WO2005044915A1 - Particulate water-absorbent resin composition and its production process - Google Patents
Particulate water-absorbent resin composition and its production process Download PDFInfo
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- WO2005044915A1 WO2005044915A1 PCT/JP2004/016777 JP2004016777W WO2005044915A1 WO 2005044915 A1 WO2005044915 A1 WO 2005044915A1 JP 2004016777 W JP2004016777 W JP 2004016777W WO 2005044915 A1 WO2005044915 A1 WO 2005044915A1
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- absorbent resin
- water
- resin composition
- particulate water
- weight
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/245—Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
- A61L15/24—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
Definitions
- water-absorbent resin examples include: partially-neutralized and crosslinked poly(acrylic acids); hydrolyzed graft polymers of starch-acrylonitrile; neutralized graft polymers of starch-acrylic acid; saponified copolymers of vinyl acetate-acrylic acid esters; crosslinked carboxymethyl cellulose; hydrolyzed copolymers of acrylonitrile or acrylamide, or crosslinked polymers of these hydrolyzed copolymers; crosslinked polymers of cationic monomers; crosslinked copolymers of isobutylene-maleic acid; and crosslinked copolymers of 2-acrylamido-2-methylpropanesulfonic acid and acrylic acid.
- aqueous liquids e.g. body fluids
- high water absorption capacity excellent absorption rate
- liquid permeability liquid permeability
- gel strength of swollen gel suction amount of sucking up water from base materials containing the aqueous liquids.
- sanitary materials e.g. disposable diapers
- their high functionalization and thinning are malting progress.
- the thinning is aimed at while the increase of the absorption amount and the prevention of the leakage are aimed at by increasing the amount (g) and ratio (weight %/ratio in absorbent structure) of the water-absorbent resin being used.
- the liquid-sucking-up property is an important property having been known so far (e.g. refer to patent documents 12 and 13 below), but it has been very difficult to obtain a particulate water-absorbent resin composition enhanced in both of the "liquid permeability" and “liquid-sucking-up property" of the water-absorbent resin, because both are antithetical physical properties.
- the "liquid permeability” in the present invention refers to the liquid permeation performance after the particulate water-absorbent resin composition has absorbed water under load, that is, liquid permeability between swollen gel particles under load, and is a liquid permeability model in diapers during practical use.
- liquid-sucking-up property refers to the liquid-sucking-up or liquid-distributing performance when a water-unabsorbed particulate water-absorbent resin composition absorbs water, that is, a rate at which water-unabsorbed dry particles suck up a liquid or a rate at which a liquid is distributed into the particulate water-absorbent resin composition, and is a liquid distribution model (which has not been found out until the present invention is made) in diapers during practical use.
- Patent Document 1 Pamphlet of WO 95/26209
- Patent Document 2 EP O 951 913 B
- Patent Document 3 EP 0 640 330 B
- Patent Document 4 Pamphlet of WO 2001/066056
- Patent Document 5 Pamphlet of WO 98/47454
- Patent Document 6 USP 6,414,214
- Patent Document 7 US Patent Publication No.
- Patent Document 8 USP 5,051,259
- Patent Document 9 EP 0 349 240 B
- Patent Document 10 EP 0 579 764 B
- Patent Document 11 EP 0 629 411 B
- Patent Document 12 EP 0 532 002 B
- Patent Document 13 USP 6,399,668 DISCLOSURE OF THE INVENTION
- an object of the present invention is to provide a novel particulate water-absorbent resin composition and its production process, wherein the novel particulate water-absorbent resin composition is provided by providing a particulate water-absorbent resin composition enhanced in both of the "liquid permeability" and “liquid-sucking-up property" (which have hitherto been antithetical physical properties) of the water-absorbent resin and is used for disposable diapers and sanitary napkins.
- a particulate water-absorbent resin composition according to the present invention is a particulate water-absorbent resin composition comprising a water-absorbent resin (A) of a crosslinked structure obtained by polymerizing an acid-group-containing unsaturated monomer, with the composition being characterized by: having a particle size such that particles in the range of 850 to 150 ⁇ m (but not including 850 ⁇ m) account for not less than 90 weight % of the entirety; and containing a tetra- or more functional polyol (B) at least on surfaces.
- A water-absorbent resin
- B tetra- or more functional polyol
- Another particulate water-absorbent resin composition according to the present invention is a particulate water-absorbent resin composition comprising a water-absorbent resin (A) of a crosslinked structure obtained by polymerizing an acid-group-containing unsaturated monomer, with the composition being characterized by containing a tetra- or more functional polyol (B) and a tri- or more functional polycation at least on surfaces.
- A water-absorbent resin
- B tetra- or more functional polyol
- Another particulate water-absorbent resin composition according to the present invention is a particulate water-absorbent resin composition comprising a water-absorbent resin (A) of a crosslinked structure obtained by polymerizing an acid-group-containing unsaturated monomer, with the composition being characterized by: having a particle size such that particles in the range of 850 to 150 ⁇ m (but not including 850 ⁇ m) account for not less than 90 weight % of the entirety; and being in the range of 0.03 to 0.15 in surface OH/C ratio as determined by photoelectron spectrometry.
