WO2005009607A1 - Procede permettant de lancer des reactions en chaine de dissociation et de polycondensation d'hydrocarbures, et dispositif permettant sa mise en oeuvre - Google Patents

Procede permettant de lancer des reactions en chaine de dissociation et de polycondensation d'hydrocarbures, et dispositif permettant sa mise en oeuvre Download PDF

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Publication number
WO2005009607A1
WO2005009607A1 PCT/RU2004/000287 RU2004000287W WO2005009607A1 WO 2005009607 A1 WO2005009607 A1 WO 2005009607A1 RU 2004000287 W RU2004000287 W RU 2004000287W WO 2005009607 A1 WO2005009607 A1 WO 2005009607A1
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Prior art keywords
radiation
syρya
usτροysτvο
slοya
raw materials
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PCT/RU2004/000287
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English (en)
Russian (ru)
Inventor
Valentin Panteleimonovich Smirnov
Vitaly Mikhaylovich Nistratov
Jury Faridovich Berdnikov
Alexandr Vladimirovich Chesnokov
Fanil Galimovich Akhmetov
Azamat Zainullovich Ishmukhametov
Irina Nikolaevna Muzalevskaya
Ildar Rashidovich Khairudinov
Viktor Kapitonovich Petukhov
Original Assignee
Smirnov Valentin Panteleimonov
Vitaly Mikhaylovich Nistratov
Jury Faridovich Berdnikov
Chesnokov Alexandr Vladimirovi
Fanil Galimovich Akhmetov
Ishmukhametov Azamat Zainullov
Irina Nikolaevna Muzalevskaya
Ildar Rashidovich Khairudinov
Viktor Kapitonovich Petukhov
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Application filed by Smirnov Valentin Panteleimonov, Vitaly Mikhaylovich Nistratov, Jury Faridovich Berdnikov, Chesnokov Alexandr Vladimirovi, Fanil Galimovich Akhmetov, Ishmukhametov Azamat Zainullov, Irina Nikolaevna Muzalevskaya, Ildar Rashidovich Khairudinov, Viktor Kapitonovich Petukhov filed Critical Smirnov Valentin Panteleimonov
Publication of WO2005009607A1 publication Critical patent/WO2005009607A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/081—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing particle radiation or gamma-radiation
    • B01J19/085—Electron beams only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G15/00—Cracking of hydrocarbon oils by electric means, electromagnetic or mechanical vibrations, by particle radiation or with gases superheated in electric arcs
    • C10G15/08—Cracking of hydrocarbon oils by electric means, electromagnetic or mechanical vibrations, by particle radiation or with gases superheated in electric arcs by electric means or by electromagnetic or mechanical vibrations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0881—Two or more materials
    • B01J2219/0884—Gas-liquid

Definitions

  • ⁇ e ⁇ m case ⁇ echenie ⁇ tsess ⁇ v zavisi ⁇ ⁇ ⁇ em ⁇ e ⁇ a ⁇ u ⁇ y and ⁇ gl ⁇ schenn ⁇ y radiation d ⁇ zy, s ⁇ n ⁇ shenie ⁇ e ⁇ miches ⁇ i ⁇ and ⁇ adiatsi ⁇ nn ⁇ - ⁇ e ⁇ miches ⁇ i ⁇ ⁇ tsess ⁇ v in ⁇ ev ⁇ aschenii is ⁇ dny ⁇ ⁇ a ⁇ tsy zavisi ⁇ ⁇ ⁇ mbinatsii m ⁇ schn ⁇ s ⁇ i radiation d ⁇ zy and ⁇ em ⁇ e ⁇ a ⁇ u ⁇ y.
