WO2006094008A2 - Vapor phase aromatics alkylation process - Google Patents

Vapor phase aromatics alkylation process Download PDF

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Publication number
WO2006094008A2
WO2006094008A2 PCT/US2006/007170 US2006007170W WO2006094008A2 WO 2006094008 A2 WO2006094008 A2 WO 2006094008A2 US 2006007170 W US2006007170 W US 2006007170W WO 2006094008 A2 WO2006094008 A2 WO 2006094008A2
Authority
WO
WIPO (PCT)
Prior art keywords
feed stream
zeolite
catalyst
benzene
aromatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2006/007170
Other languages
English (en)
French (fr)
Other versions
WO2006094008A3 (en
Inventor
Benjamin Santiago Umansky
Michael Christopher Clark
Ajit Bhaskar Dandekar
Christine Nicole Elia
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/362,255 external-priority patent/US7498474B2/en
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Priority to BRPI0607069-8A priority Critical patent/BRPI0607069B1/pt
Priority to CA2599503A priority patent/CA2599503C/en
Priority to EP06736481.0A priority patent/EP1856012B1/en
Priority to JP2007558156A priority patent/JP2008535941A/ja
Publication of WO2006094008A2 publication Critical patent/WO2006094008A2/en
Anticipated expiration legal-status Critical
Publication of WO2006094008A3 publication Critical patent/WO2006094008A3/en
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66Catalytic processes

Definitions

  • Effluent passes out of the reactor through heat exchanger 13 and then to flash drum 20 in which the light ends are separated from the product.
  • the alkylaromatic product passes out of flash drum 20 through line 22 to the fractionator 25 to provide the final stabilized gasoline blend component in line 26 with reboil loop 28 providing column heat; light ends from the fractionator pass out through line 27 from reflux loop 29.
  • the catalyst used in the guard bed will normally be the same catalyst used in the alkylation reactor as a matter of operating convenience but this is not required: if desired another catalyst or sorbent to remove contaminants from the feed may used, typically a cheaper guard bed sorbent, e.g. a used catalyst from another process or a sorbent such as alumina.
  • a cheaper guard bed sorbent e.g. a used catalyst from another process or a sorbent such as alumina.
  • the objective of the guard bed is to remove the contaminants from the feed before the feed comes to the reaction catalyst and provided that this is achieved, there is wide variety of choice as to guard bed catalysts and conditions useful to this end.
  • Reformate streams will typically come from a fixed bed, swing bed or moving bed reformer.
  • the most useful reformate fraction is a heart-cut reformate.
  • This fraction is a complex mixture of hydrocarbons recovered as the overhead of a dehexanizer column downstream from a depentanizer column.
  • the composition will vary over a range depending upon a number of factors including the severity of operation in the reformer and the composition of the reformer feed.
  • These streams will usually have the C 5 , C 4 and lower hydrocarbons removed in the depentanizer and debutanizer. Therefore, usually, the heart-cut reformate will contain at least 70 wt. % C 6 hydrocarbons, and preferably at least 90 wt. % C 6 hydrocarbons.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
PCT/US2006/007170 2005-02-28 2006-02-28 Vapor phase aromatics alkylation process Ceased WO2006094008A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BRPI0607069-8A BRPI0607069B1 (pt) 2005-02-28 2006-02-28 Método para produzir um produto de faixa de ebulição da gasolina
CA2599503A CA2599503C (en) 2005-02-28 2006-02-28 Vapor phase aromatics alkylation process
EP06736481.0A EP1856012B1 (en) 2005-02-28 2006-02-28 Vapor phase aromatics alkylation process
JP2007558156A JP2008535941A (ja) 2005-02-28 2006-02-28 気相芳香族アルキル化方法

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US65694505P 2005-02-28 2005-02-28
US60/656,945 2005-02-28
US11/362,255 2006-02-27
US11/362,255 US7498474B2 (en) 2005-02-28 2006-02-27 Vapor phase aromatics alkylation process

Publications (2)

Publication Number Publication Date
WO2006094008A2 true WO2006094008A2 (en) 2006-09-08
WO2006094008A3 WO2006094008A3 (en) 2007-10-11

Family

ID=36941752

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/007170 Ceased WO2006094008A2 (en) 2005-02-28 2006-02-28 Vapor phase aromatics alkylation process

Country Status (6)

