WO2004108096A1 - Cosmetic composition containing powder obtained by dividing soybean into individual cells - Google Patents

Cosmetic composition containing powder obtained by dividing soybean into individual cells Download PDF

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Publication number
WO2004108096A1
WO2004108096A1 PCT/JP2003/006968 JP0306968W WO2004108096A1 WO 2004108096 A1 WO2004108096 A1 WO 2004108096A1 JP 0306968 W JP0306968 W JP 0306968W WO 2004108096 A1 WO2004108096 A1 WO 2004108096A1
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WO
WIPO (PCT)
Prior art keywords
cosmetic composition
powder
soybean
cosmetic
total weight
Prior art date
Application number
PCT/JP2003/006968
Other languages
French (fr)
Japanese (ja)
Inventor
Kenichi Tomita
Shinobu Fujita
Original Assignee
Eau De Faveur Co., Ltd.
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Publication date
Application filed by Eau De Faveur Co., Ltd. filed Critical Eau De Faveur Co., Ltd.
Priority to AU2003241864A priority Critical patent/AU2003241864A1/en
Priority to PCT/JP2003/006968 priority patent/WO2004108096A1/en
Publication of WO2004108096A1 publication Critical patent/WO2004108096A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783—Angiosperms [Magnoliophyta]
    • A61K8/9789—Magnoliopsida [dicotyledons]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/12—Face or body powders for grooming, adorning or absorbing
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations

Definitions

  • the cosmetic composition of the present invention is suitable for use as a skin care cosmetic.
  • Skin care The purpose of cosmetics is to cleanse the skin and keep the outermost stratum corneum well-watered.
  • the stratum corneum is composed of keratinocytes (keratinocytes), but unlike normal cells, the nucleus and other organelles of the species are lost, and most of the cells are filled with fibrous proteins called keratin. Have been. In the cell membrane, proteins are bound from the inside of the cell by a strong cross-linking structure, forming a tough keratinous hyperplasia and constituting the skin.
  • the main raw materials for conventional powdered makeup cosmetics are inorganic extender pigments such as titanium, talc, myriki, silica and zinc white, and colored inorganic pigments mainly composed of iron oxide, and have good compatibility with the skin surface There is no material.
  • inorganic extender pigments such as titanium, talc, myriki, silica and zinc white
  • colored inorganic pigments mainly composed of iron oxide and have good compatibility with the skin surface
  • the development of surface coatings on inorganic raw materials or organic resin powders has been attempted, but none of these have yielded satisfactory results.
  • this problem has been successfully solved by adding a natural material called soybean to the cosmetic composition in a single cell state.
  • the amount of the single cell powder of soybean is 0.1 to 5%, preferably 6 to 35%, based on the total weight of the cosmetic composition. If the amount is less than 1%, the effect of adding single-cell soybean powder may not be obtained in + minutes. If the blending amount exceeds 50%, soybean oil may ooze out of the molded product during press molding of the cosmetic composition, and the quality of molded cosmetics may be degraded. When the compounding amount is within the range of 6 to 35%, the above-mentioned effect brought about by the use of single-cell soybean powder can be stably realized, and a powdery makeup cosmetic composition having a function equivalent to that of skin care cosmetics. Ideal for manufacturing things.
  • a single-cell soybean powder was obtained by the same method as described in PCT application WO01 / 0242. That is, after washing 1.1 kg of dried soybeans with water, they were immersed in water for 12 hours. Next, the soybeans were pulled out of the water without throwing away the water used for manzuke. At this time, the soybeans had absorbed water and had swelled to a total weight of 2.2 kg. Then, 1 2_Rei ° C, 1 .1 kg / cm 2 using a pressure cooker, and cook the soybeans under the conditions of lambda 0 minutes. After cooling the steamed soybeans to 60 ° C, 2.2 kg of water used for immersion and ⁇ .1 wt% of the weight of dried soybeans. Was added to soybean to obtain a first mixture.
  • a slurry liquid processed soybean in which single cells of soybean were dispersed was obtained.
  • the slurry was then heated at 10 ° C. for 15 minutes to deactivate the enzyme activity of actinase. Thereafter, the slurry was dried with a spray dryer to obtain a soybean single-cell powder for producing the cosmetic composition of the present invention.
  • Table 1 shows the results of component analysis of this soybean single-cell powder.
  • Table 2 shows the results of quantitative analysis of isoflavone components in soybean single-cell powder.
  • Example 1 the above-mentioned soybean single-cell powder was used to produce a powdered white powder (le-powder) having the composition shown in Table 3 in the following manner.
  • the powdered white powder is a powdery makeup cosmetic which is almost entirely composed of powdered raw materials without blending oil or the like.
  • soybean single-cell powder, talc, sericite, kaolin, titanium, and a coloring pigment were weighed to obtain the blending amount shown in Table 3 and mixed with a blender.
  • the remaining magnesium carbonate, zinc myristate and preservative were added to the mixture, mixed well, and mixed.
  • the fragrance was sprayed and uniformly mixed. The obtained mixture was mixed and stirred again under mild conditions such that the soybean single cells were not crushed, and the white powder of Example 1 was obtained through a sieve.
  • Example 3 the powdered soybean soybean single cell powder was used to produce a powder leaf formulation having the composition shown in Table 5 as follows. That is, soybean single-cell powder, variously treated sericite, myriki, talc, titanium, and a coloring pigment were weighed and mixed with a blender so that the mixing ratio shown in Table 5 was obtained. The remaining titanium-zinc white composite powder, nylon powder, zinc stearate, and preservative were added to the mixture, mixed well, and mixed. Then, the fragrance was sprayed and mixed uniformly. The obtained mixture was mixed and stirred again under a mild condition such that a soybean single cell was not crushed, and the powder obtained through a sieve was compression-molded to obtain the No. 3 daly foundation of Example 3.
  • the powdery foundation contains more colored pigments and white pigment than solid white powder from the viewpoint of skin color correction.
  • a binder for molding the powder is required more than the solid white powder, and it is necessary to add about 1096 of squalane-synthetic ester oil. Since a single cell powder is contained, no additional binder is required. As a result, it is possible to provide an unprecedented unique feeling of slippage and tightness, and to provide a feeling of remaining after moistening.
  • silicon-treated plate-like talc was added instead of soybean single-cell powder.
  • Squalane, octyldodecyl myristate, dimethylpolysiloxane, and polyethylene oxide-added dimethylpolysiloxane as a binder.
  • a powdery foundation of Comparative Example 3 was obtained in the same procedure as in Example 3 except that ⁇ % by weight was added.
  • Example 4 the above-described soybean single-cell powder was used to produce a cake-type foundation having the composition shown in Table 6 as follows. That is, soybean single-cell powder, kaolin, sericite, talc, titanium and a coloring pigment were weighed and mixed with a planter so that the blending amounts shown in Table 6 were obtained. The remaining titanium-zinc white composite powder and preservative are added to this, mixed well, and toned. Then, the fragrance was sprayed and mixed uniformly. The resulting mixture was mixed and stirred again under mild conditions so that single soybean cells were not crushed, and the obtained powder was compression-molded through a sieve to obtain a cake-type foundation of Example 4.
  • a cake-type foundation is a solid foundation used for sponge sponges soaked in water, and is often used in the summer due to its refreshing feeling.
  • a hydrophilic surfactant is included to give a creamy feel.
  • Example 5 a so-called single-cell soybean powder was used, and a dual-use foundation having the composition shown in Table 7 was produced as follows. That is, soybean single-cell powder, silicon-treated My power, silicone-treated talc, silicone-treated My power, silicon-treated titanium, silicone-treated ultrafine zinc powder and colored pigment were weighed so that the blending amounts shown in Table 7 were obtained. And blended in a blender. The remaining nylon powder, zinc stearate, glycerin triisooctanoate in which solid paraffin is dissolved, dimethylpolysiloxane, and a preservative are added to the mixture, mixed well, and toned. Then, the fragrance was sprayed and mixed uniformly. The obtained mixture was mixed and stirred again under mild conditions such that the soybean single cells were not crushed, and the powder obtained through a sieve was compression-molded to obtain a dual-use foundation of Example 5.
  • the dual-use foundation is so-called because it has the functions of both a powdery foundation and a cake-type foundation, and can be used with either dry sponge or water sponge. At present, it is the mainstream of the summer foundation.
  • each of the cosmetic compositions was applied to one hundred and fifty women who were testers by the half-face method.
  • a questionnaire was given on the feeling of use during use and after 5 hours.
  • the half-face method means that each examiner uses the cosmetic composition of the example in half of the face and the cosmetic composition of the comparative example in half of the face.
  • a method for simultaneously evaluating the cosmetic compositions of Comparative Examples The test was performed after the same facial cleanser was used for 5 minutes with foam and the face was fixed to make the skin condition constant. In addition, no other cosmetics such as pre-makeup milky lotion were used for clear evaluation. The following items were evaluated.
  • a commonly used puff was used as a cosmetic tool for removing powdered white powder and solid white powder, and a sponge puff without water was used as a tool for using the foundation.
  • Each tester indicated that the cosmetic composition had good removability with cosmetic tools, 2 points for the test, 1 point for the average, and ⁇ for the difficulties. Fill in.
  • Each tester gives 2 points if the cosmetic composition feels good on the skin, 1 point if it feels normal, and ⁇ point if it does not stretch well on the specified paper. Fill in.
  • Each tester puts 2 points on the prescribed paper when the cosmetic composition does not feel powder floating on the skin, 1 point when the cosmetic composition feels normal, and 0 point when the cosmetic composition has powder floating. Fill out.
  • each tester feels that there is no oil floating on the skin of the cosmetic composition, 2 points for lifting, 1 point for normal feeling, and ⁇ point for oil floating. On the designated paper.
  • each tester feels that the cosmetic composition has good adhesion on the skin, 2 points; normal, 1 point; If not, write 0 points on the specified form.
  • each tester After 5 hours of use of the cosmetic composition, each tester gives 2 points if the skin feels moist, 1 point if it feels normal, and ⁇ point if it does not feel moist Fill out the form.
  • each tester gave 2 points if the skin did not feel dry, 1 point if it felt normal, and 0 point if it felt dry. Fill out the form
  • Example 8 an OZW type emulsion was introduced as an example of the emulsion of the present invention.
  • an example of a WZO type emulsion will be introduced.
  • the amount of the soybean single-cell powder is set to 3 to 5% with respect to the total weight of the cosmetic composition, so that the soybean single-cell powder is not contained.
  • an OZW type cream having the composition shown in Table 13 was produced as follows. That is, a humectant and soybean single cell powder were added to purified water, and heated and mixed at 7 ° C. After heating and dissolving the oily components, surfactants, preservatives and fragrances were added to adjust the temperature to ⁇ ° C. This was adjusted first and added to the aqueous phase, and the emulsified particles were homogenized with a homomixer, followed by degassing and cooling to obtain the OZW type cream of this example.
  • Example 10 an OZW type cream was introduced as an example of the cream of the present invention.
  • an example of a WZO type cream is introduced.
  • a WZO-type cream having the composition shown in Table 14 was produced as the cosmetic composition of the present invention.
  • This cream was manufactured as follows. In other words, the aqueous phase (1) was heated and dissolved at 50 ° C, and then converted to a surfactant that was also heated to 50 ° C. The emulsion composition was gradually added with stirring to adjust the emulsion composition. The above-mentioned emulsified composition was uniformly dispersed in a substance obtained by heating and dissolving the oil phase at about ° C.
  • aqueous phase (2) was heated to 0 ° C, it was added to this dispersion with sufficient stirring, and the mixture was uniformly emulsified with a homomixer, then degassed and cooled to 30 ° C.
  • the WZO type cream of this example was obtained.
  • the mixing amount of the soybean single-cell powder is set to 5 to 8% based on the total weight of the cosmetic composition, so that the soybean single-cell powder is not contained.
  • jewel has good familiarity with the skin during use, along with o skin permeation and adhesion, and reduces the feeling of stickiness after use. It has been confirmed in experiments. Here are some examples.
  • a moist charge well having the composition shown in Table 15 was produced as follows. That is, after uniformly dissolving a water-soluble polymer in purified water, polyethylene glycol, soybean single-cell powder, and a chelating agent were added. A surfactant was added to dipropylene glycol, and dissolved by heating at 50 to 55 ° C, and a preservative and a fragrance were added thereto. The previously prepared aqueous phase was gradually added to this with stirring. Finally, an aqueous alkali solution was added, and the mixture was stirred for + minutes for neutralization, to obtain a moist charge well of this example. Table 15
  • the amount of the soybean single-cell powder is set to 0.1 to 2% with respect to the total weight of the cosmetic composition, so that the soybean single-cell powder is not contained.
  • the blending amount of the soybean single-cell powder is set to 8 to 5% with respect to the total weight of the cosmetic composition, so that the soybean single-cell powder is not contained.
  • the pack composition has a feeling of adhesion and penetration to the skin in use, a feeling of firmness to the skin after rinsing, no bulkiness, and a sustained moisturizing effect. It has been confirmed by experiments that it can be applied to objects. Here are some examples.
  • a rinse-off type knock having the composition shown in Table 17 was produced.
  • This pack was manufactured as follows. That is, a humectant and soybean single-cell powder were added to purified water and sufficiently wetted and dispersed. Next, a surfactant, a fragrance, and a preservative were added and dissolved in ethanol, and added to the above-mentioned aqueous phase. Thereafter, the obtained mixture was degassed to obtain a pack of this example. '
  • the soybean single-cell powder is not contained by adjusting the blending amount of the soybean single-cell powder to 0.5 to 2% with respect to the total weight of the cosmetic composition.
  • the lipstick can give the lipstick a better feeling of close contact with the lips during use, less bulkiness after use, and better stickiness of the lipstick when reused. ing.
  • Table 18 an emulsified type lipstick having the composition shown in Table 18 was produced as follows. That is, titanium dioxide, Red No. 201 and No. 202 were added to a part of castor oil together with an antioxidant, and roller treatment was performed to obtain a pigment part. On the other hand, Red No.
