WO2004103722A1 - Method of producing an integral plastic structure and structure thus obtained - Google Patents

Method of producing an integral plastic structure and structure thus obtained Download PDF

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Publication number
WO2004103722A1
WO2004103722A1 PCT/ES2004/000196 ES2004000196W WO2004103722A1 WO 2004103722 A1 WO2004103722 A1 WO 2004103722A1 ES 2004000196 W ES2004000196 W ES 2004000196W WO 2004103722 A1 WO2004103722 A1 WO 2004103722A1
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WO
WIPO (PCT)
Prior art keywords
layer
holographic
selectively
derivative
deposit
Prior art date
Application number
PCT/ES2004/000196
Other languages
Spanish (es)
French (fr)
Inventor
Francisco COBIÁN GARCÍA
Original Assignee
I.D. Tec, S.L.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from ES200301228A external-priority patent/ES2220222B1/en
Application filed by I.D. Tec, S.L. filed Critical I.D. Tec, S.L.
Publication of WO2004103722A1 publication Critical patent/WO2004103722A1/en

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Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H1/00Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
    • G03H1/02Details of features involved during the holographic process; Replication of holograms without interference recording
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B42BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42DBOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/30Identification or security features, e.g. for preventing forgery
    • B42D25/328Diffraction gratings; Holograms
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H1/00Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
    • G03H1/02Details of features involved during the holographic process; Replication of holograms without interference recording
    • G03H1/024Hologram nature or properties
    • G03H1/0244Surface relief holograms
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H1/00Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
    • G03H1/04Processes or apparatus for producing holograms
    • G03H1/18Particular processing of hologram record carriers, e.g. for obtaining blazed holograms
    • G03H2001/187Trimming process, i.e. macroscopically patterning the hologram
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H2250/00Laminate comprising a hologram layer
    • G03H2250/36Conform enhancement layer

Definitions

  • the present invention relates both to a method of obtaining an integral plastic structure and to the structure obtained, which comprises a holographic structure that includes a holographic product deposit of SZn, TiOx, SiOx, ZrOx, metallic aluminum
  • the invention is applicable in obtaining documents, identity and credit cards, passport visas, banknotes and paper documents. It is also the object of the present invention to apply the three holographic deposit procedures limited to specific and specific areas and lines of the substrate, to obtain holographic sheets for packaging, for packaging and for holographic labels for the protection of high security containers.
  • the present invention also relates to the structure of combined holographic laminate of deposit of holographic product both transparent HRI (high reflective index) and deposit of metal holographic product on the same substrate, performed by sequential application of the deposit procedures object of the present invention as the conventional PVD method of depositing holographic product. It is also the object of the present invention the structure resulting from the application of the transparent and metallic HRI combined holographic laminate in the structure of documents and identity cards integrally of polycarbonate layers.
  • the present invention also relates to the structure of superfine holographic laminate resulting from the deposition of holographic product by PVD (physical vapor deposition) procedure on a recordable plastic (shims and plastic bossable) preferably by recordable lacquer that polymerizes by the action of the UV light or by the action of electronic radiation.
  • This holographic reservoir is preferably encapsulated with lacquer or with a thermo-adhesive.
  • the heat-oriented polyester carrier sheet is separated from this structure.
  • Said holographic laminate is applicable to both banknotes, passports, visas and in documents or plastic cards.
  • the present invention also relates to the encapsulation of the lines and zones of this holographic deposit specifically limited to those areas of the substrate, by adding different layer structures depending on the type of document customization.
  • These specific structures of laminate or holographic cover are both HRI (high reflective index) type transparent and with high security metallic Holographic layer for protection of documents and identity and credit cards in general and in particular for effective protection against manipulations fraudulent identity documents whose structures are also subject to the patent.
  • Said holographic covers or holographic laminates of both types apply specifically to integrally plastic documents as well as paper-backed documents such as passport books and visas.
  • These laminates Holographic so structured specifically are integrated in turn in the different types of documents consisting entirely of plastic materials that heat and heat weld together forming a card that is damaged and irreversibly broken in fraudulent attempts to delaminate and separate their layers.
  • the high security conferred by the different holographic laminate modalities of the present invention is fundamentally based on the encapsulation of the holographic deposit layer, as well as the specific security protection and improvement measures that are additionally applied to holographic laminates produced by the conventional procedure and which are part of the present invention.
  • the invention also relates to the specific configuration and adaptation of the plastic layers of both the holographic laminate itself and the core of the document and subsequent protective cover so that the different modalities of personalization can be carried out, that is to say color printing by the thermosublimation system , by injection of colored ink, by laser printing with color toner and by engraving with destructive laser beam (burning) respectively of the source of the infrared spectrum, or green or blue, of both the facial image and personal data and signature and fingerprint of the document holder.
  • the document structures provided for in the present invention patent provide for the combined customization of several of these customization modalities in different layers or layers, to confer high security on the document.
  • the invention also relates to the solidary adaptation to the plastic structure of the identity card card, of the 2 types of holographic protection, either HRI (high reflection index) type or holographic deposit Al (aluminum), Ag (silver) or Bi (bismuth), with demetalization after its deposit, so that these holographic protection structures object of the invention are integrated and encapsulated in solidarity within the plastic structure of identity cards and documents in their possible variants, applying a generic adhesive for plastics or selectively a two-component polyurethane based adhesive to directly adhere the holographic layer of the holographic laminate to the card structure and encapsulating said holographic layer so that it is thermolaminated with the rest of the identity card structure constituting a non-delalable body when applying heat and common reagents and solvents.
  • HRI high reflection index
  • Al aluminum
  • Ag silver
  • Bi bismuth
  • holographic laminates - Holographic aluminum metallic laminates and polymeric holographic laminates with vacuum vaporization of metallic deposit, generally aluminum. Both laminates are opaque and therefore cannot effectively protect an identity document by transparency once the constituent layers of said document have been heat-laminated. Therefore they are applied as a security element with a deterrent character.
  • These two types of holographic laminates have the disadvantage that they can be cut from the original document and reused in fraudulently reproduced documents of the respective original documents, with change of personal data and fundamentally with replacement of the original printed facial image with another identity that generally with Both types of holographic laminates are only protected in a testimonial way.
  • Such opaque metallic laminates are applied in identity documents and driving license cards of both PVC like polycarbonate.
  • Transparent holographic laminates type HRI high reflective index
  • SZn or Ti0 2 deposit that are transparent and therefore could protect both the facial image printed or recorded with laser beam and the personal data of a thermo-laminated identity document.
  • the HRI thermo-laminated holographic laminate in a document or identity card is delaminated and separated without any apparent damage with the action of solvents and chemical reagents as common as acetone, ammonia hydrocarbons etc ... which represents a serious inconvenience for the security of the identity document since said laminate HRI HRI can therefore be fraudulently reused in another document reproduced from the original with facial image replaced by another identity.
  • the present invention thus relates to specific basic structures of holographic laminates of both transparent HRI type and aluminum metallized type, in which the deposition of the holographic product is carried out in very defined and concrete areas of the substrate that thus allows encapsulation between layers of said figures, logos and holographic shields, so that the respective thermo-laminated documents and identity cards are not delaminated by the continued action of water or by the action of common chemical solvents and reagents, and are always irreversibly damaged in the delamination attempts.
  • the present invention basically consists of a method comprising obtaining a holographic structure, both of transparent HRI type (high reflective index) and metallic holographic laminate that includes a deposit of a holographic product that forms a holographic layer; the holographic product deposit is made selectively by SZn, TiOx, SiOx, ZrOx, aluminum (Al), bismuth (Bi), or silver (Ag); and said Deposit is limited only to specific areas and lines selectively on a surface of the same substrate consisting of a layer selected from durable plastic (durable plastic), polycarbonate (PC) or oriented polyester; or on a surface of a layer, selected from acrylic or lacquer derivative that polymerizes and hardens by the selective action of ultraviolet (UV) light or by the action of electronic radiation.
  • a holographic structure both of transparent HRI type (high reflective index) and metallic holographic laminate that includes a deposit of a holographic product that forms a holographic layer
  • the holographic product deposit is made selectively
  • the invention provides for 2 basic specific structures of holographic covers or laminates of both the transparent HRI type and the metallic type, in which by means of two of the alternative methods of deposition by vacuum vaporization, object of the present invention, is carried out zonally the holographic deposit of the figures and logos on the substrate limited to the constituent lines of the engraving (embossing) of said figures and logos.
  • the object of the present invention is the encapsulation of said lines and holographic zones of the figures and logos by the addition of different alternative layers for the high security protection of the different types of documents and identity cards. Therefore, the three alternative methods of depositing the holographic layer applied to three differentiated processes are the object of the present invention: the first one, the conventional PVD process
  • the second PVD process also object of the invention is a specific PVD process in continuous and in holographic deposit coil by vacuum vaporization or atmospheric pressure, in concrete and localized areas of the holographic element deposited using an endless belt in which they have been Performed the perforations corresponding to the figures and logos for the passage of the holographic deposit through them.
  • the third vacuum vaporization deposition procedure is performed on substrate sheets.
  • the invention provides a method of depositing holographic product by vacuum vaporization or atmospheric pressure that is performed on the substrate cut into individualized sheets of the holographic laminate instead of making said deposit on coil.
  • this holographic laminate is constituted by a polyester or PC sheet on which the acrylic or preferably lacquer derivative layer is deposited, which polymerizes and hardens by the action of UV light or by the action of electronic radiation or by The action of the air.
  • This set is cut into sheets, each of which is previously hot embossed with the metal engraving tool (shims) designed to produce the respective recesses that constitute the holographic figures and logos.
  • silicone derivative and selectively with oil or vegetable wax compound and preferably with carnauba wax-paraffin around the lines and areas where the slits, respectively, of the holographic figures and logos have already been hot embossed.
  • the sheets are then introduced into a stacker-feeder, which by means of roller sets transports each sheet individually through the slot gate and supported by lateral guides, to a vacuum PVD vaporization chamber or atmospheric pressure of the product holographic that is selectively vaporized by heating, by magnetron (sputtering), by ionic ray, by electron beam, or by arc; the passage of each sheet through the chamber (vaporization produces the holographic deposit on the surface covering only areas free of silicone derivative printing; since this prevents the holographic product from being deposited.
  • a stacker-feeder which by means of roller sets transports each sheet individually through the slot gate and supported by lateral guides, to a vacuum PVD vaporization chamber or atmospheric pressure of the product holographic that is selectively vaporized by heating, by magnetron (sputtering), by ionic ray, by electron beam, or by arc; the passage of each sheet through the chamber (vaporization produces the holographic deposit on the surface covering only areas free of silicone derivative printing; since this prevents the
  • the sheets already provided with holographic deposit below they are transported by the respective drive wheels of the lateral guides and by the rollers to the output stacker, so that the rollers are driven synchronously by a stepper motor that is controlled by a processor by means of the passing and positioning signals of each sheet as it passes through optoelectronic sensors, the sheets are then cleaned in a vacuum chamber with oxygen plasma 0 2 where the silicone derivative is released, and where appropriate the generic synthetic oil from the respective printed areas.
  • a specific embodiment of the present invention is that corresponding to a structure comprising a combined holographic structure, with a holographic product deposit transparent HRI type (high reflective index) on specific areas of the recordable substrate (plastic embossable shims) and holographic product deposit metallized on other specific areas of the same recordable substrate;
  • This combined holographic structure consists of an oriented polyester or durable plastic support sheet (durable plastic), both in coil and in sheets, on whose surface, prior discharge of corona effect or prior plasma treatment 02, comprises a deposit or impression of silicone wax or vegetable wax preferably of carnauba wax / paraffin that forms a layer, on which a print or deposit is included, prior to corona discharge or pre-treatment of plasma O2, of recordable plastic, preferably of recordable lacquer that hardens by the action of UV light or by the action of electronic radiation, or from the air, thus forming the layer; then the mentioned surface comprises an embossing made by means of a pressure tool
  • the metal holographic product being selectively constituted by at least one of the Al, Bi, or Ag product; being thus constituted on the surface of the substrate, the holographic layer of combined holographic deposit, formed by the corresponding holographic zone transparent HRI and metallic deposits constituting a common holographic surface; then, after discharge of corona effect or prior treatment of plasma O2, it comprises a layer Zone of encapsulation preferably of lacquer that hardens by the action of UV light that corresponds to the areas of the holographic surface of the combined holographic deposit layer on which only the selective deposit of HRI transparent holographic product has been made; then it includes a gradual demetalization of the deposit of metallic holographic product; and then it comprises the encapsulation zone, preferably with lacquer, of the part of the surface corresponding to the metallic holographic product deposit, thus forming the layer on which another layer is adhered or deposited which according to the type of application of the Combined hol
  • thermo-laminated assembly comprises transparent polycarbonate sheets, on both sides of the core constituted by polycarbonate sheets, on a specific part whose surface is attached to the structure of the combined hologram containing the zonal metal hologram that is customized by means of destructive laser engraving (burning) before or after the thermo-lamination of the core with the transparent polycarbonate sheet covers; including in the laser engraving of personalization a recording of personal data and the replica of the facial image of the holder of the identity document; the combined zonal hologram being a transparent metallic zonal hRI produced by a PVD method of vaporization of a respective holographic product
  • the present invention includes a specific embodiment of holographic structure applied to banknotes, passports, visas and documents comprising a holographic structure comprising a holographic structure, selectively of transparent HRI type (high reflective index) or of metallic holographic laminate; said holographic structure is constituted by an oriented polyester support sheet or durable plastic (durable plastic), both in coil and in sheets, on whose surface, after corona discharge or plasma pretreatment 02, they are printed with silicone wax or with vegetable wax preferably with carnauba wax / paraffin only one layer that constitutes lines and zones that coincide with the lines and zones corresponding to the holographic figures, shields and logos; on whose layer or lines and areas thus printed are printed in turn with recordable plastic, preferably with recordable lacquer that hardens by the action of light (UV) or by the action of electronic radiation or by the action of air, prior to discharge of corona effect or pre-treatment of O2 plasma, covering the lines and areas with a hardened etchable lacquer; an emboss
  • Another embodiment of the present invention consists of a holographic laminate structure comprising a holographic structure, selectively of transparent HRI type (high reflective index) or of metallic holographic laminate, which is constituted by an oriented polyester or durable plastic support sheet ( durable plastic), both in coil and in sheets, on whose surface, prior discharge of corona effect or prior plasma treatment 02, the layer of silicone wax or vegetable wax is preferably deposited, preferably wax / carnauba paraffin, on whose previous surface corona discharge or plasma pretreatment 02, a layer consisting of at least one of the following products is deposited: acetate derivative, polyolefin derivative, polypropylene derivative, acrylic derivative, derivative silicone, epoxy derivative, polyurethane derivative, polyethylene terephthalate derivative, or preferably by lacquer, which hardens by the action of UV light or by the action of electronic radiation, and then after corona discharge or prior treatment of Plasma 02, the acrylic derivative layer is deposited on whose surface the engraving is made
  • the holographic product is deposited by means of a PVD (physical vapor deposition) deposition procedure that covers only specific lines and areas of the holographic product surface or by PVD (physical vapor procedure) deposition) of conventional deposit covering the entire surface of the holographic product layer, thus constituting the holographic layer containing the holographic figures and logos; then, after discharge of corona effect or prior plasma treatment 02, an encapsulation of the holographic surface is included, with a layer that depending on the type of application of the holographic laminate thus constituted is selectively formed by one of the following compounds: by lacquer which hardens selectively by the action of UV light or by the action of the radiation of electronic radiation or by air, by deposit selected from polyolefin derivative PE or polypropylene, - selectively by thermal adhesive for paper or preferably by ethylene-acrylic acid
  • polyvinylchloride chloride for D2T2 thermosublimation personalization printing, by a layer of polyurethane-based thermo-adhesive which in turn adheres a modified PET-G derivative layer
  • the specific structures of the core of the document or identity card are essential part of the present invention to adapt to the different customization modalities and that weld together with the respective holographic cover structure or sheet (both HRI and metallized) object of the present invention
  • adhesives composed of PVDC (polyvinylchloride) with the addition of vinyl and optionally chloronitrile or special lacquers that quickly harden in a few seconds by polymerization by the action of UV light (photonic action) or by the action of electron radiation or primers of both mono and bicomponent polyurethane derivatives.
  • Said lacquer is selectively constituted by multifunctional monomeric acrylates based on polyols as reactive diluents (thinners) and oligomeric acrylates as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon-acrylate, urethane-acrylate, epoxy-silicone, including its dilutable and water-emulsifiable versions.
  • a layer of acrylic compound is deposited on said layer.
  • the holographic product is deposited by vacuum vaporization, having previously directly etched (embossing) the grooves with the metal engraving tool (shims) designed with the corresponding figures and logos .
  • Said applied lacquer polymerizes and hardens by the action of UV light or, if appropriate, by the action of electronic radiation or by the action of air, and is selectively constituted by multifunctional monomeric acrylates based on polyols as reactive diluents (thinners) or oligomeric acrylates as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon acrylate, urethane-acrylate, epoxy-silicone, and their corresponding water-dilutable and emulsifiable versions.
  • the hot grooves are engraved directly with a metal engraving tool (shims) designed with the corresponding figures and logos;
  • the holographic product is then deposited by vacuum vaporization. From each of these two structures thus constituted, a coil is obtained which is processed in a vacuum vaporization chamber in which the vaporization is selectively produced by heating, by magnetron effect (sputtering), by arc action, by action of ionic ray, of at least one holographic deposit product of at least one of the elements consisting of SZn, TiOx, SiOx, zirconium oxide, Al, Ag or Bi.
  • the holographic deposit on the surface on which the indentations of the engraving lines of the figures and logos (embossing) have been made is made through perforations made on a metal or plastic endless belt or band that flows together with the coil support to be deposited inside the vacuum vaporization chamber or at atmospheric pressure dragged by the corresponding rollers through the respective slots of entry into the chamber.
  • the aforementioned perforations correspond to the lines of the figures and template logos, so that the punched and negative perforations have been practiced that are much wider and much wider than those corresponding to the original design and allow the holographic deposit to pass widely vaporized covering only the corresponding areas on the substrate surface of the coil that already contains the respective embossing lines and areas; the aforementioned ribbon with the punched holes of the figures and logos in negative moves synchronously with the support of the coil to be deposited with holographic product controlled by sensors that through a processor acts on the drive motor of the said belt or perforated band in order to adjust its positioning with respect to the areas where in the support of the coil embossing of the slits corresponding to the lines of the figures and holographic logos were performed.
  • the rewind of the coil is carried out continuously at a uniform speed depending on the deposit thickness of the holographic product deposit that has been previously calculated.
  • the process of continuous deposition of vacuum vaporization of the holographic product, object of the present invention achieves that this holographic deposit is carried out over very specific and specific areas so that the surface that forms the lines that constitute the engraved holographic figures and logos (embossing) remain without deposit which allows encapsulating the embossing lines and areas of the aforementioned holographic deposit with the different types of enclosure layer that are contained in the present invention and that confer a very high closing adhesion and therefore security .
  • These two basic structures A and B of holographic cover or laminate are derived by the addition of specific plastic layers to encapsulate the holographic layer and also make viable the different document structures combined with the corresponding customization modalities of the different possible document configurations of identity, so that they weld solidaryly constituting documents of very high security that are irreversibly damaged in any fraudulent attempt at delamination and handling.
  • the holographic layer is encapsulated by respective addition of the following layer configurations on the holographic surface of the two basic holographic roof structures A and B:
  • a layer is preferably deposited with lacquer that polymerizes and hardens by the action of UV light and, where appropriate, by the action of electronic radiation or by the action of air , so that the lacquer is selectively constituted by multifunctional monomeric acrylates based on polyols as reactive diluents (thinners) and oligomeric acrylates as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon acrylate, urethane acrylate, epoxy silicone, and their corresponding water-dilutable and emulsifiable versions.
  • corona discharge is previously carried out and then on the holographic face, it is hot deposited by coextrusion of the generic base-layer adherent compound (tie-layer) together with the modified PET-G derivative (polyethylene glycol terephthalate) and preferably of modified PET-G derivative with micronized carbon additive with flame suppressor inhibitor and, where appropriate, with oxide oxide additive titanium
  • thermo-adhesive preferably composed of ethylene-acrylic acid and alternatively by at least two of the following elements: gelatin, acrylic derivatives, acrylic acids, polyamide and polyurethane derivatives, so that the layer thus constituted thermolamine with the paper of the passport data sheet or document in general.
  • Corona effect discharge is previously carried out and then a layer of polyolefin polymer thermoadhesive composed of polyethylene or modified polyethylene, or polypropylene is deposited selectively by hot injection or extrusion.
  • a generic adhesive is preferably applied to plastics, preferably bicomponent based on polyurethane that adheres the layer consisting of a PET-G modified derivative sheet (polyethylene taraphthalate - glycol) with or without a micronized carbon additive that has a radio frequency chip embedded and integrated with its respective antenna.
  • a hot layer is already deposited selectively by hot injection, by offset printing, by screen printing, or by extrusion, so that it laminates with the paper of the passport or visa data sheet or document in general, providing it with A security chip
  • the object of the present invention is also the structure of a core (C) comprising a central assembly with 1 an layers (Cl, C2, ..
  • a modified PET-G derivative layer is extruded with generic additive for destructive laser beam engraving, or micronized carbon additive with flame inhibitor suppressor, in one of its layers it includes an integrated radio frequency chip with antenna, and on whose face it Deposits, after discharge of corona effect, by one of the following procedures: extrusion, hot injection, screen printing, corrosive printing, by hot stamping, a layer consisting of its entire surface selectively by at least one of the following elements : Vinyl derivative, PVDC (polyvinylchloride chloride), acrylonitrile, so that on this last surface, personalization of personal data and facial image is printed by im color pressure
  • the specific structuring of the core of the identity document is also an object of the invention so that it allows the specific personalization modality and a complete heat-welding is obtained both between the constituent layers of said core and with the holographic protective or laminated covers forming a non-delalable body .
  • modified PET-G one of whose layers includes an integrated radio frequency chip with antenna, and on at least one of its faces is thermolaminated or a layer is coextruded PET-G modified derivative with generic additive for destructive laser beam engraving, or micronized carbon additive with flame inhibitor suppressor, on whose face it is deposited in turn, after corona discharge, by one of the following procedures: extrusion , hot injection, silkscreen printing, corrosive printing, by hot stamping, a layer with a specific limited surface and on a specific area, consisting of one of the following products: • Selectively by at least one of the following elements: vinyl derivative, PVDC (polyvinylchloride chloride), acrylonitrile, polyurethane derivative, so that on the limited surface of the core, the customization is printed facial and personal data agen with D2T2 color thermosublimation printing.
  • PVDC polyvinylchloride chloride
  • acrylonitrile polyurethane derivative
  • one or both faces of the core consisting of layers of modified PET-G derivative, prior to corona discharge, are treated superficially on which it is deposited, by one of the following procedures: extrusion, hot injection, screen printing, printing corrosive, by hot stamping, a thin layer of up to about 15-20 ⁇ over the entire surface, consisting of modified PET-G derivative with generic additive for laser engraving or micronized carbon or titanium oxide additive and with suppressor flame inhibitor, so that on the surface of the core so constituted it is etched with destructive laser beam
  • PET-G polyethylene teraphthalate glycol
  • the present invention contains the specific structure of the outer back cover for protection of the identity document adapted and compatible both to obtain a single body or delaminable in the thermo-lamination with the specific core which is also the object of the present invention.
  • Said cover is constituted by a sheet of polyester or durable plastic to which a derivative layer has been adhered with preferably polyurethane-based adhesive PET-G modified.
  • the present invention provides that as a prior stage to each of the processes of layer deposition, adhesive deposit, holographic product deposit, lacquer printing, silicone or oil derivative printing, object of structuring and production of all structures of the present invention, pretreatment of the corresponding surface with vacuum plasma of oxygen 0 2 and selectively vacuum plasma of hydrogen H 2 , and where appropriate with the corresponding atmospheric plasma is applied. In this way the adhesion between layers increases by a factor that exceeds 200.
  • the present invention contains, by way of example, 3 preferred identity document structures of the many possible ones that can be constituted with the corresponding elements that are the object of the present invention.
  • Each of these 3 structures refers to a combination of said constituent elements that give the highest security to the identity document against delamination and fraudulent manipulation, reproduction and falsification.
  • the invention relates to the constituent elements of the holographic laminate to which at least one of its layers: either the polyester layer of the protective sheet, either the layer constituted by lacquer selectively polymerizable by the action of UV light or by the action of electronic radiation or by the action of air, either the primer layer, or even the layer of acrylic derivatives of the respective holographic laminate, both transparent HRI type and metallic type, is added in its Selectively dough a generic additive for laser engraving or a micronized carbon additive with flame suppressor inhibitor, to perform custom engraving of CLI structures (change laser image) on surface by destructive laser beam (burning).
  • CLI structures change laser image
  • burning destructive laser beam
  • the procedures for depositing holographic product limited to specific areas and lines on the substrate, object of the present invention are applicable to the holographic deposit directly on the sheet of a container or packaging surface, or container label selectively constituted by oriented polyester or by durable plastic (durable plastic).
  • Figure 1 schematically represents the basic structure A of one of the holographic laminates object of the present invention, in which the embossing layer that constitutes the holographic layer is composed of acrylic derivative which in turn carries deposited a layer of primer or a thin layer of a special lacquer polymerizable by the action of UV light or electronic radiation that adheres to the polyester cover.
  • Figure 2. Schematically represents the basic structure B of the holographic laminates object of the present invention, in which the special lacquer layer polymerizable by the action of UV light or electronic radiation or air, is directly engraved ( embossing) and on it the holographic layer is deposited by vacuum vaporization.
  • Figure 3. schematically represents a basic structure of a holographic laminate object of the present invention. It is constituted by a structure of a conventional holographic laminate in which the embossing layer is composed of acrylic derivative on which the entire surface is deposited.
  • holographic layer A thin silicone emulsion film or silicone synthetic wax emulsion is printed or deposited between the acrylic layer and the polyester cover.
  • a new layer that can be modified PET-G or polyester derivative is adhered with polyurethane base adhesive.
  • Figure 4. schematically represents the process of separating the polyester layer from the holographic sheet structure in which the coil is heat treated.
  • Figure 4a - schematically represents the structure of superfine holographic laminate resulting from depositing holographic product by PVD (physical vapor deposition) procedure on a recordable plastic (plastic embossable shims) preferably by recordable lacquer so that the holographic deposit It is preferably encapsulated with lacquer or with a thermo-adhesive.
  • the heat-oriented polyester carrier sheet is separated from this structure.
  • Figure 5. schematically represents an example of holographic final deposit design.
  • Figure 6. schematically represents the modification of a holographic PVD deposit chamber by vacuum vaporization for the realization of the PVD process in coil and in continuous holographic deposition through the perforations made in an endless belt or band.
  • Figure 6a - schematically represents a PVD holographic deposit chamber by vacuum vaporization for the realization of the holographic deposition process on specific and limited areas of the substrate in sheets of the holographic laminate.
  • Figure 7. schematically represents an exemplary detail of the shield of the design of the embossing on which the holographic layer is deposited by vacuum vaporization.
  • Figure 7a schematically represents the perforations corresponding to the lines of a holographic figure which, by way of example, is a shield, made in the tape or band flowing in the deposit chamber coincidentally with the coil substrate.
  • Figure 8. schematically represents the configuration of the endless belt provided with the perforations and negative die cuts through which the vaporized holographic product covering the lines and areas that are deposited are deposited on the area of the corresponding layer of the polyester sheet they form the engraved figures and logos (embossing).
  • Figure 8a. schematically represents the areas that are covered with the impression of the paraffin wax of carnauba or the silicone compound, leaving the areas where the engraving of the figures and logos that have been previously made without covering if deposited with the holographic compound.
  • Figure 9 schematically represents the final structure of the holographic deposit that is conveniently covered by one of the layer structures object of the present invention that in turn encapsulate said holographic deposit.
  • Figure 10 schematically represents the structure of one of the holographic laminates object of the present invention for identity documents, passports, visas and banknotes, in which the embossing layer included in the holographic structure It is composed of a thin layer of a recordable lacquer, on which the transparent HRI holographic product limited to one zone is deposited by PVD process first and in the remaining zone of said substrate metal holographic product is deposited.
  • Figure 10a schematically represents the structure of the transparent combined hologram HRI and metallic Hmz adhered on the top cover Lpc of polycarbonate or on the core C also of polycarbonate PC being thermo laminated the set with transparent Lpc sheets of polycarbonate on both sides of said core.
  • Figure 10b schematically represents the structure of one of the holographic laminates object of this for identity documents, passports, visas and banknotes, in which the embossing layer included in the holographic structure is composed of a thin layer of a recordable lacquer, on which the transparent HRI holographic product limited to one zone is deposited by PVD process first and in the remaining area of said substrate metal holographic product is deposited
  • Figure 11. shows how to complete, close and encapsulate the holographic layer relative to the basic structure A, with a layer of PET-G derivative bonded sheet with or without ray engraving additive destructive laser (burning).
  • Figure 12. - schematically and by way of example shows how to complete, close and encapsulate the holographic layer relative to the basic structure A, with coextrusion together with its corresponding base-layer (tie-layer) of a PET-derived layer G with or without destructive laser engraving (burning) additive
  • Figure 13. - schematically and by way of example shows how to complete, close and encapsulate the holographic layer relative to the basic structure A by depositing a layer consisting of at least one of the following elements: vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile, derivative of polyurethane
  • Figure 14 schematically and by way of example shows how to complete, close and encapsulate the holographic layer relative to the basic structure A, by depositing ethylene-acrylic acids with polyurethane, for thermolamination as protection of a passport booklet and of visas.
  • Figure 14a - schematically and by way of example shows how to complete, close and encapsulate the holographic layer relative to the basic structure A, by depositing ethylene-acrylic acids with polyurethane, for thermolamination as protection of the passport booklet and of visas, in whose PET-G layer a radio frequency chip with antenna has been inserted and integrated.
  • Figure 15. - schematically and by way of example shows how to complete, close and encapsulate the holographic layer relative to the basic structure A, on whose inner face a layer of thermo-adhesive composed of polyolefin polymers or polyethylene polymer or directly deposited. of modified polyethylene or polypropylene.
  • Figure 16 schematically represents a nucleus of a document consisting of sheets of PET-G modified derivative, with or without laser etched or micronized carbon etching additive, in which one or both sides of the same has been deposited a thin layer composed of PVDC with optional addition of vinyl derivatives and acrylonitrile and polyurethane that allows color printing customization by the D2T2 (Dye Diffussion Thermal Trans ⁇ er) thermosublimation system.
  • Figure 17. schematically represents a nucleus of an identity document constituted by PET-G modified derivative sheets with or without laser engraving additive or micronized carbon, in one or more both sides of it, has been deposited in a specific area, which according to the type or modality of customization is a thin layer.
  • Figure 18. schematically represents a protective back cover of a document constituted by polyester sheet to which a PET-G derivative layer with or without additive for personalization by the adhesive has been adhered by means of a two-component polyurethane adhesive. laser engraving system.
  • Figure 19. Schematically depicts a polyester or PC sheet that is sandwiched in the middle of the core of Figures 16 and 17 to compensate for structural stresses of the thermo-laminated document symmetrizing its structure.
  • Figures 19a and 19b. schematically and by way of example, represent the polyester or PC sheet that is thermo-laminated on both sides of the core of Figures 16 and 17, to compensate for structural stresses of the thermo-laminated document symmetrizing its structure.
  • Figure 20.- shows, by way of example, one of the possible preferred structures of identity documents resulting from combining the structures of the constituent elements object of the present invention, with combined customization on the surface of the core of both D2T2 color printing of thermosublimation of the phantom image, such as personalization by laser beam engraving on both sides of the personal data and the facial image of the holder on the specific limited surface area.
  • the structure is equipped with polyester, or PC, tension compensation sheets, integrated on both sides of the document core.
  • a holographic structure both of transparent HRI type (high reflective index) as a metallic holographic laminate, in which a deposit of a holographic product selected from SZn, TiOx, SiOx, ZrOx, aluminum (Al), bismuth (Bi), or silver (Ag) is made to obtain a holographic layer (2h) (figures 1,2 and 3); said deposit is made limited only to specific areas and lines either on a surface (2'a2) of a second layer (2a2) of a holographic structure, constituted by acrylic derivative or lacquer that polymerizes and hardens by the action of ultraviolet light (UV) or by the action of electronic radiation or air, depending on the type of lacquer applied; or making said holographic product deposit limited to specific areas and lines directly on a surface of a first layer (the) of oriented polyester or durable plastic in the case of packaging, plastic sheets for packaging or packaging labels.
  • a holographic product selected from SZn, TiOx, SiOx, ZrOx
  • the preferred embodiment of the invention provides for 3 different methods of depositing holographic product described below.
  • PVD physical vapor deposition
  • a continuous impression is then made on the surface (2'a2) of the coil (8a), on the areas (17) (figure 8a) and around the lines that form the figures and logos (3) (figure 5 ), which have already been embossed, selectively with synthetic silicone wax, with silicone emulsion, with natural vegetable oils, preferably with wax carnauba paraffin, thus covering all the free zones of the coil (8a) that do not have embossing lines in the holographic layer (2h) (figures 1 and 2), but leaving enough uncovered space on both sides of the cited embossing lines (17) (figure 8a).
  • a PVD tank is made on the entire surface (17 and area of the figures and logos 3), a vacuum vaporization or atmospheric pressure, in continuous process, of the holographic element (7), which as indicated it is constituted by SZn, TiOx, SiOx, ZrOx, Al, Ag or Bi, so that said product (7) is not deposited in the zone (17), by the action of the continuous deposition carried out on said zone.
  • a specific lacquer print is then made that hardens by the action of the UV light of all the lines and areas that have already been covered by the holographic product deposit, thus protecting and encapsulating said holographic deposits corresponding to the area of the figures and logos (3).
  • the next phase of the continuous process consists in carrying out the elimination and cleaning of the areas (17) that were covered with the carnauba wax-paraffin wax or silicone derivative (17) (figure 8a), by means of a vacuum chamber with oxygen plasma 0 2 , by which the silicone derivative is released.
  • This cleaning can also be carried out by applying a solvent of the silicone derivative, or, where appropriate, a solvent of the carnauba wax-paraffin, by which action is derived from the surface (2'h) of a coil (8b ), leaving only the holographic product deposit deposited on the surfaces (2h) corresponding to the logos and figures (3) figure 5, on the surface (2'a2) of the second layer (2a2) of a holographic structure.
  • the invention provides a second method of deposit of holographic product by vacuum vaporization or at atmospheric pressure that is made on the second layer (2a2) (figures 2 and 6a) cut into individual sheets of the holographic laminate instead of making said deposit on coil.
  • said holographic laminate is constituted by a first layer (la) of polyester or PC on which the second layer (2a2) of acrylic derivative or preferably lacquer is deposited which polymerizes and hardens by the action of UV light or by The action of electronic radiation.
  • This set is cut into sheets (8pe) (figure 6a) each of which is previously hot embossed with the metal engraving tool (shims) designed to produce the respective recesses that constitute the holographic figures and logos (3 ) (figure 5).
  • silicone derivative and selectively with oil compound or vegetable wax and preferably with carnauba wax-paraffin around lines and zones 17, (figure 8a) where they have already been engraved (hot embossing) the slits, respective of the holographic figures and logos.
  • the sheets are then introduced into a stacker-feeder (12stf) (figure 6a), which by means of roller sets (12'r) individually transports each sheet through the slot gate (llce) and supported by guides lateral, to a vacuum PVD vaporization chamber (10) or to atmospheric pressure of the holographic product (7) that is selectively vaporized by heating, by magnetron (sputtering), by ionic ray, by electron beam, or by arc; the passage of each sheet (8pe) through the vacuum vaporization chamber (10) produces the holographic deposit (2h) on the surface (2 'a2) covering only the free areas of silicone derivative printing; since this prevents the holographic product from being deposited (7).
  • a stacker-feeder (12stf) (figure 6a)
  • roller sets (12'r) individually transports each sheet through the slot gate (llce) and supported by guides lateral, to a vacuum PVD vaporization chamber (10) or to atmospheric pressure of the holographic product (7) that is selectively vaporized by
  • the sheets (8ps) already provided with holographic deposit they are then transported by the respective drive wheels of the lateral guides and by the rollers (12'r) to the output stacker (12sto); so that the rollers (12'r) are synchronously driven by a stepper motor (13eng) that is controlled by a processor through the passing and positioning signals of each sheet (8pe) as it passes through optoelectronic sensors (lis) .
  • the sheets (8ps) are cleaned in a vacuum chamber with oxygen plasma 0 2 where the silicone derivative is released, and where appropriate the generic synthetic oil from the respective printed areas.
  • the preferred embodiment of the invention provides a third PVD (physical vapor deposition) method of continuous holographic deposition on coil, in a vacuum vaporization (10) or atmospheric pressure deposition chamber ( Figure 6), in which the vaporization is produced by heating, magnetron effect
  • Said holographic deposit (2h) on the surface (2'a2) of the second layer (2a2) (figures 1 and 2), of a holographic structure comprises: previously hot embossing with the metal engraving tool (shims ) designed to produce the respective recesses that constitute the holographic figures and logos (3) (figure 5), on the surface (2'a2) of the second layer (2a2) in coil (8a); then, by means of a vacuum PVD vaporization chamber (10) or at atmospheric pressure (figure 6), the vaporization of at least one holographic deposit product (7) is carried out;
  • the vaporized holographic product is deposited through perforations (16), figures (7a and 8), which correspond to the figures and logos perforated in the negative in the form of frames (11) (figure 8), repetitive and that one After another they have been practiced on a band (12cp) (fig 6) endless metal or plastic.
  • Said band (12cp) rotates continuously dragged by the rollers (12r) and in permanent contact with the surface (2'a2) of the coil (8) flowing through the groove gates (llcp) so that the perforations ( 16) in the negative they correspond in the form of a mask-template, to the areas where the hot embossing slits of the figures and logos of the holographic design (3) have been positioned and made hot.
  • the aforementioned perforations (16) are wider and wider than those corresponding to the lines of the original design (3), to allow the passage through the perforations of the vaporized holographic deposit widely and cover the corresponding areas on the surface (2'a2 ) containing the lines and areas of the respective embossing.
  • the band (12cp) is dragged synchronously with the coil (8a) as it passes through the reservoir chamber (10) by means of optoelectronic sensors (12) that detect preprinted marks on said coil (8a) and on the band (12cp) , which have the same width as the coil (8a), so that it is driven by a motor (13) governed by a processor that adjusts the matching positioning of the coil (12cp) and the coil (8a); a system of pressure constituted by a plate (13sp) and selectively by a belt system and its corresponding drag rollers, press the laminate of the coil (8a) to the band (12cp) during the passage of both through the deposit chamber (10) PVD;
  • the holographic surface (2h) deposited with holographic product only in the planned areas where the slits corresponding to the holographic figures and logos were made is continuously rewound in the coil (8b).
  • the invention provides for the process of obtaining another possible holographic laminate structure described below with the help of figures 3 and 4, and comprising a first sheet (la) of transparent oriented polyester, PC polycarbonate, or durable plastic (durable plastic), as carrier (carrier) ), on whose inner surface (2 'al) a corona discharge has previously been carried out, and then a thin film of silicone wax, or of natural vegetable oil or wax, preferably carnauba wax, is deposited or printed.
  • the second layer (2a2) is deposited on said surface of this thin film, which in this case may be constituted by an acrylic compound or preferably by lacquer with an additive that previously hardens with the action of air and which finally polymerizes and hardens by the action of UV light or by the action of electronic radiation.