Country Link
EP (1) EP1856012B1 (enExample)
JP (1) JP2008535941A (enExample)
BR (1) BRPI0607069B1 (enExample)
CA (1) CA2599503C (enExample)
RU (1) RU2404949C2 (enExample)
WO (1) WO2006094008A2 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007130055A1 (en) * 2006-05-08 2007-11-15 Exxonmobil Chemical Patents Inc. Organic compound conversion process
JP2008223027A (ja) * 2007-03-14 2008-09-25 Ifp スチームクラッキング流出物からの炭化水素フラクションを脱硫する方法
JP2010513019A (ja) * 2006-12-21 2010-04-30 エクソンモービル・ケミカル・パテンツ・インク 触媒組成物とその製造方法、およびこの触媒を用いた芳香族のアルキル化方法
WO2011077242A1 (en) 2009-12-23 2011-06-30 Eni S.P.A. Process for the production of fuel components for motor vehicles

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2654699C2 (ru) * 2012-12-11 2018-05-22 Эксонмобил Кемикэл Пейтентс Инк. Способ получения кумола с рециклом продуктов алкилирования

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4016218A (en) * 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
US4992606A (en) * 1988-10-06 1991-02-12 Mobil Oil Corp. Process for preparing short chain alkyl aromatic compounds
US5334795A (en) * 1990-06-28 1994-08-02 Mobil Oil Corp. Production of ethylbenzene
US5077445A (en) * 1991-02-06 1991-12-31 Mobil Oil Corp. Liquid-phase alkylbenzene synthesis using hydrated catalyst
US5236575A (en) * 1991-06-19 1993-08-17 Mobil Oil Corp. Synthetic porous crystalline mcm-49, its synthesis and use
US5545788A (en) * 1991-06-19 1996-08-13 Mobil Oil Corporation Process for the alkylation of benzene-rich reformate using MCM-49
MX9703769A (es) * 1994-11-23 1998-05-31 Exxon Chemical Patents Inc Proceso de conversion de hidrocarburos usando un catalizador de ceolita ligado a ceolita.
US5600048A (en) * 1994-12-27 1997-02-04 Mobil Oil Corporation Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation
CN1167652C (zh) * 1997-08-18 2004-09-22 埃克森美孚化学专利公司 用含丙烯和乙烯的稀物料流烷基化芳族化合物的方法
ES2223590T3 (es) * 1999-09-20 2005-03-01 Consejo Superior De Investigaciones Cientificas Alquilacion de compuestos aromaticos.
US6525234B1 (en) * 2000-11-21 2003-02-25 Exxonmobil Oil Corporation Process for liquid phase aromatics alkylation comprising in-situ catalyst reactivation with polar compounds
US7238843B2 (en) * 2003-02-28 2007-07-03 Abb Lummus Global, Inc. Process for the production of alkylaromatics
EP1617949A4 (en) * 2003-03-21 2008-05-14 Stone & Webster Inc PRODUCTION OF ALKYLIC AROMATIC COMPOUNDS WITH REACTIVATION OF CATALYSTS

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
None
See also references of EP1856012A4

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007130055A1 (en) * 2006-05-08 2007-11-15 Exxonmobil Chemical Patents Inc. Organic compound conversion process
US8222468B2 (en) 2006-05-08 2012-07-17 Exxonmobil Chemical Patents Inc. Organic compound conversion process
JP2010513019A (ja) * 2006-12-21 2010-04-30 エクソンモービル・ケミカル・パテンツ・インク 触媒組成物とその製造方法、およびこの触媒を用いた芳香族のアルキル化方法
JP2008223027A (ja) * 2007-03-14 2008-09-25 Ifp スチームクラッキング流出物からの炭化水素フラクションを脱硫する方法
WO2011077242A1 (en) 2009-12-23 2011-06-30 Eni S.P.A. Process for the production of fuel components for motor vehicles

Also Published As

Publication number Publication date
EP1856012B1 (en) 2020-03-18
JP2008535941A (ja) 2008-09-04
WO2006094008A3 (en) 2007-10-11
CA2599503A1 (en) 2006-09-08
EP1856012A2 (en) 2007-11-21
CA2599503C (en) 2011-12-06
BRPI0607069A2 (pt) 2009-12-01
EP1856012A4 (en) 2012-01-11
RU2404949C2 (ru) 2010-11-27
BRPI0607069B1 (pt) 2015-06-30
RU2007134092A (ru) 2009-04-10

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