WO2004105513A1 - Food material or food using germinant grain, process for producing germinant grain and method of reducing germinant grain odor - Google Patents

Food material or food using germinant grain, process for producing germinant grain and method of reducing germinant grain odor Download PDF

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Publication number
WO2004105513A1
WO2004105513A1 PCT/JP2004/007364 JP2004007364W WO2004105513A1 WO 2004105513 A1 WO2004105513 A1 WO 2004105513A1 JP 2004007364 W JP2004007364 W JP 2004007364W WO 2004105513 A1 WO2004105513 A1 WO 2004105513A1
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Prior art keywords
food
germinated
brown rice
cereals
rice
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PCT/JP2004/007364
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French (fr)
Japanese (ja)
Inventor
Hiroshi Uchida
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Best Amenity Co., Ltd.
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Publication of WO2004105513A1 publication Critical patent/WO2004105513A1/en
Priority to HK06114224.3A priority Critical patent/HK1093300A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/152Cereal germ products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/20Malt products

Definitions

  • the present invention relates to a food material or food using germinated cereals, a method for producing germinated cereals, and a method for reducing odor of germinated cereals.
  • germinated cereals made from cereals such as brown rice and millet cereals are used, and the taste such as sweetness and umami is improved by alanine, and ⁇ -aminobutyric acid can be easily consumed. About.
  • Germinated brown rice in which brown rice is immersed in water and germinated to about lmm or less, has attracted attention against the background of a health boom.
  • Germinated brown rice has higher nutritional value and better digestibility than normal brown rice. It also contains a large amount of " ⁇ ⁇ -aminobutyric acid", which has medical effects such as blood pressure lowering and brain metabolism.
  • Patent Document 1 proposes germinated brown rice in which ⁇ -aminobutyric acid is efficiently enriched by immersing brown rice in water containing a predetermined amount of dissolved oxygen.
  • Patent Document 1 Japanese Patent No. 3137615
  • brown rice smell that remains in germinated brown rice.
  • This brown rice odor is also called putrefaction odor or bran odor, and is thought to be caused by various bacteria that grew when brown rice was immersed in water (originally attached to brown rice).
  • putrefaction odor or bran odor is thought to be caused by various bacteria that grew when brown rice was immersed in water (originally attached to brown rice).
  • insufficient intake of magnesium which is a kind of essential trace element extremely important for the human body, has been regarded as a problem.
  • Magnesium is present in the human body at about 25 g (0.05% of body weight), most of which is present as a compound in the skeleton.
  • magnesium has various physiological actions.
  • glycolytic enzymes For example, glycolytic enzymes
  • ATP-dependent enzymes enzymes related to sugar metabolism such as hexokinase, and enzymes related to the synthesis and degradation of nucleic acids such as DNA polymerase have a large effect on metabolism as ions essential for various enzyme reactions.
  • deficiency symptoms due to insufficient intake of magnesium include hypertension 'arteriosclerosis' diabetes, heart disease 'myocardial infarction' cerebral infarction or muscular pain 'hormonal disease' 'arrhythmia' sudden death, and furthermore osteoporosis ⁇ urine It is known that road stones or the like are surfaced in various forms. In view of the above, the development of new food materials and foods that can easily consume magnesium has been desired.
  • the inventor of the present invention has conducted intensive studies based on the idea that there is a method of extracting the original sweetness and umami of brown rice without separately adding a sweetener or an umami seasoning. Advanced.
  • brown rice is not simply water but is immersed in an aqueous solution containing a component or magnesium chloride and allowed to germinate, thereby containing alanine, a kind of amino acid that causes sweetness and umami.
  • alanine a kind of amino acid that causes sweetness and umami.
  • the unique brown rice smell can be reduced at the same time.
  • the present invention has been completed based on the above findings.
  • an object of the present invention is to use germinated cereals made from cereals such as brown rice and millet, and to improve the taste such as sweetness and umami with alanine, and to improve ⁇ -aminobutyric acid. It is an object of the present invention to provide a novel food material or food which can be easily taken.
  • Another object of the present invention is to use germinated cereals made from cereals such as brown rice and cereals, and to reduce the peculiar smell of germinated brown rice and germinated cereals to improve the taste. It is an object of the present invention to provide a new food material or food which can be made to be able to be served.
  • Another object of the present invention is to use germinated cereals made from cereals such as brown rice and cereals, so that magnesium, which is one of essential trace elements extremely important to the human body, can be easily taken.
  • cereals such as brown rice and cereals
  • An object of the present invention is to provide a method for producing germinated cereals, which improves the taste such as sweetness and umami, and enables easy intake of ⁇ -aminobutyric acid.
  • An object of the present invention is to provide a method for reducing odor that can reduce a specific odor of sprouted cereals.
  • the first invention is a food material or food, characterized by using a germinated cereal obtained by germinating a cereal by immersing the cereal in an aqueous solution containing a bittern component or magnesium salt.
  • the second invention is characterized by using a germinated cereal obtained by enriching alanine by immersing the cereal in an aqueous solution containing a nitrogen component or magnesium salt and germinating the cereal. Or food.
  • the third invention is characterized in that germinated grains enriched in alanine and magnesium are used by immersing cereals in an aqueous solution containing a nitrogen component or magnesium salt to cause germination, and Food material or food.
  • germinated brown rice or germinated cereals in which aranine is enriched by immersing brown rice or cereals in an aqueous solution containing a nitrogen component or magnesium salt and germinating the germinated rice are used.
  • the germinated brown rice or germinated cereals enriched with alanine and magnesium is obtained by immersing brown rice or cereals in an aqueous solution containing a bittern component or magnesium salt and causing germination.
  • a food material or food is obtained.
  • a sixth invention is the food material or food according to the fourth or fifth invention, wherein the brown rice is obtained from early-cut green rice.
  • the seventh invention is a method for producing germinated cereals, comprising immersing cereals in an aqueous solution containing a bittern component or magnesium salt and causing germination.
  • the eighth invention is characterized in that the pesticide is characterized by reducing odor peculiar to the cereal by immersing the cereal in an aqueous solution containing a power component or magnesium salt and causing germination. This is a method for reducing the smell of sprouts.
  • a substance that causes sweetness or umami by a kind of amino acid by immersing cereals such as brown rice or cereals in an aqueous solution containing a bittern component or magnesium salt and causing germination. It is possible to obtain germinated cereals in which the content of certain alanine and the content of ⁇ -aminobutyric acid, which is considered to have a medical effect such as a blood pressure lowering action and a stimulatory action on the brain, are enhanced. Therefore, in the food material or food according to the present invention using the germinated cereals, the taste such as sweetness and umami is improved by alanine, and ⁇ -aminobutyric acid can be easily consumed by eating. it can.
  • the taste can be further improved.
  • the food material or food according to the present invention uses germinated cereals obtained by immersing cereals in an aqueous solution containing a bittern component or magnesium salt.
  • the term "cereal” is used as a concept including a staple food (main cereal) such as rice and wheat and other miscellaneous cereals.
  • types such as white rice, red rice, and black rice are not particularly limited, and the varieties are not particularly limited.
  • Examples of the cereals include, for example, agar (including mochi) and millet (including mochi), hee, barley, buckwheat, amaranthus, quinoa (also referred to as quinoa), corn, and red beans (golden small) Beans), beans such as soybeans, sesame and the like.
