WO2004079035A1 - Procede de fabrication d'un revetement composite - Google Patents

Procede de fabrication d'un revetement composite Download PDF

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Publication number
WO2004079035A1
WO2004079035A1 PCT/RU2003/000091 RU0300091W WO2004079035A1 WO 2004079035 A1 WO2004079035 A1 WO 2004079035A1 RU 0300091 W RU0300091 W RU 0300091W WO 2004079035 A1 WO2004079035 A1 WO 2004079035A1
Authority
WO
WIPO (PCT)
Prior art keywords
aluminum
coating
differs
spraying
product
Prior art date
Application number
PCT/RU2003/000091
Other languages
English (en)
Russian (ru)
Inventor
Alexander Pavlovich Khinsky
Original Assignee
Alexander Pavlovich Khinsky
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alexander Pavlovich Khinsky filed Critical Alexander Pavlovich Khinsky
Priority to PCT/RU2003/000091 priority Critical patent/WO2004079035A1/fr
Publication of WO2004079035A1 publication Critical patent/WO2004079035A1/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/10Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
    • C23C4/11Oxides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/123Spraying molten metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/08Flame spraying

Definitions

  • Opportunity for use may be used in the same way as for application of various types of clothing, for example, for example, but also for Methods of applying protective spraying with the use of composites based on aluminum compounds by means of gas spraying are known.
  • the most widespread on the market is the use of aluminum oxide (1) for the spraying of materials on the basis of aluminum.
  • gas-thermal spraying of ceramic sprays is carried out on the preliminary applied metal finish.
  • the method of applying the aluminum finish is known, which ensures high anode properties and high resistance to erosion and corrosion (2).
  • a trip based on the ⁇ 1- ⁇ - ⁇ - ⁇ system with indium, bismuth or tula additives is paid by paying for the internal cleaning of the pipe.
  • the method makes it possible to increase the standard of clutch of acquisitions with the basic and, therefore, it is easier to use.
  • a method of receiving a large amount of waste has been known (5), including spraying of layers in a medium of inert gas with the addition of dissipated water.
  • SIGNIFICANT FOX carbon or carbon.
  • the latter are solid lubricants and prevent wear and tear. In such a way that the acquisition is applied, an acceptable layer is applied.
  • the aluminum hydroxides used in the process of spraying hydrants increase the rate of the product’s improved speed.
  • ⁇ me ⁇ g ⁇ is ⁇ dya of ⁇ isann ⁇ y ⁇ e ⁇ n ⁇ l ⁇ - ology, ⁇ y ⁇ ie not m ⁇ zhe ⁇ ⁇ blada ⁇ d ⁇ s ⁇ a ⁇ chn ⁇ vys ⁇ y izn ⁇ s ⁇ s ⁇ y ⁇ s ⁇ yu and ⁇ is- ⁇ s ⁇ yu, ch ⁇ delae ⁇ eg ⁇ ne ⁇ ig ⁇ dnym for is ⁇ lz ⁇ vaniya in ⁇ aches ⁇ ve ⁇ dl ⁇ zh ⁇ i for ⁇ i ⁇ i ⁇ azlichnymi s ⁇ s ⁇ avami.
  • ⁇ sn ⁇ vnym d ⁇ s ⁇ ins ⁇ v ⁇ m leave ⁇ g ⁇ me ⁇ da yavlyae ⁇ sya vys ⁇ aya ⁇ dn ⁇ dn ⁇ s ⁇ and ⁇ avn ⁇ me ⁇ n ⁇ s ⁇ nanesonn ⁇ g ⁇ sl ⁇ ya, ned ⁇ s ⁇ a ⁇ m - ⁇ ⁇ bs ⁇ ya ⁇ els ⁇ v ⁇ , ch ⁇ ⁇ i ⁇ a ⁇ y ⁇ e ⁇ n ⁇ l ⁇ gii not ⁇ bes ⁇ echivae ⁇ sya nadozhn ⁇ g ⁇ stse ⁇ leniya ⁇ a ⁇ ali ⁇ iches ⁇ g ⁇ n ⁇ si ⁇ elya with ⁇ e ⁇ amiches ⁇ y ⁇ dl ⁇ zh ⁇ y.
  • the method of applying plasma spray with the use of a mixture (8) of powders: aluminum oxide and metal titanium (15-60%) in the quality of the metal binder is known.
  • the method allows you to opt for high abrasion resistance.