  • a humectant, a surfactant, and a soybean single cell powder were added to purified water, and the mixture was uniformly dissolved and mixed at 80 ° C to obtain an aqueous phase.
  • the other components including the fragrance were mixed and dissolved by heating, and then the pigment portion and the dye portion were added and uniformly dispersed with a homomixer. Thereafter, the aqueous phase was added, emulsified and dispersed by a homomixer, degassed, poured into a mold and rapidly cooled to obtain a lipstick of this example.
  • an OZW-type hair cream having the composition shown in Table 19 was obtained.
  • a water-soluble polymer, a humectant, a surfactant, a chelating agent, and a soybean single cell powder were added to purified water, and the mixture was heated and dissolved and adjusted to 80 ° C.
  • the oil phase was added and emulsified using a homogenizer.
  • a potassium hydroxide solution dissolved in a part of purified water was added, stirred until the mixture became uniform, and degassed to obtain a hair cream of this example.
  • the content of the soybean single-cell powder is set to 0.1 to 1% with respect to the total weight of the cosmetic composition so that the soybean single-cell powder is not contained.
  • the body cream has good finger removal before use, good stretch on the skin during use and its close contact, the feeling of firmness of the skin after rinsing, the lack of dryness, and the moistness that accompanies it.
  • the moisturizing effect can be maintained and the effect can be imparted to body cosmetics.
  • a WZO-type daytime body cream having the composition shown in Table 2 was produced as follows. That is, squalane, silicone, a surfactant, a preservative, and a fragrance were mixed by heating and dissolved, and the hydrophobized powder was dispersed with stirring to obtain an oil phase.
  • a humectant and soybean single-cell powder were added to purified water and adjusted at 70 ° C to obtain an aqueous phase. This aqueous phase was added to the above-mentioned oil phase and subjected to a homogenizer treatment. The obtained emulsion was cooled to room temperature and degassed to obtain a body cream of this example.
  • Table 20
  • the cosmetic composition containing the single-cell soybean powder of the present invention exhibits excellent performance over multiple functions such as a moisturizing effect, a feeling of adhesion to the skin, and a prevention of dryness of the skin. It is expected to be used in a wide range of applications such as skin lotion, milky lotion, cream, jewel, essence (cosmetic), packs and other skincare cosmetics, makeup cosmetics such as foundation and lipstick, hair cosmetics, body cosmetics, etc. .
  • the cosmetic composition of the present invention when used as a powdery make-up cosmetic composition, it is different from conventional skin care cosmetics, as is clear from the comparison between the above Examples and Comparative Examples.
  • a powdered makeup cosmetic composition having a moisturizing effect comparable to that of skin care cosmetics can be provided despite being composed of the main component.
  • the use of a binder In the case of cosmetic compositions such as solid white powdery powdery foundation, the use of a binder has conventionally been indispensable in order to ensure its moldability.
  • soybean cell powder is used. Another advantage is that good moldability can be obtained without the use of any binder.

Abstract

It is intended to provide a cosmetic composition having multiple functions such as exhibiting an excellent moisturizing effect, showing a favorable adhesiveness to the skin and preventing the skin from drying after prolonged use. This composition contains a powder obtained by dividing soybeans into individual cells. By appropriately controlling the content of the soybean cell powder to 0.1 to 50% based on the whole cosmetic composition, in particular, it becomes possible to provide various cosmetics including skin-care products (face washes, cosmetic lotions, milky lotions, creams, gels, essences (cosmetic essences), packs, etc.), makeup cosmetics (foundations, lipsticks, etc.), hair cosmetics and body cosmetics each showing a humectant/moisturizing effect which has never been achieved by existing products.

Description

明細書  Specification
大豆を単細胞に分離して得られる粉末を含有する化粧料組成物 技術分野  Cosmetic composition containing powder obtained by separating soybean into single cells
本発明は、大豆を単細胞に分離して得られる粉末を含有してなる化粧料組成物に関 するものであり、 特に、 洗顔料、 化粧水、 乳液、 クリーム、 ジエル、 エッセンス （美容 液） 、 パック等のスキンケア化粧品、 ファンデーション、 口紅などのメーキャップ化粧 品、 毛髪化粧品、 ボディ化粧品等に好適な化粧料組成物に関するものである。 背景技術  The present invention relates to a cosmetic composition containing a powder obtained by separating soybeans into single cells, and more particularly to a face wash, a lotion, a milky lotion, a cream, a jewel, an essence (cosmetic), The present invention relates to a cosmetic composition suitable for skin care cosmetics such as packs, makeup cosmetics such as foundations and lipsticks, hair cosmetics, body cosmetics and the like. Background art
化粧料組成物は、人間の本能的な欲望である自己をより美しく魅力あるものに表現 するために使用され、 その使用感ゅ皮膚への密着感の向上ゆ保湿効果のさらなる改善等 を目的として開発が続けられている。 '  Cosmetic compositions are used to express human instinct, the instinct of desire, in a more beautiful and attractive manner, with the aim of further improving the moisturizing effect, including the feeling of use and the closeness to the skin. Development continues. '
例えば、特開平 1 0— 7 23 3 5号は、単細胞化植物を含んでなる皮膚外用剤につ いて記載している。 この皮膚外用剤は、 植物、 海藻等の細胞壁を有する天然素材を酵素 処理ゆ機械的分解等の手段により、 細胞壁を分解せずに、 細胞間物質を分解又は破壊し て得られる液状組成物又は凍結乾燥品を含有することを特徴としており、 単細胞化する 植物として、 ニンジン、 アロエ、 フリージア、 ィリス根が挙げられている。 また、 酵素 処理に使用される酵素としては、 Aspergillusnigerゆ Rhizopus等の微生物由来のポリ ガラクッロナ一ゼゃぺクチナーゼが例示されている。 このような単細胞化植物を外用剤 中に含有させることにより、 その植物中の有効成分の経時的安定性、 保湿効果の改善、 および特定のフリーラジカルの除去効果等を得ている。 例えば、 ニンジンを単細胞に分 離して得られる粉末を皮膚外用剤中に配合する場合は、 —力ロチン等のニンジン中の 有効成分の経時的安定性、 保湿効果およびヒドロキシラジカルの除去効果に優れ、 ァ口 ェを単細胞に分離して得られる粉末を皮膚外用剤中に配合する場合は、 アロエニン等の アロエ中の有効成分の経時安定性および保湿効果に優れると共に、 皮膚の真皮層を形成 する繊維芽細胞の増殖を促進する効果が得られると記載されている。  For example, Japanese Patent Application Laid-Open No. 10-72335 describes a skin external preparation containing a single cell plant. This external preparation for skin is a liquid composition or a liquid composition obtained by decomposing or destroying intercellular substances without decomposing cell walls by means such as enzymatic treatment and mechanical decomposition of natural materials having cell walls such as plants and seaweeds. It is characterized by containing freeze-dried products, and carrots, aloe, freesia, and iris roots are listed as single-cell plants. Examples of enzymes used for the enzyme treatment include polygalacturonectinase derived from microorganisms such as Aspergillusniger and Rhizopus. By incorporating such a single-cellular plant in an external preparation, the stability of the active ingredient in the plant over time, the moisturizing effect is improved, and the effect of removing specific free radicals is obtained. For example, when a powder obtained by separating carrots into single cells is incorporated into an external preparation for skin,-the active ingredients in carrots such as power rotin are excellent in temporal stability, moisturizing effect and hydroxy radical removing effect, When a powder obtained by separating a mouth into single cells is incorporated into an external preparation for skin, the fiber that forms the dermis layer of the skin is excellent in the stability over time and moisturizing effect of the active ingredients in aloe such as aloenin. It is described that an effect of promoting the proliferation of blast cells can be obtained.
しかしながら、上記したように、自己をさらに美しく表現し いという使甩者の要 求をさらに高いレベルで満足させる観点から、 従来の化粧料組成物には依然として改善 の余地が残されている。 発明の開示 However, as described above, there is still room for improvement in conventional cosmetic compositions from the viewpoint of satisfying the demands of messengers to express themselves more beautifully at a higher level. Disclosure of the invention
そこで、本発明の目的は、大豆単細胞の細胞膜組成と人の皮膚組成との類似性から べトとっかないサラサラした使用感を与えるとともに、 優れだ保湿効果、 従来にない皮 膚への密着感、 長時間使用後における肌乾燥感の防止等の多機能を有する化粧料組成物 を提供することにある。  Therefore, an object of the present invention is to provide a non-greasy and smooth feeling of use due to the similarity between the cell membrane composition of soybean single cells and the human skin composition, as well as an excellent moisturizing effect, an unprecedented feeling of adhesion to skin, An object of the present invention is to provide a cosmetic composition having multiple functions such as prevention of dry skin after long-term use.
すなわち、本発明の化粧料組成物は、大豆を単細胞に分離して得られる粉末を含有 してなることを特徴とする。本明細書において、大豆の単細胞粉末とは、原料大豆の個 の細胞を単細胞に分離して得られだ粉末を意味する。  That is, the cosmetic composition of the present invention is characterized by containing a powder obtained by separating soybean into single cells. In the present specification, the soybean single-cell powder means a powder obtained by separating individual cells of the raw soybean into single cells.
大豆の単細胞粉末としては、 Bacillus属の微生物が産生するぺクチナーゼを用いた 酵素処理を原料大豆に実施して得られるものを使用することが好ましい。  As the soybean single-cell powder, it is preferable to use one obtained by subjecting a raw material soybean to an enzyme treatment using a pectinase produced by a microorganism of the genus Bacillus.
ま 、大豆の単細胞粉末の配合量は、化粧料組成物の全重量に関して 0. 1 -50 であることが好ましい。  The amount of the single cell powder of soybean is preferably 0.1 to 50 with respect to the total weight of the cosmetic composition.
上記化粧料組成物を洗顔料として使用する場合は、粉末の配合量が上記化粧料組成 物の全重量に関して 5~ 1 5%であり、 化粧水として使用する場合は、 粉末の配合量が 上記化粧料組成物の全重量に関して 0. 1〜1 %であり、 化粧用乳液として使用する場 合は、 粉末の配合量が上記化粧料組成物の全重量に関して 1 ~ 3%であり、 化粧用クリ ームとして使用する場合は、 粉末の配合量が上記化粧料組成物の全重量に関して 3〜 1 5%であることが好ましい。  When the cosmetic composition is used as a facial cleanser, the amount of the powder is 5 to 15% with respect to the total weight of the cosmetic composition, and when the cosmetic composition is used as a lotion, the amount of the powder is as described above. 0.1 to 1% with respect to the total weight of the cosmetic composition, and when used as a cosmetic emulsion, the compounding amount of the powder is 1 to 3% with respect to the total weight of the cosmetic composition. When used as a cream, the amount of the powder is preferably 3 to 15% with respect to the total weight of the cosmetic composition.
また、上記化粧料組成物を化粧用ジエルとして使用する場合は、粉末の配合衋が上 記化粧料組成物の全重量に関して 5~8%であり、 化粧用エッセンスとして使用する場 合は、 粉末の配合量が上記化粧料組成物の全重量に関して 0. 1 ~2%であり、 パック 用組成物として使用する場合は、 粉末の配合量が上記化粧料組成物の全重量に関して 8 〜50%であり、 ファンデ一ションに代表される粉末状メ一キヤップ化粧品として使用 する場合は、 粉末の配合量が上記化粧料組成物の全重量に関して 6~ 35%であること が好ましい。  When the cosmetic composition is used as a cosmetic jewel, the content of the powder is 5 to 8% based on the total weight of the cosmetic composition, and when the cosmetic composition is used as a cosmetic essence, the powder Is 0.1 to 2% with respect to the total weight of the cosmetic composition, and when used as a pack composition, the powder is 8 to 50% with respect to the total weight of the cosmetic composition. When used as a powdery makeup cosmetic represented by a foundation, the amount of the powder is preferably 6 to 35% with respect to the total weight of the cosmetic composition.
さらに、上記化粧料組成物を口紅として使用する場合は、粉末の配合量が上記化粧 料組成物の全重量に関して〇. 5〜2%であり、 毛髪用化粧品として使用する揚合は、 粉末の配合量が上記化粧料組成物の全重量に関して、 0. 1〜2%であり、 ボディ化粧 品として使用する場合は、 粉末の配合量が上記化粧料組成物の全重量に関して、 〇. 1 であることが好ましい。 本発明のさらなる特徴およびそれがもたらす効果は，以下に述べる発明の詳細な説 明および実施例から理解されるだろラ。 発明を実施する めの最良の形態 Furthermore, when the above cosmetic composition is used as a lipstick, the amount of the powder is 配合 0.5 to 2% with respect to the total weight of the above cosmetic composition. The compounding amount is 0.1 to 2% with respect to the total weight of the cosmetic composition, and when used as a body cosmetic, the compounding amount of the powder is 〇.1 with respect to the total weight of the cosmetic composition. Preferably, there is. Further features of the present invention and the effects provided by the same will be understood from the detailed description and examples of the invention described below. BEST MODE FOR CARRYING OUT THE INVENTION
以下に本発明の化粧料組成物について詳細に説明する。  Hereinafter, the cosmetic composition of the present invention will be described in detail.
本発明の化粧料組成物は、少なくとも大豆を単細胞に分離して得られる単細胞粉末 を含有することを特徴とする。 し がって、 大豆の単細胞粉末だけでなく、 大豆単細胞 粉末とえんどう豆のような他の豆類の粉末との混合物を使用してちよい。  The cosmetic composition of the present invention is characterized by containing at least a single-cell powder obtained by separating soybean into single cells. Thus, not only single cell powder of soy, but also a mixture of single cell powder of soy and other legume powders such as peas may be used.