  • the "aqueous solution containing the bittern component or salted magnesium" used for germination is, for example, powdered bittern, watered, and refined (the content ratio of calcium sulfate and potassium chloride is lower than that in the raw seawater by the salt field manufacturing method).
  • the adjustment method and the like are not particularly limited. It is also possible to use so-called deep sea water obtained by removing deep sea water from NaCl.
  • the concentration of the "aqueous solution containing the bittern component" is preferably 1 to 50 g, more preferably 1 to 10 g, and more preferably 1 to 10 g per liter of water, for example, purified bittern (magnesium chloride content is about 50% by weight). . If the amount of refined bittern per liter of water, for example, is less than lg, the magnesium content of the cereal tends to decrease, which is not desirable.If it exceeds 50 g, the cereal will feel astringent and harsh, resulting in inferior taste. Not preferred.
  • the cereals to be used may be used to remove small stones before germination, for example using a sorter.
  • the cereals When germinating cereals, the cereals are immersed in an aqueous solution containing a bittern component or magnesium salt as described above.
  • an aqueous solution containing a component or magnesium salt By immersing and germinating in an aqueous solution containing a component or magnesium salt, the content of alanine, a kind of amino acid that causes sweetness and taste, can be increased.
  • the content of ⁇ -aminobutyric acid which has medical effects such as a blood pressure lowering effect and a brain metabolism promoting effect, can be increased.
  • germs are immersed in an aqueous solution containing a bittern component or magnesium chloride instead of mere water to germinate, thereby simultaneously reducing brown rice odor peculiar to brown rice and brown rice peculiar to millet. can do. The reason for this is not clear, but it is presumed that the use of an aqueous solution containing a bittern component or magnesium chloride can suppress the growth of various bacteria.
  • Examples of the grains used in the present invention include brown rice obtained from early-cut green rice.
  • Early cut green rice is also called immature rice or blue rice, and brown rice obtained from this is also called green brown rice or blue brown rice.
  • Early-cut green rice is harvested earlier than the normal time to harvest and refers to rice in which most of the rice grains are green.
  • Brown rice obtained from early-cut green rice has small grains and high nutritional value. By using this as a raw material, the "brown rice smell" peculiar to brown rice can be reduced more effectively than in the case of using normal brown rice.
  • Germination can be carried out with the shell attached or with the shell removed.
  • ⁇ -aminobutyric acid is present in a large amount in the brain of animals in a free state, and is considered to be a major inhibitory transmitter of nerves.
  • ⁇ -Aminobutyric acid has functions such as a neurodepressant effect and a tranquilizing effect, and in addition to a blood pressure lowering effect and a brain metabolism promoting effect, prevention of arteriosclerosis (prevention of lifestyle-related diseases), prevention of hangover, skin It is attracting attention as a substance that also has the effect of preventing aging. Therefore, by using cereals germinated as described above, a large amount of ⁇ -aminobutyric acid can be accumulated in a food material or food after production, and as a result, the above-mentioned medical effects can be expected.
  • the immersion conditions for the cereal are not particularly limited as long as the liquid temperature, the immersion time, and ⁇ are such that the content of alanine is maximized.
  • the liquid temperature is 0-50 ° C
  • the immersion time is 1-148 hours
  • the pH is 2.5-7.5.
  • the standard of germination is a bud length of 2 mm or less, preferably 1 mm or less, and more preferably 0.1-0.5 mm.
  • alanine and ⁇ -amino are used as components (energy) to germinate. Butyric acid is consumed, and its content is undesirably reduced.
  • alanine and ⁇ -aminobutyric acid are water-soluble, if cereals are immersed in an aqueous solution for a long time, alanine and ⁇ -aminobutyric acid may be dissolved in the aqueous solution and their contents may be reduced. It is desirable that the shoots be immediately removed from the aqueous solution and dried.
  • brown rice obtained from early-cut green rice was used as the raw brown rice.
  • the bittern is refined bittern obtained by the salt field manufacturing method (powder bite for tofu, manufactured by Teshio Co., Ltd., magnesium chloride content: 51% by weight.
  • magnesium sulfate 3.4% by weight
  • sodium chloride 2%) 0.6% by weight
  • 0.5% by weight of potassium chloride 0.5% by weight
  • water of crystallization 0.6% by weight
  • each was pulverized with a high-speed pulverizer (Cyclone Mill, manufactured by UDY), and passed through a stainless steel net having a fine hole of 0.5 mm in diameter to obtain a powder.
  • a high-speed pulverizer (Cyclone Mill, manufactured by UDY)
  • OOO g of this powder was weighed, and each was collected in a centrifugal polyethylene bottle with a volume of 30 mL, and 5 mL of distilled water and 5 mL of 16% trichloroacetic acid were added to obtain a final concentration of 8% trichloroacetic acid solution.
  • the supernatant was filtered through a syringe filter (Advantech 0.45 ⁇ m filter, manufactured by Toyo Ichiro Paper Co., Ltd.) and transferred to a 2 mL vial.
  • a syringe filter Advancedtech 0.45 ⁇ m filter, manufactured by Toyo Ichiro Paper Co., Ltd.
  • Example 1 in which the germination was carried out by dipping in an aqueous solution containing a bittern component (Shiiro Magnesium) as compared to the control brown rice, alanine, a substance causing sweetness and umami, ⁇ -aminobutyric acid, which is considered to have medical effects, clearly increased.
  • a bittern component Shiiro Magnesium
  • the germinated brown rice (control brown rice and test rice in total) obtained as described above was subjected to a sensory test by cooking rice, and the taste was determined whether or not it was immersed in an aqueous solution of the bittern component (Shiidai magnesium). We examined what difference would occur in the global evaluation.
  • the plate was fried in a stainless steel bar, drained, and air-dried in a low-temperature room at 4 ° C to adjust the water content to about 14.5%.
  • a kind of amino acid causes sweetness and taste by immersing cereals such as brown rice and millet in an aqueous solution containing a component or magnesium chloride to cause germination. It is possible to obtain germinated cereals with an increased content of alanine, a substance, and a higher content of peraminobutyric acid, which is considered to have medical effects such as hypotensive action and brain metabolism promoting action. it can. Therefore, in the food material or food according to the present invention using the germinated cereals, the taste such as sweetness and umami is improved by aranine, and ⁇ -aminobutyric acid can be easily consumed by eating. .
  • the taste can be further improved.
  • magnesium which is one of the essential trace elements extremely important for the human body, can be easily taken.
  • Brown rice obtained from early-cut green rice can more effectively reduce the brown rice odor peculiar to brown rice as compared with the case of using normal brown rice.

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  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
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  • Polymers & Plastics (AREA)
  • Cereal-Derived Products (AREA)

Abstract

A novel food material or food using germinant grains from grains, such as unmilled rice and miscellaneous cereals, not only having its eating taste, such as sweetness or flavor, enhanced by alanine but also having realized ready intake of Ϝ-aminobutyric acid. In particular, a food material or food is produced using germinant grains obtained by immersing grains in an aqueous solution containing bittern ingredient or magnesium chloride. In the use of unmilled rice or miscellaneous cereals as the grains, “unmilled rice odor” or “miscellaneous cereal odor” being odor peculiar to the unmilled rice or miscellaneous cereals can be reduced. In the use of unmilled rice obtained from early reaped green rice, “unmilled rice odor” peculiar to unmilled rice can be more effectively reduced than in the use of ordinary unmilled rice.

