WO2005080490A1 - Solution de chelats de metaux et polymeres, et applications correspondantes - Google Patents

Solution de chelats de metaux et polymeres, et applications correspondantes Download PDF

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Publication number
WO2005080490A1
WO2005080490A1 PCT/CN2004/000981 CN2004000981W WO2005080490A1 WO 2005080490 A1 WO2005080490 A1 WO 2005080490A1 CN 2004000981 W CN2004000981 W CN 2004000981W WO 2005080490 A1 WO2005080490 A1 WO 2005080490A1
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Prior art keywords
metal complex
polymer solution
complex polymer
metal
acid
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PCT/CN2004/000981
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English (en)
Chinese (zh)
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Caiteng Zhang
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Caiteng Zhang
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Priority to TW094103202A priority Critical patent/TW200600530A/zh
Publication of WO2005080490A1 publication Critical patent/WO2005080490A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H11/00—Compounds containing saccharide radicals esterified by inorganic acids; Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H23/00—Compounds containing boron, silicon, or a metal, e.g. chelates, vitamin B12
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
    • C08L5/08—Chitin; Chondroitin sulfate; Hyaluronic acid; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P19/00—Preparation of compounds containing saccharide radicals

Definitions

  • the invention relates to a metal polymer solution and its application, in particular to a metal complex polymer solution related to various condensation reaction solutions, oxidative condensation reaction solutions and other reaction solutions, and applications thereof.
  • the metal complex polymer solution is used in various catalyst reactions, fungicides, biochemical reactions for fermentation, genetic engineering, bacteria preservation systems, cell proliferation media, medical, plants, semiconductors, nanofiltration, nanomanufacturing, power generation, liquid crystal Applications and various environmental protection chemical fields, such as removing organic solvent gases and other toxic gases, and treating waste solvent liquids. Background technique
  • the condensation reaction is an important unit reaction in the chemical process. It is well known that styrene gas becomes polystyrene solid and monomer gas becomes solid polymer. Both are condensation polymerization reactions, but the polymerization reaction sometimes The initial reaction (local oxidation reaction) is required for the reaction to succeed.
  • the catalyst structure of the early condensation reaction is very complicated, and the initial reaction (local oxidation reaction) and the condensation reaction are separated.
  • oxidative condensation can be reacted together. For non-oxidative condensation with higher stability, it is not enough to react together. Some require high-temperature and high-pressure reactions to achieve this. The investment cost and financial and material resources can be imagined, but the present invention is simple to achieve.
  • chitin is a natural polysaccharide polymer that is widely found in shrimp, crab, and insect shells such as fungi and algae.
  • the physiological activity of chitin is functional Nature, non-toxic and non-irritating allergic reaction to the human body, has good biocompatibility with the human body, no antibody response, used in environmental protection can absorb heavy metals and many monovalent, bivalent or trivalent metal ions, most people only know
  • metal ions it is necessary to cooperate with other media (such as carbon tetrachloride or sodium sulfate), but it is not known that after proper proportion with monovalent, bivalent, or trivalent metal ions, it can exert oxidative cracking and condensation on specific chemical poisonous gases.
  • the reaction of polymerized organic solvents also has applications in biocides, medical, biochemical, nano, plants, semiconductors, power generation, and liquid crystal.
  • the purpose of the present invention is to overcome the defects of the existing technology and provide a new metal complex polymer solution.
  • the main technical problem to be solved is to make it have good oxidation ability, condensation ability, oxidative condensation ability, Cracking capacity.
  • Another object of the present invention is to provide a metal complex polymer solution.
  • the technical problem to be solved is to make it widely used in the field of environmental protection, fungicides, biochemical reactions for fermentation, genetic engineering, bacteria preservation system, and cell proliferation.
  • Yet another object of the present invention is to provide a metal complex polymer solution.
  • the technical problem to be solved is to make it more practical, and to greatly improve economic benefits, so as to have an improved efficacy in general and an industry. Utilization value.
  • a metal complex polymer solution according to the present invention includes one or more metal complex polymers.
  • metal complex polymer solution described above wherein the metal complex polymer solution is made of low, medium and high molecular polymers having a hydroxyl group or an amino group and a metal salt solution according to a conventional method.
  • the aforementioned metal complex polymer solution wherein the metal complex polymer solution is a low-, medium-, or high-molecular polymer having hydroxyl or amino groups dissolved by R-C00H or an inorganic acid, and then a metal salt solution is added, and the conventional method is used. Mix and mix.
  • the aforementioned metal complex polymer solution wherein the metal complex polymer solution is R-C00H or an inorganic acid dissolving low, medium and high molecular polymers having hydroxyl groups, and then adding a metal salt solution and ammonia or amines Substances, and mixed according to conventional methods.
  • the aforementioned metal complex polymer solution wherein the metal complex polymer solution is R-C00H carboxylic acid or alkaline saponification R-C00H has a medium to high amount of hydrocarbon groups such as fatty acids, and then a metal salt is added
  • the solution and ammonia or amines are mixed and mixed according to conventional methods.
  • metal salt solution is one or more monovalent, divalent or trivalent metal salt solutions, the mass percentage of which is 0. 01 ⁇ 10%
  • the aforementioned metal complex polymer solution wherein the metal salt solution is beryllium, magnesium, calcium, strontium, barium, radium, nickel, chromium, lead, copper, iron, zinc, titanium, manganese, cobalt, silver, gold , Platinum, palladium, cadmium, Lithium, rubidium, cesium, mercury, tin, zirconium, aluminum, rubidium, antimony, 4-yi, germanium, gallium, molybdenum, tungsten, 4-ethyl, chain, rhodium, iridium, thallium, thorium, ruthenium, thorium, vanadium, indium, Salt solutions of manganese, lanthanide and actinide metals.
  • the metal salt solution is beryllium, magnesium, calcium, strontium, barium, radium, nickel, chromium, lead, copper, iron, zinc, titanium, manganese, cobalt, silver, gold , Platinum, palladium
  • the aforementioned metal complex polymer solution wherein the R-C00H or the inorganic acid is one or more, and its mass percentage accounts for 1 to 10% of the mass of the metal complex polymer solution, wherein R is a base .