本発明に使用される大豆の単細胞粉末は、その各 において大豆細胞壁の損傷がほ とんどないか、 もしくは非常に軽微であって、 その細胞壁によって大豆細胞内成分を安 定に保持していればよく、 その製造方法は特に限定されない。 例えば、 Bacillus属の微 生物が産生するぺクチナーゼを用い 酵素処理により原料大豆を個 の単細胞に分離し て得られる粉末を使用することが、 品質の良い単細胞粉末を高い収率で得る観点から推 奨される。  The soybean single-cell powder used in the present invention has little or very little damage to the soybean cell wall in each case, and the soybean cell component is stably retained by the cell wall. The production method is not particularly limited. For example, using powder obtained by separating raw soybeans into individual single cells by enzymatic treatment using actinase produced by microorganisms of the genus Bacillus is considered from the viewpoint of obtaining high-quality single-cell powder in high yield. Recommended.
この酵素処理については、すでに国際公開番号 W0011へ 0242の明細書に記載さ れているので、 ここではその詳細な説明を省略するが、 簡単に言うと、 大豆を水に所定 時間浸潰し 後、 蒸煮のように水の存在下で大豆を加熱する。 加熱した大豆を冷却し、 次いで、 水と Bacillus属の微生物が産生するぺクチナーゼを大豆に添加し、 得られだ混 合物を所定時間攪拌する。 この酵素処理により、 大豆の単細胞が分散するスラリーが得 られる。 ぺクチナーゼを失活させて酵素処理を完了した後、 得られたスラリーをスプレ 一ドライヤー等の乾燥法により乾燥すれば大豆の単細胞粉末が得られる。  This enzymatic treatment has already been described in the specification of International Publication No. W0011 to 0242, so a detailed description thereof will be omitted here, but in short, after soybeans are immersed in water for a predetermined time, Heat soybeans in the presence of water, like steaming. The heated soybean is cooled, and then water and a pectinase produced by a microorganism of the genus Bacillus are added to the soybean, and the resulting mixture is stirred for a predetermined time. By this enzyme treatment, a slurry in which single cells of soybean are dispersed is obtained. After the enzyme treatment is completed by inactivating the pectinase, the obtained slurry is dried by a drying method such as a spray drier to obtain single-cell soybean powder.
上記方法によって得られた大豆の単細胞粉末は、細胞間を接合するだめの細胞間物 質のみが酵素処理によって破壊もしくは分解されるので、 個 の大豆細胞の細胞膜は健 全な状態に保だれている。 その結果、 大豆の単細胞粉末には、 大豆特有の匂いがほとん どない。 また、 分離され 個 の大豆細胞内に蓄えられだ水分として定義されるセルゥ オーター Ίま蒸散しにくく優れだ保水性を発揮する。この大豆の単細胞粉末を化粧料組成 物に配合する場合、 以下に述べるように、 従来にない皮膚への密着感、 長時間使用後に おける肌の乾燥感防止等の多ぐの面で極めて優れ 効果が得られる。  In the single-cell soybean powder obtained by the above method, only the intercellular substance that binds the cells is destroyed or decomposed by enzymatic treatment, so that the cell membrane of each soybean cell is kept in a healthy state. I have. As a result, the soybean single-cell powder has almost no soy-specific odor. In addition, it exhibits excellent water retention that is less likely to evaporate from cell to water, which is defined as water separated and stored in individual soybean cells. When this soybean single-cell powder is blended into a cosmetic composition, as described below, it is extremely excellent in many aspects such as unprecedented feeling of adhesion to the skin and prevention of dryness of the skin after long-term use. Is obtained.
すなわち、 大豆は、 蛋白質、 糖質、 脂質、 ビタミン E、 レシチン、 およびイソフラ ボン等をバランスよく含 天然素材であることはよく知られているが、 特に、 大豆に豊 富に含まれるビタミン Eは抗酸化作用を有し、 細胞の老化を防ぐとともに、 紫外線ゆ乾 燥から肌を守るスキンケア成分としての機能を発揮する。 また、 大豆に含まれるレシチ ンも、 細胞膜の働きを正常にして老化防止ゆ肌の若返り効果をも らす。 さらに、 近年 注目を集め、 大豆に含まれるイソフラボンは美白 ·細胞活性 ·抗酸化作用を有する。 こ れらの成分は大豆から抽出して得られる成分であるが、 レシチンゆイソフラボン等を大 豆から抽出する方法が複雑であるため高価であり、 これらの成分をバランスよく含 化 粧料は とえ製造したとしても極めて高価なものとなってしまう。 That is, it is well known that soy is a natural material containing protein, carbohydrate, lipid, vitamin E, lecithin, isoflavone, etc. in a well-balanced manner. Vitamin E, which is contained in wealth, has an antioxidant effect, prevents cell aging, and also functions as a skin care ingredient that protects the skin from ultraviolet drying. In addition, lecithin contained in soybeans also has the effect of normalizing the function of cell membranes, preventing aging and rejuvenating the skin. Furthermore, in recent years, isoflavones contained in soybeans have attracted attention and have whitening, cell activity and antioxidant effects. These components are obtained by extracting from soybeans.However, since the method of extracting lecithin and isoflavone from soybeans is complicated, they are expensive, and cosmetics containing these components in a well-balanced manner are difficult to obtain. Even if it is manufactured, it becomes extremely expensive.
しかしながら、本発明の化粧料組成物によれば、原料大豆を単細胞に分離して得ら れる粉末を含有するので、 脂質ゆビタミン Eに加えて前記スキンケアに有効な高価な成 分を大豆細胞本来の成分バランスのままで配合することができる。 し がって、 大豆か らの個 の特定成分の抽出等の特別な操作を必要とすることなく、 大豆に含まれるスキ ンケア成分をバランスよく含み、 コス卜パフォーマンスに優れ、 なお且つ皮膚への密着 感の向上や保湿効果を改善した化粧料組成物を提供することが可能となる。  However, according to the cosmetic composition of the present invention, since the raw material soybean contains a powder obtained by separating the soybean into single cells, the soybean cell originally contains an expensive component effective for skin care in addition to lipid soybean vitamin E. Can be blended while maintaining the component balance. Therefore, it does not require special operations such as extraction of individual components from soybeans, and it contains skincare components contained in soybeans in a well-balanced manner, has excellent cost performance, and has excellent skin performance. It is possible to provide a cosmetic composition having an improved adhesion and an improved moisturizing effect.
本発明の化粧料組成物はスキンケア化粧品としての使用に適している。スキンケア 化粧品の目的は皮膚を清潔にし、 最外層の角質層を十分に保水させることにある。 角質 層は、 角質細胞 （ケラチノサイ卜） により構成されているが、 通常の細胞とは異なり、 核をはじめ種 の細胞内小器官が消失し、 ケラチンと呼ばれる線維性タンパクで細胞内 のほとんどが満たされている。 また、 細胞膜も細胞の内側からタンパクが強固な架橋構 造によって結合し、 強靭な角質肥厚膜を形成し、 皮膚を構成している。  The cosmetic composition of the present invention is suitable for use as a skin care cosmetic. Skin care The purpose of cosmetics is to cleanse the skin and keep the outermost stratum corneum well-watered. The stratum corneum is composed of keratinocytes (keratinocytes), but unlike normal cells, the nucleus and other organelles of the species are lost, and most of the cells are filled with fibrous proteins called keratin. Have been. In the cell membrane, proteins are bound from the inside of the cell by a strong cross-linking structure, forming a tough keratinous hyperplasia and constituting the skin.
本願発明者らは、スキンケア化粧品の基材として大豆単細胞が他の植物単細胞の使 用によっては達成できない多くの画期的な有効性、 一例を挙げれば、 大豆単細胞の細胞 膜組成が角化細胞膜とほぽ類似しており、 その相溶性がきわめて良好であるため、 皮膚 への密着感を向上させると同時に、 大豆単細胞中の結合水が角質層の保湿効果を大ぎく 改善することができることを見出して発明の完成に至ったものである。  The present inventors have found that soybean single cells as a base material for skin care cosmetics have many innovative effects that cannot be achieved by using other plant single cells, for example, the cell membrane composition of soybean single cells is a keratinized cell membrane It is very similar and has very good compatibility, so that it can improve the feeling of adhesion to the skin and at the same time, the bound water in soybean single cells can greatly improve the moisturizing effect of the stratum corneum. It was found that the invention was completed.
まだ、本発明の化粧料組成物は粉末状メーキヤップ化粧品としての使用にも適して いる。 メ一キャップ化粧品には所定量のタルクが含まれている。'タルクは、 粉末状メー キャップ化粧料組成物の使用時に肌上でのすべり感を与えるという重要な効果を有する 反面、 吸油量および吸水量が高いという問題がある。 すなわち、 タルクの高い吸油量の だめ、 従来は粉末固形メーキヤップ化粧料組成物の成形性を確保するために結合剤の使 用が必須となってい 。 また、 タルクの高い吸水量は、 粉末状メーキャップ化粧料組成 物の使用時および使用後に肌の乾燥感を生じさせる原因となる。 このよ に、 肌上での 良好なすべり感を提供する めにタルクの使用は重要であるが、 結合剤の必要性ゆ肌乾 燥感の抑制の観点からはその使用量をいかに低減するかが課題となる。 Still, the cosmetic composition of the present invention is suitable for use as a powdery makeup cosmetic. Makeup cosmetics contain a certain amount of talc. 'Talc has an important effect of giving a slippery feeling on the skin when the powdery makeup cosmetic composition is used, but has a problem of high oil absorption and water absorption. That is, the use of a binder is indispensable in order to ensure high oil absorption of talc and to ensure the moldability of a powdered solid makeup cosmetic composition. In addition, the high water absorption of talc is due to the powdered makeup cosmetic composition It causes dry feeling of the skin at the time of use and after use. As described above, it is important to use talc to provide a good slipperiness on the skin, but how to reduce the amount of talc used from the viewpoint of the need for a binder and the suppression of skin dryness Is an issue.
そこで、本発明者らは、粉末状メーキャップ化粧料組成物に大豆の単細胞粉末を添 加することによって、 上記課題をも顕著に改善できることを見出して発明の完成に至つ ものである。 すなわち、 本発明者らは、 大豆の単細胞粉末がタルクに匹敵する肌上で のすベり感を提供し、 タルクの一部もしくは大部分を大豆の単細胞粉末で置き換えるこ とができることを見出した。 ま 、 大豆の単細胞粉末の個 の細胞内に蓄えられたセル ウォーターによる保水効果が、 タルクにより生じる肌乾燥感を抑制する。 し がって、 タルク配合衋の減少によって肌乾燥感を抑制するだけでなく、 大豆単細胞の持つ保水性 によって肌乾燥感がより一層抑制されるのである。 さらに、 本発明者らは、 大豆の単細 胞粉末を使用することによって、 もはや粉末固形メーキヤップ化粧料組成物を成形する ための結合剤を一切使用することなく、 所望の成形性が得られることも見出し 。 この 効果は、 結合剤を必須としてきた粉末固形メーキャップ化粧料組成物にとっては革命的 ともいえるものである。  The present inventors have found that the above-mentioned problems can be remarkably improved by adding soybean single-cell powder to the powdery makeup cosmetic composition, and have completed the invention. That is, the present inventors have found that soybean single-cell powder provides slipperiness on skin comparable to that of talc, and that part or most of talc can be replaced with soybean single-cell powder. . In addition, the water retention effect of the cell water stored in the individual cells of the single cell powder of soybean suppresses the feeling of dry skin caused by talc. Therefore, not only is skin sensation suppressed by reducing the amount of talc 肌, but also skin sensation is further suppressed by the water retention of soybean single cells. In addition, the present inventors have found that the use of soybean cell powder enables the desired moldability to be obtained without using any binder for forming the powdered solid makeup cosmetic composition. No headline. This effect can be said to be revolutionary for a powdered solid makeup cosmetic composition which has required a binder.
これによつて、メーキヤップゅスキンケア等の化粧料組成物本来の目的ではなく、 その成形性確保の めに添加されてき 結合剤成分を排除し、 従来に比してメーキヤッ プゃスキンケアに有効な成分の含有量を大幅に高めることができるよラになつ 。 尚、 これらの効果は、 ニンジン、 アロエ、 フリージア、 イリス根等の他の植物の単細胞粉末 を使用することによっては得られない大豆の単細胞粉末を化粧料組成物に含有させるこ とによってのみもだらされる本発明に固有の効果である。 このよ 5に、本発明によれば、 大豆を単細胞に分離して得られる粉末を含有し、 スクヮラン、 イソオクタン酸イソセチ ル、 ィソステアリン酸等の結合剤を含有しないひ \'ィンダーフリ一の)化粧料組成物を提 供することができる。  This removes the binder component, which is not the original purpose of the makeup composition such as makeup and skin care, but is added to ensure its moldability, and is more effective for makeup and skin care than before. The content can be greatly increased. It should be noted that these effects can be achieved only by adding soybean single-cell powder, which cannot be obtained by using single-cell powder of other plants such as carrot, aloe, freesia, and iris root, to the cosmetic composition. This is an effect unique to the present invention. As described above, according to the present invention, a cosmetic composition containing powder obtained by separating soybeans into single cells and containing no binder such as squalane, isoacetyl isooctanoate, or isostearic acid is used. A composition can be provided.
前記したよ に、本発明の化粧料組成物は、粉末状メーキャップ化粧料組成物とし て使用されることが特に好ましい。 一般に、 皮膚表面は、 核が消失しだ表皮細胞よりな る角質層と、 その細胞間物質、 すなわち、 卜リグリセライド、 コレステロール、 コレス テロールエステル、 スクワレン、 脂肪酸、 セラミト等の皮脂より構成されている。 スキ ンケア化粧品は、皮脂と相溶性の良い油分、界面活性剤と水との乳化組成物を含 ¾ので、 その使用感も保湿効果ち十分に満足できる域に達している。 しかしながら、 粉末状メー キヤップ化粧料組成物は、 その使用目的のためスキンケア化粧品と同じ主成分を使用す ることが実質的に不可能であり、 スキンケア化粧品と同等の機能を粉末状メーキヤップ 化粧料組成物に付与することが課題とされてきた。 As described above, the cosmetic composition of the present invention is particularly preferably used as a powdery makeup cosmetic composition. In general, the skin surface is composed of the stratum corneum consisting of epidermal cells whose nuclei have disappeared and their intercellular substances, that is, sebum such as triglyceride, cholesterol, cholesterol ester, squalene, fatty acids, and ceramites. . Skin care cosmetics contain an oil component having good compatibility with sebum, an emulsified composition of a surfactant and water, and the feeling of use has reached a sufficiently satisfactory range because of the moisturizing effect. However, powder The use of the same main component as skin care cosmetics is virtually impossible for cap cosmetic compositions because of the purpose of use, and the same function as that of skin care cosmetics should be imparted to powdery makeup cosmetic compositions. Has been a challenge.