  • Said lacquer is constituted by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon acrylate, urethane acrylate, epoxy silicone, and their corresponding water-dilutable or emulsifiable versions .
  • the grooves are made by hot engraving (embossing) corresponding to the lines of the holographic figures and logos (3).
  • said surface (2'a2) and in continuous process PVD on coil
  • the holographic deposit (2h) is produced with at least one of the products SZn, TiOx, SiOx, ZrOx , or Al, Ag or Bi, whose resulting surface (2'h) is in turn the holographic layer (2h).
  • a generic adhesive deposit preferably polyurethane based adhesive (2plu) is deposited on the surface (2'h) which adheres a third layer (lal) of modified PET-G or polyester derivative;
  • this third layer (lal) may optionally consist of polyethylene, polypropylene, or adhesive for passport paper and visas preferably ethylene-acrylic acid and polyurethane derivatives and alternatively at least two of the following elements: gelatin, acrylic derivatives, acrylic acids, polyamide and polyurethane derivatives; the laminate thus constituted in coil (Ir) (figure 4), is subjected, in continuous process, whereby by means of a heating station (3p) the first polyester sheet (la) is separated and rewound in coil (l'r ).
  • the second layer (2a2) is thus deposited of an acrylic nature, prior to the cleaning process and removal of the wax-paraffin in a plasma chamber 0 2 in a vacuum, also in a subsequent continuous process it is deposited on the surface (2 'al) , a protective layer (not shown) preferably constituted by lacquer that polymerizes and hardens by the action of UV light or by the action of electronic radiation or by the action of air, so that the lacquer is selectively constituted by multifunctional monomeric acrylates based on polyols as reactive diluents (thinners) and oligomeric acrylates as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon acrylate, urethane acrylate , epoxy-silicone, and their corresponding versions dilutable and emulsifiable in water.
  • a protective layer preferably constituted by lacquer that polymerizes and hard
  • the invention provides that in order to increase the adhesion between layers, as a previous stage of each of the different processes of deposit of both a layer, as an adhesive deposit, as a holographic product deposit, such as lacquer printing , or printing with silicone derivative or vegetable wax, it it applies pretreatment of activation of the corresponding surface selectively with oxygen vacuum plasma, hydrogen vacuum plasma H 2 , with the corresponding plasma of the reservoir product, or with atmospheric plasma.
  • the invention provides that said deposit can be gradually demetalized by surface areas
  • holographic product depot PDV procedures described above they provide for a variation that consists in the hot embossing process of the corresponding indentations of the respective lines of the figures and logos being carried out directly on the holographic layer (2h ) prior deposit of the holographic product by vaporization.
  • the holographic product is previously deposited on the lines and limited areas of the corresponding substrate, either directly on polyester or durable plastic sheet (la) or on the surface (2'a2 ) of the second layer (2a2), and then the hot embossing of the corresponding grooves coincidentally over the lines and areas selectively covered with the holographic product by vaporization is performed as described below:
  • the holographic deposit (2h) is carried out either directly on the surface of the layer (la), either on the surface (2'a2) of the second layer (2a2) of a holographic structure, or it is carried out by PVD process (physical vapor deposition) of continuous holographic deposit on coil (8a) (figures 1,2 and 3), the latter comprising: making a continuous impression of areas (17) around the lines that form the figures and logos (3), selectively with silicone wax emulsion, with silicone oil, with vegetable wax, preferably with carnauba wax-paraffin, covering all those remaining areas of the surface (2'a2) of the
  • the deposit limited by zones and lines of holographic product by vacuum vaporization carried out by the procedures described as part of the invention is applied directly on a first layer (the) constituted by durable plastic (durable plastic) preferably by oriented polyester of a container or packaging surface or labels for containers.
  • a first layer constituted by durable plastic (durable plastic) preferably by oriented polyester of a container or packaging surface or labels for containers.
  • Figure 1 shows the primary structure of an example of the invention, of the holographic laminate that is part of the structure of the document, and which is constituted by a first layer (la) of transparent oriented polyester, of PC polycarbonate, or of durable plastic (durable plastic), as a carrier (carrier) on whose surface a surface treatment has previously been performed by corona discharge and on which a thin layer (2al) of generic primer for plastics is deposited, selectively consisting of at least one of the following elements: vinyl compound, PVDC (polyvinyldiene chloride), acrylonitrile, polyurethane derivative and preferably said layer (2al) is made of polymerizing lacquer that hardens by the action of UV (ultra violet) light or by the action of electronic radiation, the lacquer being selectively constituted by multifunctional monomeric acrylates based on polyols as reactive diluents (thinners) and oligomeric acrylates as binders formed by at least one of the following elements: epoxy acrylate, polyester
  • FIG 2 another primary structure is shown as an example of holographic laminate of the invention that is constituted by the first layer (the) figures and logos (3) are printed directly with thick lines with lacquer that hardens by UV light or by the action of electronic radiation constituting the second printed layer (2a2).
  • the invention provides for the possibility that a second continuous layer (2a2) of lacquer that polymerizes and hardens by the action of UV light and selectively by the action of electronic radiation or is directly deposited on the first layer (the) by the action of the air.
  • the second layer (2a2) is selectively constituted by multifunctional monomeric acrylates based on polyols as reactive diluents (thinners) and oligomeric acrylates such as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon acrylate, urethane acrylate, epoxy silicone and their corresponding water soluble versions.
  • a coil (8a) is obtained as shown in figure 6, which is processed by the three differentiated alternative methods of depositing holographic product by vacuum or pressure vaporization atmospheric, which are the object of the preferred embodiment of the invention, in which the deposit of the holographic product SZn, TiOx, SiOx, ZrOx, Al, Ag or Bi is limited to specific areas and lines on the surface (2'a2) of the second layer (2a2) to obtain a holographic laminate of both the HRI type (high reflective index) and the metallic type, with subsequent encapsulation of the lines and areas of the holographic deposit corresponding to the grooves that are hot embossing of the respective holographic figures and logos (3).
  • the deposit of the holographic product SZn, TiOx, SiOx, ZrOx, Al, Ag or Bi is limited to specific areas and lines on the surface (2'a2) of the second layer (2a2) to obtain a holographic laminate of both the HRI type (high reflective index) and the metallic type, with subsequent encapsulation
  • Figure 10 represents a specific embodiment of this invention corresponding to a structure comprising a combined holographic structure, with deposit of a first holographic layer (2h ⁇ ) of transparent HRI type (high reflective index) over specific areas of the recordable substrate (shims plastic embossable) consisting of the second layer (2a2) and deposit of a second holographic layer (2h2) of metallic holographic product on other specific areas of the same recordable substrate (2a2);
  • This combined holographic structure is constituted by a first support layer (the) of oriented polyester or durable plastic (durable plastic), both in coil and in sheets, on whose surface, prior discharge of corona effect or Plasma 02 pretreatment, comprises a deposit or impression of silicone wax or vegetable wax preferably of carnauba wax / paraffin that forms a thin layer (2al); on which a print or deposit is included, prior to corona discharge or plasma 02 pretreatment, of recordable plastic, preferably of recordable lacquer that hardens by the action of UV light or by the action of electronic radiation,
  • 02 comprises a deposit of a second holographic layer
  • a fifth layer (2a5) is adhered or deposited which, depending on the type of application of the combined holographic laminate, is selectively formed by: PE polyolefin derivative deposit, polypropylene, ethylene-acrylic acid with the addition of polyurethane derivative, thermoadhesive for paper money or for passport or visas, polyvinyl derivative with addition of PVDC (polyvinyldiene chloride) for personalization with D2T2 thermo-sublimation printing, or a layer of thermo-adhesive based polyurethane which in turn adheres a layer of modified derivative of PET-G (polyethylene-terephthalate-glycol; the deposit of the second layer (2h2) of holographic metal product of the combined holographic laminate is customized by laser engraving (holographic embossing) with the replica of the facial image of the holder of the identity document or passport in which the combined holographic laminate has been thermolaminated Figure 10a r it represents an embodiment of the invention of an integrally polycarbonate
  • the core (C) is constituted by sheets (Csl) of polycarbonate, on a specific part of whose surface (C's) the structure of the combined hologram containing the zonal metal hologram (Hmz) is attached, which is customized by destructive laser engraving (burning) before or after the thermolamination of the core (C) with the transparent polycarbonate sheet covers (Lpc); including in the laser engraving of personalization a recording of personal data and the replica of the facial image of the holder of the identity document; the combined zone hologram being HRI transparent metallic zonal
  • Hmz produced by a PVD method of vaporization of the respective deposit of transparent HRI holographic product and metallic holographic product (Al, Bi, Ag) and whose structure, then be adhered or selectively thermo-laminated with the sheet (Lpc) or with the core (C), is composed of the second layer (2a2) of recordable plastic product (plastic embossable shims) or acrylic derivative, preferably of recordable lacquer on which the second layer of zonal metal holographic product of the second layer (2h2) is deposited ) and of transparent holographic product of the first layer (2hl), on which the zonal layer (2a4) of encapsulation which is formed by acrylic derivative, preferably formed by lacquer that hardens by the action of the UV light or by the action of electronic radiation, which in turn contains a fourth layer (3bl) of selectively polyurethane-based or poly-based thermo-adhesive mere polyolefin; so that depending on the size chosen for the zonal metal hologram (H
  • Figure 10b represents a specific embodiment of the present invention of holographic structure that is applied to banknotes, passports, visas and document comprising a holographic structure, selectively of transparent HRI type (high reflective index) or of metallic holographic laminate; said structure is constituted by a first support layer (la) of oriented polyester or durable plastic (durable plastic), both in coil and in sheets, on whose surface, after corona discharge or plasma pretreatment 02, are printed with silicone wax or vegetable wax preferably with carnauba wax / paraffin only a thin layer (2al) that constitute lines and areas that coincide with the lines and zones corresponding to holographic figures, shields and logos; on whose layer or lines and zones (2al) thus printed are printed in turn with recordable plastic, preferably with recordable lacquer that hardens by the action of light (UV) or by the action of electronic radiation or by the action of air, previous discharge of corona effect or previous treatment of plasma 02, covering a second layer (2a2) the lines and zones (2al) with the hardened record
  • the holographic product is deposited with the differentiated physical vapor deposition (PVD) methods of deposit differentiated by vacuum or atmospheric pressure vaporization, depositing said holographic product only on the mentioned lines and zones (2al) of the surface (2'a2) thus constituting the holographic figures and logos; then, after discharge of corona effect or prior plasma treatment 02, it is printed with thermoadhesive, selectively constituted by ethylene-acrylic acid with addition of mono or bicomponent derivative of polyurethane or by thermal adhesive for paper, covering only the mentioned lines and areas of deposit holographic; having provided that the coil or the sheets of the first support layer (la), include registration marks, previously printed, to allow accuracy in the successive impressions covering the lines and areas of the grooves engraved on the second layer (2a2) ;
  • the holographic laminate thus obtained, prior to corona discharge or prior treatment of O2 plasma, is superimposed and thermo-laminated, either in continuous coil or in sheets, to melt
  • Figure 4a represents an embodiment of the present invention holographic laminate structure comprising a holographic structure, selectively of transparent HRI (high reflective index) or laminate type 51 metallic holographic, which is constituted by a first support layer (the) of oriented polyester or durable plastic (durable plastic), both in coil and in sheets, on whose surface, after corona discharge or prior plasma treatment 02, the thin layer (2al) of silicone wax or vegetable wax, preferably carnauba wax / paraffin, is deposited on whose previous surface corona discharge or plasma pretreatment 02, a layer (2a3) selectively constituted by at least one of the following products: acetate derivative, polyolefin derivative, polypropylene derivative, acrylic derivative, silicone derivative, epoxy derivative, polyurethane derivative, polyethylene teref alato derivative, or preferably lacquer, which hardens by the action of the UV light, by the action of electronic radiation or by air action, and then after corona discharge or pre-treatment of plasma O2, is it places the second layer (2a2) of acrylic
  • PET-G polyethylene terephthalate glycol
  • the process of the invention encapsulates the holographic product deposit areas and lines of the holographic layer (2h), by the respective addition of the layer configurations on the surface (2 'h) described below, based on the structures of Figures 1 and 2:
  • corona discharge is carried out on the holographic face (2'h), and then on said surface a layer is preferably deposited with lacquer that polymerizes and hardens by the action of UV light or by the action of electronic radiation, of such that said lacquer is selectively constituted by polyols based multifunctional monomeric acrylates such as reactive diluents (thinners) and oligomeric acrylates as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicone acrylate, urethane acrylate, epoxy silicone , and their corresponding versions dilutable and emulsifiable in water.
  • lacquer that polymerizes and hardens by the action of UV light or by the action of electronic radiation
  • FIG 11 Another possibility of encapsulation is shown in Figure 11, in which after the corona effect has been discharged on the holographic face (2'h), then generic adhesive (2plu) is applied to plastics, preferably bicomponent of polyurethane-based base that adheres a third layer (lal) constituted by modified PET-G derivative (polyethylene glycol terephthalate) and preferably by modified PET-G derivative with micronized carbon additive and selectively with titanium oxide additive and with flame suppressor inhibitor.
  • a third layer constituted by modified PET-G derivative (polyethylene glycol terephthalate) and preferably by modified PET-G derivative with micronized carbon additive and selectively with titanium oxide additive and with flame suppressor inhibitor.
  • FIG 12 another possible encapsulation is shown, in which corona discharge is previously carried out and then on the holographic face (2'h), it is hot deposited by coextrusion of the generic base-layer adherent compound (tie- layer) together with the modified PET-G derivative (polyethylene glycol terephthalate) and preferably PET-G modified derivative with micronized carbon additive with flame suppressor inhibitor and selectively with titanium oxide additive, constituting the layer (la2) of encapsulated
  • a corona effect discharge is previously made and then on the holographic face (2'h) it is selectively deposited by hot injection, by off-set printing, by screen printing, or by extrusion, a seventh layer (lg) selectively composed of at least one of the following elements: vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile, polyurethane derivative.
  • thermo-adhesive preferably composed of ethylene-acrylic acid and polyurethane derivatives or alternatively at least two of the following elements: gelatin, acrylic derivatives, acrylic acids, polyamide and polyurethane derivatives, so that the eighth layer (lf) thus constituted thermolamine with the paper of the passport data sheet, visa or document in general.
  • a corona effect discharge is previously made and then on the holographic face (2'h)
  • a ninth layer (le) of thermoadhesive is selectively deposited by hot injection, or by extrusion of polyolefin polymer composed of polyethylene, modified polyethylene, or by polypropylene.
  • the preferred embodiment of the invention also relates to the core structures of the document compatible with the holographic covers described above, so that a core (C) comprising a central assembly with 1 layers (Cl, C2 ,.) is constituted. .Cn) of modified PET-G, Figure 16, one of whose layers can have integrated a radio frequency chip (5c) with antenna (5ant).
  • the core includes two third layers (lal), for which at least one of its faces (3e, 3'e) is thermolaminated or a third layer (lal) of PET-G modified derivative is extruded with generic additive for engraving by destructive laser beam, or selectively of micronized carbon with flame inhibitor suppressor. On the faces (4e, 4'e) of the third layers
  • (lal) is deposited, prior to corona discharge, by one of the following procedures: extrusion, hot injection, screen printing, corrosive printing, or by hot stamping, a seventh layer (lg) over the entire surface, which is selectively constituted by at least one of the following elements: vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile.
  • a seventh layer (lg) over the entire surface, which is selectively constituted by at least one of the following elements: vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile.
  • personalization of personal data and facial image is printed by D2T2 color printing of thermosublimation.
  • the core (C) is formed by the structure as shown in Figure 17, which is constituted by a central assembly with n layers (Cl, C2, .. Cn) of modified PET-G.
  • One of the layers of the PET-G central assembly can have integrated a radio frequency chip (5c) with antenna (5ant).
  • a radio frequency chip (5c) with antenna (5ant) On at least one of the faces (3e, 3'e) of the Central Assembly is thermolaminated or a third layer (lal) of PET-G modified derivative is extruded with generic additive for destructive laser beam engraving, selectively of micronized carbon with flame inhibitor suppressor.
  • At least one of the following elements vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile, so that on the limited surface (4z) of the core, the personalization of the facial image and personal data is printed by D2T2 color printing of thermosublimation.
  • PVDC polyvinyldiene chloride
  • acrylonitrile so that on the limited surface (4z) of the core, the personalization of the facial image and personal data is printed by D2T2 color printing of thermosublimation.
  • thermolamination of the document or identity card they are integrated either in the middle of the core (C) or on both sides thereof, a sheet of polyester or polycarbonate, for which constitutes a symmetric structure of layers that or thermolaminate on both sides (3e, 3'e) of the Core Core Assembly (C) or is integrated in the middle of said core, consisting of the following components:
  • (lg) selectively constituted by at least one of the following elements: vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile.
  • the invention provides for the provision of a structure of the back cover of the document as shown in Figure 18, which is constituted by a tenth layer (Ib) of polyester prior to corona discharge, on which it is deposited the layer (2plu) of generic adhesive for plastics preferably of polyurethane base to which the layer (lal) of PET-G modified derivative adheres selectively with micronized carbon additive and respectively with additive of Titanium oxide so that on the inside of the tenth layer (Ib) of polyester, prior security prints of logos, figures, shields, with UV inks and OVI (optical variable ink) inks have been optionally made.
  • the face (5i) of the third layer (lal) of PET-G derivative is that which is thermolaminated directly to the respective core structure of the document or identity card.
  • Figure 20.- represents by way of example one of the possible preferred structures of identity documents that result from combining the structures of the constituent elements object of the present invention, with combined customization on the surface of the core both of D2T2 color printing of thermal image sublimation of the phantom, and of personalization by laser beam engraving on both sides of the personal data and of the facial image of the holder on the specific surface area limited
  • the structure is equipped with polyester (or PC) tension compensation sheets integrated on both sides of the document core.
  • first layer the polyester of the protective sheet
  • thin layer (2al) both constituted by polymerizable lacquer by the action of UV light or by the action of electronic radiation as a primer layer (2al)
  • second layer (2a2) of the acrylic derivatives of the respective holographic laminate of both transparent and metallic type HRI type is added in its mass a generic additive for laser engraving and selectively micronized carbon additive with flame suppressor inhibitor, to perform the personalized engraving of structures on surfaces by destructive laser beam (burning).
  • the preferred embodiment of the invention explicitly provides that the holographic structures and the corresponding deposition procedures limited by zones and lines of holographic product Szn, TiOx, SiOx, ZrOx, preferably Al, Bi or Ag by vacuum vaporization, object of the present invention are directly applicable on the first layer (the) (figures 1 and 2), consisting of oriented polyester or durable plastics, so that such substrates are hot embossed with high pressure (hard embossing) with the respective slits corresponding to the lines of the holographic figures and logos that are to be produced.
  • This technology has a very immediate and extensive application in the production of packaging and packaging, as well as holographic labels for holographic protection of high-security containers for medicines, for specific multimedia and consumer items etc.

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Abstract

The invention relates to a method of producing an integral plastic structure and to the structure thus obtained. More specifically, the invention relates to the production of a holographic structure comprising a deposit of a holographic product (7) which forms a holographic layer (2h). The invention is characterised in that the holographic product deposited is selected from SZn, TiOx, SiOx, ZrOx, Al, Bi, Ag and a combination of same, and is limited to specific zones and lines that are applied on a support sheet (1a) or on a surface (2'a2) of a layer (2a2) belonging to a container, the surface of a packaging container, a label, a bank note, a document, an identity card, a credit card, or passports and visas. Moreover, the holographic deposit is encapsulated with the application of different alternating layers in order to obtain high-security protection.

Description

PROCEDIMIENTO DE OBTENCIÓN DE UNA ESTRUCTURA PLÁSTICA INTEGRAL Y ESTRUCTURA OBTENIDAPROCEDURE FOR OBTAINING AN INTEGRAL PLASTIC STRUCTURE AND OBTAINED STRUCTURE
OBJETO DE LA INVENCIÓNOBJECT OF THE INVENTION
La presente invención se refiere tanto a un procedimiento de obtención de una estructura plástica integral como a la estructura obtenida, que comprende una estructura holográfica que incluye un depósito de producto holográfico de SZn, TiOx, SiOx, ZrOx, aluminio metálicoThe present invention relates both to a method of obtaining an integral plastic structure and to the structure obtained, which comprises a holographic structure that includes a holographic product deposit of SZn, TiOx, SiOx, ZrOx, metallic aluminum
(Al) , plata (Ag) o bismuto (Bi) , limitado a zonas y líneas concretas del substrato del laminado holográfico junto con tres procedimientos alternativos diferenciados de depósito por vaporización en vacío o a presión atmosférica, como a distintas estructuras básicas específicas de laminado holográfico de muy alta seguridad en donde el depósito del producto holográfico se realiza por zonas o bien solo y únicamente se lleva a cabo en las zonas y líneas del substrato que corresponden a las figuras, logos, escudos con producto holográfico.(Al), silver (Ag) or bismuth (Bi), limited to specific areas and lines of the holographic laminate substrate together with three different alternative methods of deposit by vacuum vaporization or atmospheric pressure, as well as different specific basic structures of holographic laminate very high security where the deposit of the holographic product is made by zones or alone and is only carried out in the areas and lines of the substrate that correspond to the figures, logos, shields with holographic product.
La invención es aplicable en la obtención de documentos, tarjetas de identidad y de crédito, pasaportes visados, billetes de banco y documentos de papel. Además es objeto de la presente invención la aplicación de los tres procedimientos de depósito holográfico limitado a zonas y líneas concretas y específicas del substrato, a la obtención de láminas holográficas para envases, para empaquetamiento y para etiquetas holográficas de protección de envases de alta seguridad.The invention is applicable in obtaining documents, identity and credit cards, passport visas, banknotes and paper documents. It is also the object of the present invention to apply the three holographic deposit procedures limited to specific and specific areas and lines of the substrate, to obtain holographic sheets for packaging, for packaging and for holographic labels for the protection of high security containers.
La presente invención se refiere igualmente a la estructura de laminado holográfico combinado de depósito de producto holográfico tanto transparente HRI (high reflective index) como de depósito de producto holográfico metálico sobre el mismo substrato, realizado mediante la aplicación secuencial de los procedimientos de depósito objeto de la presente invención como del procedimiento convencional PVD de depósito de producto holográfico. Es igualmente objeto de la presente invención la estructura resultante de la aplicación del laminado holográfico combinado HRI transparente y metálico en estructura de documentos y tarjetas de identidad integralmente de capas de policarbonato.The present invention also relates to the structure of combined holographic laminate of deposit of holographic product both transparent HRI (high reflective index) and deposit of metal holographic product on the same substrate, performed by sequential application of the deposit procedures object of the present invention as the conventional PVD method of depositing holographic product. It is also the object of the present invention the structure resulting from the application of the transparent and metallic HRI combined holographic laminate in the structure of documents and identity cards integrally of polycarbonate layers.
La presente invención se refiere igualmente a la estructura de laminado holográfico superfino resultante de realizar el depósito de producto holográfico por procedimiento PVD (physical vapor deposition) sobre un plástico grabable (shims e bossable plástic) preferentemente por laca grabable que polimeriza por la acción de la luz UV o por la acción de radiación electrónica. Este depósito holográfico se encapsula preferentemente con laca o con un termoadhesivo. De esta estructura se separa la lámina portadora de poliéster orientado por el calor de la termolaminación. Siendo dicho laminado holográfico aplicable tanto a billetes de banco, pasaportes, visados como en documentos o tarjetas integrales de plástico.The present invention also relates to the structure of superfine holographic laminate resulting from the deposition of holographic product by PVD (physical vapor deposition) procedure on a recordable plastic (shims and plastic bossable) preferably by recordable lacquer that polymerizes by the action of the UV light or by the action of electronic radiation. This holographic reservoir is preferably encapsulated with lacquer or with a thermo-adhesive. The heat-oriented polyester carrier sheet is separated from this structure. Said holographic laminate is applicable to both banknotes, passports, visas and in documents or plastic cards.
La presente invención se refiere igualmente al encapsulamiento de las líneas y zonas de este depósito holográfico específicamente limitado a esas zonas del substrato, mediante adición de distintas estructuras de capas en dependencia del tipo de personalización del documento. Estas estructuras específicas de laminado o cubierta holográfica son tanto de tipo HRI (high reflective index) transparente como con capa holográfica metalizada de Al de elevada seguridad para protección de documentos y tarjetas de identidad y de crédito en general y en particular para protección efectiva contra manipulaciones fraudulentas de documentos de identidad cuyas estructuras son igualmente objeto de la Patente. Dichas cubiertas holográficas o laminados holográficos de ambos tipos se aplican de modo concreto a documentos integralmente plásticos como a documentos con soporte de papel tales como libretas de pasaportes y visados. Estos laminados holográficos así estructurados específicamente se integran a su vez en los distintos tipos de documentos constituidos integralmente por materiales plásticos que termolaminan y termosueldan entre sí de forma solidaria constituyendo una tarjeta que se daña y rompe irreversiblemente en los intentos fraudulentos de deslaminación y separación de sus capas.The present invention also relates to the encapsulation of the lines and zones of this holographic deposit specifically limited to those areas of the substrate, by adding different layer structures depending on the type of document customization. These specific structures of laminate or holographic cover are both HRI (high reflective index) type transparent and with high security metallic Holographic layer for protection of documents and identity and credit cards in general and in particular for effective protection against manipulations fraudulent identity documents whose structures are also subject to the patent. Said holographic covers or holographic laminates of both types apply specifically to integrally plastic documents as well as paper-backed documents such as passport books and visas. These laminates Holographic so structured specifically are integrated in turn in the different types of documents consisting entirely of plastic materials that heat and heat weld together forming a card that is damaged and irreversibly broken in fraudulent attempts to delaminate and separate their layers.
La elevada seguridad que confieren las distintas modalidades de laminado holográfico de la presente invención se basa fundamentalmente en el encapsulamiento de la capa de depósito holográfico, así como las medidas específicas de protección y mejora de la seguridad que son aplicados adicionalmente a laminados holográficos producidos por el procedimiento convencional y que son parte de la presente invención. La invención también se refiere a la configuración y adaptación específica de las capas plásticas tanto del propio laminado holográfico como del núcleo del documento y cubierta protectora posterior para que puedan realizarse las distintas modalidades de persona- lización, es decir impresión color por el sistema de temosublimación, por inyección de tinta color, por impresión láser con toner color y por grabado con rayo láser destructivo (burning) respectivamente de fuente del espectro infrarrojo, o verde o azul, tanto de la imagen facial como de los datos personales y firma y huella del titular del documento. Las estructuras de documentos previstas en la presente patente de invención prevén la personalización combinada de varias de estas modalidades de personalización en distintas capas o estratos, para conferir al documento una elevada seguridad.The high security conferred by the different holographic laminate modalities of the present invention is fundamentally based on the encapsulation of the holographic deposit layer, as well as the specific security protection and improvement measures that are additionally applied to holographic laminates produced by the conventional procedure and which are part of the present invention. The invention also relates to the specific configuration and adaptation of the plastic layers of both the holographic laminate itself and the core of the document and subsequent protective cover so that the different modalities of personalization can be carried out, that is to say color printing by the thermosublimation system , by injection of colored ink, by laser printing with color toner and by engraving with destructive laser beam (burning) respectively of the source of the infrared spectrum, or green or blue, of both the facial image and personal data and signature and fingerprint of the document holder. The document structures provided for in the present invention patent provide for the combined customization of several of these customization modalities in different layers or layers, to confer high security on the document.
Asimismo la invención se refiere a la adaptación solidaria a la estructura plástica de la tarjeta del documento de identidad, de los 2 tipos de protección holográfica, bien tipo HRI (high reflexión index) transpa- rente o bien depósito holográfico Al (aluminio) , Ag (plata) o Bi (bismuto) , con desmetalización después de su depósito, para que sean integradas y encapsuladas solidariamente dichas estructuras de protecciones holográficas objeto de la invención dentro de la propia estructura plástica de tarjetas de identidad y documentos en sus variantes posibles, aplicando un adhesivo genérico para plásticos o selectivamente un adhesivo bicomponente de base poliuretano para adherir directamente la capa holográfica del laminado holográfico a la estructura de la tarjeta y encapsulando dicha capa holográfica de modo que sea termolaminada con el resto de la estructura de la tarjeta de identidad constituyendo un cuerpo no deslaminable al aplicar calor y reactivos y disolventes comunes . ANTECEDENTES DE LA INVENCIÓNThe invention also relates to the solidary adaptation to the plastic structure of the identity card card, of the 2 types of holographic protection, either HRI (high reflection index) type or holographic deposit Al (aluminum), Ag (silver) or Bi (bismuth), with demetalization after its deposit, so that these holographic protection structures object of the invention are integrated and encapsulated in solidarity within the plastic structure of identity cards and documents in their possible variants, applying a generic adhesive for plastics or selectively a two-component polyurethane based adhesive to directly adhere the holographic layer of the holographic laminate to the card structure and encapsulating said holographic layer so that it is thermolaminated with the rest of the identity card structure constituting a non-delalable body when applying heat and common reagents and solvents. BACKGROUND OF THE INVENTION
Hasta ahora en el mercado de la identificación existen los siguientes tipos de laminados holográficos: - Laminados holográficos metálicos de aluminio y laminados holográficos poliméricos con vaporización en vacío de depósito metálico, generalmente aluminio. Ambos laminados son opacos y por tanto no pueden proteger eficazmente un documento de identidad por transparencia una vez termolaminadas las capas constitutivas de dicho documento. Por tanto se aplican como un elemento de seguridad con carácter disuasorio. Tienen estos dos tipos de laminados holográficos el inconveniente de que pueden ser recortados del documento original y reutilizados en documentos fraudulentamente reproducidos de los respectivos documentos originales, con cambio de datos personales y fundamentalmente con sustitución de la imagen facial impresa original por otra identidad que generalmente con ambos tipos reseñados de laminados holográficos solo se consigue proteger de una manera testimonial . Dichos laminados metálicos opacos son aplicados en documentos de identidad y tarjetas de permisos de conducción tanto de PVC como de policarbonato.So far in the identification market there are the following types of holographic laminates: - Holographic aluminum metallic laminates and polymeric holographic laminates with vacuum vaporization of metallic deposit, generally aluminum. Both laminates are opaque and therefore cannot effectively protect an identity document by transparency once the constituent layers of said document have been heat-laminated. Therefore they are applied as a security element with a deterrent character. These two types of holographic laminates have the disadvantage that they can be cut from the original document and reused in fraudulently reproduced documents of the respective original documents, with change of personal data and fundamentally with replacement of the original printed facial image with another identity that generally with Both types of holographic laminates are only protected in a testimonial way. Such opaque metallic laminates are applied in identity documents and driving license cards of both PVC like polycarbonate.
Laminados holográficos transparentes tipo HRI (high reflective index) basados en depósito de SZn o de Ti02 que son transparentes y por tanto podrían proteger tanto a la imagen facial impresa o grabada con rayo láser como a los datos personales de un documento de identidad termolaminado. Hasta ahora no ha sido posible aplicar de manera práctica y efectiva este tipo de laminado HRI transparente por diversas razones inherentes a la propia estructura tecnológica del laminado HRI para protección eficaz de documentos de identidad contra reproducción y manipulación fraudulentas y falsificación de los mismos. Existen por tanto ya experiencias acumuladas no satisfactorias en documentos de identidad con laminado holográfico HRI . De un lado, no es posible aplicar este tipo de laminado holográfico en documentos integrales de policarbonato (PC) debido a la gran dureza del PC con el grave inconveniente de que para termolaminar y termosoldar las distintas capas del documento es necesario aplicar temperaturas superiores a 195 °C de fusión superficial del PC, con lo que no es posible utilizar hologramas HRI transparentes de protección de documentos de PC ya que a esa temperatura se daña irreversiblemente la capa holográfica HRI . Por otro lado, hasta ahora los laminados holográficos HRI presentan deficiencias estructurales que hacen que la capa del soporte (carrier) de poliéster se deslamine y separe por la acción prolongada del agua (a las 24 horas se produce la deslaminación o separación) lo cual es un inconveniente grave para documentos de identidad de alta seguridad. Así mismo, el laminado holográfico HRI termolaminado en un documento o tarjeta de identidad, se deslamina y separa sin daño aparente alguno con la acción de disolventes y reactivos químicos tan comunes como la acetona, amoniaco hidrocarburos etc ... lo cual representa un grave inconveniente para la seguridad del documento de identidad ya que dicho laminado holográfico HRI puede por tanto ser reutilizado fraudulentamente en otro documento reproducido del original con imagen facial sustituida por otra identidad.Transparent holographic laminates type HRI (high reflective index) based on SZn or Ti0 2 deposit that are transparent and therefore could protect both the facial image printed or recorded with laser beam and the personal data of a thermo-laminated identity document. Until now it has not been possible to apply this type of transparent HRI laminate in a practical and effective way for various reasons inherent in the technological structure of the HRI laminate for effective protection of identity documents against fraudulent reproduction and manipulation and falsification of them. There are therefore already accumulated unsatisfactory experiences in identity documents with HRI holographic laminate. On the one hand, it is not possible to apply this type of holographic laminate in integral polycarbonate (PC) documents due to the great hardness of the PC with the serious disadvantage that to heat-laminating and heat-sealing the different layers of the document it is necessary to apply temperatures above 195 ° C of PC surface fusion, so it is not possible to use transparent HRI holograms to protect PC documents since at that temperature the HRI holographic layer is irreversibly damaged. On the other hand, so far the HRI holographic laminates have structural deficiencies that cause the layer of the polyester carrier (carrier) to be delaminated and separated by the prolonged action of the water (after 24 hours the delamination or separation occurs) which is a serious inconvenience for high security identity documents. Likewise, the HRI thermo-laminated holographic laminate in a document or identity card is delaminated and separated without any apparent damage with the action of solvents and chemical reagents as common as acetone, ammonia hydrocarbons etc ... which represents a serious inconvenience for the security of the identity document since said laminate HRI HRI can therefore be fraudulently reused in another document reproduced from the original with facial image replaced by another identity.
Es necesario añadir que también los laminados holográficos metalizados opacos adolecen igualmente aunque en menor medida de los inconvenientes de deslaminación mencionados .It is necessary to add that the opaque metallic holographic laminates also suffer, although to a lesser extent, the aforementioned delamination problems.
Resumiendo estos argumentos se constata que todos los laminados holográficos del mercado tienen el muy grave inconveniente de que la capa holográfica que cubre toda la superficie es de un espesor de varias mieras y constituye el punto débil para la deslaminación fraudulenta de los documentos termolaminados .Summarizing these arguments, it is found that all holographic laminates on the market have the very serious disadvantage that the holographic layer covering the entire surface is several microns thick and constitutes the weak point for fraudulent delamination of thermo-laminated documents.
La presente invención se refiere pues a estructuras básicas específicas de laminados holográficos tanto de tipo HRI transparente como de tipo metalizado de aluminio, en los que los el depósito del producto holográfico se realiza en zonas muy definidas y concretas del substrato que permite así el encapsulado entre capas de dichas figuras, logos y escudos holográficos, de modo que los respectivos documentos y tarjetas de identidad termolaminados no se deslaminan por la acción continuada del agua ni tampoco por la acción de los disolventes y reactivos químicos comunes, y siempre se dañan irreversiblemente en los intentos de deslaminación.The present invention thus relates to specific basic structures of holographic laminates of both transparent HRI type and aluminum metallized type, in which the deposition of the holographic product is carried out in very defined and concrete areas of the substrate that thus allows encapsulation between layers of said figures, logos and holographic shields, so that the respective thermo-laminated documents and identity cards are not delaminated by the continued action of water or by the action of common chemical solvents and reagents, and are always irreversibly damaged in the delamination attempts.
DESCRIPCIÓN DE LA INVENCIÓN La presente invención, tal y como se define en las Reivindicaciones, básicamente consiste en un procedimiento que comprende la obtención de una estructura holográfica, tanto de tipo HRI transparente (high reflective index) como laminado holográfico metalizado que incluye un depósito de un producto holográfico que forma una capa holográfica; el depósito de producto holográfico se realiza selectivamente mediante SZn, TiOx, SiOx, ZrOx, aluminio (Al) , bismuto (Bi) , o de plata (Ag) ; y dicho depósito está limitado únicamente a zonas y líneas específicas selectivamente sobre una superficie de un mismo substrato constituido por una capa seleccionada entre plástico durable (durable plástic) , policarbonato (PC) o poliéster orientado; o sobre una superficie de una capa, seleccionada entre derivado acrílico o laca que polimeriza y endurece por la acción selectiva de la luz ultravioleta (UV) o por la acción de la radiación electrónica.DESCRIPTION OF THE INVENTION The present invention, as defined in the Claims, basically consists of a method comprising obtaining a holographic structure, both of transparent HRI type (high reflective index) and metallic holographic laminate that includes a deposit of a holographic product that forms a holographic layer; the holographic product deposit is made selectively by SZn, TiOx, SiOx, ZrOx, aluminum (Al), bismuth (Bi), or silver (Ag); and said Deposit is limited only to specific areas and lines selectively on a surface of the same substrate consisting of a layer selected from durable plastic (durable plastic), polycarbonate (PC) or oriented polyester; or on a surface of a layer, selected from acrylic or lacquer derivative that polymerizes and hardens by the selective action of ultraviolet (UV) light or by the action of electronic radiation.