  • the aforementioned metal complex polymer solution wherein the R-C00H is acetic acid, citric acid, vitamin C, salicylic acid, oxalic acid, gallic acid, propionic acid, lactic acid, malic acid, succinic acid, and adipic acid , Tartaric acid, medlar acid, fatty acids, OPINES in plants, wherein the inorganic acids are hydrochloric acid, phosphoric acid, nitric acid, and gram acid.
  • the metal or polymer polymer having a low, intermediate, or high molecular weight percentage of the metal or polymer compound having a hydroxyl or amino group Low, medium and high molecular polymers are: chitin; sucrose, maltose, lactose, trehalose, disaccharides, monosaccharides; cracking oils; or artificial chitin; or cytokinin- 0-glucos ides, etc.
  • Monosaccharide bimolecules that is, a substance that combines cytokinin and glucose, can promote cytoplasmic division and have similar physiological effects as kinet in; or must be combined with ammonia (or amines) )
  • Material of polyvinyl alcohol; or humic acid that does not require acid dissolution to be compatible with ammonia (or amine) materials or 0.1-6% of hydroxypropyl methylcellulose and 1 to 4% of chitin ; Or 0.1 to 6% of hydroxypropyl fluorenyl cellulose and 1 to 4% of synthetic chitin; or hydroxypropyl fluorenyl cellulose to be compounded with ammonia (or amine) substances; or Propylfluorenyl cellulose; or Hydroxy or amino polymer or an oil or sugar, and mixtures thereof.
  • the metal complex polymer solution contains saccharides. In the foregoing metal complex polymer solution, the metal complex polymer solution contains silicic acid.
  • the aforementioned low-molecular metal complex polymer solution is characterized in that a monosaccharide molecule or a monosaccharide-containing bimolecular metal complex polymer solution or a high molecular cross-linking agent is contained.
  • the polymer crosslinker or hygroscopic agent is exemplified by PVP (polyvinylpyrrolidone).
  • the aforementioned metal complex polymer solution is characterized in that it contains / does not contain a protease or bacteria or cells.
  • a metal complex polymer solution proposed in accordance with the present invention can be applied to oxidation reactions, cleavage reactions, condensation reactions, oxidative condensation reactions, fungicides, biochemical reactions for fermentation, genetic engineering, bacteria preservation systems, culture medium for cell proliferation, Medical, nanofiltration, manufacturing nanomaterials, artificial imitation chitin, metal enzyme biocatalysts, plants, semiconductors, power generation, liquid crystals, and applications in the treatment of waste solvent liquids and removal of harmful gases.
  • a metal complex polymer solution proposed by the present invention is made of chitin; or sucrose; or maltose; or lactose; or trehalose; or disaccharides; or monosaccharides; or cracked oils; or artificial synthesis Chitin or monosaccharide bimolecules such as cytokinin-0-glucos ides; or polyvinyl alcohol solution must be mixed with ammonia (or amine) substances; or humic acid solution must be mixed with ammonia (or amine) substances without acid Dissolve; or other polymer (chemical-OH) n functional group solution to be mixed with ammonia (or amine) substances; or other polymer (chemical-0H) n functional group solution itself has -NH 2 amino group ; Or chitin 1 ⁇ 4% mixed 0.1 to 6% of hydroxypropyl fluorenyl cellulose; or artificially synthesized chitin 1 to 4% mixed with 0.1 to 6% of hydroxypropyl fluorenyl cellulose; or
  • nano-iron and desired metal can be obtained. Separate and purify iron from desired metal ; Or adjust the PH value to combine the wrong body, the structure tends to be stable and other methods. Then add the above 1 ⁇ 4% gaseous (or amine) substances.
  • the existing amino groups (such as chitin or those mixed with chitin) need not be added : uniformly mixed or stirred at high speed to form a condensation reaction solution or oxidative condensation.
  • the reaction solution locally or separately added acidified or chlorinated or hydroxide or inorganic polymer divalent iron ions have the ability to oxidize the gas), after stirring, a sufficient combination is generated to make it stable.
  • Hygroscopic agent or without any hygroscopic agent; when the polymer having hydroxyl or amino group is a mixture of chelatin 1 to 4% and 0.1 to 6% hydroxypropyl sulfonyl cellulose, or synthetic chitin 1 Mixture of ⁇ 4% and 0.1 to 6% hydroxypropyl fluorenyl cellulose, or hydroxypropyl fluorenyl cellulose with a small amount of ammonia (or amine) substances, or independent hydroxypropyl fluorenyl cellulose (Without any hygroscopic agent at this time), stir and mix to make it deliquescence, then cover the solution with saturated carbon or ceramic chemical fiber network, and then dry the soaked fiber network Moisture.
  • This condensation reaction solution or oxidative condensation reaction solution can stir and run a large number of organic solvents and waste solvents at high speed, so that the organic solvent is condensed into a solid state of clay, and developed into a waste solvent processor.
  • the chitin referred to in the present invention also includes chitin (also known as chitosan, chitin) and synthetic chitin, which are commercially available from shrimp and crab shells, and are prepared by artificial synthesis. product.
  • the main quality indicators of raw material chitin such as color moisture content, ash content, viscosity, solubility, etc., are closely related to the preparation of the condensation reaction solution or the oxidation condensation reaction solution and the quality of the sensitivity of the reaction solution.
  • the requirements for the quality index of raw material chitin are moisture content ⁇ 20%, ash content ⁇ 10%, logarithmic viscosity in the range of 0.5 to 5.5, and good solubility; condensation or oxidation reaction prepared by this method
  • the concentration of chitin in the liquid is generally 0.1 to 10%, and the preferred concentration range is 1 to 6%.
  • a chemical composition with the same chemical state and function of chitin comprising a composition containing hydroxypropyl fluorenyl cellulose (HPMC) and an amino group, which is pulled by a metal ion as a medium and a catalyst with metal ions.
  • HPMC hydroxypropyl fluorenyl cellulose
  • amino group which is pulled by a metal ion as a medium and a catalyst with metal ions.
