WO2005096888A1 - Method and apparatus for forming an article of manufacture and an article of manufacture made by a new and novel process - Google Patents
Method and apparatus for forming an article of manufacture and an article of manufacture made by a new and novel process Download PDFInfo
- Publication number
- WO2005096888A1 WO2005096888A1 PCT/US2005/010231 US2005010231W WO2005096888A1 WO 2005096888 A1 WO2005096888 A1 WO 2005096888A1 US 2005010231 W US2005010231 W US 2005010231W WO 2005096888 A1 WO2005096888 A1 WO 2005096888A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- article
- manufacture
- selectively
- catalyst
- mixing
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 82
- 238000000034 method Methods 0.000 title claims abstract description 46
- 239000000463 material Substances 0.000 claims abstract description 95
- 239000003054 catalyst Substances 0.000 claims abstract description 43
- 239000004616 structural foam Substances 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000004593 Epoxy Substances 0.000 claims abstract description 11
- 239000004568 cement Substances 0.000 claims description 21
- 239000006261 foam material Substances 0.000 claims description 8
- 239000004005 microsphere Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims 5
- 229920001651 Cyanoacrylate Polymers 0.000 claims 1
- MWCLLHOVUTZFKS-UHFFFAOYSA-N Methyl cyanoacrylate Chemical compound COC(=O)C(=C)C#N MWCLLHOVUTZFKS-UHFFFAOYSA-N 0.000 claims 1
- 230000003213 activating effect Effects 0.000 claims 1
- 239000002274 desiccant Substances 0.000 abstract description 10
- 239000000919 ceramic Substances 0.000 abstract description 9
- 238000009472 formulation Methods 0.000 abstract 1
- 239000006260 foam Substances 0.000 description 4
- 230000006378 damage Effects 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000012358 sourcing Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/20—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 for porous or cellular articles, e.g. of foam plastics, coarse-pored
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/06—Molding microballoons and binder
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
Definitions
- the present invention generally relates to a method and an apparatus for forming an article of manufacture and an article, of manufacture made by and from a new and novel process and, more particularly by way example and without limitation, to a ' method and apparatus which allows an article of manufacture to be made in a cost effective manner, having properties, which are highly desirable, and to be made in a variety of shapes and sizes, thereby
- Ceramic type article of - manufactures are used in a wide variety of applications and form many common articles used by the general • public.
- Some non-limiting examples- of these articles include toilet bowels and kitchen sinks.
- Such articles are made by the use of traditional types of clay material which is generally formed into ⁇ a desired shape and then placed within and heated by kilns. The heat causes the clay to harden and the hardened articles are then removed from ⁇ the kiln and "finished” by hand.
- the foregoing ceramic type articles do provide a desired 'function, they suffer from many drawbacks. For example, the foregoing article creation process is labor intensive, thereby greatly increa-sing the cost of producing • these articles.
- a method for creating an article of manufacture. Particularly, the method includes the steps of providing a structural epoxy foam material; providing a catalyst; mixing the structural epoxy foam material with the catalyst, thereby creating a certain mixture; creating .a .
- a method for creating an article of manufacture includes the steps of providing a syntactic cement material; providing a catalyst; mixing the syntactic cement material with the provided catalyst, thereby creating a certain mixture; creating a mold; placing the certain mixture within the created mold; and allowing the certain mixture to harden within the created mold, thereby creating the article of manufacture.
- an apparatus for selectively forming an article of manufacture is provided.
- the apparatus includes a mold; a reservoir of a catalyst; a reservoir of a structural foam material; a pump which is physically and communicatively coupled to the reservoir of structural foam material; a mixing head assembly which is physically and " communicatively coupled to the pump and which includes an auxiliary input port and an output 'port; a source' of gas which is physically and communicatively coupled to the auxiliary input port; a mixing assembly which is physically and communicatively coupled to the output port of the mixing head ' assembly; and a controller which is controll .
- the controller is adapted to selectively cause at least a portion of the reservoir of structural foam material to be communicated to the input port of the mixing head assembly while causing at least, a portion of the source of gas to be communicated to the auxiliary input port of the mixing head assembly , thereby causing at least the.
- an apparatus for selectively forming an article of manufacture is provided.
