WO2006094008A2 - Vapor phase aromatics alkylation process - Google Patents
Vapor phase aromatics alkylation process Download PDFInfo
- Publication number
- WO2006094008A2 WO2006094008A2 PCT/US2006/007170 US2006007170W WO2006094008A2 WO 2006094008 A2 WO2006094008 A2 WO 2006094008A2 US 2006007170 W US2006007170 W US 2006007170W WO 2006094008 A2 WO2006094008 A2 WO 2006094008A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- feed stream
- zeolite
- catalyst
- benzene
- aromatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
Definitions
- Effluent passes out of the reactor through heat exchanger 13 and then to flash drum 20 in which the light ends are separated from the product.
- the alkylaromatic product passes out of flash drum 20 through line 22 to the fractionator 25 to provide the final stabilized gasoline blend component in line 26 with reboil loop 28 providing column heat; light ends from the fractionator pass out through line 27 from reflux loop 29.
- the catalyst used in the guard bed will normally be the same catalyst used in the alkylation reactor as a matter of operating convenience but this is not required: if desired another catalyst or sorbent to remove contaminants from the feed may used, typically a cheaper guard bed sorbent, e.g. a used catalyst from another process or a sorbent such as alumina.
- a cheaper guard bed sorbent e.g. a used catalyst from another process or a sorbent such as alumina.
- the objective of the guard bed is to remove the contaminants from the feed before the feed comes to the reaction catalyst and provided that this is achieved, there is wide variety of choice as to guard bed catalysts and conditions useful to this end.
- Reformate streams will typically come from a fixed bed, swing bed or moving bed reformer.
- the most useful reformate fraction is a heart-cut reformate.
- This fraction is a complex mixture of hydrocarbons recovered as the overhead of a dehexanizer column downstream from a depentanizer column.
- the composition will vary over a range depending upon a number of factors including the severity of operation in the reformer and the composition of the reformer feed.
- These streams will usually have the C 5 , C 4 and lower hydrocarbons removed in the depentanizer and debutanizer. Therefore, usually, the heart-cut reformate will contain at least 70 wt. % C 6 hydrocarbons, and preferably at least 90 wt. % C 6 hydrocarbons.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BRPI0607069-8A BRPI0607069B1 (pt) | 2005-02-28 | 2006-02-28 | Método para produzir um produto de faixa de ebulição da gasolina |
| CA2599503A CA2599503C (en) | 2005-02-28 | 2006-02-28 | Vapor phase aromatics alkylation process |
| EP06736481.0A EP1856012B1 (en) | 2005-02-28 | 2006-02-28 | Vapor phase aromatics alkylation process |
| JP2007558156A JP2008535941A (ja) | 2005-02-28 | 2006-02-28 | 気相芳香族アルキル化方法 |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US65694505P | 2005-02-28 | 2005-02-28 | |
| US60/656,945 | 2005-02-28 | ||
| US11/362,255 | 2006-02-27 | ||
| US11/362,255 US7498474B2 (en) | 2005-02-28 | 2006-02-27 | Vapor phase aromatics alkylation process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2006094008A2 true WO2006094008A2 (en) | 2006-09-08 |
| WO2006094008A3 WO2006094008A3 (en) | 2007-10-11 |
Family
ID=36941752
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2006/007170 Ceased WO2006094008A2 (en) | 2005-02-28 | 2006-02-28 | Vapor phase aromatics alkylation process |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1856012B1 (enExample) |
| JP (1) | JP2008535941A (enExample) |
| BR (1) | BRPI0607069B1 (enExample) |
| CA (1) | CA2599503C (enExample) |
| RU (1) | RU2404949C2 (enExample) |
| WO (1) | WO2006094008A2 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007130055A1 (en) * | 2006-05-08 | 2007-11-15 | Exxonmobil Chemical Patents Inc. | Organic compound conversion process |
| JP2008223027A (ja) * | 2007-03-14 | 2008-09-25 | Ifp | スチームクラッキング流出物からの炭化水素フラクションを脱硫する方法 |
