim 8 is characterized in that, in the substrate arranging step, the pair of substrates are arranged while applying vibration.
  • At least the first substrate is made of a thermoplastic resin or a stimulus curable resin so as to surround a display area for displaying an image.
  • At least the first substrate is made of a thermoplastic resin or a stimulus curable resin so as to surround a display area for displaying an image.
  • a sealing step for sealing the inlet and the outlet is provided.
  • the method for manufacturing an electrophoretic display medium according to claim 11 is characterized in that, in the substrate arranging step, the frame member is in an elastic state.
  • the frame member is a thermoplastic resin
  • the frame member in the substrate arranging step, the frame member is heated and softened while at least one of the substrates.
  • the pair of substrates is arranged by moving the substrate closer to the other substrate, and in the fixing step, the frame member is cooled to fix the distance between the pair of substrates.
  • the frame member is a thermosetting resin that is cured by stimulation by heating, and the frame member is heated in the fixing step. It is characterized in that the distance between the pair of substrates is fixed by curing.
  • the frame member is a photo-curing resin that is cured by light stimulation, and the frame member is cured by light irradiation in the fixing step.
  • the distance between the pair of substrates is fixed.
  • the method for producing an electrophoretic display medium according to claim 15 is characterized in that the photocurable resin is an ultraviolet curable resin that is cured by irradiating ultraviolet rays.
  • the electrophoretic display medium according to claim 16 includes a pair of substrates formed of a first substrate and a second substrate, at least a partition member provided on the first substrate, and the pair of substrates.
  • the first of the partition members provided on the first substrate.
  • a first facing surface facing the partition member provided on the second substrate or the second substrate, and a second facing surface facing the first facing surface of the partition member provided on the second substrate or the second substrate In a state where the gap between the At least a display liquid disposing step for disposing a display liquid on the first substrate, and after the display liquid disposing step, the charged particles cannot freely pass through the distance between the first facing surface and the second facing surface.
  • an electrophoretic display medium manufacturing method comprising a substrate disposing step of disposing the pair of substrates so as to be a predetermined distance of a gap.
  • the electrophoretic display medium according to Claim 17 includes a pair of substrates each including a first substrate and a second substrate, a partition member provided on the first substrate, or the partition member and the A partition member provided on the second substrate, and a liquid chamber partitioned by the pair of substrates and the partition member is filled with a display liquid composed of charged particles and a dispersion medium for dispersing the charged particles.
  • the first opposing surface provided on the partition member provided on the first substrate and facing the second substrate or the partition member provided on the second substrate, and the second substrate is set to be a predetermined distance of a gap through which the charged particles cannot freely pass.
  • a pair of substrates is arranged.
  • the electrophoretic display medium according to claim 18 is characterized in that the charged particles are substantially spherical, and a predetermined distance of the gap is 5 times or less of an average particle diameter of the charged particles.
  • an electrode is provided on at least one of the first facing surface and the precursor second facing surface, and the predetermined distance of the gap is the first facing surface. Even if the charged particles are present between the surface and the second opposing surface, the distance applied to the charged particles in the liquid chamber from the electric field generated by the voltage applied to the electrode is substantially the same. It is characterized by.
  • the electrophoretic display medium according to claim 20 wherein the charged particles are substantially spherical, and a predetermined distance of the gap is one or more times an average particle diameter of the charged particles.
  • the electrophoretic display medium according to claim 21 is provided on at least a part of a tip of the partition member provided on the first substrate that protrudes from the first substrate. It is characterized in that an abutting body in contact with the partition member provided on the substrate or the second substrate is provided.
  • the partition member provided on the first substrate has an end surface that protrudes from the first substrate and that defines the first facing surface
  • Said The contact body is provided on an end surface of the partition member and has an end surface protruding from the end surface of the partition member, and the end surface of the contact body is smaller than the end surface of the partition member.
  • the electrophoretic display medium according to claim 23 is a thermoplastic resin that is provided in close contact with the pair of substrates between the pair of substrates and surrounds a display area for displaying an image.
  • a frame member made of resin or stimulus-curable resin is provided.
  • the frame member is a thermoplastic resin.
  • the electrophoretic display medium according to claim 25 is characterized in that the frame member is a thermosetting resin that is cured by stimulation by heating.
  • the electrophoretic display medium according to claim 26 is characterized in that the frame member is a photo-curing resin that is cured by light stimulation.
  • the electrophoretic display medium according to claim 27 is characterized in that the photocurable resin is an ultraviolet curable resin that is cured by irradiating ultraviolet rays.
  • the charged particles can freely pass through the distance between the first facing surface and the second facing surface. Since the pair of substrates are arranged so as to have a predetermined distance that cannot be performed, the charged particles do not move between the liquid chambers, so that the display image does not become uneven and an electrophoretic display medium with good display quality can be easily obtained. Can be manufactured.
  • the predetermined distance is an average of the charged particles.
  • the pair of substrates is arranged so that the particle diameter is 5 times or less. If the predetermined distance of the gap is not more than 5 times the average particle diameter of the charged particles, the charged particles do not move between the liquid chambers, so that the display image does not become uneven and the electrophoretic display medium has better display quality. Can be easily manufactured.
  • the predetermined distance is such that the partition member of one substrate and the other substrate or the other substrate Even if the charged particles exist between the partition members of the substrate, the distance applied to the charged particles in the liquid chamber from the electric field generated by the voltage applied to the electrodes is substantially the same, that is, the electrophoretic display.
  • the pair of substrates are arranged so that the force applied to the charged particles in each of the liquid chambers in the entire medium is substantially uniform, so that the display image is not uneven and the display quality is good. Can be manufactured.
  • the predetermined distance is an average of the charged particles.
  • the pair of substrates is arranged so that the particle diameter is 1 times or more. Since the predetermined distance of the gap is one or more times the average particle diameter of the charged particles, even if one charged particle is sandwiched between the first opposed surface and the second opposed surface, Since the force applied to the charged particles is substantially the same, the display image does not become uneven.
  • the display liquid is filled between the pair of substrates with the pair of substrates facing each other. Therefore, it is possible to easily manufacture an electrophoretic display medium in which bubbles are easily removed and display quality is better.
  • the distance between the substrates can be accurately maintained by the contact body, and a larger electrophoretic display medium can be manufactured.
  • the contact body and the second substrate or a partition member of the second substrate are less likely to be sandwiched between the two, so that the uniformity of the predetermined distance in the entire electrophoretic display medium is increased, and the display image can be made more uniform.
  • an electrophoretic display medium having better display quality Can be manufactured.
  • the pair of substrates are arranged while applying vibration to the pair of substrates in the substrate arranging step.
  • the uniformity of the predetermined distance in the whole increases, and the display image can be made more uniform.
  • an electrophoretic display medium with better display quality can be manufactured.
  • the distance between the first facing surface and the second facing surface is set by the frame member.
  • the display liquid is filled from the injection port between the pair of substrates in a state separated from a predetermined distance, and the height of the frame member is reduced until the predetermined distance is reached in the substrate placement step. Since the pair of substrates are arranged, it is easy to remove bubbles and the display liquid can be filled uniformly, and as a result, an electrophoretic display medium with better display quality can be manufactured. .
  • the distance between the first facing surface and the second facing surface is set by the frame member.
  • the display liquid is discharged from the discharge port while filling the display liquid from the injection port between the pair of substrates, and the substrate placement step is performed. Since the pair of substrates are arranged by reducing the height of the frame member to the predetermined distance, it is easy to remove bubbles and can uniformly fill the display liquid S. As a result, An electrophoretic display medium with better display quality can be manufactured.
  • thermoplasticity is provided in the frame member arranging step. Since the frame member made of resin is arranged, the pair of substrates can be easily arranged in the substrate arranging step, and as a result, the electrophoretic display medium can be manufactured more easily.
  • the frame member arranging step includes In addition, since the frame member, which is a thermosetting resin, is arranged, the pair of substrates can be arranged more easily in the substrate arrangement process, and as a result, it is easier to perform the swimming. A moving display medium can be manufactured.
  • the frame member arranging step includes Since the frame member, which is a photocurable resin, is arranged, the pair of substrates can be arranged more easily in the substrate arrangement process, and as a result, the electrophoretic display medium can be more easily manufactured. it can.
  • the frame member that is an ultraviolet curable resin is disposed in the frame member disposing step. Therefore, the pair of substrates can be easily arranged in the substrate arranging step, and as a result, the electrophoretic display medium can be more easily manufactured.
  • the display image is not uneven, and the image can be displayed better.
  • the force applied to the charged particles in the liquid chamber from the electric field generated by the voltage applied to the electrode during image display is substantially the same, that is, the electric In the entire electrophoretic display medium, the force applied by the charged particles in each of the liquid chambers is substantially uniform, so that the display image is not uneven.
  • the contact body can accurately maintain the distance between the substrates, so that an image can be displayed better.
  • the frame member is made of a thermoplastic resin, so that the pair of substrates can be arranged more easily. Can be manufactured easily.
  • the frame member is made of a thermosetting resin, so that the arrangement of the pair of substrates is further improved. It is easy to perform and can be easily manufactured.
  • the frame member is made of a photocurable resin, so that the arrangement of the pair of substrates is further improved. It is easy to perform and can be easily manufactured.
  • the frame member is made of an ultraviolet curable resin. It is easier to carry out and can be manufactured easily.
  • FIG. 1 is a schematic view of an electrophoretic display medium 100 viewed from the display surface side.
  • FIG. 2 is a cross-sectional view of the electrophoretic display medium 100 taken along the line AA.
  • FIG. 3 is a perspective view of a partition member 123.
  • FIG. 4 is a cross-sectional view of the second substrate 110 and the first substrate 120.
  • FIG. 5 is a cross-sectional view of the second substrate 110 placed on the frame member 130.
  • FIG. 6 is a schematic view showing filling of the display liquid 300.
  • FIG. 7 is a diagram showing the relationship between the average particle diameter of charged particles 305 and the gap L.
  • FIG. 8 is a cross-sectional view of the electrophoretic display medium 100 after moving the second substrate 110.
  • FIG. 9 is a cross-sectional view of an electrophoretic display medium 100 manufactured by the manufacturing method of Example 1. ⁇
  • FIG. 10 A perspective view of the partition member 123 in which a cylindrical contact body 124 is formed.
  • FIG. 14 is a schematic view showing a process of arranging the second substrate 110 and the first substrate 120 in the manufacturing method of Example 2.
  • FIG. 15 is a schematic view showing a process of removing excess display liquid 300 in the manufacturing method of Example 2. Explanation of symbols
  • FIG. 1 is a schematic view of the electrophoretic display medium 100 of the present invention as viewed from the display surface side.
  • FIG. 2 shows a cross-sectional view of the electrophoretic display medium 100 as viewed from the direction of the arrow of AA.
  • white particles 310 and black particles 320 which are charged particles 305 filled later are added to the second electrode 111 and the first electrode 121, respectively.
  • An image is formed by being moved between the second substrate 110 and the first substrate 120 by the electric field generated by the voltage.
  • the numeral 8 is displayed on the display surface of the electrophoretic display medium 100 of FIG.
  • the electrophoretic display medium 100 is composed of a pair of substrates, that is, a transparent second substrate 110 made of PET (polyethylene terephthalate) resin constituting the display surface, and glass provided facing the second substrate 110.
  • a first substrate 120 is included.
  • the second substrate 110 is a transparent material, it is possible to use an inorganic material such as glass, or a resin such as a polyimide resin, a polypropylene resin, or a polycarbonate resin. It is possible to use resin such as PET resin, polyimide resin, polypropylene resin, polycarbonate resin, and metals such as stainless steel and aluminum with an insulating layer on the surface.
  • the second substrate 110 has a plurality of transparent second electrodes 111 made of ITO (indium tin oxide) and provided in parallel, and further has a protective film 112 for protecting the second electrode 111. .
  • the plurality of second electrodes 111 are provided in parallel from the front to the back.
  • the first substrate 120 has a plurality of first electrodes 121 provided in a twisted position and in parallel with the second electrode 111, and further a protective film for protecting the first electrode 121. 122.
  • the plurality of first electrodes 121 are provided in parallel from the front to the back.
  • the first substrate 120 has a partition member 123 on the protective film 122.
  • the front end of the partition member 123 is not in contact with the second substrate 110, and the front surface (first opposing surface) of the partition member 123, which is the surface facing the second substrate 110, the second substrate 110 and the protective film 112.
  • a gap 250 of 10 ⁇ m exists as a predetermined distance between the surface facing the partition member 123 (second facing surface).
  • the partition member 123 has a width of 20 zm and a height of 20 zm.
  • FIG. 1 A perspective view of the partition member 123 is shown in FIG.
  • the partition members 123 are arranged in a grid at intervals of 100 xm in the vertical direction when viewed from the display surface side and in the left and right direction when viewed from the display surface side, and a plurality of liquid chambers 200 (the number of liquid chambers 200 ( It is provided so as to be divided into Fig. 2).
  • the liquid chamber 200 partitioned by the partition member 123, the second substrate 110 and the protective film 112, and the first substrate 120 and the protective film 122 is filled with the display liquid 300.
  • the display liquid 300 includes white particles 310 made of styrene acrylic resin and titanium dioxide having an average particle size of 3 / m, and black particles 320 made of styrene acrylic resin and carbon black and having an average particle size of 3 ⁇ m. And a dispersion medium 330 made of an isoparaffin-based solvent in which the white particles 310 and the black particles 320 are dispersed.
  • White particles 310 are positively charged and black particles 320 are negatively charged.
  • the white particles 310 and the black particles 320 are collectively referred to simply as charged particles 305.
  • Known dyes and pigments can be used as materials used for coloring the particles, and transparent particles or hollow particles whose surface is subjected to diffusion treatment may be used for the white particles.
  • color particles prepared using phthalocyanine-based, azo-based, quinacridone-based pigments or dyes may be used.
  • the frame member 130 keeps the distance between the second substrate 110 and the first substrate 120 at 30 zm, and prevents the display liquid 300 between the substrates from leaking outside.
  • a thermoplastic resin Not only ethylene acetate butyl resin but also polypropylene resin and modified polyolefin resin can be used.
  • the second substrate 110 and the first substrate 120 are fixed by the fixing member 140 made of an epoxy adhesive. And are fixed to each other.
  • the second substrate 110 is provided with a pair of inlets 401 and outlets 402 for filling the display liquid 300.
  • the inlet 401 and the outlet 402 are respectively provided at the apexes on the diagonal line on the display surface.
  • the inlet 401 and the outlet 402 are sealed with a sealant 450 made of an epoxy adhesive.
  • the fixing member 140 and the sealant 450 are not limited to the epoxy adhesive, and the thermoplastic resin, the photocurable resin, the low melting point glass, and the like can be used.
  • the operation of the electrophoretic display medium 100 will be described.
  • the second electrode 111 and the first electrode 121 are crossed at the intersection of the second electrode 111 and the first electrode 121 so that a potential difference of 50 V is generated with respect to the pixel whose display is to be switched.
  • the charged particles 305 in the liquid chamber 200 move between the pair of substrates.
  • the color of the charged particles 305 moved to the second substrate 110 side is displayed on the display surface.
  • the positively charged white particles 310 in the liquid chamber 200 corresponding to the pixel become the second substrate 110.
  • the negatively charged black particles 320 move to the first substrate 120 side. For this reason, white of the white particles 310 is displayed on the display surface.
  • the 10 ⁇ m gap 250 from the tip of the partition member 123 to the second substrate 110 is a gap through which the charged particles 305 having an average particle diameter of 3 am cannot pass freely.
  • the electrophoretic display medium 100 is used with its display face up, the charged particles 305 hardly move between the liquid chambers 200.
  • the concentration does not vary between the liquid chambers 200, and the image displayed on the display surface is not uneven.
  • the electrophoretic display medium 100 As an evaluation of the electrophoretic display medium 100, first, as a process inspection, when the display liquid 300 was filled between the second substrate 110 and the first substrate 120, it was visually observed whether it could be filled uniformly. Evaluate and use G for uniform and NG for non-uniform. Next, after the electrophoretic display medium 100 is completed as a completion inspection, white display and black display are performed in a state where the electrophoretic display medium 100 is leaned, and a luminance meter BM7 manufactured by Topcon Tetano House is used for each display. The brightness of each pixel is measured, and when the difference between the average value and the maximum or minimum value is 20% or less of the average value in black display, it is evaluated that there is no unevenness.
  • FIG. 5 FIG. 6, FIG. 8, FIG. 9, and FIG. 12 are cross-sectional views taken along the line BB in FIG.
  • the first substrate 120 has the plurality of first electrodes 121 provided at the twisted positions so as to face the plurality of second electrodes 111, and further protects the first electrode 121.
  • a protective film 122 is provided.
  • the first substrate 120 has a partition member 123 on the protective film 122.
  • a frame member 130 having a height of about 60 ⁇ m formed of a thermoplastic resin such as a hot melt adhesive was disposed on the outer periphery of the first substrate 120.
  • the second substrate 110 was placed on the frame member 130.
  • the gap 250 between the front surface of the partition member 123 and the second substrate 110 is about 30 ⁇ m. .
  • the hot plate 600 is used at a later stage to store heat in the frame member 130 formed of a thermoplastic resin.
  • the display liquid 300 is introduced into the inlet 401 of the second substrate 110 as shown in FIG.
  • the injection device 501 for sending out the display liquid 300 from the inside is arranged, and the discharge device 502 for sucking out and discharging excess air and the display liquid 300 is arranged at the discharge port 402. Then, the display liquid 300 was filled between the second substrate 110 and the first substrate 120 using the injection device 501 and the discharge device 502.
  • the cylindrical ends of the injection device 501 and the discharge device 502 are formed with rubber caps, and the display liquid is discharged from the contact portion between the injection port 401 and the injection device 501 and the contact portion between the discharge port 402 and the discharge device 501 during the filling operation. There is no leakage.
  • the distance between the tip surface of the partition member 123 and the second substrate 110 is 30 ⁇ , and the distance is sufficiently larger than the charged particles 305 in the display liquid 300. Since the liquid can pass through, it is possible to uniformly fill the display liquid 300 between the second substrate 110 and the first substrate 120.
  • the above-described hot plate 600 was heated to 80 ° C. At this time, since the softening point of the frame member 130 is 80 ° C, the softening force The melting point of the second substrate 110 is 260 ° C, and the melting point of the first substrate 120 is 600 ° C or higher. .
  • the pressing jig 700 is lowered and the second substrate 110 is pressed from above with the pressing jig, whereby the first The two substrates 1 10 were moved so as to approach the first substrate 120.
  • the shape of the pressing jig 700 should be such that the distance from the tip of the partition member 123 to the second substrate 110, that is, the gap 250 is 10 xm. That is, since the distance between the substrates is designed to be 30 ⁇ m, the second substrate 110 and the first substrate 120 can be arranged only by pressing operation. At this time, surplus display liquid 30
  • the second substrate 110 and the first substrate 120 were fixed by cooling the hot plate 600 to 40 ° C. and curing the frame member 130.