従来の粉末状メーキャップ化粧料の主原料は、 チタン、 タルク、 マイ力、 シリカ、 亜鉛華等の無機体質顔料と酸化鉄を主体とする有色無機顔料であり、 皮膚表面と良好な 相溶性を有する材料がない。 粉末形状で皮膚表面に相溶性の良い素材を開発するため、 例えば、 無機原料への表面コートゆ有機樹脂粉末などの開発が試みられだが、 いずれも 満足のいく結果を得るには至っていない。 本発明では、 大豆という天然素材を単細胞の 状態で化粧料組成物に添加することによつてこの問題点も解消することに成功し 。  The main raw materials for conventional powdered makeup cosmetics are inorganic extender pigments such as titanium, talc, myriki, silica and zinc white, and colored inorganic pigments mainly composed of iron oxide, and have good compatibility with the skin surface There is no material. In order to develop powdered materials with good compatibility with the skin surface, for example, the development of surface coatings on inorganic raw materials or organic resin powders has been attempted, but none of these have yielded satisfactory results. In the present invention, this problem has been successfully solved by adding a natural material called soybean to the cosmetic composition in a single cell state.
本発明のさらなる目的は、上記したように、大豆の単細胞粉末およびタルクを少な くとも含有してなる化粧料組成物を提供することにあるが、 この化粧料組成物は、 それ 以外にも目的に) ¾じて所定量のマイ力、 セリサイ卜およびカオリン等のパール剤、 チタ ン等の隠蔽剤、 着色顔料、 香料、 防腐剤等を含有することができる。  A further object of the present invention is to provide a cosmetic composition containing at least a single-cell powder of soybean and talc, as described above. In addition, a certain amount of my power, pearling agent such as sericite and kaolin, concealing agent such as titanium, coloring pigment, fragrance, preservative and the like can be contained.
尚、本発明において、大豆の単細胞粉末の配合量は、化粧料組成物の全重量に関し て、 0. 1〜5〇％、 好ましくは 6〜35%である。 配合量が〇. 1 %に満たない時は、 大豆の単細胞粉末の添加効果が +分に得られない恐れがある。 まだ、 配合量が 50%を 越えると、 化粧料組成物をプレス成形する際に大豆油が成形体からにじみ出て、 成形化 粧品としての品質が低下する恐れがある。 配合量が、 6〜3 5%の範囲内である時は、 大豆の単細胞粉末の使用によってもたらされる上記効果を安定して実現でき、 スキンケ ァ化粧品と同等の機能を有する粉末状メーキャップ化粧料組成物を製造するのに最適で ある。  In the present invention, the amount of the single cell powder of soybean is 0.1 to 5%, preferably 6 to 35%, based on the total weight of the cosmetic composition. If the amount is less than 1%, the effect of adding single-cell soybean powder may not be obtained in + minutes. If the blending amount exceeds 50%, soybean oil may ooze out of the molded product during press molding of the cosmetic composition, and the quality of molded cosmetics may be degraded. When the compounding amount is within the range of 6 to 35%, the above-mentioned effect brought about by the use of single-cell soybean powder can be stably realized, and a powdery makeup cosmetic composition having a function equivalent to that of skin care cosmetics. Ideal for manufacturing things.
—方、 タルクの配合矍は、 化粧料組成物 (粉末状メーキャップ化粧料組成物)の全重 量に関して、 1 0〜80%>であり、 目的とする用途によって適宜最適な範囲が設定され る。 例えば、 粉末状メーキャップ化粧料組成物を作製する場合には、 タルクの配合量を 化粧料組成物の全重量に関して 20〜3〇％とすることが特に好ましい。 また、 大豆の 単細胞粉末配合量：タルク配合量の比に関しては、 単細胞粉末：タルクが 2' 1 ' 4の範囲 (実施例 1〜5)とすることが好ましく、 より好ましくは 0. 了〜 1 Ό. 了 (実施例 1〜 4)である。  -On the other hand, the blending of talc is 10% to 80% based on the total weight of the cosmetic composition (powder makeup cosmetic composition), and the optimal range is appropriately set depending on the intended use. . For example, when preparing a powdery makeup cosmetic composition, it is particularly preferable that the blending amount of talc be 20 to 3% by weight based on the total weight of the cosmetic composition. Further, regarding the ratio of the soybean single cell powder blending amount: talc blending amount, the single cell powder: talc ratio is preferably in the range of 2'1'4 (Examples 1 to 5), more preferably 0.1 to 1 Ό. (Examples 1 to 4)
〔実施例〕  〔Example〕
(大豆の単細胞粉末の製造） 本発明の化粧品組成物を作成するため、 P C T出願 WO01 / 0242に記載されて いるのと同様の方法により大豆の単細胞粉末を得 。 すなわち、 1 .1 k gの乾燥大豆を 水洗した後、 水中に 1 2時間浸漬し 。 次に、 漫漬に使用しだ水を捨てることなく、 大 豆を水から引き上げた。 この時、 大豆は水分を吸収して膨潤し、 全重量が 2.2 k gにな つていた。 次に、 圧力鍋を使用して 1 2〇°C、 1 .1 k g/ c m2, Λ 0分間の条件で大 豆を蒸煮した。 蒸煮しだ大豆を 60°Cに冷却しだ後、 浸漬に使用しだ水 2.2 k gおよび 乾燥大豆の重量に関して〇.1 w t %の Bacillus属の微生物が産生したぺクチナ一ゼ (ナ ガセ生化学社製)とを大豆に添加して第 1混合物を得だ。 (Manufacture of single-cell soybean powder) In order to prepare the cosmetic composition of the present invention, a single-cell soybean powder was obtained by the same method as described in PCT application WO01 / 0242. That is, after washing 1.1 kg of dried soybeans with water, they were immersed in water for 12 hours. Next, the soybeans were pulled out of the water without throwing away the water used for manzuke. At this time, the soybeans had absorbed water and had swelled to a total weight of 2.2 kg. Then, 1 2_Rei ° C, 1 .1 kg / cm 2 using a pressure cooker, and cook the soybeans under the conditions of lambda 0 minutes. After cooling the steamed soybeans to 60 ° C, 2.2 kg of water used for immersion and 〇.1 wt% of the weight of dried soybeans. Was added to soybean to obtain a first mixture.
この第 1混合物を攪拌しながら、 60でで 30分間保持することにより酵素処理を 実施した。攪拌は、攪拌翼を 30回転 分の速度で回転させて行つだ。 この酵素処理後、 大豆細胞の単細胞への分離状態を調べる^めに顕微鏡観察を実施し 。 30分の酵素処 理によりほぽ完全に大豆細胞が単細胞に分離されてし）ることが確認され、 酵素処理は 3 〇分行えば十分であった。 顕微鏡観察により、 分離された個々の大豆細胞は、 細胞壁が ほとんどダメージを受けることなく健全な状態にあり、 その分散状態も良好であること を確認しだ。  The enzyme treatment was carried out by holding the first mixture at 60 at 30 for 30 minutes while stirring. The stirring was performed by rotating the stirring blade at a speed of 30 rotations. After this enzyme treatment, microscopic observation was performed to examine the state of separation of soybean cells into single cells. It was confirmed that the soybean cells were almost completely separated into single cells by the enzyme treatment for 30 minutes), and the enzyme treatment for 3 minutes was sufficient. Microscopic observation confirmed that the isolated soybean cells were in a healthy state with almost no damage to the cell wall, and that they were in good dispersion.
このよろにして、 大豆の単細胞が分散するスラリー (液状加工大豆)が得られた。 次 いで、 ぺクチナーゼの酵素作用を失活させるために、 スラリーを 1 0〇°Cで 1 5分間加 熱した。 その後、 このスラリーをスプレードライヤーにより乾燥して本発明の化粧料組 成物製造用の大豆単細胞粉末を得だ。この大豆単細胞粉末の成分分析結果を表 1に示す。 まだ、 大豆単細胞粉末中のイソフラボン成分について定量分析しだ結果を表 2に示す。  Thus, a slurry (liquid processed soybean) in which single cells of soybean were dispersed was obtained. The slurry was then heated at 10 ° C. for 15 minutes to deactivate the enzyme activity of actinase. Thereafter, the slurry was dried with a spray dryer to obtain a soybean single-cell powder for producing the cosmetic composition of the present invention. Table 1 shows the results of component analysis of this soybean single-cell powder. Table 2 shows the results of quantitative analysis of isoflavone components in soybean single-cell powder.
表 1  table 1
成分 大豆単細胞粉末  Ingredients Soy single cell powder
水分 5%慮大）  5% moisture)
タンパク質 40 ± 3%  Protein 40 ± 3%
脂肪分 20 ± 3%  Fat 20 ± 3%
糖質 3 2 ± 3%  Carbohydrate 3 2 ± 3%
灰分 5 ± 2% Ash content 5 ± 2%
H 中性 イソフラボン成分 分析結果 分析方法 H neutral Isoflavone component Analysis result Analysis method
ダイジン 86mg/100g 高速液体クロマ卜グラフ法 ダイゼイン 2.6mg/100g 高速液体クロマ卜グラフ法 ゲニスチン 1 20mg/100 高速液体クロマ卜グラフ法 ゲニスティン 3.5mg/100g 高速液体クロマ卜グラフ法 グリシチン 1 1 mg/100g 高速液体クロマ卜グラフ法 グリシティン 0.5mg/1〇〇g以下 液体クロマ卜グラフー質量分析法  Daizin 86mg / 100g High performance liquid chromatography Daidzein 2.6mg / 100g High performance liquid chromatography Genistin 1 20mg / 100 High performance liquid chromatography Genistin 3.5mg / 100g High performance liquid chromatography Glycitin 1 1mg / 100g High speed Liquid chromatograph method Glycitin 0.5 mg / 1〇〇g or less Liquid chromatograph-mass spectrometry
(実施例 1および比較例 1 ) . (Example 1 and Comparative Example 1).
本発明の化粧料組成物をファンデーションに代表される粉末状メーキャップ化粧 品として使用する場合は、 大豆単細胞粉末の配合量を化粧料組成物の全重量に関して 6 〜3 5%とすることにより、 大豆単細胞粉末を含有させない場合に比べ、 優れ^保湿効 果、 良好な皮膚への密着感、 長時間使用後における肌の乾燥感防止等の複数の効果を粉 末吠メーキャップ化粧品に付与することができる。 このように、 本発明の化粧料組成物 を粉末状メーキヤップ化粧品に使用する場合は、 大豆単細胞粉末の添加効果が特に顕著 に現れるので、 比較例 1〜5と対比しながら、 本発明の実施例 1 ~5に基づく粉末状メ —キャップ化粧品を以下に詳細に説明する。  When the cosmetic composition of the present invention is used as a powdery makeup cosmetic typified by a foundation, the soybean single-cell powder is blended in an amount of 6 to 35% with respect to the total weight of the cosmetic composition, soybean. Compared to the case where single cell powder is not contained, multiple effects such as excellent moisturizing effect, good feeling of adhesion to the skin, and prevention of dryness of the skin after prolonged use can be imparted to powdered makeup makeup. . As described above, when the cosmetic composition of the present invention is used in a powdery make-up cosmetic, the effect of adding soybean single-cell powder is particularly prominent, so that the examples of the present invention are compared with Comparative Examples 1 to 5. The powder cosmetics based on 1 to 5 will be described in detail below.
実施例 1では、 上記した大豆単細胞粉末を使用し、 表 3に示す組成の粉白粉 (ル一 スパウダー)を以下のよろにして製造した。 尚、 粉白粉は、 油分などを配合しないで、 ほ とんどが粉体原料のみで構成される粉末状メーキャップ化粧料である。 まず、 表 3に示 す配合量となるよ 5に、 大豆単細胞粉末、 タルク、 セリサイト、 カオリン、 チタンおよ び着色顔料を計量し、 プレンダ一にて混合した。 これに残りの炭酸マグネシウム、 ミリ スチン酸亜鉛および防腐剤を添加してよく混合し、 調色しだ。 次いで、 香料を嘖霧して 均一に混合した。 得られだ混合物を大豆単細胞が破砕されないようなマイルドな条件で 再度混合攪拌し、 ふるいを通して実施例 1の粉白粉を得た。  In Example 1, the above-mentioned soybean single-cell powder was used to produce a powdered white powder (le-powder) having the composition shown in Table 3 in the following manner. In addition, the powdered white powder is a powdery makeup cosmetic which is almost entirely composed of powdered raw materials without blending oil or the like. First, soybean single-cell powder, talc, sericite, kaolin, titanium, and a coloring pigment were weighed to obtain the blending amount shown in Table 3 and mixed with a blender. The remaining magnesium carbonate, zinc myristate and preservative were added to the mixture, mixed well, and mixed. Next, the fragrance was sprayed and uniformly mixed. The obtained mixture was mixed and stirred again under mild conditions such that the soybean single cells were not crushed, and the white powder of Example 1 was obtained through a sieve.