  • This solution is a polymer complex, and it becomes an artificial imitation chitin solution containing metal ions.
  • artificial chitin solutions can be used where chitin can be used.
  • Further fermenting the metal to nanoscale, and by means of gas phase or liquid phase or combustion or carbonization, nano metal particles or nano metal oxides or nano complexes are obtained.
  • Metal oxides can also be developed for liquid crystal liquids and other applications in a total of eight fermentation systems. These eight major fermentation systems are similar to the above principles.
  • the polymer of the polymer complex structure according to the present invention wherein the concentration of the chitin solution in acid is 0.1% of the plant, which is water, acetic acid or other acids, and the shell Or other (chemical substance-0H) n polymer, acidified or chlorinated monovalent, divalent, or trivalent metal ions in the ratio of 97: 1: 1: 1 and 88: 4: 4: 4 Sequentially stir and add, and then add ammonia (or amine shield). Those who already have amino groups do not need to add them, and can be further used for biochemical and manufacturing of nano and liquid crystal materials.
  • condensation reaction liquid can be stirred and operated at high speed to condense a large amount of organic solvents and waste solvent liquids, so that the organic solvent can be condensed into a solid state of clay, and developed into a waste solvent processor.
  • the present invention has the following advantages compared with the conventional technology:
  • the invention has fast reaction speed to solvent gas or liquid, does not need high temperature and pressure, and does not need to consume a lot of financial and material resources, and is economical and practical.
  • the invention has high safety, no need to set fire, and no worry about industrial safety.
  • the invention has a long storage period, is not easy to be damaged, and has a very long service life. There is no worry about fullness, because it is a reaction to the media.
  • the present invention solves the problem of environmentally-friendly organic solvents and heavy pollution of toxic gases and difficult fermentation problems, and solves the problem of tight chemical reaction condensation bottles.
  • the invention creates a chitin solution artificially imitated with metal ions, which increases the source and multiple applicability of chitin.
  • the present invention creates a new culture medium for fungicides, biochemical reactions for fermentation, genetic engineering, bacteria preservation systems, medicine, plants, semiconductor applications, and cell proliferation.
  • the present invention creates new technologies for nanofiltration and nanomaterial manufacturing.
  • the invention is a good metal enzyme biocatalyst.
  • the present invention creates new technologies for power generation and liquid crystal materials.
  • the metal complex polymer solution with special structure of the present invention has good oxidizing ability, condensation ability, oxidative condensation ability, and cracking ability; it can be widely used in environmental protection fields, fungicides, biochemical reactions for fermentation, genes Engineering, Bacterial Preservation System, Culture Medium for Cell Proliferation, Medical, Plant, Semiconductor, Nano Filtration, and Technology for Manufacturing Nano, Power Generation, Liquid Crystal. It has many of the above advantages and practical values. It is indeed an innovation without similar publication of similar structural designs in similar products. It is a great improvement both in structure and function. Great progress, and has produced useful and practical effects, and has a number of enhanced functions than the existing metal complex polymer solution, so it is more suitable for practical use, and has extensive industrial use value, hereby New, progressive and practical new design.
  • Fig. 1 is a schematic structural diagram of R-M-NH2 used in the present invention.
  • Fig. 2 is a schematic structural diagram of R-NH2-M applied in the present invention.
  • Fig. 3 is a process of forming a polymer metal complex, an amino group-containing polymer metal complex, and an amino group-containing polymer metal enzyme complex according to the present invention.
  • FIG. 4 is a schematic diagram of the structure of the “bow” arrangement of maltose in the present invention after adding a carboxyl group of an organic acid, a metal salt, and an amino group.
  • FIG. 5 is a series of schematic diagrams of a series of monosaccharide bimolecules contained in Cytokinins (cytokinin) in an example plant before the monosaccharide bimolecules containing organic acids, metal salts, and amino groups in the present invention are added without carboxyl groups.
  • Cytokinins cytokinin
  • Fig. 6 is a mechanism for generating an infrared photocurrent in an oxidation reaction semiconductor film for power generation by a biomass energy source according to the present invention.
  • FIG. 1 is a schematic structural diagram of RM-NH 2 used in the present invention, that is, the hydroxyl group of hydroxypropylfluorenyl cellulose (HPMC) is dehydrated with a metal and inserted into the amino group to form RM-NH 2 .
  • HPMC hydroxypropylfluorenyl cellulose
  • FIG. 2 is a schematic diagram of the structure of R-NH 2 -M used in the present invention, that is, obtained by directly reacting chitin and a metal solution.
  • FIG. 3 is a process of forming an amino-containing polymer metal complex and an amino-containing polymer metal enzyme complex in the polymer metal complex of the present invention. That is, firstly, the low, medium, and high polymer polymers and The metal ions are reacted to obtain a polymer metal complex, and the polymer metal complex is further reacted with an amino group to obtain an amino-containing polymer metal complex.
  • the amino-containing polymer metal complex is further contained under a -C00H carboxyl group. Fermented with protease to obtain amino acid-containing polymer metal enzyme complex.
  • FIG. 4 is a schematic diagram showing the structure of the “bow” arrangement of maltose in the present invention after adding a carboxyl group of an organic acid, a metal salt, and an amino group.
  • FIG. 5 shows a series of structures of monosaccharide bimolecules contained in Cytokinins (cytokinins) in plants before the monosaccharide bimolecules containing organic acids, metal salts, and amino groups in the present invention are added.
  • FIG. 6 shows the mechanism of infrared photocurrent generation in the oxidation reaction semiconductor film for bioenergy generation of the present invention.