  • the second substrate 110 and the first substrate are further fixed by fixing from the side surface of the electrophoretic display medium 100 with a fixing member 140. 12
  • the sealing liquid 50 was attached to the injection port 401 and the discharge port 402 and sealed. In this manner, the electrophoretic display medium 100 in which the charged particles 305 were uniformly filled in each liquid chamber 200 was manufactured.
  • Example 2 of the present invention will be described.
  • the manufacturing apparatus was installed in a vacuum container 850.
  • a vacuum pump 800 was connected to the vacuum vessel 850 via an intake valve 810 and an exhaust valve 820.
  • the second substrate 110 provided with only the injection port 401 was used. At this time, since the height of the frame member 130 is 50 ⁇ and the height of the partition member 123 is 20 ⁇ , the gap 250 between the tip surface of the partition member 123 and the second substrate 110 is 30 zm. It becomes.
  • the injection apparatus 501 was operated to fill the display liquid 300 between the second substrate 110 and the first substrate 120.
  • the distance between the tip surface of the partition member 123 and the second substrate 110 is 30 xm, and the distance is within the display liquid 300.
  • Charged particles 305 that are sufficiently larger than charged particles 305 can freely pass through the interval, so that the display liquid 300 is uniformly filled between the second substrate 110 and the first substrate 120. I was able to force S. After filling the display liquid 300 between the substrates, the injection device 501 was moved.
  • the pressing jig 700 is lowered, and the second substrate 110 is pressed onto the first substrate 120 by pressing the second substrate 110 from above with the pressing jig. I moved it closer.
  • the shape of the pressing jig 700 is designed so that the distance from the tip of the partition member 123 to the second substrate 110, that is, the gap 250 is 15 xm. A substrate 120 can be placed.
  • the surplus display liquid 300 was removed by moving the blade 410 from the left portion of the inlet 401 to the suction member 420 installed on the right portion while keeping the blade 410 in close contact with the second substrate 110.
  • the hot plate 600 was cooled to 40 ° C., and the frame member 130 was cured, so that the second substrate 110 and the first substrate 120 were fixed.
  • Example 3 of the present invention will be described.
  • the height of the frame member 130 when the second substrate 110 is placed on the frame member 130 is 40 am
  • the height of the partition member 123 is 20 zm, that is, the front surface of the partition member 123
  • the electrophoretic display medium 100 was manufactured in the same manner as in Example 1.
  • the display liquid 300 was uniformly distributed between the second substrate 110 and the first substrate 120. It was possible to fill in between.
  • the electrophoretic display medium 100 produced in this manner was stood and evaluated for display, no unevenness occurred. After this, the display was evaluated again after standing for one week. B) There was no unevenness in the display.
  • Example 4 of the present invention will be described.
  • the height of the frame member 130 is 30 ⁇ m
  • the height of the partition member 123 is 20 zm, that is, the front surface of the partition member 123
  • the gap 250 between the second substrate 110 is 10 zm
  • the average particle diameter of the charged particles 305 dispersed in the display liquid 300 is 0.7 ⁇ m
  • the gap 250 in the substrate placement step is 3 ⁇ m.
  • the electrophoretic display medium 100 was produced in the same manner as in Example 1 except that the pressing jig 700 designed as described above was used.
  • the display liquid 300 was uniformly distributed between the second substrate 110 and the first substrate 120. could be filled.
  • the electrophoretic display medium 100 produced in this way was stood and evaluated for display, no unevenness occurred. After this, the display was evaluated again after standing for 1 week. As a result, no unevenness occurred in the display.
  • Example 5 of the present invention will be described.
  • the height of the frame member 130 is 65 ⁇ m
  • the height of the partition member 1 23 is 20 / im, that is, the front surface of the partition member 123
  • the gap 250 between the second substrate 110 is 45 ⁇ m
  • the average particle diameter of the charged particles 305 dispersed in the display liquid 300 is 8 ⁇ m
  • the gap 250 in the substrate placement step is 40 ⁇ m.
  • the electrophoretic display medium 100 was produced in the same manner as in Example 1 except that the pressing jig 700 designed as described above was used, and the display liquid 300 was uniformly filled between the second substrate 110 and the first substrate 120. We were able to. Further, when the electrophoretic display medium 100 produced in this way was stood and evaluated for display, no unevenness occurred. After this, the display was evaluated again after being allowed to stand for 1 week.
  • Comparative Example 1 of the present invention will be described.
  • the height of the frame member 130 is 35 zm
  • the height of the partition member 12 3 is 20 zm, that is, the front surface of the partition member 123
  • the electrophoretic display medium 100 was produced in the same manner as in Example 1 except that the gap 250 between the second substrate 110 was 15 ⁇ m, and the display liquid 300 was uniformly distributed between the second substrate 110 and the first substrate 120. Can not be filled in between won.
  • Comparative Example 2 of the present invention will be described.
  • the height of the frame member 130 is 45 ⁇ m
  • the height of the partition member 123 is 20 zm, that is, the tip surface of the partition member 123
  • the pressing jig 700 designed so that the gap 250 with the second substrate 110 is 25 ⁇ m and the gap 250 in the substrate placement step is 20 ⁇ m is used.
  • the display liquid 300 could be uniformly filled between the second substrate 110 and the first substrate 120. Further, when the electrophoretic display medium 100 produced in this manner was stood and evaluated for display, no unevenness occurred. After this, the display was evaluated again after standing for 1 week, and unevenness in the display occurred.
  • Comparative Example 3 of the present invention will be described.
  • the height of the frame member 130 is 23 am
  • the height of the partition member 1 23 is 20 / im
  • the front surface of the partition member 123 Electrophoretic display as in Example 1 except that the gap 250 between the second substrate 110 is 3 / im and the average particle diameter of the charged particles 305 dispersed in the display liquid 300 is 0.7 / im.
  • the display liquid 300 could not be uniformly filled between the second substrate 110 and the first substrate 120.
  • Comparative Example 4 of the present invention will be described.
  • the height of the frame member 130 is 30 ⁇ m
  • the height of the partition member 123 is 20 / im, that is, the front surface of the partition member 123
  • the gap 250 between the second substrate 110 and the second substrate 110 is 10 / im
  • the average particle diameter of the charged particles 305 dispersed in the display liquid 300 is 0.7 / im
  • the gap 250 in the substrate placement step is 5 ⁇ m.
  • the electrophoretic display medium 100 was produced in the same manner as in Example 1 except that the pressing jig 700 designed so as to be the same as in Example 1 was obtained.
  • the display liquid 300 was uniformly distributed between the second substrate 110 and the first substrate 120. Can be filled in between.
  • the electrophoretic display medium 100 produced in this way was stood and evaluated for display, no unevenness occurred. After this, the display was evaluated again after standing for one week, and the display was uneven.
  • the height of the frame member 130 when the second substrate 110 is placed on the frame member 130 is 70 am, and the partition member 1
  • the height of 23 is 20 / im, that is, the gap 250 between the tip surface of the partition member 123 and the second substrate 110 is 50 ⁇ m, and the average particle diameter of the charged particles 305 dispersed in the display liquid 300 is 8
  • the electrophoretic display medium 100 was produced in the same manner as in Example 1 except that the pressing jig 700 designed so that the gap 250 in the substrate placement process was 45 ⁇ m was set to ⁇ m.
  • the liquid 300 could be filled between the second substrate 110 and the first substrate 120. Further, when the electrophoretic display medium 100 produced in this way was stood and evaluated for display, no unevenness occurred. After this, the display was evaluated again after standing for 1 week, and the display was uneven.
  • FIG. 7 shows a table of the results of Examples 1 to 5 and Comparative Examples 1 to 5 described above. If the gap 250 is 5 times or less of the average particle diameter of the charged particles 305, it is difficult to uniformly fill the display liquid, and unevenness can be suppressed. It can be seen that when the average particle size of 305 is 5 times or less, the charged particles 305 have an effect of suppressing movement between the compartments.
  • the gap 250 in the substrate placement step be at least 1 times the average particle size. This is because if the distance of the gap 250 is partially different, the intensity of the electric field applied to the charged particle 305 is partially different, resulting in unevenness.
  • the distance of the gap 250 is added to the charged particles 305 in the liquid chamber 200 even if the charged particles 305 exist between the gaps 250.
  • the applied forces are substantially the same distance, the force applied to the charged particles 305 in each of the liquid chambers 200 in the entire electrophoretic display medium is substantially uniform, and the display quality is improved. Therefore, the distance of the gap 250 may be less than 1 times the average particle diameter.
  • the electrophoretic display medium 100 has been described as a very small display medium consisting of 54 pixels of 9 rows ⁇ 6 columns, but the electrophoretic display medium according to the present invention. Is not limited to this number.
  • the perspective view of an example of the division member 123 provided with 124 is shown.
  • a plurality of cylindrical columns may be provided on the partition member 123 at predetermined intervals as the contact body 124, or a thin plate-shaped column force as shown in FIG. It may be provided on the partition member 123 at intervals.
  • the abutting body 124 When viewed from the vertical direction of the display surface, the abutting body 124 is not shown in FIGS. 10 and 11 if the size of the tip of the abutting body 124 is smaller than the size of the tip of the partition member 123. It may be shaped.
  • an oscillation unit 900 that vibrates the hot plate 600 is provided in contact with the hot plate 600, and oscillation occurs when the second substrate 110 is brought closer to the first substrate 120 in the above-described embodiment.
  • the second substrate 110 or the first substrate 120 may be brought close to each other while being vibrated. If arranged while applying vibration, the charged particles 305 that have been placed on the tip of the partition member 123 or the contact member 124 when the display liquid 300 is filled, and the tip force of these particles easily fall.
  • the contact body 124 may contact the second substrate 110 or the first substrate 120 through the charged particles 305 in one step.
  • the first substrate 120 has been described as having the partition member 123.
  • the second substrate 110 may have the partition member 123.
  • Both the first board 120 and the first board 120 each have a first partition member and a second partition member.
  • the first substrate 120 having the partition member 123 means that the first substrate 120 is formed by integrally forming the partition member 123, and the first substrate 120 simply places the partition member 123 thereon. You can just do it.
  • an electrophoretic display medium using non-spherical particles such as a force particle having a spherical shape such as a charged particle 305 described as being spherical in the above-described embodiment.
  • an optimal gap 250 may be appropriately set according to the shape and flexibility of the particles.
  • the second substrate 110 and the first substrate 120 are fixed with the epoxy adhesive 140.
  • other means such as a bolt, a formwork, and a clip may be used as the fixing method. .
  • the frame member 130 has been described as being a thermoplastic resin.
  • the pressing member 700 can be operated in two stages by using the frame member 130 as an elastic body such as rubber. In the first stage, after the pressing jig 700 is operated to press the second substrate 110 toward the first substrate 120, the display liquid 300 is filled between the second substrate 110 and the first substrate 120. Then, after the pressing jig 700 is operated in the second stage to set the gap 250 to a predetermined interval, the fixing member 140 may be arranged and fixed around the frame member.
  • the force is described when the frame member 130 is made of a thermoplastic resin.
  • the frame member 130 made of a high-viscosity or semi-cured thermosetting resin.
  • the second substrate 110 and the first substrate 120 may be fixed by heating the frame member 130 of the thermosetting resin. .
  • the frame member 130 is described as being a thermoplastic resin.
  • the pressing jig 700 is used to place the second substrate. After pressing 110 to the first substrate 120 side, the second substrate 110 and the first substrate 120 may be fixed by irradiating light to the photocurable resin frame member 130.
  • the material of the protective film 112 may be a plastic body or an elastic body.
  • the protective film 112 and the protective film 122 are described as being formed. However, the protective film 112 and the consistent film 122 may not be formed.

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Abstract

A first substrate (120) and a second substrate (110) are arranged by having at least a distance between a plane, which is of a partitioning member (123) arranged on the first substrate (120) and faces the second substrate (110), and the second substrate (110) to be wide when charged particles (305) are applied and to be narrow when being sealed or displaying an image so that the charged particles (305) do not freely pass through.

Description

明 細 書  Specification
電気泳動表示媒体の製造方法及び電気泳動表示媒体  Method for producing electrophoretic display medium and electrophoretic display medium
技術分野  Technical field
[0001] 本発明は、電気泳動表示媒体の製造方法及び電気泳動表示媒体に関する。  The present invention relates to an electrophoretic display medium manufacturing method and an electrophoretic display medium.
背景技術  Background art
[0002] 従来から画像を表示するための媒体として、電気泳動表示媒体が知られている。電 気泳動表示媒体は、表示面となる基板と表示面となる基板と対になる基板からなる一 対の基板間に充填された荷電粒子に電界を加えることにより、基板間において荷電 粒子を任意に移動させることができる。このような制御が行われ、荷電粒子が表示面 に移動されることによって、荷電粒子による色が表示面に表示される。これにより、画 像を表示することができる。  Conventionally, an electrophoretic display medium is known as a medium for displaying an image. In the electrophoretic display medium, an electric field is applied to charged particles filled between a pair of substrates that are paired with a substrate serving as a display surface and a substrate serving as a display surface. Can be moved to. Such control is performed, and the charged particles are moved to the display surface, whereby the color of the charged particles is displayed on the display surface. Thereby, an image can be displayed.
[0003] 日本国特許第 3189958号公報 (特許文献 1)には、基板間の空間を複数の区画 室に区画するための区画部材がそれぞれに形成された 2枚の基板を有し、 2枚の基 板はそれぞれの区画部材が対向する向きで配置され、且つ対向する区画部材の間 には荷電粒子が自由に通過できるようにするための隙間が設けられている電気泳動 表示媒体が開示されている。  [0003] Japanese Patent No. 3189958 (Patent Document 1) has two substrates each having a partition member for partitioning a space between substrates into a plurality of partition chambers. An electrophoretic display medium is disclosed in which each substrate is disposed in a direction in which the respective partition members face each other, and a gap is provided between the facing partition members so that charged particles can freely pass therethrough. ing.
発明の開示  Disclosure of the invention
発明が解決しょうとする課題  Problems to be solved by the invention
[0004] し力しながら、特許文献 1に記載の電気泳動表示媒体のように、 2つの区画部材の 間に荷電粒子が自由に通過できるだけの隙間が設けられている場合、電気泳動表 示媒体を立て掛けて使用すると、振動等の影響によって表示面から剥がれた荷電粒 子が重力によって沈降する時に、前記隙間を通って他の区画室に移動しやすくなる 。この結果、区画室によって荷電粒子の濃度が均一でなレ、、すなわち表示画像にむ らが発生するために表示品質が低下する。  [0004] However, when a gap is provided between the two partition members so that charged particles can freely pass therethrough as in the electrophoretic display medium described in Patent Document 1, the electrophoretic display medium When charged and used, the charged particles detached from the display surface due to the influence of vibration or the like can easily move to other compartments through the gap when they settle by gravity. As a result, the quality of the charged particles is uniform due to the compartments, that is, the display image is uneven, so that the display quality is degraded.
[0005] 本発明は、上述した問題点を解決するためになされたものであり、表示画像にむら が発生せず、表示品質が良好な電気泳動表示媒体の製造方法及び電気泳動表示 媒体を提供することを目的とする。 課題を解決するための手段 [0005] The present invention has been made to solve the above-described problems, and provides an electrophoretic display medium manufacturing method and an electrophoretic display medium that do not cause display image unevenness and display quality is good. The purpose is to do. Means for solving the problem
[0006] この目的を達成するために、請求項 1記載の電気泳動表示媒体の製造方法は、第 一基板と第二基板とから構成される一対の基板と、少なくとも前記第一基板に区画部 材が設けられ、前記一対の基板と前記区画部材とによって区画された液室に、荷電 粒子と前記荷電粒子を分散させる分散媒とからなる表示液が充填された電気泳動表 示媒体の製造方法において、前記第一基板に設けられた区画部材の、前記第二基 板若しくは前記第二基板に設けられた区画部材に対向する第一対向面と、前記第 二基板若しくは前記第二基板に設けられた区画部材の、前記第一対向面に対向す る第二対向面との隙間を所定距離よりも離間させた状態で、少なくとも前記第一基板 の上に前記表示液を配置する表示液配置工程と、前記表示液配置工程後、前記第 一対向面と前記第二対向面との間の隙間を前記荷電粒子が自由に通過不能な所定 距離になるように、前記一対の基板を配置する基板配置工程と、前記基板配置工程 によって配置された前記一対の基板を相互に固定する固定工程とからなる。  In order to achieve this object, an electrophoretic display medium manufacturing method according to claim 1 includes a pair of substrates each including a first substrate and a second substrate, and at least a partition portion on the first substrate. A method for producing an electrophoretic display medium in which a liquid chamber provided with a material and filled with a display liquid composed of charged particles and a dispersion medium for dispersing the charged particles in a liquid chamber partitioned by the pair of substrates and the partition member A first opposing surface of the partition member provided on the first substrate facing the second substrate or the partition member provided on the second substrate, and provided on the second substrate or the second substrate. A display liquid disposition that disposes the display liquid on at least the first substrate in a state in which a gap between the partition member and the second facing surface facing the first facing surface is separated from a predetermined distance. Before the process and the display liquid arranging process Arrangement of the pair of substrates so that the charged particles cannot pass freely through the gap between the first opposing surface and the second opposing surface, and the substrate arranging step. And a fixing step of fixing the pair of substrates to each other.
[0007] また、請求項 2記載の電気泳動表示媒体の製造方法は、前記荷電粒子が略球状 であり、前記基板配置工程において、前記隙間の所定距離が前記荷電粒子の平均 粒子径の 5倍以下になるように、前記一対の基板を配置することを特徴とする。  [0007] In the method for manufacturing an electrophoretic display medium according to claim 2, the charged particles are substantially spherical, and the predetermined distance of the gap is five times the average particle diameter of the charged particles in the substrate arranging step. The pair of substrates is arranged as follows.
[0008] また、請求項 3記載の電気泳動表示媒体の製造方法は、前記第一対向面と前駆第 二対向面の少なくともいずれか一方には電極が設けられ、前記基板配置工程におい て前記隙間の所定距離が、前記第一対向面と前記第二対向面との間に前記荷電粒 子が存在したとしても前記電極に加えられる電圧によって生じる電界から前記液室内 の荷電粒子に加えられる力が実質的に同じになる距離になるように、前記一対の基 板を配置することを特徴とする。  [0008] In the method for manufacturing an electrophoretic display medium according to claim 3, an electrode is provided on at least one of the first opposing surface and the precursor second opposing surface, and the gap is disposed in the substrate arranging step. The force applied to the charged particles in the liquid chamber from the electric field generated by the voltage applied to the electrode even if the charged particles exist between the first facing surface and the second facing surface. The pair of substrates are arranged so that the distances are substantially the same.
[0009] また、請求項 4記載の電気泳動表示媒体の製造方法は、前記荷電粒子が略球状 であり、前記基板配置工程において、前記隙間の所定距離が前記荷電粒子の平均 粒子径の 1倍以上になるように、前記一対の基板を配置することを特徴とする。  [0009] Further, in the method for manufacturing an electrophoretic display medium according to claim 4, the charged particles are substantially spherical, and the predetermined distance of the gap is one time the average particle diameter of the charged particles in the substrate arranging step. As described above, the pair of substrates is arranged.