尚、 大豆単細胞粉末の代りに、タルクの量を増量し、表 3の組成になるように配合 し ことを除いては実施例 1と同様の手順により比較例 1の粉白粉を得た。 表 3 The powder of Comparative Example 1 was obtained by the same procedure as in Example 1 except that the amount of talc was increased in place of the soybean single-cell powder and the talc was added so as to have the composition shown in Table 3. Table 3
Figure imgf000010_0001
Figure imgf000010_0001
(実施例 2および比較例 2) (Example 2 and Comparative Example 2)
実施例 2では、上記しだ大豆単細胞粉末を使用し、表 4に示す組成の固形白粉を製 造しだ。 この固形白粉は、 実施例 1の粉白粉を成形して携帯用とし ものであり、 機能 的には粉白粉とほぽ同じである。 一般に、 粉体を成形する場合は結合剤として約 5%の 油分を配合する必要があるが、 本発明の化粧料組成物は大豆の単細胞粉末を含有してい るので、 そのよ oな結合剤の添加は全く必要なかつだ。  In Example 2, a solid white powder having the composition shown in Table 4 was produced using the above-mentioned single soybean soybean powder. This solid white powder is made by molding the white powder of Example 1 to be portable, and is almost the same in function as the white powder. Generally, when molding powder, it is necessary to incorporate about 5% of oil as a binder, but since the cosmetic composition of the present invention contains a single cell powder of soybean, such a binder is required. Is absolutely necessary.
尚、 大豆単細胞粉末の代りに、 表 4に示すように、 タルク、 セリサイ卜、 カオリン、 チタンの量を増量するとともに、 結合剤として、 スクヮランおよびトリイソオクタン酸 グリセりンをそれぞれ少量添加したことを除いては実施例 2と同様の手順により比較例 2の粉白粉を得だ。  As shown in Table 4, the amounts of talc, sericite, kaolin, and titanium were increased in place of soybean single-cell powder, and small amounts of squalane and glycerin triisooctanoate were added as binders. Except for this point, a white powder of Comparative Example 2 was obtained in the same procedure as in Example 2.
表 4  Table 4
重量％ 実施例 2 比較例 2  % By weight Example 2 Comparative Example 2
大豆単細胞粉末 35. 〇 〇  Soybean single cell powder 35. 〇 〇
タルク 38. 〇 55. 0  Talc 38. 〇 55. 0
セリサイ卜 9. 0 1 5. 0  Sericit 9.00 15.0
カ才リン 5. 0 1 0. 〇  Kasai Rin 5.0 0 1 0.
チタン 3. 〇 5. 0  Titanium 3.〇5.0
炭酸マグネシウム 5. 〇 5. 0  Magnesium carbonate 5.〇 5.0
ミリスチン酸亜鉛 5. 0 5. 〇  Zinc myristate 5.0 0 5.〇
スクヮラン 0 3. 0  Squalane 0 3.0
トリイソオクタン酸グリセリン 〇 2. 0  Glycerin triisooctanoate 〇 2.0
、  ,
着色顔料 週 適  Color pigment Weekly
香料 適量 週¾ϊ  Perfume appropriate amount weekly
防腐剤 適 適 (実施例 3および比較例 3) Preservatives Appropriate (Example 3 and Comparative Example 3)
実施例 3では、上記しだ大豆単細胞粉末を使用し、表 5に示す組成のパウダリーフ アンデ一シヨンを以下のようにして製造しだ。 すなわち、 表 5に示す配合璗となるよう に、 大豆単細胞粉末、 各種処理されたセリサイト、 マイ力、 タルク、 チタンおよび着色 顔料を計量し、 プレンダ一にて混合した。 これに残りのチタン一亜鉛華複合粉体、 ナイ ロンパウダー、 ステアリン酸亜鉛、 防腐剤を添加してよく混合し、 調色しだ。 次いで、 香料を噴霧して均一に混合した。 得られた混合物を大豆単細胞が破砕されないようなマ ィルドな条件で再度混合攪拌し、 ふるいを通して得られた粉末を圧縮成形して実施例 3 のノ \°ゥダリーファンデーションを得た。  In Example 3, the powdered soybean soybean single cell powder was used to produce a powder leaf formulation having the composition shown in Table 5 as follows. That is, soybean single-cell powder, variously treated sericite, myriki, talc, titanium, and a coloring pigment were weighed and mixed with a blender so that the mixing ratio shown in Table 5 was obtained. The remaining titanium-zinc white composite powder, nylon powder, zinc stearate, and preservative were added to the mixture, mixed well, and mixed. Then, the fragrance was sprayed and mixed uniformly. The obtained mixture was mixed and stirred again under a mild condition such that a soybean single cell was not crushed, and the powder obtained through a sieve was compression-molded to obtain the No. 3 daly foundation of Example 3.
一般に、 パウダリーファンデーションは、 肌色補正の観点から、着色顔料や白色顏 料が固形白粉よりも多く配合される。 そのため、 粉体を成形する めの結合剤が固形白 粉よりも多く必要となり、 スクヮランゆ合成エステル油を約 1 096程度配合することが 必要となるが、 本発明の化粧料組成物は大豆の単細胞粉末を含有しているので、 そのよ な結合剤の添加は全く必要なかっ 。 これにより、 今までにない独特のすべり感ゆ密 着感の付与、 およびしっとりした後残り感を提供することが可能になつだ。  In general, the powdery foundation contains more colored pigments and white pigment than solid white powder from the viewpoint of skin color correction. For this reason, a binder for molding the powder is required more than the solid white powder, and it is necessary to add about 1096 of squalane-synthetic ester oil. Since a single cell powder is contained, no additional binder is required. As a result, it is possible to provide an unprecedented unique feeling of slippage and tightness, and to provide a feeling of remaining after moistening.
Figure imgf000011_0001
尚、 大豆単細胞粉末の代りに、表 5に示すように、 シリコーン処理板状タルクを増 量すると共に、 結合剤として、 スクヮラン、 ミリスチン酸ォクチルドデシル、 ジメチル ポリシロキサン、 およびポリエチレンォキサイド付加ジメチルポリシロキサンを合計で
Figure imgf000011_0001
As shown in Table 5, silicon-treated plate-like talc was added instead of soybean single-cell powder. Squalane, octyldodecyl myristate, dimethylpolysiloxane, and polyethylene oxide-added dimethylpolysiloxane as a binder.
1 0. 〇重量％添加したことを除いては実施例 3と同様の手順により比較例 3のパウダ リーファンデーションを得 。 10. A powdery foundation of Comparative Example 3 was obtained in the same procedure as in Example 3 except that 〇% by weight was added.
(実施例 4および比較例 4) (Example 4 and Comparative Example 4)
実施例 4では、上記し 大豆単細胞粉末を使用し、表 6に示す組成のケーキタイプ ファンデーションを以下のようにして製造し 。 すなわち、 表 6に示す配合量となるよ うに、 大豆単細胞粉末、 カオリン、 セリサイト、 タルク、 チタンおよび着色顔料を計量 し、 プレンターにて混合した。 これに残りのチタン一亜鉛華複合粉体、 防腐剤を添加し てよく混合し、 調色し 。 次いで、 香料を噴霧して均一に混合し 。 得られた混合物を 大豆単細胞が破砕されないようなマイルドな条件で再度混合攪拌し、 ふるいを通して得 られだ粉末を圧縮成形して実施例 4のケーキタイプファンデーションを得 。  In Example 4, the above-described soybean single-cell powder was used to produce a cake-type foundation having the composition shown in Table 6 as follows. That is, soybean single-cell powder, kaolin, sericite, talc, titanium and a coloring pigment were weighed and mixed with a planter so that the blending amounts shown in Table 6 were obtained. The remaining titanium-zinc white composite powder and preservative are added to this, mixed well, and toned. Then, the fragrance was sprayed and mixed uniformly. The resulting mixture was mixed and stirred again under mild conditions so that single soybean cells were not crushed, and the obtained powder was compression-molded through a sieve to obtain a cake-type foundation of Example 4.
一般に、ケーキタイプファンデーションとは、水を含ませた海綿ゆスポンジで使用 する固形ファンデーションで、 その清涼感から夏季に多用される。 ウエットスポンジで 取る時、 クリーミーな感触を出すため、 親水性界面活性剤が配合されることが特徴であ る。  In general, a cake-type foundation is a solid foundation used for sponge sponges soaked in water, and is often used in the summer due to its refreshing feeling. When taken with a wet sponge, a hydrophilic surfactant is included to give a creamy feel.
表 6  Table 6
Figure imgf000012_0001
尚、 大豆単細胞粉末の代りに、 表 6に示すように、 タルク、 カオリン、 セリサイト を増量すると共に、 結合剤として、 スクヮラン、 イソオクタン酸イソセチル、 イソステ アリン酸を合計で 1 4. 0重量％添加し ことを除いては実施例 4と同様の手順により 比較例 4のケーキタイブファンデーションを得た。
Figure imgf000012_0001
In addition, as shown in Table 6, talc, kaolin, and sericite were increased in place of soybean single-cell powder, and squalane, isocetyl isooctanoate, and isostelate were used as binders. A cake tie foundation of Comparative Example 4 was obtained in the same manner as in Example 4, except that 14.0% by weight of the total amount of arlic acid was added.
(実施例 5および比較例 5) (Example 5 and Comparative Example 5)
実施例 5では、 上記し 大豆単細胞粉末を使用し、 表 7に示す組成の両用 (デュア ルユース)ファンデーションを以下のようにして製造しだ。 すなわち、 表 7に示す配合量 となるように、 大豆単細胞粉末、 シリコン処理マイ力、 シリコーン処理タルク、 シリコ ーン処理マイ力、 シリコーン処理チタン、 シリコーン処理超微粒子亜鉛華および着色顔 料を計量し、 プレンダ一にて混合した。 これに残りのナイロンパウダー、 ステアリン酸 亜鉛、 固形パラフィンを溶解した卜リイソクタン酸グリセリン、 ジメチルポリシロキサ ン、 防腐剤を添加してよく混合し、 調色し 。 次いで、 香料を噴霧して均一に混合した。 得られ 混合物を大豆単細胞が破砕されないようなマイルドな条件で再度混合攪拌し、 ふるいを通して得られた粉末を圧縮成形して実施例 5の両用ファンデーションを得た。  In Example 5, a so-called single-cell soybean powder was used, and a dual-use foundation having the composition shown in Table 7 was produced as follows. That is, soybean single-cell powder, silicon-treated My power, silicone-treated talc, silicone-treated My power, silicon-treated titanium, silicone-treated ultrafine zinc powder and colored pigment were weighed so that the blending amounts shown in Table 7 were obtained. And blended in a blender. The remaining nylon powder, zinc stearate, glycerin triisooctanoate in which solid paraffin is dissolved, dimethylpolysiloxane, and a preservative are added to the mixture, mixed well, and toned. Then, the fragrance was sprayed and mixed uniformly. The obtained mixture was mixed and stirred again under mild conditions such that the soybean single cells were not crushed, and the powder obtained through a sieve was compression-molded to obtain a dual-use foundation of Example 5.
両用ファンデーションとは、パウダリーファンデーションとケーキタイプファンデ ーシヨンの両方の機能を有し、 乾いたスポンジでも水で湿らせ スポンジでも使用でき ることからそう呼ばれている。現在では、サマーファンデーションの主流となっている。  The dual-use foundation is so-called because it has the functions of both a powdery foundation and a cake-type foundation, and can be used with either dry sponge or water sponge. At present, it is the mainstream of the summer foundation.
表 7  Table 7
Figure imgf000013_0001
尚、 大豆単細胞粉末の代りに、 表了に示すように、 卜リイソクタン酸グリセリンを 増量すると共に、 結合剤として、 スクヮランを 4. 0重量％添加したことを除いては実 施例 5と同様の手順により比較例 5の両用ファンデ一ションを得だ。
Figure imgf000013_0001
In addition, instead of soybean single-cell powder, glycerin triisooctanoate was used as shown in the table. A dual-use foundation of Comparative Example 5 was obtained by the same procedure as in Example 5 except that the amount was increased and squalane was added as a binder at 4.0% by weight.
(評価方 ¾) (Evaluation method ¾)
上記した実施例 1 ~ 5および比較例 1〜 5の化粧料組成物の使用感を評価するた め、 試験者である 1〇人の女性にそれぞれの化粧料組成物をハーフフェイス法で使用し てちらい、 使用中および 5時間経過後の使用感についてアンケー卜をとつだ。 ここで、 ハーフフェイス法とは、各試験者に顔の半分に実施例の化粧料組成物を使用してもらい、 顔のも 半分に比較例の化粧料組成物をしてもら ことで実施例と比較例の化粧料組成 物を同時に評価する方法を言う。 尚、 試験は、 同一の洗顔料を用い 泡による 5分間先 顔行って肌条件を一定化した後実施した。 また、 明確な評価を得るために、 プレメーキ ャップ乳液ゆクリ一ムなどその他の化粧品は一切使用しなかった。 評価は以下の項目に ついて行った。  In order to evaluate the feeling of use of the cosmetic compositions of Examples 1 to 5 and Comparative Examples 1 to 5 described above, each of the cosmetic compositions was applied to one hundred and fifty women who were testers by the half-face method. A questionnaire was given on the feeling of use during use and after 5 hours. Here, the half-face method means that each examiner uses the cosmetic composition of the example in half of the face and the cosmetic composition of the comparative example in half of the face. And a method for simultaneously evaluating the cosmetic compositions of Comparative Examples. The test was performed after the same facial cleanser was used for 5 minutes with foam and the face was fixed to make the skin condition constant. In addition, no other cosmetics such as pre-makeup milky lotion were used for clear evaluation. The following items were evaluated.
( 1 ) 化粧料組成物の化粧用具による取出し容易性  (1) Ease of removing cosmetic compositions with cosmetic tools
粉白粉および固形白粉を取り出すための化粧用具としては、一般に使用されている パフを用い、 ファンデーションの使用用具としては水なしスポンジパフを用いた。 各試 験者は、 化粧料組成物の化粧用具による取出性が良いと感じた揚合は 2点、 普通である と感じた場合は 1点、 取り出し難いと感じた場合は〇点を所定の用紙に記入する。  A commonly used puff was used as a cosmetic tool for removing powdered white powder and solid white powder, and a sponge puff without water was used as a tool for using the foundation. Each tester indicated that the cosmetic composition had good removability with cosmetic tools, 2 points for the test, 1 point for the average, and 〇 for the difficulties. Fill in.