  • the short-term share of the op- eration is 8–11%, the cohesive rate is 9–10 Pa.
  • ⁇ a ⁇ ⁇ azyvayu ⁇ issled ⁇ vaniya in e ⁇ y ⁇ blas ⁇ i for us ⁇ eshn ⁇ g ⁇ ⁇ esheniya e ⁇ i ⁇ dvu ⁇ tasks ⁇ dn ⁇ v ⁇ emenn ⁇ , ⁇ mezhu ⁇ chny sl ⁇ y ( ⁇ dsl ⁇ y) d ⁇ lzhen, v ⁇ - ⁇ e ⁇ vy ⁇ , ⁇ blada ⁇ ⁇ e ⁇ itsien ⁇ m ⁇ e ⁇ miches ⁇ g ⁇ ⁇ asshi ⁇ eniya ( ⁇ . ⁇ . ⁇ ) ma ⁇ simaln ⁇ bliz ⁇ im ⁇ ⁇ . ⁇ . ⁇ .
  • SIGNIFICANT FOX (DR. 26) For ⁇ bes ⁇ echeniya ⁇ ⁇ sheg ⁇ stse ⁇ leniya ⁇ dsl ⁇ ya with nan ⁇ simym on eg ⁇ ⁇ ve ⁇ - n ⁇ s ⁇ ⁇ y ⁇ iem ⁇ dsl ⁇ y d ⁇ lzhen ⁇ blada ⁇ vys ⁇ azvi ⁇ y ⁇ ve ⁇ n ⁇ s ⁇ yu. Reliable free movement in this case must be at least 10 m 2 / g. 100 This must ensure high adhesion to the sprayed material.
  • ⁇ a ⁇ im ⁇ b ⁇ az ⁇ m is ⁇ lz ⁇ vanie recovery ⁇ g ⁇ iz ⁇ b ⁇ e ⁇ eniya for ⁇ lucheniya ⁇ y ⁇ iya 105 ⁇ bes ⁇ echivayuscheg ⁇ vys ⁇ uyu ⁇ chn ⁇ s ⁇ stse ⁇ leniya with ⁇ dl ⁇ zh ⁇ y and ⁇ dn ⁇ v ⁇ emenn ⁇ vys ⁇ uyu ⁇ chn ⁇ s ⁇ stse ⁇ leniya with nan ⁇ simymi on eg ⁇ ⁇ ve ⁇ n ⁇ s ⁇ i ⁇ y ⁇ iyami ⁇ azlichn ⁇ g ⁇ destination nev ⁇ zm ⁇ zhn ⁇ .
  • this may be a result of the unspecific 115 chemical spray and the original source of heat.
  • SIGNIFICANT FOX (DR. 26) 4 ⁇ vysheniya s ⁇ ds ⁇ va aluminum ne ⁇ b ⁇ ⁇ dim ⁇ ⁇ bes ⁇ echi ⁇ chas ⁇ ichn ⁇ e ⁇ lavlenie 145 chas ⁇ its gid ⁇ sida with ⁇ ve ⁇ n ⁇ s ⁇ i.
  • gibbsite and boehmite Two modifications of aluminum hydroxide are used — gibbsite and boehmite.
  • D ⁇ lni ⁇ elnye me ⁇ y, ⁇ ye is ⁇ lzuyu ⁇ sya in s ⁇ s ⁇ be ⁇ ⁇ i ⁇ u and imenn ⁇ ⁇ dacha ⁇ azlichny ⁇ ⁇ m ⁇ nen ⁇ v mixture in ⁇ azlichnye z ⁇ ny ⁇ lazmenn ⁇ y s ⁇ ui, ⁇ dacha ⁇ sh ⁇ a on s ⁇ ez s ⁇ la ⁇ lazm ⁇ na, ⁇ dacha ⁇ sh ⁇ a ⁇ d ugl ⁇ m and 160 navs ⁇ echu ⁇ u ⁇ lazmy, na ⁇ avleny on ⁇ ed ⁇ v ⁇ aschenie ⁇ sh ⁇ a gid ⁇ sida aluminum ⁇ ⁇ ln ⁇ g ⁇ ⁇ azl ⁇ zheniya ⁇ i ⁇ zhdenii Plasma structure.
  • ⁇ ⁇ slednee v ⁇ emya ⁇ a ⁇ ie is ⁇ uss ⁇ vennye ma ⁇ e ⁇ ialy ⁇ yavilis and i ⁇ ⁇ a ⁇ a ⁇ e- ⁇ is ⁇ i ⁇ i in ⁇ ensivn ⁇ issleduyu ⁇ sya.
  • the product is commercially available in accordance with the invention and is used in the manufacture of aluminum alloys based on a hydrous-based product
  • a commercially available powder is used to modify aluminum hydroxide, and specifically, gibbsite and boehmite.
  • the process is conducted in the range of 200–300 ° C for 8–16 hours, at the second stage, in the range of 520–600 ° C for 4–8 hours and at a constant temperature of 800–800 ° C. 6 - 8 hours
  • Hydraulic unit is a direct output of the bus
  • Hydration of hydraulic materials occurs as it did, in the next step.
  • anions are separated out, which are located between the layers of the catalysts and are secured
  • the temperature interval of the third stage of decomposition of the hydrous metal is 650–750 ° ⁇ , which significantly increases the temperature of the separation of the aluminum hydrous system;
  • the value of the free area after the full disposal of the hydraulic 280 cite is 200-400 m 2 / g;
  • SIGNIFICANT FOX (DR. 26) the cost of a chemical product in the form of a mixture of oxides or complex oxides (spinels) with a high free quantity.
  • ⁇ .Metal support film, for example, Sandvik software
  • any metal sheet with a thickness of 30-50mk is wound on the drum and is fixed. Boom is growing. With this, the plasma moves along the drum, ensuring
  • Table 1 shows the receipt of property and property arising from the proposed sale in comparison with the offer.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