- A water-absorbent resin
- Fig. 1 is a schematic sectional view of a measurement apparatus as used for measuring the saline flow conductivity (SFC) of the water-absorbent resin composition.
- Fig. 2 is a perspective view of an apparatus as used for determining the liquid-sucking-up rate.
- Fig. 3 is a side view of Fig. 2. [Explanation of the Symbols] 31 : Tank
- the water-absorbent resin in the present invention refers to a crosslinked polymer which is hydrogel-formable, water-swellable and water-insoluble.
- the "water-swellable” refers to a water-absorbent resin which absorbs water in a large amount of essentially not less than 5 times, favorably 50 to 1,000 times, of its own weight in ion-exchanged water
- the "water-insoluble” refers to a water-absorbent resin in which the uncrosslinked water-extractable component (water-soluble polymer) content is favorably in the range of 0 to 50 weight %, more favorably not higher than 25 weight %, still more favorably not higher than 20 weight %, yet still more favorably not higher than 15 weight %, particularly favorably not higher than 10 weight %.
- the methods for measuring them are specified in the below-mentioned detailed description of Examples of some preferred embodiments.
- the water-absorbent resin (A) of a crosslinked structure obtained by polymerizing an acid-group-containing unsaturated monomer is used as the water-absorbent resin favorably from the viewpoints of the liquid permeability and the liquid-sucking-up property.
- the acid-group-containing unsaturated monomer a monomer which will form the acid group by hydrolysis after the polymerization (e.g. acrylonitrile) is also taken as the acid-group-containing unsaturated monomer in the present invention.
- an acid-group-containing unsaturated monomer which contains the acid group during the polymerization is used.
- the water-absorbent resin in the present invention include one or more of such as: partially-neutralized polymers of poly(acrylic acids); hydrolyzed graft polymers of starch-acrylonitrile; graft polymers of starch-acrylic acid; saponified copolymers of vinyl acetate-acrylic acid esters; hydrolyzed copolymers of acrylonitrile or acrylamide, or crosslinked polymers of these hydrolyzed copolymers; modified polymers of carboxyl -group-containing crosslinked polyvinyl alcohols; and crosslinked copolymers of isobutylene-maleic anhydride.
- the partially-neutralized polymers of poly(acrylic acids) which is obtained by polymerizing and crosslinking a monomer including acrylic acid and/or its salt (neutralized product) as a main component.
- a monomer including acrylic acid and/or its salt neutralized product
- another monomer may be used jointly therewith.
- This jointly usable other monomer is exemplified in such as US patents (mentioned in (3) below) and EP patents. Examples thereof include water-soluble or hydrophobic unsaturated monomers such as methacrylic acid, (anhydrous) maleic acid, fumaric acid, crotonic acid, itaconic acid, vinylsulfonic acid,
- this monomer other than acrylic acid (salt) is favorably in the range of 0 to 30 mol %, more favorably O.to 10 mol %, in ratio to the total amount of the acrylic acid and/or its salt being used as a main component.
- these internal-crosslinldng agents include N,N'-methylenebis(meth)acrylamide, (poly)ethylene glycol di(meth) acrylate, (poly)propylene glycol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, glycerol tri(meth)acrylate, glycerol acrylate methacrylate, ethylene-oxide-modified trimethylolpropane tri(meth)acrylate, pentaerythritol hexa(meth)acrylate, triallyl - cyanurate, triallyl isocyanurate, triallyl phosphate, triallylamine, poly(meth)allyloxyalkanes, (poly) ethylene glycol diglycidyl ether, glycerol diglycidyl ether, ethylene glycol, polyethylene glycol, propylene glycol, glycerol, pentaerythritol, ethyl,
- the amount of these internal-crosslinldng agents being used is set favorably in the range of 0.001 to 2 mol %, more favorably 0.005 to 1 mol %, still more favorably 0.005 to 0.5 mol %, yet still more favorably 0.01 to 0.5 mol %, yet still more favorably 0.01 to 0.2 mol %, particularly favorably 0.03 to 0.2 mol %, most favorably 0.03 to 0.15 mol %, relative to the aforementioned monomers (except for the crosslinking agent).
- the amount of the above internal-crosslinldng agents being used is smaller than 0.001 mol % and where this amount is " larger than 2 mol %, there is a possibility that sufficient absorption properties cannot be obtained, for example, the water-extractable component content may increase, or the water absorption capacity may lower.
- the above internal-crosslinldng agent is used to introduce the crosslinked structure into the inside of the polymer, it will do to add the above internal-crosslinldng agent to the reaction system before or on the way of or after the polymerization of the above monomers or after the neutralization.
- aqueous monomer solution the concentration of the monomers in this aqueous solution depends on the temperature of the aqueous solution and on the monomers, and is therefore not especially limited. However, this concentration is favorably in the range of 10 to 70 weight %, more favorably 20 to 60 weight %.
- a solvent other than water may be used jointly therewith, if necessary. The kind of this jointly usable solvent is not especially limited.
- the reversed-phase suspension polymerization is a polymerization method in which the aqueous monomer solution is suspended in a hydrophobic organic solvent, and such a polymerization method is, for example, disclosed in US patents such as USP 4,093,776, USP 4,367,323, USP 4,446,261, USP 4,683,274, and USP 5,244,735.