(2) 化粧料組成物の肌上での伸び  (2) Elongation of the cosmetic composition on the skin
各試,験者は、化粧料組成物の肌上での伸びが良いと感じ 揚合は 2点、普通である と感じ 場合は 1点、 伸びが悪いと感じた場合は 0点を所定の用紙に記入する。  Each tester and tester felt that the cosmetic composition had good growth on the skin, 2 points for lifting, 1 point for normal, and 0 point for poor growth on the specified paper. Fill in.
( 3) 化粧料組成物の肌上での密着感 (付着感）  (3) Feeling of adhesion of the cosmetic composition on the skin (adhesion)
各試験者は、化粧料組成物の肌上での密着感が良いと感じだ場合は 2点、普通であ ると感じ 場合は 1点、 伸びが悪いと感じ 場合は〇点を所定の用紙に記入する。  Each tester gives 2 points if the cosmetic composition feels good on the skin, 1 point if it feels normal, and 〇 point if it does not stretch well on the specified paper. Fill in.
(4) 化粧料組成物の肌上での粉浮きの有無  (4) Whether the cosmetic composition has powder floating on the skin
各試験者は、化粧料組成物の肌上での粉浮きが無いと感じ 場合は 2点、普通であ ると感じた場合は 1点、 粉浮きが有る場合は 0点を所定の用紙に記入する。  Each tester puts 2 points on the prescribed paper when the cosmetic composition does not feel powder floating on the skin, 1 point when the cosmetic composition feels normal, and 0 point when the cosmetic composition has powder floating. Fill out.
( 5 ) 使用 5時間後の肌上での粉浮きの有無  (5) Existence of powder floating on the skin 5 hours after use
各試験者は、使用 5時間経過後、化粧料組成物の肌上での粉浮きが無いと感じた揚 合は 2点、 普通であると感じ 場合は 1点、 粉浮きが有る場合は 0点を所定の用紙に記 入する。 After 5 hours of use, each tester felt that the cosmetic composition had no powder floating on the skin, 2 points if it felt normal, 1 point if it felt normal, and 0 if it had powder floating. Write the points on the specified paper Enter.
(6) 使用 5時間後の肌上での油浮きの有無  (6) Oil floating on the skin 5 hours after use
各試験者は、使用 5時間経過後、化粧料組成物の肌上での油浮きが無いと感じ 揚 合は 2点、 普通であると感じ 場合は 1点、 油浮きが有る場合は〇点を所定の用紙に記 入する。  After 5 hours of use, each tester feels that there is no oil floating on the skin of the cosmetic composition, 2 points for lifting, 1 point for normal feeling, and 〇 point for oil floating. On the designated paper.
(7) 使用 5時間後における化粧料組成物の肌上での密着感 (付着感）  (7) Feeling of close contact of the cosmetic composition on the skin 5 hours after use (feeling of adhesion)
各試験者は、使用 5時間経過後、化粧料組成物の肌上での密着感が良いと感じだ場 合は 2点、 普通であると感じ 場合は 1点、 密着感が悪いと感じ 揚合は 0点を所定の 用紙に記入する。  After 5 hours of use, each tester feels that the cosmetic composition has good adhesion on the skin, 2 points; normal, 1 point; If not, write 0 points on the specified form.
(8) 使用 5時間後における肌のしっとり感の有無  (8) Moist feeling of skin 5 hours after use
各試験者は、化粧料組成物の使用 5時間経過後、肌のしっとり感が有る場合は 2点、 普通であると感じ 場合は 1点、 しっとり感が無いと感じた場合は〇点を所定の用紙に 記入する。  After 5 hours of use of the cosmetic composition, each tester gives 2 points if the skin feels moist, 1 point if it feels normal, and 〇 point if it does not feel moist Fill out the form.
(9) 使用 5時間後における肌のかさつき感の有無  (9) Whether the skin feels dry after 5 hours
各試験者は、化粧料組成物の使用 5時間経過後、肌のかさつき感が無い場合は 2点、 普通であると感じだ場合は 1点、 かさつき感が有ると感じた場合は 0点を所定の用紙に 記入する  After 5 hours of use of the cosmetic composition, each tester gave 2 points if the skin did not feel dry, 1 point if it felt normal, and 0 point if it felt dry. Fill out the form
(結果） (Result)
各評価項目について試験者が出した得点の合計点を表 8に示す。表 8の結果からわ かるように、 大豆の単細胞粉末を含有する本発明の化粧料組成物は、 すべての評価項目 において大豆の単細胞粉末を含まないものに比して優れており、 特に 5時間後の使用感 に関して比較品との間の差が大きいことがわかる。 Table 8 shows the total points scored by the tester for each evaluation item. As can be seen from the results in Table 8, the cosmetic composition of the present invention containing the single-cell powder of soybean was excellent in all the evaluation items as compared with the composition not containing the single-cell powder of soybean, and in particular, 5 hours. It can be seen that there is a large difference between the comparative product and the later use feeling.
表 8 Table 8
評価項目 粉白粉 固形白粉 パウダ- ケーキタイ ファンデー 実施例 比較例 実施例 比較例 実施例 比較例 実施例 比 Evaluation item White powder Solid white powder Powder-Cake Tie Foundation Day Example Comparative Example Example Comparative Example Example Comparative Example Example Ratio
1 1 2 2 3 3 4 4 使用中の 取り出し性 1 5 1 1〇 1 0 1 5 1 4 1 4 1 使用感 肌上での伸び 1 6 1 5 1 8 1 0 1 1 1 1 1 0 1 密着感 1 8 1〇 1 9 1〇 1 5 1 4 1 3 1 粉浮の有無 1 7 了 1 7 5 1 3 1 3 . 1 3 11 1 2 2 3 3 4 4 Removability during use 1 5 1 1〇 1 0 1 5 1 4 1 4 1 Usability Elongation on skin 1 6 1 5 1 8 1 0 1 1 1 1 1 0 1 Feeling 1 8 1〇 1 9 1〇 1 5 1 4 1 3 1 Presence or absence of powder floating 1 7 End 1 7 5 1 3 1 3 .1 3 1
5時間使 粉浮の有無 1 5 1〇 1 6 5 1 6 6 1 5 7 用後の使 /由/ナ ≤ 1 9 8 1 9 6 1 8 4 1 7 3 用感 密着感 1 8 7 1 9 7 1 9 8 1 8 7 しっとり感 1 9 3 1 9 1 9 6 1 9 4 かさつき感 1 9 4 1 9 6 20 4 1 9 4 Use for 5 hours Presence or absence of powder floating 1 5 1〇 1 6 5 1 6 6 1 5 7 Use after use / free / na ≤ 1 9 8 1 9 6 1 8 4 1 7 3 Feeling Adhesion 1 8 7 1 9 7 1 9 8 1 8 7 Moist 1 9 3 1 9 1 9 6 1 9 4 Bulk 1 9 4 1 9 6 20 4 1 9 4
(実施例 6) (Example 6)
本発明の化粧料組成物を洗顔料として使用する場合は、大豆単細胞粉末の配合量を 化粧料組成物の全重量に関して 5~ 1 5%とすることにより、 大豆単細胞粉末を含有さ せない揚合に比べ、 クリーミイな泡立ち、 洗顔後のッッパリ感の無さ、 及びしっとりし た保湿効果の持続とし、う効果を洗顔剤に付与できることが実験で確認されている。 ここ では、 その一例を紹介する。  When the cosmetic composition of the present invention is used as a face wash, the blending amount of the soybean single-cell powder is set to 5 to 15% with respect to the total weight of the cosmetic composition, so that the soybean single-cell powder is not contained. Experiments have shown that, compared to the case, it is possible to impart a cleansing foam to the cleansing agent by maintaining a moisturizing effect and a moisturizing effect without a feeling of freshness after washing the face. Here is an example.
上記し 7£大豆単細胞粉末を使用し、表 9に示す組成の洗顔料を以下のようにして製 造した。 すなわち、 精製水に保湿材および大豆単細胞粉末を添加分散溶解後に N—ァシ ルグルタミン酸ソーダを"ままこ Ίこならないように少量ずつ添加し 。 キレ一ト剤添加 後、 加熱攪拌しながら分散溶解させた。 同時に、 別釜にペンタエリスリ卜一ルーテ卜ラ 一 2—ェチルへキサノエ一卜、 その他の界面活性剤、 防腐剤を加熱溶解し水相に添加し た。 攪拌混合後、 香料を添加して十分に混合し、 脱気後、 熱交換器で室温まで冷却して 本実施例の弱酸性洗顔料を得た。  Using the soybean single cell powder as described above, a face wash having the composition shown in Table 9 was produced as follows. That is, after adding a humectant and soybean single cell powder to purified water, dispersing and dissolving, sodium N-acyl glutamate was added little by little so as not to be left as it was. After adding the chelating agent, dispersing and dissolving while heating and stirring. At the same time, pentaerythritol-lutetra-12-ethylhexanoet, other surfactants and preservatives were heated and dissolved in a separate kettle and added to the aqueous phase. After sufficiently degassing, the mixture was cooled to room temperature with a heat exchanger to obtain a weakly acidic face wash of this example.
表 9 Table 9
Figure imgf000017_0001
Figure imgf000017_0001
(実施例 7) (Example 7)
. 本発明の化粧料組成物を化粧水として使用する場合は、大豆単細胞粉末の配合量を 化粧料組成物の全重量に関して 0. 1 ~ 1 %とすることにより、 大豆単細胞粉末を含有 させない場合に比べ、 使用中の肌への密着感、 使用後のかさつき感の無さ、 及びしつと りした保湿効果の持続とし、 効果を化粧水に付与できることが実験で確認されている。 ：では、 そ 一例を紹介する。 When the cosmetic composition of the present invention is used as a lotion, the amount of soybean single cell powder is 0.1 to 1% with respect to the total weight of the cosmetic composition so that the soybean single cell powder is not contained. Experiments have confirmed that compared to, skin lotion can be given the effect by using it as a feeling of close contact with the skin during use, no bulky feeling after use, and a sustained moisturizing effect. : Let me introduce an example.
上記した大豆単細胞粉末を使用し、表 1 0に示す組成の化粧水を以下のようにして 製造した。 すなわち、 精製水に保湿剤、 p H緩衝剤、 及び大豆単細胞粉末を室温下で溶 解混合した。 一方、 エタノールにオリ—プ油、 界面活性剤、 防腐剤、 香料を加え室温下 で溶解した。 このアルコール相を前述の水相に添加し、 ホモジナイザーで乳化し、 本実 施例の半透明マイクロエマルシヨン化粧水を得た。  Using the soybean single-cell powder described above, a lotion having the composition shown in Table 10 was produced as follows. That is, a humectant, a pH buffer, and soybean single cell powder were dissolved and mixed in purified water at room temperature. On the other hand, olive oil, surfactant, preservative, and fragrance were added to ethanol and dissolved at room temperature. This alcohol phase was added to the above-mentioned aqueous phase and emulsified with a homogenizer to obtain a translucent microemulsion lotion of this example.
表 1〇  Table 1〇
Figure imgf000018_0001
Figure imgf000018_0001
(実施例 8) (Example 8)
本発明の化粧料組成物を乳液として使用する場合は、大豆単細胞粉末の配合量を化 粧料組成物の全重量に関して 1 ~3%とすることにより、 大豆単細胞粉末を含有させな い場合に比べ、 使用中の肌への伸びの良さと、 それに伴う肌への浸透感及び密着感、 使 用後のベとつき感の無さ、 及びしっとりしだ保湿効果の持続という効果を乳液に付与で きることが実験で確認されている。 ここでは、 その一例を紹介する。  When the cosmetic composition of the present invention is used as an emulsion, the amount of the soybean single-cell powder is adjusted to 1 to 3% with respect to the total weight of the cosmetic composition so that the soybean single-cell powder is not contained. Compared to the emulsion, the effect of good stretch on the skin during use, and the accompanying feeling of penetration and adhesion to the skin, the lack of stickiness after use, and the sustained moisturizing effect are given to the emulsion. Experiments have confirmed that this is possible. Here are some examples.
上記し 大豆単細胞粉末を使用し、表 1 1に示す組成の OZW型乳液を以下のよ にして製造し 。 すなわち、 精製水に、 保湿剤、 防腐剤、 及び大豆単細胞粉末を加え、 加熱溶解混合しだちのに高分子を加え室温で溶解し 。 これに水酸化カリウムを加えた ものを水相とした。 これに室温で均一混合した油分、香料を添加して乳化し 。 次いで、 ホモミキサーにて乳化粒子を均一に調整した後、 脱気して本実施例の 0/W型乳液を得 た。 表 1 1 Using the soybean single cell powder described above, an OZW type emulsion having the composition shown in Table 11 was produced as follows. That is, a humectant, a preservative, and a soybean single-cell powder were added to purified water, and a polymer was added to the mixture after heating and mixing, and the mixture was dissolved at room temperature. The aqueous phase was obtained by adding potassium hydroxide to this. The oil and fragrance uniformly mixed at room temperature were added to the mixture and emulsified. Next, the emulsified particles were uniformly adjusted with a homomixer, and then deaerated to obtain a 0 / W emulsion of the present example. Table 11
Figure imgf000019_0001
Figure imgf000019_0001
(実施例 9) (Example 9)
実施例 8では、本発明の乳液の一例として、 OZW型乳液について紹介したが、 こ こでは、 WZO型乳液の一例について紹介する。  In Example 8, an OZW type emulsion was introduced as an example of the emulsion of the present invention. Here, an example of a WZO type emulsion will be introduced.
上記した大豆単細胞粉末を使用し、表 1 2に示す組成の WZO型乳液を以下のよう にして製造した。 すなわち、 精製水に、 保湿剤、 及び大豆単細胞粉末を加え、 了 0°Cに て加熱混合した。 油性分を加熱溶解した後、 界面活性剤、 防腐剤、 香料を加えて了 0°C に調製した。 この油相を攪拌しながら、 先に調整した水相を徐々に加え、 予備乳化を行 つた。 次いで、 ホモミキサーにて乳化粒子を均一に調整し 後、 脱気、 冷却して本実施 例の WZO型乳液を得た。  Using the above-mentioned soybean single-cell powder, a WZO-type emulsion having the composition shown in Table 12 was produced as follows. That is, a humectant and soybean single-cell powder were added to purified water, and heated and mixed at 0 ° C. After heating and dissolving the oily components, surfactants, preservatives, and fragrances were added to adjust the temperature to 0 ° C. While the oil phase was being stirred, the previously adjusted aqueous phase was gradually added to perform pre-emulsification. Next, the emulsified particles were uniformly adjusted using a homomixer, and then deaerated and cooled to obtain a WZO-type emulsion of this example.