  • P ⁇ s ⁇ avlennaya problem was ⁇ eshena s ⁇ zdaniem s ⁇ s ⁇ ba initsii ⁇ vaniya tse ⁇ ny ⁇ ⁇ ea ⁇ tsy diss ⁇ tsiatsii and ⁇ li ⁇ ndensatsii uglev ⁇ d ⁇ d ⁇ v, v ⁇ lyuchayuscheg ⁇ ⁇ b ⁇ ab ⁇ u sy ⁇ ya, s ⁇ de ⁇ zhascheg ⁇ uglev ⁇ d ⁇ dy, i ⁇ nizi ⁇ uyuschim radiation ele ⁇ nami ⁇ i ⁇ vyshenn ⁇ y ⁇ em ⁇ e ⁇ a ⁇ u ⁇ e and a ⁇ m ⁇ s ⁇ e ⁇ n ⁇ m pressure ⁇ lichayuscheg ⁇ sya ⁇ em, ch ⁇ ⁇ susches ⁇ vlyayu ⁇ ⁇ b ⁇ ab ⁇ u ⁇ ve ⁇ n ⁇ s ⁇ i sl ⁇ ya sy ⁇ ya
  • the processing of radiation by emitting radiation may be subject to continuous exposure. Otherwise, according to the invention, it is possible to operate in a pulsed-pulsed mode in accordance with the invention, by treating the emitting radiation.
  • a layer or flow of raw materials is formed in the form of a gas medium containing hydrogen and / or gaseous alkanes.
  • P ⁇ s ⁇ avlennaya problem was ⁇ a ⁇ zhe ⁇ eshena s ⁇ zdaniem us ⁇ ys ⁇ va for initsii ⁇ vaniya tse ⁇ ny ⁇ ⁇ ea ⁇ tsy diss ⁇ tsiatsii and ⁇ li ⁇ ndensatsii uglev ⁇ d ⁇ d ⁇ v, s ⁇ de ⁇ zhascheg ⁇ ⁇ ea ⁇ nuyu ⁇ ame ⁇ u having vnu ⁇ ennyuyu ⁇ l ⁇ s ⁇ , is ⁇ chni ⁇ radiation ele ⁇ nn ⁇ g ⁇ having, ⁇ at me ⁇ e, ⁇ dn ⁇ vy ⁇ dn ⁇ e ⁇ n ⁇ , vy ⁇ lnenn ⁇ e of ma ⁇ e ⁇ iala, ⁇ nitsaem ⁇ g ⁇
  • the device may optionally contain a second source of electrically emitting radiation, which ensures the protection of the radioactive material.
  • P ⁇ i e ⁇ m, s ⁇ glasn ⁇ iz ⁇ b ⁇ e ⁇ eniyu, ⁇ ed ⁇ ch ⁇ i ⁇ eln ⁇ , ch ⁇ by is ⁇ chni ⁇ radiation ele ⁇ nn ⁇ g ⁇ ⁇ bes ⁇ echival s ⁇ zdanie, ⁇ at me ⁇ e, ⁇ dn ⁇ g ⁇ ⁇ uch ⁇ a ⁇ elya ⁇ ivis ⁇ s ⁇ i ⁇ ele ⁇ n ⁇ v with ene ⁇ giey in dia ⁇ az ⁇ ne ⁇ ⁇ l ⁇ 0.5 d ⁇ ⁇ l ⁇ 2.5 ⁇ e ⁇ , ch ⁇ ⁇ zv ⁇ lyae ⁇ is ⁇ lz ⁇ va ⁇ susches ⁇ vuyuschie ⁇ myshlenn ⁇ ⁇ imenimye is ⁇ chni ⁇ i radiation ele ⁇ nn ⁇ g ⁇ - us ⁇ i ⁇ eli .
  • the source of the emitting radiation may contain a source that is not intended to be used in any way Otherwise, it is agreed that the source of the emitting radiation may be the source of the ignition source.
  • P ⁇ s ⁇ avlennaya problem was ⁇ a ⁇ zhe ⁇ eshena ⁇ az ⁇ ab ⁇ y s ⁇ s ⁇ ba ele ⁇ nn ⁇ - s ⁇ imuli ⁇ vann ⁇ g ⁇ ⁇ e ⁇ inga uglev ⁇ d ⁇ ds ⁇ de ⁇ zhascheg ⁇ sy ⁇ ya, ⁇ ed ⁇ ch ⁇ i ⁇ eln ⁇ , ne ⁇ i, and ne ⁇ e ⁇ du ⁇ v ne ⁇ yany ⁇ ⁇ s ⁇ a ⁇ v, v ⁇ lyuchayuscheg ⁇ ⁇ e ⁇ miches ⁇ uyu ⁇ b ⁇ ab ⁇ u sy ⁇ ya and ⁇ b ⁇ ab ⁇ u i ⁇ nizi ⁇ uyuschim radiation ele ⁇ nami ⁇ i ⁇ vs
  • the processing of radiation by the radiation can be carried out in a non-stop mode.
