WO2005057706A1 - Fuel cell system and control method thereof - Google Patents

Fuel cell system and control method thereof Download PDF

Info

Publication number
WO2005057706A1
WO2005057706A1 PCT/KR2003/002728 KR0302728W WO2005057706A1 WO 2005057706 A1 WO2005057706 A1 WO 2005057706A1 KR 0302728 W KR0302728 W KR 0302728W WO 2005057706 A1 WO2005057706 A1 WO 2005057706A1
Authority
WO
WIPO (PCT)
Prior art keywords
fuel
fuel cell
cell stack
heating
line
Prior art date
Application number
PCT/KR2003/002728
Other languages
French (fr)
Inventor
Tae-Hee Cho
Myung-Seok Park
Hong Choi
Kyu-Jung Kim
Myeong-Ho Lee
Cheol-Hwan Kim
Yong-Jun Hwang
Seung-Tae Ko
Seong-Geun Heo
Original Assignee
Lg Electronics Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lg Electronics Inc. filed Critical Lg Electronics Inc.
Priority to PCT/KR2003/002728 priority Critical patent/WO2005057706A1/en
Priority to AU2003304609A priority patent/AU2003304609A1/en
Priority to EP03819114A priority patent/EP1704612A1/en
Priority to US10/483,385 priority patent/US20050142409A1/en
Priority to CNA038006960A priority patent/CN1689182A/en
Publication of WO2005057706A1 publication Critical patent/WO2005057706A1/en

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04225—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during start-up
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04228—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during shut-down
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/043—Processes for controlling fuel cells or fuel cell systems applied during specific periods
    • H01M8/04302—Processes for controlling fuel cells or fuel cell systems applied during specific periods applied during start-up
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/043—Processes for controlling fuel cells or fuel cell systems applied during specific periods
    • H01M8/04303—Processes for controlling fuel cells or fuel cell systems applied during specific periods applied during shut-down
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the present invention relates to a fuel cell system, and more
  • cathode 104 are stacked with the plural number; a fuel tank 108 for storing fuel including hydrogen to be supplied to the anode 102; and an air supplying
  • unit 110 for supplying air including oxygen to the cathode 104.
  • a fuel pump 112 for pumping fuel stored in the fuel tank 108 is
  • the air supplying unit 110 includes: an air pump 114 for supplying air
  • a water tank 120 for supplying water to the humidifier 118.
  • electrochemical oxidation of hydrogen is performed in the anode 102 and an
  • electrochemical deoxidation of oxygen is performed in the cathode 104 in a
  • the generated electricity is supplied to a load 126.
  • a temperature of the fuel cell stack is maintained to be high
  • a fuel cell stack that an anode and a cathode are arranged in a
  • a cooling fan for cooling the fuel cell stack when the system driving is
  • the heating unit is composed of a hydrogen combustor installed at
  • the purge unit is composed of a fuel recollecting line connected
  • controlling a fuel cell system comprising: a heating step for heating fuel; an
  • the heating step further comprises a step for driving a system by using a power source of a battery after heating fuel.
  • a recycle pump is driven to recollect fuel remaining
  • FIG. 1 is a construction view of a fuel cell system in accordance
  • Figure 2 is a construction view of a fuel cell system according to one
