WO2004089124A1 - On line formation of recessed cigarette filter - Google Patents
On line formation of recessed cigarette filter Download PDFInfo
- Publication number
- WO2004089124A1 WO2004089124A1 PCT/IB2004/001327 IB2004001327W WO2004089124A1 WO 2004089124 A1 WO2004089124 A1 WO 2004089124A1 IB 2004001327 W IB2004001327 W IB 2004001327W WO 2004089124 A1 WO2004089124 A1 WO 2004089124A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- substrate
- particulate material
- filter
- layer
- particulate
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/0225—Applying additives to filter materials with solid additives, e.g. incorporation of a granular product
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0275—Manufacture of tobacco smoke filters for filters with special features
- A24D3/0287—Manufacture of tobacco smoke filters for filters with special features for composite filters
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
- A24D3/163—Carbon
Definitions
- the present invention relates to the formation of recessed cigarette filters, and more particularly to the on line formation of filters that include smoke altering particulate material such as catalysts, adsorbents, flavors and the like.
- Many filter making procedures include combining a number of independent filter components fabricated beforehand, stored and then combined into a particular cigarette filter design, such as a plug-space-plug configuration. Such procedures require a number of steps which can be eliminated with on line formation of the filter components, such as the step of storing the preformed filter components before assembly.
- one of the objects of the present invention is a procedure for the on line formation of cigarette filters in the production of cigarettes.
- Another object of the present invention is a procedure for on line formation of filters which enables variation of the process parameters to produce filters of different construction and efficiency.
- Still another object of the present invention is a filter making process which is simple, but highly effective in producing cigarette filters at high production speeds.
- an electrostatic deposition or other process such as xerography or electrophotography that allows the formation of a layer of smoke altering particulate material on a paper substrate or the filter paper or any other suitable substrate is used on line to create an active layer in the recessed area of a cigarette filter.
- the amount of smoke altering particulate material can be varied depending on the strength of the applied field and coverage on the filter paper.
- the particulate material may be bound together using small amounts of a hot melt binder. Hot melt binders are preferred over solution or latex binders which may require extensive drying for the removal of the liquid carrier.
- particulates may be deposited in this manner such as catalysts, flavors and adsorbents, for example.
- Particulate material may be introduced in the electrostatically deposited layer to assist in the removal of specific components in the tobacco smoke stream.
- Silicas could be used to remove specific aldehydes, for example.
- the electrostatically deposited layer could also include a combination of particulates such as a carbon adsorbent and a flavorant that enhances the flavor or subjective characteristics of the cigarette. This along with the ability to apply the layer on line improves the flexibility of the cigarette designer in terms of smoke delivery and increases the ability to control the quality of the entire process.
- Another aspect of the invention deals with the use of nonwovens in place of particulate laden paper.
- a nonwoven activated carbon piece may be used in place of carbon filled paper.
- cellulose fibers used in the carbon filled paper are hygroreactive and may tend to make the smoke dry. Accordingly, use of a paperless nonwoven with activated carbon adsorbent could improve the subjective characteristics experienced during the smoking process.
- Figure 1 is a schematic diagrammatic view illustrating on line electrostatic deposition of particulate material onto a substrate and formation of the particulate coated substrate into plug form for on line insertion into the cavities between a continuous line of spaced apart cellulose acetate plugs;
- Figure 2 is a side elevational view of the particulate plug of Figure 1 after being cut and prior to the flap being folded over to complete the plug form;
- Figure 3 is a schematic diagrammatic view illustrating the plugs of Figure 1 inserted into the cavities between spaced apart cellulose acetate plugs in the continuous production of cigarette filters;
- Figure 4 is a complete plug-space-plug cigarette filter with a particulate plug in the cavity between two cellulose acetate plugs;
- Figure 5 is a schematic diagrammatic view illustrating an alternate process for on line electrostatic deposition of particulate material onto filter paper during the continuous production of plug-space-plug cigarette filters;
- Figure 6 is a plan view of the cigarette filter paper of Figure 5 with smoke altering material electrostatically deposited on the paper;
- Figure 7 is a schematic diagrammatic view illustrating still another procedure for on line electrostatic deposition of particulate material onto filter paper by indirect transfer;
- Figure 8 shows particulate material electrostatically deposited on the paper in pattern form
- Figure 9 is another schematic diagrammatic view showing particulate material deposited on both sides of a suitable substrate.
- Figure 10 is an end elevated view of a roll formed filter component where the particulate coated substrate is crimped before being rolled.