L'invention concerne des procédés de fabrication d'un revêtement par la pulvérisation d'un matériau en fusion et peut s'utiliser dans de diverses branches de l'industrie chimique, de la production d'énergie, du génie mécanique et de la métallurgie. Le revêtement composite fabriqué selon ce procédé peut s'utiliser en tant que substrat destiné à l'application de divers revêtements, par exemples, de revêtements polymères, et dans l'imprégnation par de diverses compositions, y compris les compositions catalytiques. Elle vise à produire un revêtement présentant de meilleures caractéristiques techniques et d'utilisation telles que l'adhérence et les dimensions de la surface libre que les revêtements existants, ce qui permet d'obtenir un revêtement ayant une meilleure qualité et une meilleure fiabilité. L'invention vise également une technologie plus simple et efficace d'application de revêtements. A cet effet, on introduit dans la composition un matériau assurant le développement d'une microstructure de revêtement, une poudre composite comportant un revêtement de type d'hydrotalcite. L'invention porte aussi sur la teneur qualitative et quantitative de la composition. Le revêtement ayant la composition décrite dans l'invention est pulvérisée sur la surface métallique ou céramique, et on effectue le traitement thermique par recuit. L'invention concerne aussi un procédé de traitement thermique et des régimes dudit traitement.
PCT/RU2003/000091 2003-03-06 2003-03-06 Procede de fabrication d'un revetement composite WO2004079035A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/RU2003/000091 WO2004079035A1 (fr) 2003-03-06 2003-03-06 Procede de fabrication d'un revetement composite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/RU2003/000091 WO2004079035A1 (fr) 2003-03-06 2003-03-06 Procede de fabrication d'un revetement composite

Publications (1)

Publication Number Publication Date
WO2004079035A1 true WO2004079035A1 (fr) 2004-09-16

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0853746A (ja) * 1994-03-31 1996-02-27 Agency Of Ind Science & Technol 減圧プラズマ溶射によるAl系合金への高性能摺動被膜の形成方法
RU97101513A (ru) * 1997-01-24 1999-02-10 А.П. Хинский Способ изготовления композиционного покрытия
US20010003631A1 (en) * 1999-12-13 2001-06-14 Sulzer Innotec Ag Method for sealing a porous layer at the surface of a body, in particular for the sealing of a thermal spray layer
US6254938B1 (en) * 1997-04-21 2001-07-03 Ltu, Llc Spraying method for applying a porous coating to a substrate
US20010019781A1 (en) * 1999-11-23 2001-09-06 Hasz Wayne Charles Coating system for providing environmental protection to a metal substrate, and related processes

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0853746A (ja) * 1994-03-31 1996-02-27 Agency Of Ind Science & Technol 減圧プラズマ溶射によるAl系合金への高性能摺動被膜の形成方法
RU97101513A (ru) * 1997-01-24 1999-02-10 А.П. Хинский Способ изготовления композиционного покрытия
US6254938B1 (en) * 1997-04-21 2001-07-03 Ltu, Llc Spraying method for applying a porous coating to a substrate
US20010019781A1 (en) * 1999-11-23 2001-09-06 Hasz Wayne Charles Coating system for providing environmental protection to a metal substrate, and related processes
US20010003631A1 (en) * 1999-12-13 2001-06-14 Sulzer Innotec Ag Method for sealing a porous layer at the surface of a body, in particular for the sealing of a thermal spray layer

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