- the aqueous solution polymerization is a polymerization method in which the aqueous monomer solution is polymerized without any dispersing solvent, and such a polymerization method is, for example, disclosed in: US patents such as USP 4,625,001, USP 4,873,299, USP 4,286,082, USP 4,973,632, USP 4,985,518, USP 5,124,416, USP 5,250,640, USP 5,264,495, USP 5,145,906, and USP 5,380,808; and European patents such as EP 0811636, EP 0955086, and EP 0922717. Such as monomers and initiators exemplified for these polymerization methods are also applicable to the present invention.
- the resultant polymer is usually a crosslinked hydrogel polymer, which is dried if necessary and usually pulverized before and/or after this drying, so that the water-absorbent resin is obtained.
- the drying is carried out usually in the temperature range of 60 to 250 °C, favorably 100 to 220 °C, more favorably 120 to 200 °C.
- the drying time depends on the surface area and water content of the polymer and on the kind of the drier and is selected so as to give the objective water content.
- the water content of the water-absorbent resin (composition) usable in the present invention (which is defined as the amount of water contained in the water-absorbent resin or water-absorbent resin composition and is measured by the drying loss at 105 °C in 3 hours) is not especially limited.
- the above water content is such that the water-absorbent resin (composition) can be a powder flowable even at room temperature, and is favorably such that the water-absorbent resin (composition) can be in a powder state having a water content of 0.1 to 40 weight %, more favorably 0.2 to 30 weight %, still more favorably 0.3 to 15- weight %, particularly favorably 0.5 to 10 weight %.
- Favorable particle diameters of the water-absorbent resin (composition) will be mentioned below. In the case where the water content of the water-absorbent resin is higher than 40 weight %, there is a possibility that the water absorption capacity may be low.
- particles not smaller than 300 ⁇ m account for not less than 60 weight % of the entirety.
- the entirety refers to the entirety of the particulate water-absorbent resin composition.
- particles not smaller than 250 ⁇ m account for favorably not less than 70 weight % (upper limit: 100 weight %), more favorably not less than 75 weight %.
- the weight-average particle diameter (D50) of the water-absorbent resin or particulate water-absorbent resin- composition is favorably in the range of 200 to 600 ⁇ m, more favorably 300 to 600 ⁇ m, still more favorably 300 to 500 ⁇ m, particularly favorably 350 to 450 ⁇ m.
- the particle diameters of the water-absorbent resin or particulate water-absorbent resin composition may be adjusted by such as agglomeration., if necessary.
- the water-absorbent resin in the present invention and the particulate water-absorbent resin composition obtained in the present invention may jointly be referred to generically as water-absorbent resin (composition).
- the particle shape of the water-absorbent resin or particulate water-absorbent resin composition, obtained in the above way, is such as a spherical shape, a pulverized shape, or an irregular shape and is thus not especially limited.
- the smaller logarithmic standard deviation ( ⁇ ) of the particle size distribution shows the narrower particle size distribution.
- the water-absorbent resin or particulate water-absorbent resin composition in the present invention it is important that the particle size distribution is not simply narrow, but has a certain degree of broadness.
- the logarithmic standard deviation ( ⁇ ) is less than 0.25, not only is there a possibility that the objective performance may not be obtained, but also unfavorably the productivity is greatly deteriorated.
- the logarithmic standard deviation ( ⁇ ) is more than 0.45, the particle size distribution is too broad, so there is a possibility that the objective performance may not be obtained.
- the "particles not smaller than 300 ⁇ m", referred to in the present invention refers to particles which remains on a JIS standard sieve of 300 ⁇ m in mesh opening size (to be measured) as a result of the classification by the below-mentioned sieve classification method.
- particles smaller than 300 ⁇ m similarly refers to particles which pass through the mesh of 300 ⁇ m in mesh opening size (to be measured) as a result of the classification by the below-mentioned sieve classification method. This is similar also as to the other mesh opening sizes.
- D50 weight-average particle diameter
- polyhydric alcohol compounds such as: polyhydric alcohol compounds; epoxy compounds; polyamine compounds or products by their condensation with haloepoxy compounds; oxazoline compounds; mono-, di-, or polyoxazolidinone compounds;, polyvalent metal salts; and alkylene carbonate compounds.
- surface-crosslinking agent used in the present invention, are disclosed in such as USP 6,228,930, USP 6,071,976, and USP 6,254,990. Examples thereof include: polyhydric alcohol compounds (e.g.
- haloepoxy compounds e.g. epichlorohydrin, epibromohydrin, ⁇ -methylepichlorohydrin
- oxazolidinone compounds e.g. 2-oxazolidinone
- oxetane compounds cycl
- a hydrophilic organic solvent may be used, and its amount is favorably in the range of 0 to 10 weight parts, more favorably 0 to 5 weight parts, still more favorably 0 to 3 weight parts, relative to 100 weight parts of the water-absorbent resin.
- favorable among various mixing methods is a method in which, after the surface-crosslinking agent has beforehand been mixed with water and/or the hydrophilic organic solvent if necessary, the resultant aqueous solution is sprayed or dropped to the water-absorbent resin to mix
- the amount of these tetra- or more functional polyols (B) being used is favorably in the range of 0.01 to 20 weight %, more favorably 0.1 to 10 weight %, still more favorably 0.1 to 5 weight %, particularly favorably 0.1 to 1 weight %, relative to the water-absorbent resin (A).