- the apparatus includes- a mold; a reservoir of a catalyst; a reservoir of ' a syntactic cement; a pump which is physically and communicatively coupled to the reservoir of syntactic cement; a mixing head assembly which is physically and communicatively coupled to the pump and which includes an auxiliary input port and an output port; a source of gas which is physically and communicatively coupled to the
- auxiliary input port a mixing assembly which is physically- and . communicatively coupled to the output port of the mixing head assembly; -and- a controller, which is controllably coupled to the pump, to the source of gas, and to the mixing assembly and wherein the controller is adapted to selectively cause at least a portion of the reservoir of syntactic cement to be communicated to the input port of the mixing -head assembly while causing at least a portion of the source of gas to be communicated to the auxiliary input port of the mixing head assembly , thereby causing at least the portion of the source of gas to mix with the at least the portion of the reservoir of syntactic cement within the mixing head assembly to form a - certain material, the controller further selectively causing ' the formed certain material to be communicated to the mixing .
- an article of manufacture is provided.
- the provided article of manufacture is made- - by the process of mixing a structural foam material with a catalyst material to form a selectively mixed material; placing the selectively mixed material into a mold; and allowing the selectively mixed material to harden within the mold, thereby forming the article of manufacture.
- an article of manufacture is provided.
- the provided article of manufacture is made by the process of mixing a syntactic cement material with a catalyst material to form a selectively mixed material; placing the selectively mixed material into a mold; and allowing the selectively mixed material to harden within the mold, thereby forming the article of manufacture.
- Figure 1 is a block diagram of an article creation apparatus " made in accordance with the teachings of the preferred embodiments of the invention; and Figure 2 is -a flow chart illustrating the sequence of steps associated with and comprising a first article formation methodology of the preferred embodiments of the invention.
- Figure 2 is -a flow chart illustrating the sequence of steps associated with and comprising a first article formation methodology of the preferred embodiments of the invention.
- the apparatus 10 includes a material reservoir 12 which, in one non-limiting embodiment of the invention, contains structural epoxy foam material such as but not limited to a material from the family of structural foam materials commonly known as Teorcore ⁇ and available from the Henkel Corporation.
- the apparatus 10 further includes a controller assembly 14 which is operable under stored program control and which, in one non-limiting embodiment of the invention, comprises a Dell type computer operating in a Windows environment.
- the apparatus 10 further includes a mold 16 which is adapted to have a cavity 18 which conforms to the size and shape of a desired part or- article of manufacture 20.
- the apparatus 10 further includes a catalyst source 22 which is operably coupled to a pump 24.
- the pump 24 is controllably coupled to the controller assembly 14 by the use of bus- -30.
- the apparatus 10 further includes a source of a drying agent 40 which is also operably connected to a pump 44.
- the pump 44 is also controllably coupled to the controller 14 by the use of the bus 30.
- the apparatus 10 includes a dispensing head assembly 50 having a first input port 52 which is communicatively coupled to the pump 24 and a second input port 54 which -is communicatively coupled to the pump.44..
- the apparatus 10 also includes a pump 60 which is communicatively and operably coupled to .
- the apparatus 10 includes a vibration assembly 80 which is physically coupled to- the dispensing head assembly 50 and which is controllably coupled to the controller -assembly 14 by the use of bus 30.
- the dispensing head assembly 50 may comprise a model "Twinmixer III" which is provided by the Liquid Control Corporation of North Canton, Ohio a d the pump may comprise a model "PosiFlow” programmable continuous flow metering pump or "zero shear pump” which is also provided by the Liquid Control Corporation.
- the apparatus 10 also includes a source of electrical energy 15 which is coupled to the controller assembly 14 by the use of bus 17. Referring now to Figure 2, there is shown a flow chart ' 100 which illustrates one methodology 100 which may be used according to the invention.
- the methodology 100 includes a first step 102 in which all of the various " ' foregoing elements of the apparatus 10 are “reset” or made ready to begin the overall process 100.
- the first step 102 is followed by step 104 in which a mold, such as mold 16, . is created or provided and which has a desired cavity 18 having a size and a shape which conforms to the size and the shape of a desired article of manufacture, such as article of manufacture 20.
- step 104 is followed by step 106 in which the structural foam material 110 is provided within the reservoir 12.
- Step " 106 follows step 104 and, in this step 106, a catalyst material 111 is provided within the source reservoir 22.
- this catalyst material 111 comprises an Amine type catalyst, although other catalyst materials may be utilized.
- Step 108 is followed by step 120 in which the catalyst material 111 is mixed with the epoxy structural foam material 110 within the head assembly 50.
- the controller ' assembly 14 selectively activates the pumps 60 and 24 (e.g., by sourcing electrical energy to these pumps 24, 60 from the - source 15 and by the use of bus 30) to respectively cause the materials 110 and 111 to be communicated into the head assembl 50.