  • Figure 3 is a sectional view of a fuel tank of a fuel cell system
  • Figure 4 is a block diagram showing a control means of a fuel cell
  • Figure 5 is a construction view of a fuel cell system according to one embodiment of the present invention.
  • Figure 6 is a flow chart showing a control method of a fuel cell
  • Figure 2 is a construction view of a fuel cell system according to one
  • a fuel cell system according to the present invention comprises: a
  • reaction between hydrogen and oxygen and a cathode 12 are stacked with
  • a fuel tank 16 for storing fuel to be supplied to the anode
  • a hydrogen combustor 22 for heating fuel and air supplied to the fuel cell
  • the fuel cell stack 14 is provided with a cooling fan 20 for cooling the
  • the fuel tank 16 is connected to the anode 10 of the fuel cell stack 14 by a fuel supplying line 26, and a fuel pump 28 for pumping fuel stored in
  • the fuel tank 16 is installed at one side of the fuel supplying line 26.
  • the fuel tank 16 includes a fuel kit 30 for
  • the fuel power stored in the fuel kit 30 is composed of NaOH and
  • the air supplying unit 18 includes: an air supplying line 34 for
  • an air filter 36 installed at an entrance of the air supplying line and filtering air
  • humidifier 38 is provided with a water tank 40 for supplying water.
  • the purge unit can be implemented by various methods, which will be described
  • the purge unit includes: a gas/liquid
  • the hydrogen combustor 22 is connected with the fuel supplying line
  • the purge unit drives the fuel pump 28 in a
  • purge line and the fuel supplying line are connected to each other.
  • valve is operated to connect the air supplying line and the anode each other
  • Figure 5 is a block diagram showing a control means for controlling
  • the control means includes: a temperature sensor 64 installed at the
  • on/off switch 66 for turning on/off a fuel cell
  • control unit 80 for controlling
  • Figure 6 is a flow chart showing a control method of the fuel cell
  • the fuel kit 30 is mounted at the fuel tank 16 thus to mix water
  • the fuel cell system is operated by a power of a battery (not shown) (S20).
  • the fuel pump 28 is operated and
  • the air pump 42 is operated and thereby air is
  • the hydrogen exhausted from the gas/liquid separator 44 is supplied.
  • the hydrogen is ignited in the hydrogen combustor 22 thus to generate heat
  • a temperature of the fuel cell stack 14 can reach a goal
  • control unit 80 compares a temperature of the fuel cell stack 14
  • the cell stack 14 is more than the set temperature ⁇ .
  • the set temperature ⁇ the set temperature
  • ⁇ is preferably set as 60°C.
  • control unit 80 compares a temperature of the fuel cell stack 14 with the
  • the set temperature ⁇ is preferably set as
  • control unit 80 stops an
  • unit 80 operates the cooling fan 20 by electric signals applied from the on/off
  • the purge operation is an operation for recollecting fuel
  • control unit 80 reversely drives the fuel pump 28 when the system is stopped
  • control unit 80 operates the three-valve thus to connect the air supplying line
  • the purge mode can be applied to any step since the user can stop
  • the fuel cell system if necessary while the system is operated. Also, if the
  • on/off switch 66 is adjusted into on in order to re-operate the system by the
  • the fuel cell stack can reach a goal temperature within the shortest time thus