Description

明 細 書  Specification
発芽穀類を用いた食品素材または食品、発芽穀類の製造方法、発芽穀 類の臭み低減方法  Food material or food using germinated cereals, method for producing germinated cereals, method for reducing odor of germinated cereals
技術分野  Technical field
[0001] 本発明は、発芽穀類を用いた食品素材または食品、発芽穀類の製造方法、発芽 穀類の臭み低減方法に関する。  The present invention relates to a food material or food using germinated cereals, a method for producing germinated cereals, and a method for reducing odor of germinated cereals.
更に詳しくは、玄米や雑穀等の穀類を原料とした発芽穀類を用いたものであって、 ァラニンによって甘みや旨味等の食味を向上させると共に、 γ—ァミノ酪酸を手軽に 摂取できるようにしたものに関する。  More specifically, germinated cereals made from cereals such as brown rice and millet cereals are used, and the taste such as sweetness and umami is improved by alanine, and γ-aminobutyric acid can be easily consumed. About.
背景技術  Background art
[0002] 近年、健康ブームを背景に、玄米を水に浸漬して約 lmm以下に発芽させた発芽玄 米が注目されている。発芽玄米は、通常の玄米に比べて栄養価が高ぐ消化吸収性 も良い。また、血圧降下作用や脳の代謝促進作用などの医学的効果があるとされる「 Ύ—ァミノ酪酸」も多く含有してレ、る。  [0002] In recent years, germinated brown rice, in which brown rice is immersed in water and germinated to about lmm or less, has attracted attention against the background of a health boom. Germinated brown rice has higher nutritional value and better digestibility than normal brown rice. It also contains a large amount of "多 く -aminobutyric acid", which has medical effects such as blood pressure lowering and brain metabolism.
[0003] 例えば特許文献 1には、所定量の溶在酸素を含有させた水に玄米を浸漬させるこ とにより、 τ —ァミノ酪酸を効率的に富化させた発芽玄米が提案されている。  [0003] For example, Patent Document 1 proposes germinated brown rice in which τ-aminobutyric acid is efficiently enriched by immersing brown rice in water containing a predetermined amount of dissolved oxygen.
[0004] 特許文献 1 :特許第 3137615号公報  Patent Document 1: Japanese Patent No. 3137615
[0005] 以上のように発芽玄米は、通常の玄米とは異なる全く新しい機能性健康食品として 大いに期待されている。  [0005] As described above, germinated brown rice is greatly expected as a completely new functional health food different from ordinary brown rice.
発明の開示  Disclosure of the invention
発明が解決しょうとする課題  Problems the invention is trying to solve
[0006] し力、しながら、従来の発芽玄米は、甘みや旨味等の食味の面で必ずしも満足できる ものではなかった。 [0006] However, the conventional germinated brown rice is not always satisfactory in terms of taste such as sweetness and umami.
玄米本来の甘みや旨味を損なわせる一つの要因としては、発芽玄米に残存する玄 米独特の「玄米臭」が挙げられる。この玄米臭は腐敗臭や糠臭等とも言われ、玄米を 水に浸潰した際に増殖した雑菌 (元もとは玄米に付着している雑菌)が原因で発生す ると考えられている。 [0007] ところで、近年、人体にとって極めて重要な必須微量元素の一種であるマグネシゥ ムの摂取不足が問題視されている。マグネシウムは人体に約 25g (体重の 0. 05%)存 在し、その大部分が骨格中に化合物として存在する。 One factor that impairs the original sweetness and umami of brown rice is the unique brown rice smell that remains in germinated brown rice. This brown rice odor is also called putrefaction odor or bran odor, and is thought to be caused by various bacteria that grew when brown rice was immersed in water (originally attached to brown rice). . [0007] In recent years, insufficient intake of magnesium, which is a kind of essential trace element extremely important for the human body, has been regarded as a problem. Magnesium is present in the human body at about 25 g (0.05% of body weight), most of which is present as a compound in the skeleton.
[0008] 更にマグネシウムは、多種多様な生理作用を有している。例えば解糖系酵素や [0008] Further, magnesium has various physiological actions. For example, glycolytic enzymes
ATP依存性酵素、へキソキナーゼなどの糖代謝に関する酵素、あるいは DNAポリメラ ーゼなどの核酸の合成や分解に関する酵素など、多種の酵素反応に必須なイオンと して代謝に与える影響が大きレ、。 ATP-dependent enzymes, enzymes related to sugar metabolism such as hexokinase, and enzymes related to the synthesis and degradation of nucleic acids such as DNA polymerase have a large effect on metabolism as ions essential for various enzyme reactions.
[0009] このため、マグネシウムの摂取不足による欠乏症状は、高血圧 '動脈硬化'糖尿病、 心臓病'心筋梗塞 '脳梗塞、あるいは筋肉痛'ホルモン性疾患 '不整脈'突然死、更 には骨粗鬆症 ·尿路結石等として、実に様々な形で表面化することが知られている。 以上のようなことから、マグネシウムを手軽に摂取することができる新規な食品素材 や食品の開発が望まれていた。  [0009] For this reason, deficiency symptoms due to insufficient intake of magnesium include hypertension 'arteriosclerosis' diabetes, heart disease 'myocardial infarction' cerebral infarction or muscular pain 'hormonal disease' 'arrhythmia' sudden death, and furthermore osteoporosis · urine It is known that road stones or the like are surfaced in various forms. In view of the above, the development of new food materials and foods that can easily consume magnesium has been desired.
[0010] 本発明者は上記事情に鑑み、まずは甘味料や旨味調味料等を別途添加すること なぐ玄米本来の甘みや旨み等を引き出す方法はないか、という発想のもとに鋭意研 究を進めた。  [0010] In view of the above circumstances, the inventor of the present invention has conducted intensive studies based on the idea that there is a method of extracting the original sweetness and umami of brown rice without separately adding a sweetener or an umami seasoning. Advanced.
[0011] その結果、驚くべきことに、玄米を単なる水ではなぐにがり成分または塩化マグネ シゥムを含む水溶液に浸漬し究芽させることにより、アミノ酸の一種で甘みや旨味を 起こす物質であるァラニンの含有量を高めることができることを見い出すと共に、玄米 独特の玄米臭をも同時に低減できることを見い出した。  [0011] As a result, surprisingly, brown rice is not simply water but is immersed in an aqueous solution containing a component or magnesium chloride and allowed to germinate, thereby containing alanine, a kind of amino acid that causes sweetness and umami. In addition to finding that the amount can be increased, it has also been found that the unique brown rice smell can be reduced at the same time.
[0012] 更に、にがり成分または塩ィ匕マグネシウムを含む水溶液に浸漬し発芽させることに より、玄米に含まれるマグネシウムの含有量を高めることができることを見い出した。  [0012] Furthermore, it has been found that the content of magnesium contained in brown rice can be increased by immersion in an aqueous solution containing a bittern component or magnesium salt and germination.