- the controller assembly 14 also selectively activates the vibration assembly 80, by sourcing electrical energy to the vibration assembly 80 from the source 15 and by the use of - bus 30.- This vibration occurs in step 122 which follows step 120.
- Step 124 follows either step 122 or step 120 and, • in this step 124, the, controller assembly 14 .sources - electrical energy, from the source 15 to the pump 44, to cause the drying agent 200 to be communicated into the head assembly 50 ' as the epoxy structural foam 110 and the catalyst 111 are being mixed within the. head assembly 50.
- the drying agent - may first be heated before it is communicated into the head assembly 50.
- the drying agent 200 comprises air.
- the mixed foam ilO, catalyst 111, and the drying agent 200 are each vibrated within the head assembly 50 as they are selectively mixed within the head assembly 50.
- Step 222 follows step 124 and, in this- step 222, the mixed material within the head assembly 50 is dispensed into the mold 20 (i.e., into the formed cavity 18 within the mold 20) .
- Step 224 follows step 222 and, in this step 224, the dispensed material is allowed to harden.
- Step 226 follows step 224 and, in this step 224, the hardened material is removed from the mold 20, thereby forming an article of manufacture 20.
- Step 228 follows step 226 and represents the conclusion of the methodology 100. .-
- the material 110 comprises syntactic cement and the catalyst material 111 comprises water.
- the drying agent 200 comprises liquid carbon dioxide. It should be appreciated that the article of
- the article of manufacture 20 is very resistant to acid damage, is lightweight, and may be configured in a wide variety of sizes and shapes and has the strength and structural integrity of ceramic based articles of manufacture.
- the article of manufacture 20 may comprise a toilet bowl, sink, ' countertop, or virtually any other desired article.
- placing the drying agent within the head assembly 50, as opposed to communicating the drying agent to the reservoir 12, allows the .dispensing material to have a relatively constant compressibility and better control. That is, the foam compresses as it is pumpably communicated to the head and placing a drying agent within the foam, before it is pumped, will cause the foam to have uneven compressibility and cause the pump 60 to expend greater and variable amounts of energy.
- microsphere material may be selectively added to the syntactic cement. It is to be understood that the invention is not limited to the exact construction and method which has been illustrated, but that various changes and- modifications may be made without departing from the spirit and the scope of the inventions as they are delineated in the following claims.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Structural Engineering (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002561623A CA2561623A1 (en) | 2004-04-02 | 2005-03-25 | Method and apparatus for forming an article of manufacture and an article of manufacture made by a new and novel process |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/816,624 US7300616B2 (en) | 2004-04-02 | 2004-04-02 | Method and apparatus for forming an article of manufacture and an article of manufacture made by a new and novel process |
US10/816,624 | 2004-04-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005096888A1 true WO2005096888A1 (en) | 2005-10-20 |
Family
ID=35054681
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2005/010231 WO2005096888A1 (en) | 2004-04-02 | 2005-03-25 | Method and apparatus for forming an article of manufacture and an article of manufacture made by a new and novel process |
Country Status (4)
Country | Link |
---|---|
US (1) | US7300616B2 (en) |
CA (1) | CA2561623A1 (en) |
TW (1) | TW200534986A (en) |
WO (1) | WO2005096888A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060210736A1 (en) * | 2004-08-05 | 2006-09-21 | Wycech Joseph S | Method for forming a tangible item and a tangible item which is made by a method which allows the created tangible item to efficiently absorb energy |
US7820002B2 (en) * | 2006-11-16 | 2010-10-26 | Wycech Joseph S | Method for making a reception assembly and an reception assembly |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4379729A (en) * | 1979-08-09 | 1983-04-12 | Tarmac Industrial Holdings Limited | Method and apparatus for the production of composite sheet material and a sheet material produced thereby |
US5177124A (en) * | 1987-08-19 | 1993-01-05 | Intaglio Ltd. | Plastic molded pieces having the appearance of a solid metallic piece |
US6113199A (en) * | 1997-11-20 | 2000-09-05 | Kewaunee Scientific Corporation | Laboratory countertop |
US6212700B1 (en) * | 1999-03-29 | 2001-04-10 | Sealand Technology, Inc. | Portable toilet unit |
US6376564B1 (en) * | 1998-08-27 | 2002-04-23 | Henkel Corporation | Storage-stable compositions useful for the production of structural foams |