  • the invention proposes that the preparation of the polymer complex structure forming solution includes the following steps:
  • cytokinins refers to the substance that cytokinin binds to glucose, which can promote cytokinies is, and has similar physiological effects as kinet in), or polyvinyl alcohol
  • the solution must be mixed with ammonia (or amine) substances, or The humic acid solution must be compatible with ammonia (or amine) substances without acid dissolution, or other polymers (chemicals)
  • -OH) n functional group solution should be mixed with ammonia (or amine) substances, or other polymer (chemical -OH) n functional group solution itself has -NH 2 amino group, or chitin 1 ⁇ 4% Mixture with 0.1 to 6% hydroxypropyl fluorenyl cellulose, or artificially synthesized chelatin 1 to 4% and 0.1 to 6% hydroxypropyl fluorenyl cellulose, or hydroxypropyl Methylcellulose must be mixed with ammonia (or amine) substances, or independent hydroxypropyl fluorenyl cellulose (when it is a cracking reaction solution, it is not necessary to mix with amino or ammonia or amines), or most of the above Mixed slurry
  • the ideal upper limit is generally 50%. It is better for chitin to be positively charged if it has an existing amino group. During the chelation oxidation of iron ions, iron ions can be induced to generate negative charges on the reaction gas and produce an oxidation reaction.
  • the filter can be used without hygroscopic agent and high dry sensitivity.
  • condensation reaction solution or oxidation condensation reaction solution or oxidation reaction solution or cracking reaction solution and the content of 0.1 ⁇ 3% PVP K-30 or other hygroscopic agents are uniformly dissolved with each other or without any hygroscopic agent as follows:
  • the main body is chitin 1 ⁇ 4% mixed with 0.1 ⁇ 6% hydroxypropyl fluorenyl cellulose,
  • the main body is chitin 1 ⁇ 4% mixed with 0.1 ⁇ 6% hydroxypropyl fluorenyl cellulose,
  • chitin is positively charged, mixed hydroxypropylfluorenyl cellulose will tend to be pulled by metal ions.
  • the amino group that absorbs chitin is led to free electrons, so the sensitivity is increased, and no water gas is needed.
  • the above main body is chitin, or synthetic chitin, or the polyvinyl alcohol solution must be mixed with ammonia (or amine) substances.
  • humic acid solution should be mixed with ammonia (or amines), or other polymers (chemicals
  • -0H) n functional group solution should be mixed with ammonia (or amine) substances, or other polymer (chemical-0H) n functional group solution itself already has -NH 2 amino group, it needs water vapor, or as the case may be
  • the -0H functional group generates dehydrogenation with metal ions so that the dehydration reaction cooperates with the -NH 2 functional group bridging polymer metal complex which occurs to organic solvent gas, or other poisonous gas or liquid, it has oxidative cracking and condensation polymerization reaction, So the next step is to rely on the deliquescence and high humidity (water) or dry air of PVP K-30 to operate, so the filter reaction to remove organic solvent gas is very smooth, which can last for months or even a year. How long does it fill up quickly.
  • the functional group solution of PV A or other polymer (chemical-OH) n, or the functional group solution of other polymer (chemical- 0H) n already has -NH 2 amino group, or chitin, or humic substance.
  • Acid, or hydroxypropyl phosphonium cellulose has the following fermentation (the first three may not necessarily depend on the addition of sugars as accelerators, if its (R-OH) n is similar to the structure of sugars, Under dissolution, the metal complex structure has an amino group coordination, the molecular chain contains asymmetric carbon atoms, has a special helix phenomenon, and can be fermented) and characteristics similar to the following complex principle, including hydroxypropyl hydrazone
  • the composition of cellulose (HPMC) combined with metal ions and amino groups has high efficiency and long-lasting stable fermentation characteristics.
  • hydroxypropyl methyl cellulose When metal ions are used as a medium to pull, hydroxypropyl methyl cellulose can be mixed with NH 3 , and when hydroxypropyl R-0H functional group of methylcellulose, hydrogen is dehydrogenated by metal ions and dehydrated to form RM:
  • chitin chemical solution and chemical state and chemical molecular structure It is a macromolecular complex and becomes an artificial imitation chitin solution containing metal ions, and then adding bacteria or enzymes or smaller Nucleic acids or some viable cell bodies do not need to consider their nutritional sources and metabolic problems.
  • time is determined by the size of the reaction tank, usually two weeks
  • the activity of metal ions stimulates the enzyme, NH 2
  • the tail is connected with protein enzymes, amino polysaccharides are like molasses, and they can be fermented quickly and grow with a long life span.
  • CPS75000 the higher the CPS, the higher the degree of complex polymerization, the more prone to lipophilicity, dispersing in water, but the life is infinite and permanent, suitable for cell body or bacteria or enzyme or nucleic acid storage system, replication system and environmental protection, chemical industry , Cosmetics, biochemistry, agriculture, fishery, livestock, etc. where chitin can be applied, all artificial chitin solutions containing metal ions can be used.
  • all artificial chitin solutions containing metal ions can be used.
  • the ecological environment of biodiversity the state of bacteria or enzymes, it is appropriate to use a life of less than one year under CPS400. If it is not used for fermentation, it should be freeze-dried and solidified. Therefore, the application of chitin is processed.
  • the solution is not dissolved by the acid of carboxyl group, and the amino acid-containing micrometal complex is formed by fatty acid as the main component "R", then it is not suitable for the growth of bacterial protein and has the function of inhibiting bacteria.
  • Bactericides taking tallow as an example, saponified tallow is converted into sodium salt, which is pulled together with amino groups under the traction of trace metal ions to form a complex, which is a complex salt with multiple NH 2 functional groups. Under the strong traction of NH 2 , it becomes a strong bactericide, supplemented with dilute acid as a penetrant. It can be made into a cream, a liquid, a treatment on the skin, and a purification of the environment. This amino-containing fungicide is easy to attract bacterial proteins, but bacteria without carboxyl groups cannot replicate, and bacteria are naturally destroyed, so it is a very good fungicide.
  • the main chemical composition is not a sugar structure. Fermentation can only be carried out with the addition of sugars.
  • Monosaccharides or disaccharides can be added to stabilize the stability by adding monosaccharides. Highest sex and longest life. For example, PVA itself has a small amount of acetate, and then add some acetic acid, and then add metal salt in the aqueous solution to dehydrate and dehydrate.
  • Enzymes or smaller nucleic acids or part of viable cell bodies can be fermented to grow, and its immobilized structure is as follows: fatty acids -M-NH 2 -proteinases-sugars, these structural bacteria also have a long shelf life.