Se prevén tres procedimientos alternativos diferenciados de depósito del producto holográfico por vaporización en vacío, como así mismo estructuras específicas de laminado holográfico de muy alta seguridad en donde el depósito del producto holográfico solo y únicamente se lleva a cabo en las zonas y líneas del substrato que corresponden a las figuras, logos, escudos con producto holográfico. Para este fin la invención prevé 2 estructuras específicas básicas de cubiertas o laminados holográficos tanto de tipo transparente HRI como de tipo metalizado, en las que mediante dos de los procedimientos alternativos diferenciados de depósito por vaporización en vacío, objeto de la presente invención, se realiza zonalmente el depósito holográfico de las figuras y logos sobre el substrato limitado a las líneas constitutivas del grabado (embossing) de dichas figuras y logos. Igualmente es objeto de la presente invención el encapsulamiento de dichas líneas y zonas holográficas de las figuras y logos mediante la adición de distintas capas alternativas para la protección de alta seguridad de los distintos tipos de documentos y tarjetas de identidad. Son por tanto objeto de la presente invención los tres procedimientos alternativos de depósito de la capa holográfica aplicados a tres procesos diferenciados: el primero de ellos, el procedimiento convencional PVDThree differentiated alternative procedures for depositing the holographic product by vacuum vaporization are foreseen, as well as specific structures of very high security holographic laminate where the holographic product deposit only and only takes place in the areas and lines of the substrate that correspond to the figures, logos, shields with holographic product. For this purpose, the invention provides for 2 basic specific structures of holographic covers or laminates of both the transparent HRI type and the metallic type, in which by means of two of the alternative methods of deposition by vacuum vaporization, object of the present invention, is carried out zonally the holographic deposit of the figures and logos on the substrate limited to the constituent lines of the engraving (embossing) of said figures and logos. Likewise, the object of the present invention is the encapsulation of said lines and holographic zones of the figures and logos by the addition of different alternative layers for the high security protection of the different types of documents and identity cards. Therefore, the three alternative methods of depositing the holographic layer applied to three differentiated processes are the object of the present invention: the first one, the conventional PVD process
(physical vapor deposition) de depósito holográfico en proceso continuo sobre bobina en cámara de vaporización en vacío que cubre la superficie completa del soporte sustentado por la lámina de poliéster con el depósito holográfico, debidamente modificado, tal y como se describe posteriormente según el procedimiento de la invención, para que solo cubra parcialmente dicho soporte en las líneas y zonas de las figuras y logos holográficos y así aumentar la seguridad del laminado holográfico resultante mediante encapsulado de dicho depósito holográfico. El segundo procedimiento PVD también objeto de la invención, es un proceso PVD específico en continuo y en bobina de depósito holográfico por vaporización en vacío o a presión atmosférica, en zonas concretas y localizadas del elemento holográfico depositado utilizando una cinta sin fin en la que se han realizado las perforaciones correspondientes a las figuras y logos para el paso del depósito holográfico a través de ellas. El tercer procedimiento de depósito de vaporización en vacío se realiza en pliegos del substrato. La invención prevé un procedimiento de depósito de producto holográfico por vaporización en vacío o a presión atmosférica que se realiza sobre el substrato cortado en pliegos individualizados del laminado holográfico en lugar de realizar dicho depósito sobre bobina. Para ello se constituye dicho laminado holográfico por una lámina de poliéster o de PC sobre el que se deposita la capa de derivado acrílico o preferentemente de laca que polimeriza y endurece por la acción de la luz UV o por la acción de la radiación electrónica o por la acción del aire. Este conjunto se corta en pliegos cada uno de los cuales previamente es grabado (embossing) en caliente con el útil metálico de grabado (shims) diseñado para producir las respectivas hendiduras que constituyen las figuras y logos holográficos. A continuación sobre la superficie mencionada se imprime con derivado de silicona y selectivamente con compuesto de aceite o cera vegetal y preferentemente con cera-parafina de carnauba alrededor de las líneas y zonas donde ya han sido grabadas (embossing) en caliente las hendiduras, respectivas de las figuras y logos holográficos. A continuación los pliegos son introducidos en un apilador- alimentador, que mediante unos juegos de rodillos transporta individualmente a cada pliego a través de la compuerta de ranura y sostenido por unas guías laterales, a una cámara de vaporización PVD en vacío o a presión atmosférica del producto holográfico que es vaporizado selectivamente por calentamiento, por efecto magnetrón (sputtering) , por rayo iónico, por rayo de electrones, o por arco; el paso de cada pliego por la cámara (de vaporización produce el depósito holográfico sobre la superficie cubriendo solo las zonas libres de impresión de derivado de silicona; ya que ésta impide que se deposite el producto holográfico. Los pliegos ya provistos de depósito holográfico a continuación son transportados por los respectivos ruedas de arrastre de las guías laterales y por los rodillos al apilador de salida; de forma que los rodillos son accionados síncronizadamente por un motor de pasos que es controlado por un procesador mediante las señales de paso y posicionamiento de cada pliego a su paso por unos sensores optoelectrónicos . A continuación los pliegos son limpiados en una cámara de vacío con plasma de oxígeno 02 donde se desprende el derivado de silicona, y en su caso el aceite sintético genérico de las respectivas zonas impresas.(physical vapor deposition) of holographic tank in continuous process on coil in vaporization chamber in vacuum covering the entire surface of the support supported by the polyester sheet with the holographic tank, duly modified, as described below according to the method of the invention, so that only partially support said support in the lines and areas of the figures and holographic logos and thus increase the safety of the resulting holographic laminate by encapsulating said holographic deposit. The second PVD process also object of the invention is a specific PVD process in continuous and in holographic deposit coil by vacuum vaporization or atmospheric pressure, in concrete and localized areas of the holographic element deposited using an endless belt in which they have been Performed the perforations corresponding to the figures and logos for the passage of the holographic deposit through them. The third vacuum vaporization deposition procedure is performed on substrate sheets. The invention provides a method of depositing holographic product by vacuum vaporization or atmospheric pressure that is performed on the substrate cut into individualized sheets of the holographic laminate instead of making said deposit on coil. For this purpose, this holographic laminate is constituted by a polyester or PC sheet on which the acrylic or preferably lacquer derivative layer is deposited, which polymerizes and hardens by the action of UV light or by the action of electronic radiation or by The action of the air. This set is cut into sheets, each of which is previously hot embossed with the metal engraving tool (shims) designed to produce the respective recesses that constitute the holographic figures and logos. Then, on the mentioned surface, it is printed with silicone derivative and selectively with oil or vegetable wax compound and preferably with carnauba wax-paraffin around the lines and areas where the slits, respectively, of the holographic figures and logos have already been hot embossed. The sheets are then introduced into a stacker-feeder, which by means of roller sets transports each sheet individually through the slot gate and supported by lateral guides, to a vacuum PVD vaporization chamber or atmospheric pressure of the product holographic that is selectively vaporized by heating, by magnetron (sputtering), by ionic ray, by electron beam, or by arc; the passage of each sheet through the chamber (vaporization produces the holographic deposit on the surface covering only areas free of silicone derivative printing; since this prevents the holographic product from being deposited. The sheets already provided with holographic deposit below they are transported by the respective drive wheels of the lateral guides and by the rollers to the output stacker, so that the rollers are driven synchronously by a stepper motor that is controlled by a processor by means of the passing and positioning signals of each sheet as it passes through optoelectronic sensors, the sheets are then cleaned in a vacuum chamber with oxygen plasma 0 2 where the silicone derivative is released, and where appropriate the generic synthetic oil from the respective printed areas.
Una realización específica de la presente invención es la correspondiente a una estructura que comprende una estructura holográfica combinada, con depósito de producto holográfico tipo HRI transparente (high reflective index) sobre zonas específicas del substrato grabable (shims embossable plástic) y de depósito de producto holográfico metalizado sobre otras zonas concretas del mismo substrato grabable; esta estructura holográfica combinada está constituida por una lámina soporte de poliéster orientado o de plástico durable (durable plástic) , tanto en bobina como en pliegos, sobre cuya superficie, previa descarga de efecto corona o tratamiento previo de plasma 02, comprende un deposito o impresión de cera de silicona o de cera vegetal preferentemente de cera /parafina de carnauba que forma una capa , sobre la cual se incluye una impresión o depósito, previa descarga de efecto corona o tratamiento previo de plasma O2, de plástico grabable, preferentemente de laca grabable que endurece por la acción de la luz UV o por la acción de radiación electrónica, o del aire, formando así la capa; a continuación la superficie mencionada comprende un grabado (embossing) realizado mediante útil de presiónA specific embodiment of the present invention is that corresponding to a structure comprising a combined holographic structure, with a holographic product deposit transparent HRI type (high reflective index) on specific areas of the recordable substrate (plastic embossable shims) and holographic product deposit metallized on other specific areas of the same recordable substrate; This combined holographic structure consists of an oriented polyester or durable plastic support sheet (durable plastic), both in coil and in sheets, on whose surface, prior discharge of corona effect or prior plasma treatment 02, comprises a deposit or impression of silicone wax or vegetable wax preferably of carnauba wax / paraffin that forms a layer, on which a print or deposit is included, prior to corona discharge or pre-treatment of plasma O2, of recordable plastic, preferably of recordable lacquer that hardens by the action of UV light or by the action of electronic radiation, or from the air, thus forming the layer; then the mentioned surface comprises an embossing made by means of a pressure tool
(shims) de las respectivas hendiduras correspondientes a las líneas y zonas del diseño de las figuras holográficas y seguidamente comprende, previa descarga de efecto corona o tratamiento previo de plasma O2, un depósito realizado únicamente con producto holográfico transparente HRI, aplicado mediante un procedimiento PVD (physical vapor deposition) de depósito por vaporización en vacío o a presión atmosférica; estando el producto holográfico transparente HRI constituido por al menos uno de los productos SZn, TiOx, SiOx, ZrOx; a continuación previa descarga de efecto corona o tratamiento previo de plasma 02, comprende un depósito de producto holográfico metálico aplicado selectivamente mediante un procedimiento PVD(shims) of the respective grooves corresponding to the lines and zones of the design of the holographic figures and then includes, prior discharge of corona effect or previous treatment of plasma O2, a deposit made only with HRI transparent holographic product, applied by a PVD procedure (physical vapor deposition) of tank by vacuum vaporization or atmospheric pressure; the HRI transparent holographic product being constituted by at least one of the products SZn, TiOx, SiOx, ZrOx; then after discharge of corona effect or prior plasma treatment 02, it comprises a deposit of metal holographic product selectively applied by a PVD process
(physical vapor deposition) de depósito por vaporización en vacío o a presión atmosférica; estando el producto holográfico metálico selectivamente constituido por al menos uno de los producto Al, Bi, o Ag; estando así constituida sobre la superficie del substrato, la capa holográfico de depósito holográfico combinado, formada por los correspondientes depósitos holográficos zonales transparente HRI y metálico constituyendo una superficie holográfica común; seguidamente, previa descarga de efecto corona o tratamiento previo de plasma O2, comprende una capa zonal de encapsulamiento preferentemente de laca que endurece por la acción de la luz UV que corresponde a las zonas de la superficie holográfica de la capa de depósito holográfico combinado sobre las que únicamente se ha realizado el depósito selectivo de producto holográfico transparente HRI ; seguidamente comprende una gradual desmetalización del depósito de producto holográfico metálico; y a continuación comprende la zona de encapsulamiento, preferentemente con laca, de la parte de la superficie correspondiente al depósito de producto holográfico metalizado, formando así la capa sobre la que a su vez se encuentra adherida o depositada otra capa que según el tipo de aplicación del laminado holográfico combinado está selectivamente formada por: depósito de derivado poliolefínico PE, polipropileno, ácido etileno- acrílico con adición de derivado de poliuretano, termoadhesivo para papel moneda o para pasaporte o visados, derivado de polivinilo con adición de PVDC (cloruro de polivinildieno) para personalización con impresión de termosublimación D2T2, o una capa de termoadhesivo de base poliuretano que a su vez adhiere una capa de derivado modificado de PET-G (polietileno-tereftalato-glicol ; el depósito de producto holográfico metálico del laminado holográfico combinado se personaliza mediante grabado con rayo láser (holographic embossing) con la réplica de la imagen facial del titular del documento de identidad o pasaporte en que el laminado holográfico combinado ha sido termolaminado .(physical vapor deposition) of tank by vacuum vaporization or atmospheric pressure; the metal holographic product being selectively constituted by at least one of the Al, Bi, or Ag product; being thus constituted on the surface of the substrate, the holographic layer of combined holographic deposit, formed by the corresponding holographic zone transparent HRI and metallic deposits constituting a common holographic surface; then, after discharge of corona effect or prior treatment of plasma O2, it comprises a layer Zone of encapsulation preferably of lacquer that hardens by the action of UV light that corresponds to the areas of the holographic surface of the combined holographic deposit layer on which only the selective deposit of HRI transparent holographic product has been made; then it includes a gradual demetalization of the deposit of metallic holographic product; and then it comprises the encapsulation zone, preferably with lacquer, of the part of the surface corresponding to the metallic holographic product deposit, thus forming the layer on which another layer is adhered or deposited which according to the type of application of the Combined holographic laminate is selectively formed by: PE polyolefin derivative deposit, polypropylene, ethylene-acrylic acid with addition of polyurethane derivative, thermoadhesive for paper money or for passport or visas, polyvinyl derivative with addition of PVDC (polyvinyldiene chloride) for Customization with D2T2 thermo-sublimation printing, or a polyurethane-based thermo-adhesive layer that in turn adheres a modified PET-G derivative layer (polyethylene-terephthalate-glycol; the holographic metal product deposit of the combined holographic laminate is customized by engraving with laser beam (holographic embossing) with the replica ica of the facial image of the holder of the identity document or passport in which the combined holographic laminate has been thermolaminated.
Otra realización preferente de la invención de consiste en una estructura de documento de identidad integralmente de policarbonato que comprende una estructura constituida por una lámina de policarbonato que se superpone por termolaminación a ambas caras de un núcleo de un documento integralmente de policarbonato, sobre el que previamente se ha adherido o termolaminado un holograma zonal combinado de zona holográfica HRI transparente y de zona holográfica metálica cuya zona metálica es personalizada por grabado láser destructivo, se caracteriza porque el conjunto termolaminado comprende las láminas transparentes de policarbonato, a ambas caras del núcleo constituido por láminas de policarbonato, sobre una parte concreta de cuya superficie está adherida la estructura del holograma combinado que contiene el holograma metálico zonal que es personalizado mediante grabado láser destructivo (burning) antes o después de la termolaminación del núcleo con las cubiertas de láminas de policarbonato transparente; incluyéndose en el grabado láser de personalización una grabación de datos personales y la réplica de la imagen facial del titular del documento de identidad; estando el holograma zonal combinado HRI transparente metálico zonal producido por un procedimiento PVD de vaporización de depósito respectivo de producto holográfico HRI transparente y de producto holográfico metálico (Al, Bi, Ag) y cuya estructura, después ser adherido o termolaminado selectivamente con la lámina o con el núcleo, está compuesta por la capa de producto plástico grabable (shims embossable plástic) o derivado acrílico, preferentemente de laca grabable sobre la cual se encuentra depositado la capa de producto holográfico metálico zonal y de producto holográfico transparente, sobre la que a su vez está depositado o adherido la capa de encapsulamiento que está formada por derivado acrílico, preferentemente formada por laca que endurece por la acción de la luz UV o por la acción de la radiación electrónica, que a su vez contiene una capa de termoadhesivo selectivamente de base poliuretano o de base de polímero poliolefínico; para que dependiendo del tamaño elegido para el holograma metálico zonal y su ubicación sobre la superficie respecto del posicionamiento, figuras, logos e imagen facial de datos de personalización sobre superficie que constituye la cara frontal del documento, la capa de encapsulamiento es sustituida por la propia capa de termoadhesivo.Another preferred embodiment of the invention consists of an integrally polycarbonate identity document structure comprising a structure consisting of a polycarbonate sheet that overlaps both sides of a core of an integrally polycarbonate document, on which previously a hologram has been adhered or thermolaminated Combined zone of transparent HRI holographic zone and metallic holographic zone whose metallic zone is customized by destructive laser engraving, is characterized in that the thermo-laminated assembly comprises transparent polycarbonate sheets, on both sides of the core constituted by polycarbonate sheets, on a specific part whose surface is attached to the structure of the combined hologram containing the zonal metal hologram that is customized by means of destructive laser engraving (burning) before or after the thermo-lamination of the core with the transparent polycarbonate sheet covers; including in the laser engraving of personalization a recording of personal data and the replica of the facial image of the holder of the identity document; the combined zonal hologram being a transparent metallic zonal hRI produced by a PVD method of vaporization of a respective holographic product of transparent holographic product and a metallic holographic product (Al, Bi, Ag) and whose structure, then being adhered or selectively thermolaminated with the sheet or with the core, it is composed of the layer of recordable plastic product (plastic embossable shims) or acrylic derivative, preferably of recordable lacquer on which the layer of zonal metal holographic product and transparent holographic product is deposited, on which its At the same time, the encapsulation layer that is formed by acrylic derivative is deposited or adhered, preferably formed by lacquer that hardens by the action of UV light or by the action of electronic radiation, which in turn contains a layer of selectively based thermoadhesive polyurethane or polyolefin polymer base; so that depending on the size chosen for the zonal metal hologram and its location on the surface with respect to the positioning, figures, logos and facial image of personalization data on the surface that constitutes the front face of the document, the encapsulation layer is replaced by the thermo adhesive layer itself.
La presente invención incluye una realización específica de estructura holográfica aplicada a billetes de banco, pasaportes, visados y documento que comprende una estructura holográfica que comprende una estructura holográfica, selectivamente de tipo HRI transparente (high reflective index) o de laminado holográfico metalizado; dicha estructura holográfica está constituida por una lámina soporte de poliéster orientado o de plástico durable (durable plástic) , tanto en bobina como en pliegos, sobre cuya superficie, previa descarga de efecto corona o tratamiento previo de plasma 02, se imprimen con cera de silicona o con cera vegetal preferentemente con cera /parafina de carnauba únicamente una capa que constituyen unas líneas y zonas que coinciden con las líneas y zonas correspondientes a las figuras, escudos y logos holográficos; sobre cuya capa o líneas y zonas así impresas se imprimen a su vez con plástico grabable, preferentemente con laca grabable que endurece por la acción de la luz (UV) o por la acción de radiación electrónica o por la acción del aire, previa descarga de efecto corona o tratamiento previo de plasma O2, cubriendo una capa las líneas y zonas con la laca grabable endurecida; a continuación se efectúa un grabado (embossing) mediante hendiduras coincidentes con las mencionadas líneas y zonas de la superficie de la capa y seguidamente, previa descarga de efecto corona o tratamiento previo de plasma O2, se realiza el depósito de producto holográfico con los procedimientos PVD (physical vapor deposition) alternativos diferenciados de depósito por vaporización en vacío o a presión atmosférica, depositando dicho producto holográfico únicamente sobre las mencionadas líneas y zonas de la superficie constituyendo así las figuras y logos holográficos; seguidamente, previa descarga de efecto corona o tratamiento previo de plasma 02, se imprime con termoadhesivo, constituido selectivamente por ácido etileno-acrílico con adición de derivado mono o bicomponente de poliuretano o por termoadhesivo para papel, cubriendo únicamente las citadas líneas y zonas de depósito holográfico; habiéndose previsto que la bobina o los pliegos de la lámina soporte de poliéster orientado o de PC, comprendan marcas de registro, previamente impresas, para permitir la exactitud en las sucesivas impresiones que cubren las líneas y zonas de las hendiduras grabadas sobre la capa; el laminado holográfico así obtenido, previa descarga de efecto corona o tratamiento previo de plasma 02, es superpuesto y termolaminado, bien en bobina en continuo o bien en pliegos, para fundir la cera de silicona o preferentemente la cera/parafina de carnauba y así desprender la lámina soporte (carrier) de poliéster por el calor aplicado, para fuertemente adherir al papel de cada billete de banco la protección formada por el holograma trasparente HRI o metálico, selectivamente desmetalizado por zonas; que comprende los logos y figuras holográficos cuyas líneas están protegidas contra el desgaste por la cobertura de la laca endurecida; estando la capa holográfica depositada compuesta selectivamente por SZn, TiOx, SiOx, ZrOx, Al, Bi, o Ag y está limitada únicamente a zonas y líneas específicas selectivamente sobre la superficie la citada capa.The present invention includes a specific embodiment of holographic structure applied to banknotes, passports, visas and documents comprising a holographic structure comprising a holographic structure, selectively of transparent HRI type (high reflective index) or of metallic holographic laminate; said holographic structure is constituted by an oriented polyester support sheet or durable plastic (durable plastic), both in coil and in sheets, on whose surface, after corona discharge or plasma pretreatment 02, they are printed with silicone wax or with vegetable wax preferably with carnauba wax / paraffin only one layer that constitutes lines and zones that coincide with the lines and zones corresponding to the holographic figures, shields and logos; on whose layer or lines and areas thus printed are printed in turn with recordable plastic, preferably with recordable lacquer that hardens by the action of light (UV) or by the action of electronic radiation or by the action of air, prior to discharge of corona effect or pre-treatment of O2 plasma, covering the lines and areas with a hardened etchable lacquer; an embossing is then carried out by means of grooves coinciding with the aforementioned lines and areas of the surface of the layer and then, after discharge of corona effect or prior treatment of O2 plasma, the holographic product is deposited with the PVD procedures (differentiated physical vapor deposition) differentiated deposit by vacuum vaporization or atmospheric pressure, depositing said holographic product only on the mentioned lines and areas of the surface thus constituting holographic figures and logos; then, after discharge of corona effect or prior plasma treatment 02, Prints with thermo-adhesive, selectively constituted by ethylene-acrylic acid with the addition of mono- or bi-component polyurethane derivative or by thermo-adhesive for paper, covering only the aforementioned holographic deposit lines and areas; the coil or sheets of the oriented polyester or PC support sheet being provided to comprise registration marks, previously printed, to allow accuracy in the successive prints covering the lines and areas of the grooves etched on the layer; The holographic laminate thus obtained, prior to corona discharge or prior plasma treatment 02, is superimposed and thermo-laminated, either in continuous coil or in sheets, to melt the silicone wax or preferably the carnauba wax / paraffin and thus detach the support sheet (carrier) of polyester by the heat applied, to strongly adhere to the paper of each banknote the protection formed by the transparent HRI or metallic hologram, selectively demetallized by zones; comprising the logos and holographic figures whose lines are protected against wear by the coverage of the hardened lacquer; the deposited holographic layer being selectively composed of SZn, TiOx, SiOx, ZrOx, Al, Bi, or Ag and is limited only to specific areas and lines selectively on the surface of said layer.
Otra realización de la presente invención consiste en una estructura de laminado holográfico que comprende una estructura holográfica, selectivamente de tipo HRI transparente (high reflective index) o de laminado holográfico metalizado, que está constituido por una lámina soporte de poliéster orientado o de plástico durable (durable plástic), tanto en bobina como en pliegos, sobre cuya superficie, previa descarga de efecto corona o tratamiento previo de plasma 02, se deposita la capa de cera de silicona o de cera vegetal preferentemente cera /parafina de carnauba, sobre cuya superficie previa descarga de efecto corona o tratamiento previo de plasma 02, se deposita una capa constituida selectivamente por al menos uno de los siguientes productos: derivado de acetato, derivado poliolefínico, derivado de polipropileno, derivado acrílico, derivado de silicona, derivado epoxi, derivado de poliuretano, derivado de polietileno-tereftalato, o preferentemente por laca, que endurece por la acción de la luz UV o por la acción de la radiación electrónica, y a continuación previa descarga de efecto corona o tratamiento previo de plasma 02, se deposita la capa de derivado acrílico sobre cuya superficie se efectúa el grabadoAnother embodiment of the present invention consists of a holographic laminate structure comprising a holographic structure, selectively of transparent HRI type (high reflective index) or of metallic holographic laminate, which is constituted by an oriented polyester or durable plastic support sheet ( durable plastic), both in coil and in sheets, on whose surface, prior discharge of corona effect or prior plasma treatment 02, the layer of silicone wax or vegetable wax is preferably deposited, preferably wax / carnauba paraffin, on whose previous surface corona discharge or plasma pretreatment 02, a layer consisting of at least one of the following products is deposited: acetate derivative, polyolefin derivative, polypropylene derivative, acrylic derivative, derivative silicone, epoxy derivative, polyurethane derivative, polyethylene terephthalate derivative, or preferably by lacquer, which hardens by the action of UV light or by the action of electronic radiation, and then after corona discharge or prior treatment of Plasma 02, the acrylic derivative layer is deposited on whose surface the engraving is made
(embossing) de las respectivas hendiduras de las líneas y zonas correspondientes a las figuras y logos; a continuación, previa descarga de efecto corona o tratamiento previo de plasma 02, se deposita el producto holográfico mediante procedimiento PVD (physical vapor deposition) de depósito que cubre solo líneas y zonas específicas de la superficie de producto holográfico o mediante procedimiento PVD (physical vapor deposition) de depósito convencional que cubre toda la superficie de la capa de producto holográfico, constituyendo así la capa holográfica que contiene las figuras y logos holográficos; seguidamente, previa descarga de efecto corona o tratamiento previo de plasma 02, se incluye un encapsulamiento de la superficie holográfica, con una capa que en función del tipo de aplicación del laminado holográfico así constituido está formada selectivamente por uno de los siguientes compuestos : por laca que endurece selectivamente por la acción de la luz UV o por la acción de la radiación de la radiación electrónica o por el aire, por depósito seleccionado entre derivado poliolefínico PE o polipropileno, - selectivamente por termoadhesivo para papel o preferentemente por ácido etileno-acrílico con adición de derivado de poliuretano, para su aplicación en papel moneda, pasaportes y visados y documentos, y para impresión de personalización de termosublimación D2T2,(embossing) of the respective indentations of the lines and zones corresponding to the figures and logos; then, after discharge of corona effect or prior plasma treatment 02, the holographic product is deposited by means of a PVD (physical vapor deposition) deposition procedure that covers only specific lines and areas of the holographic product surface or by PVD (physical vapor procedure) deposition) of conventional deposit covering the entire surface of the holographic product layer, thus constituting the holographic layer containing the holographic figures and logos; then, after discharge of corona effect or prior plasma treatment 02, an encapsulation of the holographic surface is included, with a layer that depending on the type of application of the holographic laminate thus constituted is selectively formed by one of the following compounds: by lacquer which hardens selectively by the action of UV light or by the action of the radiation of electronic radiation or by air, by deposit selected from polyolefin derivative PE or polypropylene, - selectively by thermal adhesive for paper or preferably by ethylene-acrylic acid with polyurethane derivative addition, for application in paper money, passports and visas and documents, and for D2T2 thermosublimation customization printing,
- por derivado de polivinilo con adición de PVDC- by polyvinyl derivative with addition of PVDC
(cloruro de polivinildieno) para impresión de personalización de termosublimación D2T2, por una capa de termoadhesivo de base poliuretano que a su vez adhiere una capa de derivado modificado de PET-G(polyvinylchloride chloride) for D2T2 thermosublimation personalization printing, by a layer of polyurethane-based thermo-adhesive which in turn adheres a modified PET-G derivative layer
(polietileno-tereftalato-glicol) .(polyethylene terephthalate glycol).
De las dos estructuras básicas específicas de cubiertas o laminados holográficos que se contemplan en la presente invención, se derivan estructuras muy concretas de laminados holográficos, también objeto de la presente invención, mediante adición de capas plásticas específicas que adaptan de forma concreta e integran por termosoldado completo los laminados holográficos de ambos tipos a las respectivas distintas estructuras de cada documento de identidad y a cada una de las distintas modalidades de personalización de los mismos, ya sea por impresión de termosublimación D2T2 (Dye Diffussion Thermal Transfer) sobre el núcleo ya sea directamente sobre la cara interna del propio laminado holográfico (sistema Re-Transfer) ya sea mediante grabado láser destructivo (tanto del espectro infrarrojo, verde como del azul) o combinación de distintas modalidades de personalización sobre un mismo documento para obtener así una más elevada seguridad del mismo. Asimismo, forman parte esencial de la presente invención las estructuras específicas del núcleo del documento o tarjeta de identidad para adaptarse a las distintas modalidades de personalización y que termosueldan solidariamente con la respectiva estructura de cubierta o lámina holográfica (tanto HRI como metalizada) objeto de la presente invención. En la estructuración de las capas constitutivas de las dos configuraciones básicas específicas de cubierta o laminado holográfico, objeto de la invención, se han aplicado opcionalmente o bien adhesivos compuestos por PVDC (cloruro de polivildieno) con adición de vinilos y opcionalmente de cloronitrilo o bien lacas especiales que endurecen rápidamente en algunos segundos por polimerización por la acción de la luz UV (acción fotónica) o por la acción de la radiación de electrones o imprimaciones de derivados de poliuretano tanto mono como bicomponente. Con ello se tiene de un lado una elevadísima adherencia de la capa holográfica con su respectiva lámina protectora de poliéster (o de otro plástico durable) y de otro lado el laminado holográfico encapsulado se hace completamente resistente tanto a la acción prolongada del agua como a la acción de una amplia gama de reactivos y disolventes comunes de forma que en todos los casos se produce deslaminación del laminado holográfico con daño irreversible del mismo. Puesto que la laca especial aplicada así endurecida por la acción respectiva de la luz UV o de la radiación electrónica es elevadamente resistente al rayado y al desgaste aunque se produjera la deslaminación de la capa protectora de poliéster del laminado holográfico, dicha laca especial así endurecida seguiría protegiendo a la capa holográfica de modo altamente eficaz. Las dos estructuras básicas específicas de cubierta o laminado holográfico, objeto de la invención, se configuran y se conjuntan respectivamente con los siguientes componentes y elementos constitutivos:From the two specific basic structures of holographic covers or laminates contemplated in the present invention, very specific structures of holographic laminates are derived, also object of the present invention, by the addition of specific plastic layers that adapt in concrete form and integrate by heat welding complete the holographic laminates of both types to the respective different structures of each identity document and to each of the different personalization modalities thereof, either by printing D2T2 (Dye Diffussion Thermal Transfer) thermosublimation on the core or directly on the internal side of the holographic laminate itself (Re-Transfer system) either by destructive laser engraving (both infrared, green and blue) or combination of different customization methods on the same document to obtain a higher security of the same . Likewise, the specific structures of the core of the document or identity card are essential part of the present invention to adapt to the different customization modalities and that weld together with the respective holographic cover structure or sheet (both HRI and metallized) object of the present invention In the structuring of the constitutive layers of the two specific basic configurations of cover or holographic laminate, object of the invention, have been optionally applied either adhesives composed of PVDC (polyvinylchloride) with the addition of vinyl and optionally chloronitrile or special lacquers that quickly harden in a few seconds by polymerization by the action of UV light (photonic action) or by the action of electron radiation or primers of both mono and bicomponent polyurethane derivatives. With this, one has a very high adhesion of the holographic layer with its respective protective sheet of polyester (or other durable plastic) and on the other hand the encapsulated holographic laminate becomes completely resistant to both the prolonged action of the water and the action of a wide range of common reagents and solvents so that in all cases delamination of the holographic laminate occurs with irreversible damage to it. Since the special lacquer applied thus hardened by the respective action of UV light or electronic radiation is highly resistant to scratching and wear even if the delamination of the polyester protective layer of the holographic laminate occurs, said special lacquer thus hardened would continue protecting the holographic layer in a highly effective way. The two specific basic structures of holographic cover or laminate, object of the invention, are configured and combined respectively with the following components and constituent elements:
A. Una lámina de poliéster orientado transparente o de PC, o de plástico durable (durable plástic) , como soporte (carrier) sobre cuya superficie previamente se ha realizado una descarga de efecto corona y sobre la cual se deposita una capa fina de imprimación genérica para plásticos o selectivamente constituida por al menos uno de los siguientes elementos: compuesto vinílico, PVDC (cloruro de polivinildieno) , acrilonitrilo, derivado de poliuretano y preferentemente dicha capa es de laca que polimeriza y endurece por la acción de la luz UV y en su caso por la acción de radiación electrónica o por la acción del aire. Dicha laca está constituida selectivamente por acrilatos monómeros multifuncionales basados en polyols como diluyentes reactivos (thinners) y acrilatos oligómeros como aglutinantes (binders) formados por al menos uno de los siguientes elementos: epoxi-acrilato, poliéster-acrilato, poliéter-acrilato, metano-acrilato, silicon-acrilato, uretano-acrilato, epoxi-silicona, incluidas sus versiones diluibles y emulsionables en agua. Sobre dicha capa se deposita a su vez una capa de compuesto acrílico.A. A transparent or PC oriented polyester sheet, or durable plastic (durable plastic), as a carrier (carrier) on whose surface a corona effect discharge has previously been made and on which a thin layer of generic primer is deposited for plastics or selectively consisting of at least one of the following elements: vinyl compound, PVDC (chloride of polyvinyldiene), acrylonitrile, polyurethane derivative and preferably said layer is made of lacquer that polymerizes and hardens by the action of UV light and, where appropriate, by the action of electronic radiation or by the action of air. Said lacquer is selectively constituted by multifunctional monomeric acrylates based on polyols as reactive diluents (thinners) and oligomeric acrylates as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon-acrylate, urethane-acrylate, epoxy-silicone, including its dilutable and water-emulsifiable versions. A layer of acrylic compound is deposited on said layer.
Sobre dicha superficie del soporte en ambas modalidades indicadas, se deposita por vaporización en vacío el producto holográfico, habiéndose realizado previamente el grabado directamente en caliente (embossing) de las hendiduras con el útil metálico de grabado (shims) diseñado con las correspondientes figuras y logos. B. Una lámina de poliéster orientado transparente o de policarbonato PC, o de plástico durable (durable plástic) , como soporte (carrier) sobre cuya superficie previamente se ha practicado una descarga de efecto corona y sobre la cual se deposita laca con uno de los sistemas: offset o con sistema flexograph, en bobina una capa que cubre la totalidad de la superficie de la bobina, o bien formada por una retícula de líneas finas o de puntos. Dicha laca aplicada polimeriza y endurece por la acción de la luz UV o en su caso por la acción de radiación electrónica o por la acción del aire, y está constituida selectivamente por acrilatos monómeros multifuncionales basados en polyols como diluyentes reactivos (thinners) o acrilatos oligómeros como aglutinantes (binders) formados por al menos uno de los siguientes elementos: epoxi-acrilato, poliéster- acrilato, poliéter-acrilato, metano-acrilato, silicon- acrilato, uretano-acrilato, epoxi-silicona, y sus correspondientes versiones diluibles y emulsionables en agua. Sobre dichas superficies indicadas, previamente son grabadas directamente las hendiduras en caliente (embossing) con un útil metálico de grabado (shims) diseñado con las correspondientes figuras y logos; a continuación se deposita por vaporización en vacío el producto holográfico. De cada una de estas dos estructuras así constituidas se obtiene una bobina que es procesada en una cámara de depósito por vaporización en vacío en que la vaporización es producida selectivamente por calentamiento, por efecto magnetrón (sputtering) , por acción del arco, por acción de rayo iónico, de al menos un producto de depósito holográfico de al menos uno de los elementos constituidos por SZn, TiOx, SiOx, óxido de circonio, Al, Ag o Bi . El depósito holográfico sobre la superficie sobre la que se han realizado las hendiduras de las líneas de grabado de las figuras y logos (embossing) , se realiza a través unas perforaciones practicadas sobre una cinta o banda sin fin metálica o de plástico que fluye conjuntamente con el soporte en bobina que se va a depositar dentro de la cámara de vaporización por vacío o a presión atmosférica arrastrada por los correspondientes rodillos a través de las respectivas ranuras de entrada a la cámara. Las citadas perforaciones se corresponden con las líneas de las figuras y logos plantilla, de forma que se han practicado los troquelados y perforaciones en negativo que son mucho más amplias y mucho más anchas que las correspondientes del diseño original y permiten el paso ampliamente del depósito holográfico vaporizado cubriendo únicamente las correspondientes zonas en la superficie del substrato de la bobina que contiene ya las líneas y áreas de los grabados (embossing) respectivo; la citada cinta con las perforaciones troqueladas de las figuras y logos en negativo se mueve sincronizadamente con el soporte de la bobina que se va a depositar con producto holográfico controlado por sensores que a través de un procesador actúa sobre el motor de arrastre de la citada cinta o banda perforada a fin de ajustar el posicionamiento de la misma respecto de las zonas donde en el soporte de la bobina se practicaron el grabado (embossing) de las hendiduras correspondientes a las líneas de las figuras y logos holográficos. El rebobinado de la bobina se efectúa de modo continuo a velocidad uniforme en función del espesor de depósito del depósito de producto holográfico que se ha calculado previamente.On said surface of the support in both modalities indicated, the holographic product is deposited by vacuum vaporization, having previously directly etched (embossing) the grooves with the metal engraving tool (shims) designed with the corresponding figures and logos . B. A sheet of transparent oriented polyester or PC polycarbonate, or durable plastic (durable plastic), as a carrier (carrier) on whose surface a corona effect discharge has previously been performed and on which lacquer is deposited with one of the systems: offset or with flexograph system, in coil a layer that covers the entire surface of the coil, or formed by a grid of fine lines or points. Said applied lacquer polymerizes and hardens by the action of UV light or, if appropriate, by the action of electronic radiation or by the action of air, and is selectively constituted by multifunctional monomeric acrylates based on polyols as reactive diluents (thinners) or oligomeric acrylates as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon acrylate, urethane-acrylate, epoxy-silicone, and their corresponding water-dilutable and emulsifiable versions. On said indicated surfaces, the hot grooves (embossing) are engraved directly with a metal engraving tool (shims) designed with the corresponding figures and logos; The holographic product is then deposited by vacuum vaporization. From each of these two structures thus constituted, a coil is obtained which is processed in a vacuum vaporization chamber in which the vaporization is selectively produced by heating, by magnetron effect (sputtering), by arc action, by action of ionic ray, of at least one holographic deposit product of at least one of the elements consisting of SZn, TiOx, SiOx, zirconium oxide, Al, Ag or Bi. The holographic deposit on the surface on which the indentations of the engraving lines of the figures and logos (embossing) have been made, is made through perforations made on a metal or plastic endless belt or band that flows together with the coil support to be deposited inside the vacuum vaporization chamber or at atmospheric pressure dragged by the corresponding rollers through the respective slots of entry into the chamber. The aforementioned perforations correspond to the lines of the figures and template logos, so that the punched and negative perforations have been practiced that are much wider and much wider than those corresponding to the original design and allow the holographic deposit to pass widely vaporized covering only the corresponding areas on the substrate surface of the coil that already contains the respective embossing lines and areas; the aforementioned ribbon with the punched holes of the figures and logos in negative moves synchronously with the support of the coil to be deposited with holographic product controlled by sensors that through a processor acts on the drive motor of the said belt or perforated band in order to adjust its positioning with respect to the areas where in the support of the coil embossing of the slits corresponding to the lines of the figures and holographic logos were performed. The rewind of the coil is carried out continuously at a uniform speed depending on the deposit thickness of the holographic product deposit that has been previously calculated.
El proceso de depósito en continuo de vaporización en vacío del producto holográfico, objeto de la presente invención, consigue que este depósito holográfico se realice sobre zonas muy concretas y específicas de forma que la superficie que forma las líneas que constituyen las figuras y logos holográficos grabadas (embossing) queden sin depósito lo que permite encapsular las líneas y zonas grabadas (embossing) del mencionado depósito holográfico con los distintos tipos de capa de cerramiento que están contenidas en la presente invención y que confieren una muy elevada adherencia de cierre y por tanto seguridad.The process of continuous deposition of vacuum vaporization of the holographic product, object of the present invention, achieves that this holographic deposit is carried out over very specific and specific areas so that the surface that forms the lines that constitute the engraved holographic figures and logos (embossing) remain without deposit which allows encapsulating the embossing lines and areas of the aforementioned holographic deposit with the different types of enclosure layer that are contained in the present invention and that confer a very high closing adhesion and therefore security .
De estas dos estructuras básicas A y B de cubierta o laminado holográfico se derivan por adición de capas plásticas específicas para encapsular la capa holográfica y así mismo hacer viable las distintas estructuras de documento combinadas con las correspondientes modalidades de personalización de las diferentes posibles configuraciones de documentos de identidad, de modo que termosueldan solidariamente constituyendo documentos de muy alta seguridad que se dañan irreversiblemente en todo intento fraudulento de deslaminación y manipulación. Se encapsula la capa holográfica mediante la adición respectiva de las siguientes configuraciones de capas sobre la superficie holográfica de las dos estructuras básicas de cubiertas holográficas A y B:These two basic structures A and B of holographic cover or laminate are derived by the addition of specific plastic layers to encapsulate the holographic layer and also make viable the different document structures combined with the corresponding customization modalities of the different possible document configurations of identity, so that they weld solidaryly constituting documents of very high security that are irreversibly damaged in any fraudulent attempt at delamination and handling. The holographic layer is encapsulated by respective addition of the following layer configurations on the holographic surface of the two basic holographic roof structures A and B:
• se efectúa previamente descarga de efecto corona y a continuación, sobre la cara holográfica, se deposita una capa preferentemente con laca que polimeriza y endurece por la acción de la luz UV y en su caso por la acción de radiación electrónica o por la acción del aire, de forma que la laca está constituida selectivamente por acrilatos monómeros multifuncionales basados en polyols como diluyentes reactivos (thinners) y acrilatos oligómeros como aglutinantes (binders) formados por al menos uno de los siguientes elementos: epoxi-acrilato, poliéster- acrilato, poliéter-acrilato, metano-acrilato, silicon- acrilato, uretano-acrilato, epoxi-silicona, y sus correspondientes versiones diluibles y emulsionables en agua .• The corona effect is previously discharged and then, on the holographic face, a layer is preferably deposited with lacquer that polymerizes and hardens by the action of UV light and, where appropriate, by the action of electronic radiation or by the action of air , so that the lacquer is selectively constituted by multifunctional monomeric acrylates based on polyols as reactive diluents (thinners) and oligomeric acrylates as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon acrylate, urethane acrylate, epoxy silicone, and their corresponding water-dilutable and emulsifiable versions.