[0013] また更に、玄米以外のキビ、ヒェ、ハトムギ、ソバ、大豆等の雑穀についても検討を 進めた結果、同じくにがり成分または塩化マグネシウムを含む水溶液に浸漬し発芽さ せることにより、上記した同様の効果が得られることを見い出した。 [0013] Furthermore, as a result of study on millet, millet, barley, buckwheat, buckwheat, soybeans and other cereals other than brown rice, the same germination was achieved by immersion in an aqueous solution containing a bittern component or magnesium chloride. Has been found to be effective.
本発明は、以上のような知見に基づいて完成したものである。  The present invention has been completed based on the above findings.
[0014] (本発明の目的) (Object of the present invention)
そこで本発明の目的は、玄米や雑穀等の穀類を原料とした発芽穀類を用いたもの であって、ァラニンによって甘みや旨味等の食味を向上させると共に、 γ—アミノ酪酸 を手軽に摂取できるようにした新規な食品素材または食品を提供することにある。 Therefore, an object of the present invention is to use germinated cereals made from cereals such as brown rice and millet, and to improve the taste such as sweetness and umami with alanine, and to improve γ-aminobutyric acid. It is an object of the present invention to provide a novel food material or food which can be easily taken.
[0015] 本発明の他の目的は、玄米や雑穀等の穀類を原料とした発芽穀類を用いたもので あって、発芽玄米や発芽雑穀等の特有の臭いを低減させて、食味をより向上させるこ とができるようにした新規な食品素材または食品を提供することにある。  [0015] Another object of the present invention is to use germinated cereals made from cereals such as brown rice and cereals, and to reduce the peculiar smell of germinated brown rice and germinated cereals to improve the taste. It is an object of the present invention to provide a new food material or food which can be made to be able to be served.
[0016] 本発明の他の目的は、玄米や雑穀等の穀類を原料とした発芽穀類を用いたもので あって、人体にとって極めて重要な必須微量元素の一種であるマグネシウムを手軽 に摂取できるようにした新規な食品素材または食品を提供することにある。  [0016] Another object of the present invention is to use germinated cereals made from cereals such as brown rice and cereals, so that magnesium, which is one of essential trace elements extremely important to the human body, can be easily taken. To provide a novel food material or food.
[0017] 本発明の目的は、甘みや旨味等の食味を向上させると共に、 γ—ァミノ酪酸を手軽 に摂取できるようにした発芽穀類の製造方法を提供することにある。  [0017] An object of the present invention is to provide a method for producing germinated cereals, which improves the taste such as sweetness and umami, and enables easy intake of γ-aminobutyric acid.
[0018] 本発明の目的は、発芽穀類の特有の臭みを低減させることができる臭み低減方法 を提供することにある。  [0018] An object of the present invention is to provide a method for reducing odor that can reduce a specific odor of sprouted cereals.
課題を解決するための手段  Means for solving the problem
[0019] 上記目的を達成するために講じた本発明の手段は次のとおりである。  [0019] The means of the present invention taken to achieve the above object are as follows.
[0020] 第 1の発明にあっては、にがり成分または塩ィ匕マグネシウムを含む水溶液に穀類を 浸潰して発芽させた発芽穀類を用いたことを特徴とする、食品素材または食品である  [0020] The first invention is a food material or food, characterized by using a germinated cereal obtained by germinating a cereal by immersing the cereal in an aqueous solution containing a bittern component or magnesium salt.
[0021] 第 2の発明にあっては、に力 ^成分または塩ィ匕マグネシウムを含む水溶液に穀類を 浸漬し発芽させてァラニンを富化した発芽穀類を用いたことを特徴とする、食品素材 または食品である。 [0021] The second invention is characterized by using a germinated cereal obtained by enriching alanine by immersing the cereal in an aqueous solution containing a nitrogen component or magnesium salt and germinating the cereal. Or food.
[0022] 第 3の発明にあっては、に力 ^成分または塩ィ匕マグネシウムを含む水溶液に穀類を 浸漬し発芽させてァラニン及びマグネシウムを富化した発芽穀類を用いたことを特徴 とする、食品素材または食品である。  [0022] The third invention is characterized in that germinated grains enriched in alanine and magnesium are used by immersing cereals in an aqueous solution containing a nitrogen component or magnesium salt to cause germination, and Food material or food.
[0023] 第 4の発明にあっては、に力 ^成分または塩ィ匕マグネシウムを含む水溶液に玄米ま たは雑穀を浸漬し発芽させてァラニンを富化した発芽玄米または発芽雑穀を用いた ことを特徴とする、食品素材または食品である。  [0023] In the fourth invention, germinated brown rice or germinated cereals in which aranine is enriched by immersing brown rice or cereals in an aqueous solution containing a nitrogen component or magnesium salt and germinating the germinated rice are used. A food material or food.
[0024] 第 5の発明にあっては、にがり成分または塩ィ匕マグネシウムを含む水溶液に玄米ま たは雑穀を浸漬し発芽させてァラニン及びマグネシウムを富化した発芽玄米または 発芽雑穀を用いたことを特徴とする、食品素材または食品である。 [0025] 第 6の発明にあっては、玄米は早刈り緑色米から得たものであることを特徴とする、 第 4または第 5の発明に係る食品素材または食品である。 [0024] In the fifth invention, the germinated brown rice or germinated cereals enriched with alanine and magnesium is obtained by immersing brown rice or cereals in an aqueous solution containing a bittern component or magnesium salt and causing germination. A food material or food. [0025] A sixth invention is the food material or food according to the fourth or fifth invention, wherein the brown rice is obtained from early-cut green rice.
[0026] 第 7の発明にあっては、にがり成分または塩ィ匕マグネシウムを含む水溶液に穀類を 浸漬して発芽させることを特徴とする、発芽穀類の製造方法である。 [0026] The seventh invention is a method for producing germinated cereals, comprising immersing cereals in an aqueous solution containing a bittern component or magnesium salt and causing germination.
[0027] 第 8の発明にあっては、に力 ^成分または塩ィ匕マグネシウムを含む水溶液に穀類を 浸漬して発芽させることにより、穀類の特有の臭みを低減させることを特徴とする、発 芽穀類の臭み低減方法である。 [0027] The eighth invention is characterized in that the pesticide is characterized by reducing odor peculiar to the cereal by immersing the cereal in an aqueous solution containing a power component or magnesium salt and causing germination. This is a method for reducing the smell of sprouts.
発明の効果  The invention's effect
[0028] (a)本発明によれば、にがり成分または塩ィヒマグネシウムを含む水溶液に玄米や雑 穀等の穀類を浸漬して発芽させることにより、アミノ酸の一種で甘みや旨味を起こす 物質であるァラニンの含有量と、血圧降下作用や脳の代 Hi促進作用などの医学的 効果があるとされる γ—ァミノ酪酸の含有量を高めた発芽雑穀を得ることができる。 よって、この発芽雑穀を用いた本発明に係る食品素材または食品は、ァラニンによ つて甘みや旨味等の食味がより美味しく向上しており、食すことにより γ—アミノ酪酸 を手軽に摂取することができる。  [0028] (a) According to the present invention, a substance that causes sweetness or umami by a kind of amino acid by immersing cereals such as brown rice or cereals in an aqueous solution containing a bittern component or magnesium salt and causing germination. It is possible to obtain germinated cereals in which the content of certain alanine and the content of γ-aminobutyric acid, which is considered to have a medical effect such as a blood pressure lowering action and a stimulatory action on the brain, are enhanced. Therefore, in the food material or food according to the present invention using the germinated cereals, the taste such as sweetness and umami is improved by alanine, and γ-aminobutyric acid can be easily consumed by eating. it can.