  • fatty acids The complex structure of carboxyl and metal ion and amino group can also fix the enzyme protein, because this fatty acid contains R with high carbon molecules, and other organic acids containing carboxyl group. Multi-carbon R cannot dominate the body to produce the wrong body.
  • fatty acid-M-NH 2 -proteinase-sugar structure is a replica of cell tissue.
  • Food sources of the human body oil (fatty acid), minerals (metal ions) ), Protein (source of amino groups), enzymes in the body, sugars (rice, noodles), acid substances (organic acids such as onions, lemons), these substances are the source of human cells, and various types of human stem cells such as neural stem cells , Skin stem cells, embryonic stem cells, stem cells of various internal organs, etc.
  • the development of these cells has been developed with different protein enzymes in the body. Therefore, the repair of human cells requires fatty acids-M-NH 2 -proteinase-sugar The structure is achieved. When foods are deliberately lacking carboxylic acid substances, then the rapid expansion of enzymes in the body can be inhibited, and the cell synthesis in the body is also slowed.
  • the body has Germs can inhibit the development of germs.
  • AIDS as an example.
  • the long-term diet control is used to reduce the germs and supplemented with enzymes in the body for long-term treatment.
  • the enzymes in AIDS patients are much larger than AIDS.
  • AIDS bacteria are slowly disappeared.
  • kidney cell recovery first detoxify and detoxify, and then control with the above dietary methods.
  • eat acid supplemented with enzymes in the kidney cells to treat.
  • the kidney function also recovers, so you can use Application in medicine.
  • Another example is a tumor substance in plants, which contains Octopine Fami ly Nopal ine Fami ly, which is a medium carbon (hydrocarbyl) carboxylic acid. It also forms the structure of RM-NH 2 -protease-sugar, which enables cells to continue Splitting can even create important chemicals such as Cytokinin and auxin, monosaccharide-containing bimolecules, and let plants grow endlessly.
  • sucrose can be fermented to grow by adding acetic acid, pure water, metal salts, and ammonia water and adding bacteria or enzymes or smaller nucleic acids or some viable cell bodies.
  • Its immobilized structure is as follows: sucrose-M-NH 2 -proteinase, this type of structure does not require auxiliary sugars, because it is sucrose itself, and the bacteria have a long shelf life. If monosaccharides, acetic acid, pure water, metal salts, and ammonia are mixed uniformly, polymer complexes cannot be represented, and only small molecular complexes with a single scattered distribution cannot be formed. The entire block cannot be connected, and the stability of the fermentation is durable.
  • Monosaccharides and monomolecules are combined to form a bimolecular compound with monosaccharides, and then mixed with acetic acid, pure water, metal salts, and ammonia water. Then add bacteria or enzymes or smaller nucleic acids. Or part of the viable cell body can be fermented and grown, and its immobilized structure is shown as follows: it contains bisaccharide-M-NH2-proteinase, which has a long shelf life. It can be used to achieve metal nanocrystallization.
  • the nutrition sources are light, water, mineral plants in the soil, fragmented organic hydrocarbons and free ammonia nitrogen, carbon dioxide in the air, plants will synthesize sugars and acids containing carboxyl groups.
  • cytokinins in plants, such as cytokinin-o-glucos ides. Together with the special DM and RNA of the plant, it can develop photosynthesis or conduct electricity (instead of light) of the plant to produce a large number of unique plant chemicals or non-conductive production (to change the DNA vector and adaptable reaction mechanism), different in plants. DNA and RNA are produced by photosynthesis in different carriers to produce different chemicals. Now we can control the DNA and RNA of plants, plant bodies, and Photosynthetic mechanisms can produce plant-specific chemicals from nutritional sources. Take the fermentation tank as an example, according to the plant production conditions to control light, water, mineral plants and fragmented organic hydrocarbons and free ammonia nitrogen, carbon dioxide, DNA and RNA fixed carriers can also cultivate the necessary chemicals.
  • the chain-OH symmetrical connection shows a bow-shaped arrangement of the overall molecular dislocation.
  • the "bow" -shaped arrangement of the interlaced energy can be like a filter cloth, with a strong tension solution, with warp and weft, and its fine pores can filter Nano components become nano filter cloth.
  • R-NH 2 contains an amino group, so that the entire solution has both amino groups
  • Basic has carboxyl group (acid group), which is a so-called positive and negative molecule, which drives the thixotropy of the whole solution.
  • negative molecules and adjacent positive molecules gradually develop into complex structures of tens or hundreds of units.
  • amino acids also have amino (basic) and carboxyl groups ( Sour (Basic), whose link is a straight line, and the formed chain is rolled into a circle, forming a unique shape of each protein. Because of the great miscibility between the positive and negative forms of the wrong body solution and the protein tissue form, it has developed into a carrier for protein materials such as cells, bacteria, enzymes, nucleic acids, DNA, RNA and other materials.
  • the host R-0H can be dehydrogenated and dehydrated to R-NH 2 by the metal ion, or the host itself has amino-NH 2 ;
  • reaction amount of metal ions when the reaction amount of metal ions is equivalent, it means that when the main body R-0H is dehydrated and dehydrated by metal ions to form a stable polymer metal complex, too few metal ions will cause the complex to be unstable, and too many metal ions will cause excessive precipitation. Thing.
  • reaction solutions are added with special metal-containing biocatalysts according to the reaction mode, and their catalysts have a complementary and multiplier effect on the treatment of gas or chemical substances.
  • This solution can be added with other precipitants, or with an alkali, or with an excess of metal to precipitate, or with an adsorbent to promote precipitation, and turn it into an enzyme biocatalyst that solidifies metals.
  • Chitin exists in nature and repairs human tissues like cells in the human body. For example, glucosaminoglycan-protein exists in human tissues, and chitin-like solutions containing metal ions can also mimic human tissues.
  • humic acid can grow faster and more robustly in plants with metal ions (inorganic salts) and amino groups than amino-free plants.
  • injured puppy legs have exposed large bones. But applying chitin and metal trace elements is better than chitin alone, and soon the skin, meat, and tendons are restored; for example, in the cultivation system of hydroxypropyl methylcellulose, single-cell cyanobacteria or There is no problem in yeast culture.
