WO2006125353A1 - Epurateur a purification catalytique et concentration pour le traitement d’un gaz organique - Google Patents

Epurateur a purification catalytique et concentration pour le traitement d’un gaz organique Download PDF

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Publication number
WO2006125353A1
WO2006125353A1 PCT/CN2005/002261 CN2005002261W WO2006125353A1 WO 2006125353 A1 WO2006125353 A1 WO 2006125353A1 CN 2005002261 W CN2005002261 W CN 2005002261W WO 2006125353 A1 WO2006125353 A1 WO 2006125353A1
Authority
WO
WIPO (PCT)
Prior art keywords
catalytic purification
adsorption
organic waste
adsorption wheel
desorption
Prior art date
Application number
PCT/CN2005/002261
Other languages
English (en)
Chinese (zh)
Inventor
Lihui Zhong
Shenxiu Zhong
Original Assignee
Lihui Zhong
Shenxiu Zhong
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lihui Zhong, Shenxiu Zhong filed Critical Lihui Zhong
Publication of WO2006125353A1 publication Critical patent/WO2006125353A1/fr

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/07Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases in which combustion takes place in the presence of catalytic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30Physical properties of adsorbents
    • B01D2253/34Specific shapes
    • B01D2253/342Monoliths
    • B01D2253/3425Honeycomb shape