• se efectúa previamente descarga de efecto corona y a continuación, sobre la cara holográfica, se aplica adhesivo genérico para plásticos preferentemente bicomponente de base poliuretano que adhiere una capa de derivado modificado PET-G (tereftalato polietileno- glicol) y preferentemente de derivado modificado PET-G con aditivo de carbón micronizado y con inhibidor supresor de llama y en su caso con aditivo de óxido de titanio.• Corona effect discharge is carried out previously and then, on the holographic side, generic adhesive is preferably applied to plastics, preferably two-component polyurethane-based, which adheres a layer of PET-G modified derivative (polyethylene glycol terephthalate) and preferably PET-modified derivative G with micronized carbon additive and with flame suppressor inhibitor and, where appropriate, with titanium oxide additive.
• previamente se efectúa descarga de efecto corona y a continuación sobre la cara holográfica, se deposita en caliente por coextrusión del compuesto genérico adherente de capa-base (tie-layer) junto con el derivado modificado PET-G (tereftalato polietileno- glicol) y preferentemente de derivado modificado PET- G con aditivo de carbón micronizado con inhibidor supresor de llama y en su caso con aditivo de óxido de titanio .• corona discharge is previously carried out and then on the holographic face, it is hot deposited by coextrusion of the generic base-layer adherent compound (tie-layer) together with the modified PET-G derivative (polyethylene glycol terephthalate) and preferably of modified PET-G derivative with micronized carbon additive with flame suppressor inhibitor and, where appropriate, with oxide oxide additive titanium
• previamente se efectúa descarga de efecto corona y a continuación sobre la cara holográfica, se deposita selectivamente mediante inyección en caliente, o mediante impresión offset, o mediante impresión serigráfica, o mediante extrusión, una capa constituida por al menos uno de los siguientes elementos: derivado vinílico, PVDC (cloruro de polivinildieno) , acrilonitrilo, derivado de poliuretano.• previously corona discharge is carried out and then on the holographic face, it is deposited selectively by hot injection, or by offset printing, or by screen printing, or by extrusion, a layer consisting of at least one of the following elements: derivative vinyl, PVDC (polyvinyldiene chloride), acrylonitrile, polyurethane derivative.
• previamente se efectúa descarga de efecto corona y a continuación sobre la cara holográfica, se deposita selectivamente mediante inyección en caliente, o mediante impresión off-set, o mediante impresión serigráfica, o mediante extrusión, una capa de termoadhesivo compuesta preferentemente por ácido etileno-acrílico y alternativamente por al menos dos de los elementos siguientes: gelatina, derivados acrílicos, ácidos acrílicos, poliamida y derivados de poliuretano, de forma que la capa así constituida termolamina con el papel de la hoja de datos de pasaporte o documento en general .• previously corona discharge is carried out and then on the holographic face, it is deposited selectively by hot injection, or by off-set printing, or by screen printing, or by extrusion, a layer of thermo-adhesive preferably composed of ethylene-acrylic acid and alternatively by at least two of the following elements: gelatin, acrylic derivatives, acrylic acids, polyamide and polyurethane derivatives, so that the layer thus constituted thermolamine with the paper of the passport data sheet or document in general.
• previamente se efectúa descarga de efecto corona y a continuación se deposita selectivamente mediante inyección en caliente o mediante extrusión, una capa de termoadhesivo de polímero poliolefínico compuesta por polietileno o por polietileno modificado, o por polipropileno .• Corona effect discharge is previously carried out and then a layer of polyolefin polymer thermoadhesive composed of polyethylene or modified polyethylene, or polypropylene is deposited selectively by hot injection or extrusion.
• como modalidad alternativa para realizar el encapsulado, previamente se efectúa descarga de efecto corona y a continuación sobre la cara holográfica se aplica adhesivo genérico para plásticos preferentemente bicomponente de base poliuretano que adhiere la capa constituida por una lámina de derivado modificado PET-G (taraftalato polietileno- glicol)con o sin aditivo de carbón micronizado que tiene embutido e integrado un chip de radiofrecuencia con su respectiva antena. A continuación se deposita selectivamente mediante inyección en caliente, mediante impresión offset, mediante impresión serigráfica, o mediante extrusión, una capa ya descrita, de forma que termolamina con el papel de la hoja de datos de pasaporte o visado o documento en general, dotándolo de un chip de seguridad. También es objeto de la presente invención la estructura de un núcleo (C) que comprende un conjunto central con 1 a n capas (Cl, C2 , .. Cn) de PET-G modificado, y sobre al menos una de sus caras se termolamina o se extrusiona una capa de derivado modificado PET-G con aditivo genérico para grabado por rayo láser destructivo, o aditivo de carbón micronizado con supresor inhibidor de llama, en una de sus capas incluye un chip integrado de radiofrecuencia con antena, y sobre cuya cara se deposita, previa descarga de efecto corona, por uno de los procedimientos siguientes: extrusión, inyección en caliente, impresión serigráfica, impresión corrosiva, por termodepósito (hot stamping) , una capa constituida en toda su superficie selectivamente por al menos uno de los elementos siguientes: derivado vinílico, PVDC (cloruro de polivinildieno) , acrilonitrilo, de forma que sobre esta última superficie, se imprime la personalización de los datos personales e imagen facial mediante impresión color• As an alternative modality for encapsulation, corona discharge is previously carried out and then on the holographic face a generic adhesive is preferably applied to plastics, preferably bicomponent based on polyurethane that adheres the layer consisting of a PET-G modified derivative sheet (polyethylene taraphthalate - glycol) with or without a micronized carbon additive that has a radio frequency chip embedded and integrated with its respective antenna. Subsequently, a hot layer is already deposited selectively by hot injection, by offset printing, by screen printing, or by extrusion, so that it laminates with the paper of the passport or visa data sheet or document in general, providing it with A security chip The object of the present invention is also the structure of a core (C) comprising a central assembly with 1 an layers (Cl, C2, .. Cn) of modified PET-G, and on at least one of its faces is thermolaminated or A modified PET-G derivative layer is extruded with generic additive for destructive laser beam engraving, or micronized carbon additive with flame inhibitor suppressor, in one of its layers it includes an integrated radio frequency chip with antenna, and on whose face it Deposits, after discharge of corona effect, by one of the following procedures: extrusion, hot injection, screen printing, corrosive printing, by hot stamping, a layer consisting of its entire surface selectively by at least one of the following elements : Vinyl derivative, PVDC (polyvinylchloride chloride), acrylonitrile, so that on this last surface, personalization of personal data and facial image is printed by im color pressure
D2T2 de termosublimación.D2T2 thermosublimation.
Es igualmente objeto de la invención la estructuración específica del núcleo del documento de identidad para que permita la modalidad de personalización específica y se obtenga un termosoldado completo tanto entre las capas constitutivas de dicho núcleo como con las cubiertas protectoras o laminados holográficos formando un cuerpo no deslaminable . Para obtener este resultado, se constituye un núcleo que comprende n capas (Cl, C2,..Cn) de PET-G modificado, una de cuyas capas incluye un chip integrado de radiofrecuencia con antena, y sobre al menos una de sus caras se termolamina o se coextrusiona una capa de derivado modificado PET-G con aditivo genérico para grabado por rayo láser destructivo, o aditivo de carbón micronizado con supresor inhibidor de llama, sobre cuya cara se deposita a su vez, previa descarga de efecto corona, por uno de los procedimientos siguientes: extrusión, inyección en caliente, impresión serigráfica, impresión corrosiva, por termodepósito (hot stamping) , una capa con una superficie específica limitada y sobre una zona concreta, constituida por uno de los siguientes productos : • Selectivamente por al menos uno de los elementos siguientes: derivado vinílico, PVDC (cloruro de polivinildieno) , acrilonitrilo, derivado de poliuretano, de forma que sobre la superficie limitada del núcleo, se imprime la personalización la imagen facial y de datos personales mediante impresión color D2T2 de termosublimación.The specific structuring of the core of the identity document is also an object of the invention so that it allows the specific personalization modality and a complete heat-welding is obtained both between the constituent layers of said core and with the holographic protective or laminated covers forming a non-delalable body . To get this result, you it constitutes a core comprising n layers (Cl, C2, .. Cn) of modified PET-G, one of whose layers includes an integrated radio frequency chip with antenna, and on at least one of its faces is thermolaminated or a layer is coextruded PET-G modified derivative with generic additive for destructive laser beam engraving, or micronized carbon additive with flame inhibitor suppressor, on whose face it is deposited in turn, after corona discharge, by one of the following procedures: extrusion , hot injection, silkscreen printing, corrosive printing, by hot stamping, a layer with a specific limited surface and on a specific area, consisting of one of the following products: • Selectively by at least one of the following elements: vinyl derivative, PVDC (polyvinylchloride chloride), acrylonitrile, polyurethane derivative, so that on the limited surface of the core, the customization is printed facial and personal data agen with D2T2 color thermosublimation printing.
• Por compuesto genérico para impresión con sistema de inyección de tinta y alternativamente conteniendo gelatina, para la personalización con impresora color de inyección de tinta• By generic compound for printing with inkjet system and alternatively containing gelatin, for customization with inkjet color printer
• Por al menos uno de los elementos siguientes: de gelatina pura, de derivados acrílicos, de derivados polímeros de poliamida, o combinación de ellos, de manera que la superficie limitada así cubierta es personalizada con la imagen facial mediante el sistema fotográfico de Transferencia por Difusión Inversa por el que el negativo portador de la imagen color o en escala de grises, se superpone sobre la superficie o zona limitada y aplicando ligera presión y en presencia de un revelador fotográfico, en cuya operación se transfiere la imagen facial y en su caso la huella, firma y texto a la citada superficie limitada.• For at least one of the following elements: pure gelatin, acrylic derivatives, polyamide polymer derivatives, or a combination of them, so that the limited surface thus covered is personalized with the facial image through the photographic transfer system. Reverse diffusion whereby the negative carrier of the color or grayscale image is superimposed on the surface or limited area and applying light pressure and in the presence of a developer photographic, in whose operation the facial image is transferred and where appropriate the fingerprint, signature and text to the aforementioned limited surface.
Análogamente, una o ambas caras del núcleo constituidos por capas de derivado modificado PET-G, previa descarga de efecto corona, son tratadas superficialmente sobre la que se deposita, por uno de los procedimientos siguientes: extrusión, inyección en caliente, impresión serigráfica, impresión corrosiva, por termodepósito (hot stamping) , una fina capa de hasta aproximadamente 15-20μ en toda la superficie, constituida por derivado modificado de PET-G con aditivo genérico para grabado láser o aditivo de carbón micronizado o de óxido de titanio y con supresor inhibidor de llama , de forma que sobre la superficie del núcleo así constituida se graba con rayo láser destructivoSimilarly, one or both faces of the core consisting of layers of modified PET-G derivative, prior to corona discharge, are treated superficially on which it is deposited, by one of the following procedures: extrusion, hot injection, screen printing, printing corrosive, by hot stamping, a thin layer of up to about 15-20μ over the entire surface, consisting of modified PET-G derivative with generic additive for laser engraving or micronized carbon or titanium oxide additive and with suppressor flame inhibitor, so that on the surface of the core so constituted it is etched with destructive laser beam
(burning) la correspondiente personalización del documento de identidad, de la imagen facial, imagen fantasma (ghost facial image) y datos personales.(burning) the corresponding personalization of the identity document, of the facial image, ghost image (ghost facial image) and personal data.
Es igualmente objeto de la invención la inserción a ambos lados del núcleo o en el centro del mismo de una lámina de poliéster o de policarbonato que compensan las tensiones de las distintas capas una vez termolaminado el documento. A ambas caras de dicha lámina se adhieren mediante adhesivo preferentemente de base poliuretano láminas de derivado modificado de PET-G (polietilen- taraftalato-glicol) .It is also the object of the invention the insertion on both sides of the core or in the center thereof of a polyester or polycarbonate sheet that compensate the tensions of the different layers once the document has been heat-laminated. On both sides of said sheet, preferably PET-G (polyethylene teraphthalate glycol) derivative sheets are adhered by polyurethane-based adhesive.
La presente invención contiene la estructura específica de la cubierta posterior exterior de protección del documento de identidad adaptadas y compatibilizadas tanto para obtener un único cuerpo ni deslaminable en la termolaminación con el núcleo específico que igualmente es objeto de la presente invención. La citada cubierta está constituida por una lámina de poliéster o de plástico durable a la que se le ha adherido con adhesivo preferentemente de base poliuretano una capa de derivado modificado de PET-G.The present invention contains the specific structure of the outer back cover for protection of the identity document adapted and compatible both to obtain a single body or delaminable in the thermo-lamination with the specific core which is also the object of the present invention. Said cover is constituted by a sheet of polyester or durable plastic to which a derivative layer has been adhered with preferably polyurethane-based adhesive PET-G modified.
La presente invención prevé que como etapa previa a cada uno de los procesos de depósito de capa, de depósito de adhesivo, depósito de producto holográfico, impresión con laca, impresión con derivado de silicona o aceite, objeto de la estructuración y producción de todas las estructuras de la presente invención, se aplica tratamiento previo de activación de la correspondiente superficie con plasma en vacío de oxígeno 02 y selectivamente plasma en vacío de hidrógeno H2, y en su caso con el correspondiente plasma atmosférico. De esta forma la adherencia entre capas aumenta por un factor que llega a superar a 200.The present invention provides that as a prior stage to each of the processes of layer deposition, adhesive deposit, holographic product deposit, lacquer printing, silicone or oil derivative printing, object of structuring and production of all structures of the present invention, pretreatment of the corresponding surface with vacuum plasma of oxygen 0 2 and selectively vacuum plasma of hydrogen H 2 , and where appropriate with the corresponding atmospheric plasma is applied. In this way the adhesion between layers increases by a factor that exceeds 200.
La presente invención contiene a modo de ejemplo, 3 estructuras preferentes de documento de identidad de las muchas posibles que pueden ser constituidas con los elementos correspondientes que son objeto de la presente invención. Cada una de estas 3 estructuras se refiere a una combinación de dichos elementos constitutivos que dan la más elevada seguridad al documento de identidad contra deslaminación y manipulación fraudulenta, reproducción y falsificación.The present invention contains, by way of example, 3 preferred identity document structures of the many possible ones that can be constituted with the corresponding elements that are the object of the present invention. Each of these 3 structures refers to a combination of said constituent elements that give the highest security to the identity document against delamination and fraudulent manipulation, reproduction and falsification.
La invención se refiere a los elementos constitutivos del laminado holográfico a los que al menos a una de sus capas: ya sea la capa de poliéster de la lámina protectora, ya sea la capa constituida por laca polimerizable selectivamente por la acción de la luz UV o por la acción de radiación electrónica o por la acción del aire, o ya sea la capa de imprimación, o incluso a la capa de los derivados acrílicos del respectivo laminado holográfico, tanto de tipo HRI transparente como de tipo metalizado, se le agrega en su masa selectivamente un aditivo genérico para grabado por rayo láser o un aditivo de carbón micronizado con inhibidor supresor de llama, para realizar el grabado personalizado de estructuras CLI (change láser image) en superficie por rayo láser destructivo (burning) .The invention relates to the constituent elements of the holographic laminate to which at least one of its layers: either the polyester layer of the protective sheet, either the layer constituted by lacquer selectively polymerizable by the action of UV light or by the action of electronic radiation or by the action of air, either the primer layer, or even the layer of acrylic derivatives of the respective holographic laminate, both transparent HRI type and metallic type, is added in its Selectively dough a generic additive for laser engraving or a micronized carbon additive with flame suppressor inhibitor, to perform custom engraving of CLI structures (change laser image) on surface by destructive laser beam (burning).
Así mismo los procedimientos de depósito de producto holográfico limitado a zonas y líneas específicas sobre el substrato, objeto de la presente invención son aplicables al depósito holográfico directamente sobre la lámina de un envase o superficie de empaquetado, o etiqueta de envase constituido selectivamente por poliéster orientado o por plástico durable (durable plástic) . BREVE DESCRIPCIÓN DE LAS FIGURASLikewise, the procedures for depositing holographic product limited to specific areas and lines on the substrate, object of the present invention are applicable to the holographic deposit directly on the sheet of a container or packaging surface, or container label selectively constituted by oriented polyester or by durable plastic (durable plastic). BRIEF DESCRIPTION OF THE FIGURES
A continuación se describen una serie de figuras en las que con carácter ilustrativo y no limitativo se representan distintas realizaciones de la invención.A series of figures are described below in which different embodiments of the invention are shown by way of illustration and not limitation.
La Figura 1.- representa de forma esquemática la estructura básica A de uno de los laminados holográficos objeto de la presente invención, en la que la capa de grabado (embossing) que constituye la capa holográfica está compuesta por derivado acrílico que a su vez lleva depositada una capa de imprimación o una fina capa de una laca especial polimerizable por la acción de la luz UV o de radiación electrónica que se adhiere a la cubierta de poliéster.Figure 1.- schematically represents the basic structure A of one of the holographic laminates object of the present invention, in which the embossing layer that constitutes the holographic layer is composed of acrylic derivative which in turn carries deposited a layer of primer or a thin layer of a special lacquer polymerizable by the action of UV light or electronic radiation that adheres to the polyester cover.
La Figura 2. - representa de forma esquemática la estructura básica B de los laminados holográficos objeto de la presente invención, en que la capa de laca especial polimerizable por la acción de la luz UV o de radiación electrónica o del aire, es directamente grabada (embossing) y sobre ella se deposita por vaporización en vacío la capa holográfica. La Figura 3.- representa de forma esquemática una estructura básica de un laminado holográfico objeto de la presente invención. Está constituida por una estructura de un laminado holográfico convencional en que la capa de grabado (embossing) está compuesta por derivado acrílico sobre la que se deposita en toda su superficie la capa holográfica. Entre la capa acrílica y la cubierta de poliéster se imprime o se deposita una finísima película de emulsión de silicona o de cera sintética de silicona. Sobre la capa holográfica se adhiere con adhesivo de base poliuretano una nueva capa que puede ser de derivado modificado PET-G o de poliéster.Figure 2. - Schematically represents the basic structure B of the holographic laminates object of the present invention, in which the special lacquer layer polymerizable by the action of UV light or electronic radiation or air, is directly engraved ( embossing) and on it the holographic layer is deposited by vacuum vaporization. Figure 3.- schematically represents a basic structure of a holographic laminate object of the present invention. It is constituted by a structure of a conventional holographic laminate in which the embossing layer is composed of acrylic derivative on which the entire surface is deposited. holographic layer A thin silicone emulsion film or silicone synthetic wax emulsion is printed or deposited between the acrylic layer and the polyester cover. On the holographic layer, a new layer that can be modified PET-G or polyester derivative is adhered with polyurethane base adhesive.
La Figura 4.- representa de forma esquemática el proceso de separación de la capa de poliéster de la estructura de lámina holográfica en la que la bobina es tratada mediante calor.Figure 4.- schematically represents the process of separating the polyester layer from the holographic sheet structure in which the coil is heat treated.
La Figura 4a.- representa de forma esquemática la estructura de laminado holográfico superfino resultante de realizar el depósito de producto holográfico por procedimiento PVD (physical vapor deposition) sobre un plástico grabable (shims embossable plástic) preferentemente por laca grabable de forma que el depósito holográfico se encapsula preferentemente con laca o con un termoadhesivo. De esta estructura se separa la lámina portadora de poliéster orientado por el calor de la termolaminación. La Figura 5.- representa de forma esquemática un ejemplo de diseño de depósito final holográfico.Figure 4a.- schematically represents the structure of superfine holographic laminate resulting from depositing holographic product by PVD (physical vapor deposition) procedure on a recordable plastic (plastic embossable shims) preferably by recordable lacquer so that the holographic deposit It is preferably encapsulated with lacquer or with a thermo-adhesive. The heat-oriented polyester carrier sheet is separated from this structure. Figure 5.- schematically represents an example of holographic final deposit design.
La Figura 6.- representa de forma esquemática la modificación de una cámara de depósito holográfico PVD por vaporización en vacío para la realización del proceso PVD en bobina y en continuo de depósito holográfico a través de las perforaciones practicadas en una cinta o banda sin fin.Figure 6.- schematically represents the modification of a holographic PVD deposit chamber by vacuum vaporization for the realization of the PVD process in coil and in continuous holographic deposition through the perforations made in an endless belt or band.
La Figura 6a.- representa de forma esquemática una cámara de depósito holográfico PVD por vaporización en vacío para la realización del proceso de depósito holográfico sobre zonas específicas y limitadas del substrato en pliegos del laminado holográfico.Figure 6a.- schematically represents a PVD holographic deposit chamber by vacuum vaporization for the realization of the holographic deposition process on specific and limited areas of the substrate in sheets of the holographic laminate.
La Figura 7.- representa de forma esquemática un detalle a modo de ejemplo del escudo del diseño del grabado (embossing) sobre el que se deposita por vaporización en vacío la capa holográfica.Figure 7.- schematically represents an exemplary detail of the shield of the design of the embossing on which the holographic layer is deposited by vacuum vaporization.
La figura 7a.- representa de forma esquemática las perforaciones correspondientes a las líneas de una figura holográfica que a modo de ejemplo es un escudo, realizadas en la cinta o banda que fluye en la cámara de depósito coincidentemente con el substrato en bobina.Figure 7a.- schematically represents the perforations corresponding to the lines of a holographic figure which, by way of example, is a shield, made in the tape or band flowing in the deposit chamber coincidentally with the coil substrate.
La Figura 8. - . representa de forma esquemática la configuración de la cinta sin fin provista de las perforaciones y troquelados en negativo a través de los cuales se deposita, sobre la zona de la capa correspondiente de la lámina de poliéster, el producto holográfico vaporizado cubriendo las líneas y zonas que forman las figuras y logos grabadas (embossing) . La Figura 8a.- representa de forma esquemática las zonas que son cubiertas con la impresión de la cera parafina de carnauba o del compuesto de silicona dejando sin cubrir las zonas donde se ha realizado previamente el grabado (embossing) de las figuras y logos que han de ser depositados con el compuesto holográfico.Figure 8. -. schematically represents the configuration of the endless belt provided with the perforations and negative die cuts through which the vaporized holographic product covering the lines and areas that are deposited are deposited on the area of the corresponding layer of the polyester sheet they form the engraved figures and logos (embossing). Figure 8a.- schematically represents the areas that are covered with the impression of the paraffin wax of carnauba or the silicone compound, leaving the areas where the engraving of the figures and logos that have been previously made without covering if deposited with the holographic compound.
La Figura 9.- representa de forma esquemática la estructura final del depósito holográfico que es convenientemente cubierta por una de las estructuras de capas objeto de la presente invención que a su vez encapsulan dicho depósito holográfico.Figure 9.- schematically represents the final structure of the holographic deposit that is conveniently covered by one of the layer structures object of the present invention that in turn encapsulate said holographic deposit.
La Figura 10.- representa de forma esquemática la estructura de uno de los laminados holográficos objeto de la presente invención para documentos de identidad, pasaportes, visados y billetes de banco, en la que la capa de grabado (embossing) incluida en la estructura holográfica está compuesta por una fina capa de una laca grabable, sobre la que se deposita por procedimiento PVD primeramente el producto holográfico HRI transparente limitado a una zona y en la zona restante de dicho substrato se deposita producto holográfico metálico. La Figura 10a . -representa de forma esquemática la estructura del holograma zonal combinado transparente HRI y metálico Hmz adherido sobre la cubierta superior Lpc de policarbonato o sobre el núcleo C también de policarbonato PC siendo termolaminado el conjunto con láminas Lpc transparentes de policarbonato en ambas caras de dicho núcleo.Figure 10.- schematically represents the structure of one of the holographic laminates object of the present invention for identity documents, passports, visas and banknotes, in which the embossing layer included in the holographic structure It is composed of a thin layer of a recordable lacquer, on which the transparent HRI holographic product limited to one zone is deposited by PVD process first and in the remaining zone of said substrate metal holographic product is deposited. Figure 10a. - schematically represents the structure of the transparent combined hologram HRI and metallic Hmz adhered on the top cover Lpc of polycarbonate or on the core C also of polycarbonate PC being thermo laminated the set with transparent Lpc sheets of polycarbonate on both sides of said core.
La Figura 10b.- representa de forma esquemática la estructura de uno de los laminados holográficos objeto de la presente para documentos de identidad, pasaportes, visados y billetes de banco, en la que la capa de grabado (embossing) incluida en la estructura holográfica está compuesta por una fina capa de una laca grabable, sobre la que se deposita por procedimiento PVD primeramente el producto holográfico HRI transparente limitado a una zona y en la zona restante de dicho substrato se deposita producto holográfico metálicoFigure 10b.- schematically represents the structure of one of the holographic laminates object of this for identity documents, passports, visas and banknotes, in which the embossing layer included in the holographic structure is composed of a thin layer of a recordable lacquer, on which the transparent HRI holographic product limited to one zone is deposited by PVD process first and in the remaining area of said substrate metal holographic product is deposited
La Figura 11.- representa de forma esquemática y a modo de ejemplo la forma de completar, cerrar y encapsular la capa holográfica relativa a la estructura básica A, con una capa de lámina adherida de derivado PET- G con o sin aditivo de grabado por rayo láser destructivo (burning) .Figure 11.- schematically and by way of example shows how to complete, close and encapsulate the holographic layer relative to the basic structure A, with a layer of PET-G derivative bonded sheet with or without ray engraving additive destructive laser (burning).
La Figura 12. - representa esquemáticamente y a modo de ejemplo la forma de completar, cerrar y encapsular la capa holográfica relativa a la estructura básica A, con coextrusión junto con su correspondiente capa-base (tie- layer) de una capa de derivado PET-G con o sin aditivo de grabado por rayo láser destructivo (burning) La Figura 13.- representa esquemáticamente y a modo de ejemplo la forma de completar, cerrar y encapsular la capa holográfica relativa a la estructura básica A mediante el depósito de una capa constituida por al menos uno de los elementos siguientes: derivado vinílico, PVDC (cloruro de polivinildieno) , acrilonitrilo, derivado de poliuretano .Figure 12. - schematically and by way of example shows how to complete, close and encapsulate the holographic layer relative to the basic structure A, with coextrusion together with its corresponding base-layer (tie-layer) of a PET-derived layer G with or without destructive laser engraving (burning) additive Figure 13.- schematically and by way of example shows how to complete, close and encapsulate the holographic layer relative to the basic structure A by depositing a layer consisting of at least one of the following elements: vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile, derivative of polyurethane
La Figura 14.- representa esquemáticamente y a modo de ejemplo la forma de completar, cerrar y encapsular la capa holográfica relativa a la estructura básica A, mediante el depósito de ácidos etileno-acrílicos con poliuretano, para termolaminación como protección de una libreta de pasaportes y de visados.Figure 14.- schematically and by way of example shows how to complete, close and encapsulate the holographic layer relative to the basic structure A, by depositing ethylene-acrylic acids with polyurethane, for thermolamination as protection of a passport booklet and of visas.
La Figura 14a.- representa esquemáticamente y a modo de ejemplo la forma de completar, cerrar y encapsular la capa holográfica relativa a la estructura básica A, mediante el depósito de ácidos etileno-acrílicos con poliuretano, para termolaminación como protección de la libreta de pasaportes y de visados, en cuya capa de PET-G se ha insertado e integrado un chip de radiofrecuencia con antena.Figure 14a.- schematically and by way of example shows how to complete, close and encapsulate the holographic layer relative to the basic structure A, by depositing ethylene-acrylic acids with polyurethane, for thermolamination as protection of the passport booklet and of visas, in whose PET-G layer a radio frequency chip with antenna has been inserted and integrated.
La Figura 15.- representa esquemáticamente y a modo de ejemplo la forma de completar, cerrar y encapsular la capa holográfica relativa a la estructura básica A, sobre cuya cara interna se ha depositado directamente una capa de termoadhesivo compuesta por polímeros poliolefínicos o polímero de polietileno o de polietileno modificado o polipropileno .Figure 15.- schematically and by way of example shows how to complete, close and encapsulate the holographic layer relative to the basic structure A, on whose inner face a layer of thermo-adhesive composed of polyolefin polymers or polyethylene polymer or directly deposited. of modified polyethylene or polypropylene.
La Figura 16.- representa de forma esquemática un núcleo de un documento constituido por láminas de derivado modificado PET-G, con o sin aditivo de grabado por rayo láser o de carbón micronizado, en el que en una o ambas caras del mismo se ha depositado una fina capa compuesta por PVDC con adición optativa de derivados vinílicos y de acrilonitrilo y poliuretano que permite la impresión color de personalización por el sistema de D2T2 (Dye Diffussion Thermal Transíer) de termosublimación.Figure 16.- schematically represents a nucleus of a document consisting of sheets of PET-G modified derivative, with or without laser etched or micronized carbon etching additive, in which one or both sides of the same has been deposited a thin layer composed of PVDC with optional addition of vinyl derivatives and acrylonitrile and polyurethane that allows color printing customization by the D2T2 (Dye Diffussion Thermal Transíer) thermosublimation system.
La Figura 17.- representa de forma esquemática un núcleo de un documento de identidad constituido por láminas de derivado modificado PET-G con o sin aditivo de grabado por rayo láser o de carbón micronizado, en una o ambas caras del mismo, se ha depositado en una zona específica, que según el tipo o modalidad de personalización está constituida una fina capa.Figure 17.- schematically represents a nucleus of an identity document constituted by PET-G modified derivative sheets with or without laser engraving additive or micronized carbon, in one or more both sides of it, has been deposited in a specific area, which according to the type or modality of customization is a thin layer.
La Figura 18. - representa de forma esquemática una cubierta posterior de protección de un documento constituido por lámina de poliéster a la que se ha adherido, mediante adhesivo bicomponente de poliuretano, una capa de derivado PET-G con o sin aditivo para personalización por el sistema de grabado por rayo láser. La Figura 19.- representa de forma esquemática una lámina de poliéster o de PC que se intercala en medio del núcleo de las figuras 16 y 17 para compensar tensiones estructurales del documento termolaminado simetrizando su estructura. Las Figuras 19a y 19b.- representan de forma esquemática y a modo de ejemplo, la lámina de poliéster o de PC que es termolaminada a ambas caras del núcleo de las figuras 16 y 17, para compensar tensiones estructurales del documento termolaminado simetrizando su estructura. La Figura 20.- representa a modo de ejemplo de una las posibles estructuras preferentes de documentos de identidad que resultan de conjuntar las estructuras de los elementos constitutivos objeto de la presente invención, con personalización combinada sobre la superficie del núcleo tanto de impresión color D2T2 de termosublimación de la imagen fantasma, como de personalización por grabado de rayo láser en ambas caras de los datos personales y de la imagen facial del titular sobre la zona específica de superficie limitada. La estructura está dotada de láminas de compensación de tensiones de poliéster, o de PC, integradas a ambos lados del núcleo del documento.Figure 18. - schematically represents a protective back cover of a document constituted by polyester sheet to which a PET-G derivative layer with or without additive for personalization by the adhesive has been adhered by means of a two-component polyurethane adhesive. laser engraving system. Figure 19.- Schematically depicts a polyester or PC sheet that is sandwiched in the middle of the core of Figures 16 and 17 to compensate for structural stresses of the thermo-laminated document symmetrizing its structure. Figures 19a and 19b.- schematically and by way of example, represent the polyester or PC sheet that is thermo-laminated on both sides of the core of Figures 16 and 17, to compensate for structural stresses of the thermo-laminated document symmetrizing its structure. Figure 20.- shows, by way of example, one of the possible preferred structures of identity documents resulting from combining the structures of the constituent elements object of the present invention, with combined customization on the surface of the core of both D2T2 color printing of thermosublimation of the phantom image, such as personalization by laser beam engraving on both sides of the personal data and the facial image of the holder on the specific limited surface area. The structure is equipped with polyester, or PC, tension compensation sheets, integrated on both sides of the document core.
DESCRIPCIÓN DE LA REALIZACIÓN PREFERIDA DE LA INVENCIÓN Comprende la obtención de una estructura holográfica, tanto de tipo HRI transparente (high reflective index) como de laminado holográfico metalizado, en la que se realiza un depósito de un producto holográfico seleccionado entre SZn, TiOx, SiOx, ZrOx, aluminio (Al) , bismuto (Bi) , o plata (Ag) para obtener una capa holográfica (2h) (figuras 1,2 y 3); dicho depósito se realiza limitado únicamente a zonas y líneas específicas bien sobre una superficie (2'a2) de una segunda capa (2a2) de una estructura holográfica, constituida por derivado acrílico o por laca que polimeriza y endurece por la acción de la luz ultravioleta (UV) o por la acción de la radiación electrónica o del aire, según el tipo de laca aplicada; o bien realizando dicho depósito de producto holográfico limitado a zonas y líneas concretas directamente sobre una superficie de una primera capa (la) de poliéster orientado o de plástico durable en el caso de envases, láminas plásticas para empaquetado o etiquetas de envases. En este último caso la estructura holográfica únicamente está constituida por dicha primera capa (la) .DESCRIPTION OF THE PREFERRED EMBODIMENT OF THE INVENTION It comprises obtaining a holographic structure, both of transparent HRI type (high reflective index) as a metallic holographic laminate, in which a deposit of a holographic product selected from SZn, TiOx, SiOx, ZrOx, aluminum (Al), bismuth (Bi), or silver (Ag) is made to obtain a holographic layer (2h) (figures 1,2 and 3); said deposit is made limited only to specific areas and lines either on a surface (2'a2) of a second layer (2a2) of a holographic structure, constituted by acrylic derivative or lacquer that polymerizes and hardens by the action of ultraviolet light (UV) or by the action of electronic radiation or air, depending on the type of lacquer applied; or making said holographic product deposit limited to specific areas and lines directly on a surface of a first layer (the) of oriented polyester or durable plastic in the case of packaging, plastic sheets for packaging or packaging labels. In the latter case, the holographic structure consists only of said first layer (the).
La realización preferida de la invención prevé 3 procedimientos diferenciados de depósito de producto holográfico que a continuación se describen.The preferred embodiment of the invention provides for 3 different methods of depositing holographic product described below.
Proceso PVD (physical vapor deposition) de depósito holográfico en continuo sobre bobina, en el que en primer lugar se realiza grabado (embossing) en caliente con un útil metálico de grabado (shims) diseñado para producir las respectivas hendiduras que constituyen las figuras y logos holográficos (3) (figura 5) , sobre la superficie (2'a2) de la segunda capa (2a2) (figuras 1 y 2), en bobina (8a) (figura 6) . A continuación se realiza una impresión en continuo sobre la superficie (2'a2) de la bobina (8a) , sobre las zonas (17) (figura 8a) y alrededor de las líneas que forman las figuras y logos (3) (figura 5) , que ya han sido grabados (embossing) , selectivamente con cera sintética de silicona, con emulsión de silicona, con aceites vegetales naturales, preferentemente con cera- parafina de carnauba, cubriendo así todas las zonas libres de la bobina (8a) que no tienen líneas de grabado (embossing) en la capa holográfica (2h) (figuras 1 y 2), pero dejando suficiente espacio sin cubrir a ambos lados de las citadas líneas de grabado (embossing) (17) (figura 8a) . A continuación se realiza sobre la totalidad de la superficie (17 y zona de las figuras y logos 3) , un depósito PVD por vaporización en vacío o a presión atmosférica, en proceso continuo, del elemento holográfico (7) , que tal y como fue señalado está constituido por SZn, TiOx, SiOx, ZrOx, Al, Ag o Bi, de manera que dicho producto (7) no se deposita en la zona (17) , por la acción del la deposición en continuo realizada sobre dicha zona. Opcionalmente y como medida de seguridad, se efectúa a continuación una impresión con laca específica que endurece por la acción de la luz UV de todas las líneas y zonas que ya han sido cubiertas por el depósito de producto holográfico, protegiéndolo y encapsulando así dichos depósitos holográficos correspondientes a la zona de las figuras y logos (3) . La siguiente fase del proceso en continuo consiste en efectuar la eliminación y limpieza de las zonas (17) que fueron cubiertas con la impresión de cera-parafina de carnauba o de derivado de silicona (17) (figura 8a) , mediante cámara de vacío con plasma de oxígeno 02, por el que se desprende el derivado de silicona. Esta limpieza puede realizarse también mediante la aplicación de un disolvente del derivado de silicona, o en su caso de disolvente de la cera-parafina de carnauba, por cuya acción se desprende dicho derivado de la superficie (2'h) de una bobina (8b) , quedando únicamente el depósito de producto holográfico depositado sobre las superficies (2h) correspondientes a los logos y figuras (3) figura 5, sobre la superficie (2'a2) de la segunda capa (2a2) de una estructura holográfica. La invención prevé un segundo procedimiento de depósito de producto holográfico por vaporización en vacío o a presión atmosférica que se realiza sobre la segunda capa (2a2) (figuras 2 y 6a) cortado en pliegos individualizados del laminado holográfico en lugar de realizar dicho depósito sobre bobina. Para ello se constituye dicho laminado holográfico por una primera capa (la) de poliéster o de PC sobre el que se deposita la segunda capa (2a2) de derivado acrílico o preferentemente de laca que polimeriza y endurece por la acción de la luz UV o por la acción de la radiación electrónica. Este conjunto se corta en pliegos (8pe) (figura 6a) cada uno de los cuales previamente es grabado (embossing) en caliente con el útil metálico de grabado (shims) diseñado para producir las respectivas hendiduras que constituyen las figuras y logos holográficos (3) (figura 5) . A continuación sobre la superficie (2'a2) se imprime con derivado de silicona y selectivamente con compuesto de aceite o cera vegetal y preferentemente con cera-parafina de carnauba alrededor de las líneas y zonas 17, (figura 8a) donde ya han sido grabadas (embossing) en caliente las hendiduras, respectivas de las figuras y logos holográficos. A continuación los pliegos son introducidos en un apilador- alimentador (12stf) (figura 6a) , que mediante unos juegos de rodillos (12'r) transporta individualmente a cada pliego a través de la compuerta de ranura (llce) y sostenido por unas guías laterales, a una cámara (10) de vaporización PVD en vacío o a presión atmosférica del producto holográfico (7) que es vaporizado selectivamente por calentamiento, por efecto magnetrón (sputtering) , por rayo iónico, por rayo de electrones, o por arco; el paso de cada pliego (8pe) por la cámara (10) de vaporización en vacío produce el depósito holográfico (2h) sobre la superficie (2 ' a2) cubriendo solo las zonas libres de impresión de derivado de silicona; ya que ésta impide que se deposite el producto holográfico (7) . Los pliegos (8ps) ya provistos de depósito holográfico a continuación son transportados por los respectivos ruedas de arrastre de las guías laterales y por los rodillos (12'r) al apilador de salida (12sto) ; de forma que los rodillos (12'r) son accionados síncronizadamente por un motor de pasos (13eng) que es controlado por un procesador mediante las señales de paso y posicionamiento de cada pliego (8pe) a su paso por unos sensores optoelectrónicos (lis) . A continuación los pliegos (8ps) son limpiados en una cámara de vacío con plasma de oxígeno 02 donde se desprende el derivado de silicona, y en su caso el aceite sintético genérico de las respectivas zonas impresas.PVD (physical vapor deposition) process of continuous holographic deposit on coil, in which first it is done hot embossing with a metal engraving tool (shims) designed to produce the respective indentations that constitute the figures and logos holographic (3) (figure 5), on the surface (2'a2) of the second layer (2a2) (figures 1 and 2), in coil (8a) (figure 6). A continuous impression is then made on the surface (2'a2) of the coil (8a), on the areas (17) (figure 8a) and around the lines that form the figures and logos (3) (figure 5 ), which have already been embossed, selectively with synthetic silicone wax, with silicone emulsion, with natural vegetable oils, preferably with wax carnauba paraffin, thus covering all the free zones of the coil (8a) that do not have embossing lines in the holographic layer (2h) (figures 1 and 2), but leaving enough uncovered space on both sides of the cited embossing lines (17) (figure 8a). Subsequently, a PVD tank is made on the entire surface (17 and area of the figures and logos 3), a vacuum vaporization or atmospheric pressure, in continuous process, of the holographic element (7), which as indicated it is constituted by SZn, TiOx, SiOx, ZrOx, Al, Ag or Bi, so that said product (7) is not deposited in the zone (17), by the action of the continuous deposition carried out on said zone. Optionally and as a security measure, a specific lacquer print is then made that hardens by the action of the UV light of all the lines and areas that have already been covered by the holographic product deposit, thus protecting and encapsulating said holographic deposits corresponding to the area of the figures and logos (3). The next phase of the continuous process consists in carrying out the elimination and cleaning of the areas (17) that were covered with the carnauba wax-paraffin wax or silicone derivative (17) (figure 8a), by means of a vacuum chamber with oxygen plasma 0 2 , by which the silicone derivative is released. This cleaning can also be carried out by applying a solvent of the silicone derivative, or, where appropriate, a solvent of the carnauba wax-paraffin, by which action is derived from the surface (2'h) of a coil (8b ), leaving only the holographic product deposit deposited on the surfaces (2h) corresponding to the logos and figures (3) figure 5, on the surface (2'a2) of the second layer (2a2) of a holographic structure. The invention provides a second method of deposit of holographic product by vacuum vaporization or at atmospheric pressure that is made on the second layer (2a2) (figures 2 and 6a) cut into individual sheets of the holographic laminate instead of making said deposit on coil. For this purpose, said holographic laminate is constituted by a first layer (la) of polyester or PC on which the second layer (2a2) of acrylic derivative or preferably lacquer is deposited which polymerizes and hardens by the action of UV light or by The action of electronic radiation. This set is cut into sheets (8pe) (figure 6a) each of which is previously hot embossed with the metal engraving tool (shims) designed to produce the respective recesses that constitute the holographic figures and logos (3 ) (figure 5). Then on the surface (2'a2) it is printed with silicone derivative and selectively with oil compound or vegetable wax and preferably with carnauba wax-paraffin around lines and zones 17, (figure 8a) where they have already been engraved (hot embossing) the slits, respective of the holographic figures and logos. The sheets are then introduced into a stacker-feeder (12stf) (figure 6a), which by means of roller sets (12'r) individually transports each sheet through the slot gate (llce) and supported by guides lateral, to a vacuum PVD vaporization chamber (10) or to atmospheric pressure of the holographic product (7) that is selectively vaporized by heating, by magnetron (sputtering), by ionic ray, by electron beam, or by arc; the passage of each sheet (8pe) through the vacuum vaporization chamber (10) produces the holographic deposit (2h) on the surface (2 'a2) covering only the free areas of silicone derivative printing; since this prevents the holographic product from being deposited (7). The sheets (8ps) already provided with holographic deposit, they are then transported by the respective drive wheels of the lateral guides and by the rollers (12'r) to the output stacker (12sto); so that the rollers (12'r) are synchronously driven by a stepper motor (13eng) that is controlled by a processor through the passing and positioning signals of each sheet (8pe) as it passes through optoelectronic sensors (lis) . Subsequently, the sheets (8ps) are cleaned in a vacuum chamber with oxygen plasma 0 2 where the silicone derivative is released, and where appropriate the generic synthetic oil from the respective printed areas.