US6664314B1 (en) * | 1998-03-19 | 2003-12-16 | Blanco Gmbh & Co Kg | Moulding compositions for the production of sanitary-ware components having more than one visible side |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1559002A (en) * | 1976-04-07 | 1980-01-09 | British Petroleum Co | Structural foams polymer ceramics |
USH2047H1 (en) * | 1999-11-10 | 2002-09-03 | Henkel Corporation | Reinforcement laminate |
US6787579B2 (en) * | 2001-05-02 | 2004-09-07 | L&L Products, Inc. | Two-component (epoxy/amine) structural foam-in-place material |
-
2004
- 2004-04-02 US US10/816,624 patent/US7300616B2/en not_active Expired - Fee Related
-
2005
- 2005-03-25 CA CA002561623A patent/CA2561623A1/en not_active Abandoned
- 2005-03-25 WO PCT/US2005/010231 patent/WO2005096888A1/en active Application Filing
- 2005-03-30 TW TW94110043A patent/TW200534986A/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4379729A (en) * | 1979-08-09 | 1983-04-12 | Tarmac Industrial Holdings Limited | Method and apparatus for the production of composite sheet material and a sheet material produced thereby |
US5177124A (en) * | 1987-08-19 | 1993-01-05 | Intaglio Ltd. | Plastic molded pieces having the appearance of a solid metallic piece |
US6113199A (en) * | 1997-11-20 | 2000-09-05 | Kewaunee Scientific Corporation | Laboratory countertop |
US6664314B1 (en) * | 1998-03-19 | 2003-12-16 | Blanco Gmbh & Co Kg | Moulding compositions for the production of sanitary-ware components having more than one visible side |
US6376564B1 (en) * | 1998-08-27 | 2002-04-23 | Henkel Corporation | Storage-stable compositions useful for the production of structural foams |
US6212700B1 (en) * | 1999-03-29 | 2001-04-10 | Sealand Technology, Inc. | Portable toilet unit |
Also Published As
Publication number | Publication date |
---|---|
US20050221074A1 (en) | 2005-10-06 |
US7300616B2 (en) | 2007-11-27 |
CA2561623A1 (en) | 2005-10-20 |
TW200534986A (en) | 2005-11-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Bos et al. | Additive manufacturing of concrete in construction: potentials and challenges of 3D concrete printing | |
US7468154B2 (en) | Flexible hydraulic compositions | |
TW443995B (en) | High strength porous concrete structure and method of manufacturing the high strength porous concrete structure | |
CN101337827A (en) | Light aggregate foam concrete building blocks and method for manufacturing same | |
Elistratkin et al. | On the question of mix composition selection for construction 3D printing | |
JP2020512268A (en) | Concrete, a dry mix for the preparation of this concrete, and a method for the preparation of this concrete | |
CN110845196A (en) | High-strength inorganic artificial stone and manufacturing method thereof | |
CN104499498A (en) | Construction method of mass concrete construction | |
US7736574B2 (en) | Perlite composition and method of making the same | |
WO2005096888A1 (en) | Method and apparatus for forming an article of manufacture and an article of manufacture made by a new and novel process | |
Tan et al. | A review of 3D printable construction materials and applications | |
KR20090120634A (en) | A method for manufacturing light brick using used-materials | |
US6099638A (en) | Cement composition for modeling | |
CN107098720A (en) | A kind of zigzag lightweight concrete heat insulating composite building block, formula and preparation method thereof | |
WO2005104750A2 (en) | Method and apparatus for forming a finished article of manufacture and a finished article of manufacture made by a new and novel process | |
CN103539408B (en) | A kind of brick and preparation method thereof | |
WO2007049136A2 (en) | Method of making constructional elements | |
JPH05194057A (en) | Composite solid product of polystyrene/foam cement, and its production | |
JPH10121730A (en) | Reduction construction method for crack due to temperature of concrete | |
Annappa | Green cement based material optimization for additive manufacturing in construction | |
CN110204251A (en) | A kind of neo-epoxy resin concrete material and preparation method thereof | |
JP4500982B2 (en) | Curing and curing method for cement-based moldings | |
Singh et al. | Additive Manufacturing through Digital Concrete by Extrusion and Non-extrusion method | |
JPH026378A (en) | Production of lightweight cellular concrete | |
JPH0640759A (en) | Production of high-strength light-weight concrete molded body and concrete molded body |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2561623 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2005730318 Country of ref document: EP |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWW | Wipo information: withdrawn in national office |
Country of ref document: DE |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: 2005730318 Country of ref document: EP |
|
122 | Ep: pct application non-entry in european phase |