- Figure 1 illustrates an arrangement for depositing particulate material 10 from a first supply 12 onto a continuous thin flexible substrate 14.
- the substrate may be paper or nonwoven material, for example, and the particulate material 10 may comprise any smoke altering particles such as adsorbents, catalysts and flavorants.
- Adsorbents may include carbon, zeolite, APS silica gel and other adsorbent materials alone or in combination with one another.
- silica is particularly effective for removing specific aldehydes from tobacco smoke.
- An electrostatic charge is applied onto the substrate 14 by any suitable mechanism such as the corona discharge device 16 shown in Figure 1.
- the strength of the charge is selected in accordance with the thickness of particulate material coated onto the substrate 14 with higher charges producing greater thickness.
- the substrate becomes coated with the material.
- the particles may be bound together using small amounts of hot melt binder, if desired.
- the coated substrate may pass through the nip of a pair of rollers 18 to fuse or otherwise press the particulate material 10 into the substrate 14, as shown in Figure 1.
- the particulate material may be deposited in a single pass or multiple layers may be applied to the substrate.
- a second supply 12A of the same or different particulate 10A deposits another layer on the first deposited layer, and rollers 18A press the material onto the substrate.
- the particulate coated substrate 14 is then cut into pieces by cutter 20 and those pieces are deposited into cavities between spaced apart filter components, as explained more fully below.
- the cut pieces are formed into a cylindrical plug 22 by rolling the coated substrate piece into that configuration.
- Figures 1 and 2 illustrate the plug 22, and in Figure 2 flap 24 is ready for folding over to complete the plug form.
- Figure 3 illustrates an arrangement for producing a continuous line of plug- space-plug filters.
- This arrangement includes filter paper 26 with spaced apart plugs 28 of cellulose acetate on the filter paper. Cavities 30 are located between the cellulose acetate plugs, and the plug rolls 22 of particulate coated substrate are deposited into these cavities.
- the continuous filter of Figure 3 is cut at 32 into the plug- space-plug filter 34 shown as in Figure 4.
- the spaced apart cellulose acetate plugs 28 A and B define the cavity 30 into which the plug roll 22 has been deposited.
- the filter paper 26 surrounds this assembly.
- FIG 5 illustrates an alternative embodiment of the present invention where the filter paper 26 is coated with particulate material 10B from a source 12B.
- an electrostatic charge is applied to the filter paper 26 with charger device 16.
- the filter paper 30 with particulate thereon passes through the rollers 18 and thereafter cellulose acetate plugs 28 are appropriately positioned on the coated filter paper.
- the coated filter paper is ultimately wrapped around the spaced apart cellulose acetate plugs 28 with plows 36 and the continuous filter arrangement is later cut into individual cigarette filter assemblies, such as shown in Figure 4.
- the cavities are somewhat hollow and the smoke altering particulate material 10 is in the form of an inside surface layer within the cavity 30.
- Figure 6 shows the filter paper 26 coated with the particulate material 10B.
- Figure 7 illustrates another embodiment of the present invention where the continuous thin flexible substrate 14 is indirectly coated with particulate material 10C.
- a rotating transfer roll 30 receives an electrostatic charge from device 16, and particulate material 10C is deposited on the charged surface of the roll from a supply 12C.
- the particulate material on the surface of the roll is transferred onto substrate 14 by suction, from a plenum 32, for example. Thereafter, the layer of material 10C passes through the nip of rollers 18 to fuse or otherwise press the material into the substrate.
- the coated substrate is subsequently cut and formed into filter pieces, as described above.
- Figure 7 also illustrates an optional second transfer station 30A for depositing another layer on the substrate similar to the system described above in conjunction with Figure 1.
- the layer of particulate material 10D of Figure 8 is deposited on substrate 14 in pattern form.
- the charging device may be constructed and arranged to place a pattered charge on the substrate, and the particulate only adheres to the substrate at the charged portions thereof.
- Figure 9 shows an arrangement for applying particulate material layers 10 and 10E on opposite sides of substrate 14.
- a first supply 12 of particulate material is located on one side of the substrate and a second supply 12E is located on the other side of the substrate.
- An electrostatic charge is applied to both sides of substrate 14 by devices 16 and 16E. Otherwise the system is similar to Figure 1 , and the coated substrate is formed into filter components in the same manner as described above.