[0010] また、請求項 5記載の電気泳動表示媒体の製造方法は、前記表示液配置工程に ぉレ、て、前記一対の基板を対向させた状態で前記一対の基板間に表示液を充填す ることを特 ί数とする。 [0011] また、請求項 6記載の電気泳動表示媒体の製造方法は、少なくとも第一基板に設 けられた前記区画部材若しくは第一基板には当接体が設置してあり、前記基板配置 工程において、前記当接体が、第二基板若しくは前記第二基板に設けられた区画 部材と接することを特徴とする。 [0010] Further, in the method for manufacturing an electrophoretic display medium according to claim 5, the display liquid is filled between the pair of substrates in a state where the pair of substrates are opposed to each other in the display liquid arranging step. This is the special number. [0011] Further, in the method for manufacturing an electrophoretic display medium according to claim 6, a contact member is provided at least on the partition member or the first substrate provided on the first substrate, and the substrate arranging step The contact body is in contact with a second substrate or a partition member provided on the second substrate.
[0012] また、請求項 7記載の電気泳動表示媒体の製造方法は、前記区画部材は前記第 一基板若しくは前記第二基板から突出し、前記第一対向面若しくは前記第二対向面 が規定された端面を有し、前記当接体は前記区画部材の端面に設けられると共に前 記区画部材の端面より突出する端面を有し、前記当接体の端面は前記区画部材の 端面よりも小さレ、ことを特徴とする。  [0012] In the method of manufacturing an electrophoretic display medium according to claim 7, the partition member protrudes from the first substrate or the second substrate, and the first facing surface or the second facing surface is defined. An end surface, and the contact body is provided on an end surface of the partition member and has an end surface protruding from the end surface of the partition member, and the end surface of the contact body is smaller than the end surface of the partition member, It is characterized by that.
[0013] また、請求項 8記載の電気泳動表示媒体の製造方法は、前記基板配置工程にお いて、振動を与えながら前記一対の基板を配置することを特徴とする。  [0013] Further, the method for manufacturing an electrophoretic display medium according to claim 8 is characterized in that, in the substrate arranging step, the pair of substrates are arranged while applying vibration.
[0014] また、請求項 9記載の電気泳動表示媒体の製造方法は、少なくとも前記第一基板 に、画像を表示するための表示領域の周囲を囲むように熱可塑性樹脂若しくは刺激 硬化性樹脂からなるフレーム部材を配置するフレーム部材配置工程を有し、前記一 対の基板の少なくとも一方若しくは前記フレーム部材には前記表示液を充填するた めの注入口が形成されており、前記表示液配置工程において、前記第一対向面と 前記第二対向面との距離が前記隙間の所定距離よりも離された状態で、前記注入 口から前記表示液を注入して前記一対の基板間に充填し、前記基板配置工程にお いて、少なくとも前記第二基板を前記第一基板に近づけるように移動させ、前記フレ 一ム部材の高さを縮めて前記一対の基板を配置し、前記固定工程後、前記注入口 を封止する封止工程を有することを特徴とする。  [0014] Further, in the method for manufacturing an electrophoretic display medium according to claim 9, at least the first substrate is made of a thermoplastic resin or a stimulus curable resin so as to surround a display area for displaying an image. A frame member disposing step of disposing a frame member, wherein at least one of the pair of substrates or the frame member is formed with an inlet for filling the display liquid; In the state where the distance between the first facing surface and the second facing surface is separated from the predetermined distance of the gap, the display liquid is injected from the inlet and filled between the pair of substrates, In the substrate placement step, at least the second substrate is moved closer to the first substrate, the height of the frame member is reduced to place the pair of substrates, and after the fixing step, the implantation is performed. And having a sealing step of sealing the.
[0015] また、請求項 10記載の電気泳動表示媒体の製造方法は、少なくとも前記第一基板 に、画像を表示するための表示領域の周囲を囲むように熱可塑性樹脂若しくは刺激 硬化性樹脂からなるフレーム部材を配置するフレーム部材配置工程を有し、前記一 対の基板の少なくとも一方若しくは前記フレーム部材には前記表示液を充填するた めの注入口と排出口が形成されており、前記表示液配置工程において、前記第一 対向面と前記第二対向面との距離が前記隙間の所定距離よりも離された状態で、前 記注入口から前記表示液を注入して前記一対の基板間に充填しながら余剰の前記 表示液を前記排出口から排出し、前記基板配置工程において、少なくとも前記第二 基板を前記第一基板に近づけるように移動させ、前記フレーム部材の高さを縮めて 前記一対の基板を配置し、前記固定工程後、前記注入口と前記排出口を封止する 封止工程を有することを特徴とする。 [0015] Further, in the method for manufacturing an electrophoretic display medium according to claim 10, at least the first substrate is made of a thermoplastic resin or a stimulus curable resin so as to surround a display area for displaying an image. A frame member arranging step of arranging a frame member, wherein at least one of the pair of substrates or the frame member is formed with an inlet and an outlet for filling the display liquid, and the display liquid In the disposing step, the display liquid is injected from the injection port between the pair of substrates in a state where the distance between the first facing surface and the second facing surface is separated from the predetermined distance of the gap. Surplus while filling Discharging the display liquid from the discharge port, in the substrate placement step, moving at least the second substrate closer to the first substrate, reducing the height of the frame member, and placing the pair of substrates, After the fixing step, a sealing step for sealing the inlet and the outlet is provided.
[0016] また、請求項 11記載の電気泳動表示媒体の製造方法は、前記基板配置工程にお いて、前記フレーム部材は弾性を有する状態であることを特徴とする。  [0016] Further, the method for manufacturing an electrophoretic display medium according to claim 11 is characterized in that, in the substrate arranging step, the frame member is in an elastic state.
[0017] また、請求項 12記載の電気泳動表示媒体の製造方法は、前記フレーム部材は熱 可塑性樹脂であり、前記基板配置工程において、前記フレーム部材を加熱して軟化 させつつ、少なくとも一方の基板を他方の基板に近づけるように移動させて前記一対 の基板を配置し、前記固定工程において、前記フレーム部材を冷却して前記一対の 基板間の距離を固定することを特徴とする。  [0017] Further, in the method for manufacturing an electrophoretic display medium according to claim 12, the frame member is a thermoplastic resin, and in the substrate arranging step, the frame member is heated and softened while at least one of the substrates. The pair of substrates is arranged by moving the substrate closer to the other substrate, and in the fixing step, the frame member is cooled to fix the distance between the pair of substrates.
[0018] また、請求項 13記載の電気泳動表示媒体の製造方法は、前記フレーム部材は加 熱による刺激で硬化する熱硬化性樹脂であり、前記固定工程において、前記フレー ム部材を加熱して硬化させることにより前記一対の基板間の距離を固定することを特 徴とする。  [0018] Further, in the method for manufacturing an electrophoretic display medium according to claim 13, the frame member is a thermosetting resin that is cured by stimulation by heating, and the frame member is heated in the fixing step. It is characterized in that the distance between the pair of substrates is fixed by curing.
[0019] また、請求項 14記載の電気泳動表示媒体の製造方法は、前記フレーム部材は光 による刺激で硬化する光硬化性樹脂であり、前記固定工程において、前記フレーム 部材を光照射により硬化させることにより前記一対の基板間の距離を固定することを 特徴とする。  [0019] In the method for manufacturing an electrophoretic display medium according to claim 14, the frame member is a photo-curing resin that is cured by light stimulation, and the frame member is cured by light irradiation in the fixing step. Thus, the distance between the pair of substrates is fixed.
[0020] また、請求項 15記載の電気泳動表示媒体の製造方法は、前記光硬化性樹脂が、 紫外線を照射することにより硬化する紫外線硬化性樹脂であることを特徴とする。  [0020] The method for producing an electrophoretic display medium according to claim 15 is characterized in that the photocurable resin is an ultraviolet curable resin that is cured by irradiating ultraviolet rays.
[0021] また、請求項 16記載の電気泳動表示媒体は、第一基板と第二基板とから構成され る一対の基板と、少なくとも前記第一基板に設けられた区画部材と、前記一対の基板 とによって区画された液室に、荷電粒子と前記荷電粒子を分散させる分散媒とからな る表示液が充填された電気泳動表示媒体において、前記第一基板に設けられた区 画部材の前記第二基板若しくは前記第二基板に設けられた区画部材に対向する第 一対向面と、前記第二基板若しくは前記第二基板に設けられた区画部材の前記第 一対向面に対向する第二対向面との隙間を所定距離よりも離間させた状態で、少な くとも前記第一基板の上に表示液を配置する表示液配置工程と、前記表示液配置 工程後、前記第一対向面と前記第二対向面との距離を前記荷電粒子が自由に通過 不能な隙間の所定距離になるように前記一対の基板を配置する基板配置工程とから なる電気泳動表示媒体の製造方法によって製造される。 [0021] In addition, the electrophoretic display medium according to claim 16 includes a pair of substrates formed of a first substrate and a second substrate, at least a partition member provided on the first substrate, and the pair of substrates. In an electrophoretic display medium in which a liquid chamber partitioned by a display liquid composed of charged particles and a dispersion medium for dispersing the charged particles is filled, the first of the partition members provided on the first substrate. A first facing surface facing the partition member provided on the second substrate or the second substrate, and a second facing surface facing the first facing surface of the partition member provided on the second substrate or the second substrate In a state where the gap between the At least a display liquid disposing step for disposing a display liquid on the first substrate, and after the display liquid disposing step, the charged particles cannot freely pass through the distance between the first facing surface and the second facing surface. Manufactured by an electrophoretic display medium manufacturing method comprising a substrate disposing step of disposing the pair of substrates so as to be a predetermined distance of a gap.
[0022] また、請求項 17記載の電気泳動表示媒体は、第一基板と第二基板とから構成され る一対の基板と、前記第一基板に設けられた区画部材、若しくは前記区画部材及び 前記第二基板に設けられた区画部材とを備え、前記一対の基板と前記区画部材とに よって区画された液室に、荷電粒子と前記荷電粒子を分散させる分散媒とからなる 表示液が充填された電気泳動表示媒体において、前記第一基板に設けられた区画 部材に設けられて前記第二基板若しくは前記第二基板に設けられた区画部材に対 向する第一対向面と、前記第二基板若しくは前記第二基板に設けられた区画部材 に設けられて前記第一対向面に対向する第二対向面との距離を前記荷電粒子が自 由に通過不能な隙間の所定距離になるように前記一対の基板が配置される。  [0022] In addition, the electrophoretic display medium according to Claim 17 includes a pair of substrates each including a first substrate and a second substrate, a partition member provided on the first substrate, or the partition member and the A partition member provided on the second substrate, and a liquid chamber partitioned by the pair of substrates and the partition member is filled with a display liquid composed of charged particles and a dispersion medium for dispersing the charged particles. In the electrophoretic display medium, the first opposing surface provided on the partition member provided on the first substrate and facing the second substrate or the partition member provided on the second substrate, and the second substrate Alternatively, the distance between the second opposing surface provided on the partition member provided on the second substrate and facing the first opposing surface is set to be a predetermined distance of a gap through which the charged particles cannot freely pass. A pair of substrates is arranged.
[0023] また、請求項 18記載の電気泳動表示媒体は、前記荷電粒子が略球状であり、前記 隙間の所定距離が前記荷電粒子の平均粒子径の 5倍以下であることを特徴とする。  [0023] The electrophoretic display medium according to claim 18 is characterized in that the charged particles are substantially spherical, and a predetermined distance of the gap is 5 times or less of an average particle diameter of the charged particles.
[0024] また、請求項 19記載の電気泳動表示媒体は、前記第一対向面と前駆第二対向面 の少なくともいずれか一方には電極が設けられ、前記隙間の所定距離は、前記第一 対向面と前記第二対向面との間に前記荷電粒子が存在したとしても前記電極に加え られる電圧によって生じる電界から前記液室内の荷電粒子に加えられる力が実質的 に同じになる距離であることを特徴とする。  [0024] Further, in the electrophoretic display medium according to claim 19, an electrode is provided on at least one of the first facing surface and the precursor second facing surface, and the predetermined distance of the gap is the first facing surface. Even if the charged particles are present between the surface and the second opposing surface, the distance applied to the charged particles in the liquid chamber from the electric field generated by the voltage applied to the electrode is substantially the same. It is characterized by.
[0025] また、請求項 20記載の電気泳動表示媒体は、前記荷電粒子が略球状であり、前記 隙間の所定距離が前記荷電粒子の平均粒子径の 1倍以上であることを特徴とする。  [0025] Further, the electrophoretic display medium according to claim 20, wherein the charged particles are substantially spherical, and a predetermined distance of the gap is one or more times an average particle diameter of the charged particles.
[0026] また、請求項 21記載の電気泳動表示媒体は、前記第一基板に設けられた区画部 材の、前記第一基板から突出している先端の少なくとも一部に設けられて、前記第二 基板若しくは前記第二基板に設けられた区画部材と接する当接体を備えたことを特 徴とする。  [0026] In addition, the electrophoretic display medium according to claim 21 is provided on at least a part of a tip of the partition member provided on the first substrate that protrudes from the first substrate. It is characterized in that an abutting body in contact with the partition member provided on the substrate or the second substrate is provided.
[0027] また、請求項 22記載の電気泳動表示媒体は、前記第一基板に設けられた区画部 材は、前記第一基板から突出して前記第一対向面が規定された端面を有し、前記当 接体は前記区画部材の端面に設けられると共に前記区画部材の端面より突出する 端面を有し、前記当接体の端面は前記区画部材の端面よりも小さいことを特徴とする [0027] Further, in the electrophoretic display medium according to claim 22, the partition member provided on the first substrate has an end surface that protrudes from the first substrate and that defines the first facing surface, Said The contact body is provided on an end surface of the partition member and has an end surface protruding from the end surface of the partition member, and the end surface of the contact body is smaller than the end surface of the partition member.
[0028] また、請求項 23記載の電気泳動表示媒体は、前記一対の基板間に前記一対の基 板と密着して設けられ、且つ画像を表示するための表示領域の周囲を囲む熱可塑 性樹脂若しくは刺激硬化性樹脂からなるフレーム部材を備えたことを特徴とする。 [0028] In addition, the electrophoretic display medium according to claim 23 is a thermoplastic resin that is provided in close contact with the pair of substrates between the pair of substrates and surrounds a display area for displaying an image. A frame member made of resin or stimulus-curable resin is provided.
[0029] また、請求項 24記載の電気泳動表示媒体は、前記フレーム部材が熱可塑性樹脂 であることを特徴とする。  [0029] Further, in the electrophoretic display medium according to claim 24, the frame member is a thermoplastic resin.
[0030] また、請求項 25記載の電気泳動表示媒体は、前記フレーム部材が加熱による刺激 で硬化する熱硬化性樹脂であることを特徴とする。  [0030] In addition, the electrophoretic display medium according to claim 25 is characterized in that the frame member is a thermosetting resin that is cured by stimulation by heating.
[0031] また、請求項 26記載の電気泳動表示媒体は、前記フレーム部材が光による刺激で 硬化する光硬化性樹脂であることを特徴とする。  [0031] Further, the electrophoretic display medium according to claim 26 is characterized in that the frame member is a photo-curing resin that is cured by light stimulation.
[0032] また、請求項 27記載の電気泳動表示媒体は、前記光硬化性樹脂が、紫外線を照 射することにより硬化する紫外線硬化性樹脂であることを特徴とする。  [0032] The electrophoretic display medium according to claim 27 is characterized in that the photocurable resin is an ultraviolet curable resin that is cured by irradiating ultraviolet rays.
発明の効果  The invention's effect
[0033] 請求項 1記載の電気泳動表示媒体の製造方法によれば、基板配置工程において、 前記第一対向面と前記第二対向面との距離を、前記荷電粒子が自由に通過するこ とが出来ない所定距離になるように前記一対の基板を配置するので、液室間を荷電 粒子が移動しないため表示画像にむらが発生せず、表示品質が良好な電気泳動表 示媒体を容易に製造することが出来る。  [0033] According to the method for manufacturing an electrophoretic display medium of claim 1, in the substrate disposing step, the charged particles can freely pass through the distance between the first facing surface and the second facing surface. Since the pair of substrates are arranged so as to have a predetermined distance that cannot be performed, the charged particles do not move between the liquid chambers, so that the display image does not become uneven and an electrophoretic display medium with good display quality can be easily obtained. Can be manufactured.
[0034] また、請求項 2記載の電気泳動表示媒体の製造方法によれば、請求項 1記載の発 明が奏する効果に加え、前記基板配置工程において、前記所定距離が、前記荷電 粒子の平均粒子径の 5倍以下になるように前記一対の基板を配置する。前記隙間の 所定距離が、前記荷電粒子の平均粒子径の 5倍以下ならば、液室間を荷電粒子が 移動しないため表示画像にむらが発生せず、より表示品質が良好な電気泳動表示 媒体を容易に製造することができる。  [0034] Further, according to the method for manufacturing an electrophoretic display medium according to claim 2, in addition to the effect of the invention according to claim 1, in the substrate placement step, the predetermined distance is an average of the charged particles. The pair of substrates is arranged so that the particle diameter is 5 times or less. If the predetermined distance of the gap is not more than 5 times the average particle diameter of the charged particles, the charged particles do not move between the liquid chambers, so that the display image does not become uneven and the electrophoretic display medium has better display quality. Can be easily manufactured.
[0035] また、請求項 3記載の電気泳動表示媒体の製造方法によれば、前記基板配置工程 において、前記所定距離が、一方の基板の区画部材と他方の基板若しくは他方の 基板の区画部材との間に前記荷電粒子が存在したとしても、電極に加えられる電圧 によって生じる電界から前記液室内の荷電粒子に加えられる力が実質的に同じにな る距離、すなわち電気泳動表示媒体の全体において個々の前記液室内の荷電粒子 に加えられる力が略均一になるように前記一対の基板を配置するので、表示画像に むらが発生せず、表示品質が良好な電気泳動表示媒体を製造することができる。 [0035] According to the method for manufacturing an electrophoretic display medium of claim 3, in the substrate placement step, the predetermined distance is such that the partition member of one substrate and the other substrate or the other substrate Even if the charged particles exist between the partition members of the substrate, the distance applied to the charged particles in the liquid chamber from the electric field generated by the voltage applied to the electrodes is substantially the same, that is, the electrophoretic display. The pair of substrates are arranged so that the force applied to the charged particles in each of the liquid chambers in the entire medium is substantially uniform, so that the display image is not uneven and the display quality is good. Can be manufactured.