  • a layer or flow of raw materials is formed in the form of a gas medium containing hydrogen and / or gaseous alkanes.
  • P ⁇ s ⁇ avlennaya task was ⁇ a ⁇ zhe ⁇ eshena ⁇ az ⁇ ab ⁇ y us ⁇ an ⁇ v ⁇ i ele ⁇ nn ⁇ - s ⁇ imuli ⁇ vann ⁇ g ⁇ ⁇ e ⁇ inga uglev ⁇ d ⁇ d ⁇ v, ⁇ ed ⁇ ch ⁇ i ⁇ eln ⁇ , ne ⁇ i, ne ⁇ e ⁇ du ⁇ v and ne ⁇ yany ⁇ ⁇ s ⁇ a ⁇ v, s ⁇ de ⁇ zhaschaya ⁇ e ⁇ i ⁇ i ⁇ atsi ⁇ nnuyu ⁇ l ⁇ nnu, sis ⁇ emu ⁇ dachi sy ⁇ ya equipped us ⁇ ys ⁇ v ⁇ m nag ⁇ eva, us ⁇ ys ⁇ va ⁇ v ⁇ da ⁇ du ⁇ v v ⁇ zg ⁇ n ⁇ i and us ⁇ ys ⁇ v ⁇ ⁇ v ⁇ da ⁇ yazhely ⁇ ⁇ s ⁇ a ⁇ v, ⁇ lichayuscheesy
  • P ⁇ i e ⁇ m, s ⁇ glasn ⁇ iz ⁇ b ⁇ e ⁇ eniyu, ⁇ ed ⁇ ch ⁇ i ⁇ eln ⁇ , ch ⁇ by is ⁇ chni ⁇ radiation ele ⁇ nn ⁇ g ⁇ ⁇ bes ⁇ echival s ⁇ zdanie, ⁇ at me ⁇ e, ⁇ dn ⁇ g ⁇ ⁇ uch ⁇ a ⁇ elya ⁇ ivis ⁇ s ⁇ i ⁇ ele ⁇ n ⁇ v with ene ⁇ giey in dia ⁇ az ⁇ ne ⁇ ⁇ l ⁇ 0.5 d ⁇ ⁇ l ⁇ 2.5 ⁇ e ⁇ , ch ⁇ ⁇ zv ⁇ lyae ⁇ is ⁇ lz ⁇ va ⁇ susches ⁇ vuyuschie ⁇ myshlenn ⁇ ⁇ imenimye is ⁇ chni ⁇ i radiation ele ⁇ nn ⁇ g ⁇ - us ⁇ i ⁇ eli .
  • Figure 2 is a graph of the amount of absorbed energy at the depth of absorption at the irradiation of the layer of raw materials from one source, according to the invention
  • Fig. 5 installation of an electronic-stimulated hydrocarbon packaging according to the invention, a variant of execution.