[0029] (b)更に本発明によれば、玄米や雑穀を用いて発芽穀類を得た場合の特有の臭み、 いわゆる「玄米臭」や「雑穀臭」等を低減させることができる。よって、その特有の臭み によって食品素材または食品の甘みや旨味が損なわれることを防ぐことができるので(B) Further, according to the present invention, it is possible to reduce a peculiar smell when a sprouted cereal is obtained using brown rice or millet, so-called “brown rice smell” or “millet grain smell”. Therefore, it is possible to prevent the sweetness and umami of the food material or food from being impaired by the unique odor.
、食味をより向上させることができる。 , The taste can be further improved.
[0030] (c)更に本発明によれば、マグネシウムの含有量を高めた発芽雑穀を得ることができ る。よって、この発芽雑穀を用いた本発明に係る食品素材または食品を食すことで、 人体にとって極めて重要な必須微量元素の一種であるマグネシウムを手軽に摂取で きる。 (C) Further, according to the present invention, germinated cereals with an increased magnesium content can be obtained. Therefore, by eating the food material or food according to the present invention using the germinated cereals, magnesium, which is a kind of essential trace element extremely important for the human body, can be easily taken.
[0031] (d)早刈り緑色米から得た玄米を使用したものは、通常の玄米を用いた場合と比べ て、玄米独特の「玄米臭」をより効果的に低減させることができる。  (D) Using brown rice obtained from early-cut green rice can more effectively reduce the brown rice smell peculiar to brown rice as compared with the case using normal brown rice.
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0032] 本発明に係る食品素材または食品は、にがり成分または塩ィ匕マグネシウムを含む 水溶液に穀類を浸漬して発芽させた発芽穀類を用いてレ、る。 [0033] 本明細書で「穀類」の用語は、例えば米や麦等のように主食とするもの(主穀)やそ れ以外の雑穀も含む広レ、概念として使用してレ、る。 [0032] The food material or food according to the present invention uses germinated cereals obtained by immersing cereals in an aqueous solution containing a bittern component or magnesium salt. [0033] In the present specification, the term "cereal" is used as a concept including a staple food (main cereal) such as rice and wheat and other miscellaneous cereals.
[0034] 例えば「米」の場合、白米 ·赤米 ·黒米等の種類は特に限定するものではなぐその 品種についても特に限定するものではない。 [0034] For example, in the case of "rice", types such as white rice, red rice, and black rice are not particularly limited, and the varieties are not particularly limited.
また「麦」の場合についても、大麦.小麦 ·ハダカムギ 'ライムギ ·ェンバタ 'もち麦の 種類は特に限定するものではなぐその品種についても特に限定するものではなレ、。  Also, in the case of "wheat", the type of barley. Wheat · hadakamugi 'rye · embata' glutinous barley is not particularly limited, and its varieties are not particularly limited.
[0035] 雑穀としては、例えば、ァヮ(モチアヮ等も含む)、キビ (モチキビ等も含む)、ヒェ、 ハトムギ、ソバ、アマランサス、キヌァ(キノァとも称される)、トウモロコシ、小豆(金時小 豆も含む)や大豆等の豆類、ゴマ等を挙げることができる。 [0035] Examples of the cereals include, for example, agar (including mochi) and millet (including mochi), hee, barley, buckwheat, amaranthus, quinoa (also referred to as quinoa), corn, and red beans (golden small) Beans), beans such as soybeans, sesame and the like.
[0036] 発芽に用いる「にがり成分または塩ィ匕マグネシウムを含む水溶液」は、例えば粉末 にがり、水にがり、精製にがり(塩田製法により硫酸カルシウム及び塩化カリウムの含 有比率を原海水における含有比率よりも少なくしたもの)、食品添加用の塩化マグネ シゥム含有物、あるいは塩化マグネシウム含有水等を用いることで得ることができるが[0036] The "aqueous solution containing the bittern component or salted magnesium" used for germination is, for example, powdered bittern, watered, and refined (the content ratio of calcium sulfate and potassium chloride is lower than that in the raw seawater by the salt field manufacturing method). Can be obtained by using magnesium chloride containing water for food addition, or magnesium chloride containing water, etc.
、その調整方法等は特に限定するものではなレ、。なお、深海水を脱 NaCl化した、い わゆる海洋深層水も利用することができる。 The adjustment method and the like are not particularly limited. It is also possible to use so-called deep sea water obtained by removing deep sea water from NaCl.
[0037] 「にがり成分を含む水溶液」の濃度は、水 1L当たり、例えば精製にがり(塩化マグネ シゥムの含有率は約 50重量%) 1— 50gが好ましぐ更に 1一 10gが好ましレ、。水 1L 当たり、例えば精製にがりが lg未満では、穀類のマグネシウム含有量が減る傾向が あるので好ましくなぐ 50gを越えると、穀類に渋みやえぐみが感じられ、結果的に食 味が劣る傾向があるため好ましくない。 [0037] The concentration of the "aqueous solution containing the bittern component" is preferably 1 to 50 g, more preferably 1 to 10 g, and more preferably 1 to 10 g per liter of water, for example, purified bittern (magnesium chloride content is about 50% by weight). . If the amount of refined bittern per liter of water, for example, is less than lg, the magnesium content of the cereal tends to decrease, which is not desirable.If it exceeds 50 g, the cereal will feel astringent and harsh, resulting in inferior taste. Not preferred.
[0038] 使用する穀類は、発芽させる前に例えば選別機を使用して小さな石を取り除いたり[0038] The cereals to be used may be used to remove small stones before germination, for example using a sorter.
、ネットなどに入れて水洗いし埃を取り除く処理等の前処理を行っておくことが望まし レ、。 It is desirable to carry out pretreatment such as washing in water and removing dust in a net.
[0039] 穀類を発芽させる際は、上記した通り、穀類をにがり成分または塩ィ匕マグネシウムを 含む水溶液に浸漬させる。に力 ^成分または塩ィヒマグネシウムを含む水溶液に浸漬 し発芽させることにより、アミノ酸の一種で甘みや旨味を起こす物質であるァラニンの 含有量を高めることができる。また、血圧降下作用や脳の代謝促進作用など医学的 効果がある γ—ァミノ酪酸の含有量を高めることができる。 [0040] また、穀類を単なる水ではなぐにがり成分または塩化マグネシウムを含む水溶液 に浸漬し発芽させることにより、玄米であれば玄米独特の玄米臭、雑穀であれば雑 穀独特の雑穀臭も同時に低減することができる。この理由は明らかではないが、にが り成分または塩化マグネシウムを含む水溶液を使用することにより、雑菌の増殖を抑 えることができるからではなレ、かと推察される。 When germinating cereals, the cereals are immersed in an aqueous solution containing a bittern component or magnesium salt as described above. By immersing and germinating in an aqueous solution containing a component or magnesium salt, the content of alanine, a kind of amino acid that causes sweetness and taste, can be increased. In addition, the content of γ-aminobutyric acid, which has medical effects such as a blood pressure lowering effect and a brain metabolism promoting effect, can be increased. [0040] In addition, germs are immersed in an aqueous solution containing a bittern component or magnesium chloride instead of mere water to germinate, thereby simultaneously reducing brown rice odor peculiar to brown rice and brown rice peculiar to millet. can do. The reason for this is not clear, but it is presumed that the use of an aqueous solution containing a bittern component or magnesium chloride can suppress the growth of various bacteria.