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

Disclosed is a fuel cell system comprising: a fuel tank (16) connected to a anode (10) of a fuel cell stack (14) for supplying hydrogen-including fuel to the anode (10); an air supplying unit (18) connected to a cathode (12) of the fuel cell stack for supplying oxygen-including air to the cathode (12); a heating unit for heating air and fuel supplied to the fuel cell stack; and a purge unit for returning fuel remaining at each system to the fuel tank (16) when a system driving is stopped. According to this, a temperature of the fuel cell stack can reach a goal temperature within the shortest time by heating fuel at the time of driving a system, and fuel remaining at the fuel cell stack and each system is returned to the fuel tank when the system driving is stopped, thereby increasing a performance of the fuel cell system.

Description

FUEL CELL SYSTEM AND CONTROL METHOD THEREOF
TECHNICAL FIELD
The present invention relates to a fuel cell system, and more
particularly, to a fuel cell system capable of increasing a reliability of a fuel
cell by making a temperature of a fuel cell stack reach a goal temperature
within the shortest time and capable of enhancing a stability of the fuel cell by
fast dropping a temperature of the fuel cell stack at the time of stopping the
fuel cell, and a control method thereof.
BACKGROUND ART In general, a fuel cell system has been proposed as a substitution of
fossil fuel and differently from a general cell (a second cell), it supplies fuel
(hydrogen or hydrocarbon) to an anode and supplies oxygen to a cathode.
Thus, the fuel cell system undergoes an electrochemical reaction between
hydrogen and oxygen without a combustion reaction (oxidation reaction) of
fuel and thereby directly converts an energy difference between before and
after a reaction into electric energy.
As shown in Figure 1 , a fuel cell system in accordance with the
conventional art comprises: a fuel cell stack 106 where an anode 102 having
an electrolyte membrane (not shown) therein in order to generate electric
energy by an electrochemical reaction between hydrogen and oxygen and a
cathode 104 are stacked with the plural number; a fuel tank 108 for storing fuel including hydrogen to be supplied to the anode 102; and an air supplying
unit 110 for supplying air including oxygen to the cathode 104.
A fuel pump 112 for pumping fuel stored in the fuel tank 108 is
installed between the fuel tank 108 and the anode 102 of the fuel cell stack
106.
The air supplying unit 110 includes: an air pump 114 for supplying air
in the atmosphere to the cathode 104 of the fuel cell stack 106; an air filter
116 for filtering air supplied to the fuel cell stack 106; and a humidifier 118 for
humidifying air supplied to the fuel cell stack 106. Herein, the humidifier 118
is provided with a water tank 120 for supplying water to the humidifier 118.
Processes for generating electric energy by supplying fuel to the
conventional fuel cell will be explained as follows.
If the fuel pump 112 is operated by a control signal of a control unit
(not shown), fuel stored in the fuel tank 108 is pumped thus to be supplied to
the anode 102 of the fuel cell stack 106. Also, if the air pump 114 is operated,
air filtered by the air filter 116 passes through the humidifier 118 thus to be
humidified and is supplied to the cathode 104 of the fuel cell stack 106.
Once fuel and air are supplied to the fuel cell stack 106, an
electrochemical oxidation of hydrogen is performed in the anode 102 and an
electrochemical deoxidation of oxygen is performed in the cathode 104 in a
state that the electrolyte membrane (not shown) is positioned between the
anode 102 and the cathode 104. At this time, generated electron moves and
thereby electricity is generated. The generated electricity is supplied to a load 126.
In the conventional fuel cell system, it takes a lot of time to make a
temperature of the fuel cell stack reach a goal temperature, so that a
reliability and a function of the fuel cell are degraded. Also, a temperature of the fuel cell stack is maintained to be high
even after stopping the fuel cell, so that a stability of the fuel cell is lowered.
DISCLOSURE OF THE INVENTION
Therefore, it is an object of the present invention to provide a fuel cell
system capable of increasing a reliability and a function of a fuel cell by
making a temperature of a fuel cell stack reach a goal temperature within the
shortest time by heating fuel by using heat generated when fuel powder is
mixed with water and heat generated when hydrogen generated from an
anode of the fuel cell stack is ignited, and a control method thereof. It is another object of the present invention to provide a fuel cell
system capable of increasing a stability of a fuel cell by fast dropping a
temperature of a fuel cell stack when the fuel cell system is stopped and
capable of increasing a performance by returning fuel remaining at each
system to a fuel tank, and a control method thereof. To achieve these objects, there is provided a fuel cell system
comprising: a fuel cell stack that an anode and a cathode are arranged in a
state that an electrolyte membrane is interposed therebetween; a fuel tank