  • the best option for carrying out the invention of the ways of initiating the significant reactions of dissociation and the increase in the concentration of hydrocarbons is the occurrence of the occurrence of the event ⁇ a ⁇ ig.1 ⁇ azan ⁇ s ⁇ ema ⁇ ichn ⁇ ⁇ ns ⁇ u ⁇ ivn ⁇ e vsh ⁇ lnenie us ⁇ ys ⁇ va 1 initsii ⁇ vaniya tse ⁇ ny ⁇ ⁇ ea ⁇ tsy diss ⁇ tsiatsii and ⁇ li ⁇ ndensatsii uglev ⁇ d ⁇ d ⁇ v s ⁇ glasn ⁇ iz ⁇ b ⁇ e ⁇ eniyu on ⁇ ig. ⁇ a- ⁇ is ⁇ s ⁇ blenn ⁇ g ⁇ for ⁇ b ⁇ ab ⁇ i dis ⁇ e ⁇ ny ⁇ ⁇ tsy is ⁇ dn ⁇ g ⁇ uglev ⁇ d ⁇ ds ⁇ de ⁇ zhascheg ⁇ sy ⁇ ya with ⁇ dn ⁇ y s ⁇ ny on
  • the source 2 of the elec- tric radiation has an output screen of 8 for the output of the bunch of 9 elec- trons; ⁇ ea ⁇ naya ⁇ ame ⁇ a 3 ( ⁇ ig. ⁇ a. ⁇ b) vy ⁇ lnena, na ⁇ ime ⁇ , me ⁇ alliches ⁇ y and imee ⁇ vnu ⁇ ennyuyu ⁇ l ⁇ s ⁇ 10 ⁇ is ⁇ s ⁇ blennuyu for ⁇ azmescheniya sl ⁇ ya 11 ( ⁇ ig.
  • the chamber 3 is equipped with a port 14 for the supply of raw materials to the internal cavity 10 connected to the unit 5 of the feed and connected to the gases 15.16, connected to the gas Process Products from the Internal Partnership 10.
  • the camera 3 is also equipped with a vent 17 for supplying a gas medium connected to a gas medium.
  • the best display of 8 can be performed, for example, in the form of a rectangle, the length of the handle corresponds to a width of 12 or a layer of 11 which is processed.
  • Us ⁇ ys ⁇ v ⁇ 5 ⁇ dachi is ⁇ dn ⁇ g ⁇ sy ⁇ ya m ⁇ zhe ⁇ ⁇ bes ⁇ echiva ⁇ ⁇ dachu sy ⁇ ya in ⁇ ea ⁇ nuyu ⁇ ame ⁇ u 3 na ⁇ ime ⁇ , s ⁇ uey with s ⁇ zdaniem in ⁇ ea ⁇ n ⁇ y ⁇ ame ⁇ e 3 sl ⁇ ya 11 sy ⁇ ya ( ⁇ ig. ⁇ a) zadann ⁇ y ⁇ lschiny, na ⁇ ime ⁇ in ⁇ is ⁇ s ⁇ blenn ⁇ y for eg ⁇ ⁇ azmescheniya em ⁇ s ⁇ i, s ⁇ glasn ⁇ iz ⁇ b ⁇ e ⁇ eniyu, za ⁇ lnyaya its d ⁇ given depth ⁇ , according to the invention, equal to the calculated value ⁇ of the depth of absorption.
  • the capacitance may be performed, for example, in the form of a tray.
  • Us ⁇ ys ⁇ v ⁇ 5 ⁇ dachi is ⁇ dn ⁇ g ⁇ sy ⁇ ya equipped with 6 heating raw materials, sh ⁇ lnennym, na ⁇ ime ⁇ , as ⁇ e ⁇ m ⁇ s ⁇ a ⁇ a or ⁇ e ⁇ l ⁇ bmenni ⁇ a.
  • the working body of the exchange can be used, for example, heavy fractions received after the loss of service, there is no connection to the product.
  • Devices 7 of the waste of gas and liquid products of the processing for example, of the main pumps and the process of the processing of the product.
  • the efficiency of initiating the chain reactions of dissociation and political compensation in the main is due to the efficiency of the use of energy 11 relativistic elec- trons, characterized by absorbed absorbed energy and deep absorption of elec- tric radiation.
  • Izbezha ⁇ nee ⁇ e ⁇ ivn ⁇ g ⁇ is ⁇ lz ⁇ vaniya m ⁇ schn ⁇ s ⁇ i radiation ele ⁇ nn ⁇ g ⁇ , s ⁇ glasn ⁇ iz ⁇ b ⁇ e ⁇ eniyu, ⁇ zv ⁇ lyae ⁇ ⁇ a ⁇ zhe ⁇ bluchenie sl ⁇ ya or ⁇ a with dvu ⁇ ⁇ iv ⁇ l ⁇ zhny ⁇ s ⁇ n .