[0041] 更に、本発明に用いる穀類として、早刈り緑色米から得られた玄米を挙げることが できる。早刈り緑色米は、未熟米、青米とも称され、これから得られた玄米は緑玄米 や青玄米とも称される。早刈り緑色米とは、通常の収穫適期よりも早い時期に刈り取 られるもので、米粒の多くが緑色を呈する米のことを指称している。  [0041] Examples of the grains used in the present invention include brown rice obtained from early-cut green rice. Early cut green rice is also called immature rice or blue rice, and brown rice obtained from this is also called green brown rice or blue brown rice. Early-cut green rice is harvested earlier than the normal time to harvest and refers to rice in which most of the rice grains are green.
早刈り緑色米から得られた玄米は、粒が小さくて栄養価も高い。そして、これを原料 として用いることにより、通常の玄米を用いた場合と比べて、玄米独特の「玄米臭」を より効果的に低減させることができる。  Brown rice obtained from early-cut green rice has small grains and high nutritional value. By using this as a raw material, the "brown rice smell" peculiar to brown rice can be reduced more effectively than in the case of using normal brown rice.
[0042] 発芽は、殻がついたまま行うこともできるし、殻を除いた状態で行うこともできる。  [0042] Germination can be carried out with the shell attached or with the shell removed.
[0043] 上記した γ—ァミノ酪酸は、動物の脳中に遊離の状態で多く存在しており、神経の 主要な抑制性伝達物質と考えられている。 γ _ァミノ酪酸は、神経抑制作用や精神 安定作用などの機能を有しており、血圧降下作用や脳の代謝促進作用の他、動脈 硬化の予防 (生活習慣病の予防)、二日酔い防止、皮膚の老化防止などの効果もあ る物質として注目されている。よって、以上のようにして発芽させた穀類を用いること で、製造後の食品素材または食品に γ _ァミノ酪酸を多く蓄積でき、結果的に上記し たような医学的な効果が期待できる。  [0043] The above-mentioned γ-aminobutyric acid is present in a large amount in the brain of animals in a free state, and is considered to be a major inhibitory transmitter of nerves. γ-Aminobutyric acid has functions such as a neurodepressant effect and a tranquilizing effect, and in addition to a blood pressure lowering effect and a brain metabolism promoting effect, prevention of arteriosclerosis (prevention of lifestyle-related diseases), prevention of hangover, skin It is attracting attention as a substance that also has the effect of preventing aging. Therefore, by using cereals germinated as described above, a large amount of γ-aminobutyric acid can be accumulated in a food material or food after production, and as a result, the above-mentioned medical effects can be expected.
[0044] 穀類の浸漬条件としては、ァラニンの含有量が最も多くなるような液温、浸漬時間、 ρΗであれば、特に限定するものではなレ、。例えば液温は 0— 50°Cで、浸漬時間は 1 一 48時間、 pHは 2. 5— 7. 5である。  [0044] The immersion conditions for the cereal are not particularly limited as long as the liquid temperature, the immersion time, and ρΗ are such that the content of alanine is maximized. For example, the liquid temperature is 0-50 ° C, the immersion time is 1-148 hours, and the pH is 2.5-7.5.
[0045] にがり成分または塩化マグネシウムを含む水溶液に浸漬して発芽させたら、ァラニ ンの含有量が低下しないように、穀類を乾燥して発芽を止めることが望ましい。発芽 の目安は、芽の長さ 2mm以下であり、好ましくは lmm以下であり、更に好ましくは 0. 1—0. 5mmで ¾> 。  After germination by immersion in an aqueous solution containing a bittern component or magnesium chloride, it is desirable to stop germination by drying the cereal so that the content of alanine does not decrease. The standard of germination is a bud length of 2 mm or less, preferably 1 mm or less, and more preferably 0.1-0.5 mm.
芽が伸びすぎると、発芽するための成分 (エネルギー)として、ァラニンと γ—アミノ 酪酸が消費され、その含有量が減っていくので好ましくない。 If the buds grow too much, alanine and γ-amino are used as components (energy) to germinate. Butyric acid is consumed, and its content is undesirably reduced.
また、ァラニンと γ _ァミノ酪酸は水溶性であるため、穀類を長時間水溶液に浸漬さ せておくと、ァラニンと γ—ァミノ酪酸が水溶液に溶け出し、その含有量が減る恐れが あるので、芽が出たら水溶液から直ちに取り出し乾燥させることが望ましい。  In addition, since alanine and γ-aminobutyric acid are water-soluble, if cereals are immersed in an aqueous solution for a long time, alanine and γ-aminobutyric acid may be dissolved in the aqueous solution and their contents may be reduced. It is desirable that the shoots be immediately removed from the aqueous solution and dried.
実施例  Example
[0046] 以下、本発明を実施例により説明するが、本発明はこれらに限定されるものではな レ、。  Hereinafter, the present invention will be described with reference to Examples, but the present invention is not limited thereto.
なお、本実施例では、原料玄米として、早刈り緑色米から得られた玄米を用いた。  In this example, brown rice obtained from early-cut green rice was used as the raw brown rice.
[0047] [実施例 1] [Example 1]
(ァラニンと γ—ァミノ酪酸にっレ、て)  (Alanine and γ-aminobutyric acid)
脱イオン水 1L当たり、にがり 10gを溶解した水溶液を得た。この水溶液 (pH5. 9に 調整、室温 25°Cで保持)に、上記した原料玄米を lkgを投入し、 4時間浸潰した。  An aqueous solution in which 10 g of bittern was dissolved per 1 L of deionized water was obtained. To this aqueous solution (adjusted to pH 5.9 and kept at room temperature of 25 ° C.), lkg of the above-mentioned raw brown rice was put and immersed for 4 hours.
[0048] なお、にがりとしては、塩田製法で得られた精製にがり(豆腐用粉末にがり、株式会 社天塩製、塩化マグネシウム含量 51重量%。他に、硫酸マグネシウム 3. 4重量%、 塩化ナトリウム 2. 6重量%、塩化カリウム 0. 5重量%、及び結晶水約 42. 5重量%を 含有)を使用した。 [0048] The bittern is refined bittern obtained by the salt field manufacturing method (powder bite for tofu, manufactured by Teshio Co., Ltd., magnesium chloride content: 51% by weight. In addition, magnesium sulfate: 3.4% by weight, sodium chloride: 2%) 0.6% by weight, 0.5% by weight of potassium chloride and about 42.5% by weight of water of crystallization).
[0049] 浸漬後、得られた発芽玄米を水溶液から取り出し、直ちに 40°Cの乾燥機で乾燥さ せて発芽を止めた。  [0049] After immersion, the germinated brown rice obtained was taken out of the aqueous solution and immediately dried with a dryer at 40 ° C to stop germination.