La realización preferida de la invención prevé un tercer procedimiento PVD (physical vapor deposition) de depósito holográfico en continuo sobre bobina, en una cámara de depósito por vaporización en vacío (10) o a presión atmosférica (figura 6) , en la que la vaporización se produce por calentamiento, por efecto magnetrónThe preferred embodiment of the invention provides a third PVD (physical vapor deposition) method of continuous holographic deposition on coil, in a vacuum vaporization (10) or atmospheric pressure deposition chamber (Figure 6), in which the vaporization is produced by heating, magnetron effect
(sputtering) , por rayo iónico, rayo de electrones, por arco, de al menos un producto holográfico de depósito (7) . Dicho depósito holográfico (2h) sobre la superficie (2'a2) de la segunda capa (2a2) (figuras 1 y 2) , de una estructura holográfica, comprende: previamente grabar (embossing) en caliente con el útil metálico de grabado (shims) diseñado para producir las respectivas hendiduras que constituyen las figuras y logos holográficos (3) (figura 5), sobre la superficie (2'a2) de la segunda capa (2a2) en bobina (8a) ; seguidamente, mediante una cámara de depósito de vaporización PVD en vacío (10) o a presión atmosférica (figura 6) , se realiza la vaporización, de al menos un producto holográfico de depósito (7) ; el depósito del producto holográfico vaporizado se realiza a través de unas perforaciones (16), figuras (7a y 8), que corresponden a las figuras y logos perforados en negativo en forma de cuadros (11) (figura 8) , repetitivos y que uno tras otro han sido practicados sobre una banda (12cp) (fig 6) metálica o plástica sin fin. Dicha banda (12cp) rota continuamente arrastrada por los rodillos (12r) y en contacto permanente con la superficie (2'a2) de la bobina (8) que fluye a través de las compuertas de ranura (llcp) de modo que las perforaciones (16) en negativo corresponden en forma de máscara-plantilla, a las zonas donde se han posicionado y realizado las hendiduras del grabado (embossing) en caliente de las líneas de las figuras y logos del diseño holográfico (3) . Las citadas perforaciones (16) son más amplias y anchas que las correspondientes a las líneas del diseño original (3), para permitir ampliamente el paso a través de las perforaciones del depósito holográfico vaporizado y cubrir las correspondientes zonas en la superficie (2'a2) que contienen las líneas y áreas de los grabados (embossing) respectivos. La banda (12cp) se arrastra sincronizadamente con la bobina (8a) a su paso por la cámara (10) de depósito mediante unos sensores optoelectrónicos (12) que detectan unas marcas preimpresas sobre dicha bobina (8a) y sobre la banda (12cp) , que tienen el mismo ancho que la bobina (8a) , de forma que es accionada por un motor (13) gobernado por un procesador que ajusta el posicionamiento coincidente de la bobina (12cp) y de la bobina (8a) ;un sistema de presión constituido por una placa (13sp) y selectivamente por un sistema de banda y sus correspondientes rodillos de arrastre, presionan el laminado de la bobina (8a) a la banda (12cp) durante el paso de ambas por la cámara (10) de depósito PVD; la superficie holográfica (2h) depositada con producto holográfico únicamente en las zonas previstas donde se realizaron las hendiduras correspondientes a las figuras y logos holográficos es rebobinada en continuo en la bobina (8b) . La invención prevé el proceso de obtención de otra posible estructura de laminado holográfico que a continuación se describe con ayuda de las figuras 3 y 4, y que comprende una primera lámina (la) de poliéster orientado transparente, de policarbonato PC, o de plástico durable (durable plástic) , como soporte (carrier) , sobre cuya superficie interior (2 'al) previamente se ha practicado descarga de efecto corona, y a continuación se deposita o imprime una fina película de cera de silicona, o de aceite o cera vegetal natural preferentemente cera- parafina de carnauba. Sobre la citada superficie de esta fina película se deposita la segunda capa (2a2) que en este caso puede estar constituida por compuesto acrílico o preferentemente por laca con aditivo que endurece previamente con la acción del aire y que polimeriza y endurece finalmente por la acción de la luz UV o por la acción de radiación electrónica. Dicha laca está constituida por al menos uno de los siguientes elementos: epoxi-acrilato, poliéster-acrilato, poliéter-acrilato, metano-acrilato, silicon-acrilato, uretano-acrilato, epoxi- silicona, y sus correspondientes versiones diluibles o emulsionables en agua. Seguidamente se realizan, sobre la superficie (2'a2) las hendiduras por grabado en caliente (embossing) correspondientes a las líneas de las figuras y logos holográficos (3) . A continuación sobre dicha superficie (2'a2), y en proceso continuo PVD sobre bobina(sputtering), by ionic beam, electron beam, by arc, of at least one holographic deposit product (7). Said holographic deposit (2h) on the surface (2'a2) of the second layer (2a2) (figures 1 and 2), of a holographic structure, comprises: previously hot embossing with the metal engraving tool (shims ) designed to produce the respective recesses that constitute the holographic figures and logos (3) (figure 5), on the surface (2'a2) of the second layer (2a2) in coil (8a); then, by means of a vacuum PVD vaporization chamber (10) or at atmospheric pressure (figure 6), the vaporization of at least one holographic deposit product (7) is carried out; The vaporized holographic product is deposited through perforations (16), figures (7a and 8), which correspond to the figures and logos perforated in the negative in the form of frames (11) (figure 8), repetitive and that one After another they have been practiced on a band (12cp) (fig 6) endless metal or plastic. Said band (12cp) rotates continuously dragged by the rollers (12r) and in permanent contact with the surface (2'a2) of the coil (8) flowing through the groove gates (llcp) so that the perforations ( 16) in the negative they correspond in the form of a mask-template, to the areas where the hot embossing slits of the figures and logos of the holographic design (3) have been positioned and made hot. The aforementioned perforations (16) are wider and wider than those corresponding to the lines of the original design (3), to allow the passage through the perforations of the vaporized holographic deposit widely and cover the corresponding areas on the surface (2'a2 ) containing the lines and areas of the respective embossing. The band (12cp) is dragged synchronously with the coil (8a) as it passes through the reservoir chamber (10) by means of optoelectronic sensors (12) that detect preprinted marks on said coil (8a) and on the band (12cp) , which have the same width as the coil (8a), so that it is driven by a motor (13) governed by a processor that adjusts the matching positioning of the coil (12cp) and the coil (8a); a system of pressure constituted by a plate (13sp) and selectively by a belt system and its corresponding drag rollers, press the laminate of the coil (8a) to the band (12cp) during the passage of both through the deposit chamber (10) PVD; The holographic surface (2h) deposited with holographic product only in the planned areas where the slits corresponding to the holographic figures and logos were made is continuously rewound in the coil (8b). The invention provides for the process of obtaining another possible holographic laminate structure described below with the help of figures 3 and 4, and comprising a first sheet (la) of transparent oriented polyester, PC polycarbonate, or durable plastic (durable plastic), as carrier (carrier) ), on whose inner surface (2 'al) a corona discharge has previously been carried out, and then a thin film of silicone wax, or of natural vegetable oil or wax, preferably carnauba wax, is deposited or printed. The second layer (2a2) is deposited on said surface of this thin film, which in this case may be constituted by an acrylic compound or preferably by lacquer with an additive that previously hardens with the action of air and which finally polymerizes and hardens by the action of UV light or by the action of electronic radiation. Said lacquer is constituted by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon acrylate, urethane acrylate, epoxy silicone, and their corresponding water-dilutable or emulsifiable versions . Subsequently, on the surface (2'a2) the grooves are made by hot engraving (embossing) corresponding to the lines of the holographic figures and logos (3). Then on said surface (2'a2), and in continuous process PVD on coil
(8a) en cámara de vaporización en vacío o a presión atmosférica, por procedimiento convencional de depósito o por alguno de los procedimientos PVD descritos anteriormente, se produce el depósito holográfico (2h) con al menos uno de los productos SZn, TiOx, SiOx, ZrOx, o Al, Ag o Bi, cuya superficie (2'h) resultante a su vez es la capa holográfica (2h) .(8a) in a vacuum vaporization chamber or at atmospheric pressure, by conventional deposition procedure or by any of the PVD procedures described above, the holographic deposit (2h) is produced with at least one of the products SZn, TiOx, SiOx, ZrOx , or Al, Ag or Bi, whose resulting surface (2'h) is in turn the holographic layer (2h).
En el siguiente paso del proceso se deposita sobre la superficie (2'h) un depósito de adhesivo genérico, preferentemente adhesivo de base poliuretano (2plu) que adhiere una tercera capa (lal) de derivado modificado PET- G o de poliéster; esta tercera capa (lal) puede estar constituida opcionalmente por polietileno, polipropileno, o por adhesivo para papel de pasaporte y visados preferentemente por ácido etileno-acrílico y derivados de poliuretano y alternativamente por al menos dos de los elementos siguientes: gelatina, derivados acrílicos, ácidos acrílicos, poliamida y derivados de poliuretano; el laminado así constituido en bobina (Ir) (figura 4) , se somete, en proceso continuo, por el que mediante una estación de calentamiento (3p) es separada la primera lámina de poliéster (la) y rebobinada en bobina (l'r) . Caso de ser la segunda capa (2a2)así depositada de naturaleza acrílica, previo proceso de limpieza y eliminación de la cera-parafina en cámara de plasma 02 en vacío, igualmente en proceso continuo posterior se deposita sobre la superficie (2 'al), una capa de protección (no representada) constituida preferentemente por laca que polimeriza y endurece por la acción de la luz UV o por la acción de radiación electrónica o por la acción del aire, de forma que la laca está constituida selectivamente por acrilatos monómeros multifuncionales basados en polyols como diluyentes reactivos (thinners) y acrilatos oligómeros como aglutinantes (binders) formados por al menos uno de los siguientes elementos: epoxi-acrilato, poliéster- acrilato, poliéter-acrilato, metano-acrilato, silicon- acrilato, uretano-acrilato, epoxi-silicona, y sus correspondientes versiones diluibles y emulsionables en agua. Es de señalar que la invención prevé que para incrementar la adherencia entre capas, como etapa previa de cada uno de los distintos procesos de depósito tanto de una capa, como de depósito de adhesivo, como de depósito de producto holográfico, como de impresión con laca, o impresión con derivado de silicona o cera vegetal, se aplica tratamiento previo de activación de la correspondiente superficie selectivamente con plasma en vacío de oxígeno, plasma en vacío de hidrógeno H2, con el correspondiente plasma del producto de depósito, o con plasma atmosférico.In the next step of the process a generic adhesive deposit, preferably polyurethane based adhesive (2plu), is deposited on the surface (2'h) which adheres a third layer (lal) of modified PET-G or polyester derivative; this third layer (lal) may optionally consist of polyethylene, polypropylene, or adhesive for passport paper and visas preferably ethylene-acrylic acid and polyurethane derivatives and alternatively at least two of the following elements: gelatin, acrylic derivatives, acrylic acids, polyamide and polyurethane derivatives; the laminate thus constituted in coil (Ir) (figure 4), is subjected, in continuous process, whereby by means of a heating station (3p) the first polyester sheet (la) is separated and rewound in coil (l'r ). If the second layer (2a2) is thus deposited of an acrylic nature, prior to the cleaning process and removal of the wax-paraffin in a plasma chamber 0 2 in a vacuum, also in a subsequent continuous process it is deposited on the surface (2 'al) , a protective layer (not shown) preferably constituted by lacquer that polymerizes and hardens by the action of UV light or by the action of electronic radiation or by the action of air, so that the lacquer is selectively constituted by multifunctional monomeric acrylates based on polyols as reactive diluents (thinners) and oligomeric acrylates as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon acrylate, urethane acrylate , epoxy-silicone, and their corresponding versions dilutable and emulsifiable in water. It should be noted that the invention provides that in order to increase the adhesion between layers, as a previous stage of each of the different processes of deposit of both a layer, as an adhesive deposit, as a holographic product deposit, such as lacquer printing , or printing with silicone derivative or vegetable wax, it it applies pretreatment of activation of the corresponding surface selectively with oxygen vacuum plasma, hydrogen vacuum plasma H 2 , with the corresponding plasma of the reservoir product, or with atmospheric plasma.
En los procedimientos descritos de depósito metálico selectivo de Al, Ag o de Bi por vaporización en vacío o a presión atmosférica que constituye la capa holográfica (2h) , la invención prevé que dicho depósito se pueda desmetalizar gradualmente por áreas de la superficieIn the described methods of selective metallic deposit of Al, Ag or Bi by vacuum vaporization or at atmospheric pressure constituting the holographic layer (2h), the invention provides that said deposit can be gradually demetalized by surface areas
(2h) para disminuir la densidad del depósito metálico de(2h) to decrease the density of the metal deposit of
Al, Ag o del Bi y hacer más transparente una zona específica de la superficie holográfica (2h) . Para ello, sobre la capa de depósito holográfico (2h) se imprime sucesivamente un corrosivo del Al, Ag, o Bi y se lava subsiguientemente cubriendo por zonas las figuras y logos selectivamente de Al, Ag o de Bi .Al, Ag or Bi and make a specific area of the holographic surface more transparent (2h). For this, a corrosive of Al, Ag, or Bi is successively printed on the holographic deposit layer (2h) and subsequently washed by covering the figures and logos selectively of Al, Ag or Bi.
En los procedimientos PDV de depósito de producto holográfico descritos anteriormente, prevén una variación que consiste en que el proceso de grabado en caliente (embossing) de las correspondientes hendiduras de las respectivas líneas de las figuras y logos se realice directamente sobre la capa holográfica (2h) previo depósito del producto holográfico por vaporización. Para ello aplicando dichos procedimientos de depósito ya descritos se realiza previamente el depósito del producto holográfico sobre las líneas y zonas limitadas del substrato correspondiente, ya sea directamente sobre lámina de poliéster o plástico durable (la) o ya sea sobre la superficie (2'a2) de la segunda capa (2a2), y a continuación se realiza el grabado (embossing) en caliente de las hendiduras correspondientes coincidentemente sobre las líneas y zonas cubiertas selectivamente con el producto holográfico por vaporización como se describe a continuación: El depósito holográfico (2h) se realiza bien directamente sobre la superficie de la capa (la) , bien sobre la superficie (2'a2) de la segunda capa (2a2) de una estructura holográfica, o se realiza mediante proceso PVD (physical vapor deposition) de depósito holográfico en continuo sobre bobina (8a) (figuras 1,2 y 3), comprendiendo este último: realizar una impresión en continuo de unas zonas (17) alrededor de las líneas que forman las figuras y logos (3) , selectivamente con emulsión de cera de silicona, con aceite de silicona, con cera vegetal, preferentemente con cera-parafina de carnauba, cubriendo todas aquellas zonas restantes de la superficie (2'a2) de la bobina (8a) sobre las que posteriormente no se van a grabar (embossing) las figuras y logos sobre la segunda capa (2a2) , y dejando suficiente espacio sin cubrir a ambos lados de las líneas de grabado (embossing) de las figuras y logos que posteriormente se van a grabar (embossing) ; realizándose a continuación un depósito PVD por vaporización en vacío o a presión atmosférica, en proceso convencional continuo de obtención de una capa holográfica continua (2h) ; seguidamente se efectúa la eliminación y limpieza de las zonas que fueron cubiertas con la impresión en continuo (17) , selectivamente mediante paso de la estructura holográfica (8b) a través de una cámara de vacío con plasma de oxígeno en proceso continuo, o mediante la aplicación de un disolvente del derivado de silicona para desprender el derivado de silicona y en su caso la cera- parafina de carnauba, junto con el depósito de producto holográfico que residualmente haya quedado sobre ella; conteniendo la superficie holográfica (2'h) de la bobinaIn the holographic product depot PDV procedures described above, they provide for a variation that consists in the hot embossing process of the corresponding indentations of the respective lines of the figures and logos being carried out directly on the holographic layer (2h ) prior deposit of the holographic product by vaporization. To do this, applying said deposit procedures already described, the holographic product is previously deposited on the lines and limited areas of the corresponding substrate, either directly on polyester or durable plastic sheet (la) or on the surface (2'a2 ) of the second layer (2a2), and then the hot embossing of the corresponding grooves coincidentally over the lines and areas selectively covered with the holographic product by vaporization is performed as described below: The holographic deposit (2h) is carried out either directly on the surface of the layer (la), either on the surface (2'a2) of the second layer (2a2) of a holographic structure, or it is carried out by PVD process (physical vapor deposition) of continuous holographic deposit on coil (8a) (figures 1,2 and 3), the latter comprising: making a continuous impression of areas (17) around the lines that form the figures and logos (3), selectively with silicone wax emulsion, with silicone oil, with vegetable wax, preferably with carnauba wax-paraffin, covering all those remaining areas of the surface (2'a2) of the coil (8a) on which later it is not the figures and logos are going to be engraved (embossing) on the second layer (2a2), and leaving enough space without covering both sides of the embossing lines of the figures and logos that will later be engraved (embossing); a PVD tank is then carried out by vaporization under vacuum or at atmospheric pressure, in a continuous conventional process of obtaining a continuous holographic layer (2h); then the removal and cleaning of the areas that were covered with continuous printing (17), selectively by passing the holographic structure (8b) through a vacuum chamber with oxygen plasma in continuous process, or through the application of a solvent of the silicone derivative to release the silicone derivative and, if necessary, carnauba ceraparaffin, together with the holographic product deposit that has been residual on it; containing the holographic surface (2'h) of the coil
(8b) únicamente depósito de producto holográfico (7) sobre las correspondientes líneas de las figuras logos (3); seguidamente se procede a grabar (embossing) en caliente, con útil metálico de grabado (shims) , las hendiduras que constituyen las figuras y logos holográficos (3) sobre la superficie (2'a2) de la segunda capa (2a2) o en su caso de la superficie (la) , en bobina (8a) previamente cubiertas con depósito de producto holográfico.(8b) only holographic product deposit (7) on the corresponding lines of the logos figures (3); Next, we proceed to hot embossing, with metal engraving tool (shims), the indentations that constitute the holographic figures and logos (3) on the surface (2'a2) of the second layer (2a2) or, where appropriate, of the surface (la), in coil (8a) previously covered with a holographic product tank.
Otra variante que prevé el procedimiento del grabado sobre el depósito holográfico (24) se describe con ayuda de la figura 6, en la que el depósito holográficoAnother variant that provides for the engraving procedure on the holographic tank (24) is described with the aid of Figure 6, in which the holographic tank
(2h) se efectúa bien directamente sobre la superficie de la primera capa (la), o bien sobre la superficie (2'a2) de la segunda capa (2a2) de una estructura holográfica, y se realiza mediante proceso PVD (physical vapor deposition) de depósito holográfico en continuo sobre bobina (8a) que comprende: mediante una cámara de depósito por vaporización en vacío (10) o a presión atmosférica se realiza la vaporización, selectivamente por calentamiento, por efecto magnetrón (sputtering) , por rayo iónico, por rayo de electrones, o por arco, de al menos un producto de depósito holográfico (7) ; realizándose el depósito del producto holográfico vaporizado través de unas perforaciones (16) de una banda sin fin selectivamente metálica o plástica (12cp) que rota continuamente arrastrada por unos rodillos (12r) y en contacto permanente con la superficie (2'a2) de la bobina (8a) que fluye a través de unas compuertas de ranura (llcp) ; correspondiendo coincidentemente el posicionamiento de las perforaciones repetitivas (16) de la banda sin fin, con las respectivas zonas sobre las que se han posicionado las hendiduras de las líneas de las figuras y logos (3) en la bobina (8a) ; siendo las citadas perforaciones (16) más amplias y anchas que las correspondientes a las líneas de las figuras y logos (3) , para permitir ampliamente el paso a través de las perforaciones del depósito holográfico vaporizado y cubrir las correspondientes zonas en la superficie (2'a2) que contienen las líneas y áreas de los grabados(2h) is carried out either directly on the surface of the first layer (la), or on the surface (2'a2) of the second layer (2a2) of a holographic structure, and is carried out by PVD (physical vapor deposition) ) Continuous holographic deposit on coil (8a) comprising: by means of a vacuum vaporization (10) or atmospheric pressure deposit chamber, vaporization is carried out, selectively by heating, by magnetron (sputtering) effect, by ionic ray, by electron beam, or by arc, of at least one holographic deposit product (7); the vaporized holographic product deposit being made through perforations (16) of a selectively metallic or plastic endless band (12cp) that rotates continuously dragged by rollers (12r) and in permanent contact with the surface (2'a2) of the coil (8a) flowing through groove gates (llcp); the positioning of the repetitive perforations (16) of the endless band correspondingly corresponds, with the respective areas on which the grooves of the lines of the figures and logos (3) in the coil (8a) have been positioned; the aforementioned perforations (16) being wider and wider than those corresponding to the lines of the figures and logos (3), to allow the passage through the perforations of the vaporized holographic deposit and cover the corresponding areas on the surface (2) 'a2) containing the lines and areas of the engravings
(embossing) respectivos; y constantemente se arrastra la banda (12cp) sincronizadamente con la bobina (8a) a su paso por la cámara (10) de depósito, y mediante unos sensores optoelectrónicos (12) se detectan unas marcas preimpresas sobre dicha bobina (8a) y sobre la cinta (12cp) , que tienen el mismo ancho que la bobina (8a) , que es accionada por un motor (13) gobernado por un procesador que ajusta el posicionamiento coincidente de la banda (12cp) y de la bobina (8a) ; presionándose el laminado de la bobina (8a) contra la banda (12cp) durante el paso de ambas por la cámara (10) de depósito PVD mediante un sistema de presión constituido selectivamente por una placa (13sp) o por un sistema de banda con rodillos de arrastre (12r) ; seguidamente se graban (embossing) en caliente con útil metálico de grabado (shims) las correspondientes hendiduras que constituyen las figuras y logos holográficos (3) sobre la superficie (2'a2) de la segunda capa (2a2) o en su caso sobre la superficie de la primera capa (la) en bobina (8a) ya cubierta con el depósito de producto holográfico; seguidamente se rebobina en continuo en una bobina (8b) .(embossing) respective; and constantly the band (12cp) is dragged synchronously with the coil (8a) in its path by the deposit chamber (10), and by means of optoelectronic sensors (12), preprinted marks are detected on said coil (8a) and on the tape (12cp), which have the same width as the coil (8a), which is driven by a motor (13) governed by a processor that adjusts the coincident positioning of the band (12cp) and the coil (8a); the laminate of the coil (8a) being pressed against the band (12cp) during the passage of both through the PVD deposit chamber (10) by means of a pressure system selectively constituted by a plate (13sp) or by a roller belt system drag (12r); then the corresponding indentations that constitute the holographic figures and logos (3) on the surface (2'a2) of the second layer (2a2) or, where appropriate, on the surface (2'2) are etched (hot embossing). surface of the first layer (the) in coil (8a) already covered with the holographic product tank; then it is continuously rewound in a coil (8b).
Así mismo los procedimientos anteriores se aplican en la obtención de laminados holográficos para documentos, tarjetas de identidad y de crédito, pasaportes, visados y billetes de banco.Likewise, the above procedures are applied in obtaining holographic laminates for documents, identity and credit cards, passports, visas and banknotes.
De igual forma, el depósito limitado por zonas y líneas de producto holográfico por vaporización en vacío realizado por los procedimientos descritos como parte de la invención se aplica directamente sobre una primera capa (la) constituida por plástico durable (durable plástic) preferentemente por poliéster orientado de un envase o superficie de empaquetado o de etiquetas para envases.Similarly, the deposit limited by zones and lines of holographic product by vacuum vaporization carried out by the procedures described as part of the invention is applied directly on a first layer (the) constituted by durable plastic (durable plastic) preferably by oriented polyester of a container or packaging surface or labels for containers.
En la figura 1 se muestra la estructura primaria de un ejemplo de la invención, del laminado holográfico que forma parte de la estructura del documento, y que está constituido por una primera capa (la) de poliéster orientado transparente, de policarbonato PC, o de plástico durable (durable plástic) , como soporte (carrier) sobre cuya superficie previamente se ha practicado tratamiento superficial mediante descarga de efecto corona y sobre la cual se deposita una capa fina (2al) de imprimación genérica para plásticos, selectivamente constituida por al menos uno de los siguientes elementos: compuesto vinílico, PVDC (cloruro de polivinildieno) , acrilonitrilo, derivado de poliuretano y preferentemente dicha capa (2al) es de laca que polimeriza que endurece por la acción de la luz UV (ultra violeta) o por la acción de radiación electrónica, estando la laca constituida selectivamente por acrilatos monómeros multifuncionales basados en polyols como diluyentes reactivos (thinners) y acrilatos oligómeros como aglutinantes (binders) formados por al menos uno de los siguientes elementos: epoxi- acrilato, poliéster-acrilato, poliéter-acrilato, metano- acrilato, silicon-acrilato, uretano-acrilato, epoxi- silicona, y sus versiones diluibles y emulsionables en agua, de tal forma que sobre dicha capa (2al) se deposita a su vez una segunda capa (2a2) de compuesto acrílico.Figure 1 shows the primary structure of an example of the invention, of the holographic laminate that is part of the structure of the document, and which is constituted by a first layer (la) of transparent oriented polyester, of PC polycarbonate, or of durable plastic (durable plastic), as a carrier (carrier) on whose surface a surface treatment has previously been performed by corona discharge and on which a thin layer (2al) of generic primer for plastics is deposited, selectively consisting of at least one of the following elements: vinyl compound, PVDC (polyvinyldiene chloride), acrylonitrile, polyurethane derivative and preferably said layer (2al) is made of polymerizing lacquer that hardens by the action of UV (ultra violet) light or by the action of electronic radiation, the lacquer being selectively constituted by multifunctional monomeric acrylates based on polyols as reactive diluents (thinners) and oligomeric acrylates as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate , methane acrylate, silicon acrylate, urethane acrylate, epoxy silicone, and its dilutable versions and water-mulsifiable, such that a second layer (2a2) of acrylic compound is deposited on said layer (2al).
En la figura 2 se muestra otra estructura primaria como ejemplo de laminado holográfico de la invención que está constituida por la primera capa (la) se imprimen directamente con líneas gruesas las figuras y logos (3) con laca que endurece por la luz UV o por la acción de la radiación electrónica constituyendo la segunda capa impresa (2a2) . De manera alternativa, la invención prevé la posibilidad de que sobre la primera capa (la) se deposite directamente una segunda capa continua (2a2) de laca que polimeriza y endurece por la acción de la luz UV y selectivamente por la acción de radiación electrónica o por la acción del aire. En ambos casos la segunda capa (2a2) está constituida selectivamente por acrilatos monómeros multifuncionales basados en polyols como diluyentes reactivos (thinners) y acrilatos oligómeros como aglutinantes (binders) formados por al menos uno de los siguientes elementos: epoxi-acrilato, poliéster-acrilato, poliéter-acrilato, metano-acrilato, silicon-acrilato, uretano-acrilato, epoxi-silicona y sus correspondientes versiones solubles al agua.In figure 2 another primary structure is shown as an example of holographic laminate of the invention that is constituted by the first layer (the) figures and logos (3) are printed directly with thick lines with lacquer that hardens by UV light or by the action of electronic radiation constituting the second printed layer (2a2). Alternatively, the invention provides for the possibility that a second continuous layer (2a2) of lacquer that polymerizes and hardens by the action of UV light and selectively by the action of electronic radiation or is directly deposited on the first layer (the) by the action of the air. In both cases the second layer (2a2) is selectively constituted by multifunctional monomeric acrylates based on polyols as reactive diluents (thinners) and oligomeric acrylates such as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon acrylate, urethane acrylate, epoxy silicone and their corresponding water soluble versions.
De ambas estructuras holográficas constituidas según fue descrito en las figuras 1 y 2 se obtiene una bobina (8a) tal como se muestra en la figura 6, que es procesada mediante los tres procedimientos alternativos diferenciados de depósito de producto holográfico por vaporización en vacío o a presión atmosférica, que son objeto de la realización preferida de la invención, en los que se limita el depósito del producto holográfico SZn, TiOx, SiOx, ZrOx, Al , Ag o Bi a zonas y líneas específicas sobre la superficie (2'a2) de la segunda capa (2a2) para obtener un laminado holográfico tanto de tipo HRI (high reflective index) como del tipo metalizado, con posterior encapsulamiento de las líneas y zonas del depósito holográfico correspondientes a las hendiduras que son grabadas (embossing) en caliente de las respectivas figuras y logos (3) holográficos.From both holographic structures constituted as described in figures 1 and 2 a coil (8a) is obtained as shown in figure 6, which is processed by the three differentiated alternative methods of depositing holographic product by vacuum or pressure vaporization atmospheric, which are the object of the preferred embodiment of the invention, in which the deposit of the holographic product SZn, TiOx, SiOx, ZrOx, Al, Ag or Bi is limited to specific areas and lines on the surface (2'a2) of the second layer (2a2) to obtain a holographic laminate of both the HRI type (high reflective index) and the metallic type, with subsequent encapsulation of the lines and areas of the holographic deposit corresponding to the grooves that are hot embossing of the respective holographic figures and logos (3).
La Figura 10 representa una realización específica de esta invención correspondiente a una estructura que comprende una estructura holográfica combinada, con depósito de una primera capa holográfica (2hι) de producto holográfico tipo HRI transparente (high reflective index) sobre zonas específicas del substrato grabable (shims embossable plástic) constituido por la segunda capa (2a2) y de depósito de una segunda capa holográfica (2h2) de producto holográfico metalizado sobre otras zonas concretas del mismo substrato grabable (2a2) ; esta estructura holográfica combinada está constituida por una primera capa soporte (la) de poliéster orientado o de plástico durable (durable plástic) , tanto en bobina como en pliegos, sobre cuya superficie, previa descarga de efecto corona o tratamiento previo de plasma 02, comprende un depósito o impresión de cera de silicona o de cera vegetal preferentemente de cera /parafina de carnauba que forma una capa fina (2al) ; sobre la cual se incluye una impresión o depósito, previa descarga de efecto corona o tratamiento previo de plasma 02, de plástico grabable, preferentemente de laca grabable que endurece por la acción de la luz UV o por la acción de radiación electrónica, formando así la capa segunda (2a2) ; a continuación en la superficie (2 ' a2) comprende un grabado (embossing) realizado mediante útil de presión (shims) de las respectivas hendiduras correspondientes a las líneas y zonas del diseño de las figuras holográficas y seguidamente comprende, previa descarga de efecto corona o tratamiento previo de plasma 02, un depósito de una primera capa holográfica (2hl) realizado únicamente con producto holográfico transparente HRI , aplicado mediante un procedimiento PVD (physical vapor deposition) de depósito por vaporización en vacío o a presión atmosférica; estando el producto holográfico transparente HRI constituido por al menos uno de los productos SZn, TiOx, SiOx, ZrOx; a continuación previa descarga de efecto corona o tratamiento previo de plasmaFigure 10 represents a specific embodiment of this invention corresponding to a structure comprising a combined holographic structure, with deposit of a first holographic layer (2hι) of transparent HRI type (high reflective index) over specific areas of the recordable substrate (shims plastic embossable) consisting of the second layer (2a2) and deposit of a second holographic layer (2h2) of metallic holographic product on other specific areas of the same recordable substrate (2a2); This combined holographic structure is constituted by a first support layer (the) of oriented polyester or durable plastic (durable plastic), both in coil and in sheets, on whose surface, prior discharge of corona effect or Plasma 02 pretreatment, comprises a deposit or impression of silicone wax or vegetable wax preferably of carnauba wax / paraffin that forms a thin layer (2al); on which a print or deposit is included, prior to corona discharge or plasma 02 pretreatment, of recordable plastic, preferably of recordable lacquer that hardens by the action of UV light or by the action of electronic radiation, thus forming the second layer (2a2); then on the surface (2 'a2) it comprises an engraving (embossing) made by means of a pressure tool (shims) of the respective slits corresponding to the lines and areas of the design of the holographic figures and then comprises, prior to the discharge of the corona effect or Plasma 02 pretreatment, a deposit of a first holographic layer (2hl) made only with HRI transparent holographic product, applied by means of a PVD (physical vapor deposition) deposition process by vacuum vaporization or atmospheric pressure; the HRI transparent holographic product being constituted by at least one of the products SZn, TiOx, SiOx, ZrOx; then prior corona discharge or plasma pretreatment
02, comprende un depósito de una segunda capa holográfica02, comprises a deposit of a second holographic layer
(2h2) de producto holográfico metálico aplicado selectivamente mediante un procedimiento PVD (physical vapor deposition) de depósito por vaporización en vacío o a presión atmosférica; estando el producto holográfico metálico selectivamente constituido por al menos uno de los productos Al, Bi, o Ag; estando así constituida sobre la superficie (2'a2) del substrato (2a2) , la capa holográfica de depósito holográfico combinado, formada por los correspondientes depósitos holográficos zonales (2hl) y (2h2) con su superficie (2'h); seguidamente, previa descarga de efecto corona o tratamiento previo de plasma 02, comprende una capa zonal (2a4) de encapsulamiento preferentemente de laca que endurece por la acción de la luz UV que corresponde a las zonas de la superficie (2 ' h) de la capa de depósito holográfico combinado (2h) sobre las que únicamente se ha realizado el depósito de la primera capa (2hl) selectivo de producto holográfico transparente HRI ; seguidamente comprende una gradual desmetalización del depósito de producto holográfico metálico; y a continuación comprende la zona de encapsulamiento, preferentemente con laca, de la parte de la superficie (2'h) correspondiente al depósito de producto holográfico metalizado de la segunda capa (2h2) , formando así la capa(2h2) of metal holographic product selectively applied by means of a PVD (physical vapor deposition) deposition process by vacuum vaporization or atmospheric pressure; the metal holographic product being selectively constituted by at least one of the products Al, Bi, or Ag; being thus constituted on the surface (2'a2) of the substrate (2a2), the holographic layer of combined holographic deposit, formed by the corresponding holographic zone deposits (2hl) and (2h2) with its surface (2'h); then, after discharge of corona effect or plasma pretreatment 02, it comprises a zonal layer (2a4) of encapsulation preferably of lacquer that hardens by the action of UV light that corresponds to the areas of the surface (2 'h) of the combined holographic deposit layer (2h) on which only the deposit of the first layer (2hl) has been made ) HRI transparent holographic product selective; then it includes a gradual demetalization of the deposit of metallic holographic product; and then comprises the encapsulation zone, preferably with lacquer, of the part of the surface (2'h) corresponding to the deposit of metallic holographic product of the second layer (2h2), thus forming the layer
(2a4) sobre la que a su vez se encuentra adherida o depositada una quinta capa (2a5) que según el tipo de aplicación del laminado holográfico combinado está selectivamente formada por: depósito de derivado poliolefínico PE, polipropileno, ácido etileno-acrílico con adición de derivado de poliuretano, termoadhesivo para papel moneda o para pasaporte o visados, derivado de polivinilo con adición de PVDC (cloruro de polivinildieno) para personalización con impresión de termosublimación D2T2 , o una capa de termoadhesivo de base poliuretano que a su vez adhiere una capa de derivado modificado de PET-G (polietileno-tereftalato-glicol ; el depósito de la segunda capa (2h2) de producto holográfico metálico del laminado holográfico combinado se personaliza mediante grabado con rayo láser (holographic embossing) con la réplica de la imagen facial del titular del documento de identidad o pasaporte en que el laminado holográfico combinado ha sido termolaminado. La Figura 10a representa una realización de la invención de una estructura de documento de identidad integralmente de policarbonato que comprende una estructura constituida por una lámina (Lpc) de policarbonato que se superpone por termolaminación a ambas caras de un núcleo (C) de un documento integralmente de policarbonato, sobre el que previamente se ha adherido o termolaminado un holograma zonal combinado de zona holográfica HRI transparente de la primera capa (2hl) y de zona holográfica metálica de la segunda capa (2h2) cuya zona metálica (Hmz) es personalizada por grabado láser destructivo. El núcleo (C) está constituido por láminas (Csl)de policarbonato, sobre una parte concreta de cuya superficie (C'sl) está adherida la estructura del holograma combinado que contiene el holograma metálico zonal (Hmz) que es personalizado mediante grabado láser destructivo (burning) antes o después de la termolaminación del núcleo (C) con las cubiertas de láminas (Lpc) de policarbonato transparente; incluyéndose en el grabado láser de personalización una grabación de datos personales y la réplica de la imagen facial del titular del documento de identidad; estando el holograma zonal combinado HRI transparente metálico zonal(2a4) on which a fifth layer (2a5) is adhered or deposited which, depending on the type of application of the combined holographic laminate, is selectively formed by: PE polyolefin derivative deposit, polypropylene, ethylene-acrylic acid with the addition of polyurethane derivative, thermoadhesive for paper money or for passport or visas, polyvinyl derivative with addition of PVDC (polyvinyldiene chloride) for personalization with D2T2 thermo-sublimation printing, or a layer of thermo-adhesive based polyurethane which in turn adheres a layer of modified derivative of PET-G (polyethylene-terephthalate-glycol; the deposit of the second layer (2h2) of holographic metal product of the combined holographic laminate is customized by laser engraving (holographic embossing) with the replica of the facial image of the holder of the identity document or passport in which the combined holographic laminate has been thermolaminated Figure 10a r it represents an embodiment of the invention of an integrally polycarbonate identity document structure comprising a structure consisting of a sheet (Lpc) of polycarbonate which is superimposed by thermolamination on both sides of a core (C) of an integrally polycarbonate document, on which has previously been adhered or thermolaminated a combined zonal hologram of transparent HRI holographic zone of the first layer (2hl) and metallic holographic zone of the second layer (2h2) whose metallic zone (Hmz) is customized by destructive laser engraving. The core (C) is constituted by sheets (Csl) of polycarbonate, on a specific part of whose surface (C's) the structure of the combined hologram containing the zonal metal hologram (Hmz) is attached, which is customized by destructive laser engraving (burning) before or after the thermolamination of the core (C) with the transparent polycarbonate sheet covers (Lpc); including in the laser engraving of personalization a recording of personal data and the replica of the facial image of the holder of the identity document; the combined zone hologram being HRI transparent metallic zonal
(Hmz) producido por un procedimiento PVD de vaporización de depósito respectivo de producto holográfico HRI transparente y de producto holográfico metálico (Al, Bi, Ag) y cuya estructura, después ser adherido o termolaminado selectivamente con la lámina (Lpc) o con el núcleo (C) , está compuesta por la segunda capa (2a2) de producto plástico grabable (shims embossable plástic) o derivado acrílico, preferentemente de laca grabable sobre la cual se encuentra depositado la segunda capa de producto holográfico metálico zonal de la segunda capa (2h2) y de producto holográfico transparente de la primera capa (2hl) , sobre la que a su vez está depositado o adherido la capa zonal (2a4) de encapsulamiento que está formada por derivado acrílico, preferentemente formada por laca que endurece por la acción de la luz UV o por la acción de la radiación electrónica, que a su vez contiene una cuarta capa (3bl) de termoadhesivo selectivamente de base poliuretano o de base de polímero poliolefínico; para que dependiendo del tamaño elegido para el holograma metálico zonal (Hmz) y su ubicación sobre la superficie (C'sl) respecto del posicionamiento, figuras, logos e imagen facial de datos de personalización sobre superficie (C'sl) que constituye la cara frontal del documento, la capa zonal de encapsulamiento (2a4) es sustituida por la propia cuarta capa de termoadhesivo (3bl) .(Hmz) produced by a PVD method of vaporization of the respective deposit of transparent HRI holographic product and metallic holographic product (Al, Bi, Ag) and whose structure, then be adhered or selectively thermo-laminated with the sheet (Lpc) or with the core (C), is composed of the second layer (2a2) of recordable plastic product (plastic embossable shims) or acrylic derivative, preferably of recordable lacquer on which the second layer of zonal metal holographic product of the second layer (2h2) is deposited ) and of transparent holographic product of the first layer (2hl), on which the zonal layer (2a4) of encapsulation which is formed by acrylic derivative, preferably formed by lacquer that hardens by the action of the UV light or by the action of electronic radiation, which in turn contains a fourth layer (3bl) of selectively polyurethane-based or poly-based thermo-adhesive mere polyolefin; so that depending on the size chosen for the zonal metal hologram (Hmz) and its location on the surface (C'sl) with respect to the positioning, figures, logos and facial image of personalization data on surface (C'sl) that constitutes the front face of the document, the zonal encapsulation layer (2a4) is replaced by the own fourth layer of thermoadhesive (3bl).