[0036] また、請求項 4記載の電気泳動表示媒体の製造方法によれば、請求項 3記載の発 明が奏する効果に加え、前記基板配置工程において、前記所定距離が、前記荷電 粒子の平均粒子径の 1倍以上になるように前記一対の基板を配置する。前記隙間の 所定距離が、前記荷電粒子の平均粒子径の 1倍以上であるため、前記第一対向面 と前記第二対向面との間に前記荷電粒子が 1つ挟まれたとしても液室内の前記荷電 粒子に電界力 加えられる力が実質的に同じであるため、表示画像にむらが発生し ない。  [0036] Further, according to the method for manufacturing an electrophoretic display medium according to claim 4, in addition to the effect of the invention according to claim 3, in the substrate placement step, the predetermined distance is an average of the charged particles. The pair of substrates is arranged so that the particle diameter is 1 times or more. Since the predetermined distance of the gap is one or more times the average particle diameter of the charged particles, even if one charged particle is sandwiched between the first opposed surface and the second opposed surface, Since the force applied to the charged particles is substantially the same, the display image does not become uneven.
[0037] また、請求項 5記載の電気泳動表示媒体の製造方法によれば、前記表示液配置ェ 程において、前記一対の基板を対向させた状態で一対の基板間に表示液を充填す るため、気泡の除去が容易であり、より表示品質が良好な電気泳動表示媒体を容易 に製造することができる。  [0037] According to the method for manufacturing an electrophoretic display medium of claim 5, in the display liquid disposing step, the display liquid is filled between the pair of substrates with the pair of substrates facing each other. Therefore, it is possible to easily manufacture an electrophoretic display medium in which bubbles are easily removed and display quality is better.
[0038] また、請求項 6記載の電気泳動表示媒体の製造方法によれば、前記当接体により 基板間の距離を正確に保つことができ、より大きい電気泳動表示媒体を製造すること ができる。  [0038] According to the method for manufacturing an electrophoretic display medium according to claim 6, the distance between the substrates can be accurately maintained by the contact body, and a larger electrophoretic display medium can be manufactured. .
[0039] また、請求項 7記載の電気泳動表示媒体の製造方法によれば、請求項 5記載の発 明が奏する効果に加え、前記当接体と第二基板若しくは第二基板の区画部材との間 に前記荷電粒子が挟まれにくいので、電気泳動表示媒体の全体における所定距離 の均一性が高まり、表示画像をより均一にでき、その結果、より表示品質が良好な電 気泳動表示媒体を製造することができる。  [0039] Further, according to the method for manufacturing an electrophoretic display medium according to claim 7, in addition to the effect of the invention according to claim 5, the contact body and the second substrate or a partition member of the second substrate The charged particles are less likely to be sandwiched between the two, so that the uniformity of the predetermined distance in the entire electrophoretic display medium is increased, and the display image can be made more uniform. As a result, an electrophoretic display medium having better display quality Can be manufactured.
[0040] また、請求項 8記載の電気泳動表示媒体の製造方法によれば、前記基板配置工程 において前記一対の基板に振動を与えながら前記一対の基板を配置するため、電 気泳動表示媒体の全体における所定距離の均一性が高まり、表示画像をより均一に でき、その結果、より表示品質が良好な電気泳動表示媒体を製造することができる。 [0041] また、請求項 9記載の電気泳動表示媒体の製造方法によれば、前記表示液配置ェ 程において、前記フレーム部材により、前記第一対向面と前記第二対向面との距離 が前記所定距離よりも離された状態で、前記注入口から前記表示液を前記一対の基 板間に充填し、前記基板配置工程において、前記フレーム部材の高さを前記所定距 離になるまで縮めて前記一対の基板を配置するため、気泡を除去することが容易で 、且つ均一に表示液を充填することができ、その結果、より表示品質が良好な電気泳 動表示媒体を製造することができる。 [0040] Further, according to the method for manufacturing an electrophoretic display medium according to claim 8, the pair of substrates are arranged while applying vibration to the pair of substrates in the substrate arranging step. The uniformity of the predetermined distance in the whole increases, and the display image can be made more uniform. As a result, an electrophoretic display medium with better display quality can be manufactured. [0041] According to the method for manufacturing an electrophoretic display medium according to claim 9, in the display liquid arranging step, the distance between the first facing surface and the second facing surface is set by the frame member. The display liquid is filled from the injection port between the pair of substrates in a state separated from a predetermined distance, and the height of the frame member is reduced until the predetermined distance is reached in the substrate placement step. Since the pair of substrates are arranged, it is easy to remove bubbles and the display liquid can be filled uniformly, and as a result, an electrophoretic display medium with better display quality can be manufactured. .
[0042] また、請求項 10記載の電気泳動表示媒体の製造方法によれば、前記表示液配置 工程において、前記フレーム部材により、前記第一対向面と前記第二対向面との距 離が前記所定距離よりも離された状態で、前記注入口から前記表示液を前記一対の 基板間に充填しながら余剰の前記表示液を前記排出口から排出し、前記基板配置 工程にぉレ、て、前記フレーム部材の高さを前記所定距離になるまで縮めて前記一対 の基板を配置するため、気泡を除去することが容易で、かつ均一に表示液を充填す ること力 Sでき、その結果、より表示品質が良好な電気泳動表示媒体を製造することが できる。  [0042] Further, according to the method for manufacturing an electrophoretic display medium according to claim 10, in the display liquid arranging step, the distance between the first facing surface and the second facing surface is set by the frame member. In a state separated from a predetermined distance, the display liquid is discharged from the discharge port while filling the display liquid from the injection port between the pair of substrates, and the substrate placement step is performed. Since the pair of substrates are arranged by reducing the height of the frame member to the predetermined distance, it is easy to remove bubbles and can uniformly fill the display liquid S. As a result, An electrophoretic display medium with better display quality can be manufactured.
[0043] また、請求項 11記載の電気泳動表示媒体の製造方法によれば、請求項 9または請 求項 10のいずれかに記載の発明が奏する効果に加え、前記フレーム部材配置工程 において、前記フレーム部材が弾性を有する状態で、前記フレーム部材を配置する ため、前記基板配置工程において前記液室の密閉性が高くなる。  [0043] According to the method for manufacturing an electrophoretic display medium according to claim 11, in addition to the effect produced by the invention according to claim 9 or claim 10, in the frame member arranging step, Since the frame member is disposed in a state where the frame member has elasticity, the liquid chamber is highly sealed in the substrate disposing step.
[0044] また、請求項 12記載の電気泳動表示媒体の製造方法によれば、請求項 9または請 求項 10のいずれかに記載の発明が奏する効果に加え、前記フレーム部材配置工程 において熱可塑性樹脂である前記フレーム部材を配置するため、前記基板配置ェ 程における前記一対の基板の配置をより容易に行え、その結果、より簡単に電気泳 動表示媒体を製造することができる。  [0044] Further, according to the method for producing an electrophoretic display medium according to claim 12, in addition to the effect produced by the invention according to claim 9 or claim 10, thermoplasticity is provided in the frame member arranging step. Since the frame member made of resin is arranged, the pair of substrates can be easily arranged in the substrate arranging step, and as a result, the electrophoretic display medium can be manufactured more easily.
[0045] また、請求項 13記載の電気泳動表示媒体の製造方法によれば、請求項 9または請 求項 10のいずれかに記載の発明が奏する効果に加え、前記フレーム部材配置工程 におレ、て熱硬化性樹脂である前記フレーム部材を配置するため、前記基板配置ェ 程における前記一対の基板の配置をより容易に行え、その結果、より簡単に電気泳 動表示媒体を製造することができる。 [0045] Further, according to the method for manufacturing an electrophoretic display medium according to claim 13, in addition to the effect produced by the invention according to claim 9 or claim 10, the frame member arranging step includes In addition, since the frame member, which is a thermosetting resin, is arranged, the pair of substrates can be arranged more easily in the substrate arrangement process, and as a result, it is easier to perform the swimming. A moving display medium can be manufactured.
[0046] また、請求項 14記載の電気泳動表示媒体の製造方法によれば、請求項 9または請 求項 10のいずれかに記載の発明が奏する効果に加え、前記フレーム部材配置工程 におレ、て光硬化性樹脂である前記フレーム部材を配置するため、前記基板配置ェ 程における前記一対の基板の配置をより容易に行え、その結果、より簡単に電気泳 動表示媒体を製造することができる。  [0046] Further, according to the method for manufacturing an electrophoretic display medium according to claim 14, in addition to the effect produced by the invention according to claim 9 or claim 10, the frame member arranging step includes Since the frame member, which is a photocurable resin, is arranged, the pair of substrates can be arranged more easily in the substrate arrangement process, and as a result, the electrophoretic display medium can be more easily manufactured. it can.
[0047] また、請求項 15記載の電気泳動表示媒体の製造方法によれば、請求項 14記載の 発明が奏する効果に加え、前記フレーム部材配置工程において紫外線硬化性樹脂 である前記フレーム部材を配置するため、前記基板配置工程における前記一対の基 板の配置をより容易に行え、その結果、より簡単に電気泳動表示媒体を製造すること ができる。  [0047] According to the method for manufacturing an electrophoretic display medium according to claim 15, in addition to the effect of the invention according to claim 14, the frame member that is an ultraviolet curable resin is disposed in the frame member disposing step. Therefore, the pair of substrates can be easily arranged in the substrate arranging step, and as a result, the electrophoretic display medium can be more easily manufactured.
[0048] また、請求項 16記載の電気泳動表示媒体によれば、液室間を荷電粒子が移動し ないため表示画像にむらが発生せず、良好に画像を表示することができる。  [0048] Further, according to the electrophoretic display medium of claim 16, since the charged particles do not move between the liquid chambers, the display image is not uneven, and the image can be displayed satisfactorily.
[0049] また、請求項 17記載の電気泳動表示媒体によれば、液室間を荷電粒子が移動し ないため表示画像にむらが発生せず、良好に画像を表示することができる。  [0049] In addition, according to the electrophoretic display medium of claim 17, since the charged particles do not move between the liquid chambers, the display image is not uneven, and the image can be displayed satisfactorily.
[0050] また、請求項 18記載の電気泳動表示媒体によれば、液室間を荷電粒子が移動し ないため表示画像にむらが発生せず、より良好に画像を表示することができる。  [0050] Further, according to the electrophoretic display medium of claim 18, since the charged particles do not move between the liquid chambers, the display image is not uneven, and the image can be displayed better.
[0051] また、請求項 19記載の電気泳動表示媒体によれば、画像表示の際に電極に加え られる電圧によって生じる電界から前記液室内の荷電粒子に加えられる力が実質的 に同じ、すなわち電気泳動表示媒体の全体において個々の前記液室内の荷電粒子 の加えられる力が略均一であるため、表示画像にむらが発生しない。  [0051] According to the electrophoretic display medium of claim 19, the force applied to the charged particles in the liquid chamber from the electric field generated by the voltage applied to the electrode during image display is substantially the same, that is, the electric In the entire electrophoretic display medium, the force applied by the charged particles in each of the liquid chambers is substantially uniform, so that the display image is not uneven.
[0052] また、請求項 20記載の電気泳動表示媒体によれば、画像表示の際に液室内の前 記荷電粒子に電界力 加えられる力が実質的に同じであるため、表示画像にむらが 発生しない。  [0052] Further, according to the electrophoretic display medium of claim 20, since the force applied to the charged particles in the liquid chamber during the image display is substantially the same, the display image is uneven. Does not occur.
[0053] また、請求項 21記載の電気泳動表示媒体によれば、前記当接体が基板間の距離 を正確に保たれるので、より良好に画像を表示することができる。  [0053] In addition, according to the electrophoretic display medium of claim 21, the contact body can accurately maintain the distance between the substrates, so that an image can be displayed better.
[0054] また、請求項 22記載の電気泳動表示媒体によれば、請求項 19記載の発明が奏す る効果に加え、前記当接体と他方の基板若しくは他方の基板の区画部材との間に前 記荷電粒子が挟まれにくいので、電気泳動表示媒体の全体における所定距離の均 一性が高まり、表示画像をより均一にでき、その結果、より良好に画像を表示すること ができる。 [0054] According to the electrophoretic display medium of claim 22, in addition to the effect of the invention of claim 19, between the contact body and the other substrate or the partition member of the other substrate. in front Since the charged particles are difficult to be sandwiched, the uniformity of the predetermined distance in the entire electrophoretic display medium is increased, and the display image can be made more uniform, and as a result, the image can be displayed better.
[0055] また、請求項 23記載の電気泳動表示媒体によれば、製造時に気泡を除去すること が容易で、且つ均一に表示液を充填することができるので、表示画像がより均一であ る。  [0055] In addition, according to the electrophoretic display medium of claim 23, it is easy to remove bubbles at the time of manufacture and the display liquid can be filled uniformly, so that the display image is more uniform. .
[0056] また、請求項 24記載の電気泳動表示媒体によれば、請求項 21記載の発明が奏す る効果に加え、フレーム部材が熱可塑性樹脂であるため、前記一対の基板の配置が より容易に行われ、簡単に製造されることができる。  [0056] According to the electrophoretic display medium of claim 24, in addition to the effect of the invention of claim 21, the frame member is made of a thermoplastic resin, so that the pair of substrates can be arranged more easily. Can be manufactured easily.
[0057] また、請求項 25記載の電気泳動表示媒体によれば、請求項 21記載の発明が奏す る効果に加え、フレーム部材が熱硬化性樹脂であるため、前記一対の基板の配置が より容易に行われ、簡単に製造されることができる。 [0057] Further, according to the electrophoretic display medium according to claim 25, in addition to the effect provided by the invention according to claim 21, the frame member is made of a thermosetting resin, so that the arrangement of the pair of substrates is further improved. It is easy to perform and can be easily manufactured.
[0058] また、請求項 26記載の電気泳動表示媒体によれば、請求項 21記載の発明が奏す る効果に加え、フレーム部材が光硬化性樹脂であるため、前記一対の基板の配置が より容易に行われ、簡単に製造されることができる。 [0058] Further, according to the electrophoretic display medium according to claim 26, in addition to the effect provided by the invention according to claim 21, the frame member is made of a photocurable resin, so that the arrangement of the pair of substrates is further improved. It is easy to perform and can be easily manufactured.
[0059] また、請求項 27記載の電気泳動表示媒体によれば、請求項 21記載の発明が奏す る効果に加え、フレーム部材が紫外線硬化性樹脂であるため、前記一対の基板の配 置がより容易に行われ、簡単に製造されることができる。 [0059] Further, according to the electrophoretic display medium according to claim 27, in addition to the effect exhibited by the invention according to claim 21, the frame member is made of an ultraviolet curable resin. It is easier to carry out and can be manufactured easily.
図面の簡単な説明  Brief Description of Drawings
[0060] [図 1]表示面側から見た電気泳動表示媒体 100の概略図。  FIG. 1 is a schematic view of an electrophoretic display medium 100 viewed from the display surface side.
[図 2]電気泳動表示媒体 100の A— A断面図。  FIG. 2 is a cross-sectional view of the electrophoretic display medium 100 taken along the line AA.
[図 3]区画部材 123の斜視図。  3 is a perspective view of a partition member 123. FIG.
[図 4]第二基板 110と第一基板 120との断面図。  FIG. 4 is a cross-sectional view of the second substrate 110 and the first substrate 120.
[図 5]フレーム部材 130に載置された第二基板 110の断面図。  FIG. 5 is a cross-sectional view of the second substrate 110 placed on the frame member 130.
[図 6]表示液 300の充填を示す概略図。  FIG. 6 is a schematic view showing filling of the display liquid 300.
[図 7]荷電粒子 305の平均粒子径と隙間 Lとの関係を示す図。  FIG. 7 is a diagram showing the relationship between the average particle diameter of charged particles 305 and the gap L.
[図 8]第二基板 110を移動後の電気泳動表示媒体 100の断面図。  FIG. 8 is a cross-sectional view of the electrophoretic display medium 100 after moving the second substrate 110.
[図 9]実施例 1の製造方法で製造された電気泳動表示媒体 100の断面図。 Ο FIG. 9 is a cross-sectional view of an electrophoretic display medium 100 manufactured by the manufacturing method of Example 1. Ο
ο  ο
園 10]円柱状の当接体 124が形成された区画部材 123の斜視図。  10] A perspective view of the partition member 123 in which a cylindrical contact body 124 is formed.
園1—  Garden 1—
〇 11]板状の当接体 124が形成された区画部材 123の斜視図。  O 11] Perspective view of partition member 123 on which a plate-like contact body 124 is formed.
 Yes
園 12]ホットプレート 600に当接して設けられた発振部 900を示す図。  [12] A diagram showing the oscillation unit 900 provided in contact with the hot plate 600.
園 13]電気泳動表示媒体 100の C— C断面図。  13] A cross-sectional view of the electrophoretic display medium 100 taken along the line C-C.
[図 14]実施例 2の製造方法の第二基板 110と第一基板 120との配置の過程を示す 概略図。  FIG. 14 is a schematic view showing a process of arranging the second substrate 110 and the first substrate 120 in the manufacturing method of Example 2.
[図 15]実施例 2の製造方法の余剰の表示液 300を除去する過程を示す概略図。 符号の説明  FIG. 15 is a schematic view showing a process of removing excess display liquid 300 in the manufacturing method of Example 2. Explanation of symbols
電気泳動表不媒体  Electrophoresis surface medium
110 第二基板  110 Second board
111 二 極  111 Bipolar
112 保護膜  112 Protective film
120 第一基板  120 First board
121 一 i 極  121 one i pole
122 保護膜  122 Protective film
123 区画部材  123 compartment
124 当接体  124 Abutment body
130 フレーム部材  130 Frame member
140 固定部材  140 Fixed member
200 液室  200 liquid chamber
250 隙間  250 gap
300 表示液  300 Display solution
305 荷電粒子  305 charged particles
310 白色粒子  310 white particles
320 黒色粒子  320 black particles
401 注入口  401 inlet
402 排出口  402 outlet
450 封止剤 501 注入装置 450 Sealant 501 injection device
502 排出装置  502 Ejector
600 ホットプレート  600 hot plate
700 押付治具  700 Pressing jig
800 真空ポンプ  800 vacuum pump
810 吸気バルブ  810 Intake valve
820 排気バルブ  820 Exhaust valve
850 真空容器  850 vacuum vessel
900 発振部  900 Oscillator
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0062] 以下、本発明の実施の形態について図面を参照して説明する。図 1は本発明の電 気泳動表示媒体 100を表示面側から見た模式図である。電気泳動表示媒体 100の A— Aにおける断面の矢印方向から見た断面図を図 2に示す。図 2に示すように、電 気泳動表示媒体 100は内部に充填された後述する荷電粒子 305である白色粒子 31 0及び黒色粒子 320が、第二電極 111と第一電極 121とに加えられた電圧によって 発生した電界によって第二基板 110と第一基板 120との間を移動させられることによ り画像が形成される。図 1の電気泳動表示媒体 100の表示面には数字の 8が表示さ れている。 Hereinafter, embodiments of the present invention will be described with reference to the drawings. FIG. 1 is a schematic view of the electrophoretic display medium 100 of the present invention as viewed from the display surface side. FIG. 2 shows a cross-sectional view of the electrophoretic display medium 100 as viewed from the direction of the arrow of AA. As shown in FIG. 2, in the electrophoretic display medium 100, white particles 310 and black particles 320 which are charged particles 305 filled later are added to the second electrode 111 and the first electrode 121, respectively. An image is formed by being moved between the second substrate 110 and the first substrate 120 by the electric field generated by the voltage. The numeral 8 is displayed on the display surface of the electrophoretic display medium 100 of FIG.