[0050] 次レ、で、高速粉砕機(サイクロンミル、 UDY社製)で各々粉砕し、直径 0. 5mmの 微細孔を有するステンレス網を通過させ、粉末を得た。この粉末 1. OOOgをそれぞれ 秤量し、これらを各々容積 30mLの遠心用ポリエチレン瓶に採取し、蒸留水 5mL、 1 6%トリクロ口酢酸 5mLを加えて、終濃度 8%トリクロ口酢酸溶液とした。  [0050] Next, each was pulverized with a high-speed pulverizer (Cyclone Mill, manufactured by UDY), and passed through a stainless steel net having a fine hole of 0.5 mm in diameter to obtain a powder. 1. OOO g of this powder was weighed, and each was collected in a centrifugal polyethylene bottle with a volume of 30 mL, and 5 mL of distilled water and 5 mL of 16% trichloroacetic acid were added to obtain a final concentration of 8% trichloroacetic acid solution.
[0051] 更に超音波発生機 (ブランソン B— 42S、ブランソン器機社製)で 2分間の超音波処 理を行った後、冷却遠心機 (インバーターマイクロ冷却遠心機、久保田製作所製)に より、 10000卬 mで 5分間の遠心処理を行った。  [0051] Further, after performing an ultrasonic treatment for 2 minutes with an ultrasonic generator (Branson B-42S, manufactured by Branson Kiki Co., Ltd.), a cooling centrifuge (an inverter micro-cooled centrifuge, manufactured by Kubota Seisakusho) produced 10,000 Centrifugation was performed at 卬 m for 5 minutes.
[0052] その上澄み液をシリンジフィルター(アドバンテック 0· 45 μ mフィルター、トーョ一ろ 紙社製)で濾過して 2mLバイアル瓶に移した。  [0052] The supernatant was filtered through a syringe filter (Advantech 0.45 µm filter, manufactured by Toyo Ichiro Paper Co., Ltd.) and transferred to a 2 mL vial.
これを高速アミノ酸アナライザー(HITACHI L_8500、 日立製作所製、生体液分析 法、イオン交換カラム No.855-3503)にセットして、遊離アミノ酸含有量を自動分析し た。 This is a high-speed amino acid analyzer (HITACHI L_8500, manufactured by Hitachi, Ltd.) Method and ion exchange column No. 855-3503), and the free amino acid content was automatically analyzed.
[0053] 標準液は、ァラニン及び γ—ァミノ酪酸を含む濃度既知の 40種のアミノ酸混合標準 液を用いた。このうち、ァラニンは分析開始力 約 37. 5分後のピーク、 γ—アミノ酪 酸は約 65. 5分後のピークに検出され、そのピーク面積比で、試料中のァラニン及び Ύ—ァミノ酪酸の含有量を算出した。  [0053] As a standard solution, a mixed solution of 40 amino acids containing known concentrations of alanine and γ-aminobutyric acid was used. Of these, alanine was detected at a peak after about 37.5 minutes of analysis starting power, and γ-aminobutyric acid was detected at a peak after about 65.5 minutes, and the ratio of peak area to alanine and Ύ-aminobutyric acid in the sample was determined. Was calculated.
[0054] 他方、対照として、玄米を水に浸漬せず (発芽させないで)そのまま用いる以外は、 上記した方法と同様にして試料を作成し、ァラニン及び Ί—ァミノ酪酸の含有量を分 祈した。分析条件等も上記と同じである。表 1にその分析結果をそれぞれ示す。 On the other hand, as a control, a sample was prepared in the same manner as described above, except that brown rice was used without immersion in water (without germination), and the contents of alanine and Ί -aminobutyric acid were prayed. . The analysis conditions are the same as above. Table 1 shows the analysis results.
[0055] [表 1] 表 1 [Table 1] Table 1
Figure imgf000009_0001
Figure imgf000009_0001
[0056] 表 1の結果から明らかなとおり、対照玄米に比べて、にがり成分 (塩ィ匕マグネシウム) を含む水溶液に浸漬して発芽させた実施例 1では、甘みや旨味を起こす物質である ァラニンと、医学的効果があるとされる γ—ァミノ酪酸が明らかに増加した。 As is clear from the results in Table 1, in Example 1, in which the germination was carried out by dipping in an aqueous solution containing a bittern component (Shiiro Magnesium) as compared to the control brown rice, alanine, a substance causing sweetness and umami, Γ-aminobutyric acid, which is considered to have medical effects, clearly increased.
[0057] (官能試験)  (Sensory test)
以上のようにして得られた発芽玄米(対照玄米と試験米の計 2種)を炊飯して官能 試験を行い、にがり成分 (塩ィ匕マグネシウム)の水溶液に浸漬するかしないかで、味 覚的な評価にどのような違いが生じるかを検討した。  The germinated brown rice (control brown rice and test rice in total) obtained as described above was subjected to a sensory test by cooking rice, and the taste was determined whether or not it was immersed in an aqueous solution of the bittern component (Shiidai magnesium). We examined what difference would occur in the global evaluation.
[0058] その結果、対照玄米に比べて、にがり成分 (塩化マグネシウム)を含む水溶液に浸 漬して発芽させたものでは、甘みと旨味を含めた食味が改善され、玄米臭が低減さ れていた。 [0058] As a result, when germinated by immersion in an aqueous solution containing a bittern component (magnesium chloride), the taste including sweetness and umami is improved, and the brown rice odor is reduced, as compared with the control brown rice. Was.
[0059] [実施例 2] [Example 2]
(マグネシウムについて)  (About magnesium)
各々脱イオン水 1Lに塩ィ匕マグネシウム 1. 5gを溶解し、塩化マグネシウム濃度を 1. 5% (重量/容量)に調整した水溶液を得た。この水溶液に上記した原料玄米を各々 lkgを投入し、表 2に示した設定時間どおりに浸漬した。 Dissolve 1.5 g of magnesium salt in 1 L of deionized water and adjust the magnesium chloride concentration to 1. An aqueous solution adjusted to 5% (weight / volume) was obtained. To this aqueous solution, lkg of each of the above-mentioned raw brown rice was added and immersed for the set time shown in Table 2.
[0060] 浸漬後、ステンレス製のざるに揚げて水切りし、 4°Cの低温室内で通風乾燥して含 水率を約 14. 5%に調整した。 [0060] After immersion, the plate was fried in a stainless steel bar, drained, and air-dried in a low-temperature room at 4 ° C to adjust the water content to about 14.5%.
このようにして、試験米 4種 (No.4 7)を調整後、各々 30gを粉砕して米粉 1. 000 gを秤量した。  In this way, after preparing four kinds of test rice (No. 47), 30 g of each was crushed and 1.000 g of rice flour was weighed.
[0061] これを 1%塩酸溶液 lOOmLに投入し、良く振とうしてミネラルを抽出し、適宜希釈し て原子吸光光度計 (HITACHI Z8200型)により、マグネシウムを測定し、その結果は 原料米 lOOg中の mgとして表 2に示した。  [0061] This was poured into lOOmL of a 1% hydrochloric acid solution, shaken well to extract minerals, diluted appropriately, and measured for magnesium using an atomic absorption spectrophotometer (HITACHI Z8200 type). The results are shown in Table 2 as mg.