- Figure 10 is cross-sectional view of a filter component 40 similar to the one shown in Figure 2. However, in filter component 40 the substrate 14 coated with particulate material is crimped prior to being roll formed into its final configuration.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Laminated Bodies (AREA)
- Filtering Materials (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
- Manufacturing Of Cigar And Cigarette Tobacco (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020117019989A KR101174611B1 (en) | 2003-04-09 | 2004-04-02 | Recessed cigarette filter |
BRPI0409254-6A BRPI0409254B1 (en) | 2003-04-09 | 2004-04-02 | process for producing cigarette filters and filter element. |
PL04725454T PL1610632T3 (en) | 2003-04-09 | 2004-04-02 | On line formation of recessed cigarette filter |
EP04725454A EP1610632B1 (en) | 2003-04-09 | 2004-04-02 | On line formation of recessed cigarette filter |
DE602004014599T DE602004014599D1 (en) | 2003-04-09 | 2004-04-02 | FLOW ROPE MANUFACTURE OF CIGARETTE FILTERS WITH REMOVAL |
JP2006506552A JP4522403B2 (en) | 2003-04-09 | 2004-04-02 | Online manufacturing method for embedded cigarette filter |
CN2004800095538A CN1770987B (en) | 2003-04-09 | 2004-04-02 | On line formation of recessed cigarette filter |
KR1020057018969A KR101174519B1 (en) | 2003-04-09 | 2005-10-05 | On line formation of recessed cigarette filter |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/410,626 | 2003-04-09 | ||
US10/410,626 US20040200491A1 (en) | 2003-04-09 | 2003-04-09 | On line formation of recessed cigarette filter |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004089124A1 true WO2004089124A1 (en) | 2004-10-21 |
Family
ID=33130817
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2004/001327 WO2004089124A1 (en) | 2003-04-09 | 2004-04-02 | On line formation of recessed cigarette filter |
Country Status (12)
Country | Link |
---|---|
US (2) | US20040200491A1 (en) |
EP (2) | EP1908360B1 (en) |
JP (1) | JP4522403B2 (en) |
KR (2) | KR101174611B1 (en) |
CN (2) | CN1770987B (en) |
AT (2) | ATE398939T1 (en) |
BR (1) | BRPI0409254B1 (en) |
DE (2) | DE602004023142D1 (en) |
ES (2) | ES2305759T3 (en) |
PL (2) | PL1908360T3 (en) |
RU (1) | RU2342892C2 (en) |
WO (1) | WO2004089124A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008146161A2 (en) * | 2007-05-31 | 2008-12-04 | Philip Morris Products S.A. | Filter including electrostatically charged fiber material |
US8393334B2 (en) | 2008-06-02 | 2013-03-12 | Philip Morris Usa Inc. | Smoking article with transparent section |
WO2013068081A1 (en) | 2011-11-07 | 2013-05-16 | Philip Morris Products S.A. | Smoking article with colour change segment |
WO2013068100A1 (en) | 2011-11-07 | 2013-05-16 | Philip Morris Products S.A. | Smoking article with visible contents |
US9788572B2 (en) | 2009-10-09 | 2017-10-17 | Philip Morris Usa Inc. | Method and apparatus for manufacture of smoking article filter assembly including electrostatically charged fibers |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7478637B2 (en) * | 2004-11-09 | 2009-01-20 | Philip Morris Usa Inc. | Continuous process for surface modification of cigarette filter materials |
WO2007104908A1 (en) * | 2006-03-10 | 2007-09-20 | British American Tobacco (Investments) Limited | Smoking article filter |
DE102006049823A1 (en) * | 2006-10-19 | 2008-04-24 | Hauni Maschinenbau Ag | Apparatus and method for processing filter material for cigarette filters or the like |
CN101969797A (en) * | 2008-02-07 | 2011-02-09 | 菲尔特隆纳国际有限公司 | Tobacco smoke filter |
IT1398609B1 (en) * | 2010-03-12 | 2013-03-08 | Montrade S R L | METHOD FOR THE REALIZATION OF CORDONS OF FILTERING MATERIAL FOR SMOKE ITEMS |
ITBO20100150A1 (en) * | 2010-03-12 | 2011-09-13 | Montrade S R L | METHOD FOR THE REALIZATION OF COMBINED FILTERS FOR SMOKE ITEMS |