表 1 2  Table 1 2
( 零。ハ 実施例 9 大豆単細胞粉末 1 . 〇 マイクロクりスタリンワックス 1 . 〇  (Zero. C Example 9 Soybean single cell powder 1. 〇 Microcrystalline starch wax 1. 〇
2. 0 ラノ uン 2. 0 流動パラフィン 20. 0 スクヮラン 1〇. 0 ジプロピレングリコール 6. 0 ソルビタンセスキォレイン酸エステル 4. 〇 ポリオキシエチレン一 20—ソルピタンモノォレイン酸エステル 1 . 0 防腐剤 0. 2 香料 0. 1 精製水 残余 (実施例 1〇） 2.0 Lanano 2.0 Liquid paraffin 20.0 Squalane 1.0 Dipropylene glycol 6.0 Sorbitan sesquioleate 4.0 Polyoxyethylene 20-sorbitan monooleate 1.0 Preservative 0.2 Fragrance 0.1 Purified water Residue (Example 1)
本発明の化粧料組成物をクリームとして使用する場合は、大豆単細胞粉末の配合量 を化粧料組成物の全重量に関して 3〜 5%とすることにより、 大豆単細胞粉末を含有さ せない場合に比べ、 使用前のクリームの指取れの良さ、 使用中め肌への伸びの良さ、 そ れに伴う肌への浸透感及び密着感、 使用後のベたつき感の無さ、 及びしっとり、 すべす べした保湿効果の持続とし う効果をクリ一ムに付与できることが実験で確認されている。 ここでは、 その一例を紹介する。  When the cosmetic composition of the present invention is used as a cream, the amount of the soybean single-cell powder is set to 3 to 5% with respect to the total weight of the cosmetic composition, so that the soybean single-cell powder is not contained. , Good cream fingeriness before use, good stretch to the middle skin during use, a feeling of penetration and adhesion to the skin with it, no stickiness after use, and moist and smooth Experiments have confirmed that the cream can be given the effect of maintaining the moisturizing effect. Here are some examples.
上記し 大豆単細胞粉末を使用し、表 1 3に示す組成の OZW型クリームを以下の ようにして製造した。すなわち、精製水に、保湿剤、及び大豆単細胞粉末を加え、 7〇°C にて加熱混合した。油性分を加熱溶解した後、界面活性剤、防腐剤、香料を加えて了〇°C に調製し 。 これを先に調整し 水相に加え、 ホモミキサーにて乳化粒子を均一化し 後、 脱気、 冷却して本実施例の OZW型クリームを得た。  Using the soybean single cell powder described above, an OZW type cream having the composition shown in Table 13 was produced as follows. That is, a humectant and soybean single cell powder were added to purified water, and heated and mixed at 7 ° C. After heating and dissolving the oily components, surfactants, preservatives and fragrances were added to adjust the temperature to 〇 ° C. This was adjusted first and added to the aqueous phase, and the emulsified particles were homogenized with a homomixer, followed by degassing and cooling to obtain the OZW type cream of this example.
表 1 3  Table 13
Figure imgf000020_0001
(実施例 1 1 )
Figure imgf000020_0001
(Example 11)
実施例 1 0では、本発明のクリームの一例として、 OZW型クリームについて紹介 し が、 ここでは、 WZO型クリームの一例について紹介する。  In Example 10, an OZW type cream was introduced as an example of the cream of the present invention. Here, an example of a WZO type cream is introduced.
上記した大豆単細胞粉末を使用し、本発明の化粧料組成物として表 1 4に示す組成 の WZO型クリームを製造し 。 このクリームは、 以下のようにして製造した。 すなわ ち、 水相 （1 ) を 5 0°Cで加熱溶解し ものを、 同じく 5 0Όに加熱した界面活性剤へ 攪拌しながら徐 に添加して乳化組成物を調整しだ。 油相を了〇°Cに加熱溶解したもの の中に前述の乳化組成物を均一に分散させだ。 さらに、 水相.（2) を了 0°Cに加熱した ちのをこの分散液中に十分に攪拌しながら添加し、 ホモミキサーで均一に乳化した後、 脱気し 30°Cまで冷却して本実施例の WZO型クリ一厶を得 。 Using the soybean single cell powder described above, a WZO-type cream having the composition shown in Table 14 was produced as the cosmetic composition of the present invention. This cream was manufactured as follows. In other words, the aqueous phase (1) was heated and dissolved at 50 ° C, and then converted to a surfactant that was also heated to 50 ° C. The emulsion composition was gradually added with stirring to adjust the emulsion composition. The above-mentioned emulsified composition was uniformly dispersed in a substance obtained by heating and dissolving the oil phase at about ° C. After the aqueous phase (2) was heated to 0 ° C, it was added to this dispersion with sufficient stirring, and the mixture was uniformly emulsified with a homomixer, then degassed and cooled to 30 ° C. The WZO type cream of this example was obtained.
表 1 4  Table 14
Figure imgf000021_0001
Figure imgf000021_0001
(実施例 1 2) (Example 1 2)
本発明の化粧料組成物をジエルとして使用する揚合は、大豆単細胞粉末の配合量を 化粧料組成物の全重量に関して 5 ~8 %>とすることにより、 大豆単細胞粉末を含有させ ない場合に比べ、使用中の肌への馴染みの良さと、それに伴 o肌への浸透感及び密着感、 使用後のベ 7£つき感を抑えだしつとりし 保湿効果の持続という効果をジエルに付与で きることが実験で確認されている。 ここでは、 その一例を紹介する。  When the cosmetic composition of the present invention is used as a jewel, the mixing amount of the soybean single-cell powder is set to 5 to 8% based on the total weight of the cosmetic composition, so that the soybean single-cell powder is not contained. Compared to Jewel, it has good familiarity with the skin during use, along with o skin permeation and adhesion, and reduces the feeling of stickiness after use. It has been confirmed in experiments. Here are some examples.
上記し 大豆単細胞粉末を使用し、表 1 5に示す組成のモイスチャージエルを以下 のようにして製造し 。 すなわち、 精製水に水溶性高分子を均一に溶解させた後、 ポリ エチレングリコール、 大豆単細胞粉末、 キレー卜剤を添加しだ。 ジプロピレングリコ一 ルに界面活性剤を加え、 50~5 5°Cで加熱溶解し、 これに防腐剤、 香料を添加した。 先に調製した水相を攪拌しながらこれに徐 に添加し 。 最後に、 アルカリ水溶液を添 加し、 中和のために +分攪拌して、 本実施例のモイスチャージエルを得だ。 表 1 5Using the soybean single-cell powder described above, a moist charge well having the composition shown in Table 15 was produced as follows. That is, after uniformly dissolving a water-soluble polymer in purified water, polyethylene glycol, soybean single-cell powder, and a chelating agent were added. A surfactant was added to dipropylene glycol, and dissolved by heating at 50 to 55 ° C, and a preservative and a fragrance were added thereto. The previously prepared aqueous phase was gradually added to this with stirring. Finally, an aqueous alkali solution was added, and the mixture was stirred for + minutes for neutralization, to obtain a moist charge well of this example. Table 15
Figure imgf000022_0001
Figure imgf000022_0001
(実施例 1 3) (Example 13)
本発明の化粧料組成物をエッセンスとして使用する場合は、大豆単細胞粉末の配合 量を化粧料組成物の全重量に関して 0. 1 ~2%とすることにより、 大豆単細胞粉末を 含有させない場合に比べ、 使用中の肌への密着感、 使用後のかさつき感の無さ及びしつ とりした保湿効果の持続とし う効果をェッセンスに付与できることが実験で確認されて いる。 ここでは、 その一例を紹介する。  When the cosmetic composition of the present invention is used as an essence, the amount of the soybean single-cell powder is set to 0.1 to 2% with respect to the total weight of the cosmetic composition, so that the soybean single-cell powder is not contained. Experiments have shown that essence can be given an effect of maintaining close contact with the skin during use, lack of bulkiness after use, and a sustained moisturizing effect. Here are some examples.
上記し 大豆単細胞粉末を使用し、表 1 6に示す組成の半透明保湿エッセンスを以 下のようにして製造した。  Using the soybean single cell powder described above, a translucent moisturizing essence having the composition shown in Table 16 was produced as follows.
表 1 6 Table 16
Figure imgf000022_0002
すなわち、 精製水に保湿剤、 p H緩衝剤、 ヒアルロン酸、及び大豆単細胞粉末を順 次室温にて溶解混合した。 次に、 エタノールに界面活性剤、 オリ一ブ油、 香料、 防腐剤 を順次溶解後、 前述の水相を添加、 溶解混合して本実施例のエッセンスを得 。
Figure imgf000022_0002
That is, humectant, pH buffer, hyaluronic acid, and soybean single-cell powder were added to purified water in order. Next, the mixture was dissolved and mixed at room temperature. Next, a surfactant, an olive oil, a fragrance, and a preservative were sequentially dissolved in ethanol, and the above-mentioned aqueous phase was added and dissolved and mixed to obtain the essence of the present example.
(実施例 1 4) (Example 14)
本発明の化粧料組成物をパック用組成物として使用する場合は、大豆単細胞粉末の 配合量を化粧料組成物の全重量に関して 8〜 5〇％とすることにより、 大豆単細胞粉末 を含有させない揚合に比べ、 使用中の肌への密着感及び浸透感、 洗い流し 後の肌への ッッパリ感、 かさつき感の無さと、 それに伴ラしっとりとしだ保湿効果の持続とい ο効 果をパック用組成物に付与できることが実験で確認されている。 ここでは、 その一例を 紹介する。  When the cosmetic composition of the present invention is used as a pack composition, the blending amount of the soybean single-cell powder is set to 8 to 5% with respect to the total weight of the cosmetic composition, so that the soybean single-cell powder is not contained. Compared to the combination, the pack composition has a feeling of adhesion and penetration to the skin in use, a feeling of firmness to the skin after rinsing, no bulkiness, and a sustained moisturizing effect. It has been confirmed by experiments that it can be applied to objects. Here are some examples.
上記し 大豆単細胞粉末を使用し、表 1 7に示す組成の洗い流しタイプノ \°ックを製 造しだ。 このパックは、 以下のようにして製造した。 すなわち、 精製水に保湿剤及び大 豆単細胞粉末を加え、 十分に湿潤、 分散させ 。 次に、 エタノールに界面活性剤、 香料、 防腐剤を添加溶解し、 前述の水相に添加した。 その後得られ 混合物を脱気して本実施 例のパックを得た。 '  Using the soybean single-cell powder described above, a rinse-off type knock having the composition shown in Table 17 was produced. This pack was manufactured as follows. That is, a humectant and soybean single-cell powder were added to purified water and sufficiently wetted and dispersed. Next, a surfactant, a fragrance, and a preservative were added and dissolved in ethanol, and added to the above-mentioned aqueous phase. Thereafter, the obtained mixture was degassed to obtain a pack of this example. '
表 1 7  Table 17
Figure imgf000023_0001
Figure imgf000023_0001
(実施例 1 5) (Example 15)
本発明の化粧料組成物を口紅に使用する揚合は、大豆単細胞粉末の配合量を化粧料 組成物の全重量に関して 0. 5〜2%とすることにより、 大豆単細胞粉末を含有させな い場合に比べ、 使用中の口唇への密着感、 使用後の口唇のかさつき感の無さ、 再使用時 の口紅組成物の口唇へのつきの良さという効果を口紅に付与できることが実験で確認さ れている。 ここでは、 その一例を紹介する。 上記した大豆単細胞粉末を使用し、表 1 8に示す組成の乳化タイプ口紅を以下のよ うにして製造し 。 すなわち、 二酸化チタン、 赤色 20 1号、 202号を酸化防止剤と 共にヒマシ油の一部に加えローラー処理し顔料部を得だ。 一方、 赤色 223号をヒマシ 油に溶解し染料部を得た。 さらに、 精製水に保湿剤、 界面活性剤及び大豆単細胞粉末を 加え、 80°Cで均一に溶解混合して水相部を得だ。 香料を含 他の成分を混合し、 加熱 溶解しだ後、 顔料部、 染料部を加えホモミキサーで均一に分散させた。 その後、 水相部 を加え、 ホモミキサーで乳化分散し、 脱気後、 金型に流し込んで急冷し、 本実施例の口 紅を得た。 When the cosmetic composition of the present invention is used for lipstick, the soybean single-cell powder is not contained by adjusting the blending amount of the soybean single-cell powder to 0.5 to 2% with respect to the total weight of the cosmetic composition. Experiments have shown that the lipstick can give the lipstick a better feeling of close contact with the lips during use, less bulkiness after use, and better stickiness of the lipstick when reused. ing. Here are some examples. Using the soybean single cell powder described above, an emulsified type lipstick having the composition shown in Table 18 was produced as follows. That is, titanium dioxide, Red No. 201 and No. 202 were added to a part of castor oil together with an antioxidant, and roller treatment was performed to obtain a pigment part. On the other hand, Red No. 223 was dissolved in castor oil to obtain a dye part. Further, a humectant, a surfactant, and a soybean single cell powder were added to purified water, and the mixture was uniformly dissolved and mixed at 80 ° C to obtain an aqueous phase. The other components including the fragrance were mixed and dissolved by heating, and then the pigment portion and the dye portion were added and uniformly dispersed with a homomixer. Thereafter, the aqueous phase was added, emulsified and dispersed by a homomixer, degassed, poured into a mold and rapidly cooled to obtain a lipstick of this example.