  • the fermented bacteria and enzyme solution are used to break the insect eggs into the solution.
  • the tiny nanometer DNA and RNA can be reproduced and cultured on it. It has a spiral shape, which is in line with the original bacteria and enzymes. Clear path. It is proved that this series of solutions can be developed on top of a variety of protein series.
  • cell tissue a variety of proteins are its characteristics. Based on this, various tissue culture techniques are developed.
  • the above series of fermentation solutions are comparable to invertebrate propellant tissue culture media. It is faster than it. It can establish pure cell populations without purification.
  • the metal ion part of the solution in this system can be mixed with various inorganic salts (single addition). It is determined by the culture requirements.
  • Plant hair roots are moved to hair root medium, and animals are moved to animal medium.
  • the seed cell solution can be mixed with nutrient solution, and then the cell tissue continues to develop on it.
  • Take chicken as an example. Take fatty acid-M-NH 2 -protease-sugar structured chicken feed, which is equipped with chicken. Enzyme booster in the body, this chicken can grow up in 45 days without any side effects. Therefore, a large number of animal and plant proliferation and stem cell technology and asexual replication technology can be developed.
  • the metal solution In the era of nanotechnology, the metal solution generally dried at 10-6 meters to become 1 ( ⁇ 9 yards level, generally through the sol-gel method is converted into a gel in order to reach an organometallic, chemical production process is also very Difficult and complicated, but today the protease is almost close to the nanometer level.
  • the R-metal ion-NH 2 -protease is linked to each other in a linked state.
  • the metal complex system it becomes an organic metal, and the positive and negative (negative) attractive forces in the solution are constantly attracted to each other, so that the metal ions are miniaturized, and then become nanoscale.
  • Metal ion nanometers can be used for various special purposes.
  • a protease with a large nanometer number will obtain a larger number of metal nanometers
  • a protease with a smaller nanometer number will be smaller
  • a nucleic acid with a smaller nanometer number will be smaller.
  • some different proteases have different metal crystal phases, and protein enzymes that specialize in heavy metals can create special crystal phase structures.
  • metal ions can be added to the fermentation system to maximize it by about 10%. However, fermentation should be performed while stirring to prevent precipitation. It is advisable to obtain a stable metal ion dose with a smaller number of nanometers.
  • metal ions that cannot be combined can be heated and mixed uniformly; or metal ions with small ionic radius must be mixed with other metal ions; or half fermented with a small amount of iron ions before adding difficult-to-combine metals Ions to continue fermenting to form iron, and iron can be obtained after firing, and then the metal can be separated and purified by magnets; or the pH can be adjusted to bind the wrong body and the structure tends to be stable.
  • the protease is killed by high temperature or the local semi-combustion is turned into nano-film or sintering carbonation to remove organic matter, and become metal carbide or oxide;
  • the compound metal gas is decomposed by evaporation, and then condensed to recover
  • the hydrocarbon and amino group are cleaved with ( ⁇ 2 strong oxygen in the liquid, so that the gas is C0 2 , H 2 0, N 2 fly away.
  • the composite metal must be mixed and added independently before adding the fermentation solution) for further application or the following applications, because nano metal particles can remove chemicals, such as the function of dechlorination; nano oxide powder It has the characteristics of high specific surface area and high pore distribution in the pore volume, and it has a good adsorption capacity for solvents.
  • a titanium catalyst solution is a practical example.
  • titanium sulfate and hydroxypropylfluorenyl cellulose which have been dissolved in acid are combined, The amino group is made into a catalyst solution, and titanium ions are nano-sized by fermentation. After coating, the Ti compound in the composite is semi-combustible and tends to Ti oxide to form a titanium dioxide powder film.
  • the above reaction liquid is a new type of polymer liquid crystal material.
  • This kind of biological liquid crystal has fluidity and order like crystal structure. People have found many RNA, DNA, proteins, lipids, lipoproteins. Polysaccharides and other biological macromolecules and liquid crystal shields are formed by single-helix and double-helix structures.
  • This fermentation series (such as hydroxypropyl fluorenyl cellulose) is the double helix structure produced by fermentation (the unfermented complex structure is a single helix structure, or the water-soluble single helix structure can be used as a liquid crystal, and then added After the nucleic acid is fermented, the protease is added to the double helix structure.)
  • the unfermented complex structure is a single helix structure, or the water-soluble single helix structure can be used as a liquid crystal, and then added After the nucleic acid is fermented, the protease is added to the double helix structure.
  • This Chinese helix structure does not require a solvent and can exist stably, so it is more developmental.
  • This solution is combined with silver sulfate fermentation to silverize nanometer, to obtain nano liquid crystal liquid with high light transmittance and low resistance in visible light region, or dry into a thin film Crystal and liquid crystal thin film electrodes can be used in flat displays.
  • the above reaction solution is a new type of semiconductor component material, which can be a natural electronic component made of protein or cellulose components, for example, the DNA of a plant is fixed in a monosaccharide fermentation system, containing a monosaccharide bimolecule-M-NH2-proteinase.
  • the sugar-M-NH2-proteinase-polymer bridge linker develops organic EL (Organic Electroluminescence) based on the characteristics of photosynthesis in plants.
  • the two major system enzymes are not so tightly fixed. Only when there is external force enzyme activity It will increase and increase, so it is necessary for the plant to receive light and grow with internal electrons.
  • the above reaction liquid is a new type of biomass energy power generation material. It can receive light or other stimuli with specific genes and / or enzymes.
  • the internally generated electrons react to continuously conduct electrons, forming an accumulation of electrons and the occurrence of electromotive force, which generates an electric current.
  • the alfalfa bud seeds in the plant are dormant, and given radiation such as infrared light, the alfalfa buds will germinate.
  • we have extracted the genes and enzymes that have just germinated from the alfalfa buds, and used it in the chitin-NH 2- M-proteinase is the top of the oxidation reaction system. After fermentation, it is dry-coated on the electrode plate.
  • the electrode plate is coated with a coating that emits infrared light.
  • the other side of the electrode plate is PVA -metal M -NH 2 -proteinase-
  • the sugar system acts as a conductive dielectric film, in which the metal is Ru (2) as the sensitizer, and the electrolyte is next.