[0063] この電気泳動表示媒体 100は一対の基板、即ち表示面を構成する PET (ポリェチ レンテレフタレート)樹脂からなる透明な第二基板 110及び第二基板 110に対向して 設けられたガラスからなる第一基板 120を有する。第二基板 110は透明な材料であ れば良ぐガラス等の無機物や、ポリイミド樹脂やポリプロピレン樹脂やポリカーボネ ート樹脂等の樹脂を用いることができ、第一基板 120にはガラス等の無機物や、 PET 樹脂やポリイミド樹脂やポリプロピレン樹脂やポリカーボネート樹脂等の樹脂や、表面 に絶縁層を設けたステンレスやアルミ等の金属、を用レ、ること力できる。第二基板 11 0は、 ITO (インジウム'スズ酸化物)からなる平行に設けられた透明な複数の第二電 極 111を有し、さらに第二電極 111を保護するための保護膜 112を有する。図 2にお レ、て、複数の第二電極 111は手前から奥に向かって平行に設けられてレ、る。 [0064] また、第一基板 120は、第二電極 111とねじれの位置にあり、かつ平行に設けられ た複数の第一電極 121を有し、さらに第一電極 121を保護するための保護膜 122を 有する。図 13においては、複数の第一電極 121は手前から奥に向かって平行に設 けられている。また、この第一基板 120は保護膜 122の上に区画部材 123を有して いる。この区画部材 123の先端は第二基板 110とは接しておらず、第二基板 110に 対向する面である区画部材 123の先端の面 (第一対向面)と第二基板 110及び保護 膜 112の区画部材 123に対向する面(第二対向面)との間に所定距離として 10 μ m の隙間 250が存在する。区画部材 123の幅は 20 z mで、高さが 20 z mである。 The electrophoretic display medium 100 is composed of a pair of substrates, that is, a transparent second substrate 110 made of PET (polyethylene terephthalate) resin constituting the display surface, and glass provided facing the second substrate 110. A first substrate 120 is included. If the second substrate 110 is a transparent material, it is possible to use an inorganic material such as glass, or a resin such as a polyimide resin, a polypropylene resin, or a polycarbonate resin. It is possible to use resin such as PET resin, polyimide resin, polypropylene resin, polycarbonate resin, and metals such as stainless steel and aluminum with an insulating layer on the surface. The second substrate 110 has a plurality of transparent second electrodes 111 made of ITO (indium tin oxide) and provided in parallel, and further has a protective film 112 for protecting the second electrode 111. . In FIG. 2, the plurality of second electrodes 111 are provided in parallel from the front to the back. [0064] The first substrate 120 has a plurality of first electrodes 121 provided in a twisted position and in parallel with the second electrode 111, and further a protective film for protecting the first electrode 121. 122. In FIG. 13, the plurality of first electrodes 121 are provided in parallel from the front to the back. The first substrate 120 has a partition member 123 on the protective film 122. The front end of the partition member 123 is not in contact with the second substrate 110, and the front surface (first opposing surface) of the partition member 123, which is the surface facing the second substrate 110, the second substrate 110 and the protective film 112. A gap 250 of 10 μm exists as a predetermined distance between the surface facing the partition member 123 (second facing surface). The partition member 123 has a width of 20 zm and a height of 20 zm.
[0065] この区画部材 123の斜視図を図 3に示す。区画部材 123は表示面側から見て上下 方向及び表示面側から見て左右方向にそれぞれ 100 x mの間隔で格子状に並べら れ、基板間を画素に対応する数の複数の液室 200 (図 2)に区画するように設けられ ている。  A perspective view of the partition member 123 is shown in FIG. The partition members 123 are arranged in a grid at intervals of 100 xm in the vertical direction when viewed from the display surface side and in the left and right direction when viewed from the display surface side, and a plurality of liquid chambers 200 (the number of liquid chambers 200 ( It is provided so as to be divided into Fig. 2).
[0066] この区画部材 123と、第二基板 110及び保護膜 112と、第一基板 120及び保護膜 122と、で区画された液室 200には、表示液 300が充填されている。この表示液 300 は、スチレンアクリル樹脂と二酸化チタンからなる平均粒子径が 3 / mの白色粒子 31 0及び同じくスチレンアクリル樹脂とカーボンブラックからなる平均粒子径が 3 μ mの 黒色粒子 320と、この白色粒子 310及び黒色粒子 320とを分散させるイソパラフィン 系溶媒からなる分散媒 330とからなる。 白色粒子 310は正に帯電しており、黒色粒子 320は負に帯電している。以下、白色粒子 310及び黒色粒子 320を合わせて単に荷 電粒子 305と称す。  The liquid chamber 200 partitioned by the partition member 123, the second substrate 110 and the protective film 112, and the first substrate 120 and the protective film 122 is filled with the display liquid 300. The display liquid 300 includes white particles 310 made of styrene acrylic resin and titanium dioxide having an average particle size of 3 / m, and black particles 320 made of styrene acrylic resin and carbon black and having an average particle size of 3 μm. And a dispersion medium 330 made of an isoparaffin-based solvent in which the white particles 310 and the black particles 320 are dispersed. White particles 310 are positively charged and black particles 320 are negatively charged. Hereinafter, the white particles 310 and the black particles 320 are collectively referred to simply as charged particles 305.
[0067] 粒子の着色に用レ、る材料としては公知の染料や顔料が使用でき、白色粒子におい ては表面を拡散処理した透明粒子や中空粒子を用いても良い。またフタロシアニン 系やァゾ系やキナクリドン系等の顔料や染料を用いて作製したカラー粒子を用いて も良い。  [0067] Known dyes and pigments can be used as materials used for coloring the particles, and transparent particles or hollow particles whose surface is subjected to diffusion treatment may be used for the white particles. In addition, color particles prepared using phthalocyanine-based, azo-based, quinacridone-based pigments or dyes may be used.
[0068] また、この一対の基板の周囲には、この一対の基板に挟まれた状態で、熱可塑性 樹脂であるエチレン酢酸ビュル樹脂からなるフレーム部材 130が配置されている。フ レーム部材 130は、第二基板 110と第一基板 120との間隔を 30 z mに保ち、かつ、 基板間の表示液 300が外部に漏れ出すのを防止している。熱可塑性樹脂としては、 エチレン酢酸ビュル樹脂に限らず、ポリプロピレン樹脂や変性ポリオレフイン樹脂等 を用いることができる。 [0068] Further, around the pair of substrates, a frame member 130 made of ethylene butyl acetate resin, which is a thermoplastic resin, is disposed in a state sandwiched between the pair of substrates. The frame member 130 keeps the distance between the second substrate 110 and the first substrate 120 at 30 zm, and prevents the display liquid 300 between the substrates from leaking outside. As a thermoplastic resin, Not only ethylene acetate butyl resin but also polypropylene resin and modified polyolefin resin can be used.
[0069] また、フレーム部材 130の更に外側から、第二基板 110と第一基板 120とをより確 実に固定するために、エポキシ接着剤からなる固定部材 140によって第二基板 110 と第一基板 120とが互いに固定されている。  [0069] In order to more reliably fix the second substrate 110 and the first substrate 120 from the outer side of the frame member 130, the second substrate 110 and the first substrate 120 are fixed by the fixing member 140 made of an epoxy adhesive. And are fixed to each other.
[0070] また、第二基板 110には、表示液 300を充填するための一対の注入口 401と排出 口 402とが設けられている。注入口 401と排出口 402は表示面において対角線上の 頂点にそれぞれ設けられている。そして、表示液 300の充填後、注入口 401と排出 口 402はエポキシ接着剤からなる封止剤 450によって封止されている。固定部材 14 0や封止剤 450としては、エポキシ接着剤に限らず、上記熱可塑性樹脂や光硬化性 樹脂や低融点ガラス等を用いることができる。  In addition, the second substrate 110 is provided with a pair of inlets 401 and outlets 402 for filling the display liquid 300. The inlet 401 and the outlet 402 are respectively provided at the apexes on the diagonal line on the display surface. After the display liquid 300 is filled, the inlet 401 and the outlet 402 are sealed with a sealant 450 made of an epoxy adhesive. The fixing member 140 and the sealant 450 are not limited to the epoxy adhesive, and the thermoplastic resin, the photocurable resin, the low melting point glass, and the like can be used.
[0071] 次に電気泳動表示媒体 100の動作について説明する。電気泳動表示媒体 100に 画像が表示される際は、第二電極 111と第一電極 121との交点である各画素におい て、表示を切り換えたい画素に対して 50Vの電位差が生じるように第二電極 111と第 一電極 121とに加える電圧を制御することにより、液室 200内の荷電粒子 305がー 対の基板間を移動する。そして表示面には第二基板 110側に移動させられた荷電 粒子 305の色が表示される。  Next, the operation of the electrophoretic display medium 100 will be described. When an image is displayed on the electrophoretic display medium 100, the second electrode 111 and the first electrode 121 are crossed at the intersection of the second electrode 111 and the first electrode 121 so that a potential difference of 50 V is generated with respect to the pixel whose display is to be switched. By controlling the voltage applied to the electrode 111 and the first electrode 121, the charged particles 305 in the liquid chamber 200 move between the pair of substrates. Then, the color of the charged particles 305 moved to the second substrate 110 side is displayed on the display surface.
[0072] 即ち、ある画素において、第二電極 111に対する第一電極 121の電位差が + 50V である場合、その画素に対応する液室 200内の正に帯電された白色粒子 310が第 二基板 110側に移動し、負に帯電された黒色粒子 320が第一基板 120側に移動す る。このため表示面には白色粒子 310の白が表示される。  That is, in a certain pixel, when the potential difference of the first electrode 121 with respect to the second electrode 111 is +50 V, the positively charged white particles 310 in the liquid chamber 200 corresponding to the pixel become the second substrate 110. The negatively charged black particles 320 move to the first substrate 120 side. For this reason, white of the white particles 310 is displayed on the display surface.
[0073] また、ある画素において、第二電極 111に対する第一電極 121の電位差が— 50V である場合、その画素に対応する液室 200内の負に帯電された黒色粒子 320が第 二基板 110側に移動し、正に帯電された白色粒子 310が第一基板 120側に移動す る。このため表示面には黒色粒子 320の黒が表示される。  In addition, in a certain pixel, when the potential difference of the first electrode 121 with respect to the second electrode 111 is −50 V, the negatively charged black particles 320 in the liquid chamber 200 corresponding to the pixel become the second substrate 110. The positively charged white particles 310 move to the first substrate 120 side. For this reason, black of the black particles 320 is displayed on the display surface.
[0074] このように画素に応じて、第二電極 111と第一電極 121とに印加する電圧をそれぞ れ制御することにより、電気泳動表示媒体 100に任意の画像が書き込まれる。  As described above, by controlling the voltages applied to the second electrode 111 and the first electrode 121 according to the pixels, an arbitrary image is written on the electrophoretic display medium 100.
[0075] また、画像が表示された後、第二電極 111及び第一電極 121への電圧の印加を止 めたとしても、基板間を移動した荷電粒子 305の状態は、荷電粒子 305と第二基板 1 10若しくは荷電粒子 305と第一基板 120との間に生ずる鏡像力と言われる電気的引 力によって維持される。このため、電気泳動表示媒体 100は、電源が切られたとして も電気泳動表示媒体 100の表示面には画像の表示が維持される。 [0075] After the image is displayed, the voltage application to the second electrode 111 and the first electrode 121 is stopped. However, the state of the charged particle 305 that has moved between the substrates is caused by an electric attractive force called an image force generated between the charged particle 305 and the second substrate 110 or between the charged particle 305 and the first substrate 120. Maintained. For this reason, even if the electrophoretic display medium 100 is turned off, the image display is maintained on the display surface of the electrophoretic display medium 100.
[0076] 後述するように、区画部材 123の先端から第二基板 110までの 10 x mの隙間 250 は、平均粒子径 3 a mの荷電粒子 305が自由に通過することができない隙間である。  As will be described later, the 10 × m gap 250 from the tip of the partition member 123 to the second substrate 110 is a gap through which the charged particles 305 having an average particle diameter of 3 am cannot pass freely.
[0077] よって、この電気泳動表示媒体 100は表示面を立て掛けて使用する場合などにお レ、ても、荷電粒子 305が各液室 200間をほとんど移動することがないので、荷電粒子 305の濃度が液室 200毎にばらつきが発生せず、表示面に表示される画像にむらが 発生することがなくなる。  [0077] Therefore, even when the electrophoretic display medium 100 is used with its display face up, the charged particles 305 hardly move between the liquid chambers 200. The concentration does not vary between the liquid chambers 200, and the image displayed on the display surface is not uneven.
[0078] 電気泳動表示媒体 100に対する評価としては、まず、工程検查として表示液 300を 第二基板 110と第一基板 120との間に充填した時に、均一に充填できたのかを目視 観察で評価し、均一の場合を G、不均一の場合を NGとする。次いで、完成検査とし て電気泳動表示媒体 100が完成した後、電気泳動表示媒体 100を立て掛けた状態 で白表示と黒表示を行い、それぞれの表示に対してトプコンテタノハウス社製の輝度 計 BM7を用いて画素毎の輝度を測定し、平均値と最大値もしくは最小値との差が、 黒表示においては平均値の 2割以下である場合をむらが発生していないと評価して G、 2割を超える場合はむらが発生したと評価して NGとし、白表示においては平均値 の 1割以下である場合をむらが発生していないと評価して G、 1割を超える場合はむ らが発生したと評価して NGとする。さらに、電気泳動表示媒体 100を立て掛けた状 態で 1週間静置した後に、再度完成検査と同じ評価を行い、むらの発生の有無を評 価する。  [0078] As an evaluation of the electrophoretic display medium 100, first, as a process inspection, when the display liquid 300 was filled between the second substrate 110 and the first substrate 120, it was visually observed whether it could be filled uniformly. Evaluate and use G for uniform and NG for non-uniform. Next, after the electrophoretic display medium 100 is completed as a completion inspection, white display and black display are performed in a state where the electrophoretic display medium 100 is leaned, and a luminance meter BM7 manufactured by Topcon Tetano House is used for each display. The brightness of each pixel is measured, and when the difference between the average value and the maximum or minimum value is 20% or less of the average value in black display, it is evaluated that there is no unevenness. If it exceeds 20%, it is evaluated as NG, and if it is less than 10% of the average value in white display, it is evaluated as non-uniformity G. If it exceeds 10, it is uneven. Assess that it occurred and set it as NG. Furthermore, after leaving the electrophoretic display medium 100 in a leaning state for one week, the same evaluation as the completion inspection is performed again to evaluate the occurrence of unevenness.
[0079] 次に、電気泳動表示媒体 100の製造方法について説明する。図 4、図 5、図 6、図 8 、図 9、図 12は図 1の B— Bにおける断面を矢印方向から見た図である。  Next, a method for manufacturing the electrophoretic display medium 100 will be described. 4, FIG. 5, FIG. 6, FIG. 8, FIG. 9, and FIG. 12 are cross-sectional views taken along the line BB in FIG.
[0080] また、第一基板 120は上述したように、複数の第二電極 111に対向して、ねじれの 位置に設けられた複数の第一電極 121を有し、さらに第一電極 121を保護するため の保護膜 122を有する。また、この第一基板 120は保護膜 122の上に区画部材 123 を有している。 [0081] また、第一基板 120の外周にはホットメルト接着剤等の熱可塑性樹脂で形成された 高さ約 60 μ mのフレーム部材 130を配置した。 Further, as described above, the first substrate 120 has the plurality of first electrodes 121 provided at the twisted positions so as to face the plurality of second electrodes 111, and further protects the first electrode 121. A protective film 122 is provided. The first substrate 120 has a partition member 123 on the protective film 122. In addition, a frame member 130 having a height of about 60 μm formed of a thermoplastic resin such as a hot melt adhesive was disposed on the outer periphery of the first substrate 120.
[0082] 次に、図 5に示すように、第二基板 110をフレーム部材 130の上に乗せるようにして 配置した。このとき、フレーム部材 130の高さが 50 z mであり、区画部材 123の高さ 力 ¾0 x mであるので、区画部材 123の先端の面と、第二基板 110との隙間 250が 30 μ mどなる。 Next, as shown in FIG. 5, the second substrate 110 was placed on the frame member 130. At this time, since the height of the frame member 130 is 50 zm and the height force of the partition member 123 is ¾0 xm, the gap 250 between the front surface of the partition member 123 and the second substrate 110 is about 30 μm. .
[0083] 更に、第一基板 120の下方はホットプレート 600と接触している。ホットプレート 600 は熱可塑性樹脂で形成されたフレーム部材 130に熱をカ卩えるために、後の段階で使 用される。  Further, the lower part of the first substrate 120 is in contact with the hot plate 600. The hot plate 600 is used at a later stage to store heat in the frame member 130 formed of a thermoplastic resin.
[0084] 次に、平均粒子径が共に 3 a mの白色粒子 310と黒色粒子 320を分散した表示液 300を用意した後、図 6に示すように第二基板 110の注入口 401に表示液 300を注 入するため内部から表示液 300を送り出す注入装置 501を配置し、排出口 402に余 分な空気と表示液 300とを吸い出して排出するための排出装置 502を配置した。そ して注入装置 501及び排出装置 502を用いて、表示液 300を第二基板 110と第一 基板 120との間に充填した。注入装置 501及び排出装置 502の筒先はゴムキャップ で形成されており、充填作業中に、注入口 401と注入装置 501との接触部及び排出 口 402と排出装置 501との接触部から表示液が漏れ出すことがない。区画部材 123 の先端の面と、第二基板 110との間隔は 30 μ ΐηであり、前記間隔が表示液 300中の 荷電粒子 305に対して十分に大きぐ荷電粒子 305は前記間隔を自由に通過するこ とができるので、均一に表示液 300を第二基板 110と第一基板 120との間に充填す ること力 Sできた。  Next, after preparing a display liquid 300 in which white particles 310 and black particles 320 both having an average particle diameter of 3 am are dispersed, the display liquid 300 is introduced into the inlet 401 of the second substrate 110 as shown in FIG. The injection device 501 for sending out the display liquid 300 from the inside is arranged, and the discharge device 502 for sucking out and discharging excess air and the display liquid 300 is arranged at the discharge port 402. Then, the display liquid 300 was filled between the second substrate 110 and the first substrate 120 using the injection device 501 and the discharge device 502. The cylindrical ends of the injection device 501 and the discharge device 502 are formed with rubber caps, and the display liquid is discharged from the contact portion between the injection port 401 and the injection device 501 and the contact portion between the discharge port 402 and the discharge device 501 during the filling operation. There is no leakage. The distance between the tip surface of the partition member 123 and the second substrate 110 is 30 μΐη, and the distance is sufficiently larger than the charged particles 305 in the display liquid 300. Since the liquid can pass through, it is possible to uniformly fill the display liquid 300 between the second substrate 110 and the first substrate 120.