Definitions

  • the utility model relates to an exhaust gas purifying device, in particular to a concentrated catalytic purifying device for treating industrial organic waste gas. Background technique
  • the applicant discloses a "combined industrial exhaust catalytic purification furnace" in a utility model patent 92209439.
  • X which is independent of a catalytic reactor, a preheater, a heat pipe heat exchanger, a butterfly valve group, a cold air valve, a base, and the like.
  • the assembly is directly assembled into a combined monolithic structure using a sealing surface, and a noble metal non-precious metal double catalyst multi-layer bed is used.
  • the device is manufactured and used in a low cost, is easy to maintain, and can purify different organic exhaust gases, but the device is only applicable.
  • the direct catalytic purification process is to directly pass the benzene series and other organic waste gases and the oxygen in the air in the industrial production to the catalytic bed of the catalytic purification furnace at a certain temperature and flow rate, and occur on the surface of the catalyst.
  • the oxidation reaction produces odorless and harmless carbon dioxide and water for the purpose of eliminating pollution.
  • a catalytic purification process under conditions of low concentration of organic pollutants and large displacement, in order to bring the exhaust gas to a light-off temperature, it is necessary to consume a large amount of energy to preheat it.
  • the utility model aims to overcome the defects of the existing concentrated catalytic purification device, and provides a treatment industry which integrates adsorption and catalytic combustion of organic waste gas, can save a large amount of energy, and has no secondary pollution in the purification process, and has high purification rate.
  • a concentrated catalytic purification device for organic waste gas is a concentrated catalytic purification device for organic waste gas.
  • the present invention provides a concentrated catalytic purification device for treating industrial organic waste gas, comprising a catalytic purification furnace 40, characterized in that it has a rotary separation mechanism 10, an input end of the rotary separation mechanism and a gas input pipe. 20 is connected, and the output ends thereof are respectively connected to the inlet of the catalytic purification furnace 40 and the purified gas exhaust pipe 131, and the outlet of the catalytic purification furnace is connected to the desorption circulating fan 30.
  • the rotary separating mechanism 10 includes a rotary suction wheel 11 and a drive mechanism 12 which is rotatably mounted on the bracket 13 and rotatably coupled to a drive mechanism 12 mounted on the lower outer side of the suction wheel.
  • the adsorption wheel 11 has a cylindrical rim 111.
  • the outer circumference of the rim is provided with a chain 121 for connecting with the driving mechanism 12.
  • the adsorption wheel is filled with a honeycomb-shaped active fiber sheet 115 for adsorbing organic waste. Nearly three quarters form the adsorption zone 11A, and another about a quarter of the space forms the desorption zone 11B, and the desorption zone is connected to the catalytic purification furnace 40 through a pipe.
  • the driving mechanism 12 is a sprocket chain mechanism, which includes a chain 121, a sprocket 122 and a speed reducer 123.
  • the chain 121 is fixed on the outer circumference of the adsorption wheel 11, and the sprocket 122 is mounted on the output shaft of the speed reducer 123 at the bottom of the bracket 13. Above, the reducer is connected to the motor.
  • the input end of the catalytic purification furnace 40 is connected to the outlet of the adsorption wheel desorption zone 11B via a pipe, and the output end thereof is connected to the desorption cycle fan 30 via a pipe, and the desorption cycle fan is connected to the inlet of the desorption zone 11B of the adsorption wheel 11.
  • the positive effect of the utility model is that it integrates the adsorption and concentration and catalytic combustion functions of the organic man-made gas, and the organic waste in the industrial waste gas can be adsorbed and separated by the rotary separation mechanism, and then pumped to the catalytic purification furnace for concentrated catalytic combustion. , so that the industrial building gas is continuously and completely purified, and since the hot air of the concentrated catalytic purification furnace is sent to the rotating separation mechanism, there is The machine waste is desorbed, so that a large amount of energy can be saved, the purification process is continuous and stable, no secondary pollution, high purification rate, small volume of the device, low cost and low operating cost.
  • FIG. 1 is a schematic view of the overall structure of the present invention.
  • Figure 2 is a plan view of Figure 1.
  • FIG. 3 is a schematic view of the structure of the adsorption wheel of the present invention, wherein FIG. 3A is a front view of the adsorption wheel, FIG. 3B is a side view of FIG. 3A, FIG. 3C is a top view of FIG. 3A, and FIG. 3D is a schematic view of the connection of the adsorption wheel, FIG. Schematic diagram of the adsorption zone of the adsorption wheel.
  • FIG. 4 is a schematic view showing the structure of the drive mechanism. detailed description
  • the concentrated catalytic purification device for treating industrial organic waste gas of the present invention comprises a rotary separation mechanism 10, a desorption circulation fan 30 and a catalytic purification furnace 40, wherein the catalytic purification furnace 40 adopts a combination of 92209439.
  • the industrial exhaust catalytic purification furnace the main point of the utility model is that a rotary separating mechanism 10 is provided, the structure of which is shown in Fig. 3, and the rotary separating mechanism comprises a rotary adsorption wheel 11 and a driving mechanism 12, as shown in Fig. 3A.
  • Fig. 10 the structure of which is shown in Fig. 3
  • the rotary separating mechanism comprises a rotary adsorption wheel 11 and a driving mechanism 12, as shown in Fig. 3A.
  • the adsorption wheel 11 has a cylindrical rim 111 made of metal, and the spokes 112 are provided in the rim, and a chain 121 for connecting to the drive mechanism 12 is fixed to the outer circumference of the rim.
  • a bushing 113 is mounted in the center of the rim, and an axle 114 is mounted in the bushing, and both ends of the axle are supported on the bracket 13.
  • Fig. 3D a bushing 113 is mounted in the center of the rim, and an axle 114 is mounted in the bushing, and both ends of the axle are supported on the bracket 13.
  • the adsorption wheel is filled with an active fiber sheet 115 for adsorbing organic waste, which may be an activated carbon fiber sheet or other fiber sheet, which is arranged in a wave shape along the circumference, and between each two layers of the fiber sheet A living fiber spacer is separated, and a honeycomb passage is formed between the waveforms of the fiber sheet, thereby forming an adsorption zone 11A in a space of nearly three quarters of the adsorption wheel, and the organic waste gas is rotated when the adsorption wheel rotates The organic waste is adsorbed on the fiber sheet 115 through the adsorption passage 11A in the axial direction through the honeycomb passage.
  • an active fiber sheet 115 for adsorbing organic waste which may be an activated carbon fiber sheet or other fiber sheet, which is arranged in a wave shape along the circumference, and between each two layers of the fiber sheet A living fiber spacer is separated, and a honeycomb passage is formed between the waveforms of the fiber sheet, thereby forming an adsorption
  • the driving mechanism 12 is a sprocket chain mechanism. As shown in FIG. 3A and FIG. 4, the driving mechanism includes a chain 121 and a sprocket 122 and a speed reducer 123.
  • the sprocket 122 is mounted on the reducer 123 at the bottom of the bracket 13. On the output shaft, the reducer is connected to a motor (not shown). As shown in Figs. 1 and 2, the input end of the rotary separating mechanism is connected to the organic exhaust gas inlet pipe 20, and the output end thereof is connected to the inlet of the catalytic converter 40 and the purge gas exhaust pipe 1 31, respectively.
  • the input end of the catalytic purification furnace is connected to the outlet of the adsorption wheel desorption zone 11B via a pipe, and the output end thereof is connected to the desorption circulation fan 30 via a pipe, and the desorption cycle fan is connected to the inlet of the desorption zone 11B of the adsorption wheel 11, and the catalytic purification furnace is connected.
  • a tapered housing 13 is mounted on both sides of the adsorption wheel 11, and the two ends of the housing are respectively connected to the exhaust gas inlet pipe 20 and the purge gas exhaust pipe 1 31 (see Figs. 1, 2).
  • the industrial organic waste gas is sent to the adsorption wheel 11 through the organic waste gas input pipe 20, and after passing through the adsorption wheel, the organic waste is adsorbed onto the active fiber sheet 115 to purify the exhaust gas, and the clean air after separation is used.
  • the outlet fan is exhausted by the purge gas exhaust pipe 1 31. Since the adsorption wheel will reach saturation after a certain period of adsorption, the organic waste adsorbed to the adsorption wheel needs to be desorbed.
  • the desorption is to send a small amount of hot air into the adsorption wheel for heating and evaporation, so that the exhaust gas after catalytic combustion becomes a heat source for desorption. .
  • the desorbed high-concentration exhaust gas is sent to the catalytic purification furnace 40 through the desorption circulating fan 30 for catalytic combustion (i.e., low-temperature oxidation), and the hot air discharged after the catalytic combustion is sent to the desorption zone 11B of the adsorption wheel 11 through the pipeline for desorption.
  • catalytic combustion i.e., low-temperature oxidation