  • Figure 4 shows the dependence of the output ⁇ ) ⁇ livny ⁇ ⁇ a ⁇ tsy ⁇ ⁇ em ⁇ e ⁇ a ⁇ u ⁇ y mazu ⁇ a ⁇ i ⁇ imenenii s ⁇ s ⁇ ba initsii ⁇ vaniya ⁇ ea ⁇ tsy diss ⁇ tsiatsii and ⁇ li ⁇ ndensatsii, ⁇ ivaya "with” - vy ⁇ da benzin ⁇ v ⁇ y ⁇ a ⁇ tsii, ⁇ ivaya " ⁇ -" - vy ⁇ da dizeln ⁇ g ⁇ ⁇ liva, ⁇ i ⁇ bluchenii mazu ⁇ a, imeyuscheg ⁇ anal ⁇ gichnye above u ⁇ azannym ⁇ izi ⁇ - ⁇ imiches ⁇ ie ⁇ a ⁇ a ⁇ e ⁇ is ⁇ i ⁇ i, ⁇ elya ⁇ ivis ⁇ s ⁇ imi ele ⁇ nami with energy 10.0 ⁇ e ⁇ .
  • the optimum temperature of the fuel oil for the electric stimulated cooking makes up 410 to 420 ° C.
  • the end of gas products after the temperature of the fuel oil reaches 400 ° C and begins to change slightly after heating to the temperature of 430 ⁇ 440. Therefore, heating of raw materials above 430 ° C will result in significant energy consumption, however, it will not result in an increase in the effec- tive and lowering radiation.
  • Device 1 for initiating a series of reactions of dissociation and compensation operates the following way.
  • Is ⁇ dn ⁇ e sy ⁇ e nag ⁇ evayu ⁇ in us ⁇ ys ⁇ ve 5 ⁇ dachi is ⁇ dn ⁇ g ⁇ sy ⁇ ya d ⁇ ⁇ em ⁇ e ⁇ a ⁇ u ⁇ y not less than 410 ° C and in ⁇ dayu ⁇ ⁇ ea ⁇ nuyu ⁇ ame ⁇ u 3 za ⁇ lnennuyu gaz ⁇ v ⁇ y s ⁇ ed ⁇ y, s ⁇ de ⁇ zhaschey v ⁇ d ⁇ d and / or al ⁇ any where ⁇ dve ⁇ gayu ⁇ ⁇ blucheniyu ⁇ elya ⁇ ivis ⁇ s ⁇ imi ele ⁇ nami ene ⁇ giey in dia ⁇ az ⁇ ne ⁇ ⁇ l ⁇ 0.5 d ⁇ ⁇ l ⁇ 10 , 0 ECO, preferably, in the range from 1.5 to 2.5 ACE, in the continuous mode 13 or pulsed-radiative exposure.
  • the gas medium washes the output windows 8 of the radiation source 2 and cools the foil.
  • the expiry time is selected from the access to the processed dose of 10 kg.
  • Raw materials may be used in liquids, liquids, and gas, and may have varying levels of salinity and varying chemical composition. Depending on the amount of weekly and weekly hydrocarbons in the processed product, there is a difference in the amount of food that is inadequate to food.
  • Us ⁇ ys ⁇ v ⁇ 1 s ⁇ de ⁇ zhi ⁇ is ⁇ chni ⁇ 2 i ⁇ nizi ⁇ uyuscheg ⁇ radiation ⁇ ea ⁇ nuyu ⁇ ame ⁇ u 3
  • S ⁇ mi ⁇ vanny ⁇ a ⁇ im ⁇ b ⁇ az ⁇ m ⁇ ⁇ bluchayu ⁇ ⁇ uch ⁇ m ⁇ elya ⁇ ivis ⁇ s ⁇ i ⁇ ele ⁇ n ⁇ v is ⁇ chni ⁇ a 2 i ⁇ nizi ⁇ uyuscheg ⁇ radiation with ⁇ dn ⁇ y s ⁇ ny, ⁇ a ⁇ ⁇ azan ⁇ on ⁇ ig.5, or dvu ⁇ s ⁇ n and za ⁇ em zhid ⁇ ie ⁇ du ⁇ y na ⁇ avlyayu ⁇ in ⁇ e ⁇ i ⁇ i ⁇ atsi ⁇ nnuyu ⁇ l ⁇ nnu 22 ⁇ sleduyuscheg ⁇ ⁇ deleniya leg ⁇ i ⁇ ⁇ a ⁇ tsy and gaz ⁇ b ⁇ aznye ⁇ du ⁇ y ⁇ v ⁇ dya ⁇ for ⁇ sleduyuschey ⁇ chis ⁇ i of foreign impurities.
