WO2006058722A1 - Procede de surfacage et de coloration d'un article - Google Patents

Procede de surfacage et de coloration d'un article Download PDF

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Publication number
WO2006058722A1
WO2006058722A1 PCT/EP2005/012772 EP2005012772W WO2006058722A1 WO 2006058722 A1 WO2006058722 A1 WO 2006058722A1 EP 2005012772 W EP2005012772 W EP 2005012772W WO 2006058722 A1 WO2006058722 A1 WO 2006058722A1
Authority
WO
WIPO (PCT)
Prior art keywords
colouration
article
surface finishing
article according
realised
Prior art date
Application number
PCT/EP2005/012772
Other languages
English (en)
Inventor
Paolo Canonico
Original Assignee
Mascioni S.P.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mascioni S.P.A. filed Critical Mascioni S.P.A.
Publication of WO2006058722A1 publication Critical patent/WO2006058722A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/0015—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterized by the colour of the layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/12—Organic material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14—Metallic material, boron or silicon
    • C23C14/20—Metallic material, boron or silicon on organic substrates
    • C23C14/205—Metallic material, boron or silicon on organic substrates by cathodic sputtering
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/56—Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks
    • C23C14/562—Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks for coating elongated substrates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/003—Treatment with radio-waves or microwaves
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
    • D06M10/025—Corona discharge or low temperature plasma
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/08—Organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles

Definitions

  • the present invention generally refers to a process of surface finishing and colouration suitable to be applied to any material, and in particular to a process of surface finishing and colouration of a textile article of any nature.
  • a metallisation process of a textile article by vacuum deposition is known.
  • the article is made to cross a special vacuum vaporiser in which the heating and subsequent vaporisation of the metal (generally aluminium) takes place.
  • the vaporised metal particles move independently from each other along rectilinear trajectories and metallise the substrate by means of condensation.
  • the pigments' disadvantage lies in their low stability under wet and dry friction, particularly for brilliant colours.
  • Another drawback of the pigments lies in the fact that they confer a certain stiffness to the touch, due to the presence of a polymeric binder.
  • the technical task set by the present invention is therefore to realise a process for the surface finishing and colouration of an article which permits eliminating the reported technical drawbacks of the known art .
  • one object of the invention is to realise a process for the surface finishing and colouration of a textile article which permits conferring new chromatic and water repellent properties to the textile article thus treated.
  • Another object of the invention is to realise a process for the surface finishing and colouration of an article which does not pollute the environment.
  • Another object of the invention is to realise a process for the surface finishing and colouration of an article which permits applying metallic layers of practically every type.
  • Another object of the invention is to realise a process for the surface finishing and colouration of an article which permits depositing one or more metallic layers which are stable and resistant to wet and dry friction.
  • the last object of the invention is to realise a process for the surface finishing and colouration of a textile article which confers extreme softness to the touch to the article thus realised.
  • Figure 1 schematically shows a reaction chamber where the textile article is treated by vacuum magnetron sputtering.
  • the process of surface finishing of a textile article consists in subjecting the textile article, in natural or synthetic fabric, to one or more successive treatments by vacuum magnetron sputtering for the surface deposition of one or more layers adapted to confer specific properties to the article.
  • the vacuum magnetron sputtering technique consists of generating an electrical discharge between one or more cathodes composed of the material to be deposited and an anode.
  • the gas ions in which the discharge occurs collide with the cathode or cathodes, causing the ejection of particles which migrate towards the substrate (the surface of the textile article subjected to treatment) , where they are deposited.
  • the cathode or cathodes are provided with magnets which confine the discharge in proximity to the cathodes themselves, thus increasing the frequency of the collision events which are the source of the material ejections.
  • Each treatment is realised with a plasmatic gas comprising one or more elements chosen from Ar, Ne, Kr, Xe, N 2 , O 2 , with a magnetron discharge current density comprised between 10 and 1,000 mA/cm 2 and a plasmatic gas pressure comprised between 10 "2 and 1 Pa.
  • Each treatment is realised so to superficially coat the textile article in a complete manner.
  • one or more target cathodes are used, realised in a metallic material chosen from aluminium, titanium, stainless steel, copper, bronze, silver, gold, platinum, brass or other metals or metallic alloys.
  • N 2 and/or O 2 gas in the plasmatic gas, comprised between 1 and 50% in concentration, chemically reactant with the metallic material of the target cathode (s) .
  • the duration of the treatment depends on the colouration which one intends to attain.
  • the process also permits depositing at least one water repellent layer by utilising one or more target cathodes realised in polymeric material based • on • polyolefins or containing fluorine.
  • the electrons situated in such zone move according to a complex trajectory, and ionise the gas with the result of creating a toroidal zone 4 of plasmatic gas close to the surface of the cathode.
  • the positive ions are accelerated towards the cathode 1 and bombard its surface in an erosion zone 5.
  • the material particles which abandon the target cathode 1 are deposited on the textile article 6 in the form of a thin layer 7.
  • the article to be treated is moved, also reversibly so that it is subjected to additional treatments, by an uncoiler roller 8 to a coiler roller 9.
  • a polyester fabric sample is situated in the vacuum reaction chamber at a distance of 240 mm from a Ti target cathode.