connected to the anode of the fuel cell stack by a fuel supplying line for supplying hydrogen-including fuel to the anode; an air supplying unit
connected to the cathode of the fuel cell stack by an air supplying line for
supplying oxygen-including air to the cathode; a heating unit for heating air
and fuel supplied to the fuel cell stack; and a purge unit for returning fuel
remaining at each system to the fuel tank when a system driving is stopped. A cooling fan for cooling the fuel cell stack when the system driving is
stopped is installed at the fuel cell stack.
The heating unit is composed of a hydrogen combustor installed at
the fuel supplying line and the air supplying line for heating fuel and air
supplied to the fuel cell stack by using hydrogen generated from the fuel cell
stack as a heating source.
The purge unit is composed of a fuel recollecting line connected
between the fuel cell stack and the fuel tank for recollecting fuel discharged
from the fuel cell stack into the fuel tank, and a recycling pump installed at
the fuel recollecting line for returning fuel remaining at each system to the
fuel tank through the fuel recollecting line when a system driving is stopped.
To achieve these objects, there is also provided a method for
controlling a fuel cell system comprising: a heating step for heating fuel; an
electricity generating step for supplying the heated fuel and air to a fuel cell
stack and thus generating electric energy; and a purge step for returning fuel
remaining at each system to a fuel tank when a system driving is stopped
while performing the first and second steps.
The heating step further comprises a step for driving a system by using a power source of a battery after heating fuel.
In the heating step, fuel is heated by using heat generated when fuel
is mixed with water.
In the heating step, a fuel kit where fuel powder (NaOH and BH4
powder) is stored is mounted to a fuel tank where water is stored and thereby
fuel powder is mixed with water.
In the purge step, a recycle pump is driven to recollect fuel remaining
at the fuel cell stack and each line to the fuel tank through a recollecting line
when a system driving is stopped.
BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a construction view of a fuel cell system in accordance
with the conventional art;
Figure 2 is a construction view of a fuel cell system according to one
embodiment of the present invention;
Figure 3 is a sectional view of a fuel tank of a fuel cell system
according to the present invention;
Figure 4 is a block diagram showing a control means of a fuel cell
system according to one embodiment of the present invention; Figure 5 is a construction view of a fuel cell system according to
another embodiment of the present invention; and
Figure 6 is a flow chart showing a control method of a fuel cell
system according to one embodiment of the present invention. MODES FOR CARRYING OUT THE PREFERRED EMBODIMENTS
Hereinafter, a control method of a fuel cell system according to the
present invention will be explained with reference to attached drawings. Even if a plurality of embodiments can exist in the control method of
a fuel cell system according to the present invention, the most preferable
embodiment will be explained.
Figure 2 is a construction view of a fuel cell system according to one
embodiment of the present invention. A fuel cell system according to the present invention comprises: a
fuel cell stack 14 where an anode 10 having an electrolyte membrane (not
shown) therein in order to generate electric energy by an electrochemical
reaction between hydrogen and oxygen and a cathode 12 are stacked with
the plural number; a fuel tank 16 for storing fuel to be supplied to the anode
10; an air supplying unit 18 for supplying oxygen including air to the cathode
12; a hydrogen combustor 22 for heating fuel and air supplied to the fuel cell
stack 14 by using hydrogen generated from the anode 10 after a reaction; a
purge unit for recollecting fuel remaining at each system to the fuel tank 16
when the system is stopped; and a control means for controlling each
component.
The fuel cell stack 14 is provided with a cooling fan 20 for cooling the
fuel cell stack 14.
The fuel tank 16 is connected to the anode 10 of the fuel cell stack 14 by a fuel supplying line 26, and a fuel pump 28 for pumping fuel stored in
the fuel tank 16 is installed at one side of the fuel supplying line 26.
Also, as shown in Figure 3, the fuel tank 16 includes a fuel kit 30 for
increasing a temperature of fuel by using reaction heat generated when fuel
powder is mixed with water stored in the fuel tank 16 before operating the
fuel cell system; and a blade 32 for making fuel power be mixed with water
well when the fuel power is supplied to the fuel tank 16 from the fuel kit 30.
The fuel power stored in the fuel kit 30 is composed of NaOH and
BH4. If the NaOH is mixed with water, a reaction is performed as a following
reaction formula and heat is generated.
Reaction formula: NaOH + H20 -> NaOH (H20) + 9-13 Kcal/mol The air supplying unit 18 includes: an air supplying line 34 for
introducing air in the atmosphere to the cathode 12 of the fuel cell stack 14;
an air filter 36 installed at an entrance of the air supplying line and filtering air