- these polyols (B) can be extracted from the particulate water-absorbent resin composition and can be quantified by such as liquid chromatography and gas chromatography. incidentally, if all hydroxyl groups in the polyol (B) reacts with acid groups of the water-absorbent resin to thus disappear, then it is difficult to obtain the effect of enhancing the liquid-sucking-up property in the present invention.
- the tetra- or more functional polyol (B) is formed into a solution (particularly, an aqueous solution), if necessary, and then dropped or sprayed to the water-absorbent resin (A) to mix them together.
- the aforementioned surface-crosslinking agent (C) (more favorably the polyhydric alcohol, still more favorably the tri- or less-functional polyol having 3 to 8 carbon atoms) other than the tetra- or more functional polyol (B) jointly therewith, if necessary.
- the amount of the surface-crosslinldng agent (C) other than the polyol (B), being used, is favorably in the range of 0 to 8 weight parts, more favorably 0.01 to 5 weight parts, still more favorably 0.1 to 3 weight parts, relative to 100 weight parts of the water-absorbent resin.
- tetra- or more functional polyol (B) is contained at least on surfaces, then OH groups which have not changed in form due to such as the crosslinking reaction remain to thus give the hydrophihcity, so that the wettability of the particulate water-absorbent resin composition is. more exhibited.
- the aforementioned tetra- or more functional polyol (B) is as previously described herein.
- the content of the tri- or more polyvalent metal is favorably in the range of 0.01 to 10 weight %, more favorably 0.1 to 5.0 weight %, still more favorably 0.2 to 2.0 weight %, relative to the particulate water-absorbent resin composition.
- the tri- or more polyvalent metal is free of especial limitation if it is in the range where used as a water-soluble compound. However, it is, for example, favorably used as a compound of at least one counter-anion selected from the group consisting of: inorganic compounds having OH " , CO 3 2" , or SO 4 2" ; organic acids (e.g.
- the tri- or more polyvalent metal may be added in a state of a powder (powdery particles) or in a state of a slurry where the polyvalent metal is dispersed in such as water or an organic solvent.
- the tri- or more polyvalent metal is added in a state of a solution of the polyvalent metal, such as an aqueous solution or a solution in which the polyvalent metal is dissolved in a mixed solvent of water/the organic solvent.
- the organic solvent hereupon usable include: monohydric alcohols (e.g. isopropyl alcohol); polyhydric alcohols (e.g. propylene glycol, glycerol); acids (e.g.
- the aforementioned solution of the polyvalent metal may contain compounds of metals having a valence of less than 3 (e.g. sodium hydroxide, sodium carbonate, sodium hydrogencarbonate, sodium acetate, sodium lactate, potassium hydroxide, lithium hydroxide).
- liquid-sucking-up rate (WR) is more than 180 s, it is not appropriate for practical use for diapers, because, in practical use, the liquid (water) cannot be sucked up to the entire surfaces or top surface of the diapers in the diapers worn along buttocks.
- the liquid permeability and the liquid-sucking-up property have hitherto been antithetical physical properties, whereas, as to the particulate water-absorbent resin composition according to the present invention, there is obtained a particulate water-absorbent resin composition enhanced in both with good balance, and the liquid-sucking-up rate (WR) is very fast in comparison with the AAP and the SFC.
- the particulate water-absorbent resin composition according to the present invention is, in capacity-without-load sucking-up efficiency (CRC/WR), favorably not less than 0.15 (g/g/s) and not more than 2 (g/g/s), more favorably not less than 0.20 (g/g/s) and not more than 2 (g/g/s), particularly favorably not less than 0.25 (g/g/s) and not more than 2 (g/g/s), and thus much higher than conventional ones (around 0.1 (g/g/s)). Therefore, this composition is so excellent in the balance between the water absorption capacity without load and the liquid-sucking-up property as to be favorable for. sanitary materials.
- CRC/WR capacity-without-load sucking-up efficiency
- Such a phenomenon is, for example, recognized also from a great difference between a value given by measuring the liquid distribution velocity (LDV) with the particle size of the particulate water-absorbent resin composition left as it is (Bulk) and a value given by measuring the liquid distribution velocity (LDV) with the particle size of the particulate water-absorbent resin composition classified in the range of 500 to 300 ⁇ m.
- LDV liquid distribution velocity
- an example of preferred embodiments of the use of the particulate water-absorbent resin composition according to the present invention in absorbent structures is application to a water-absorbent composite of expansion anisotropy (expandability in the thickness directions) illustrated in USP 5,853,867.
- a water-absorbent composite of expansion anisotropy illustrated in USP 5,853,867.
- the particulate water-absorbent resin composition according to the present invention wliich is excellent in the distributability, is used, then there are advantages in that there can be obtained an absorbent structure greatly improved not only as to the expansion in the thickness directions, but also as to the liquid distribution in the sideways (horizontal) directions.
- A area of top of gel layer in cell 41 (28.27 cm 2 );
- a receptacle 48 to collect the passed liquid was placed under the cell 41, and this collecting receptacle 48 was set on a balance 49.