  • the chamber is pumped to the pressure of 6.67xlO ⁇ 3 ⁇ Pa.
  • the chamber is filled with Ar at the pressure of 2.66XlO '1 Pa.
  • a magnetron current discharge is generated by means of high voltage application to the cathode of 60 s duration, at a current density of 105 mA/cm 2 .
  • a polyamide fabric sample is situated in the vacuum reaction chamber at a distance of 200 mm from a Cu target cathode.
  • the chamber is pumped to the pressure of 6.67xlO ⁇ 3 Pa.
  • the chamber is filled with Kr at the pressure of 1.33XlO "1 Pa.
  • a magnetron current discharge is generated by means of high voltage application to the cathode of 60 s duration, at a current density of 210 mA/cm 2 .
  • a Cu coating layer results, having a thickness of approximately 100 A.
  • a polyester fabric sample is situated in the vacuum reaction chamber at a distance of 240 mm from a stainless steel target cathode.
  • the chamber is pumped to the pressure of 6.67xlO "3 Pa.
  • the chamber is filled with Ne at the pressure of SxIO "1 Pa.
  • a magnetron current discharge is generated by means of high voltage application to the cathode of 120 s duration, at a current density of 80 mA/cm 2 .
  • a stainless steel coating layer results, having a thickness of approximately 100 A.
  • a fibre glass fabric sample is situated in the vacuum reaction chamber at a distance of 200 mm from a brass target cathode.
  • the chamber is pumped to the pressure of 6.67xlO '3 Pa.
  • the chamber is filled with Ar at the pressure of 3.33XlO '1 Pa.
  • a magnetron current discharge is generated by means of high voltage application to the cathode of 120 s duration, at a current density of 1,000 mA/ctn 2 .
  • a brass coating layer results, having a thickness of approximately 300 A.
  • a polyester fabric sample is situated in the vacuum reaction chamber at a distance of 240 mm from a Ti target cathode.
  • the chamber is pumped to the pressure of 6.67xlO ⁇ 3 Pa.
  • the chamber is filled with Ar at the pressure of 2.66XlO "1 Pa.
  • a magnetron current discharge is generated by means of high voltage application to the cathode of 120 s duration, at a current density of 200 mA/cm 2 .
  • O 2 is added to the plasmatic gas and the treatment is continued in an 85% Ar, 15% O 2 gas mixture at the pressure of 3.07XlO "1 Pa. After 200 s of treatment, the sample has a blue colouration.
  • a polyester fabric sample, coated with a thin layer of brass at the conditions stated in Example 4, is situated in the vacuum reaction chamber at a distance of 240 mm from a Ti target cathode.
  • the chamber is pumped to the pressure of 6.67xlO "3 Pa.
  • the chamber is filled with Ar at the pressure of 2.66XlO "1 Pa.
  • a magnetron current discharge is generated by means of high voltage application to the cathode, at a current density of 100-250 mA/cm 2 .
  • the Ti layer is deposited on the fabric for no more than 10 s.
  • O 2 is added to the plasmatic gas and the treatment is continued in a 90% Ar, 10% O 2 gas mixture at the pressure of 2.93XlO "1 Pa. After 105 s of treatment, the sample has an intense yellow colouration.
  • a polyester fabric sample, coated with a Cu layer at the conditions stated in Example 4, is situated in the vacuum reaction chamber at a distance of 240 mm from a Ti target cathode.
  • the chamber is pumped to the pressure of 6.67xlO "3 Pa.
  • the chamber is filled with Ar at the pressure of 2.66XlO "1 Pa.
  • a magnetron current discharge is generated by means of high voltage application to the cathode, at a current density of 100-250 mA/cm 2 .
  • the Ti layer is deposited on the fabric for no more than 10 s.
  • O 2 is added to the plasmatic gas and the treatment is continued in an 80% Ar, 20% O 2 gas mixture at the pressure of 3.33XlO '1 Pa. After 95 s of treatment the sample has an orange colouration; after 240 s of treatment the sample has a pink colouration.
  • a polyester fabric sample, coated with a Ti layer at the conditions stated in Example I 1 is situated in the vacuum reaction chamber at a distance of 240 mm from a Ti target cathode.
  • the chamber is pumped to the pressure of 6.67xlO '3 Pa.
  • the chamber is filled with a mixture of 93% Ar and 7% N 2 , and at the pressure of 2.93XlO "1 Pa a magnetron current discharge is generated by means of high voltage application to the cathode, at a current density of 100-250 mA/cm 2 .
  • the sample After 240 s of treatment, the sample has a gold type colouration.
  • a polyester fabric sample is situated in the vacuum reaction chamber at a distance of 200 mm from a Teflon target cathode.
  • the chamber is pumped to the pressure of 6.67xlO ⁇ 3 Pa.
  • the chamber is filled with Ar at the pressure of 1.33XlO "1 Pa.
  • small Teflon particles are deposited on the fabric surface, creating a permanent layer having water repellent properties similar to Teflon.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