sucked into the air supplying line 34; an air pump 42 installed at one side of
the air supplying line 34 and generating a suction power for sucking external
air; and a humidifier 38 for humidifying air sucked by the air pump 42. The
humidifier 38 is provided with a water tank 40 for supplying water.
The purge unit can be implemented by various methods, which will
be explained as follows.
The purge unit according to one embodiment includes: a gas/liquid
separator 44 for separating fuel discharged from the anode 10 of the fuel cell
stack 14 after reaction into gas and liquid; a recycling line 48 for recollecting liquid fuel discharged from the gas/liquid separator 44 into the fuel tank "16;
and a recycling pump 46 installed at the recycling line 48 and pumping
recycling liquid fuel to the fuel tank 16.
The purge unit according to one embodiment recollects fuel
remaining at the fuel cell stack 14 to the fuel tank 16 through the recycli ng
line 48 by driving the recycling pump 46 for a certain time after the system is
stopped.
NaB02 and 4H2 generated in the anode 10 of the fuel cell stack 14
after reaction are separated into gas and liquid. Herein, water and NaBO2 of
liquid are recollected into the fuel tank 16 through the fuel recycling line 48
and the hydrogen gas is exhausted outside.
The hydrogen combustor 22 is connected with the fuel supplying line
26 and the air supplying line 34 and connected with the gas/liquid separator
by a hydrogen supplying line 50, thereby heating fuel and air which pass
through the fuel supplying line 26 and the air supplying line 34 by using heat
generated when hydrogen supplied from the gas/liquid separator 44 is ignited.
The purge unit according to a second embodiment reversely
drives the fuel pump 28 when the system is stopped and thereby returns fuel
remaining at the fuel cell stack 14 and each line to the fuel tank 16. That is,
when the system is stopped, the purge unit drives the fuel pump 28 in a
reverse direction by a control unit 80 for a certain time.
The purge unit according to a third embodiment, as shown in Figu re
4, is composed of a purge line connected between the fuel supplying line and the air supplying line, and a three-way valve installed at a part where the
purge line and the fuel supplying line are connected to each other.
In the purge unit according to the third embodiment, the three-way
valve is operated to connect the air supplying line and the anode each other
when the system is stopped, and the air pump 42 is operated to supply air to
the anode and thereby fuel remaining at the anode is returned to the fuel tank
through the recycling line.
Figure 5 is a block diagram showing a control means for controlling
the fuel cell system according to the present invention. The control means includes: a temperature sensor 64 installed at the
fuel cell stack 14 and detecting a temperature of the fuel cell stack 14; an
on/off switch 66 for turning on/off a fuel cell; and a control unit 80 for
controlling an operation of each component according to signals applied from
the temperature sensor 64 and the on/off switch 66. A control method of the fuel cell system according to the present
invention will be explained as follows.
Figure 6 is a flow chart showing a control method of the fuel cell
system according to the present invention.
First, the fuel kit 30 is mounted at the fuel tank 16 thus to mix water
stored in the fuel tank 16 with fuel powder stored in the fuel kit 30, thereby
fabricating fuel solution. At this time, as said water and fuel powder are mixed
with each other in the fuel tank 16, heat is generated (S10).
Also, if a temperature of the fuel solution reaches a proper level, the fuel cell system is operated by a power of a battery (not shown) (S20).
That is, by a power of the battery, the fuel pump 28 is operated and
thereby fuel of which temperature is increased by a mixture in the fuel tank
16 is supplied to the anode 10 of the fuel cell stack 14. At the same time, by
a power of the battery, the air pump 42 is operated and thereby air is
supplied to the cathode 12 from the air supplying unit 18. According to this,
fuel and air react with the electrolyte membrane thus to form ions. In the
process that the ions form water by an electrochemical reaction, electron is
generated from the anode 10 and moves to the cathode 12, thereby
generating electricity.
Also, hydrogen generated from the anode 10 of the fuel cell stack 14
after reaction is obtained by the gas/liquid separator 44 thus to be supplied to
the hydrogen supplying line 50.
The hydrogen exhausted from the gas/liquid separator 44 is supplied
to the hydrogen combustor 22 through the hydrogen supplying line 50. Then,
the hydrogen is ignited in the hydrogen combustor 22 thus to generate heat,
and fuel and air supplied to the fuel cell stack 14 are heated by passing
through the hydrogen combustor 22 (S30).
Like this, at the first stage, fuel is heated by using heat generated
from a mixture between fuel and water in the fuel tank 16, and after the fuel
cell system is operated, fuel is heated by the hydrogen combustor 22.
According to this, a temperature of the fuel cell stack 14 can reach a goal