- the inner diameter of the cell 41 was 6 cm, and a No. 400 stainless metal gauze (mesh opening size: 38 ⁇ m) 42 was set at the bottom thereof.
- Holes 47 sufficient for the liquid to pass through were opened in the lower portion of a piston 46, and its bottom portion was equipped with a well-permeable glass filter 45 so that the water-absorbent resin composition or its swollen gel would not enter the holes 47.
- the cell 41 was placed on a stand to put the cell thereon.
- the face, contacting with the cell, of the stand was set on a stainless metal gauze 43 that did not inhibit the liquid permeation.
- the synthetic urine (1) as used was obtained by mixing together the following: 0.25 g of calcium chloride dihydrate; 2.0 g of potassium chloride; 0.50 g of magnesium chloride hexahydrate; 2.0 g of sodium sulfate; 0.85 g of ammonium dihydrogenphosphate; 0.15 g of diammonium hydrogenphosphate; and 994.25 g of pure water.
- the weight-average particle diameter (D50) was read.
- ⁇ Logarithmic standard deviation ( ⁇ ) of particle size distribution The water-absorbent resin (or particulate water-absorbent resin composition) was classified with JIS standard sieves having mesh opening sizes of 850 ⁇ m, 710 ⁇ m, 600 ⁇ m, 500 ⁇ m, 425 ⁇ m, 300 ⁇ m, 212 ⁇ m, 150 ⁇ m, and 45 ⁇ m: Then, the percentages R of the residues on these sieves were plotted on a logarithmic probability paper.
- the materials were decanted, and then a filter paper having been cut into strips was used to remove the liquid to such a degree that no liquid residue became seen between particles clearly with the eye.
- the resultant particulate water-absorbent resin composition was dried at 60 °C under about 100 mmHg for 4.5 hours and then at 100 °C under about 100 mmHg for 17 hours and then further at 100 °C under about 1 mmHg with a vacuum drier for 3 hours, thus obtaining a particulate water-absorbent resin composition having been wash-treated with the physiological saline solution.
- Example Operation h3 washing treatment with methanol and water: About 50 mg of the physiological-saline-solution-wash-treated particulate water-absorbent resin composition having been obtained from Experimental Operation h2 was placed into the sample tube (inner diameter 18 mm x height 44 mm), and then 2 ml of solution (having been prepared by mixing 100 ml of methanol with 0.5 g of 36 weight % hydrochloric acid) was added thereto. Then, the above sample tube was sealed airtightly, and then the particulate water-absorbent resin composition and the above solution therein were stirred with an ultrasonic cleaner (as equipped with a vibrator of 35 kHz) for 5 minutes.
- an ultrasonic cleaner as equipped with a vibrator of 35 kHz
- the resultant particulate water-absorbent resin composition was dried, with a vacuum drier, at 90 °C under about 100 mmHg for 15 hours and then at 90 °C under about 1 mmHg for 2 hours, thus obtaining a particulate water-absorbent resin composition having been wash-treated with methanol and water.
- Experimental Operation h4 surface trifluoroacetation
- the methanol-and-water-wash-treated particulate water-absorbent resin composition having been obtained from Experimental Operation h3 (about 50 mg) was taken into a polypropylene-made cup (1) of 10 mm in diameter and 20 mm in height having 40 to 50 holes of 100 to 300 ⁇ m in diameter in its sides.
- the sample tube was sealed airtightly and then left at room temperature for 1 to 3 hours to make a reaction between the TFAA and the OH groups on surfaces of the particulate water-absorbent resin composition having been processed (surface- washed) by the experimental operations hi to h3 (the present operation is an operation for making the liquid TFAA untouched directly with the particulate water-absorbent resin composition in the cup and making the vapor of the TFAA contact with the particulate water-absorbent resin composition to thus react therewith).
- the particulate water-absorbent resin composition was dried, with a vacuum drier, at 60 °C under about 100 mmHg for not less than 2 hours and then further at 60 °C under about 1 mmHg for not less than 2 hours.
- the resultant particulate water-absorbent resin composition was preserved under the coexistence of silica gel in a desiccator. Then, within 1 week, the preserved sample was subjected to the measurement as shown in Experimental Operation h5.
- MgK ⁇ rays were used as an excitation X-ray source, and the conditions were set at an acceleration voltage of 10 kV, an emission current of 10 mA, a pass energy of the detector of 10 eV, and an energy-sweeping interval of the detector of 0.1 eV, and the scan was repeated 10 times in number of times of the integration, whereby photoelectron spectra were obtained.
- the resultant particles were disintegrated to such a degree that they could pass through a JIS standard sieve having a mesh opening size of 600 ⁇ m.
- a particulate water-absorbent resin composition (1) was obtained. Its physical properties were measured. Their results are shown in Table 1.
- a comparative particulate water-absorbent resin composition (1) was obtained. Its physical properties were measured. Their results are shown in Table .1.
- the comparative particulate water-absorbent resin composition (1) was 322 ⁇ m in weight-average particle diameter (D50) and 0.36 in logarithmic standard deviation ( ⁇ ) of particle size distribution.
- the particulate water-absorbent resin composition was talcen out and then passed through a mesh opening size of 600 ⁇ m with a JIS 600- ⁇ m standard sieve, thus obtaining a particulate water-absorbent resin composition (10).