Cette invention concerne un procédé de surfaçage et de coloration d'un article consistant à soumettre l'article textile à un ou plusieurs traitements successifs par pulvérisation magnétron sous vide en vue du dépôt en surface d'une ou plusieurs couches conçues pour conférer des propriétés spécifiques à l'article.
PCT/EP2005/012772 2004-12-03 2005-11-30 Procede de surfacage et de coloration d'un article WO2006058722A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI2004A002323 2004-12-03
ITMI20042323 ITMI20042323A1 (it) 2004-12-03 2004-12-03 Procedimento di finitura e coloraziione superficiale di un articolo

Publications (1)

Publication Number Publication Date
WO2006058722A1 true WO2006058722A1 (fr) 2006-06-08

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PCT/EP2005/012772 WO2006058722A1 (fr) 2004-12-03 2005-11-30 Procede de surfacage et de coloration d'un article

Country Status (2)

Country Link
IT (1) ITMI20042323A1 (fr)
WO (1) WO2006058722A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3812505A4 (fr) * 2018-06-22 2021-09-29 Guangdong Rising Well Science & Technology Co., Ltd. Procédé de coloration de tissu et tissu coloré
CN114318861A (zh) * 2020-10-10 2022-04-12 上海水星家用纺织品股份有限公司 基于磁控溅射法的结构色织物制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3706218A1 (de) * 1987-02-26 1988-09-08 Werner Prof Dr Weisweiler Vorrichtung und verfahren zur kontinuierlichen beschichtung der einzelnen fasern eines faserbuendels mit oberflaechenschuetzenden und haftvermittelnden carbid- oder plasmapolymer-filmen
US4895630A (en) * 1985-08-28 1990-01-23 W. H. Brady Co. Rapidly removable undercoating for vacuum deposition of patterned layers onto substrates
EP0434299A1 (fr) * 1989-12-20 1991-06-26 The Standard Oil Company Revêtements multicouches pour les renforcements utilisés dans les composites à haute température
JPH03279469A (ja) * 1990-03-22 1991-12-10 Osaka Prefecture 金属薄膜を有する繊維体の製造方法
JPH07252769A (ja) * 1994-01-21 1995-10-03 Asahi Glass Co Ltd 顕色繊維物およびその製造方法
EP0695622A2 (fr) * 1994-07-22 1996-02-07 Fraunhofer-Gesellschaft Zur Förderung Der Angewandten Forschung E.V. Procédé et installation pour la modification par plasma d'objets poreux plats
DE19823203A1 (de) * 1998-05-25 1999-12-02 Techno Coat Oberflaechentechni Verfahren zur Herstellung von flexiblem Bandmaterial mit verbesserten Oberflächeneigenschaften

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4895630A (en) * 1985-08-28 1990-01-23 W. H. Brady Co. Rapidly removable undercoating for vacuum deposition of patterned layers onto substrates
DE3706218A1 (de) * 1987-02-26 1988-09-08 Werner Prof Dr Weisweiler Vorrichtung und verfahren zur kontinuierlichen beschichtung der einzelnen fasern eines faserbuendels mit oberflaechenschuetzenden und haftvermittelnden carbid- oder plasmapolymer-filmen
EP0434299A1 (fr) * 1989-12-20 1991-06-26 The Standard Oil Company Revêtements multicouches pour les renforcements utilisés dans les composites à haute température
JPH03279469A (ja) * 1990-03-22 1991-12-10 Osaka Prefecture 金属薄膜を有する繊維体の製造方法
JPH07252769A (ja) * 1994-01-21 1995-10-03 Asahi Glass Co Ltd 顕色繊維物およびその製造方法
EP0695622A2 (fr) * 1994-07-22 1996-02-07 Fraunhofer-Gesellschaft Zur Förderung Der Angewandten Forschung E.V. Procédé et installation pour la modification par plasma d'objets poreux plats
DE19823203A1 (de) * 1998-05-25 1999-12-02 Techno Coat Oberflaechentechni Verfahren zur Herstellung von flexiblem Bandmaterial mit verbesserten Oberflächeneigenschaften

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 199204, Derwent World Patents Index; Class F07, AN 1992-030721, XP002371439 *
PATENT ABSTRACTS OF JAPAN vol. 1996, no. 02 29 February 1996 (1996-02-29) *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3812505A4 (fr) * 2018-06-22 2021-09-29 Guangdong Rising Well Science & Technology Co., Ltd. Procédé de coloration de tissu et tissu coloré
JP2021527761A (ja) * 2018-06-22 2021-10-14 クワントン ライジング ウェル サイエンス アンド テクノロジー カンパニー リミテッドＧｕａｎｇｄｏｎｇ Ｒｉｓｉｎｇ Ｗｅｌｌ Ｓｃｉｅｎｃｅ ＆ Ｔｅｃｈｎｏｌｏｇｙ Ｃｏ．， Ｌｔｄ． 織物の着色方法及び着色した織物
US11505860B2 (en) 2018-06-22 2022-11-22 Guangdong Rising Well Science & Technology Co., Ltd. Fabric coloring method and colored fabric
JP7343577B2 (ja) 2018-06-22 2023-09-12 クワントン ライジング ウェル サイエンス アンド テクノロジー カンパニー リミテッド 織物の着色方法及び着色した織物
CN114318861A (zh) * 2020-10-10 2022-04-12 上海水星家用纺织品股份有限公司 基于磁控溅射法的结构色织物制备方法

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