US8671951B2 (en) * | 2010-03-26 | 2014-03-18 | Philip Morris Usa Inc. | Methods of manufacturing cigarettes and filter subassemblies with squeezable flavor capsule |
DE102011114522A1 (en) * | 2011-09-29 | 2013-04-04 | Focke & Co. (Gmbh & Co. Kg) | Method and apparatus for producing a package for a group of smokable articles |
ITBO20120106A1 (en) * | 2012-03-05 | 2013-09-06 | Montrade Srl | METHOD AND MACHINE FOR THE PRODUCTION OF FILTERS WITHOUT PAPER FOR SMOKE ITEMS |
EP2901871A1 (en) * | 2014-01-31 | 2015-08-05 | Philip Morris Products S.A. | Multi-segment filter tube |
CN106822757A (en) * | 2017-01-26 | 2017-06-13 | 德钦县升平镇黎德曼扎亚有限公司 | The preparation method of a drinkable joss stick produced in Xizang |
WO2021127828A1 (en) * | 2019-12-23 | 2021-07-01 | 湖南中烟工业有限责任公司 | Device and method for preparing fully granular cigarette/filter rod, and prepared fully granular cigarette/filter rod |
CN114190586B (en) * | 2020-09-02 | 2024-01-19 | 湖南中烟工业有限责任公司 | Natural aroma enhancement type harm reduction full-particle filter stick and preparation method and application thereof |
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US2928400A (en) * | 1954-06-24 | 1960-03-15 | Eastman Kodak Co | Fibrous tobacco smoke filters |
GB1045826A (en) * | 1964-04-01 | 1966-10-19 | Henry Klein | Improved filter for tobacco smoke and method of production of same |
US3339560A (en) * | 1964-08-19 | 1967-09-05 | Eastman Kodak Co | Tobacco smoke filters |
US5322495A (en) * | 1992-04-27 | 1994-06-21 | Philip Morris Incorporated | High speed vacuum assisted free flowing material inserter in filter rod manufacture |
US5465739A (en) * | 1992-04-15 | 1995-11-14 | R. J. Reynolds Tobacco Company | Cigarette and cigarette filter element therefor |
US5590449A (en) * | 1993-11-24 | 1997-01-07 | Hauni Maschinenbau Ag | Apparatus for stretching plasticizing and gathering a tow of filter material for tobacco smoke |
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NL34851C (en) * | 1927-11-23 | |||
US2576047A (en) * | 1948-10-21 | 1951-11-20 | Battelle Development Corp | Method and apparatus for printing electrically |
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US5031646A (en) * | 1990-01-16 | 1991-07-16 | R. J. Reynolds Tobacco Company | Cigarette |
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DE4209606A1 (en) * | 1992-03-25 | 1993-09-30 | Hauni Werke Koerber & Co Kg | Method and device for treating at least one web of threads filter material for cigarette filters |
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US5404890A (en) * | 1993-06-11 | 1995-04-11 | R. J. Reynolds Tobacco Company | Cigarette filter |
GB9325536D0 (en) * | 1993-12-14 | 1994-02-16 | Rothmans International Ltd | Smoking article and filter therefor |
US5875824A (en) * | 1996-08-06 | 1999-03-02 | Atwell; Charles G. | Method and apparatus for high speed delivery of particulate material |
ES2336646T3 (en) * | 2000-09-18 | 2010-04-15 | ROTHMANS, BENSON & HEDGES INC. | LOW EMISSION CIGARETTE OF SECONDARY CURRENT SMOKE WITH FUEL PAPER. |
ATE377361T1 (en) * | 2002-08-16 | 2007-11-15 | Hauni Maschinenbau Ag | METHOD AND DEVICE FOR SUPPLYING AN ADDITIVE, PREFERABLY LIQUID, TO A MOVING, EXPANDED BELT OF FILTER MATERIAL |
-
2003
- 2003-04-09 US US10/410,626 patent/US20040200491A1/en not_active Abandoned
-
2004
- 2004-04-02 DE DE602004023142T patent/DE602004023142D1/en not_active Expired - Lifetime
- 2004-04-02 ES ES04725454T patent/ES2305759T3/en not_active Expired - Lifetime
- 2004-04-02 RU RU2005134654/12A patent/RU2342892C2/en not_active IP Right Cessation
- 2004-04-02 WO PCT/IB2004/001327 patent/WO2004089124A1/en active IP Right Grant
- 2004-04-02 EP EP07021885A patent/EP1908360B1/en not_active Expired - Lifetime
- 2004-04-02 EP EP04725454A patent/EP1610632B1/en not_active Expired - Lifetime