temperature within the shortest time. While the fuel cell system is operated, it is judged that a temperature
of the fuel cell stack 14 is higher than a set temperature α or not (S40).
That is, if the temperature sensor 64 mounted at the fuel cell stack 14
detects a temperature of the fuel cell stack 14 and thus applies to the control
unit 80, the control unit 80 compares a temperature of the fuel cell stack 14
with the set temperature α and thereby judges that a temperature of the fuel
cell stack 14 is more than the set temperature α. Herein, the set temperature
α is preferably set as 60°C.
In said process, if a temperature of the fuel cell stack 14 is judged to
be more than the set temperature α, the battery is charged, the system is
operated by using electric current generated from the fuel cell stack 14, and
current is supplied to a load (S50).
While the fuel cell system is operated, it is judged that the system is
a purge mode state (S60). That is, it is judged that the user stops the system
by adjusting the on/off switch 66 in order to stop the fuel cell system or not.
Herein, if it is judged that the system is not the purge mode state, it is
judged that a temperature of the fuel cell stack 14 is higher than a set
temperature β (S70). That is, if the temperature sensor 64 detects a
temperature of the fuel cell stack 14 and thereby applies to the control unit 80,
the control unit 80 compares a temperature of the fuel cell stack 14 with the
set temperature β. Herein, the set temperature β is preferably set as
approximately 80°C.
In said process, if a temperature of the fuel cell stack 14 is judged to be higher than the set temperature, the cooling fan 20 is operated thus to
prevent a temperature of the fuel cell stack 14 from being increased more
than the set temperature β.
Again, it is judged that the system is a purge mode state (S90). If the system is not a purge mode state, it is judged that a
temperature of the fuel cell stack 14 becomes lower than the set temperature
α (S100).
Also, if it is judged that a temperature of the fuel cell stack 14
becomes lower than the set temperature α, the control unit 80 stops an
operation of the cooling fan 20 (S110).
In the steps of S60 and S90, if it is judged that the system is a purge
mode state, that is, if the user adjusts the on/off switch 66 into off, the control
unit 80 operates the cooling fan 20 by electric signals applied from the on/off
switch 66 thus to perform a cooling of the fuel cell stack 14 and to perform a
purge operation of the system (S120 and S130).
Herein, the purge operation is an operation for recollecting fuel
remaining at each line of the system or the fuel cell stack 14 into the fuel tank
16 before stopping the system.
Various embodiments of the purge operation will be explained as
follows.
By the purge operation according to one embodiment, the control unit
80 drives the recycling pump 46 for a certain time when the system is
stopped and thereby recollects fuel remaining at the fuel cell stack 14 and each line to the fuel tank 16 through the recycling line 48.
By the purge operation according to the second embodiment, the
control unit 80 reversely drives the fuel pump 28 when the system is stopped,
and thereby returns fuel remaining at the fuel supplying line 26 and the fuel
cell stack 14 to the fuel tank 16.
By the purge operation according to the third embodiment, the
control unit 80 operates the three-valve thus to connect the air supplying line
and the anode of the fuel cell stack each other and the air pump is driven
thus to inject air into the anode, thereby returning fuel remaining at the anode
to the fuel tank 16 through the recycling line 48.
Then, if the purge operation is completed, the system is stopped
(S140).
The purge mode can be applied to any step since the user can stop
the fuel cell system if necessary while the system is operated. Also, if the
on/off switch 66 is adjusted into on in order to re-operate the system by the
user after the system is stopped, a power of the battery is transmitted to each
part of the system thus to repeat said processes (S150).
According to the fuel cell system and the control method thereof, at
the first stage, fuel is heated by using heat generated when fuel power is
mixed with water, and after the system is operated, fuel is heated by using
hydrogen generated at the anode after reaction. Therefore, a temperature of
the fuel cell stack can reach a goal temperature within the shortest time thus
to enhance a function and a reliability of the fuel cell. Also, when the fuel cell system is temporarily stopped or an
operation of the fuel cell system is finished, the cooling fan is operated thus
to cool the fuel cell system within a short time, thereby enhancing a stability
of the system. Besides, when the system is stopped, fuel remaining at the fuel cell
stack and each system is returned to the fuel tank thus to increase a
performance.
It will be apparent to those skilled in the art that various modifications
and variations can be made in the present invention without departing from
the spirit or scope of the invention. Thus, it is intended that the present
invention cover modifications and variations of this invention provided they
come within the scope of the appended claims and their equivalents.