La Figura 10b representa una realización específica de la presente invención de estructura holográfica que es aplicada a billetes de banco, pasaportes, visados y documento que comprende una estructura holográfica, selectivamente de tipo HRI transparente (high reflective index) o de laminado holográfico metalizado; dicha estructura está constituida por una primera capa soporte (la) de poliéster orientado o de plástico durable (durable plástic), tanto en bobina como en pliegos, sobre cuya superficie, previa descarga de efecto corona o tratamiento previo de plasma 02, se imprimen con cera de silicona o con cera vegetal preferentemente con cera /parafina de carnauba únicamente una capa fina (2al) que constituyen unas líneas y zonas que coinciden con las líneas y zonas correspondientes a las figuras, escudos y logos holográficos; sobre cuya capa o líneas y zonas (2al) así impresas se imprimen a su vez con plástico grabable, preferentemente con laca grabable que endurece por la acción de la luz (UV) o por la acción de radiación electrónica o por la acción del aire, previa descarga de efecto corona o tratamiento previo de plasma 02, cubriendo una segunda capa (2a2) las líneas y zonas (2al) con la laca grabable endurecida; a continuación se efectúa un grabado (embossing) mediante hendiduras coincidentes con las mencionadas líneas y zonas (2al) de la superficie (2'a2) de la segunda capaFigure 10b represents a specific embodiment of the present invention of holographic structure that is applied to banknotes, passports, visas and document comprising a holographic structure, selectively of transparent HRI type (high reflective index) or of metallic holographic laminate; said structure is constituted by a first support layer (la) of oriented polyester or durable plastic (durable plastic), both in coil and in sheets, on whose surface, after corona discharge or plasma pretreatment 02, are printed with silicone wax or vegetable wax preferably with carnauba wax / paraffin only a thin layer (2al) that constitute lines and areas that coincide with the lines and zones corresponding to holographic figures, shields and logos; on whose layer or lines and zones (2al) thus printed are printed in turn with recordable plastic, preferably with recordable lacquer that hardens by the action of light (UV) or by the action of electronic radiation or by the action of air, previous discharge of corona effect or previous treatment of plasma 02, covering a second layer (2a2) the lines and zones (2al) with the hardened recordable lacquer; an embossing is then carried out by means of grooves coinciding with the mentioned lines and zones (2al) of the surface (2'a2) of the second layer
(2a2) y seguidamente, previa descarga de efecto corona o tratamiento previo de plasma 02, se realiza el depósito de producto holográfico con los procedimientos PVD (physical vapor deposition) alternativos diferenciados de depósito por vaporización en vacío o a presión atmosférica, depositando dicho producto holográfico únicamente sobre las mencionadas líneas y zonas (2al) de la superficie (2'a2) constituyendo así las figuras y logos holográficos; seguidamente, previa descarga de efecto corona o tratamiento previo de plasma 02, se imprime con termoadhesivo, constituido selectivamente por ácido etileno-acrílico con adición de derivado mono o bicomponente de poliuretano o por termoadhesivo para papel, cubriendo únicamente las citadas líneas y zonas de depósito holográfico; habiéndose previsto que la bobina o los pliegos de la primera capa soporte (la) , comprendan marcas de registro, previamente impresas, para permitir la exactitud en las sucesivas impresiones que cubren las líneas y zonas de las hendiduras grabadas sobre segunda la capa (2a2) ; el laminado holográfico así obtenido, previa descarga de efecto corona o tratamiento previo de plasma O2, es superpuesto y termolaminado, bien en bobina en continuo o bien en pliegos, para fundir la cera de silicona o preferentemente la cera /parafina de carnauba y así desprender la capa soporte (carrier) (la) de poliéster por el calor aplicado, para fuertemente adherir al papel de cada billete de banco la protección formada por el holograma trasparente HRI o metálico, selectivamente desmetalizado por zonas; que comprende los logos y figuras holográficos cuyas líneas están protegidas contra el desgaste por la cobertura de la laca de la segunda capa (2a2) endurecida; estando la capa holográfica (2h) depositada compuesta selectivamente por SZn, TiOx, SiOx, ZrOx, Al, Bi, o Ag y está limitada únicamente a zonas y líneas específicas selectivamente sobre la superficie (2'a2) de la segunda capa (2a2) .(2a2) and then, after discharge of corona effect or prior plasma treatment 02, the holographic product is deposited with the differentiated physical vapor deposition (PVD) methods of deposit differentiated by vacuum or atmospheric pressure vaporization, depositing said holographic product only on the mentioned lines and zones (2al) of the surface (2'a2) thus constituting the holographic figures and logos; then, after discharge of corona effect or prior plasma treatment 02, it is printed with thermoadhesive, selectively constituted by ethylene-acrylic acid with addition of mono or bicomponent derivative of polyurethane or by thermal adhesive for paper, covering only the mentioned lines and areas of deposit holographic; having provided that the coil or the sheets of the first support layer (la), include registration marks, previously printed, to allow accuracy in the successive impressions covering the lines and areas of the grooves engraved on the second layer (2a2) ; The holographic laminate thus obtained, prior to corona discharge or prior treatment of O2 plasma, is superimposed and thermo-laminated, either in continuous coil or in sheets, to melt the silicone wax or preferably the carnauba wax / paraffin and thus detach the carrier layer (la) of polyester by the heat applied, to strongly adhere to the paper of each banknote the protection formed by the transparent HRI or metallic hologram, selectively demetalized by zones; comprising the logos and holographic figures whose lines are protected against wear by the lacquer covering of the second hardened layer (2a2); the deposited holographic layer (2h) being selectively composed of SZn, TiOx, SiOx, ZrOx, Al, Bi, or Ag and is limited only to specific areas and lines selectively on the surface (2'a2) of the second layer (2a2) .
La Figura 4a representa una realización de la presente invención estructura de laminado holográfico que comprende una estructura holográfica, selectivamente de tipo HRI transparente (high reflective index) o de laminado 51 holográfico metalizado, que está constituido por una primera capa soporte (la) de poliéster orientado o de plástico durable (durable plástic) , tanto en bobina como en pliegos, sobre cuya superficie, previa descarga de efecto corona o tratamiento previo de plasma 02, se deposita la capa fina (2al) de cera de silicona o de cera vegetal preferentemente cera /parafina de carnauba, sobre cuya superficie previa descarga de efecto corona o tratamiento previo de plasma 02, se deposita una capa (2a3) constituida selectivamente por al menos uno de los siguientes productos: derivado de acetato, derivado poliolefínico, derivado de polipropileno, derivado acrílico, derivado de silicona, derivado epoxi, derivado de poliuretano, derivado de polietileno-teref alato, o preferentemente por laca, que endurece por la acción de la luz UV, por la acción de la radiación electrónica o por acción del aire, y a continuación previa descarga de efecto corona o tratamiento previo de plasma O2, se deposita la segunda capa (2a2) de derivado acrílico sobre cuya superficie (2'a2) se efectúa el grabado (embossing) de las respectivas hendiduras de las líneas y zonas correspondientes a las figuras y logos; a continuación, previa descarga de efecto corona o tratamiento previo de plasma 02, se deposita el producto holográfico mediante procedimiento PVD (physical vapor deposition) de depósito que cubre solo líneas y zonas específicas de la superficieFigure 4a represents an embodiment of the present invention holographic laminate structure comprising a holographic structure, selectively of transparent HRI (high reflective index) or laminate type 51 metallic holographic, which is constituted by a first support layer (the) of oriented polyester or durable plastic (durable plastic), both in coil and in sheets, on whose surface, after corona discharge or prior plasma treatment 02, the thin layer (2al) of silicone wax or vegetable wax, preferably carnauba wax / paraffin, is deposited on whose previous surface corona discharge or plasma pretreatment 02, a layer (2a3) selectively constituted by at least one of the following products: acetate derivative, polyolefin derivative, polypropylene derivative, acrylic derivative, silicone derivative, epoxy derivative, polyurethane derivative, polyethylene teref alato derivative, or preferably lacquer, which hardens by the action of the UV light, by the action of electronic radiation or by air action, and then after corona discharge or pre-treatment of plasma O2, is it places the second layer (2a2) of acrylic derivative on whose surface (2'a2) the embossing of the respective slits of the lines and zones corresponding to the figures and logos is made; then, after discharge of corona effect or prior plasma treatment 02, the holographic product is deposited by means of PVD (physical vapor deposition) deposition procedure that covers only specific lines and areas of the surface
(2'a2) de producto holográfico o mediante procedimiento PVD(2'a2) of holographic product or by PVD procedure
(physical vapor deposition) de depósito convencional que cubre toda la superficie (2'a2) de la segunda capa (2a2) de producto holográfico, constituyendo así la capa holográfica que contiene las figuras y logos holográficos (2'h); seguidamente, previa descarga de efecto corona o tratamiento previo de plasma O2, se incluye un encapsulamiento de la superficie holográfica (2'h), con una capa zonal (2a4) que en función del tipo de aplicación del laminado holográfico así constituido está formada selectivamente por uno de los siguientes compuestos: por laca que endurece selectivamente por la acción de la luz UV o por la acción de la radiación de la radiación electrónica, por el aire. por depósito seleccionado entre derivado poliolefínico PE o polipropileno. selectivamente por termoadhesivo para papel o preferentemente por ácido etileno-acrílico con adición de derivado de poliuretano, para su aplicación en papel moneda, pasaportes y visados y documentos, y para impresión de personalización de termosublimación D2T2.(physical vapor deposition) of a conventional tank covering the entire surface (2'a2) of the second layer (2a2) of holographic product, thus constituting the holographic layer containing the holographic figures and logos (2'h); then, after discharge of corona effect or prior treatment of O2 plasma, an encapsulation of the holographic surface (2'h) is included, with a zonal layer (2a4) that depending on the type of application of the holographic laminate thus constituted is selectively formed by one of the following compounds: by lacquer that selectively hardens by the action of UV light or by the action of electronic radiation radiation, by air. by deposit selected from polyolefin derivative PE or polypropylene. selectively by thermo-adhesive for paper or preferably by ethylene-acrylic acid with addition of polyurethane derivative, for application in paper money, passports and visas and documents, and for personalization printing of D2T2 thermosublimation.
- por derivado de polivinilo con adición de PVDC (cloruro de polivinildieno) para impresión de personalización de termosublimación D2T2.- by polyvinyl derivative with addition of PVDC (polyvinyldiene chloride) for D2T2 thermosublimation customization printing.
- por una capa de termoadhesivo de base poliuretano que a su vez adhiere una capa de derivado modificado de PET-G (polietileno-tereftalato- glicol) .- by a layer of polyurethane based thermoadhesive which in turn adheres a modified derivative layer of PET-G (polyethylene terephthalate glycol).
En cualquiera de los ejemplos descritos de estructura holográficas, el procedimiento de la invención realiza el encapsulado de las zonas y líneas de depósito de producto holográfico de la capa holográfica (2h) , mediante la adición respectiva de las configuraciones de capas sobre la superficie (2'h) que a continuación se describen, tomando por base las estructuras de las figuras 1 y 2:In any of the described examples of holographic structure, the process of the invention encapsulates the holographic product deposit areas and lines of the holographic layer (2h), by the respective addition of the layer configurations on the surface (2 'h) described below, based on the structures of Figures 1 and 2:
- Previamente se efectúa descarga de efecto corona sobre la cara holográfica (2'h), y a continuación sobre dicha superficie se deposita una capa preferentemente con laca que polimeriza y endurece por la acción de la luz UV o por la acción de radiación electrónica, de forma que dicha laca está constituida selectivamente por acrilatos monómeros multifuncionales basados en polyols como diluyentes reactivos (thinners) y acrilatos oligómeros como aglutinantes (binders) formados por al menos uno de los siguientes elementos: epoxi-acrilato, poliéster-acrilato, poliéter-acrilato, metano-acrilato, silicon-acrilato, uretano-acrilato, epoxi-silicona, y sus correspondientes versiones diluibles y emulsionables en agua.- Previously, corona discharge is carried out on the holographic face (2'h), and then on said surface a layer is preferably deposited with lacquer that polymerizes and hardens by the action of UV light or by the action of electronic radiation, of such that said lacquer is selectively constituted by polyols based multifunctional monomeric acrylates such as reactive diluents (thinners) and oligomeric acrylates as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicone acrylate, urethane acrylate, epoxy silicone , and their corresponding versions dilutable and emulsifiable in water.
- Otra posibilidad de encapsulado se muestra en la figura 11, en la que tras efectuarse la descarga de efecto corona sobre la cara holográfica (2'h), a continuación se aplica adhesivo (2plu) genérico para plásticos preferentemente bicomponente de base poliuretano que adhiere una tercera capa (lal) constituida por derivado modificado PET-G (tereftalato polietileno-glicol) y preferentemente por derivado modificado PET-G con aditivo de carbón micronizado y selectivamente con aditivo de óxido de titanio y con inhibidor supresor de llama.- Another possibility of encapsulation is shown in Figure 11, in which after the corona effect has been discharged on the holographic face (2'h), then generic adhesive (2plu) is applied to plastics, preferably bicomponent of polyurethane-based base that adheres a third layer (lal) constituted by modified PET-G derivative (polyethylene glycol terephthalate) and preferably by modified PET-G derivative with micronized carbon additive and selectively with titanium oxide additive and with flame suppressor inhibitor.
- En la figura 12 se muestra otro posible encapsulado, en el que previamente se efectúa descarga de efecto corona y a continuación sobre la cara holográfica (2'h), se deposita en caliente por coextrusión del compuesto genérico adherente de capa-base (tie-layer) junto con el derivado modificado PET-G (tereftalato polietileno- glicol) y preferentemente de derivado modificado PET-G con aditivo de carbón micronizado con inhibidor supresor de llama y selectivamente con aditivo de óxido de titanio, constituyéndose la capa (la2) de encapsulado.- In Figure 12 another possible encapsulation is shown, in which corona discharge is previously carried out and then on the holographic face (2'h), it is hot deposited by coextrusion of the generic base-layer adherent compound (tie- layer) together with the modified PET-G derivative (polyethylene glycol terephthalate) and preferably PET-G modified derivative with micronized carbon additive with flame suppressor inhibitor and selectively with titanium oxide additive, constituting the layer (la2) of encapsulated
En la figura 13, para realizar el encapsulado, previamente se efectúa descarga de efecto corona y a continuación sobre la cara holográfica (2'h) se deposita selectivamente mediante inyección en caliente, mediante impresión off-set, mediante impresión serigráfica, o mediante extrusión, una séptima capa (lg) selectivamente compuesta por al menos uno de los siguientes elementos: derivado vinílico, PVDC (cloruro de polivinildieno) , acrilonitrilo, derivado de poliuretano. En la figura 14, para realizar el encapsulado, previamente se efectúa descarga de efecto corona y a continuación sobre la cara holográfica (2'h), se deposita selectivamente mediante inyección en caliente, mediante impresión off-set, mediante impresión serigráfica, o mediante extrusión, una octava capa (lf) de termoadhesivo compuesta preferentemente por ácido etileno-acrílico y derivados de poliuretano o alternativamente por al menos dos de los elementos siguientes: gelatina, derivados acrílicos, ácidos acrílicos, poliamida y derivados de poliuretano, de forma que la octava capa (lf) así constituida termolamina con el papel de la hoja de datos de pasaporte, visado o documento en general.In Figure 13, to perform the encapsulation, a corona effect discharge is previously made and then on the holographic face (2'h) it is selectively deposited by hot injection, by off-set printing, by screen printing, or by extrusion, a seventh layer (lg) selectively composed of at least one of the following elements: vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile, polyurethane derivative. In Figure 14, to perform the encapsulation, a corona effect discharge is previously made and then on the holographic face (2'h), it is selectively deposited by hot injection, by off-set printing, by screen printing, or by extrusion , an eighth layer (lf) of thermo-adhesive preferably composed of ethylene-acrylic acid and polyurethane derivatives or alternatively at least two of the following elements: gelatin, acrylic derivatives, acrylic acids, polyamide and polyurethane derivatives, so that the eighth layer (lf) thus constituted thermolamine with the paper of the passport data sheet, visa or document in general.
- En la figura 14a, como modalidad alternativa para realizar el encapsulado, previamente se efectúa descarga de efecto corona y a continuación sobre la cara holográfica (2'h), se aplica adhesivo (2plu) genérico para plásticos preferentemente bicomponente de base poliuretano que adhiere la tercera capa (lal) constituida por una lámina de derivado modificado PET-G (tereftalato polietileno-glicol) con o sin aditivo de carbón micronizado que tiene embutido e integrado un chip de radiofrecuencia- In Figure 14a, as an alternative modality to perform the encapsulation, corona discharge is previously carried out and then on the holographic face (2'h), generic adhesive (2plu) is applied for plastics, preferably two-component polyurethane-based plastics that adheres the third layer (lal) consisting of a PET-G modified derivative sheet (polyethylene glycol terephthalate) with or without micronized carbon additive that has a radio frequency chip embedded and integrated
(5c) con su antena (5ant) . A continuación se deposita selectivamente mediante inyección en caliente, mediante impresión off-set, mediante impresión serigráfica, o mediante extrusión, una octava capa (lf) ya descrita, de forma que termolamina con el papel de la hoja de datos de pasaporte o visado o documento en general, dotándolo de un chip de seguridad. - En la figura 15, para realizar el encapsulado, previamente se efectúa descarga de efecto corona y a continuación sobre la cara holográfica (2'h), se deposita selectivamente mediante inyección en caliente, o mediante extrusión, una novena capa (le) de termoadhesivo de polímero poliolefínico compuesta por polietileno, polietileno modificado, o por polipropileno.(5c) with its antenna (5ant). Subsequently, it is selectively deposited by hot injection, by off-set printing, by screen printing, or by extrusion, an eighth layer (lf) already described, so that it thermolaminates with the paper of the passport or visa data sheet or document in general, providing it with a security chip. - In Figure 15, to perform the encapsulation, a corona effect discharge is previously made and then on the holographic face (2'h), a ninth layer (le) of thermoadhesive is selectively deposited by hot injection, or by extrusion of polyolefin polymer composed of polyethylene, modified polyethylene, or by polypropylene.
La realización preferida de la invención también se refiere a las estructuras del núcleo del documento compatible con las cubiertas holográficas descritas con anterioridad, de forma que se constituye un núcleo (C) que comprende un conjunto central con 1 a n capas (Cl, C2,..Cn) de PET-G modificado, Figura 16, una de cuyas capas puede tener integrado un chip (5c) de radiofrecuencia con antena (5ant) . Además el núcleo incluye dos terceras capas (lal) , para lo que sobre al menos una de sus caras (3e, 3'e) se termolamina o se extrusiona una tercera capa (lal) de derivado modificado PET-G con aditivo genérico para grabado por rayo láser destructivo, o selectivamente de carbón micronizado con supresor inhibidor de llama. Sobre las caras (4e,4'e) de las terceras capasThe preferred embodiment of the invention also relates to the core structures of the document compatible with the holographic covers described above, so that a core (C) comprising a central assembly with 1 layers (Cl, C2 ,.) is constituted. .Cn) of modified PET-G, Figure 16, one of whose layers can have integrated a radio frequency chip (5c) with antenna (5ant). In addition, the core includes two third layers (lal), for which at least one of its faces (3e, 3'e) is thermolaminated or a third layer (lal) of PET-G modified derivative is extruded with generic additive for engraving by destructive laser beam, or selectively of micronized carbon with flame inhibitor suppressor. On the faces (4e, 4'e) of the third layers
(lal) se deposita, previa descarga de efecto corona, por uno de los procedimientos siguientes: extrusión, inyección en caliente, impresión serigráfica, impresión corrosiva, o por termodepósito (hot stamping) , una séptima capa (lg) en toda la superficie, que está constituida selectivamente por al menos uno de los elementos siguientes: derivado vinílico, PVDC (cloruro de polivinildieno), acrilonitrilo. Sobre la superficie de la séptima capa(lg), se imprime la personalización de los datos personales e imagen facial mediante impresión color D2T2 de termosublimación.(lal) is deposited, prior to corona discharge, by one of the following procedures: extrusion, hot injection, screen printing, corrosive printing, or by hot stamping, a seventh layer (lg) over the entire surface, which is selectively constituted by at least one of the following elements: vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile. On the surface of the seventh layer (lg), personalization of personal data and facial image is printed by D2T2 color printing of thermosublimation.
Además la realización preferida prevé que el núcleo (C) esté formado por la estructura según se representa en la Figura 17, que se constituye por un conjunto central con n capas (Cl, C2,..Cn) de PET-G modificado. Una de las capas del conjunto central de PET-G puede tener integrado un chip (5c) de radiofrecuencia con antena (5ant) . Sobre al menos una de las caras ( 3e, 3'e) del Conjunto Central se termolamina o se extrusiona una tercera capa (lal) de derivado modificado PET-G con aditivo genérico para grabado por rayo láser destructivo, selectivamente de carbón micronizado con supresor inhibidor de llama. Sobre las caras (4e,4'e) se deposita, previa descarga de efecto corona, por uno de los procedimientos siguientes: extrusión, inyección en caliente, impresión serigráfica, impresión corrosiva, por termodepósito (hot stamping) , una capa con una superficie limitada y concreta (4z) constituida por uno de los siguientes productos:In addition, the preferred embodiment provides that the core (C) is formed by the structure as shown in Figure 17, which is constituted by a central assembly with n layers (Cl, C2, .. Cn) of modified PET-G. One of the layers of the PET-G central assembly can have integrated a radio frequency chip (5c) with antenna (5ant). On at least one of the faces (3e, 3'e) of the Central Assembly is thermolaminated or a third layer (lal) of PET-G modified derivative is extruded with generic additive for destructive laser beam engraving, selectively of micronized carbon with flame inhibitor suppressor. On the faces (4e, 4'e), one of the following procedures is deposited, prior to corona discharge, extrusion, hot injection, screen printing, corrosive printing, by hot stamping, a layer with a surface Limited and concrete (4z) consisting of one of the following products:
- Al menos uno de los elementos siguientes: derivado vinílico, PVDC (cloruro de polivinildieno) , acrilonitrilo, de forma que sobre la superficie limitada (4z) del núcleo, se imprime la personalización la imagen facial y de datos personales mediante impresión color D2T2 de termosublimación.- At least one of the following elements: vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile, so that on the limited surface (4z) of the core, the personalization of the facial image and personal data is printed by D2T2 color printing of thermosublimation.
- Por compuesto genérico para impresión con sistema de inyección de tinta, y alternativamente conteniendo gelatina, para la personalización con impresora color de inyección de tinta.- By generic compound for printing with inkjet system, and alternatively containing gelatin, for customization with inkjet color printer.
- Por al menos uno de los elementos siguientes: de gelatina pura, de derivados acrílicos, de derivados polímeros de poliamida, o combinación de ellos, de manera que la superficie (4z) así cubierta es personalizada con la imagen facial mediante el sistema fotográfico de Transferencia por Difusión Inversa por el que el negativo portador de la imagen color o en escala de grises, se superpone sobre la superficie concreta (4z) y aplicando ligera presión y en presencia de un revelador fotográfico, en cuya operación se transfiere la imagen facial y en su caso la huella, firma y texto a la citada superficie limitada (4z) . Para simetrizar y paliar las posibles tensiones que se producen en la termolaminación del documento o tarjeta de identidad, se integran bien en medio del núcleo (C) o bien a ambos lados del mismo, una lámina de poliéster o de policarbonato, para lo que se constituye una estructura simétrica de capas que o se termolaminan sobre ambas caras (3e,3'e) del Conjunto Central del núcleo (C) o es integrada en medio de dicho núcleo, constituidas por los siguientes componentes:- For at least one of the following elements: pure gelatin, acrylic derivatives, polyamide polymer derivatives, or combination thereof, so that the surface (4z) thus covered is personalized with the facial image by means of the photographic system of Reverse Diffusion Transfer whereby the negative carrier of the color or grayscale image is superimposed on the concrete surface (4z) and applying light pressure and in the presence of a photographic developer, in whose operation the facial image is transferred and where appropriate, the footprint, signature and text to the aforementioned limited area (4z). To symmetrize and alleviate the possible tensions that occur in the thermolamination of the document or identity card, they are integrated either in the middle of the core (C) or on both sides thereof, a sheet of polyester or polycarbonate, for which constitutes a symmetric structure of layers that or thermolaminate on both sides (3e, 3'e) of the Core Core Assembly (C) or is integrated in the middle of said core, consisting of the following components:
Simétricamente sobre ambas caras (3e,3'e) del Conjunto Central (Cl, C2,..Cn)del núcleo(C) tal y como se muestra en las figuras 19a y 19b, se adhiere respectivamente una estructura de capas constituida simétricamente por: una décima capa (Ib) formada por una lámina de poliéster o de policarbonato a ambas caras de la cual con adhesivo genérico o con adhesivo de base poliuretano (2plu) se adhiere de un lado una tercera capaSymmetrically on both sides (3e, 3'e) of the Central Assembly (Cl, C2, .. Cn) of the core (C) as shown in Figures 19a and 19b, a layer structure constituted symmetrically by respectively adheres : a tenth layer (Ib) formed by a polyester or polycarbonate sheet on both sides of which a third layer is adhered on one side with a generic adhesive or polyurethane base adhesive (2plu)
(lal) de PET-G opcionalmente con aditivo para grabado láser, preferentemente de carbón micronizado, y al otro lado se adhiere igualmente una capa (lal) de derivado PET- G, con o sin aditivo de carbón micronizado. Sobre esta última capa se deposita a continuación la séptima capa(lal) of PET-G optionally with additive for laser engraving, preferably of micronized carbon, and also a layer (lal) of PET-G derivative is adhered, with or without micronized carbon additive. The seventh layer is then deposited on this last layer
(lg) constituida selectivamente por al menos uno de los elementos siguientes: derivado vinílico, PVDC (cloruro de polivinildieno), acrilonitrilo. Integrada en medio del Conjunto Central del núcleo (C),tal y como se muestra en la figura 19 estructura constituida por tercera capa (Ib) de poliéster o de policarbonato PC, sobre cuyas caras se adhiere respectivamente con adhesivo genérico o con adhesivo de base poliuretano (2plu) , una tercera capa opaca (lal) de derivado modificado de PET-G.(lg) selectively constituted by at least one of the following elements: vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile. Integrated in the middle of the Core Core Assembly (C), as shown in Figure 19 structure consisting of third layer (Ib) of polyester or PC polycarbonate, on whose faces it is adhered respectively with generic adhesive or with base adhesive polyurethane (2plu), a third opaque layer (lal) of modified derivative of PET-G.
También cabe señalar que la invención prevé la disposición de una estructura de la cubierta posterior del documento tal como se muestra en la Figura 18, que está constituida por una décima capa (Ib) de poliéster previa descarga de efecto corona, sobre la que se deposita la capa (2plu) de adhesivo genérico para plásticos preferentemente de base poliuretano a la que se adhiere la capa (lal) de derivado modificado de PET-G selectivamente con aditivo de carbón micronizado y respectivamente con aditivo de óxido de titanio de forma que en la cara interior de la décima capa (Ib) de poliéster se han realizado opcionalmente impresiones previas de seguridad de logos, figuras, escudos, con tintas UV y con tintas OVI (optical variable ink) . La cara (5i) de la tercera capa (lal) de derivado de PET-G es la que se termolamina directamente a la respectiva estructura del núcleo del documento o tarjeta de identidad.It should also be noted that the invention provides for the provision of a structure of the back cover of the document as shown in Figure 18, which is constituted by a tenth layer (Ib) of polyester prior to corona discharge, on which it is deposited the layer (2plu) of generic adhesive for plastics preferably of polyurethane base to which the layer (lal) of PET-G modified derivative adheres selectively with micronized carbon additive and respectively with additive of Titanium oxide so that on the inside of the tenth layer (Ib) of polyester, prior security prints of logos, figures, shields, with UV inks and OVI (optical variable ink) inks have been optionally made. The face (5i) of the third layer (lal) of PET-G derivative is that which is thermolaminated directly to the respective core structure of the document or identity card.
Combinando las estructuras de las cubiertas holográficas con las respectivas estructuras del núcleo de documento y con su correspondiente cubierta posterior, que son objeto de la realización preferida, se obtienen estructuras específicas de documentos y tarjetas de identidad así como para su utilización en pasaportes y visados, en las que es posible utilizar una sola modalidad como así mismo una combinación específica de modalidades de personalización del documento.By combining the structures of the holographic covers with the respective structures of the document core and with their corresponding back cover, which are the object of the preferred embodiment, specific structures of documents and identity cards are obtained as well as for use in passports and visas, in which it is possible to use a single modality as well as a specific combination of modalities of personalization of the document.
Así, a modo de ejemplo, se obtienen las configuraciones de estructuras de documentos: La Figura 20.- representa a modo de ejemplo una de las posibles estructuras preferentes de documentos de identidad que resultan de conjuntar las estructuras de los elementos constitutivos objeto de la presente invención, con personalización combinada sobre la superficie del núcleo tanto de impresión color D2T2 de termosublimación de la imagen fantasma, como de personalización por grabado de rayo láser en ambas caras de los datos personales y de la imagen facial del titular sobre la zona específica de superficie limitada. La estructura está dotada de láminas de compensación de tensiones de poliéster ( o de PC) integradas a ambos lados del núcleo del documento.Thus, by way of example, the configurations of document structures are obtained: Figure 20.- represents by way of example one of the possible preferred structures of identity documents that result from combining the structures of the constituent elements object of the present invention, with combined customization on the surface of the core both of D2T2 color printing of thermal image sublimation of the phantom, and of personalization by laser beam engraving on both sides of the personal data and of the facial image of the holder on the specific surface area limited The structure is equipped with polyester (or PC) tension compensation sheets integrated on both sides of the document core.
Para hacer posible la aplicación de estructuras lenticulares CLI (Changing Láser Image) personalizadas por grabado con rayo láser destructivo preformadas y grabadas en la superficie exterior de las cubiertas del documento, se prevé que a los elementos constitutivos de al menos una de las capas: primera capa (la) de poliéster de la lámina protectora, capa fina (2al) tanto constituida por laca polimerizable por la acción de la luz UV o por la acción de radiación electrónica como capa de imprimación (2al) y selectivamente a la segunda capa (2a2) de los derivados acrílicos del respectivo laminado holográfico tanto de tipo HRI transparente como de tipo metalizado se le agrega en su masa un aditivo genérico para grabado por rayo láser y selectivamente aditivo de carbón micronizado con inhibidor supresor de llama, para realizar el grabado personalizado de estructuras en superficie por rayo láser destructivo (burning) .To make the application of custom CLI (Changing Laser Image) lenticular structures possible by engraving with destructive laser beam preformed and engraved on the outer surface of the document covers, it is envisaged that to the constituent elements of at least one of the layers: first layer (the) polyester of the protective sheet, thin layer (2al) both constituted by polymerizable lacquer by the action of UV light or by the action of electronic radiation as a primer layer (2al) and selectively to the second layer (2a2) of the acrylic derivatives of the respective holographic laminate of both transparent and metallic type HRI type is added in its mass a generic additive for laser engraving and selectively micronized carbon additive with flame suppressor inhibitor, to perform the personalized engraving of structures on surfaces by destructive laser beam (burning).
Así mismo la realización preferida de la invención prevé de forma explícita que las estructuras holográficas y los correspondientes procedimientos de depósito limitado por zonas y líneas de producto holográfico Szn, TiOx, SiOx, ZrOx, preferentemente Al, Bi o Ag por vaporización en vacío, objeto de la presente invención son aplicables directamente sobre la primera capa (la) (figuras 1 y 2) , constituido por poliéster orientado o por plástico durables (durable plastics) de forma que tales substratos son grabados en caliente con elevada presión (hard embossing) con las respectivas hendiduras correspondientes a las líneas de las figuras y logos holográficos que se desean producir. Esta tecnología tiene una aplicación muy inmediata y extensa en la producción de envases y empaquetados, así como etiquetas holográficas para protección holográfica de envases de alta seguridad para medicamentos, para artículos multimedia y de consumo específicos etc.. Likewise, the preferred embodiment of the invention explicitly provides that the holographic structures and the corresponding deposition procedures limited by zones and lines of holographic product Szn, TiOx, SiOx, ZrOx, preferably Al, Bi or Ag by vacuum vaporization, object of the present invention are directly applicable on the first layer (the) (figures 1 and 2), consisting of oriented polyester or durable plastics, so that such substrates are hot embossed with high pressure (hard embossing) with the respective slits corresponding to the lines of the holographic figures and logos that are to be produced. This technology has a very immediate and extensive application in the production of packaging and packaging, as well as holographic labels for holographic protection of high-security containers for medicines, for specific multimedia and consumer items etc.

Claims

REIVINDICACIONES 1.- PROCEDIMIENTO DE OBTENCIÓN DE UNA ESTRUCTURA PLÁSTICA INTEGRAL, que comprende la obtención de una estructura holográfica, seleccionada entre un laminado HRI transparente (high reflective index), un laminado holográfico metalizado y combinación de los mismos, que incluye un depósito de un producto holográfico (7) que forma una capa holográfica (2h) ; se caracteriza porque el depósito de producto holográfico está seleccionado entre SZn, TiOx, SiOx, ZrOx, Al, Bi, Ag; y combinación de los mismos, y porque dicho depósito de producto holográfico está limitado únicamente a zonas y líneas específicas aplicadas sobre una superficie seleccionada entre: CLAIMS 1.- PROCEDURE FOR OBTAINING AN INTEGRAL PLASTIC STRUCTURE, which includes obtaining a holographic structure, selected from a transparent HRI laminate (high reflective index), a metallic holographic laminate and combination thereof, which includes a deposit of a holographic product (7) that forms a holographic layer (2h); It is characterized in that the holographic product tank is selected from SZn, TiOx, SiOx, ZrOx, Al, Bi, Ag; and combination thereof, and because said holographic product deposit is limited only to specific areas and lines applied on a surface selected from:
- una superficie de una capa (la) seleccionada entre plástico durable (durable plástic) , policarbonato (PC) , y poliéster orientado; y- a surface of a layer (la) selected from durable plastic (durable plastic), polycarbonate (PC), and oriented polyester; Y
- una superficie (2'a2) de una segunda capa (2a2) , seleccionada entre derivado acrílico, plástico gradable (shim embossable plástic) y laca que polimeriza y endurece por la acción seleccionada entre luz ultravioleta (UV) , radiación electrónica y aire.- a surface (2'a2) of a second layer (2a2), selected from acrylic derivative, gradable plastic (plastic embossable shim) and lacquer that polymerizes and hardens by the action selected between ultraviolet (UV) light, electronic radiation and air.