- the performances of the resultant particulate water-absorbent resin composition (10) are shown in Tables 5 and 6.
- the water content of the resultant particulate water-absorbent resin composition (10) was 1.5 weight %.
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- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
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Abstract
Description
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Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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EP04799629.3A EP1680470B1 (en) | 2003-11-07 | 2004-11-05 | Particulate water-absorbent resin composition and its production process |
US10/577,355 US7872076B2 (en) | 2003-11-07 | 2004-11-05 | Particulate water-absorbent resin composition and its production process |
BRPI0416199-8A BRPI0416199A (en) | 2003-11-07 | 2004-11-05 | particulate water absorbing resin composition and its production process |
MXPA06004345A MXPA06004345A (en) | 2003-11-07 | 2004-11-05 | Particulate water-absorbent resin composition and its production process. |
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JP2003377898 | 2003-11-07 | ||
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US (1) | US7872076B2 (en) |
EP (1) | EP1680470B1 (en) |
KR (1) | KR100823418B1 (en) |
CN (1) | CN100429273C (en) |
BR (1) | BRPI0416199A (en) |
MX (1) | MXPA06004345A (en) |
RU (1) | RU2322463C2 (en) |
TW (1) | TWI263509B (en) |
WO (1) | WO2005044915A1 (en) |
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58183754A (en) * | 1982-04-20 | 1983-10-27 | Sanyo Chem Ind Ltd | Water absorbing resin composition |
EP0349240A2 (en) * | 1988-06-28 | 1990-01-03 | Nippon Shokubai Co., Ltd. | Water-absorbent resin and production process |
JPH04214735A (en) * | 1990-04-02 | 1992-08-05 | Nippon Shokubai Co Ltd | Surface treatment of water absorbing resin |
EP0629411A1 (en) * | 1993-06-18 | 1994-12-21 | SANYO CHEMICAL INDUSTRIES, Ltd. | Absorbent composition and disposable diaper containing the same |
JP2000342963A (en) * | 1995-09-01 | 2000-12-12 | Nippon Shokubai Co Ltd | Absorbent composition, production thereof and absorptive article containing the same |
WO2002020068A1 (en) * | 2000-09-04 | 2002-03-14 | Stockhausen Gmbh & Co. Kg | Pulverulent, cross-linked polymers, capable of absorbing aqueous liquids and blood |
JP2002138147A (en) * | 2000-10-31 | 2002-05-14 | Nippon Shokubai Co Ltd | Method of producing water-swellable crosslinked polymer |
JP2002539281A (en) * | 1999-03-05 | 2002-11-19 | シュトックハウゼン ゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー コマンディートゲゼルシャフト | Powdery crosslinked absorbent polymer for absorbing aqueous liquids and blood, process for its production and use |
Family Cites Families (57)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5346389A (en) | 1976-10-07 | 1978-04-25 | Kao Corp | Preparation of self-crosslinking polymer of acrylic alkali metal salt |
US4286082A (en) | 1979-04-06 | 1981-08-25 | Nippon Shokubai Kagaku Kogyo & Co., Ltd. | Absorbent resin composition and process for producing same |
GB2088392B (en) | 1980-12-03 | 1984-05-02 | Sumitomo Chemical Co | Production of hydrogels |
JPS57158209A (en) | 1981-03-25 | 1982-09-30 | Kao Corp | Production of bead-form highly water-absorbing polymer |
US4985518A (en) | 1981-10-26 | 1991-01-15 | American Colloid Company | Process for preparing water-absorbing resins |
JPS58180233A (en) | 1982-04-19 | 1983-10-21 | Nippon Shokubai Kagaku Kogyo Co Ltd | Absorbing agent |
US4625001A (en) | 1984-09-25 | 1986-11-25 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for continuous production of cross-linked polymer |
JPS6187702A (en) | 1984-10-05 | 1986-05-06 | Seitetsu Kagaku Co Ltd | Production of water-absorptive resin |
DE3609545A1 (en) | 1986-03-21 | 1987-09-24 | Basf Ag | METHOD FOR THE DISCONTINUOUS PRODUCTION OF CROSSLINKED, FINE-PARTICLE POLYMERISATS |
JPS63302834A (en) * | 1987-06-04 | 1988-12-09 | Yotsukaichi Gosei Kk | Contact medium of probe for ultrasonic diagnosis and preparation thereof |
DK157899C (en) | 1987-12-15 | 1990-09-03 | Coloplast As | A dressing |
CA1333439C (en) | 1988-05-23 | 1994-12-06 | Akito Yano | Method for production of hydrophilic polymer |
US6087002A (en) | 1988-06-28 | 2000-07-11 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Water absorbent resin |
KR930007272B1 (en) | 1988-06-28 | 1993-08-04 | 닙본 쇼쿠바이 가브시기 가이샤 | Water-absorbent resin and production process |