  • the electrolyte contains 0.02 mol / L of 12 and 0.5 mol / L of Li l.
  • One end is a pt electrode.
  • the situation shows that the synthesis reaction has the effect of holes, so that the oxidation reaction of the chitin system can release electrons e, and the energy level h passes through the sensitizer of the PVA system in the electrolyte and the pt electrode generates oxidation and reduction reactions.
  • the electrons accumulated on the nanocrystals having the oxidation-reactive semiconductor electrode film are collected on the surface of the transmissive electrode and transmitted to the counter electrode through an external circuit.
  • a new type of filter automatic fermentation method Natural inorganic filter honeycomb hole network can grow many bacteria and organisms. Because there are many minerals and rot free media in the inorganic matter, the new filter is made according to the above principle and becomes a The biggest advantage of the inorganic polymer metal complex bacteria-containing carrier is that it is waterproof. As an example, 7 kg of PVA powder is hydrolyzed to form an aqueous solution, then 15 kg of silicic acid solution and 6 kg of metal salts are mixed. The filter is slowly dried and sintered into a ceramic mesh. At this time, the structure is PVA-SI-M metal, and then an acidic chitin solution impregnated with a carboxyl group is added to the ceramic filter.
  • PVA-SI-M-chitin-protease which is now an inorganic polymer metal complex.
  • the bacteria-containing carrier can meet the needs of the development of inorganic and organic related applications with the inorganic system.
  • a method to promote the increase of protease activity in the dry type Generally, bacteria and enzymes are in the aqueous solution or liquid state, and their activity only appears, and the reaction is good, and the function can be expressed. But in the dry type, the bacteria and enzymes are not dead. It is dormant, or the activity declines, cannot respond, and the function cannot be expressed.
  • the reason why bacteria and enzymes can exhibit activity and function in aqueous solution or liquid is because the medium of water is the living carrier of bacteria and enzymes, and the conductive ions in water are bacteria and bacteria. The enzyme reacts to the buffer pool of electronic activity, so bacteria and enzymes in the liquid have vitality. At present, there is a dry system of bacteria and enzymes that can have good vitality.
  • the reaction structure is RM-NH 2
  • the M metal is a trace amount.
  • the structure of the bridged protease is R-a small amount of M-NH 2 -protease, because the relationship of a small amount of M is not stable, and the metal M is beaten freely on each NH 2 -protease.
  • it is a dry structure at this time, because The free pulsation of the metal is as if the conductive ions are moving in the whole body, as in water, so the active energy can be displayed in dry mode, the reaction is good, and the function can be expressed.
  • hydroxypropyl fluorene-based fibers It is soluble in vitamin C.
  • the condensation reaction solution and the oxidative condensation reaction solution are used to treat liquid solvents and waste solvents by using a condensation reaction solution or another type of condensation reaction solution or an oxidative condensation reaction solution or another type of oxidative condensation reaction solution in a high-speed stirring tank.
  • a small amount of liquid solvent at the stirring speed of 100 to 5,000 revolutions per minute, the liquid solvent will react to condense into a plastic film, and finally become fine cement, mixed into the liquid or floated around the reaction tank, and filtered through the filtration system. After the cement is discharged, the waste solvent liquid can be added slowly and continuously. This is a set of waste solvent treatment methods.
  • the embodiment proposed by the present invention apply 1 to 4% (DMAC) powder of chitin with a viscosity of 300 CPS, and place it in 1-4% acetic acid or other acids (including acids with -C00H carboxyl groups, etc.) Inorganic acid) and 97-88% water in a mixed solution, at 20 ° C, made a transparent chitin slurry.
  • DMAC dimethyl methacrylate
  • the mass percentage of the components of the oxidation reaction solution is:
  • the mass composition of the oxidation reaction solution is:
  • the mass percentage composition of the cracking reaction solution is:
  • the mass percentage composition of the condensation reaction solution (also fermentable, nano applications) is:
  • the mass percentage composition of the oxidation condensation reaction solution (also fermentable, nano applications) is:
  • the mass percentage composition of the condensation reaction solution is:
  • the biochemical solution for fermentation is also a metal enzyme biocatalyst, and it is also an artificial imitation chitin solution. Its percentage composition of shield amount is:
  • composition of the bactericide solution is the percentage of shield amount:
  • the application of the bacteria preservation system (also fermentable, nano applications), its mass percentage composition is: sterile water 82%
  • Carbohydrates (monosaccharide or disaccharide) 5%
  • Carbohydrate (monosaccharide or disaccharide) 4%
  • the mass percentage composition is: sterile water 90%
  • the mass percentage composition of the cell proliferation medium is:
  • the mass percentage composition of the nano-manufacturing fluid is:
  • Nano-titanium dioxide fine particle film was obtained after semi-combustion after full fermentation coating.
  • the mass percentage composition of nano liquid crystal is:
  • organic EL in semiconductors (also fermentable, nano applications), its mass percentage composition is: sterile water 90%
  • Polymer cross-linking agent such as PVP 0.03%
  • Inorganic polymer metal complex filter also fermentable, nano application, its mass percentage group becomes:
  • Reactive filters are made of different thicknesses and sizes according to market needs. Generally, 60cm in length and 60cm in width and 10cm or 5cm in thickness are commonly used. This has been coated with activated carbon or ceramic chemical fiber network as the carrier. , Its porosity is above 80%, mixed with 0.1 ⁇ 3% of PVPK-30 are added to the condensation reaction solution or oxidative condensation reaction solution, using two-way forward and reverse double rollers to compress and loosen the filter, and In the compression loosening filter, the above-mentioned medicinal solution is injected to fully absorb and soak, and then dried to remove water. The drying temperature is 90 ° C for 40 minutes, and the storage is fixed.
  • the reaction condition is that the organic solvent waste gas or petroleum-based gas or organic solvent has a similar molecular weight and similar structural gas, and is compatible with Moist (aqueous) or dry air for use.
  • the waste solvent treatment method uses a condensation reaction chemical solution or another type of condensation reaction chemical solution or an oxidative condensation reaction solution.