[0085] 基板間に表示液 300の充填が完了した後、上述したホットプレート 600を 80°Cに加 熱した。この時、フレーム部材 130の軟化点は 80°Cであるため軟化する力 第二基 板 110の融点は 260°C、第一基板 120の融点は 600°C以上であるため軟化しなレ、。  [0085] After the filling of the display liquid 300 between the substrates was completed, the above-described hot plate 600 was heated to 80 ° C. At this time, since the softening point of the frame member 130 is 80 ° C, the softening force The melting point of the second substrate 110 is 260 ° C, and the melting point of the first substrate 120 is 600 ° C or higher. .
[0086] 図 8に示すように、このようにフレーム部材 130を軟ィ匕させた状態で、押付治具 700 を降下させ、押付治具で第二基板 110を上方から押付けることによって、第二基板 1 10を第一基板 120に近づけるように移動させた。押付治具 700の形状は、区画部材 123の先端から第二基板 110までの間隔即ち隙間 250が 10 x mになるように、すな わち基板間の距離が 30 μ mになるよう設計してあるため、押付け操作のみで第二基 板 110及び第一基板 120を配置させることが可能である。この際、余剰の表示液 30As shown in FIG. 8, with the frame member 130 softened in this manner, the pressing jig 700 is lowered and the second substrate 110 is pressed from above with the pressing jig, whereby the first The two substrates 1 10 were moved so as to approach the first substrate 120. The shape of the pressing jig 700 should be such that the distance from the tip of the partition member 123 to the second substrate 110, that is, the gap 250 is 10 xm. That is, since the distance between the substrates is designed to be 30 μm, the second substrate 110 and the first substrate 120 can be arranged only by pressing operation. At this time, surplus display liquid 30
0は、排出装置 502を用いて回収した。 0 was collected using the discharge device 502.
[0087] 次に、ホットプレート 600を 40°Cに冷却し、フレーム部材 130を硬化させることで、 第二基板 110と第一基板 120とを固定した。 Next, the second substrate 110 and the first substrate 120 were fixed by cooling the hot plate 600 to 40 ° C. and curing the frame member 130.
[0088] そして、押付治具 700を外した後、図 9に示すように、更に固定部材 140でこの電 気泳動表示媒体 100の側面からも固定することにより、第二基板 110と第一基板 12Then, after removing the pressing jig 700, as shown in FIG. 9, the second substrate 110 and the first substrate are further fixed by fixing from the side surface of the electrophoretic display medium 100 with a fixing member 140. 12
0とを、より確実に固定した。 0 was fixed more securely.
[0089] 次に、注入装置 501 (図 8参照)及び排出装置 502 (図 8参照)を外した。注入口 40Next, the injection device 501 (see FIG. 8) and the discharge device 502 (see FIG. 8) were removed. Inlet 40
1と排出口 402の周囲に付着した表示液 300を吸収部材 420 (図示せず)を用いて 拭き取った後、封止斉 50を注入口 401と排出口 402に付けて封止した。このように して、各液室 200内に均一に荷電粒子 305が充填された電気泳動表示媒体 100を 製造した。 After the display liquid 300 adhering to the periphery of 1 and the discharge port 402 was wiped off using an absorbent member 420 (not shown), the sealing liquid 50 was attached to the injection port 401 and the discharge port 402 and sealed. In this manner, the electrophoretic display medium 100 in which the charged particles 305 were uniformly filled in each liquid chamber 200 was manufactured.
[0090] このように作製した電気泳動表示媒体 100を立て掛けて表示評価したところ、むら は発生しなかった。この後、 1週間静置した後に再度表示評価を行ったところ、表示 にむらは発生しな力 た。  [0090] When the thus produced electrophoretic display medium 100 was leaned against and evaluated for display, no unevenness occurred. After this, the display was evaluated again after standing for 1 week. As a result, the display was uneven.
[0091] 次に本発明の実施例 2について説明する。図 14に示すように、製造装置を真空容 器 850内に設置した。真空容器 850には、吸気バルブ 810と、排気バルブ 820を介 して真空ポンプ 800を接続した。  Next, Example 2 of the present invention will be described. As shown in FIG. 14, the manufacturing apparatus was installed in a vacuum container 850. A vacuum pump 800 was connected to the vacuum vessel 850 via an intake valve 810 and an exhaust valve 820.
[0092] また、注入口 401のみを設けた第二基板 110を用いた。この時、フレーム部材 130 の高さが 50 μ ΐηであり、区画部材 123の高さが 20 μ ΐηであるので、区画部材 123の 先端の面と、第二基板 110との隙間 250が 30 z mとなる。 Further, the second substrate 110 provided with only the injection port 401 was used. At this time, since the height of the frame member 130 is 50 μΐη and the height of the partition member 123 is 20 μΐη, the gap 250 between the tip surface of the partition member 123 and the second substrate 110 is 30 zm. It becomes.
[0093] 平均粒子径が共に 3 z mの白色粒子 310と黒色粒子 320とを分散した表示液 300 を、注入装置 501内に充填した後、吸気バルブ 810を閉じ、排気バルブ 820を開け、 真空ポンプ 800を作動させた。 [0093] After filling display liquid 300 in which white particles 310 and black particles 320, both having an average particle size of 3 zm, are dispersed in injection device 501, intake valve 810 is closed, exhaust valve 820 is opened, and a vacuum pump Activated 800.
[0094] 真空容器 850内が真空になったことを確認した後、注入装置 501を作動させて、表 示液 300を第二基板 110と第一基板 120との間に充填した。この時、区画部材 123 の先端の面と、第二基板 110との間隔は 30 x mであり、前記間隔が表示液 300中の 荷電粒子 305に対して十分に大きぐ荷電粒子 305は前記間隔を自由に通過するこ とができるので、均一に表示液 300を第二基板 110と第一基板 120との間に充填す ること力 Sできた。基板間に表示液 300の充填が完了後、注入装置 501を移動した。 After confirming that the inside of the vacuum vessel 850 was evacuated, the injection apparatus 501 was operated to fill the display liquid 300 between the second substrate 110 and the first substrate 120. At this time, the distance between the tip surface of the partition member 123 and the second substrate 110 is 30 xm, and the distance is within the display liquid 300. Charged particles 305 that are sufficiently larger than charged particles 305 can freely pass through the interval, so that the display liquid 300 is uniformly filled between the second substrate 110 and the first substrate 120. I was able to force S. After filling the display liquid 300 between the substrates, the injection device 501 was moved.
[0095] 図 15に示すように、ホットプレート 600を 80。Cにカロ熱し、フレーム部材 130のみを 軟化させた状態で、押付治具 700を降下させ、押付治具で第二基板 110を上方から 押付けることによって、第二基板 110を第一基板 120に近づけるように移動させた。 押付治具 700の形状は、区画部材 123の先端から第二基板 110までの間隔即ち隙 間 250が 15 x mになるように設計してあるため、押付け操作のみで第二基板 110及 び第一基板 120を配置させることが可能である。この際、余剰の表示液 300は、ブレ ード 410を第二基板 110に密着させて状態で、注入口 401の左部から右部に設置し た吸着部材 420へ移動させることにより除去した。  [0095] As shown in FIG. With the heat applied to C and only the frame member 130 softened, the pressing jig 700 is lowered, and the second substrate 110 is pressed onto the first substrate 120 by pressing the second substrate 110 from above with the pressing jig. I moved it closer. The shape of the pressing jig 700 is designed so that the distance from the tip of the partition member 123 to the second substrate 110, that is, the gap 250 is 15 xm. A substrate 120 can be placed. At this time, the surplus display liquid 300 was removed by moving the blade 410 from the left portion of the inlet 401 to the suction member 420 installed on the right portion while keeping the blade 410 in close contact with the second substrate 110.
[0096] 次に、ホットプレート 600を 40°Cに冷却し、フレーム部材 130を硬化させることで、 第二基板 110と第一基板 120とを固定した。  Next, the hot plate 600 was cooled to 40 ° C., and the frame member 130 was cured, so that the second substrate 110 and the first substrate 120 were fixed.
[0097] そして、排気バルブ 820を閉め、真空ポンプ 800を停止した後、吸気バブル 810を 空けて真空容器 850の内部を常圧に戻し、押付治具 700を外した。その後、実施例 1と同様に、電気泳動表示媒体 100の側面を固定固定部材 140で固定し、注入口 4 01を封止剤 450で封止することにより、各液室 200内に均一に荷電粒子 305が充填 された電気泳動表示媒体 100を製造した。  [0097] Then, after closing the exhaust valve 820 and stopping the vacuum pump 800, the suction bubble 810 was opened, the inside of the vacuum vessel 850 was returned to normal pressure, and the pressing jig 700 was removed. Thereafter, similarly to Example 1, the side surface of the electrophoretic display medium 100 is fixed with the fixing and fixing member 140, and the injection port 401 is sealed with the sealant 450, so that the liquid chambers 200 are uniformly charged. An electrophoretic display medium 100 filled with particles 305 was produced.
[0098] このように作製した電気泳動表示媒体 100を立て掛けて表示評価したところ、むら は発生しなかった。この後、 1週間静置した後に再度表示評価を行ったところ、表示 にむらは発生しな力 た。  [0098] When the thus produced electrophoretic display medium 100 was stood and evaluated for display, unevenness did not occur. After this, the display was evaluated again after standing for 1 week. As a result, the display was uneven.
[0099] 次いで、本発明の実施例 3について説明する。第二基板 110をフレーム部材 130 の上に乗せるようにして配置した時のフレーム部材 130の高さを 40 a m、区画部材 1 23の高さを 20 z m、すなわち区画部材 123の先端の面と、第二基板 110との隙間 2 50を 20 μ mとした以外は、実施例 1と同様に電気泳動表示媒体 100を作製したとこ ろ、均一に表示液 300を第二基板 110と第一基板 120との間に充填することができ た。さらに、このように作製した電気泳動表示媒体 100を立て掛けて表示評価したと ころ、むらは発生しなかった。この後、 1週間静置した後に再度表示評価を行ったとこ ろ、表示にむらは発生しなかった。 [0099] Next, Example 3 of the present invention will be described. The height of the frame member 130 when the second substrate 110 is placed on the frame member 130 is 40 am, the height of the partition member 123 is 20 zm, that is, the front surface of the partition member 123, Except that the gap 250 between the second substrate 110 and the second substrate 110 was set to 20 μm, the electrophoretic display medium 100 was manufactured in the same manner as in Example 1. As a result, the display liquid 300 was uniformly distributed between the second substrate 110 and the first substrate 120. It was possible to fill in between. Furthermore, when the electrophoretic display medium 100 produced in this manner was stood and evaluated for display, no unevenness occurred. After this, the display was evaluated again after standing for one week. B) There was no unevenness in the display.
[0100] 次いで、本発明の実施例 4について説明する。第二基板 110をフレーム部材 130 の上に乗せるようにして配置した時のフレーム部材 130の高さを 30 μ m、区画部材 1 23の高さを 20 z m、すなわち区画部材 123の先端の面と、第二基板 110との隙間 2 50を 10 z mとし、表示液 300に分散させた荷電粒子 305の平均粒子径を 0. 7 μ m とし、前記基板配置工程における隙間 250が 3 μ mになるように設計した押付治具 7 00を用いた以外は、実施例 1と同様に電気泳動表示媒体 100を作製したところ、均 一に表示液 300を第二基板 110と第一基板 120との間に充填することができた。さら に、このように作製した電気泳動表示媒体 100を立て掛けて表示評価したところ、む らは発生しなかった。この後、 1週間静置した後に再度表示評価を行ったところ、表 示にむらは発生しなかった。  [0100] Next, Example 4 of the present invention will be described. When the second substrate 110 is placed on the frame member 130, the height of the frame member 130 is 30 μm, and the height of the partition member 123 is 20 zm, that is, the front surface of the partition member 123 The gap 250 between the second substrate 110 is 10 zm, the average particle diameter of the charged particles 305 dispersed in the display liquid 300 is 0.7 μm, and the gap 250 in the substrate placement step is 3 μm. The electrophoretic display medium 100 was produced in the same manner as in Example 1 except that the pressing jig 700 designed as described above was used. The display liquid 300 was uniformly distributed between the second substrate 110 and the first substrate 120. Could be filled. Furthermore, when the electrophoretic display medium 100 produced in this way was stood and evaluated for display, no unevenness occurred. After this, the display was evaluated again after standing for 1 week. As a result, no unevenness occurred in the display.
[0101] 次いで、本発明の実施例 5について説明する。第二基板 110をフレーム部材 130 の上に乗せるようにして配置した時のフレーム部材 130の高さを 65 μ m、区画部材 1 23の高さを 20 /i m、すなわち区画部材 123の先端の面と、第二基板 110との隙間 2 50を 45 μ mとし、表示液 300に分散させた荷電粒子 305の平均粒子径を 8 μ mとし 、前記基板配置工程における隙間 250が 40 μ mになるように設計した押付治具 700 を用いた以外は、実施例 1と同様に電気泳動表示媒体 100を作製したところ、均一に 表示液 300を第二基板 110と第一基板 120との間に充填することができた。さらに、 このように作製した電気泳動表示媒体 100を立て掛けて表示評価したところ、むらは 発生しなかった。この後、 1週間静置した後に再度表示評価を行ったところ、表示に むらは発生しなかった。  [0101] Next, Example 5 of the present invention will be described. When the second substrate 110 is placed on the frame member 130, the height of the frame member 130 is 65 μm, the height of the partition member 1 23 is 20 / im, that is, the front surface of the partition member 123 The gap 250 between the second substrate 110 is 45 μm, the average particle diameter of the charged particles 305 dispersed in the display liquid 300 is 8 μm, and the gap 250 in the substrate placement step is 40 μm. The electrophoretic display medium 100 was produced in the same manner as in Example 1 except that the pressing jig 700 designed as described above was used, and the display liquid 300 was uniformly filled between the second substrate 110 and the first substrate 120. We were able to. Further, when the electrophoretic display medium 100 produced in this way was stood and evaluated for display, no unevenness occurred. After this, the display was evaluated again after being allowed to stand for 1 week.
[0102] また、本発明に係る電気泳動表示媒体 100において、その隙間 250の最適値を見 出すべく比較例 1〜比較例 5に係る実験を行った。  [0102] In addition, in the electrophoretic display medium 100 according to the present invention, experiments related to Comparative Examples 1 to 5 were performed in order to find the optimum value of the gap 250.
[0103] 先ず、本発明の比較例 1について説明する。第二基板 110をフレーム部材 130の 上に乗せるようにして配置した時のフレーム部材 130の高さを 35 z m、区画部材 12 3の高さを 20 z m、すなわち区画部材 123の先端の面と、第二基板 110との隙間 25 0を 15 μ mとした以外は、実施例 1と同様に電気泳動表示媒体 100を作製したところ 、均一に表示液 300を第二基板 110と第一基板 120との間に充填することができな かった。 First, Comparative Example 1 of the present invention will be described. When the second substrate 110 is placed on the frame member 130, the height of the frame member 130 is 35 zm, the height of the partition member 12 3 is 20 zm, that is, the front surface of the partition member 123, The electrophoretic display medium 100 was produced in the same manner as in Example 1 except that the gap 250 between the second substrate 110 was 15 μm, and the display liquid 300 was uniformly distributed between the second substrate 110 and the first substrate 120. Can not be filled in between won.
[0104] 次いで、本発明の比較例 2について説明する。第二基板 110をフレーム部材 130 の上に乗せるようにして配置した時のフレーム部材 130の高さを 45 μ m、区画部材 1 23の高さを 20 z m、すなわち区画部材 123の先端の面と、第二基板 110との隙間 2 50を 25 μ mとし、前記基板配置工程における隙間 250が 20 μ mになるように設計し た押付治具 700を用いた以外は、実施例 1と同様に電気泳動表示媒体 100を作製し たところ、均一に表示液 300を第二基板 110と第一基板 120との間に充填することが できた。さらに、このように作製した電気泳動表示媒体 100を立て掛けて表示評価し たところ、むらは発生しなかった。この後、 1週間静置した後に再度表示評価を行った ところ、表示にむらが発生した。  [0104] Next, Comparative Example 2 of the present invention will be described. When the second substrate 110 is placed on the frame member 130, the height of the frame member 130 is 45 μm, and the height of the partition member 123 is 20 zm, that is, the tip surface of the partition member 123 The same as in Example 1 except that the pressing jig 700 designed so that the gap 250 with the second substrate 110 is 25 μm and the gap 250 in the substrate placement step is 20 μm is used. When the electrophoretic display medium 100 was produced, the display liquid 300 could be uniformly filled between the second substrate 110 and the first substrate 120. Further, when the electrophoretic display medium 100 produced in this manner was stood and evaluated for display, no unevenness occurred. After this, the display was evaluated again after standing for 1 week, and unevenness in the display occurred.
[0105] 次いで、本発明の比較例 3について説明する。第二基板 110をフレーム部材 130 の上に乗せるようにして配置した時のフレーム部材 130の高さを 23 a m、区画部材 1 23の高さを 20 /i m、すなわち区画部材 123の先端の面と、第二基板 110との隙間 2 50を 3 /i mとし、表示液 300に分散させた荷電粒子 305の平均粒子径を 0. 7 /i mと した以外は、実施例 1と同様に電気泳動表示媒体 100を作製したところ、均一に表示 液 300を第二基板 110と第一基板 120との間に充填することができなかった。  [0105] Next, Comparative Example 3 of the present invention will be described. When the second substrate 110 is placed on the frame member 130, the height of the frame member 130 is 23 am, the height of the partition member 1 23 is 20 / im, that is, the front surface of the partition member 123 Electrophoretic display as in Example 1 except that the gap 250 between the second substrate 110 is 3 / im and the average particle diameter of the charged particles 305 dispersed in the display liquid 300 is 0.7 / im. When the medium 100 was manufactured, the display liquid 300 could not be uniformly filled between the second substrate 110 and the first substrate 120.
[0106] 次いで、本発明の比較例 4について説明する。第二基板 110をフレーム部材 130 の上に乗せるようにして配置した時のフレーム部材 130の高さを 30 μ m、区画部材 1 23の高さを 20 /i m、すなわち区画部材 123の先端の面と、第二基板 110との隙間 2 50を 10 /i mとし、表示液 300に分散させた荷電粒子 305の平均粒子径を 0. 7 /i m とし、前記基板配置工程における隙間 250が 5 β mになるように設計した押付治具 7 00を用いた以外は、実施例 1と同様に電気泳動表示媒体 100を作製したところ、均 一に表示液 300を第二基板 110と第一基板 120との間に充填することができた。さら に、このように作製した電気泳動表示媒体 100を立て掛けて表示評価したところ、む らは発生しなかった。この後、 1週間静置した後に再度表示評価を行ったところ、表 示にむらが発生した。 [0106] Next, Comparative Example 4 of the present invention will be described. When the second substrate 110 is placed on the frame member 130, the height of the frame member 130 is 30 μm, and the height of the partition member 123 is 20 / im, that is, the front surface of the partition member 123 The gap 250 between the second substrate 110 and the second substrate 110 is 10 / im, the average particle diameter of the charged particles 305 dispersed in the display liquid 300 is 0.7 / im, and the gap 250 in the substrate placement step is 5 β m. The electrophoretic display medium 100 was produced in the same manner as in Example 1 except that the pressing jig 700 designed so as to be the same as in Example 1 was obtained. The display liquid 300 was uniformly distributed between the second substrate 110 and the first substrate 120. Can be filled in between. Furthermore, when the electrophoretic display medium 100 produced in this way was stood and evaluated for display, no unevenness occurred. After this, the display was evaluated again after standing for one week, and the display was uneven.