US5244735A (en) | 1988-06-28 | 1993-09-14 | Nippon Shokubai Kagaku Kabushiki Kaisha | Water-absorbent resin and production process |
JP2930555B2 (en) | 1988-07-04 | 1999-08-03 | 株式会社日本触媒 | Method for producing water absorbent resin |
US5145906A (en) | 1989-09-28 | 1992-09-08 | Hoechst Celanese Corporation | Super-absorbent polymer having improved absorbency properties |
DE69124749T2 (en) | 1990-04-27 | 1997-06-12 | Nippon Catalytic Chem Ind | Process for the production of salt-resistant resin |
DE4020780C1 (en) | 1990-06-29 | 1991-08-29 | Chemische Fabrik Stockhausen Gmbh, 4150 Krefeld, De | |
DE69108804T2 (en) | 1990-07-17 | 1995-08-24 | Sanyo Chemical Ind Ltd | Process for the production of water-absorbent resins. |
US5250640A (en) | 1991-04-10 | 1993-10-05 | Nippon Shokubai Co., Ltd. | Method for production of particulate hydrogel polymer and absorbent resin |
SK279288B6 (en) | 1991-04-12 | 1998-09-09 | The Procter & Gamble Company | Absorbent structure for absorbing body fluids |
GB9107952D0 (en) | 1991-04-15 | 1991-05-29 | Dow Rheinmuenster | Surface crosslinked and surfactant coated absorbent resin particles and method of preparation |
EP0761191B1 (en) | 1991-09-11 | 2001-04-04 | Kimberly-Clark Worldwide, Inc. | Absorbent composites and absorbent articles containing same |
DE69333752T3 (en) * | 1992-06-10 | 2011-03-03 | Nippon Shokubai Co. Ltd. | Process for the preparation of a hydrophilic resin |
AU5329994A (en) | 1992-10-14 | 1994-05-09 | Dow Chemical Company, The | Water-absorbent polymer having improved properties |
US5385983A (en) | 1992-11-12 | 1995-01-31 | The Dow Chemical Company | Process for preparing a water-absorbent polymer |
US5447727A (en) | 1992-10-14 | 1995-09-05 | The Dow Chemical Company | Water-absorbent polymer having improved properties |
NZ268535A (en) | 1993-06-30 | 1998-05-27 | Procter & Gamble | Absorbent article comprising layers of superabsorbent material |
DE69528821T2 (en) | 1994-02-17 | 2003-03-27 | Procter & Gamble | ABSORBENT MATERIALS WITH IMPROVED ABSORPTION PROPERTIES AND METHOD FOR THEIR PRODUCTION |
US5599335A (en) | 1994-03-29 | 1997-02-04 | The Procter & Gamble Company | Absorbent members for body fluids having good wet integrity and relatively high concentrations of hydrogel-forming absorbent polymer |
US5830543A (en) | 1994-05-30 | 1998-11-03 | Nippon Shokubai Co., Ltd. | Gelling material for aqueous fluids |
TW522024B (en) * | 1995-09-01 | 2003-03-01 | Nippon Catalytic Chem Ind | Absorbing agent composite, absorbent material, and absorbent product containing absorbent material |
EP0812873B2 (en) | 1995-12-27 | 2018-10-24 | Nippon Shokubai Co., Ltd. | Water absorbent and process and equipment for the production thereof |
US6194531B1 (en) | 1996-06-05 | 2001-02-27 | Nippon Shokubai Co., Ltd. | Method for production of cross-linked polymer |
ID19116A (en) * | 1996-10-15 | 1998-06-18 | Nippon Catalytic Chem Ind | WATER ABSORPTION MATERIALS AND ITS PRODUCTION PROCESSES |
CA2284974A1 (en) | 1997-04-18 | 1998-10-29 | Stephen Allen Goldman | Absorbent members for body fluids using hydrogel-forming absorbent polymer |
US6228930B1 (en) | 1997-06-18 | 2001-05-08 | Nippon Shokubai Co., Ltd. | Water-absorbent resin granule-containing composition and production process for water-absorbent resin granule |
TW473485B (en) | 1997-12-10 | 2002-01-21 | Nippon Catalytic Chem Ind | The production process of a water-absorbent resin |
US6254990B1 (en) | 1998-02-18 | 2001-07-03 | Nippon Shokubai Co., Ltd. | Surface-crosslinking process for water-absorbent resin |
EP0951913A1 (en) | 1998-04-22 | 1999-10-27 | The Procter & Gamble Company | High liquid suction absorbent structures with permanently hydrophilic meltblown non-woven wrap sheet with small diameter fibers |
KR100476170B1 (en) | 1998-04-28 | 2005-03-10 | 니폰 쇼쿠바이 컴파니 리미티드 | Method for preparing gel state material containing water from water absorbing resin |
DE19825486C2 (en) | 1998-06-08 | 2000-07-06 | Stockhausen Chem Fab Gmbh | Water-absorbing polymers with supramolecular cavity molecules, process for their preparation and their use |
DE19854574A1 (en) | 1998-11-26 | 2000-05-31 | Basf Ag | Process for post-crosslinking hydrogels with N-acyl-2-oxazolidinones |
DE19939662A1 (en) * | 1999-08-20 | 2001-02-22 | Stockhausen Chem Fab Gmbh | Absorbent, crosslinked polymer, used as absorber aqueous liquid, e.g. body fluids, packaging material, plant culture, soil improver or carrier, contains bound or enclosed cyclodextrin (derivative) and silicon-rich zeolite |