' 表 1 8 '' Table 18
Figure imgf000024_0001
Figure imgf000024_0001
(実施例 1 6) (Example 16)
本発明の化粧料組成物を毛髪用化粧品として使用する揚合は、大豆単細胞粉末の配 合量を化粧料組成物の全重量に関して 0. 1 ~2%とすることにより、 大豆単細胞粉末 を含有させない場合に比べ、 使用前のヘアクリームの指取れの良さ、 使用中の毛髪への 伸びの良さ、 及びそれに伴う整髪力の強さ、 洗髪後の毛髪のしっとりとした保湿効果の 持続とし、う効果を毛髪用化粧品に付与できることが実験で確認されている。 ここでは、 その一例を紹介する。  When the cosmetic composition of the present invention is used as a cosmetic for hair, the soybean single-cell powder is contained by adjusting the amount of the soybean single-cell powder to 0.1 to 2% with respect to the total weight of the cosmetic composition. Compared to the case where hair is not used, the goodness of fingering of the hair cream before use, the good elongation to the hair during use, and the strength of the hair styling accompanying it, and the moisturizing effect of the hair after shampooing are maintained. Experiments have shown that the effect can be imparted to hair cosmetics. Here are some examples.
上記し 大豆単細胞粉末を使用し、表 1 9に示す組成の OZW型ヘアクリームを以 下のようにして製造し 。 すなわち、 流動パラフィンにワセリン、 サラシミツロウ、 防 腐剤、 香料を加え、 加熱溶解し 80°Cに調整した。 一方、 精製水中に水溶性高分子、 保 湿剤、 界面活性剤、 キレー卜剤及び大豆単細胞粉末を加え、 加熱溶解混合して 80°Cに 調製した。 水相部を攪拌しながら油相部を加え、 ホモジナイザーを用いて乳化しだ。 3 0°C迄冷却を行っ 後、 精製水の一部に溶解した水酸化カリウム液を加え、 均一になる まで攪拌し、 脱気して本実施例のヘアクリームを得た。 Using the soybean single-cell powder described above, an OZW-type hair cream having the composition shown in Table 19 was obtained. Manufactured as below. That is, petrolatum, beeswax, preservatives, and fragrance were added to liquid paraffin, and the mixture was heated and dissolved to adjust to 80 ° C. On the other hand, a water-soluble polymer, a humectant, a surfactant, a chelating agent, and a soybean single cell powder were added to purified water, and the mixture was heated and dissolved and adjusted to 80 ° C. While stirring the aqueous phase, the oil phase was added and emulsified using a homogenizer. After cooling to 30 ° C, a potassium hydroxide solution dissolved in a part of purified water was added, stirred until the mixture became uniform, and degassed to obtain a hair cream of this example.
表 1 9  Table 19
Figure imgf000025_0001
Figure imgf000025_0001
(実施例 "1 7)  (Example "1 7")
本発明の化粧料組成物をボディ用化粧品として使用する場合は、大豆単細胞粉末の 配合量を化粧料組成物の全重量に関して 0. 1 ~ 1 %とすることにより、 大豆単細胞粉 末を含有させない場合に比べ、 使用前のボディクリームの指取れの良さ、 使用中の肌へ の伸びの良さとその密着感、 洗い流し 後の肌のッッパリ感、 かさつき感の無さと、 そ れに伴うしっとりとした保湿効果の持続とし、 効果をボディ用化粧品に付与できること が実験で確認されている。 ここでは、 その一例を紹介する。  When the cosmetic composition of the present invention is used as a cosmetic for a body, the content of the soybean single-cell powder is set to 0.1 to 1% with respect to the total weight of the cosmetic composition so that the soybean single-cell powder is not contained. Compared to the case, the body cream has good finger removal before use, good stretch on the skin during use and its close contact, the feeling of firmness of the skin after rinsing, the lack of dryness, and the moistness that accompanies it. Experiments have shown that the moisturizing effect can be maintained and the effect can be imparted to body cosmetics. Here are some examples.
上記した大豆単細胞粉末を使用し、表 2〇に示す組成の WZO型日中用ボディクリ —ムを以下のようにして製造し 。 すなわち、 スクヮラン、 シリコーン、 界面活性剤、 防腐剤、 香料を加熱溶解混合し、 それに疎水化処理粉末を攪拌しながら分散させ油相部 を得た。 一方、 精製水中に保湿剤及び大豆単細胞粉末を添加し、 70°Cにて調整し、 水 相部を得た。 この水相部を前述の油相部に添加し、 ホモジナイザー処理を行った。 得ら れた乳化物を室温まで冷却、 脱気して本実施例のボディクリームを得 。 表 20 Using the soybean single-cell powder described above, a WZO-type daytime body cream having the composition shown in Table 2 was produced as follows. That is, squalane, silicone, a surfactant, a preservative, and a fragrance were mixed by heating and dissolved, and the hydrophobized powder was dispersed with stirring to obtain an oil phase. On the other hand, a humectant and soybean single-cell powder were added to purified water and adjusted at 70 ° C to obtain an aqueous phase. This aqueous phase was added to the above-mentioned oil phase and subjected to a homogenizer treatment. The obtained emulsion was cooled to room temperature and degassed to obtain a body cream of this example. Table 20
Figure imgf000026_0001
産業上の利用可能性
Figure imgf000026_0001
Industrial applicability
上記し よろに、本発明の大豆の単細胞粉末を含有する化粧料組成物は、保湿効果、 皮膚への密着感、 肌の乾燥感防止等の多機能にわたって優れ 性能を発揮するので、 洗 顔料、 化粧水、 乳液、 クリーム、 ジエル、 エッセンス （美容液） 、 パック等のスキンケ ァ化粧品、 ファンデーション、 口紅などのメーキャップ化粧品、 毛髪化粧品、 ボディ化 粧品等の広範囲にわ ってその ¾用が期待される。  As described above, the cosmetic composition containing the single-cell soybean powder of the present invention exhibits excellent performance over multiple functions such as a moisturizing effect, a feeling of adhesion to the skin, and a prevention of dryness of the skin. It is expected to be used in a wide range of applications such as skin lotion, milky lotion, cream, jewel, essence (cosmetic), packs and other skincare cosmetics, makeup cosmetics such as foundation and lipstick, hair cosmetics, body cosmetics, etc. .
特に、本発明の化粧料組成物を粉末状メーキヤップ化粧料組成物として使用する場 合は、 上記した実施例と比較例との間の比較からも明らかなように、 従来のスキンケア 化粧品とは異なる主成分で構成されているにもかかわらず、 スキンケア化粧品に匹敵す る保湿効果を有する粉末状メーキャップ化粧料組成物を提供することができる。 まだ、 固形白粉ゆパウダリーファンデーションのような化粧料組成物にあっては、 従来、 その 成形性を確保する め結合剤の使用が必須であつだが、 本発明においては、 大豆の単細 胞粉末を添加しだことにより一切の結合剤を使用することなく良好な成形性を得ること ができるという長所もある。  In particular, when the cosmetic composition of the present invention is used as a powdery make-up cosmetic composition, it is different from conventional skin care cosmetics, as is clear from the comparison between the above Examples and Comparative Examples. A powdered makeup cosmetic composition having a moisturizing effect comparable to that of skin care cosmetics can be provided despite being composed of the main component. In the case of cosmetic compositions such as solid white powdery powdery foundation, the use of a binder has conventionally been indispensable in order to ensure its moldability. In the present invention, soybean cell powder is used. Another advantage is that good moldability can be obtained without the use of any binder.

Claims

請求の範囲 The scope of the claims
1 . 大豆を単細胞に分離して得られる粉末を含有してなる化粧料組成物。 1. A cosmetic composition containing a powder obtained by separating soybeans into single cells.
2. 請求項 1に記載の化粧料組成物において、 2. In the cosmetic composition according to claim 1,
上記粉末が、 Bacillus属の微生物が産生するぺクチナーゼを用い 酵素処理を原料 大豆に実施して得られる粉末である。  The above powder is a powder obtained by performing an enzyme treatment on soybean as a raw material using a pectinase produced by a microorganism of the genus Bacillus.
3. 請求項 1に記載の化粧料組成物において、 3. In the cosmetic composition according to claim 1,
上記粉末の配合量は、 上記化粧料組成物の全重量に関して、 0. 1 ~50%である。  The compounding amount of the powder is 0.1 to 50% with respect to the total weight of the cosmetic composition.
4. 上記粉末の配合量が、 上記化粧料組成物の全重量に関して 5〜1 5%である請求項 1に記載の化粧料組成物をでなる洗顔料。 4. The face wash comprising the cosmetic composition according to claim 1, wherein the amount of the powder is 5 to 15% based on the total weight of the cosmetic composition.
5. 上記粉末の配合量が、 上記化粧料組成物の全重量に関して〇. 1〜1 %>である請求 項 1に記載の化粧料組成物でなる化粧水。 5. A lotion comprising the cosmetic composition according to claim 1, wherein the amount of the powder is in the range of 0.1 to 1% based on the total weight of the cosmetic composition.
6. 上記粉末の配合量が、 上記化粧料組成物の全重量に関して 1〜3%である請求項 1 に記載の化粧料組成物でなる化粧用乳液。 6. A cosmetic emulsion comprising the cosmetic composition according to claim 1, wherein the amount of the powder is 1 to 3% with respect to the total weight of the cosmetic composition.
7. 上記粉末の配合量が、 上記化粧料組成物の全重量に関して 3〜1 5%である請求項 1に記載の化粧料組成物でなる化粧用クリーム。 7. A cosmetic cream comprising the cosmetic composition according to claim 1, wherein the amount of the powder is 3 to 15% with respect to the total weight of the cosmetic composition.
8. 上記粉末の配合量が、 上記化粧料組成物の全重量に関して 5〜8%である請求項 1 に記載の化粧料組成物でなるジエル。 8. The jewel comprising the cosmetic composition according to claim 1, wherein the blending amount of the powder is 5 to 8% with respect to the total weight of the cosmetic composition.
9. 上記粉末の配合量が、 上記化粧料組成物の全重量に関して 0. 1 ~2%である請求 項 1に記載の化粧料組成物でなる化粧用エッセンス。 9. A cosmetic essence comprising the cosmetic composition according to claim 1, wherein the blending amount of the powder is 0.1 to 2% with respect to the total weight of the cosmetic composition.
1 0. 上記粉末の配合量が、 上記化粧料組成物の全重量に関して 8~50%である請求 項 1に記載の化粧料組成物でなるパック用組成物。 10. The pack composition comprising the cosmetic composition according to claim 1, wherein the amount of the powder is 8 to 50% with respect to the total weight of the cosmetic composition.
1 1 . 上記粉末の配合量が、 上記化粧料組成物の全重量に関して 6~35%である請求 項 1に記載の化粧料組成物でなる粉末状メ一キヤップ化粧品。 11. A powdery makeup cosmetic comprising the cosmetic composition according to claim 1, wherein the amount of the powder is 6 to 35% based on the total weight of the cosmetic composition.
1 2. 上記粉末の配合量が、 上記化粧料組成物の全重量に関して〇. 5〜2%である請 求項 1に記載の化粧料組成物でなる口紅。 1 2. A lipstick comprising the cosmetic composition according to claim 1, wherein the amount of the powder is in the range of 0.5 to 2% with respect to the total weight of the cosmetic composition.
1 3. 上記粉末の配合量が、 上記化粧料組成物の全重量に関して、 0. 1〜2%である 請求項 1に記載の化粧料組成物でなる毛髪用化粧品。 1 3. A hair cosmetic comprising the cosmetic composition according to claim 1, wherein the amount of the powder is 0.1 to 2% with respect to the total weight of the cosmetic composition.
1 4. 上記粉末の配合量が、 上記化粧料組成物の全重量に関して、 0. 1〜1 %である 請求項 1に記載の化粧料組成物でなるボディ化粧品。 1 4. A body cosmetic comprising the cosmetic composition according to claim 1, wherein the blending amount of the powder is 0.1 to 1% with respect to the total weight of the cosmetic composition.
1 5. 大豆を単細胞に分離して得られる粉末であって、 その各 において大豆細胞壁の 損傷がほとんどないか、 もしくは非常に軽微であって、 その細胞壁によって大豆細胞内 成分を安定に保持してなる大豆単細胞粉末を含有する化粧料組成物。 1 5. Powder obtained by separating soybeans into single cells, in each of which there is little or very little damage to the soybean cell wall, and the soybean cell wall A cosmetic composition containing soybean single-cell powder in which components are stably retained.
PCT/JP2003/006968 2003-06-02 2003-06-02 Cosmetic composition containing powder obtained by dividing soybean into individual cells WO2004108096A1 (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05339147A (en) * 1992-06-12 1993-12-21 Uoji Kusumoto Cleaner for beauty culture
EP0815838A2 (en) * 1996-06-28 1998-01-07 Shiseido Company, Ltd. External skin treatment composition
EP1120047A1 (en) * 1999-08-06 2001-08-01 Toru Akazawa Method for processing soybean by using enzyme, processed soybean thus obtained and foods containing the thus processed soybean
JP2001271096A (en) * 2000-03-28 2001-10-02 Tkc Takahashi Computer Kaikei:Kk Cleansing agent, packing agent, anti-irritant and deodorant
JP2003221312A (en) * 2002-01-28 2003-08-05 Eau De Faveur:Kk Cosmetic composition containing powder obtained by digesting soybean into single cell

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05339147A (en) * 1992-06-12 1993-12-21 Uoji Kusumoto Cleaner for beauty culture
EP0815838A2 (en) * 1996-06-28 1998-01-07 Shiseido Company, Ltd. External skin treatment composition
EP1120047A1 (en) * 1999-08-06 2001-08-01 Toru Akazawa Method for processing soybean by using enzyme, processed soybean thus obtained and foods containing the thus processed soybean
JP2001271096A (en) * 2000-03-28 2001-10-02 Tkc Takahashi Computer Kaikei:Kk Cleansing agent, packing agent, anti-irritant and deodorant
JP2003221312A (en) * 2002-01-28 2003-08-05 Eau De Faveur:Kk Cosmetic composition containing powder obtained by digesting soybean into single cell

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