| JP2010513019A (ja) * | 2006-12-21 | 2010-04-30 | エクソンモービル・ケミカル・パテンツ・インク | 触媒組成物とその製造方法、およびこの触媒を用いた芳香族のアルキル化方法 |
| WO2011077242A1 (en) | 2009-12-23 | 2011-06-30 | Eni S.P.A. | Process for the production of fuel components for motor vehicles |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2654699C2 (ru) * | 2012-12-11 | 2018-05-22 | Эксонмобил Кемикэл Пейтентс Инк. | Способ получения кумола с рециклом продуктов алкилирования |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4016218A (en) * | 1975-05-29 | 1977-04-05 | Mobil Oil Corporation | Alkylation in presence of thermally modified crystalline aluminosilicate catalyst |
| US4992606A (en) * | 1988-10-06 | 1991-02-12 | Mobil Oil Corp. | Process for preparing short chain alkyl aromatic compounds |
| US5334795A (en) * | 1990-06-28 | 1994-08-02 | Mobil Oil Corp. | Production of ethylbenzene |
| US5077445A (en) * | 1991-02-06 | 1991-12-31 | Mobil Oil Corp. | Liquid-phase alkylbenzene synthesis using hydrated catalyst |
| US5236575A (en) * | 1991-06-19 | 1993-08-17 | Mobil Oil Corp. | Synthetic porous crystalline mcm-49, its synthesis and use |
| US5545788A (en) * | 1991-06-19 | 1996-08-13 | Mobil Oil Corporation | Process for the alkylation of benzene-rich reformate using MCM-49 |
| MX9703769A (es) * | 1994-11-23 | 1998-05-31 | Exxon Chemical Patents Inc | Proceso de conversion de hidrocarburos usando un catalizador de ceolita ligado a ceolita. |
| US5600048A (en) * | 1994-12-27 | 1997-02-04 | Mobil Oil Corporation | Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation |
| CN1167652C (zh) * | 1997-08-18 | 2004-09-22 | 埃克森美孚化学专利公司 | 用含丙烯和乙烯的稀物料流烷基化芳族化合物的方法 |
| ES2223590T3 (es) * | 1999-09-20 | 2005-03-01 | Consejo Superior De Investigaciones Cientificas | Alquilacion de compuestos aromaticos. |
| US6525234B1 (en) * | 2000-11-21 | 2003-02-25 | Exxonmobil Oil Corporation | Process for liquid phase aromatics alkylation comprising in-situ catalyst reactivation with polar compounds |
| US7238843B2 (en) * | 2003-02-28 | 2007-07-03 | Abb Lummus Global, Inc. | Process for the production of alkylaromatics |
| EP1617949A4 (en) * | 2003-03-21 | 2008-05-14 | Stone & Webster Inc | PRODUCTION OF ALKYLIC AROMATIC COMPOUNDS WITH REACTIVATION OF CATALYSTS |
-
2006
- 2006-02-28 JP JP2007558156A patent/JP2008535941A/ja active Pending
- 2006-02-28 EP EP06736481.0A patent/EP1856012B1/en not_active Not-in-force
- 2006-02-28 CA CA2599503A patent/CA2599503C/en not_active Expired - Fee Related
- 2006-02-28 BR BRPI0607069-8A patent/BRPI0607069B1/pt not_active IP Right Cessation
- 2006-02-28 RU RU2007134092/04A patent/RU2404949C2/ru not_active IP Right Cessation
- 2006-02-28 WO PCT/US2006/007170 patent/WO2006094008A2/en not_active Ceased
Non-Patent Citations (2)
| Title |
|---|
| None |
| See also references of EP1856012A4 |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007130055A1 (en) * | 2006-05-08 | 2007-11-15 | Exxonmobil Chemical Patents Inc. | Organic compound conversion process |
| US8222468B2 (en) | 2006-05-08 | 2012-07-17 | Exxonmobil Chemical Patents Inc. | Organic compound conversion process |
| JP2010513019A (ja) * | 2006-12-21 | 2010-04-30 | エクソンモービル・ケミカル・パテンツ・インク | 触媒組成物とその製造方法、およびこの触媒を用いた芳香族のアルキル化方法 |
| JP2008223027A (ja) * | 2007-03-14 | 2008-09-25 | Ifp | スチームクラッキング流出物からの炭化水素フラクションを脱硫する方法 |
| WO2011077242A1 (en) | 2009-12-23 | 2011-06-30 | Eni S.P.A. | Process for the production of fuel components for motor vehicles |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1856012B1 (en) | 2020-03-18 |
| JP2008535941A (ja) | 2008-09-04 |
| WO2006094008A3 (en) | 2007-10-11 |
| CA2599503A1 (en) | 2006-09-08 |
| EP1856012A2 (en) | 2007-11-21 |
| CA2599503C (en) | 2011-12-06 |
| BRPI0607069A2 (pt) | 2009-12-01 |
| EP1856012A4 (en) | 2012-01-11 |
| RU2404949C2 (ru) | 2010-11-27 |
| BRPI0607069B1 (pt) | 2015-06-30 |
| RU2007134092A (ru) | 2009-04-10 |
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