[0107] 次いで、本発明の比較例 5について説明する。第二基板 110をフレーム部材 130 の上に乗せるようにして配置した時のフレーム部材 130の高さを 70 a m、区画部材 1 23の高さを 20 /i m、すなわち区画部材 123の先端の面と、第二基板 110との隙間 2 50を 50 μ mとし、表示液 300に分散させた荷電粒子 305の平均粒子径を 8 μ mとし 、前記基板配置工程における隙間 250が 45 β mになるように設計した押付治具 700 を用いた以外は、実施例 1と同様に電気泳動表示媒体 100を作製したところ、均一に 表示液 300を第二基板 110と第一基板 120との間に充填することができた。さらに、 このように作製した電気泳動表示媒体 100を立て掛けて表示評価したところ、むらは 発生しなかった。この後、 1週間静置した後に再度表示評価を行ったところ、表示に むらが発生した。 [0107] Next, Comparative Example 5 of the present invention will be described. The height of the frame member 130 when the second substrate 110 is placed on the frame member 130 is 70 am, and the partition member 1 The height of 23 is 20 / im, that is, the gap 250 between the tip surface of the partition member 123 and the second substrate 110 is 50 μm, and the average particle diameter of the charged particles 305 dispersed in the display liquid 300 is 8 The electrophoretic display medium 100 was produced in the same manner as in Example 1 except that the pressing jig 700 designed so that the gap 250 in the substrate placement process was 45 β m was set to μm. The liquid 300 could be filled between the second substrate 110 and the first substrate 120. Further, when the electrophoretic display medium 100 produced in this way was stood and evaluated for display, no unevenness occurred. After this, the display was evaluated again after standing for 1 week, and the display was uneven.
[0108] 以上の実施例 1〜実施例 5と、比較例 1〜比較例 5の結果を表にしたものを図 7に 示す。隙間 250が荷電粒子 305の平均粒子径の 5倍以下であると、表示液を均一に 充填することが困難となり、かつ、むらの発生を抑制することができるという結果から、 隙間 250が荷電粒子 305の平均粒子径の 5倍以下であると、荷電粒子 305が区画 室間を移動することを抑制する効果を生じることがわかる。  FIG. 7 shows a table of the results of Examples 1 to 5 and Comparative Examples 1 to 5 described above. If the gap 250 is 5 times or less of the average particle diameter of the charged particles 305, it is difficult to uniformly fill the display liquid, and unevenness can be suppressed. It can be seen that when the average particle size of 305 is 5 times or less, the charged particles 305 have an effect of suppressing movement between the compartments.
[0109] また、第二基板 110及び第一基板 120を配置させる際に、区画部材 123の上に荷 電粒子 305が乗っていたとしても、基板間の距離が所定の距離よりも長くなることがな いように、前記基板配置工程における隙間 250は平均粒子径の 1倍以上にするのが 望ましレ、。なぜなら、隙間 250の距離が部分的に異なると、荷電粒子 305に加えられ る電界の強度が部分的に異なることになり、その結果としてむらを生じるためである。  Further, when the second substrate 110 and the first substrate 120 are disposed, even if the charged particles 305 are on the partition member 123, the distance between the substrates is longer than a predetermined distance. In order to prevent this, it is desirable that the gap 250 in the substrate placement step be at least 1 times the average particle size. This is because if the distance of the gap 250 is partially different, the intensity of the electric field applied to the charged particle 305 is partially different, resulting in unevenness.
[0110] 尚、本発明の実施の形態の電気泳動表示媒体 100では、隙間 250の距離が、隙 間 250の間に荷電粒子 305が存在したとしても液室 200内の荷電粒子 305に加えら れる力が実質的に同じになる距離であれば、電気泳動表示媒体の全体において個 々の前記液室 200内の荷電粒子 305に加えられる力が略均一になり、表示品質が 良好になる。従って、隙間 250の距離は平均粒子径の 1倍以下の距離であってもよ レ、。  In the electrophoretic display medium 100 according to the embodiment of the present invention, the distance of the gap 250 is added to the charged particles 305 in the liquid chamber 200 even if the charged particles 305 exist between the gaps 250. When the applied forces are substantially the same distance, the force applied to the charged particles 305 in each of the liquid chambers 200 in the entire electrophoretic display medium is substantially uniform, and the display quality is improved. Therefore, the distance of the gap 250 may be less than 1 times the average particle diameter.
[0111] 上述の説明では、説明を簡単にするために、電気泳動表示媒体 100を 9行 X 6列 の 54画素からなる非常に小さな表示媒体として説明したが、本発明に係る電気泳動 表示媒体はこの数字に限るものではない。  In the above description, for the sake of simplicity, the electrophoretic display medium 100 has been described as a very small display medium consisting of 54 pixels of 9 rows × 6 columns, but the electrophoretic display medium according to the present invention. Is not limited to this number.
[0112] 上述の実施例では区画部材 123の先端には第二基板 110と接触する部分が無い ものとして説明したが、区画部材 123の先端に部分的に第二基板 110と当接する当 接体 124を設けた第一基板 120を用いるようにしても良レ、。図 10及び図 11は当接体[0112] In the above embodiment, there is no portion in contact with the second substrate 110 at the tip of the partition member 123. As described above, the first substrate 120 provided with the contact member 124 that partially contacts the second substrate 110 at the tip of the partition member 123 may be used. Figures 10 and 11 are contact bodies
124が設けられた区画部材 123の一例の斜視図を示す。 The perspective view of an example of the division member 123 provided with 124 is shown.
[0113] 当接体 124として図 10のように、円柱状の柱が区画部材 123の上に所定の間隔で 複数設けられていても良いし、図 11のように細い板状の柱力 所定の間隔で区画部 材 123の上に設けられていても良い。 [0113] As shown in FIG. 10, a plurality of cylindrical columns may be provided on the partition member 123 at predetermined intervals as the contact body 124, or a thin plate-shaped column force as shown in FIG. It may be provided on the partition member 123 at intervals.
[0114] これらの当接体 124は、区画部材 123及び当接体 124を表示面側から見た場合、 区画部材 123の先端の大きさより当接体 124の先端の大きさが小さいため、荷電粒 子 305が当接体 124の先端に乗りに《なっている。 [0114] When the partition member 123 and the contact body 124 are viewed from the display surface side, these contact bodies 124 are charged because the tip of the contact body 124 is smaller than the tip of the partition member 123. The particles 305 are placed on the tip of the contact body 124.
[0115] 当接体 124は、表示面の鉛直方向から見た場合、区画部材 123の先端の大きさよ り当接体 124の先端の大きさが小さければ図 10及び図 11に示した以外の形状をし ていても良い。 [0115] When viewed from the vertical direction of the display surface, the abutting body 124 is not shown in FIGS. 10 and 11 if the size of the tip of the abutting body 124 is smaller than the size of the tip of the partition member 123. It may be shaped.
[0116] また、図 12のようにホットプレート 600を振動させる発振部 900をホットプレート 600 に当接させて設け、上述の実施例で第二基板 110を第一基板 120に近づける際に、 発振部を駆動することによって、第二基板 110若しくは第一基板 120に振動を与え ながら近づけるようにしても良い。振動を与えながら配置すれば、表示液 300の充填 の際に区画部材 123若しくは当接体 124の先端に乗っかってしまった荷電粒子 305 、それらの先端力 落下しやすくなる。  In addition, as shown in FIG. 12, an oscillation unit 900 that vibrates the hot plate 600 is provided in contact with the hot plate 600, and oscillation occurs when the second substrate 110 is brought closer to the first substrate 120 in the above-described embodiment. By driving the part, the second substrate 110 or the first substrate 120 may be brought close to each other while being vibrated. If arranged while applying vibration, the charged particles 305 that have been placed on the tip of the partition member 123 or the contact member 124 when the display liquid 300 is filled, and the tip force of these particles easily fall.
[0117] また、当接体 124は、荷電粒子 305を一段介して第二基板 110若しくは第一基板 1 20に接しても良い。  In addition, the contact body 124 may contact the second substrate 110 or the first substrate 120 through the charged particles 305 in one step.
[0118] また、上述の実施例では第一基板 120が区画部材 123を有するものとして説明し たが、第二基板 110が区画部材 123を有していても良いし、第二基板 110と第一基 板 120との両方が第一区画部材と第二区画部材とをそれぞれを有してレ、ても良レ、。 ここで第一基板 120が区画部材 123を有するとは、第一基板 120が区画部材 123を 一体に形成されてレ、ても良レ、し、単に第一基板 120が区画部材 123を載置してレ、る だけでも良い。  In the above-described embodiment, the first substrate 120 has been described as having the partition member 123. However, the second substrate 110 may have the partition member 123. Both the first board 120 and the first board 120 each have a first partition member and a second partition member. Here, the first substrate 120 having the partition member 123 means that the first substrate 120 is formed by integrally forming the partition member 123, and the first substrate 120 simply places the partition member 123 thereon. You can just do it.
[0119] また、上述の実施例では荷電粒子 305が球状であるとして説明した力 粒子の形 状が板状等、球状でない粒子を使用した電気泳動表示媒体も存在するので、その場 合は粒子の形状や柔軟性等に合わせて適宜最適な隙間 250の間隔を設定するよう にすれば良い。 [0119] In addition, there is an electrophoretic display medium using non-spherical particles such as a force particle having a spherical shape such as a charged particle 305 described as being spherical in the above-described embodiment. In this case, an optimal gap 250 may be appropriately set according to the shape and flexibility of the particles.
[0120] また、上述の実施例では第二基板 110及び第一基板 120をエポキシ接着剤 140で 固定したが、固定する方法としてはボルトや型枠やクリップ等、他の手段を用いても 良い。  [0120] In the above-described embodiment, the second substrate 110 and the first substrate 120 are fixed with the epoxy adhesive 140. However, other means such as a bolt, a formwork, and a clip may be used as the fixing method. .
[0121] また、上述の第一実施例では、フレーム部材 130が熱可塑性樹脂であるとして説明 したが、フレーム部材 130をゴム等の弾性体にして、 2段階に押付治具 700が動作で きるようにし、第一の段階に押付治具 700を動作させて第二基板 110を第一基板 12 0側に押付けた後、第二基板 110と第一基板 120との間に表示液 300を充填し、第 二の段階に押付治具 700を動作させて隙間 250を所定の間隔にした後にフレーム 部材の周囲に固定部材 140を配置して固定しても良い。  [0121] In the first embodiment described above, the frame member 130 has been described as being a thermoplastic resin. However, the pressing member 700 can be operated in two stages by using the frame member 130 as an elastic body such as rubber. In the first stage, after the pressing jig 700 is operated to press the second substrate 110 toward the first substrate 120, the display liquid 300 is filled between the second substrate 110 and the first substrate 120. Then, after the pressing jig 700 is operated in the second stage to set the gap 250 to a predetermined interval, the fixing member 140 may be arranged and fixed around the frame member.
[0122] また、上述の実施例では、フレーム部材 130が熱可塑性樹脂であるとして説明した 力 フレーム部材 130を高粘度もしくは半硬化状態の熱硬化性樹脂にして、基板を 配置する際は、押付治具 700で第二基板 110を第一基板 120側に押付けた後、熱 硬化性樹脂のフレーム部材 130を加熱して、第二基板 110及び第一基板 120を固 定するようにしても良い。  [0122] Further, in the above-described embodiment, the force is described when the frame member 130 is made of a thermoplastic resin. When the substrate is placed with the frame member 130 made of a high-viscosity or semi-cured thermosetting resin. After the second substrate 110 is pressed against the first substrate 120 side by the jig 700, the second substrate 110 and the first substrate 120 may be fixed by heating the frame member 130 of the thermosetting resin. .
[0123] また、上述の実施例では、フレーム部材 130が熱可塑性樹脂であるとして説明した 、フレーム部材 130を光硬化性樹脂にして、基板を配置する際は、押付治具 700 で第二基板 110を第一基板 120側に押付けた後、光硬化性樹脂のフレーム部材 13 0に光線を照射して、第二基板 110及び第一基板 120を固定するようにしても良い。  [0123] In the above-described embodiment, the frame member 130 is described as being a thermoplastic resin. When the frame member 130 is made of a photocurable resin and the substrate is placed, the pressing jig 700 is used to place the second substrate. After pressing 110 to the first substrate 120 side, the second substrate 110 and the first substrate 120 may be fixed by irradiating light to the photocurable resin frame member 130.
[0124] また、上記光硬化性樹脂の中でも、紫外線硬化樹脂を用いると、硬化時間が短い ため、なお良い。  [0124] Further, among the above-mentioned photo-curable resins, it is more preferable to use an ultraviolet curable resin since the curing time is short.
[0125] また、隙間 250の距離が荷電粒子 305の粒子径よりも小さい場合には、電極に加え られる電圧によって荷電粒子 305に加わる電界が実質的に均一になるように、少なく とも区画部材 123若しくは保護膜 112の材質を、塑性体若しくは弾性体で構成しても 良い。  [0125] When the distance of the gap 250 is smaller than the particle diameter of the charged particles 305, at least the partition member 123 so that the electric field applied to the charged particles 305 by the voltage applied to the electrodes is substantially uniform. Alternatively, the material of the protective film 112 may be a plastic body or an elastic body.
[0126] また、上記実施例では、保護膜 112、保護膜 122が形成されてレ、るものとして説明 したが、保護膜 112、矛膜 122は形成されていなくても良い。  In the above embodiment, the protective film 112 and the protective film 122 are described as being formed. However, the protective film 112 and the consistent film 122 may not be formed.

Claims

請求の範囲  The scope of the claims
[1] 第一基板(120)と第二基板(110)とから構成される一対の基板と、  [1] a pair of substrates composed of a first substrate (120) and a second substrate (110);
少なくとも前記第一基板(120)に区画部材(123)が設けられ、前記一対の基板と 前記区画部材(123)とによって区画された液室(200)に、荷電粒子(305)と前記荷 電粒子(305)を分散させる分散媒(330)とからなる表示液(300)が充填された電気 泳動表示媒体(100)の製造方法において、  A partition member (123) is provided at least on the first substrate (120), and charged particles (305) and the charge are charged in a liquid chamber (200) partitioned by the pair of substrates and the partition member (123). In the method for producing an electrophoretic display medium (100) filled with a display liquid (300) comprising a dispersion medium (330) for dispersing particles (305),
前記第一基板(120)に設けられた区画部材(123)の、前記第二基板(110)若しく は前記第二基板(110)に設けられた区画部材に対向する第一対向面と、前記第二 基板(110)若しくは前記第二基板(110)に設けられた区画部材の前記第一対向面 に対向する第二対向面との隙間(250)を所定距離よりも離間させた状態で、少なくと も前記第一基板(120)の上に前記表示液(300)を配置する表示液配置工程と、 前記表示液配置工程後、前記第一対向面と前記第二対向面との間の隙間(250) を前記荷電粒子(305)が自由に通過不能な所定距離になるように、前記一対の基 板を配置する基板配置工程と、  A first facing surface of the partition member (123) provided on the first substrate (120) facing the partition member provided on the second substrate (110) or the second substrate (110); In a state where the gap (250) between the second substrate (110) or the second facing surface facing the first facing surface of the partition member provided on the second substrate (110) is separated from a predetermined distance. A display liquid disposing step of disposing at least the display liquid (300) on the first substrate (120); and after the display liquid disposing step, between the first opposing surface and the second opposing surface. A substrate disposing step of disposing the pair of substrates so that the charged particles (305) cannot pass through the gap (250) at a predetermined distance.
前記基板配置工程によって配置された前記一対の基板を相互に固定する固定ェ 程とからなる電気泳動表示媒体(100)の製造方法。  A method of manufacturing an electrophoretic display medium (100) comprising a fixing step for fixing the pair of substrates arranged in the substrate arranging step to each other.
[2] 前記荷電粒子(305)が略球状であり、 [2] The charged particle (305) is substantially spherical,
前記基板配置工程にぉレ、て、前記隙間(250)の所定距離が前記荷電粒子(305) の平均粒子径の 5倍以下になるように、前記一対の基板を配置することを特徴とする 請求項 1記載の電気泳動表示媒体(100)の製造方法。  The pair of substrates are arranged so that a predetermined distance of the gap (250) is 5 times or less of an average particle diameter of the charged particles (305) in the substrate arranging step. The method for producing an electrophoretic display medium (100) according to claim 1.
[3] 前記第一対向面と前駆第二対向面の少なくともいずれか一方には電極(111、 12 1)が設けられ、 [3] An electrode (111, 121) is provided on at least one of the first facing surface and the second precursor facing surface,
前記基板配置工程において前記前記隙間(250)の所定距離が、前記第一対向面 と前記第二対向面との間に前記荷電粒子(305)が存在したとしても前記電極(111 、 121)に加えられる電圧によって生じる電界から前記液室(200)内の荷電粒子(30 5)に加えられる力が実質的に同じになる距離になるように、前記一対の基板を配置 することを特徴とする請求項 1に記載の電気泳動表示媒体(100)の製造方法。  Even if the charged particles (305) exist between the first facing surface and the second facing surface at a predetermined distance of the gap (250) in the substrate arranging step, the electrodes (111, 121) The pair of substrates are arranged so that the force applied to the charged particles (305) in the liquid chamber (200) from the electric field generated by the applied voltage is substantially the same. The method for producing an electrophoretic display medium (100) according to claim 1.
[4] 前記荷電粒子(305)が略球状であり、 前記基板配置工程にぉレ、て、前記隙間(250)の所定距離が前記荷電粒子(305) の平均粒子径の 1倍以上になるように、前記一対の基板を配置することを特徴とする 請求項 3記載の電気泳動表示媒体(100)の製造方法。 [4] The charged particles (305) are substantially spherical, The pair of substrates are arranged so that a predetermined distance of the gap (250) is at least one time larger than an average particle diameter of the charged particles (305) in the substrate arranging step. The method for producing an electrophoretic display medium (100) according to claim 3.
[5] 前記表示液配置工程において、前記一対の基板を対向させた状態で前記一対の 基板間に表示液(300)を充填することを特徴とする請求項 1に記載の電気泳動表示 媒体 (100)の製造方法。  [5] The electrophoretic display medium according to [1], wherein in the display liquid disposing step, the display liquid (300) is filled between the pair of substrates in a state where the pair of substrates are opposed to each other. 100) production method.