US6414214B1 (en) | 1999-10-04 | 2002-07-02 | Basf Aktiengesellschaft | Mechanically stable hydrogel-forming polymers |
EP1265571A1 (en) | 2000-03-06 | 2002-12-18 | The Procter & Gamble Company | Process of making absorbent structures comprising absorbent polymer compositions with a permeability maintenance agent |
US6809158B2 (en) | 2000-10-20 | 2004-10-26 | Nippon Shokubai Co., Ltd. | Water-absorbing agent and process for producing the same |
JP4315680B2 (en) | 2000-12-29 | 2009-08-19 | ビーエーエスエフ ソシエタス・ヨーロピア | Absorbent composition |
JP3987348B2 (en) | 2001-01-26 | 2007-10-10 | 株式会社日本触媒 | Manufacturing method of water-absorbing agent |
JP4326752B2 (en) | 2001-06-08 | 2009-09-09 | 株式会社日本触媒 | Method for producing water-absorbing agent |
CN1277583C (en) | 2001-06-08 | 2006-10-04 | 株式会社日本触媒 | Water-absorbing agent, its production and sanitary material |
US6727345B2 (en) | 2001-07-03 | 2004-04-27 | Nippon Shokubai Co., Ltd. | Continuous production process for water-absorbent resin powder and powder surface detector used therefor |
JP4157333B2 (en) | 2001-07-03 | 2008-10-01 | 株式会社日本触媒 | Continuous production method of surface-modified water-absorbent resin powder |
JP4214735B2 (en) | 2002-08-07 | 2009-01-28 | 富士ゼロックス株式会社 | Endless belt and fixing device using the same |
DE10239074A1 (en) | 2002-08-26 | 2004-03-11 | Basf Ag | Water-absorbing product, e.g. useful for making hygiene articles, comprises water-absorbing polymer particles and a nitrogen-containing polymer |
US7169843B2 (en) * | 2003-04-25 | 2007-01-30 | Stockhausen, Inc. | Superabsorbent polymer with high permeability |
-
2004
- 2004-11-05 CN CNB2004800318911A patent/CN100429273C/en active Active
- 2004-11-05 WO PCT/JP2004/016777 patent/WO2005044915A1/en active Application Filing
- 2004-11-05 TW TW093133872A patent/TWI263509B/en not_active IP Right Cessation
- 2004-11-05 MX MXPA06004345A patent/MXPA06004345A/en unknown
- 2004-11-05 EP EP04799629.3A patent/EP1680470B1/en active Active
- 2004-11-05 RU RU2006119934/04A patent/RU2322463C2/en not_active IP Right Cessation
- 2004-11-05 US US10/577,355 patent/US7872076B2/en active Active
- 2004-11-05 KR KR1020067011054A patent/KR100823418B1/en not_active IP Right Cessation
- 2004-11-05 BR BRPI0416199-8A patent/BRPI0416199A/en not_active IP Right Cessation
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58183754A (en) * | 1982-04-20 | 1983-10-27 | Sanyo Chem Ind Ltd | Water absorbing resin composition |
EP0349240A2 (en) * | 1988-06-28 | 1990-01-03 | Nippon Shokubai Co., Ltd. | Water-absorbent resin and production process |
JPH04214735A (en) * | 1990-04-02 | 1992-08-05 | Nippon Shokubai Co Ltd | Surface treatment of water absorbing resin |
EP0629411A1 (en) * | 1993-06-18 | 1994-12-21 | SANYO CHEMICAL INDUSTRIES, Ltd. | Absorbent composition and disposable diaper containing the same |
JP2000342963A (en) * | 1995-09-01 | 2000-12-12 | Nippon Shokubai Co Ltd | Absorbent composition, production thereof and absorptive article containing the same |
JP2002539281A (en) * | 1999-03-05 | 2002-11-19 | シュトックハウゼン ゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー コマンディートゲゼルシャフト | Powdery crosslinked absorbent polymer for absorbing aqueous liquids and blood, process for its production and use |
WO2002020068A1 (en) * | 2000-09-04 | 2002-03-14 | Stockhausen Gmbh & Co. Kg | Pulverulent, cross-linked polymers, capable of absorbing aqueous liquids and blood |
JP2002138147A (en) * | 2000-10-31 | 2002-05-14 | Nippon Shokubai Co Ltd | Method of producing water-swellable crosslinked polymer |
Non-Patent Citations (1)
Title |
---|
See also references of EP1680470A4 * |
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Also Published As
Publication number | Publication date |
---|---|
BRPI0416199A (en) | 2007-01-16 |
RU2006119934A (en) | 2007-12-27 |
RU2322463C2 (en) | 2008-04-20 |
EP1680470A1 (en) | 2006-07-19 |
KR100823418B1 (en) | 2008-04-18 |
EP1680470A4 (en) | 2009-03-04 |
US7872076B2 (en) | 2011-01-18 |
EP1680470B1 (en) | 2016-02-03 |
KR20060094983A (en) | 2006-08-30 |
CN100429273C (en) | 2008-10-29 |
CN1875065A (en) | 2006-12-06 |
TW200526277A (en) | 2005-08-16 |
US20080139693A1 (en) | 2008-06-12 |
MXPA06004345A (en) | 2006-06-27 |
TWI263509B (en) | 2006-10-11 |
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