- 2004-04-02 ES ES07021885T patent/ES2333171T3/en not_active Expired - Lifetime
- 2004-04-02 CN CN2004800095538A patent/CN1770987B/en not_active Expired - Fee Related
- 2004-04-02 BR BRPI0409254-6A patent/BRPI0409254B1/en not_active IP Right Cessation
- 2004-04-02 AT AT04725454T patent/ATE398939T1/en not_active IP Right Cessation
- 2004-04-02 DE DE602004014599T patent/DE602004014599D1/en not_active Expired - Lifetime
- 2004-04-02 KR KR1020117019989A patent/KR101174611B1/en active IP Right Grant
- 2004-04-02 PL PL07021885T patent/PL1908360T3/en unknown
- 2004-04-02 CN CN2011100727154A patent/CN102100404A/en active Pending
- 2004-04-02 PL PL04725454T patent/PL1610632T3/en unknown
- 2004-04-02 AT AT07021885T patent/ATE442061T1/en not_active IP Right Cessation
- 2004-04-02 JP JP2006506552A patent/JP4522403B2/en not_active Expired - Fee Related
-
2005
- 2005-10-05 KR KR1020057018969A patent/KR101174519B1/en active IP Right Grant
-
2006
- 2006-12-21 US US11/643,155 patent/US7918232B2/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2928400A (en) * | 1954-06-24 | 1960-03-15 | Eastman Kodak Co | Fibrous tobacco smoke filters |
GB1045826A (en) * | 1964-04-01 | 1966-10-19 | Henry Klein | Improved filter for tobacco smoke and method of production of same |
US3339560A (en) * | 1964-08-19 | 1967-09-05 | Eastman Kodak Co | Tobacco smoke filters |
US5465739A (en) * | 1992-04-15 | 1995-11-14 | R. J. Reynolds Tobacco Company | Cigarette and cigarette filter element therefor |
US5322495A (en) * | 1992-04-27 | 1994-06-21 | Philip Morris Incorporated | High speed vacuum assisted free flowing material inserter in filter rod manufacture |
US5590449A (en) * | 1993-11-24 | 1997-01-07 | Hauni Maschinenbau Ag | Apparatus for stretching plasticizing and gathering a tow of filter material for tobacco smoke |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008146161A2 (en) * | 2007-05-31 | 2008-12-04 | Philip Morris Products S.A. | Filter including electrostatically charged fiber material |
WO2008146161A3 (en) * | 2007-05-31 | 2009-01-29 | Philip Morris Prod | Filter including electrostatically charged fiber material |
US8393334B2 (en) | 2008-06-02 | 2013-03-12 | Philip Morris Usa Inc. | Smoking article with transparent section |
US9788572B2 (en) | 2009-10-09 | 2017-10-17 | Philip Morris Usa Inc. | Method and apparatus for manufacture of smoking article filter assembly including electrostatically charged fibers |
US10226070B2 (en) | 2009-10-09 | 2019-03-12 | Philip Morris Usa Inc. | Filter rod including electrostatically charged fibers |
WO2013068081A1 (en) | 2011-11-07 | 2013-05-16 | Philip Morris Products S.A. | Smoking article with colour change segment |
WO2013068100A1 (en) | 2011-11-07 | 2013-05-16 | Philip Morris Products S.A. | Smoking article with visible contents |
Also Published As
Publication number | Publication date |
---|---|
KR20110100325A (en) | 2011-09-09 |
ES2333171T3 (en) | 2010-02-17 |
RU2005134654A (en) | 2006-05-10 |
JP4522403B2 (en) | 2010-08-11 |
EP1610632A1 (en) | 2006-01-04 |
ES2305759T3 (en) | 2008-11-01 |
KR101174519B1 (en) | 2012-08-16 |
CN1770987B (en) | 2011-04-06 |
CN102100404A (en) | 2011-06-22 |
RU2342892C2 (en) | 2009-01-10 |
ATE398939T1 (en) | 2008-07-15 |
DE602004014599D1 (en) | 2008-08-07 |
ATE442061T1 (en) | 2009-09-15 |
PL1908360T3 (en) | 2010-02-26 |
BRPI0409254B1 (en) | 2012-07-10 |
DE602004023142D1 (en) | 2009-10-22 |
US20070102012A1 (en) | 2007-05-10 |
KR101174611B1 (en) | 2012-08-16 |
EP1610632B1 (en) | 2008-06-25 |
BRPI0409254A (en) | 2006-03-28 |
CN1770987A (en) | 2006-05-10 |
KR20050113672A (en) | 2005-12-02 |
EP1908360B1 (en) | 2009-09-09 |
JP2006522600A (en) | 2006-10-05 |
US7918232B2 (en) | 2011-04-05 |
EP1908360A1 (en) | 2008-04-09 |
US20040200491A1 (en) | 2004-10-14 |
PL1610632T3 (en) | 2008-12-31 |
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