  • the size of the reaction tank is determined according to the amount of the used waste solvent solution, and the amount of solvent waste liquid is determined by the reaction rate of the chemical solution.
  • the barrel tank has a capacity of 500L in a circular shape, and the mixer rotates at a speed of five hundred revolutions per minute, so that the upper cover of the barrel tank is closed, leaving only the shaft hole of the mixer and the solvent dosing port, and the barrel tank.
  • a liquid recovery and filtration system is attached to allow the cement to be discharged.
  • the solvent waste liquid is added at a rate of 150cc per minute.
  • the dosing machine is used for dosing, so the waste solvent waste liquid can be added slowly without worry. .

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Abstract

La présente invention concerne une solution de chélats de métaux et polymèrex et les applications correspondantes. La solution contient une ou plusieurs sortes de chélats de métal et polymère. Ces chélats s'obtiennent à partir d'un polymère hydroxylé ou aminé que l'on mélange uniformément avec une solution de sels de métaux. Cette solution convient à de nombreux domaines d'application tels que les réaction d'oxydation, la condensation, le craquage, la condensation oxydative, la dissolution des chitosans artificiels, les antiseptiques, les réactions de biochimie en relation avec la fermentation, le génie génétique, les systèmes de conservation des champignons, les milieux de culture pour multiplication cellulaire, les traitements médicaux, les végétaux, les semi-conducteurs, la nanofiltration, l'élaboration de matériaux nanométriques, les sources électriques, et les afficheurs à cristaux liquides. Ces solutions de chélats de métaux et de polymères sont utilisables également pour la protection de l'environnement, l'élimination de gaz toxiques, et le traitement des effluents liquides.
PCT/CN2004/000981 2004-02-23 2004-08-24 Solution de chelats de metaux et polymeres, et applications correspondantes WO2005080490A1 (fr)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150093638A1 (en) * 2013-09-30 2015-04-02 Panasonic Corporation Non-aqueous electrolyte secondary battery
US20160036057A1 (en) * 2014-07-30 2016-02-04 Panasonic intellectual property Management co., Ltd Nonaqueous electrolyte secondary battery
CN108866531A (zh) * 2018-07-20 2018-11-23 广东顺德中海源富环保科技有限公司 一种含锆硅烷处理剂及利用该含锆硅烷处理剂的钝化方法
CN109705235A (zh) * 2018-12-29 2019-05-03 湖北工程学院 一种壳聚糖-金属配合物及其制备方法和应用

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0366612A (ja) * 1989-08-04 1991-03-22 Sato Seiyaku Kk 口内軟膏
JPH0549684A (ja) * 1991-08-22 1993-03-02 T Hasegawa Co Ltd 消臭組成物
CN1234367A (zh) * 1998-05-06 1999-11-10 中国科学院福建物质结构研究所 一种回收、分离、提纯no气体的方法
WO2001012218A1 (fr) * 1999-08-16 2001-02-22 Zonagen, Inc. Procedes et matieres servant au traitement du carcinome prostatique
CN1317496A (zh) * 2000-04-11 2001-10-17 海南大学 壳聚糖金属配合物的形成与控制降解
KR20010106359A (ko) * 2001-10-30 2001-11-29 조석형 가축사료용 킬레이트 화합물
CN1356295A (zh) * 2001-12-11 2002-07-03 广州甘蔗糖业研究所 利用糖蜜酒精糟生产甘蔗专用有机复混肥的方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0366612A (ja) * 1989-08-04 1991-03-22 Sato Seiyaku Kk 口内軟膏
JPH0549684A (ja) * 1991-08-22 1993-03-02 T Hasegawa Co Ltd 消臭組成物
CN1234367A (zh) * 1998-05-06 1999-11-10 中国科学院福建物质结构研究所 一种回收、分离、提纯no气体的方法
WO2001012218A1 (fr) * 1999-08-16 2001-02-22 Zonagen, Inc. Procedes et matieres servant au traitement du carcinome prostatique
CN1317496A (zh) * 2000-04-11 2001-10-17 海南大学 壳聚糖金属配合物的形成与控制降解
KR20010106359A (ko) * 2001-10-30 2001-11-29 조석형 가축사료용 킬레이트 화합물
CN1356295A (zh) * 2001-12-11 2002-07-03 广州甘蔗糖业研究所 利用糖蜜酒精糟生产甘蔗专用有机复混肥的方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
JIANG TING DA ET AL: "PROGRESS OF RESEARCH ON CHITOSAN COMPLEXES AS CATALYST.", no. 1, 1996, pages 23 - 27 *
JIN YAN. ET AL: "SYNTHESIS AND CHARACTERIZATION OF NANOMETER-SIZED ZnS..Mn IN CHITOSAN.", CHINESE JOURNAL OF LUNINESCENE., vol. 19, no. 3, September 1997 (1997-09-01), pages 253 *
ZHOU Y. ET AL: "The research on Structure and Property of Chitosan Linking Menbrane.", JOURNAL OF MOLECULAR SCIENCE., vol. 13, no. 3, September 1997 (1997-09-01), pages 168 - 169 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150093638A1 (en) * 2013-09-30 2015-04-02 Panasonic Corporation Non-aqueous electrolyte secondary battery
US9478830B2 (en) * 2013-09-30 2016-10-25 Panasonic Corporation Non-aqueous electrolyte secondary battery comprising phosphoric acid ester compound containing at least one metal element
US20160036057A1 (en) * 2014-07-30 2016-02-04 Panasonic intellectual property Management co., Ltd Nonaqueous electrolyte secondary battery
US9947931B2 (en) * 2014-07-30 2018-04-17 Panasonic Corporation Non-aqueous electrolyte secondary battery including phosphoric acid ester compound containing at least one metal element
CN108866531A (zh) * 2018-07-20 2018-11-23 广东顺德中海源富环保科技有限公司 一种含锆硅烷处理剂及利用该含锆硅烷处理剂的钝化方法
CN109705235A (zh) * 2018-12-29 2019-05-03 湖北工程学院 一种壳聚糖-金属配合物及其制备方法和应用

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