  • ⁇ i is ⁇ lz ⁇ vanii us ⁇ an ⁇ v ⁇ i ele ⁇ nn ⁇ -s ⁇ imuli ⁇ vann ⁇ g ⁇ ⁇ zhe ⁇ by ⁇ d ⁇ s ⁇ ignu ⁇ a defined by ⁇ lz ⁇ va ⁇ elem ⁇ izv ⁇ di ⁇ eln ⁇ s ⁇ us ⁇ ys ⁇ va 1 s ⁇ s ⁇ ave us ⁇ an ⁇ v ⁇ i and ⁇ a ⁇ zhe ⁇ izv ⁇ di ⁇ eln ⁇ s ⁇ m ⁇ zhe ⁇ ⁇ eguli ⁇ va ⁇ sya in ⁇ echenie ⁇ tsessa in zavisim ⁇ s ⁇ i ⁇ s ⁇ s ⁇ i ⁇ dachi is ⁇ dn ⁇ g ⁇ sy ⁇ ya, ⁇ l ⁇ n ⁇ s ⁇ i ⁇ du ⁇ v ⁇ e ⁇ e ⁇ ab ⁇ i, ⁇ dve ⁇ gayuschi ⁇ sya
  • Samples were placed in the tank in the case of the camera, respectively, with a thickness of 4.9 cm, 1.2 cm and 0.6 cm when the frequency of the word was changed to a value of 1.5 .
  • the average capacity of the absorbed dose for the unit is 1.1 kg / s
  • the capacity of the dosages in the center of the electric beam was up to 40 kg / s, it is available for 20%.
  • ⁇ As a result of the main reaction from fuel oil, the operation of the electric and radiation-reducing radiation resulted in the formation of light fuel-based extracts from the analysis.
  • Example 8 The off-gas from the borehole is designed to be supplied to the processing chamber 3 of the device 1 for the initiation of the disengagement and disruption of the 19 i ⁇ nizi ⁇ uyuscheg ⁇ radiation, ⁇ dve ⁇ gayu ⁇ ⁇ blucheniyu v ⁇ zdeys ⁇ viem ⁇ elya ⁇ ivis ⁇ s ⁇ imi ele ⁇ nami ene ⁇ giey 0.5 ⁇ e ⁇ with dvu ⁇ ⁇ iv ⁇ l ⁇ zhny ⁇ s ⁇ n, ch ⁇ susches ⁇ venn ⁇ uvelichivae ⁇ z ⁇ nu ⁇ blucheniya IL snizhae ⁇ za ⁇ a ⁇ y ene ⁇ gii radiation ⁇ i ⁇ dina ⁇ v ⁇ m ⁇ as ⁇ de gas.
  • Disposal of a layer or waste stream in the process of processing of a gas and / or gas-containing alkalis in the process of inlet of a waste water ⁇ me ⁇ g ⁇ , ⁇ i s ⁇ i ⁇ sn ⁇ venii vy ⁇ dn ⁇ g ⁇ ⁇ na is ⁇ chni ⁇ a ele ⁇ nn ⁇ g ⁇ radiation ⁇ bychn ⁇ vy ⁇ lnenn ⁇ g ⁇ of me ⁇ alliches ⁇ y ⁇ lgi with v ⁇ d ⁇ d ⁇ m and / or gaz ⁇ b ⁇ aznymi al ⁇ anami ⁇ is ⁇ di ⁇ ⁇ lazhdenie vy ⁇ dn ⁇ g ⁇ ⁇ na, ch ⁇ umenshae ⁇ ve ⁇ ya ⁇ n ⁇ s ⁇ ⁇ g ⁇ aniya ⁇ lgi, ⁇ vn ⁇ ae ⁇ bez ⁇ asn ⁇
  • the gas is heated up in order to facilitate the dissociation of its molecules by radiation.