2.- PROCEDIMIENTO DE OBTENCIÓN DE UNA ESTRUCTURA PLÁSTICA INTEGRAL, según reivindicación 1, se caracteriza porque la laca está constituida por al menos uno de los siguientes elementos: epoxi-acrilato, poliéster- acrilato, poliéter-acrilato, metano-acrilato, silicon- acrilato, uretano-acrilato, epoxi-silicona, y sus versiones diluibles y emulsionables en agua; y estando la segunda capa (2a2) de plástico grabable (shim embossable plástic) constituida por al menos uno de los siguientes productos: derivado acrílico, derivado de acetato, derivado poliolefínico, derivado de polipropileno, derivado epoxi, derivado de poliuretano, derivado de polietileno- tereftalato. 2. PROCEDURE FOR OBTAINING AN INTEGRAL PLASTIC STRUCTURE, according to claim 1, characterized in that the lacquer is constituted by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon. acrylate, urethane acrylate, epoxy silicone, and its water-dilutable and emulsifiable versions; and the second layer (2a2) being of recordable plastic (plastic embossable shim) consisting of at least one of the following products: acrylic derivative, acetate derivative, polyolefin derivative, polypropylene derivative, epoxy derivative, polyurethane derivative, polyethylene derivative - terephthalate.
3.- PROCEDIMIENTO DE OBTENCIÓN DE UNA ESTRUCTURA3.- PROCEDURE FOR OBTAINING A STRUCTURE
PLÁSTICA INTEGRAL, según reivindicación 1, caracterizado porque el depósito de la capa holográfica (2h) sobre la superficie (2'a2) de la segunda capa (2a2) de una estructura holográfica, se realiza mediante proceso PVDINTEGRAL PLASTICS, according to claim 1, characterized in that the deposition of the holographic layer (2h) on the surface (2'a2) of the second layer (2a2) of a holographic structure, is carried out by PVD process
(physical vapor deposition) de depósito holográfico en continuo sobre bobina (8a), que comprende: grabar(physical vapor deposition) of continuous holographic deposit on coil (8a), comprising: record
(embossing) en caliente, con útil metálico de grabado (shims) , hendiduras que constituyen las figuras y logos holográficos (3) sobre la superficie (2'a2) de la segunda capa (2a2) en bobina (8a) ; seguidamente realizar una impresión en continuo de unas zonas (17) alrededor de las líneas que forman las figuras y logos (3) , con un producto seleccionado entre emulsión de cera de silicona, aceite de silicona, cera vegetal, y cera-parafina de carnauba, cubriendo todas aquellas zonas restantes de la superficie (2'a2) de la segunda capa (2a2) de la bobina (8a) sobre las que no se han grabado (embossing) las figuras y logos sobre la superficie (2'a2) de la segunda capa (2a2), y dejando suficiente espacio sin cubrir a ambos lados de las líneas de grabado (embossing) de las figuras y logos (3) ; realizándose a continuación un depósito PVD por vaporización seleccionado entre vaporización en vacío, y vaporización a presión atmosférica en proceso convencional continuo de obtención de una capa holográfica continua (2h) ; seguidamente se efectúa la eliminación y limpieza de las zonas (17) que fueron cubiertas con la impresión en continuo, mediante una operación seleccionada entre paso de la estructura holográfica a través de una cámara de vacío con plasma de oxígeno en proceso continuo, y mediante la aplicación de un disolvente de derivado de silicona para desprender el derivado de silicona y en su caso la cera- parafina de carnauba, junto con el depósito de producto holográfico que residualmente haya quedado sobre ella; conteniendo la superficie holográfica (2'h) de la bobina (8b) únicamente depósito de producto holográfico (7) sobre las correspondientes líneas grabadas (embossing) de las figuras logos (3) .(hot embossing), with metal engraving tool (shims), indentations that constitute the holographic figures and logos (3) on the surface (2'a2) of the second layer (2a2) in coil (8a); then make a continuous impression of areas (17) around the lines that form the figures and logos (3), with a product selected from silicone wax emulsion, silicone oil, vegetable wax, and carnauba wax-paraffin , covering all remaining areas of the surface (2'a2) of the second layer (2a2) of the coil (8a) on which the figures and logos on the surface (2'a2) of the surface (2'a2) of the second layer (2a2), and leaving enough uncovered space on both sides of the embossing lines of the figures and logos (3); a PVD tank is then carried out by vaporization selected from vacuum vaporization, and atmospheric pressure vaporization in a continuous conventional process of obtaining a continuous holographic layer (2h); then the elimination and cleaning of the areas (17) that were covered with continuous printing is carried out, by an operation selected between the passage of the holographic structure through a vacuum chamber with oxygen plasma in continuous process, and by means of the application of a silicone derivative solvent to release the silicone derivative and, if necessary, carnauba ceraparaffin, together with the holographic product deposit that has been left on it; containing the holographic surface (2'h) of the coil (8b) only deposit of holographic product (7) on the corresponding embossing lines of the logos figures (3).
4. -PROCEDIMIENTO DE OBTENCIÓN DE UNA ESTRUCTURA PLÁSTICA INTEGRAL, según reivindicación 1, caracterizado porque el depósito de producto holográfico seleccionado entre vaporización en vacío y vaporización a presión atmosférica, se realiza sobre pliegos (8pe) en la superficie (2'a2) de la segunda capa (2a2) del laminado holográfico; para lo que el laminado holográfico se corta en pliegos (8pe) , cada uno de los cuales es grabado4.-PROCESS FOR OBTAINING AN INTEGRAL PLASTIC STRUCTURE, according to claim 1, characterized in that the deposit of holographic product selected between vacuum vaporization and atmospheric pressure vaporization, is performed on sheets (8pe) on the surface (2'a2) of the second layer (2a2) of the holographic laminate; for which the holographic laminate is cut into sheets (8pe), each of which is engraved
(embossing) en caliente mediante útil metálico de grabado(hot embossing) by metal engraving tool
(shims) de hendiduras que constituyen las figuras y logos holográficos (3); a continuación se imprime, con un productos seleccionado entre derivado de silicona, cera vegetal, y cera-parafina de carnauba, sobre todas las áreas de la superficie (2'a2) de la segunda capa (2a2) a ambos lados de las líneas y zonas donde han sido grabadas(shims) of indentations that constitute the holographic figures and logos (3); It is then printed, with a product selected from silicone derivative, vegetable wax, and carnauba wax-paraffin, on all surface areas (2'a2) of the second layer (2a2) on both sides of the lines and areas where they have been recorded
(embossing) en caliente las hendiduras de las líneas de las figuras y logos; a continuación los pliegos son introducidos en un apilador-alimentador (12stf) que mediante unos juegos de rodillos (12'r) transporta individualmente cada pliego, a través de una compuerta de ranura (llce) y sostenido por unas guías laterales dotadas de ruedas de arrastre, a una cámara (10) de vaporización PVD seleccionada entre vaporización en vacío, y vaporización a presión atmosférica, del producto holográfico (7) , en la que es vaporizado por un proceso seleccionado entre calentamiento, efecto magnetrón (sputtering), rayo iónico, rayo de electrones, y arco; para producir el depósito de la capa holográfica (2h) sobre la superficie (2'a2) de la segunda capa (2a2) cubriendo solo las zonas que previamente han sido grabadas (embossing) y que están libres de impresión de derivado de silicona y en su caso de cera-parafina de carnauba; seguidamente los pliegos (8ps) ya provistos de depósito holográfico son transportados por las respectivas ruedas de arrastre de las guías laterales y por los rodillos (12'r) a un apilador de salida (12sto) ; siendo los rodillos (12'r) accionados sincronizadamente por un motor de pasos (13eng) que es controlado por un procesador mediante unas marcas impresas de paso y posicionamiento previstas en cada pliego (8pe) a su paso por unos sensores optoelectrónicos (lis) ; a continuación los pliegos (8ps) ya provistos de depósito holográfico son limpiados en una cámara de vacío con plasma de oxígeno 02 donde se desprende el derivado de silicona, y en su caso la cera-parafina de carnauba de las respectivas zonas impresas .(hot embossing) the indentations of the lines of the figures and logos; then the sheets are introduced in a stacker-feeder (12stf) that by means of roller sets (12'r) individually transports each sheet, through a slot gate (llce) and supported by lateral guides provided with wheels of drag, to a PVD vaporization chamber (10) selected between vacuum vaporization, and atmospheric pressure vaporization, of the holographic product (7), in which it is vaporized by a process selected from heating, magnetron effect (sputtering), ionic ray , electron beam, and arc; to produce the deposit of the holographic layer (2h) on the surface (2'a2) of the second layer (2a2) covering only the areas that have previously been recorded (embossing) and that are free of silicone derivative printing and in his case of carnauba wax-paraffin; then the sheets (8ps) already provided with holographic deposit are transported by the respective drive wheels of the lateral guides and by the rollers (12'r) to an output stacker (12sto); the rollers (12'r) being synchronously driven by a stepper motor (13eng) which is controlled by a processor by means of printed step and positioning marks provided in each sheet (8pe) as it passes through optoelectronic sensors (lis); then the sheets (8ps) already provided with holographic deposit are cleaned in a vacuum chamber with oxygen plasma 0 2 where the silicone derivative is released, and where appropriate the carnauba wax-paraffin from the respective printed areas.
5. -PROCEDIMIENTO DE OBTENCIÓN DE UNA ESTRUCTURA PLÁSTICA INTEGRAL, según reivindicaciones 1 y 2, caracterizado porque el depósito holográfico (2h) sobre la superficie (2'a2) de la segunda capa (2a2) de una estructura holográfica, se realiza mediante proceso PVD (physical vapor deposition) de depósito holográfico en continuo sobre bobina (8a) que comprende : grabar5.-PROCESS FOR OBTAINING AN INTEGRAL PLASTIC STRUCTURE, according to claims 1 and 2, characterized in that the holographic deposit (2h) on the surface (2'a2) of the second layer (2a2) of a holographic structure, is carried out by process PVD (physical vapor deposition) of continuous holographic deposit on coil (8a) comprising: record
(embossing) en caliente con útil metálico de grabadohot embossing with metal engraving tool
(shims) hendiduras que constituyen las figuras y logos holográficos (3) sobre la superficie (2'a2) de la segunda capa (2a2) en bobina (8a); seguidamente, mediante una cámara (10) de depósito por vaporización seleccionada entre vaporización en vacío, y vaporización a presión atmosférica, se realiza la vaporización, mediante un proceso seleccionado entre calentamiento, efecto magnetrón(shims) indentations that constitute the holographic figures and logos (3) on the surface (2'a2) of the second layer (2a2) in coil (8a); then, by means of a vaporization chamber (10) selected between vacuum vaporization, and atmospheric pressure vaporization, the vaporization is carried out, by a process selected between heating, magnetron effect
(sputtering) , rayo iónico, rayo de electrones, y arco, de al menos un producto de depósito holográfico (7) ; realizándose el depósito del producto holográfico vaporizado a través de unas perforaciones (16) de una banda sin fin (12cp) seleccionada entre una banda plástica y una banda metálica que gira continuamente arrastrada por unos rodillos (12r) y en contacto permanente con la superficie (2'a2) de la segunda capa (2a2) de la bobina (8a) que fluye a través de unas compuertas de ranura (llcp) ; correspondiendo coincidentemente el posicionamiento de las perforaciones repetitivas (16) de la banda sin fin, con las respectivas zonas sobre las que se han posicionado las hendiduras de las líneas de las figuras y logos (3) en la bobina (8a) ; siendo las citadas perforaciones (16) más amplias y anchas que las correspondientes a las líneas de las figuras y logos (3) , para permitir ampliamente el paso a través de las perforaciones del depósito holográfico vaporizado y cubrir las correspondientes zonas en la superficie (2'a2) de la segunda capa (2a2) que contienen las líneas y áreas de los grabados (embossing) respectivos; y constantemente se arrastra la banda (12cp) sincronizadamente con la bobina (8a) a su paso por la cámara (10) de depósito, y mediante unos sensores optoelectrónicos (12) se detectan unas marcas preimpresas sobre dicha bobina (8a) y sobre la banda (12cp) , que tienen el mismo ancho que la bobina (8a) , la cual es accionada por un motor (13) gobernado por un procesador que ajusta el posicionamiento coincidente de la banda (12cp) y de la bobina (8a) ,- presionándose el laminado de la bobina (8a) contra la banda (12cp) durante el paso de ambas por la cámara (10) de depósito PVD mediante un sistema de presión constituido selectivamente por una placa (13sp) y por un sistema de banda con rodillos de arrastre; seguidamente se rebobina en continuo en una segunda bobina (8b) .(sputtering), ionic beam, electron beam, and arc, of at least one holographic deposit product (7); the vaporized holographic product deposit being made through perforations (16) of an endless band (12cp) selected between a plastic band and a metal band that rotates continuously dragged by rollers (12r) and in permanent contact with the surface (2'a2) of the second layer (2a2) of the coil (8a) flowing through groove gates (llcp); the positioning of the repetitive perforations (16) of the endless band correspondingly corresponds, with the respective areas on which the grooves of the lines of the figures and logos (3) in the coil (8a) have been positioned; the aforementioned perforations (16) being wider and wider than those corresponding to the lines of the figures and logos (3), to allow the passage through the perforations of the vaporized holographic deposit and cover the corresponding areas on the surface (2) 'a2) of the second layer (2a2) containing the lines and areas of the respective embossing; and the band (12cp) is constantly dragged synchronously with the coil (8a) as it passes through the reservoir chamber (10), and by means of optoelectronic sensors (12) preprinted marks are detected on said coil (8a) and on the band (12cp), which have the same width as the coil (8a), which is driven by a motor (13) governed by a processor that adjusts the matching positioning of the band (12cp) and the coil (8a), - the roll of the coil (8a) being pressed against the band (12cp) during the passage of both through the PVD deposit chamber (10) by means of a pressure system selectively constituted by a plate (13sp) and by a belt system with drag rollers; then it is continuously rewound in a second coil (8b).
6. -PROCEDIMIENTO DE OBTENCIÓN DE UNA ESTRUCTURA PLÁSTICA INTEGRAL, según reivindicaciones 1,2 ó 4, caracterizado porque el laminado holográfico se obtiene mediante una primera capa (la) como soporte (carrier) sobre cuya superficie se realiza una descarga de efecto corona y a continuación se deposita una capa fina de imprimación (2al) seleccionada entre cera vegetal y cera-parafina de carnauba, y a continuación sobre la superficie de dicha capa fina de imprimación (2al) se deposita una segunda capa6.-PROCESS FOR OBTAINING AN INTEGRAL PLASTIC STRUCTURE, according to claims 1,2 or 4, characterized in that the holographic laminate is obtained by means of a first layer (the) as a support (carrier) on whose surface a corona effect discharge is already made a thin layer of primer (2al) selected between vegetable wax and carnauba wax-paraffin is then deposited, and then on the surface of said thin layer of primer (2al) a second layer is deposited
(2a2) seleccionada entre laca, y compuesto acrílico; sobre cuya superficie (2'a2) se realiza un grabado (embossing) de las figuras y logos, de modo que a continuación en proceso continuo PVD en cámara de vaporización seleccionada entre vaporización en vacío, y vaporización a presión atmosférica, se produce el depósito de la capa holográfica(2a2) selected from lacquer, and acrylic compound; on whose surface (2'a2) an embossing of the figures and logos is made, so that in a continuous process PVD in a vaporization chamber selected between vacuum vaporization and atmospheric pressure vaporization, the deposit is produced of the holographic layer
(2h) y a continuación se deposita sobre la superficie (2'h) de dicha capa holográfica (2h) un adhesivo de base poliuretano (2plu) , que adhiere una tercera capa (lal) , seleccionada entre derivado modificado PET-G, poliéster, polietileno, polipropileno, y termoadhesivo compuesto por un producto seleccionado entre:(2h) and then a polyurethane base adhesive (2plu) is deposited on the surface (2'h) of said holographic layer (2h), which adheres a third layer (lal), selected from PET-G modified derivative, polyester, polyethylene, polypropylene, and thermoadhesive consisting of a product selected from:
- ácido etileno-acrílico y derivados de poliuretano, - y al menos dos de los elementos siguientes: gelatina, derivados acrílicos, ácidos acrílicos, poliamida y derivados de poliuretano; bobinándose a continuación el laminado holográfico así obtenido en una tercera bobina (Ir) que mediante una estación de calentamiento (3p) se somete en proceso continuo para separar la primera capa de poliéster (la) , la cual se rebobina en una cuarta bobina (l'r); previa limpieza en plasma 02 y en proceso continuo posterior se deposita sobre una superficie (2 'al) de la segunda capa (2a2) , cuando dicha segunda capa (2a2) sea de naturaleza acrílica, una capa de protección constituida preferentemente por laca.- ethylene-acrylic acid and polyurethane derivatives, - and at least two of the following elements: gelatin, acrylic derivatives, acrylic acids, polyamide and polyurethane derivatives; then winding the holographic laminate thus obtained in a third coil (Ir) which, by means of a heating station (3p), is subjected in a continuous process to separate the first layer of polyester (la), which is rewound into a fourth coil (l 'r); after cleaning in plasma 0 2 and in subsequent continuous process, it is deposited on a surface (2 'al) of the second layer (2a2), when said second layer (2a2) is of an acrylic nature, a protective layer preferably constituted by lacquer.
7. -PROCEDIMIENTO DE OBTENCIÓN DE ESTRUCTURA PLÁSTICA INTEGRAL, según reivindicaciones 1-6, caracterizado porque como etapa previa de cada uno de los procesos de depósito de las diferentes capas, de depósito de adhesivo, depósito de producto holográfico, impresión con laca, impresión con derivado de silicona, y aceite, se aplica tratamiento previo de activación de la correspondiente superficie selectivamente con plasma en vacío de oxígeno 02, plasma en vacío de hidrógeno H2, con el correspondiente plasma del producto de depósito, y con plasma atmosférico.7.-INTEGRAL PLASTIC STRUCTURE OBTAINING PROCEDURE, according to claims 1-6, characterized in that as a previous stage of each of the processes of deposit of the different layers, of adhesive deposit, holographic product deposit, lacquer printing, printing with silicone derivative, and oil, pretreatment of activation of the corresponding surface is applied selectively with plasma in vacuum of oxygen 0 2 , plasma in vacuum of hydrogen H 2 , with the corresponding plasma of the deposit product, and with atmospheric plasma.
8.- PROCEDIMIENTO DE OBTENCIÓN DE UNA ESTRUCTURA PLÁSTICA INTEGRAL, según las reivindicaciones anteriores caracterizado porque el deposito metálico seleccionado entre Al, Ag, y Bi por vaporización seleccionada entre vaporización en vacío, y vaporización a presión atmosférica, que constituye la capa holográfica (2h) , se desmetaliza gradualmente por áreas de la superficie (2'h) de la capa holográfica (2h) para disminuir la densidad del depósito metálico respectivo y hacer más transparente una zona específica de la superficie holográfica (2'h) de la capa holográfica (2h) sobre la que se imprime sucesivamente el corrosivo respectivo del Al, de la Ag y en su caso del Bi y se lava subsiguientemente cubriendo por zonas las figuras y logos selectivamente de Al , Ag y Bi .8. PROCEDURE FOR OBTAINING AN INTEGRAL PLASTIC STRUCTURE, according to the preceding claims, characterized in that the metal deposit selected from Al, Ag, and Bi by vaporization selected from vacuum vaporization, and atmospheric pressure vaporization, which constitutes the holographic layer (2h ), it is gradually demetallized by areas of the surface (2'h) of the holographic layer (2h) to decrease the density of the respective metal deposit and make a specific area of the holographic surface (2'h) of the holographic layer more transparent (2h) on which the respective corrosive of Al, of Ag and, if applicable, of Bi is successively printed and subsequently washed covering areas and logos selectively of Al, Ag and Bi.
9.- PROCEDIMIENTO DE OBTENCIÓN DE UNA ESTRUCTURA PLÁSTICA INTEGRAL, según reivindicaciones 1 y 2, caracterizado porque el depósito de la capa holográfica9.- PROCEDURE FOR OBTAINING AN INTEGRAL PLASTIC STRUCTURE, according to claims 1 and 2, characterized in that the deposit of the holographic layer
(2h) selectivamente realizado sobre la superficie de la primera capa (la) y sobre la superficie (2'a2) de la segunda capa (2a2) de una estructura holográfica, se realiza mediante proceso PVD (physical vapor deposition) de depósito holográfico en continuo sobre una bobina (8a) , que comprende: realizar una impresión en continuo de unas zonas (17) alrededor de las líneas que forman las figuras y logos (3) , con un producto seleccionado entre emulsión de cera de silicona, aceite de silicona, cera vegetal, y cera- parafina de carnauba, cubriendo todas aquellas zonas restantes de la superficie (2'a2) de la segunda capa (2a2) de la bobina (8a) sobre las que posteriormente no se van a grabar (embossing) las figuras y logos sobre la segunda capa (2a2), y dejando suficiente espacio sin cubrir a ambos lados de las líneas de grabado (embossing) de las figuras y logos que posteriormente serán grabados (embossing) ; realizándose a continuación un depósito PVD por vaporización seleccionado entre vaporización en vacío, y vaporización a presión atmosférica, en proceso convencional continuo de obtención de una capa holográfica continua (2h) ; seguidamente se efectúa la eliminación y limpieza de las zonas que fueron cubiertas con la impresión en continuo (17), selectivamente mediante:(2h) selectively performed on the surface of the first layer (la) and on the surface (2'a2) of the second layer (2a2) of a holographic structure, it is carried out by PVD (physical vapor deposition) process of holographic deposit in continuous on a coil (8a), comprising: making a continuous printing of areas (17) around the lines that form the figures and logos (3), with a product selected from silicone wax emulsion, silicone oil , vegetable wax, and carnauba wax-paraffin, covering all those remaining areas of the surface (2'a2) of the second layer (2a2) of the coil (8a) on which the embossing will not be recorded later. figures and logos on the second layer (2a2), and leaving enough uncovered space on both sides of the embossing lines of the figures and logos that will later be recorded (embossing); a PVD tank is then carried out by vaporization selected from vacuum vaporization, and atmospheric pressure vaporization, in a continuous conventional process of obtaining a continuous holographic layer (2h); then the removal and cleaning of the areas that were covered with continuous printing (17), selectively by means of:
- paso de la estructura holográfica a través de una cámara de vacío con plasma de oxígeno en proceso continuo, y la aplicación de un disolvente del derivado de silicona para desprender el derivado de silicona y en su caso desprender la cera-parafina de carnauba, junto con el depósito de producto holográfico que residualmente haya quedado sobre ella; conteniendo la superficie holográfica (2'h) de la segunda bobina (8b) únicamente depósito de producto holográfico- passage of the holographic structure through a vacuum chamber with oxygen plasma in continuous process, and the application of a solvent of the silicone derivative to release the silicone derivative and, where appropriate, release the carnauba wax-paraffin, together with the deposit of holographic product that has been left on it; containing the holographic surface (2'h) of the second coil (8b) only holographic product deposit
(7) sobre las correspondientes líneas grabadas (embossing) de las figuras logos (3) ; seguidamente se procede a grabar(7) on the corresponding embossing lines of the logos figures (3); then proceed to record
(embossing) en caliente, con útil metálico de grabado(embossing) hot, with metal engraving tool
(shims) , las hendiduras que constituyen las figuras y logos holográficos (3) selectivamente sobre la superficie(shims), the recesses that constitute the holographic figures and logos (3) selectively on the surface
(2'a2) de la capa (2a2) y en su caso sobre la superficie de la primera capa (la) en bobina (8a) , previamente cubiertas con depósito de producto holográfico (7) .(2'a2) of the layer (2a2) and, where appropriate, on the surface of the first layer (la) in coil (8a), previously covered with a holographic product tank (7).
10.- PROCEDIMIENTO DE OBTENCIÓN DE UNA10.- PROCEDURE FOR OBTAINING A
ESTRUCTURA PLÁSTICA INTEGRAL, según reivindicaciones 1 y 2, caracterizado porque el depósito de la capa holográfica (2h) realizado sobre la superficie seleccionada entre la superficie de la primera capa (la) , y sobre la superficieINTEGRAL PLASTIC STRUCTURE, according to claims 1 and 2, characterized in that the deposit of the holographic layer (2h) made on the selected surface between the surface of the first layer (la), and on the surface
(2'a2) de la segunda capa (2a2) de una estructura holográfica, se realiza mediante proceso PVD (physical vapor deposition) de depósito holográfico en continuo sobre una bobina (8a) que comprende: mediante una cámara (10) de depósito por vaporización seleccionado entre vaporización en vacío y vaporización a presión atmosférica, se realiza la vaporización, por un proceso seleccionado entre calentamiento efecto magnetrón (sputtering) , rayo iónico, rayo de electrones, y arco, de al menos un producto de depósito holográfico (7) ; realizándose el depósito del producto holográfico vaporizado través de unas perforaciones (16) de una banda sin fin (12cp) seleccionada entre una banda metálica y una banda plástica que rota continuamente arrastrada por unos rodillos (12r) y en contacto permanente con la superficie (2'a2) de la segunda capa (2a2) de la bobina (8a) que fluye a través de unas compuertas de ranura (llcp) ; correspondiendo coincidentemente el posicionamiento de las perforaciones repetitivas (16) de la banda sin fin, con las respectivas zonas sobre las que se han posicionado las hendiduras de las líneas de las figuras y logos (3) en la bobina (8a); siendo las citadas perforaciones (16) más amplias y anchas que las correspondientes a las líneas de las figuras y logos (3) , para permitir ampliamente el paso a través de las perforaciones del depósito holográfico vaporizado y cubrir las correspondientes zonas en la superficie (2'a2) de la segunda capa (2a2) que contienen las líneas y áreas de los grabados (embossing) respectivos; y constantemente se arrastra la banda (12cp) sincronizadamente con la bobina (8a) a su paso por la cámara (10) de depósito, y mediante unos sensores optoelectrónicos (12) se detectan unas marcas preimpresas sobre dicha bobina (8a) y sobre la banda (12cp) , que tienen el mismo ancho que la bobina (8a) , que es accionada por un motor (13) gobernado por un procesador que ajusta el posicionamiento coincidente de la banda (12cp) y de la bobina (8a) ; presionándose el laminado de la bobina (8a) contra la banda (12cp) durante el paso de ambas por la cámara (10) de depósito PVD mediante un sistema de presión constituido selectivamente por una placa (13sp) por un sistema de banda con rodillos de arrastre; seguidamente se graban (embossing) en caliente con útil metálico de grabado (shims) las correspondientes hendiduras que constituyen las figuras y logos holográficos (3) sobre una superficie seleccionada entre una superficie (2'a2) de la segunda capa (2a2) y una superficie de la primera capa (la) en bobina (8a) , previamente cubiertas con depósito de producto holográfico (7) ; seguidamente se rebobina en continuo en una segunda bobina (8b) . (2'a2) of the second layer (2a2) of a holographic structure, it is carried out by means of PVD (physical vapor deposition) process of continuous holographic deposit on a coil (8a) comprising: by means of a chamber (10) of vaporization tank selected between vacuum vaporization and atmospheric pressure vaporization, vaporization is performed, by a process selected between magnetron (sputtering) heating, ionic beam, electron beam, and arc, of at least one product holographic deposit (7); the deposit of the vaporized holographic product being made through perforations (16) of an endless band (12cp) selected between a metal band and a plastic band that rotates continuously dragged by rollers (12r) and in permanent contact with the surface (2 'a2) of the second layer (2a2) of the coil (8a) flowing through groove gates (llcp); the positioning of the repetitive perforations (16) of the endless band correspondingly corresponds, with the respective areas on which the grooves of the lines of the figures and logos (3) in the coil (8a) have been positioned; the aforementioned perforations (16) being wider and wider than those corresponding to the lines of the figures and logos (3), to allow the passage through the perforations of the vaporized holographic deposit and cover the corresponding areas on the surface (2) 'a2) of the second layer (2a2) containing the lines and areas of the respective embossing; and the band (12cp) is constantly dragged synchronously with the coil (8a) as it passes through the reservoir chamber (10), and by means of optoelectronic sensors (12) preprinted marks are detected on said coil (8a) and on the band (12cp), which have the same width as the coil (8a), which is driven by a motor (13) governed by a processor that adjusts the matching positioning of the band (12cp) and the coil (8a); the laminate of the coil (8a) being pressed against the band (12cp) during the passage of both through the PVD deposit chamber (10) by means of a selectively constituted pressure system by a plate (13sp) by a belt system with drag rollers; then the corresponding indentations that constitute the holographic figures and logos (3) on a surface selected between a surface (2'a2) of the second layer (2a2) and an engraving (hot embossing) are etched with hot metal engraving tool (shims). surface of the first layer (la) in coil (8a), previously covered with holographic product tank (7); then it is continuously rewound in a second coil (8b).
11.- PROCEDIMIENTO DE OBTENCIÓN DE UNA11.- PROCEDURE FOR OBTAINING A
ESTRUCTURA PLÁSTICA INTEGRAL, según reivindicaciones 1-10, caracterizado porque se aplica en la obtención de documentos, tarjetas de identidad y de crédito, pasaportes, visados y billetes de banco. INTEGRAL PLASTIC STRUCTURE, according to claims 1-10, characterized in that it is applied in obtaining documents, identity and credit cards, passports, visas and banknotes.
12.- PROCEDIMIENTO DE OBTENCIÓN DE UNA12.- PROCEDURE FOR OBTAINING A
ESTRUCTURA PLÁSTICA INTEGRAL, según la reivindicaciones 1,2, 3 y 5-10, caracterizado porque el depósito limitado por zonas y líneas de producto holográfico, se aplica directamente sobre una primera capa (la) seleccionada entre un envase, una superficie de empaquetado, y una etiqueta de envase .INTEGRAL PLASTIC STRUCTURE, according to claims 1,2, 3 and 5-10, characterized in that the deposit limited by zones and lines of holographic product, is applied directly on a first layer (la) selected between a container, a packaging surface, and a container label.
13.- ESTRUCTURA PLÁSTICA INTEGRAL, que comprende una estructura holográfica, seleccionada entre una estructura holográfica simple y una estructura holográfica combinada que comprenden un laminado seleccionado entre un laminado HRI transparente (high reflective index) , un laminado holográfico metalizado y combinación de los mismos, que incluye un depósito de un producto holográfico13.- INTEGRAL PLASTIC STRUCTURE, which comprises a holographic structure, selected between a simple holographic structure and a combined holographic structure comprising a laminate selected from a transparent HRI laminate (high reflective index), a metallic holographic laminate and combination thereof, which includes a deposit of a holographic product
(7) que forma una capa holográfica (2h) ; se caracteriza porque la capa holográfica (2h) está compuesta por producto holográfico seleccionado entre SZn, TiOx, SiOx, ZrOx, Al, Bi, Ag y combinación de los mismos cuyo depósito está limitado únicamente a zonas y líneas específicas sobre una superficie (2'a2) de una segunda capa (2a2) , constituida por un producto seleccionado entre derivado acrílico, laca plástico gradable y combinación de los mismos; que a su vez está sobre una superficie de una primera capa soporte (la) seleccionada entre plástico durable (durable plástic) , policarbonato (PC) y poliéster orientado. (7) forming a holographic layer (2h); It is characterized in that the holographic layer (2h) is composed of holographic product selected from SZn, TiOx, SiOx, ZrOx, Al, Bi, Ag and a combination thereof whose deposit is limited only to specific areas and lines on a surface (2 ' a2) of a second layer (2a2), consisting of a product selected from acrylic derivative, lacquer gradable plastic and combination thereof; which in turn is on a surface of a first support layer (la) selected from durable plastic (durable plastic), polycarbonate (PC) and oriented polyester.
14. -ESTRUCTURA PLÁSTICA INTEGRAL, según reivindicación 13, caracterizada porque el laminado holográfico está constituido por una primera capa (la) como soporte (carrier) sobre cuya superficie tras una descarga de efecto corona comprende una capa fina (2al) de imprimación para plásticos, seleccionada entre al menos uno de los siguientes elementos: compuesto vinílico, PVDC14. - INTEGRAL PLASTIC STRUCTURE, according to claim 13, characterized in that the holographic laminate is constituted by a first layer (the) as a support (carrier) on whose surface after a corona discharge comprises a thin layer (2al) of primer for plastics , selected from at least one of the following elements: vinyl compound, PVDC
(cloruro de polivinildieno) , acrilonitrilo, derivado de poliuretano, y laca; de tal forma que sobre dicha capa fina(polyvinyldiene chloride), acrylonitrile, polyurethane derivative, and lacquer; such that on said thin layer
(2al) se deposita a su vez una segunda capa (2a2) de compuesto acrílico.(2al) a second layer (2a2) of acrylic compound is deposited.
15.- ESTRUCTURA PLÁSTICA INTEGRAL, según reivindicaciones 13 y 14 caracterizada porque el laminado holográfico está constituido por una primera capa (la) como soporte (carrier) sobre cuya superficie y tras realizarse una descarga de efecto corona, comprende selectivamente una impresión de líneas gruesas de las figuras y logos (3) de laca grabable para constituir la segunda capa (2a2) impresa; y selectivamente se deposita directamente una segunda capa continua (2a2) de laca; incluyéndose sobre la superficie (2'a2) de dicha segunda capa el depósito del producto de la capa holográfica (2h) .15.- INTEGRAL PLASTIC STRUCTURE, according to claims 13 and 14, characterized in that the holographic laminate is constituted by a first layer (the) as a support (carrier) on whose surface and after a corona effect discharge is carried out, it selectively comprises a printing of thick lines of the engravable lacquer figures and logos (3) to constitute the second printed layer (2a2); and selectively a second continuous layer (2a2) of lacquer is directly deposited; the product deposit of the holographic layer (2h) being included on the surface (2'a2) of said second layer.
16.- ESTRUCTURA PLÁSTICA INTEGRAL, según las reivindicaciones 13,14 y 15 que comprende una estructura holográfica combinada, constituida por un depósito de una primera capa holográfica (2hι) tipo HRI transparente (high reflective index) sobre zonas específicas de un substrato grabable (shims embossable plástic) constituido por una segunda capa (2a2) ; y por un depósito de una segunda capa16.- INTEGRAL PLASTIC STRUCTURE, according to claims 13,14 and 15 comprising a combined holographic structure, consisting of a deposit of a first holographic layer (2hι) type transparent HRI (high reflective index) on specific areas of a recordable substrate ( plastic embossable shims) consisting of a second layer (2a2); and for a second layer deposit
(2h2) holográfica metalizado sobre otras zonas concretas de la misma segunda capa (2a2) que constituye un substrato grabable; se caracteriza porque está constituida por una primera capa soporte (la) seleccionada entre poliéster orientado y plástico durable (durable plástic) , prevista en una configuración seleccionada entre una bobina y pliegos, sobre cuya superficie, selectivamente previa descarga de efecto corona y selectivamente por tratamiento previo de plasma 02, comprende selectivamente un deposito y selectivamente una impresión seleccionada entre cera de silicona, cera vegetal y cera/parafina de carnauba que forma una fina capa (2al) ; sobre la que se incluye selectivamente una impresión y selectivamente un depósito, selectivamente previa descarga de efecto corona y selectivamente previo tratamiento de plasma O2, seleccionado entre plástico grabable y laca grabable que endurece por la acción seleccionada entre luz UV, radiación electrónica, y acción del aire para formar así la segunda capa (2a2) ; a continuación en la superficie (2'a2) de la segunda capa (2a2) comprende un grabado (embossing) realizado mediante útil de presión (shims) de las respectivas hendiduras correspondientes a las líneas y zonas del diseño de las figuras holográficas (3) y seguidamente comprende, selectivamente previa descarga de efecto corona y selectivamente previo tratamiento de plasma O2, un depósito de una primera capa holográfica (2hl) de producto holográfico transparente HRI , aplicado mediante un procedimiento PVD (physical vapor deposition) de depósito por seleccionado entre vaporización en vacío y vaporización a presión atmosférica; estando la primera capa holográfica (2hl) constituida por al menos uno de los productos holográficos SZn, TiOx, SiOx, ZrOx; a continuación selectivamente previa descarga de efecto corona y selectivamente por tratamiento previo de plasma O2, comprende una segunda capa holográfica (2h2)de depósito de producto holográfico metálico aplicado mediante un procedimiento PVD (physical vapor deposition) de depósito seleccionado entre vaporización en vacío y vaporización a presión atmosférica; estando la segunda capa holográfica(2h2) metallic holographic on other specific areas of the same second layer (2a2) that constitutes a substrate recordable; it is characterized in that it is constituted by a first support layer (la) selected between oriented polyester and durable plastic (durable plastic), provided in a configuration selected between a coil and sheets, on whose surface, selectively prior discharge of corona effect and selectively by treatment prior to plasma 02, it selectively comprises a deposit and selectively a print selected from silicone wax, vegetable wax and carnauba wax / paraffin that forms a thin layer (2al); on which a print is selectively included and selectively a reservoir, selectively prior corona discharge and selectively prior O2 plasma treatment, selected from recordable plastic and recordable lacquer that hardens by the action selected between UV light, electronic radiation, and action of the air to form the second layer (2a2); then on the surface (2'a2) of the second layer (2a2) it comprises an engraving (embossing) made by pressing tool (shims) of the respective slits corresponding to the lines and areas of the design of the holographic figures (3) and then comprises, selectively prior corona discharge and selectively prior O2 plasma treatment, a deposit of a first holographic layer (2hl) of HRI transparent holographic product, applied by means of a PVD (physical vapor deposition) deposition method by selected between vaporization in vacuum and vaporization at atmospheric pressure; the first holographic layer (2hl) being constituted by at least one of the holographic products SZn, TiOx, SiOx, ZrOx; then selectively prior corona discharge and selectively by pretreatment of O2 plasma, it comprises a second holographic layer (2h2) of deposit of metallic holographic product applied by means of a PVD (physical vapor deposition) deposition method selected between vacuum vaporization and atmospheric pressure vaporization; the second holographic layer being
(2h2) constituida por un producto holográfico metálico constituido por al menos uno de los productos Al, Bi, y Ag; estando así constituida sobre la superficie (2'a2) de la segunda capa (2a2), el depósito holográfico zonal combinado(2h2) consisting of a metal holographic product consisting of at least one of the products Al, Bi, and Ag; being thus constituted on the surface (2'a2) of the second layer (2a2), the combined holographic zone deposit
(2hl) y (2h2) ; comprendiendo además; selectivamente previa descarga de efecto corona y selectivamente previo tratamiento plasma 02,- una capa zonal (2a4) de encapsulamiento de laca que corresponde a las zonas de la superficie de la primera capa holográfica (2hl) ; seguidamente comprende una gradual desmetalización del depósito de producto holográfico metálico; y a continuación comprende una zona de encapsulamiento de laca, en la superficie de la segunda capa holográfica (2h2) , formando así la capa zonal (2a4) sobre la que a está selectivamente adherida y selectivamente depositada una quinta capa (2a5) que según el tipo de aplicación del laminado holográfico combinado está selectivamente formada por: - depósito de derivado poliolefínico PE,(2hl) and (2h2); further comprising; selectively prior discharge of corona effect and selectively prior plasma treatment 02, - a zonal layer (2a4) of lacquer encapsulation corresponding to the surface areas of the first holographic layer (2hl); then it includes a gradual demetalization of the deposit of metallic holographic product; and then comprises a lacquer encapsulation zone, on the surface of the second holographic layer (2h2), thus forming the zonal layer (2a4) on which a fifth layer (2a5) is selectively adhered to and selectively deposited which according to the type of application of the combined holographic laminate is selectively formed by: - PE polyolefin derivative deposit,
- depósito depolipropileno,- depolipropylene tank,
- depósito de ácido etileno-acrílico con adición de derivado de poliuretano, y selctivamente por termoadhesivo para papel moneda, para pasaporte, y visados,- deposit of ethylene-acrylic acid with the addition of polyurethane derivative, and then by thermal adhesive for paper money, passport, and visas,
- depósito de derivado de polivinilo con adición de PVDC (cloruro de polivinildieno) para personalización con impresión de termosublimación D2T2,- polyvinyl derivative tank with addition of PVDC (polyvinylchloride chloride) for customization with D2T2 thermosublimation printing,
- una capa de termoadhesivo de base poliuretano que a su vez adhiere una capa de derivado modificado de- a layer of polyurethane based thermoadhesive which in turn adheres a modified derivative layer of
PET-G (polietileno-tereftalato-glicol ; y comprendiendo la segunda capa holográfica (2h2)de depósito de producto holográfico metálico con una personalización mediante grabado con rayo láser (holographic embossing) con la réplica de la imagen facial del titular de un documento seleccionado entre un documento de identidad y un pasaporte en que el laminado holográfico combinado ha sido termolaminado.PET-G (polyethylene-terephthalate-glycol; and comprising the second holographic layer (2h2) of deposit of metal holographic product with a personalization by laser engraving (holographic embossing) with the replica of the facial image of the holder of a document selected between an identity document and a passport in which the combined holographic laminate has been thermolaminated.