Claims

1. A fuel cell system comprising: a fuel cell stack that an anode and a cathode are arranged in a state
that an electrolyte membrane is interposed therebetween; a fuel tank connected to the anode of the fuel cell stack by a fuel
supplying line for supplying hydrogen-including fuel to the anode; an air supplying unit connected to the cathode of the fuel cell stack
by an air supplying line for supplying oxygen-including air to the cathode; a heating unit for heating air and fuel supplied to the fuel cell stack;
and a purge unit for returning fuel remaining at each system to the fuel
tank when a system driving is stopped.
2. The fuel cell system of claim 1 , wherein a cooling fan for
cooling the fuel cell stack when the system driving is stopped is installed at
the fuel cell stack.
3. The fuel cell system of claim 1 , wherein the heating unit is
composed of a hydrogen combustor installed at the fuel supplying line and
the air supplying line for heating fuel and air supplied to the fuel cell stack by
using hydrogen generated from the fuel cell stack as a heating source.
4. The fuel cell system of claim 1 , wherein the heating unit is
composed of a fuel kit installed at the fuel tank for heating fuel by using heat
generated when fuel power is mixed with water stored in the fuel tank.
5. The fuel cell system of claim 1 , wherein the purge unit is
composed of: a fuel recollecting line connected between the fuel cell stack and the
fuel tank for recollecting fuel discharged from the fuel cell stack into the fuel
tank; and a recycling pump installed at the fuel recollecting line for returning
fuel remaining at each system to the fuel tank through the fuel recollecting
line when a system driving is stopped.
6. The fuel cell system of claim 1 , wherein the purge unit is
composed of: a fuel pump installed at the fuel supplying line for pumping fuel; and a controller for returning fuel remaining at each system to the fuel
tank by reversely driving the fuel pump when a system driving is stopped.
7. The fuel cell system of claim 1 , wherein the purge unit is
composed of a purge line connected between the fuel supplying line and the
air supplying line and a three-way valve installed at a part where the purge
line and the fuel supplying line are connected to each other, and returns remaining fuel to the fuel tank by injecting air into the anode when a system
driving is stopped.
8. A method for controlling a fuel cell system comprising: a heating step for heating fuel; an electricity generating step for supplying the heated fuel and air to
a fuel cell stack and thus generating electric energy; and a purge step for returning fuel remaining at each system to a fuel
tank when a system driving is stopped while performing the first and second
steps.
9. The method of claim 8, further comprising a step for driving a
system by using a power source of a battery after heating fuel in the heating
step.
10. The method of claim 8, wherein fuel is heated by using heat
generated when fuel is mixed with water in the heating step.
11. The method of claim 10, wherein a fuel kit where fuel powder
(NaOH and BH4 powder) is stored is mounted to a fuel tank where water is
stored and thereby fuel powder is mixed with water in the heating step.
12. The method of claim 8, wherein fuel is heated by using hydrogen generated from the anode of the fuel cell stack as a heating source
in the heating step.
13. The method of claim 8, further comprising a step for charging
a battery when a temperature of the fuel cell stack is higher than a set
temperature in the electricity generating step.
14. The method of claim 8, wherein a recycle pump is driven to
recollect fuel remaining at the fuel cell stack and each line to the fuel tank
through a recollecting line when a system driving is stopped in the purge step.
15. The method of claim 14, further comprising a step for cooling
the fuel cell stack by driving a cooling fan in the purge step.
16. The method of claim 8, wherein fuel remaining at the fuel
supplying line and the fuel cell stack is returned to the fuel tank by reversely
driving a fuel pump in the purge step.
17. The method of claim 8, wherein fuel remaining at the fuel cell
stack is returned to the fuel tank by injecting air into the anode of the fuel cell
stack when a system driving is stopped in the purge step.
PCT/KR2003/002728 2003-12-12 2003-12-12 Fuel cell system and control method thereof WO2005057706A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
PCT/KR2003/002728 WO2005057706A1 (en) 2003-12-12 2003-12-12 Fuel cell system and control method thereof
AU2003304609A AU2003304609A1 (en) 2003-12-12 2003-12-12 Fuel cell system and control method thereof
EP03819114A EP1704612A1 (en) 2003-12-12 2003-12-12 Fuel cell system and control method thereof
US10/483,385 US20050142409A1 (en) 2003-12-12 2003-12-12 Fuel cell system and control method thereof
CNA038006960A CN1689182A (en) 2003-12-12 2003-12-12 Fuel cell system and control method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/KR2003/002728 WO2005057706A1 (en) 2003-12-12 2003-12-12 Fuel cell system and control method thereof

Publications (1)

Publication Number Publication Date
WO2005057706A1 true WO2005057706A1 (en) 2005-06-23

Family

ID=34675616

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2003/002728 WO2005057706A1 (en) 2003-12-12 2003-12-12 Fuel cell system and control method thereof

Country Status (5)

Country Link
US (1) US20050142409A1 (en)
EP (1) EP1704612A1 (en)
CN (1) CN1689182A (en)
AU (1) AU2003304609A1 (en)
WO (1) WO2005057706A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2417606A (en) * 2004-08-31 2006-03-01 Antig Tech Co Ltd Semi-Active Fuel Cell Apparatus
CN112186223A (en) * 2020-09-27 2021-01-05 重庆长安新能源汽车科技有限公司 Automobile fuel cell system and air humidity control method thereof

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20110007937A (en) * 2007-05-21 2011-01-25 주식회사 씨티앤티 The method of purging for fuel cell
JP2008300227A (en) * 2007-05-31 2008-12-11 Toshiba Corp Fuel cell device and electronic equipment system equipped with this
US9222388B2 (en) 2013-02-28 2015-12-29 Tenneco Automotive Operating Company Inc. Urea common rail
JP6788841B2 (en) * 2017-03-14 2020-11-25 トヨタ自動車株式会社 Fuel cell system
JP6760154B2 (en) * 2017-03-15 2020-09-23 トヨタ自動車株式会社 Fuel cell system
CN112582653B (en) * 2020-12-18 2022-08-30 上海汉测智能科技有限公司 Hydrogen precooling system and method for hydrogen fuel cell testing device