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

La présente invention concerne un épurateur à purification catalytique et concentration destiné à traiter un effluent gazeux organique industriel et incluant un incinérateur à purification catalytique avec séparateur rotatif. Le séparateur rotatif comporte des roues d’absorption rotatives remplies d’éléments fibreux actifs alvéolaires et des roues d’entraînement. Trois quarts des roues d'adsorption rotatives forment une zone d’adsorption, le quart restant formant une zone de désorption. La zone de désorption est reliée par des tuyaux à l’incinérateur à purification catalytique. L’extrémité d’entrée dudit incinérateur est reliée par des tuyaux à l’orifice de sortie de la zone de désorption, tandis que l’extrémité de sortie du même incinérateur est reliée à un ventilateur cyclique de désorption. Ledit ventilateur est relié à l’orifice de sortie de la zone de désorption des roues d’absorption. La présente invention permet d’absorber et de catalyser l'effluent gazeux organique. Elle permet de réaliser d’importantes économies d’énergie. Aucun gaz polluant n’est généré par le procédé de purification, qui offre en outre en rendement élevé.
PCT/CN2005/002261 2005-05-23 2005-12-20 Epurateur a purification catalytique et concentration pour le traitement d’un gaz organique WO2006125353A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CNU2005200589703U CN2805890Y (zh) 2005-05-23 2005-05-23 治理工业有机废气的浓缩催化净化装置
CN200520058970.3 2005-05-23

Publications (1)

Publication Number Publication Date
WO2006125353A1 true WO2006125353A1 (fr) 2006-11-30

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PCT/CN2005/002261 WO2006125353A1 (fr) 2005-05-23 2005-12-20 Epurateur a purification catalytique et concentration pour le traitement d’un gaz organique

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CN (1) CN2805890Y (fr)
WO (1) WO2006125353A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111569609A (zh) * 2020-05-15 2020-08-25 苏州市科林除尘设备有限公司 一种有机废气治理装置及方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008122896A2 (fr) * 2007-04-10 2008-10-16 Fanli Meng Four
CN102072495B (zh) * 2010-12-17 2012-08-22 张家港市三星净化设备制造有限公司 有机废气催化燃烧装置

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5607654A (en) * 1991-06-10 1997-03-04 Beco Engineering Company Method for minimizing environmental release of toxic compounds in the incineration of wastes
US6261092B1 (en) * 2000-05-17 2001-07-17 Megtec Systems, Inc. Switching valve
WO2001088439A1 (fr) * 2000-05-17 2001-11-22 Dae Yang Environment Co., Ltd. Systeme oxydant de regeneration rotatif a ailettes de distribution
US20040219649A1 (en) * 2003-03-10 2004-11-04 Novozymes A/S Alcohol product processes

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5607654A (en) * 1991-06-10 1997-03-04 Beco Engineering Company Method for minimizing environmental release of toxic compounds in the incineration of wastes
US6261092B1 (en) * 2000-05-17 2001-07-17 Megtec Systems, Inc. Switching valve
WO2001088439A1 (fr) * 2000-05-17 2001-11-22 Dae Yang Environment Co., Ltd. Systeme oxydant de regeneration rotatif a ailettes de distribution
US20040219649A1 (en) * 2003-03-10 2004-11-04 Novozymes A/S Alcohol product processes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111569609A (zh) * 2020-05-15 2020-08-25 苏州市科林除尘设备有限公司 一种有机废气治理装置及方法

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CN2805890Y (zh) 2006-08-16

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