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Abstract

La présente invention relève des industries chimique, gazière, pétrolière, pétrochimique et d'autres secteurs liés à la transformation de matières premières contenant des hydrocarbures, en particulier à la fabrication d'un produit de condensation formé de gaz d'hydrocarbures légers, et à la transformation du pétrole présentant une viscosité élevée et de résidus pétroliers. Le procédé selon l'invention consiste à traiter thermiquement la matière première, et à traiter la surface d'une couche ou d'un flux d'une matière première initiale dans un milieu gazeux contenant de l'hydrogène et/ou des alcanes gazeux, à une température et à une pression atmosphérique élevées, et ce par l'intermédiaire d'un rayonnement ionisant faisant appel à des électrons relativistes dont l'énergie est comprise dans une gamme allant d'environ 0,5 à 10,0 MeV, et de préférence d'environ 0,5 à environ 3,5 MeV, l'épaisseur de la couche ou du flux de matière première étant équivalente à la profondeur d'absorption du rayonnement électronique définie par la relation λ x ρ = 0,5 E 0,1, où λ représente la profondeur d'absorption du rayonnement électronique, exprimée en cm ; ρ représente la masse volumique de la matière première, exprimée en g/cm3 ; E représente l'énergie des électrons, exprimée en MeV. L'irradiation est réalisée d'un côté de la couche ou des deux côtés opposés de la couche, en continu ou à l'aide d'impulsions intermittentes. L'invention concerne également des dispositifs permettant de mettre en oeuvre ledit procédé.
PCT/RU2004/000287 2003-07-24 2004-07-26 Procede permettant de lancer des reactions en chaine de dissociation et de polycondensation d'hydrocarbures, et dispositif permettant sa mise en oeuvre WO2005009607A1 (fr)

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RU2003122425 2003-07-24
RU2003122425/15A RU2252069C2 (ru) 2003-07-24 2003-07-24 Способ инициирования цепных реакций диссоциации и поликонденсации углеводородов и устройство для его осуществления

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US7931785B2 (en) 2008-11-05 2011-04-26 Azamat Zaynullovich Ishmukhametov Method for cracking, unification and refining of hydrocarbons and device for its implementation
WO2011159200A1 (fr) * 2010-06-16 2011-12-22 Учреждение Российской Академии Наук Институт Физической Химии И Электрохимии Им. А. Н. Фрумкина Ран (Ифхэ Ран) Procédé de conversion d'alcanes gazeux

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AR058345A1 (es) 2005-12-16 2008-01-30 Petrobeam Inc Craqueo autosostenido en frio de hidrocarburos
RU2622289C1 (ru) * 2016-06-02 2017-06-14 Сергей Александрович Курмаев Способ получения светлых углеводородов
RU2758057C1 (ru) * 2020-12-09 2021-10-26 Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть-ОНПЗ") Способ получения линейных альфа-олефинов

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US4885065A (en) * 1987-05-29 1989-12-05 The University Of Michigan-Ann Arbor Electron beam, ion beam, or neutral particle beam induced modification of or enhancement of combustion reactions
RU2099387C1 (ru) * 1996-04-17 1997-12-20 Александр Владимирович Пономарев Способ переработки конденсированных углеводородов
RU2142496C1 (ru) * 1997-05-05 1999-12-10 Чесноков Борис Павлович Способ инициирования химических реакций в процессе переработки нефти и нефтепродуктов и устройство для его осуществления

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7931785B2 (en) 2008-11-05 2011-04-26 Azamat Zaynullovich Ishmukhametov Method for cracking, unification and refining of hydrocarbons and device for its implementation
WO2011159200A1 (fr) * 2010-06-16 2011-12-22 Учреждение Российской Академии Наук Институт Физической Химии И Электрохимии Им. А. Н. Фрумкина Ран (Ифхэ Ран) Procédé de conversion d'alcanes gazeux

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