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6194095B1 (en) * 1998-12-15 2001-02-27 Robert G. Hockaday Non-bipolar fuel cell stack configuration
US20030022037A1 (en) * 2001-07-25 2003-01-30 Ballard Power Systems Inc. Fuel cell system method, apparatus and scheduling
WO2003071615A2 (en) * 2001-09-07 2003-08-28 General Motors Corporation Fuel cell energy management system for cold environments

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3077618B2 (en) * 1997-03-05 2000-08-14 富士電機株式会社 Solid polymer electrolyte fuel cell
US6558827B1 (en) * 2001-02-26 2003-05-06 Utc Fuel Cells, Llc High fuel utilization in a fuel cell
TW548872B (en) * 2002-04-18 2003-08-21 Asia Pacific Fuel Cell Tech Small-power air-cooling type fuel cell
US6838199B2 (en) * 2002-12-26 2005-01-04 Utc Fuel Cells, Llc Start up system and method for a fuel cell power plant using a cathode electrode fuel purge

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6194095B1 (en) * 1998-12-15 2001-02-27 Robert G. Hockaday Non-bipolar fuel cell stack configuration
US20030022037A1 (en) * 2001-07-25 2003-01-30 Ballard Power Systems Inc. Fuel cell system method, apparatus and scheduling
WO2003071615A2 (en) * 2001-09-07 2003-08-28 General Motors Corporation Fuel cell energy management system for cold environments

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2417606A (en) * 2004-08-31 2006-03-01 Antig Tech Co Ltd Semi-Active Fuel Cell Apparatus
GB2417606B (en) * 2004-08-31 2006-10-18 Antig Tech Co Ltd Semi-active fuel cell apparatus
CN112186223A (en) * 2020-09-27 2021-01-05 重庆长安新能源汽车科技有限公司 Automobile fuel cell system and air humidity control method thereof

Also Published As

Publication number Publication date
CN1689182A (en) 2005-10-26
EP1704612A1 (en) 2006-09-27
US20050142409A1 (en) 2005-06-30
AU2003304609A1 (en) 2005-06-29

Similar Documents

Publication Publication Date Title
WO2011148262A2 (en) Fuel cell system and control method therefor
US20050266280A1 (en) Electronic apparatus system, fuel cell unit and power supply control method
WO2005053075A1 (en) Fuel cell system and method of starting it
EP1998397B1 (en) Fuel cell system and method of starting operation of fuel cell system
US9653744B2 (en) Method of starting fuel cell system for vehicle and fuel cell system
CA2473213C (en) Method of starting up operation of fuel cell at low temperature
US7008710B2 (en) Fuel cell system with air cooling device
US20050142409A1 (en) Fuel cell system and control method thereof
JP4835222B2 (en) Vehicle power generation system
JP4505489B2 (en) Fuel cell system and starting method thereof
JP2007141744A (en) Fuel cell system
JP4742592B2 (en) Fuel cell system and operation method thereof
JP2005166424A (en) Fuel cell system
US20060292411A1 (en) Fuel cell system
US20070141409A1 (en) Fuel cell system and control method thereof
EP2056387B1 (en) Fuel cell system and scavenging method therefor
US8153319B2 (en) System and method for purging condensate from an electrochemical cell stack prior to operation
US20050079392A1 (en) Fuel cell apparatus and method of controlling the same
US6576356B1 (en) Preconditioning membranes of a fuel cell stack
KR100724396B1 (en) Fuel sell system and control method thereof
RU2319258C1 (en) Fuel cell and method of control of fuel cell
JP2007250216A (en) Fuel cell system and method of operating same
JP2009129679A (en) Fuel cell system
JP5186525B2 (en) Fuel cell system and starting method thereof
US20050142418A1 (en) Fuel cell system

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 03800696.0

Country of ref document: CN

WWE Wipo information: entry into national phase

Ref document number: 10483385

Country of ref document: US

AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): BW GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 1020067011430

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 2003819114

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2006124848

Country of ref document: RU

WWP Wipo information: published in national office

Ref document number: 2003819114

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: JP