17. -ESTRUCTURA PLÁSTICA INTEGRAL, según las reivindicaciones 13-16 se caracteriza porque comprende una primera capa soporte (la) seleccionada entre poliéster orientado y plástico durable (durable plástic) , prevista en una configuración seleccionada entre una bobina y pliegos, sobre cuya superficie, selectivamente previa descarga de efecto corona y selectivamente previo tratamiento de plasma 02, comprende una impresión seleccionada entre cera de silicona, cera vegetal, cera/parafina de carnauba que forma únicamente una fina capa (2al) que constituyen unas líneas y zonas (2al) que coinciden con las líneas y zonas correspondientes a las figuras, escudos y logos holográficos (3); sobre cuya capa fina (2al) comprende una impresión seleccionada entre plástico grabable, y laca grabable, selectivamente previa descarga de efecto corona y selectivamente previo tratamiento de plasma 02, comprende una segunda capa (2a2) que cubre las líneas y zonas de la fina capa (2al) con laca grabable endurecida; a continuación comprende un grabado (embossing) mediante hendiduras coincidentes con las mencionadas líneas y zonas de la fina capa (2al) sobre la superficie (2'a2) de la segunda capa (2a2) y selectivamente, previa descarga de efecto corona y selectivamente previo tratamiento de plasma O2, comprende un depósito de producto holográfico con procedimiento PVD (physical vapor deposition) de depósito por vaporización seleccionado entre vaporización en vacío y vaporización a presión atmosférica, estando depositado dicho producto holográfico únicamente sobre las mencionadas líneas y zonas de la fina capa (2al) y sobre la superficie (2'a2) constituyendo así las figuras y logos holográficos; selectivamente previa descarga de efecto corona y selectivamente previo tratamiento de plasma 02, comprende una impresión con termoadhesivo, seleccionado entre ácido etileno-acrílico con adición de derivado mono o bicomponente de poliuretano y termoadhesivo para papel, cubriendo únicamente las citadas líneas y zonas de depósito holográfico; habiéndose previsto que selectivamente la bobina y selectivamente los pliegos de la primera capa soporte (la) , comprendan marcas de registro, previamente impresas, para permitir la exactitud en las sucesivas impresiones que cubren las líneas y zonas de las hendiduras grabadas sobre la segunda capa (2a2) ; el laminado holográfico así constituido selectivamente, previa descarga de efecto corona y selectivamente previo tratamiento de plasma 02, es superpuesto y termolaminado, selectivamente en bobina en continuo y selectivamente en pliegos, para fundir la cera de silicona, y en su caso la cera/parafina de carnauba y así desprender la primera capa soporte (carrier) (la) de poliéster por el calor aplicado, para fuertemente adherir a un papel de cada billete de banco una protección formada por el holograma trasparente HRI y en su caso el holograma metálico, que ha sido selectivamente desmetalizado por zonas; que comprende los logos y figuras holográficos17.-INTEGRAL PLASTIC STRUCTURE, according to claims 13-16 is characterized in that it comprises a first support layer (la) selected between oriented polyester and durable plastic (durable plastic), provided in a configuration selected between a coil and sheets, on whose surface , selectively prior discharge of corona effect and selectively prior plasma treatment 02, comprises an impression selected from silicone wax, vegetable wax, carnauba wax / paraffin that forms only a thin layer (2al) that constitutes lines and zones (2al) which coincide with the lines and zones corresponding to the holographic figures, shields and logos (3); on whose thin layer (2al) comprises a print selected between engravable plastic, and engravable lacquer, selectively prior corona discharge and selectively prior plasma treatment 02, comprises a second layer (2a2) covering the lines and areas of the thin layer (2al) with hardened recordable lacquer; then it comprises an embossing by means of grooves coinciding with the aforementioned lines and zones of the thin layer (2al) on the surface (2'a2) of the second layer (2a2) and selectively, prior to corona discharge and selectively prior O2 plasma treatment, comprises a holographic product tank with PVD (physical vapor deposition) method of vaporization tank selected between vacuum vaporization and atmospheric pressure vaporization, said holographic product being deposited only on said lines and areas of the thin layer (2al) and on the surface (2'a2) thus constituting holographic figures and logos; selectively prior corona discharge and selectively prior plasma treatment 02, comprises a printing with thermoadhesive, selected from ethylene-acrylic acid with the addition of mono or bicomponent derivative of polyurethane and thermoadhesive for paper, covering only the aforementioned holographic deposit lines and zones; having provided that the coil selectively and selectively the sheets of the first support layer (la), comprise registration marks, previously printed, to allow accuracy in the successive impressions covering the lines and areas of the grooves engraved on the second layer ( 2a2); The holographic laminate thus constituted selectively, prior to corona discharge and selectively after plasma treatment 02, is superimposed and thermolaminated, selectively in continuous coil and selectively in sheets, to melt the silicone wax, and if necessary the wax / paraffin of carnauba and thus detach the first support layer (carrier) of the polyester by the heat applied, to strongly adhere to a paper of each banknote a protection formed by the HRI transparent hologram and in its case the metallic hologram, which it has been selectively demetallized by zones; which includes the logos and holographic figures
18. -ESTRUCTURA PLÁSTICA INTEGRAL, según reivindicaciones 16 y 17 que comprende una estructura de documento o tarjeta de identidad constituida por una lámina transparente (Lpc) de policarbonato que se superpone por termolaminación a ambas caras de un núcleo (C) de un documento integralmente de policarbonato; habiéndose previsto que previa y selectivamente sobre el núcleo (C) y previa y selectivamente sobre la lámina transparente (Lpc) , comprende selectivamente adherido y selectivamente termolaminado, un holograma zonal combinado constituido por una primera capa (2hl) holográfica HRI transparente y una segunda capa holográfica metálica (2h2) cuya zona metálica (Hmz) comprende una personalización mediante grabado por rayo láser destructivo (burning) , se caracteriza porque el núcleo (C) comprende una primera lámina (Csl) de policarbonato, en la que sobre una parte concreta de su superficie (C'sl) comprende adherida la estructura holográfica combinada que comprende el holograma metálico zonal (Hmz) el cual comprende una personalización mediante grabado láser destructivo (burning) realizado selectivamente antes y selectivamente después de la termolaminación del núcleo (C) con las cubiertas de láminas (Lpc) de policarbonato transparente; incluyendo el grabado láser de personalización una grabación de datos personales y la réplica de la imagen facial del titular del documento de identidad; estando el holograma zonal producido por un procedimiento PVD de vaporización de depósito respectivo de producto holográfico HRI transparente y de producto holográfico metálico y cuya estructura, comprende una segunda capa (2a2) sobre la cual comprende un depósito de la segunda capa de holográfica metálica zonal (2h2) y de la primera capa holográfica transparente (2hl) , sobre la que a su vez comprende selectivamente depositada y selectivamente adherida una capa seleccionada entre una capa zonal (2a4) de encapsulamiento que comprende un producto seleccionado entre derivado acrílico y laca que a su vez contiene una cuarta capa (3bl) de termoadhesivo seleccionado entre termoadhesivo de base de poliuretano y termoadhesivo de base de polímero poliolefínico; y dicha cuarta capa (3bl) .18.-INTEGRAL PLASTIC STRUCTURE, according to claims 16 and 17 comprising a document structure or identity card consisting of a transparent sheet (Lpc) of polycarbonate that is superimposed by thermolamination on both sides of a core (C) of a document integrally of polycarbonate; it being provided that previously and selectively on the core (C) and before and selectively on the transparent sheet (Lpc), it comprises selectively adhered and selectively thermolaminated, a combined zonal hologram consisting of a transparent holographic first layer (2hl) and a second layer holographic metal (2h2) whose metallic zone (Hmz) comprises a personalization by means of engraving by destructive laser beam (burning), is characterized in that the core (C) comprises a first sheet (Csl) of polycarbonate, in which the combined holographic structure comprising the zonal metal hologram (Hmz) which comprises a personalization by means of a particular hologram comprises adhered destructive laser engraving (burning) performed selectively before and selectively after thermolamination of the core (C) with transparent polycarbonate sheet covers (Lpc); including the personalization laser engraving a recording of personal data and the replica of the facial image of the holder of the identity document; the zone hologram being produced by a PVD method of vaporization of the respective deposit of transparent HRI holographic product and metal holographic product and whose structure comprises a second layer (2a2) on which it comprises a reservoir of the second zone zonal metal holographic layer ( 2h2) and of the first transparent holographic layer (2hl), on which in turn it comprises selectively deposited and selectively adhered a layer selected between a zonal layer (2a4) of encapsulation comprising a product selected between acrylic derivative and lacquer which at its It also contains a fourth layer (3bl) of thermo-adhesive selected from polyurethane-based thermo-adhesive and polyolefin polymer-based thermo-adhesive; and said fourth layer (3bl).
19. ESTRUCTURA PLÁSTICA INTEGRAL, según reivindicaciones 13-16 que se caracteriza porque la estructura holográfica comprende una primera capa soporte (la) seleccionada entre poliéster orientado y plástico durable (durable plástic) , prevista en una configuración seleccionada entre una bobina y pliegos, sobre cuya superficie, selectivamente previa descarga de efecto corona y selectivamente previo tratamiento de plasma 02, comprende un depósito de una capa fina (2al) seleccionada entre cera de silicona, cera vegetal, y cera/parafina de carnauba, sobre cuya superficie, selectivamente previa descarga de efecto corona y selectivamente tratamiento previo de plasma O2, comprende un depósito de una capa (2a3) constituida selectivamente por al menos uno de los siguientes productos: derivado de acetato, derivado poliolefínico, derivado de polipropileno, derivado acrílico, derivado de silicona, derivado epoxi, derivado de poliuretano, derivado de polietileno-tereftalato, y laca, y selectivamente previa descarga de efecto corona y selectivamente previo tratamiento de plasma 02, comprende un depósito de una segunda capa (2a2) de derivado acrílico sobre cuya superficie (2'a2) comprende un grabado (embossing) de las respectivas hendiduras de las líneas y zonas correspondientes a las figuras y logos (3) ; selectivamente previa descarga de efecto corona, y selectivamente previo tratamiento de plasma O2, comprende un depósito de producto holográfico realizado selectivamente mediante procedimiento PVD (physical vapor deposition) de depósito que cubre solo líneas y zonas específicas de la superficie (2'a2) de la segunda capa (2a2) de producto holográfico y selectivamente mediante procedimiento PVD (physical vapor deposition) de depósito convencional que cubre toda la superficie (2'a2) de la segunda capa (2a2) de producto holográfico, constituyendo así la capa holográfica (2h) que contiene las figuras y logos holográficos (3) ; selectivamente previa descarga de efecto corona y selectivamente previo tratamiento de plasma 02, comprede un encapsulamiento de la superficie (2'h) de la capa holográfica (2h) con una capa zonal (2a4) que en función del tipo de aplicación del laminado holográfico así constituido está formada selectivamente por uno de los siguientes compuestos:19. INTEGRAL PLASTIC STRUCTURE, according to claims 13-16, characterized in that the holographic structure comprises a first support layer (la) selected between oriented polyester and durable plastic, provided in a configuration selected between a coil and sheets, on whose surface, selectively prior corona discharge and selectively prior plasma treatment 02, comprises a deposit of a thin layer (2al) selected from silicone wax, vegetable wax, and carnauba wax / paraffin, on whose surface, selectively prior corona discharge and selectively pretreatment of O2 plasma, comprises a deposit of a layer (2a3) selectively constituted by at least one of the following products: acetate derivative, polyolefin derivative, polypropylene derivative, derivative acrylic, silicone derivative, epoxy derivative, polyurethane derivative, polyethylene terephthalate derivative, and lacquer, and selectively prior corona discharge and selectively prior plasma treatment 02, comprises a deposit of a second layer (2a2) of acrylic derivative on whose surface (2'a2) it comprises an engraving (embossing) of the respective indentations of the lines and zones corresponding to the figures and logos (3); selectively prior corona discharge, and selectively prior plasma O2 treatment, comprises a holographic product reservoir selectively made by means of a PVD (physical vapor deposition) deposition method that covers only specific surface lines and areas (2'a2) of the second layer (2a2) of holographic product and selectively by conventional PVD procedure (physical vapor deposition) covering the entire surface (2'a2) of the second layer (2a2) of holographic product, thus constituting the holographic layer (2h) which contains holographic figures and logos (3); selectively prior corona discharge and selectively prior plasma treatment 02, comprises encapsulation of the surface (2'h) of the holographic layer (2h) with a zonal layer (2a4) that depending on the type of application of the holographic laminate thus constituted is selectively formed by one of the following compounds:
- por laca que endurece por la acción seleccionada entre luz UV, radiación de la radiación electrónica, y aire, por depósito seleccionado entre derivado poliolefínico PE o polipropileno, termoadhesivo seleccionado entre termoadhesivo para papel y termoadhesivo por ácido etileno- acrílico con adición de derivado de poliuretano, para su aplicación en papel moneda, pasaportes y visados y documentos, y para impresión de personalización de termosublimación D2T2,- by lacquer that hardens by the action selected between UV light, electronic radiation radiation, and air, by deposit selected from polyolefin derivative PE or polypropylene, thermo-adhesive selected from thermo-adhesive for paper and thermo-adhesive by ethylene-acrylic acid with addition of polyurethane derivative, for application in paper money, passports and visas and documents, and for customizing printing of thermosublimation D2T2,
- por derivado de polivinilo con adición de PVDC (cloruro de polivinildieno) para impresión de personalización de termosublimación D2T2,- by polyvinyl derivative with addition of PVDC (polyvinylchloride chloride) for D2T2 thermosublimation customization printing,
- por una capa de termoadhesivo de base poliuretano que a su vez adhiere una capa de derivado modificado de PET-G (polietileno-tereftalato- glicol) .- by a layer of polyurethane based thermoadhesive which in turn adheres a modified derivative layer of PET-G (polyethylene terephthalate glycol).
20.- ESTRUCTURA PLÁSTICA INTEGRAL, según las reivindicaciones 16 y 18, se caracteriza porque el depósito holográfico de la primera capa (2hl) y de la segunda capa (2h2) se realiza sobre una segunda capa compuesta por substratos grabables (2a2) distintos que constituyen hologramas separados que se integran en un misma tarjeta de identidad.20.- INTEGRAL PLASTIC STRUCTURE, according to claims 16 and 18, is characterized in that the holographic deposit of the first layer (2hl) and the second layer (2h2) is made on a second layer composed of different recordable substrates (2a2) that they constitute separate holograms that are integrated into the same identity card.
21.- ESTRUCTURA PLÁSTICA INTEGRAL, según las reivindicaciones 13 a 20, caracterizado porque las líneas y zonas de depósito holográfico de la capa holográfica (2h) sobre la superficie holográfica (2'h) y las zonas de la superficie (2'a2) de la segunda capa (2a2) no cubiertas por dicho depósito holográfico están encapsuladas; comprendiendo dicho encapsulado, previa descarga de efecto corona, una capa seleccionada entre:21. INTEGRAL PLASTIC STRUCTURE, according to claims 13 to 20, characterized in that the holographic deposit lines and zones of the holographic layer (2h) on the holographic surface (2'h) and the surface areas (2'a2) of the second layer (2a2) not covered by said holographic deposit are encapsulated; said encapsulation comprising, after corona discharge, a layer selected from:
- una capa de laca que polimeriza y endurece por un proceso seleccionado entre luz UV, radiación electrónica, y aire; una capa de adhesivo (2plu) para plásticos preferentemente bicomponente de base poliuretano sobre la que adhiere una tercera capa (lal) , seleccionada entre derivado modificado PET-G (taraftalato polietileno-glicol) , derivado modificado PET-G con aditivo de carbón micronizado, y aditivo de óxido de titanio con inhibidor supresor de llama;- a lacquer layer that polymerizes and hardens by a process selected from UV light, electronic radiation, and air; a layer of adhesive (2plu) for plastics preferably bi-component based on polyurethane on the one that adheres a third layer (lal), selected from modified PET-G derivative (polyethylene glycol taraphthalate), modified PET-G derivative with micronized carbon additive, and titanium oxide additive with flame suppressor inhibitor;
- una sexta capa (la2) constituida selectivamente por un compuesto adherente de capa-base (tie-layer) junto con derivado modificado PET-G (taraftalato polietileno-glicol) , por un derivado modificado PET-G con aditivo de carbón micronizado con un producto seleccionado entre un inhibidor supresor de llama, y un aditivo de óxido de titanio; que se deposita en caliente por coextrusión;- a sixth layer (la2) selectively constituted by an adherent layer-base compound (tie-layer) together with modified PET-G derivative (polyethylene glycol taraphthalate), by a modified PET-G derivative with micronized carbon additive with a product selected from a flame suppressor inhibitor, and a titanium oxide additive; which is hot deposited by coextrusion;
- una séptima capa (lg) constituida selectivamente por al menos uno de los siguientes elementos: derivado vinílico, PVDC (cloruro de polivinildieno) , acrilonitrilo, y derivado de poliuretano; que se deposita selectivamente mediante inyección en caliente, impresión off-set, impresión serigráfica, y extrusión; - una octava capa (lf) de termoadhesivo compuesta selectivamente por ácido etileno-acrílico y selectivamente por al menos dos de los elementos siguientes: gelatina, derivados acrílicos, ácidos acrílicos, poliamida y derivados de poliuretano, que se deposita selectivamente mediante inyección en caliente, impresión off-set, impresión serigráfica, y extrusión, para termolaminar la octava capa (lf) con un papel de una hoja de datos seleccionado entre un pasaporte, visado y documento; - una tercera capa (lal) adherida de derivado modificado PET-G que tiene integrado un chip de radiofrecuencia (5c) con antena plana (5ant) , y sobre dicha tercera capa (lal) comprende un depósito depositado selectivamente, mediante inyección en caliente, impresión off-set, impresión serigráfica, y extrusión, comprendiendo además una octava capa (lf) de termoadhesivo que comprende un producto seleccionado entre ácido etileno-acrílico con derivados de poliuretano, y al menos dos de los elementos siguientes: gelatina, derivados acrílicos, ácidos acrílicos, poliamida y derivados de poliuretano, para que la octava capa (lf) así constituida termolamine con un papel de una hoja seleccionada entre una hoja de datos de pasaporte y de documento; - una novena capa (le) de termoadhesivo de polímero poliolefínico compuesta selectivamente por polietileno, polietileno modificado, y por polipropileno, que se deposita mediante un proceso seleccionado entre inyección en caliente, y extrusión. - a seventh layer (lg) selectively constituted by at least one of the following elements: vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile, and polyurethane derivative; which is selectively deposited by hot injection, off-set printing, screen printing, and extrusion; - an eighth layer (lf) of thermo-adhesive selectively composed of ethylene-acrylic acid and selectively at least two of the following elements: gelatin, acrylic derivatives, acrylic acids, polyamide and polyurethane derivatives, which is selectively deposited by hot injection, off-set printing, screen printing, and extrusion, for thermolaminating the eighth layer (lf) with a paper from a data sheet selected from a passport, visa and document; - a third layer (lal) attached of modified PET-G derivative which has integrated a radio frequency chip (5c) with flat antenna (5ant), and on said third layer (lal) comprises a deposit deposited selectively, by hot injection, off-set printing, screen printing, and extrusion, further comprising an eighth layer (lf) of thermoadhesive comprising a product selected from ethylene-acrylic acid with polyurethane derivatives, and at least two of the following elements: gelatin, acrylic derivatives, acrylic acids, polyamide and polyurethane derivatives, so that the eighth layer (lf) thus constituted thermolamine with a paper of a sheet selected between a passport and document data sheet; - a ninth layer (le) of polyolefin polymer thermo-adhesive selectively composed of polyethylene, modified polyethylene, and polypropylene, which is deposited by a process selected from hot injection and extrusion.
22.- ESTRUCTURA PLÁSTICA INTEGRAL, según las reivindicaciones, 13 a 21 , caracterizada porque comprende un conjunto central con n capas (Cl, C2,..Cn) de PET-G modificado que forman parte de un núcleo (C) , que selectivamente en una de sus capas incluye un chip integrado (5c) de radiofrecuencia con antena (5ant) , y sobre al menos una de sus caras (3e,3'e) que comprende una tercera capa (lal) , seleccionada entre una capa termolaminada y una capa extrusionada que a su vez está seleccionada entre derivado modificado PET-G con aditivo genérico para grabado por rayo láser destructivo, y carbón micronizado con supresor inhibidor de llama; comprendiendo por depósito en las caras (4e,4'e) de la primera capa (la) y en toda su superficie, previa descarga de efecto corona, selectivamente mediante extrusión, inyección en caliente, impresión serigráfica, impresión corrosiva, y selectivamente por termodepósito (hot stamping) , una séptima capa (lg) constituida por al menos uno de los elementos siguientes: derivado vinílico, PVDC22.- INTEGRAL PLASTIC STRUCTURE, according to claims 13 to 21, characterized in that it comprises a central set with n layers (Cl, C2, .. Cn) of modified PET-G that are part of a core (C), which selectively in one of its layers it includes an integrated radio frequency chip (5c) with antenna (5ant), and on at least one of its faces (3e, 3'e) comprising a third layer (lal), selected from a thermo-laminated layer and an extruded layer which in turn is selected from modified PET-G derivative with generic additive for destructive laser beam etching, and micronized carbon with flame inhibitor suppressor; comprising by deposit on the faces (4e, 4'e) of the first layer (la) and on its entire surface, after corona discharge, selectively by extrusion, hot injection, screen printing, corrosive printing, and selectively by thermo tank (hot stamping), a seventh layer (lg) consisting of at least one of the following elements: vinyl derivative, PVDC
(cloruro de polivinildieno) y acrilonitrilo; comprendiendo la superficie de la séptima capa (lg) una impresión de una personalización de los datos personales e imagen facial mediante impresión color D2T2 de termosublimación.(polyvinyldiene chloride) and acrylonitrile; comprising the surface of the seventh layer (lg) an impression of a personalization of personal data and facial image through D2T2 color printing of thermosublimation.
23.- ESTRUCTURA PLÁSTICA INTEGRAL, según las reivindicaciones 13 a 22, caracterizada porque comprende un núcleo (C) formado por un conjunto central con n capas (Cl, C2,..Cn) de PET-G modificado, que selectivamente una de sus capas integra un chip (5c) de radiofrecuencia con antena (5ant) , y que sobre al menos una de sus caras (3e,3'e) comprende una tercera capa (lal) seleccionada entre una capa termolaminada y una capa extrusionada que a su vez está seleccionada entre derivado modificado PET-G con aditivo genérico para grabado por rayo láser destructivo, y carbón micronizado con supresor inhibidor de llama, sobre cuyas caras (4e,4'e) comprende un depóstio previa descarga de efecto corona, selectivamente mediante extrusión, inyección en caliente, impresión serigráfica, impresión corrosiva, y termodepósito (hot stamping) ; de una capa con una superficie limitada y concreta (4z) constituida selectivamente por: - al menos uno de los elementos siguientes: derivado vinílico, PVDC (cloruro de polivinildieno) , acrilonitrilo, en cuya superficie limitada (4z) del núcleo, comprende una impresión de la imagen facial y datos personales mediante impresión color D2T2 de termosublimación; - un compuesto convencional que absorbe las tintas de impresión por inyección y que selectivamente contiene gelatina, para la personalización con impresora color de inyección de tinta;23.- INTEGRAL PLASTIC STRUCTURE, according to claims 13 to 22, characterized in that it comprises a core (C) formed by a central assembly with n layers (Cl, C2, .. Cn) of modified PET-G, which selectively one of its layers integrates a radiofrequency chip (5c) with antenna (5ant), and that on at least one of its faces (3e, 3'e) comprises a third layer (lal) selected between a thermolaminated layer and an extruded layer that at its It is also selected from a modified PET-G derivative with a generic additive for destructive laser beam etching, and micronized carbon with a flame inhibitor suppressant, on whose faces (4e, 4'e) it comprises a prior deposition, corona discharge, selectively by extrusion , hot injection, screen printing, corrosive printing, and hot stamping; of a layer with a limited and concrete surface (4z) selectively constituted by: - at least one of the following elements: vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile, on whose limited surface (4z) of the core, comprises an impression of facial image and personal data by means of D2T2 color printing of thermosublimation; - a conventional compound that absorbs inkjet printing inks and selectively contains gelatin, for personalization with a color inkjet printer;
- al menos uno de los elementos siguientes: gelatina pura, de derivados acrílicos, derivados polímeros de liami- da, y combinación de ellos, cuya superficie (4z) comprende una personalización con la imagen facial y datos personales mediante sistema fotográfico de Transferencia por Difusión Inversa por el que selectivamente el negativo portador de la imagen seleccionada entre una imagen color y una imagen en escala de grises, se superpone sobre la superficie concreta (4z) y aplicando ligera presión y en presencia de un revelador fotográfico, es transferida dicha personalización. - at least one of the following elements: pure gelatin, of acrylic derivatives, polymeric derivatives of liamida, and combination thereof, whose surface (4z) comprises personalization with facial image and personal data by means of a photographic system of Diffusion Transfer Reverse by which selectively the negative carrier of the selected image between a color image and an image in grayscale, it is superimposed on the concrete surface (4z) and applying light pressure and in the presence of a photographic developer, said customization is transferred.
24.- ESTRUCTURA PLÁSTICA INTEGRAL, según las reivindicaciones 13 a 23, caracterizada porque al menos una de las caras (3e,3e') del Conjunto Central del núcleo (C) comprende una personalización realizada selectivamente con rayo láser destructivo (burning) y con impresión de termosublimación color y al menos una de dichas caras (3e,3e') de dicho núcleo (C) comprende una termolaminación con el laminado holográfico (2h) al que se le ha agregado sobre su superficie (2'h) selectivamente una configuración de capas seleccionada entre: - una capa de laca constituida por laca que polimeriza y endurece por la acción seleccionada entre luz ultravioleta (UV) , radiación electrónica, y aire; una capa de adhesivo (2plu) para plásticos bicomponente de base poliuretano sobre la que adhiere una tercera capa (lal) , seleccionada entre derivado modificado PET-G (taraftalato polietileno-glicol) , derivado modificado PET-G con aditivo de carbón micronizado con inhibidor supresor de llama, y un aditivo de óxido de titanio;24.- INTEGRAL PLASTIC STRUCTURE, according to claims 13 to 23, characterized in that at least one of the faces (3e, 3e ') of the Central Assembly of the core (C) comprises a customization made selectively with destructive laser beam (burning) and with color thermo-sublimation printing and at least one of said faces (3e, 3e ') of said core (C) comprises a thermolamination with the holographic laminate (2h) to which a configuration has been selectively added on its surface (2'h) of layers selected from: - a lacquer layer consisting of lacquer that polymerizes and hardens by the action selected from ultraviolet (UV) light, electronic radiation, and air; a layer of adhesive (2plu) for two-component polyurethane-based plastics onto which a third layer (lal) adheres, selected from a modified derivative PET-G (polyethylene glycol taraphthalate), a modified PET-G derivative with a micronized carbon additive with inhibitor flame suppressor, and a titanium oxide additive;
- una sexta capa coextrusionada (la2) con un compuesto seleccionado entre un adherente de capa-base (tie-layer) junto con derivado modificado PET-G (taraftalato polietileno-glicol) , un derivado modificado PET-G con aditivo de carbón micronizado con inhibidor supresor de llama, y un aditivo de óxido de titanio; - una séptima capa (lg) constituida selectivamente por al menos uno de los siguientes elementos: derivado vinílico, PVDC (cloruro de polivinildieno) , acrilonitrilo, y derivado de poliuretano;- a sixth coextruded layer (la2) with a compound selected from a base-layer adherent (tie-layer) together with modified PET-G derivative (polyethylene glycol taraphthalate), a modified PET-G derivative with micronized carbon additive with flame suppressor inhibitor, and a titanium oxide additive; - a seventh layer (lg) selectively constituted by at least one of the following elements: vinyl derivative, PVDC (polyvinyldiene chloride), acrylonitrile, and polyurethane derivative;
- una tercera capa (lal) de derivado modificado PET-G que tiene integrado un chip de radiofrecuencia (5c) con antena plana (5ant) , y una novena capa (le) de termoadhesivo de polímero poliolefínico; para que la capa holográfica sea quemada y dañada irreversiblemente cuando se intentan modificar y retocar, mediante grabado con rayo láser a través de la capa holográfica (2h) , los rasgos de la imagen facial y los datos personales originalmente grabados directamente con rayo láser sobre el núcleo.- a third layer (lal) of modified PET-G derivative that has integrated a radio frequency chip (5c) with flat antenna (5ant), and a ninth layer (le) of polyolefin polymer thermoadhesive; so that the holographic layer is burned and irreversibly damaged when trying to modify and retouch, by means of laser engraving through the holographic layer (2h), the facial image features and personal data originally recorded directly with laser beam on the core.
25.- ESTRUCTURA PLÁSTICA INTEGRAL, según reivindicaciones 13 a 24, caracterizada porque comprende una estructura simétrica de capas seleccionadas entre capas termolaminadas sobre ambas caras (3e,3'e), del conjunto central (Cl,C2,..Cn) del núcleo (C) y capas integradas en medio del conjunto central de dicho núcleo (C) ; estando constituidas dichas capas termolaminadas por una décima capa (Ib) seleccionada entre poliéster y policarbonato, sobre cuyas caras se adhieren mediante adhesivo (2plu) , de base poliuretano, sendas terceras capas (lal) de derivado modificado de PET-G selectivamente con aditivo para grabado láser, con carbón micronizado, y selectivamente con aditivo de carbón micronizado, y sobre las caras exteriores de las terceras capas (lal) comprende un depósito de una séptima capa (lg) constituida selectivamente por al menos uno de los elementos siguientes: derivado vinílico, PVDC (cloruro de polivinildieno) y acrilonitrilo; y estando constituidas las capas integradas en medio del núcleo (C) por una décima capa (Ib) seleccionada entre poliéster y policarbonato PC, sobre cuyas caras se adhiere con adhesivo, preferentemente con adhesivo de base poliuretano (2plu) , una tercera capa opaca (lal) de derivado modificado de PET-G.25.- INTEGRAL PLASTIC STRUCTURE, according to claims 13 to 24, characterized in that it comprises a symmetrical structure of layers selected between thermo-laminated layers on both sides (3e, 3'e), of the central assembly (Cl, C2, .. Cn) of the core (C) and layers integrated in the middle of the central assembly of said core (C); said thermolaminated layers being constituted by a tenth layer (Ib) selected between polyester and polycarbonate, on whose faces they are adhered by means of adhesive (2plu), of polyurethane base, third layers (lal) of PET-G modified derivative selectively with additive for laser engraving, with micronized carbon, and selectively with micronized carbon additive, and on the outer faces of the third layers (lal) comprises a deposit of a seventh layer (lg) selectively constituted by at least one of the following elements: vinyl derivative , PVDC (polyvinyldiene chloride) and acrylonitrile; and the layers integrated in the middle of the core (C) being constituted by a tenth layer (Ib) selected from polyester and PC polycarbonate, on whose faces it is adhered with adhesive, preferably with polyurethane base adhesive (2plu), a third opaque layer ( lal) of modified derivative of PET-G.
26.- ESTRUCTURA PLÁSTICA INTEGRAL, según las reivindicaciones 13 a 25, caracterizada porque la cubierta posterior de un documento comprende una décima capa (Ib) de poliéster sobre la que comprende, previa descarga de efecto corona, un depósito de una capa de adhesivo (2plu) para plásticos de base de poliuretano a la que se adhiere una tercera capa (lal) de derivado modificado de PET-G que comprende un producto seleccionado entre aditivo de carbón micronizado y aditivo de óxido de titanio, comprendiendo la cara interior de la décima capa (Ib) impresiones de seguridad seleccionadas entre logos, figuras y escudos, de tintas UV y de tintas OVI (optical variable ink) .26.- INTEGRAL PLASTIC STRUCTURE, according to claims 13 to 25, characterized in that the back cover of a document comprises a tenth layer (Ib) of polyester on which it comprises, after effect discharge corona, a deposit of one layer of adhesive (2plu) for polyurethane-based plastics to which a third layer (lal) of modified PET-G derivative which comprises a product selected from micronized carbon additive and oxide additive adheres titanium, comprising the inside of the tenth layer (Ib) security prints selected from logos, figures and shields, UV inks and OVI inks (optical variable ink).
27.- ESTRUCTURA PLÁSTICA INTEGRAL, según las reivindicaciones 13 a 26, caracterizada porque comprende una combinación termolaminada de una estructura holográfica, de un núcleo y una cubierta posterior para obtener estructuras específicas de documentos, tarjetas de identidad, pasaportes y visados.27.- INTEGRAL PLASTIC STRUCTURE, according to claims 13 to 26, characterized in that it comprises a thermo-laminated combination of a holographic structure, a core and a back cover to obtain specific document structures, identity cards, passports and visas.
28.- ESTRUCTURA PLÁSTICA INTEGRAL, según las reivindicaciones 13 a 27, caracterizada porque la laca que polimeriza y endurece por la acción seleccionada entre luz UV, radiación electrónica, y aire, está seleccionada entre acrilatos monómeros multifuncionales basados en polyols como diluyentes reactivos (thinners) y acrilatos oligómeros como aglutinantes (binders) formados por al menos uno de los siguientes elementos: epoxi-acrilato, poliéster-acrilato, poliéter-acrilato, metano-acrilato, silicon-acrilato, uretano-acrilato, epoxi-silicona, y sus versiones diluibles y emulsionables en agua; y porque porque el plástico grabable (shim embossable plástic) está constituido por al menos uno de los siguientes productos: derivado acrílico, derivado de acetato, derivado poliolefínico, derivado de polipropileno, derivado epoxi, derivado de poliuretano, derivado de polietileno- tereftalato.28.- INTEGRAL PLASTIC STRUCTURE, according to claims 13 to 27, characterized in that the lacquer that polymerizes and hardens by the selected action between UV light, electronic radiation, and air, is selected from multifunctional monomers based on polyols as reactive diluents (thinners ) and oligomeric acrylates as binders formed by at least one of the following elements: epoxy acrylate, polyester acrylate, polyether acrylate, methane acrylate, silicon acrylate, urethane acrylate, epoxy silicone, and their versions dilutable and emulsifiable in water; and because because the recordable plastic (shim embossable plastic) is constituted by at least one of the following products: acrylic derivative, acetate derivative, polyolefin derivative, polypropylene derivative, epoxy derivative, polyurethane derivative, polyethylene terephthalate derivative.
29.- ESTRUCTURA PLÁSTICA INTEGRAL, según las reivindicaciones 13-28, caracterizada porque a los elementos constitutivos de al menos una de las capas: primera capa (la) de poliéster de la lámina protectora, capa fina (2al) constituida selectivamente por laca polimerizable, por depósito de imprimación, por cera de silicona preferentemente de cera de carnauba, y la segunda capa (2a2) de los derivados acrílicos del respectivo laminado holográfico tanto de tipo HRI transparente como de tipo metalizado, comprende un agregado en su masa de un aditivo seleccionado entre un aditivo genérico para grabado por rayo láser y un aditivo de carbón micronizado con inhibidor supresor de llama, para realizar el grabado personalizado de estructuras en superficie por rayo láser destructivo (burning) .29.- INTEGRAL PLASTIC STRUCTURE, according to claims 13-28, characterized in that the constituent elements of at least one of the layers: first polyester layer (la) of the protective sheet, thin layer (2al) selectively constituted by polymerizable lacquer, by primer deposit, by silicone wax preferably of carnauba wax, and the second layer (2a2) of the acrylic derivatives of the respective holographic laminate of both transparent and metallized HRI type, comprises an aggregate in its mass of an additive selected from a generic additive for laser engraving and a micronized carbon additive with flame suppressor inhibitor, to perform custom engraving of surface structures by destructive laser beam (burning).
30.- ESTRUCTURA PLÁSTICA INTEGRAL, según la reivindicación 13 caracterizada porque la primera capa (la) es selectivamente de un envase, de una superficie de empaquetado, y de una etiqueta de envase constituido selectivamente por poliéster orientado, por plástico durable (durable plástic) . 30.- INTEGRAL PLASTIC STRUCTURE, according to claim 13, characterized in that the first layer (la) is selectively of a container, of a packaging surface, and of a container label selectively constituted by oriented polyester, by durable plastic (durable plastic) .
PCT/ES2004/000196 2003-05-26 2004-05-04 Method of producing an integral plastic structure and structure thus obtained WO2004103722A1 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
ESP200301228 2003-05-26
ES200301228A ES2220222B1 (en) 2003-05-26 2003-05-26 PROCEDURE FOR OBTAINING AN INTEGRAL PLASTIC STRUCTURE AND OBTAINED STRUCTURE.
ES200301822A ES2222835B1 (en) 2003-05-26 2003-07-31 IMPROVEMENTS INTRODUCED IN PATENT 200301228 BY PROCEDURE FOR OBTAINING AN INTEGRAL PLASTIC STRUCTURE AND OBTAINED STRUCTURE.
ESP200301822 2003-07-31
ES200302941A ES2234432B1 (en) 2003-05-26 2003-12-12 IMPROVEMENTS INTRODUCED IN THE PATENT N. P-200301228/1, BY: PROCEDURE FOR OBTAINING AN INTEGRAL PLASTIC STRUCTURE AND OBTAINED STRUCTURE.
ESP200302941 2003-12-12

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5513019A (en) * 1993-04-16 1996-04-30 Crown Roll Leaf, Inc. Semi-transparent reflective layer for a phase hologram
US5759683A (en) * 1994-04-04 1998-06-02 Novavision, Inc. Holographic document with holographic image or diffraction pattern directly embossed thereon

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5513019A (en) * 1993-04-16 1996-04-30 Crown Roll Leaf, Inc. Semi-transparent reflective layer for a phase hologram
US5759683A (en) * 1994-04-04 1998-06-02 Novavision, Inc. Holographic document with holographic image or diffraction pattern directly embossed thereon

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