[6] 少なくとも第一基板(120)に設けられた前記区画部材(123)若しくは第一基板(1 20)には当接体( 124)が設置してあり、  [6] At least the partition member (123) or the first substrate (120) provided on the first substrate (120) is provided with a contact body (124),
前記基板配置工程において、前記当接体(124)が、第二基板(110)若しくは前記 第二基板(110)に設けられた区画部材と接することを特徴とする請求項 1に記載の 電気泳動表示媒体(100)の製造方法。  2. The electrophoresis according to claim 1, wherein, in the substrate placement step, the contact body (124) is in contact with a second substrate (110) or a partition member provided on the second substrate (110). Manufacturing method of display medium (100).
[7] 前記区画部材(123)は前記第一基板(120)若しくは前記第二基板(110)から突 出し、前記第一対向面若しくは前記第二対向面が規定された端面を有し、前記当接 体(124)は前記区画部材(123)の端面に設けられると共に前記区画部材(123)の 端面より突出する端面を有し、前記当接体(124)の端面は前記区画部材(123)の 端面よりも小さいことを特徴とする請求項 6に記載の電気泳動表示媒体(100)の製 造方法。  [7] The partition member (123) protrudes from the first substrate (120) or the second substrate (110), and has an end surface in which the first opposing surface or the second opposing surface is defined, The contact body (124) is provided on the end surface of the partition member (123) and has an end surface protruding from the end surface of the partition member (123). The end surface of the contact body (124) is the end surface of the partition member (123). The method for producing an electrophoretic display medium (100) according to claim 6, wherein the electrophoretic display medium (100) is smaller than an end surface of the electrophoretic display medium.
[8] 前記基板配置工程において、振動を与えながら前記一対の基板を配置することを 特徴とする請求項 1に記載の電気泳動表示媒体(100)の製造方法。  8. The method for manufacturing an electrophoretic display medium (100) according to claim 1, wherein in the substrate arranging step, the pair of substrates are arranged while applying vibration.
[9] 少なくとも前記第一基板(120)に、画像を表示するための表示領域の周囲を囲む ように熱可塑性樹脂若しくは刺激硬化性樹脂からなるフレーム部材( 130)を配置す るフレーム部材配置工程を有し、  [9] A frame member arranging step of arranging a frame member (130) made of a thermoplastic resin or a stimulus curable resin so as to surround at least the first substrate (120) so as to surround a display area for displaying an image. Have
前記一対の基板の少なくとも一方若しくは前記フレーム部材(130)には前記表示 液(300)を充填するための注入口(401)が形成されており、  An inlet (401) for filling the display liquid (300) is formed in at least one of the pair of substrates or the frame member (130),
前記表示液配置工程において、前記第一対向面と前記第二対向面との距離が前 記隙間(250)の所定距離よりも離された状態で、前記注入口(401)から前記表示液 (300)を注入して前記一対の基板間に充填し、  In the display liquid disposing step, the display liquid (401) is inserted from the inlet (401) in a state where the distance between the first facing surface and the second facing surface is separated from a predetermined distance of the gap (250). 300) and filling between the pair of substrates,
前記基板配置工程において、少なくとも前記第二基板(110)を前記第一基板(12 0)に近づけるように移動させ、前記フレーム部材(130)の高さを縮めて前記一対の 基板を配置し、 In the substrate placement step, at least the second substrate (110) is replaced with the first substrate (12 0), the height of the frame member (130) is reduced, and the pair of substrates are arranged,
前記固定工程後、前記注入口(401)を封止する封止工程を有することを特徴とす る請求項 1に記載の電気泳動表示媒体(100)の製造方法。  The method for manufacturing an electrophoretic display medium (100) according to claim 1, further comprising a sealing step of sealing the injection port (401) after the fixing step.
少なくとも前記第一基板(120)に、画像を表示するための表示領域の周囲を囲む ように熱可塑性樹脂若しくは刺激硬化性樹脂からなるフレーム部材 ( 130)を配置す るフレーム部材配置工程を有し、  A frame member disposing step of disposing at least a frame member (130) made of a thermoplastic resin or a stimulus curable resin so as to surround a periphery of a display region for displaying an image on the first substrate (120); ,
前記一対の基板の少なくとも一方若しくは前記フレーム部材(130)には前記表示 液(300)を充填するための注入口(401)と排出口(402)が形成されており、 前記表示液配置工程において、前記第一対向面と前記第二対向面との距離が前 記隙間(250)の所定距離よりも離された状態で、前記注入口(401)から前記表示液 (300)を注入して前記一対の基板間に充填しながら余剰の前記表示液(300)を前 記排出口(402)から排出し、  At least one of the pair of substrates or the frame member (130) is formed with an inlet (401) and an outlet (402) for filling the display liquid (300). The display liquid (300) is injected from the injection port (401) in a state where the distance between the first opposing surface and the second opposing surface is separated from the predetermined distance of the gap (250). Excess display liquid (300) is discharged from the discharge port (402) while filling between the pair of substrates,
前記基板配置工程において、少なくとも前記第二基板(110)を前記第一基板(12 0)に近づけるように移動させ、前記フレーム部材(130)の高さを縮めて前記一対の 基板を配置し、  In the substrate placement step, at least the second substrate (110) is moved so as to approach the first substrate (120), the height of the frame member (130) is reduced, and the pair of substrates is placed,
前記固定工程後、前記注入口(401)と前記排出口(402)を封止する封止工程を 有することを特徴とする請求項 1に記載の電気泳動表示媒体(100)の製造方法。 前記基板配置工程において、前記フレーム部材(130)は弾性を有する状態である ことを特徴とする請求項 9若しくは請求項 10に記載の電気泳動表示媒体(100)の製 造方法。  The method for manufacturing an electrophoretic display medium (100) according to claim 1, further comprising a sealing step of sealing the inlet (401) and the outlet (402) after the fixing step. The method for manufacturing an electrophoretic display medium (100) according to claim 9 or 10, wherein the frame member (130) is in an elastic state in the substrate disposing step.
前記フレーム部材(130)は熱可塑性樹脂であり、  The frame member (130) is a thermoplastic resin,
前記基板配置工程において、前記フレーム部材(130)を加熱して軟化させつつ、 少なくとも一方の基板を他方の基板に近づけるように移動させて前記一対の基板を 配置し、  In the substrate placement step, the frame member (130) is heated and softened, and at least one of the substrates is moved closer to the other substrate to place the pair of substrates,
前記固定工程において、前記フレーム部材(130)を冷却して前記一対の基板間 の距離を固定することを特徴とする請求項 9若しくは請求項 10に記載の電気泳動表 示媒体 (100)の製造方法。 [13] 前記フレーム部材(130)は加熱による刺激で硬化する熱硬化性樹脂であり、 前記固定工程において、前記フレーム部材(130)を加熱して硬化させることにより 前記一対の基板間の距離を固定することを特徴とする請求項 9若しくは請求項 10に 記載の電気泳動表示媒体(100)の製造方法。 The manufacturing method of the electrophoretic display medium (100) according to claim 9 or 10, wherein, in the fixing step, the frame member (130) is cooled to fix a distance between the pair of substrates. Method. [13] The frame member (130) is a thermosetting resin that cures when stimulated by heating. In the fixing step, the frame member (130) is heated and cured to reduce a distance between the pair of substrates. The method for producing an electrophoretic display medium (100) according to claim 9 or 10, wherein the electrophoretic display medium (100) is fixed.
[14] 前記フレーム部材(130)は光による刺激で硬化する光硬化性樹脂であり、 [14] The frame member (130) is a photocurable resin that is cured by stimulation with light,
前記固定工程において、前記フレーム部材(130)を光照射により硬化させることに より前記一対の基板間の距離を固定することを特徴とする請求項 9若しくは請求項 1 The distance between the pair of substrates is fixed by curing the frame member (130) by light irradiation in the fixing step.
0に記載の電気泳動表示媒体(100)の製造方法。 A method for producing the electrophoretic display medium (100) according to 0.
[15] 前記光硬化性樹脂が、紫外線を照射することにより硬化する紫外線硬化性樹脂で あることを特徴とする請求項 14に記載の電気泳動表示媒体(100)の製造方法。 15. The method for producing an electrophoretic display medium (100) according to claim 14, wherein the photocurable resin is an ultraviolet curable resin that is cured by irradiation with ultraviolet rays.
[16] 第一基板(120)と第二基板(110)とから構成される一対の基板と、 [16] a pair of substrates composed of a first substrate (120) and a second substrate (110);
少なくとも前記第一基板(120)に設けられた区画部材(123)と、前記一対の基板と によって区画された液室(200)に、荷電粒子(305)と前記荷電粒子(305)を分散さ せる分散媒(330)とからなる表示液(300)が充填された電気泳動表示媒体(100) において、  Charged particles (305) and charged particles (305) are dispersed in at least a partition member (123) provided on the first substrate (120) and a liquid chamber (200) partitioned by the pair of substrates. An electrophoretic display medium (100) filled with a display liquid (300) comprising a dispersion medium (330)
前記第一基板(120)に設けられた区画部材(123)の前記第二基板(110)若しく は前記第二基板(110)に設けられた区画部材に対向する第一対向面と、前記第二 基板(110)若しくは前記第二基板(110)に設けられた区画部材の前記第一対向面 に対向する第二対向面との隙間(250)を所定距離よりも離間させた状態で、少なくと も前記第一基板(120)の上に表示液(300)を配置する表示液配置工程と、 前記表示液配置工程後、前記第一対向面と前記第二対向面との距離を前記荷電 粒子(305)が自由に通過不能な隙間(250)の所定距離になるように前記一対の基 板を配置する基板配置工程と、  A first facing surface of the partition member (123) provided on the first substrate (120) facing the second substrate (110) or the partition member provided on the second substrate (110); In a state where the gap (250) between the second opposing surface facing the first opposing surface of the partition member provided on the second substrate (110) or the second substrate (110) is separated from a predetermined distance, At least a display liquid disposing step of disposing a display liquid (300) on the first substrate (120), and after the display liquid disposing step, a distance between the first facing surface and the second facing surface is A substrate disposing step of disposing the pair of substrates so that a predetermined distance of the gap (250) through which the charged particles (305) cannot freely pass is set;
前記基板配置工程によって配置された前記一対の基板を相互に固定する固定ェ 程とからなる電気泳動表示媒体(100)。  An electrophoretic display medium (100) comprising a fixing step for fixing the pair of substrates arranged in the substrate arranging step to each other.
[17] 第一基板(120)と第二基板(110)とから構成される一対の基板と、 [17] a pair of substrates composed of a first substrate (120) and a second substrate (110);
前記第一基板( 120)に設けられた区画部材(123)、若しくは前記区画部材(123) 及び前記第二基板(110)に設けられた区画部材とを備え、前記一対の基板と前記 区画部材(123)とによって区画された液室(200)に、荷電粒子(305)と前記荷電粒 子(305)を分散させる分散媒(330)とからなる表示液(300)が充填された電気泳動 表示媒体(100)において、 A partition member (123) provided on the first substrate (120), or a partition member provided on the partition member (123) and the second substrate (110), the pair of substrates and the The liquid chamber (200) partitioned by the partition member (123) was filled with a display liquid (300) composed of charged particles (305) and a dispersion medium (330) for dispersing the charged particles (305). In the electrophoresis display medium (100),
前記第一基板(120)に設けられた区画部材(123)に設けられて前記第二基板(1 10)若しくは前記第二基板(110)に設けられた区画部材に対向する第一対向面と、 前記第二基板(110)若しくは前記第二基板(110)に設けられた区画部材に設けら れて前記第一対向面に対向する第二対向面との距離を前記荷電粒子(305)が自由 に通過不能な隙間(250)の所定距離になるように前記一対の基板が配置された電 気泳動表示媒体(100)。  A first facing surface provided on a partition member (123) provided on the first substrate (120) and facing the partition member provided on the second substrate (110) or the second substrate (110); The charged particle (305) has a distance from a second opposing surface provided on the second substrate (110) or a partition member provided on the second substrate (110) and facing the first opposing surface. An electrophoretic display medium (100) in which the pair of substrates are arranged so as to be a predetermined distance of a gap (250) that cannot freely pass.
[18] 前記荷電粒子(305)が略球状であり、  [18] The charged particle (305) is substantially spherical,
前記隙間(250)の所定距離が前記荷電粒子(305)の平均粒子径の 5倍以下であ ることを特徴とする請求項 17に記載の電気泳動表示媒体(100)。  The electrophoretic display medium (100) according to claim 17, wherein the predetermined distance of the gap (250) is not more than 5 times the average particle diameter of the charged particles (305).
[19] 前記第一対向面と前駆第二対向面の少なくともいずれか一方には電極(111、 12 1)が設けられ、  [19] An electrode (111, 121) is provided on at least one of the first facing surface and the precursor second facing surface,
前記隙間(250)の所定距離は、前記第一対向面と前記第二対向面との間に前記 荷電粒子(305)が存在したとしても前記電極(111、 121)に加えられる電圧によって 生じる電界から前記液室(200)内の荷電粒子(305)に加えられる力が実質的に同 じになる距離であることを特徴とする請求項 17に記載の電気泳動表示媒体(100)。  The predetermined distance of the gap (250) is an electric field generated by a voltage applied to the electrodes (111, 121) even if the charged particles (305) exist between the first facing surface and the second facing surface. The electrophoretic display medium (100) according to claim 17, wherein the distance applied to the charged particles (305) in the liquid chamber (200) is substantially the same.
[20] 前記荷電粒子(305)が略球状であり、  [20] The charged particle (305) is substantially spherical,
前記隙間(250)の所定距離が前記荷電粒子(305)の平均粒子径の 1倍以上であ ることを特徴とする請求項 19記載の電気泳動表示媒体。  The electrophoretic display medium according to claim 19, wherein the predetermined distance of the gap (250) is one or more times the average particle diameter of the charged particles (305).
[21] 前記第一基板(120)に設けられた区画部材(123)の、前記第一基板(120)から 突出している先端の少なくとも一部に設けられて、前記第二基板(110)若しくは前記 第二基板(110)に設けられた区画部材と接する当接体(124)を備えたことを特徴と する請求項 17に記載の電気泳動表示媒体(100)。  [21] The partition member (123) provided on the first substrate (120) is provided at least at a part of the tip protruding from the first substrate (120), and the second substrate (110) or The electrophoretic display medium (100) according to claim 17, further comprising an abutment body (124) in contact with a partition member provided on the second substrate (110).
[22] 前記第一基板(120)に設けられた区画部材(123)は、前記第一基板(120)から 突出して前記第一対向面が規定された端面を有し、前記当接体(124)は前記区画 部材(123)の端面に設けられると共に前記区画部材(123)の端面より突出する端面 を有し、前記当接体(124)の端面は前記区画部材(123)の端面よりも小さいことを 特徴とする請求項 21に記載の電気泳動表示媒体(100)。 [22] The partition member (123) provided on the first substrate (120) has an end surface protruding from the first substrate (120) and defining the first facing surface, and the contact body ( 124) is provided on the end surface of the partition member (123) and projects from the end surface of the partition member (123) The electrophoretic display medium (100) according to claim 21, wherein an end surface of the contact body (124) is smaller than an end surface of the partition member (123).
[23] 前記一対の基板間に前記一対の基板と密着して設けられ、且つ画像を表示するた めの表示領域の周囲を囲む熱可塑性樹脂若しくは刺激硬化性樹脂からなるフレー ム部材(130)を備えたことを特徴とする請求項 17に記載の電気泳動表示媒体(100[23] A frame member (130) made of a thermoplastic resin or a stimulus-curable resin that is provided in close contact with the pair of substrates and surrounds a display area for displaying an image. The electrophoretic display medium (100) according to claim 17, further comprising:
) o ) o
[24] 前記フレーム部材(130)が熱可塑性樹脂であることを特徴とする請求項 23に記載 の電気泳動表示媒体(100)。  24. The electrophoretic display medium (100) according to claim 23, wherein the frame member (130) is a thermoplastic resin.
[25] 前記フレーム部材(130)が加熱による刺激で硬化する熱硬化性樹脂であることを 特徴とする請求項 23に記載の電気泳動表示媒体(100)。 25. The electrophoretic display medium (100) according to claim 23, wherein the frame member (130) is a thermosetting resin that is cured by a stimulus by heating.
[26] 前記フレーム部材(130)が光による刺激で硬化する光硬化性樹脂であることを特 徴とする請求項 23に記載の電気泳動表示媒体(100)。 26. The electrophoretic display medium (100) according to claim 23, wherein the frame member (130) is a photocurable resin that is cured by light stimulation.
[27] 前記光硬化性樹脂が、紫外線を照射することにより硬化する紫外線硬化性樹脂で あることを特徴とする請求項 26に記載の電気泳動表示媒体(100)。 27. The electrophoretic display medium (100) according to claim 26, wherein the photocurable resin is an ultraviolet curable resin that is cured by irradiation with ultraviolet rays.
PCT/JP2006/311923 2005-06-30 2006-06-14 Method for manufacturing electrophoretic display medium, and electrophoretic display medium WO2007004396A1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102338962A (en) * 2010-07-14 2012-02-01 乐金显示有限公司 Electrophoretic display device and method of fabrication thereof
CN110908212A (en) * 2019-12-20 2020-03-24 无锡威峰科技股份有限公司 Display plasma module with double-layer exposure structure and manufacturing method thereof

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010039356A (en) * 2008-08-07 2010-02-18 Bridgestone Corp Apparatus and method for manufacturing panel for information display
JP2010072070A (en) * 2008-09-16 2010-04-02 Konica Minolta Holdings Inc Electrochemical display element and method of manufacturing the same
KR20120029706A (en) * 2010-09-17 2012-03-27 삼성전기주식회사 An electronic paper display device and a method for manufacturing the same
KR20120035635A (en) * 2010-10-06 2012-04-16 삼성전기주식회사 Electronic paper display device and method for manufacturing the same
JP2012093384A (en) * 2010-10-22 2012-05-17 Seiko Epson Corp Display sheet, display device and electronic apparatus

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01177517A (en) * 1988-01-06 1989-07-13 Kinseki Ltd Electrophorectic display device
JP2000352945A (en) * 1999-06-09 2000-12-19 Canon Inc Display device and its production
JP2005164950A (en) * 2003-12-02 2005-06-23 Chemitoronics Co Ltd Electrophoretic color panel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01177517A (en) * 1988-01-06 1989-07-13 Kinseki Ltd Electrophorectic display device
JP2000352945A (en) * 1999-06-09 2000-12-19 Canon Inc Display device and its production
JP2005164950A (en) * 2003-12-02 2005-06-23 Chemitoronics Co Ltd Electrophoretic color panel

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102338962A (en) * 2010-07-14 2012-02-01 乐金显示有限公司 Electrophoretic display device and method of fabrication thereof
US8681415B2 (en) 2010-07-14 2014-03-25 Lg Display Co., Ltd. Electrophoretic display device and fabrication method thereof
CN110908212A (en) * 2019-12-20 2020-03-24 无锡威峰科技股份有限公司 Display plasma module with double-layer exposure structure and manufacturing method thereof

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