[0062] 他方、対照玄米として、玄米を水に浸漬せずにそのまま用いる以外は、上記した方 法と同様にして試料を作成し、マグネシウムの含有量を分析した。分析条件等も上記 と同じである。その結果も併せて表 2に示す。 On the other hand, as a control brown rice, a sample was prepared in the same manner as described above except that brown rice was used without immersion in water, and the content of magnesium was analyzed. The analysis conditions are the same as above. Table 2 also shows the results.
[0063] [表 2] [0063] [Table 2]
表 2  Table 2
Figure imgf000010_0001
Figure imgf000010_0001
[0064] 表 2の結果から明らかなとおり、玄米をにがり成分 (塩ィ匕マグネシウム)を含む水溶 液に浸漬することにより、玄米に含まれるマグネシウムの含有量を増加させることがで きた。  As is clear from the results in Table 2, it was possible to increase the content of magnesium contained in brown rice by immersing brown rice in an aqueous solution containing a bittern component (magnesium salt).
[0065] なお、本明細書で使用している用語と表現はあくまで説明上のものであって、限定 的なものではなぐ上記用語、表現と等価の用語、表現を除外するものではない。 産業上の利用可能性  [0065] Note that the terms and expressions used in the present specification are for explanation only, and do not exclude the above-mentioned terms and expressions equivalent to the expressions and expressions which are not limiting. Industrial applicability
[0066] 以上のように、本発明によれば、に力 ^成分または塩化マグネシウムを含む水溶液 に玄米や雑穀等の穀類を浸漬して発芽させることにより、アミノ酸の一種で甘みや旨 味を起こす物質であるァラニンの含有量と、血圧降下作用や脳の代謝促進作用など の医学的効果があるとされる Ίーァミノ酪酸の含有量を高めた発芽雑穀を得ることが できる。よって、この発芽雑穀を用いた本発明に係る食品素材または食品は、ァラニ ンによって甘みや旨味等の食味がより美味しく向上しており、食すことにより γ—アミノ 酪酸を手軽に摂取することができる。 [0066] As described above, according to the present invention, a kind of amino acid causes sweetness and taste by immersing cereals such as brown rice and millet in an aqueous solution containing a component or magnesium chloride to cause germination. It is possible to obtain germinated cereals with an increased content of alanine, a substance, and a higher content of peraminobutyric acid, which is considered to have medical effects such as hypotensive action and brain metabolism promoting action. it can. Therefore, in the food material or food according to the present invention using the germinated cereals, the taste such as sweetness and umami is improved by aranine, and γ-aminobutyric acid can be easily consumed by eating. .
[0067] 更に本発明によれば、玄米や雑穀を用いて発芽穀類を得た場合の特有の臭み、 いわゆる「玄米臭」や「雑穀臭」等を低減させることができる。よって、その特有の臭み によって食品素材または食品の甘みや旨味が損なわれることを防ぐことができるのでFurther, according to the present invention, it is possible to reduce the peculiar smell when germinated cereals are obtained using brown rice or millet, so-called “brown rice smell” or “millet odor”. Therefore, it is possible to prevent the sweetness and umami of the food material or food from being impaired by the unique odor.
、食味をより向上させることができる。 , The taste can be further improved.
[0068] 更に本発明によれば、マグネシウムの含有量を高めた発芽雑穀を得ることができる[0068] Further, according to the present invention, germinated cereals with an increased magnesium content can be obtained.
。よって、この発芽雑穀を用いた本発明に係る食品素材または食品を食すことで、人 体にとって極めて重要な必須微量元素の一種であるマグネシウムを手軽に摂取でき る。 . Therefore, by eating the food material or food according to the present invention using the germinated cereals, magnesium, which is one of the essential trace elements extremely important for the human body, can be easily taken.
[0069] 早刈り緑色米から得た玄米を使用したものは、通常の玄米を用いた場合と比べて、 玄米独特の「玄米臭」をより効果的に低減させることができる。  [0069] Brown rice obtained from early-cut green rice can more effectively reduce the brown rice odor peculiar to brown rice as compared with the case of using normal brown rice.

Claims

請求の範囲 The scope of the claims
[1] にがり成分または塩化マグネシウムを含む水溶液に穀類を浸漬して発芽させた発 芽穀類を用いたことを特徴とする、  [1] A germinated cereal obtained by immersing cereal in an aqueous solution containing a bittern component or magnesium chloride, and using germinated cereal.
食品素材または食品。  Food material or food.
[2] にがり成分または塩化マグネシウムを含む水溶液に穀類を浸漬し発芽させてァラニ ンを富化した発芽穀類を用いたことを特徴とする、  [2] A germinated cereal obtained by immersing cereal in an aqueous solution containing a bittern component or magnesium chloride and germinating to thereby use an aranine-enriched germinated cereal.
食品素材または食品。  Food material or food.
[3] にがり成分または塩化マグネシウムを含む水溶液に穀類を浸漬し発芽させてァラニ ン及びマグネシウムを富化した発芽穀類を用いたことを特徴とする、  [3] A germinated cereal enriched in alanine and magnesium by immersing the cereal in an aqueous solution containing a bittern component or magnesium chloride and germinating the germ,
食品素材または食品。  Food material or food.
[4] にがり成分または塩化マグネシウムを含む水溶液に玄米または雑穀を浸漬し発芽 させてァラニンを富化した発芽玄米または発芽雑穀を用いたことを特徴とする、 食品素材または食品。  [4] A food material or food characterized by using germinated brown rice or germinated cereals that are enriched in aranine by immersing brown rice or cereals in an aqueous solution containing a bittern component or magnesium chloride and causing germination.
[5] にがり成分または塩化マグネシウムを含む水溶液に玄米または雑穀を浸漬し発芽 させてァラニン及びマグネシウムを富化した発芽玄米または発芽雑穀を用いたことを 特徴とする、  [5] A germinated brown rice or a germinated millet enriched with alanine and magnesium by immersing brown rice or a millet in an aqueous solution containing a bittern component or magnesium chloride to cause germination,
食品素材または食品。  Food material or food.
[6] 玄米は早刈り緑色米から得たものであることを特徴とする、 [6] Brown rice is obtained from early-cut green rice,
請求項 4または 5記載の食品素材または食品。  A food material or food according to claim 4 or 5.
[7] にがり成分または塩化マグネシウムを含む水溶液に穀類を浸漬して発芽させること を特徴とする、 [7] germinating by immersing cereals in an aqueous solution containing a bittern component or magnesium chloride,
発芽穀類の製造方法。  Method for producing germinated cereals.
[8] にがり成分または塩化マグネシウムを含む水溶液に穀類を浸漬して発芽させること により、発芽穀類の特有の臭みを低減させることを特徴とする、  [8] By immersing cereals in an aqueous solution containing a bittern component or magnesium chloride to germinate, the characteristic odor of germinated cereals is reduced.
発芽穀類の臭み低減方法。  A method for reducing the odor of germinated cereals.
PCT/JP2004/007364 2003-05-28 2004-05-28 Food material or food using germinant grain, process for producing germinant grain and method of reducing germinant grain odor WO2004105513A1 (en)

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