WO2004067581A3 - Katalysatorkombination, isotaktische polymere sowie ein verfahren zur herstellung von linearen isotaktischen polymeren und dessen verwendung - Google Patents

Katalysatorkombination, isotaktische polymere sowie ein verfahren zur herstellung von linearen isotaktischen polymeren und dessen verwendung Download PDF

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Publication number
WO2004067581A3
WO2004067581A3 PCT/EP2004/000694 EP2004000694W WO2004067581A3 WO 2004067581 A3 WO2004067581 A3 WO 2004067581A3 EP 2004000694 W EP2004000694 W EP 2004000694W WO 2004067581 A3 WO2004067581 A3 WO 2004067581A3
Authority
WO
WIPO (PCT)
Prior art keywords
polymers
membered
isotactic
catalyst combination
isotactic polymers
Prior art date
Application number
PCT/EP2004/000694
Other languages
English (en)
French (fr)
Other versions
WO2004067581A2 (de
Inventor
Bernhard Rieger
Sandra Deisenhofer
Original Assignee
Inventis Technologies Gmbh
Bernhard Rieger
Sandra Deisenhofer
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inventis Technologies Gmbh, Bernhard Rieger, Sandra Deisenhofer filed Critical Inventis Technologies Gmbh
Priority to JP2006501622A priority Critical patent/JP2006517991A/ja
Priority to US10/543,703 priority patent/US7381679B2/en
Priority to CA002514645A priority patent/CA2514645A1/en
Priority to EP04705387A priority patent/EP1590376A2/de
Publication of WO2004067581A2 publication Critical patent/WO2004067581A2/de
Publication of WO2004067581A3 publication Critical patent/WO2004067581A3/de
Priority to NO20053659A priority patent/NO20053659L/no
Priority to HK06110747.9A priority patent/HK1090935A1/xx

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Die vorliegende Erfindung betrifft eine Katalysator-kombin ation zur Herstellung von linearen isotaktischen Polymeren enthaltend einen asyminetrischen Metallkomplex gemäß Formel (I) sowie einen Aktivator: wobei R6-R9 Wasserstoff, lineares oder verzweigtes C1- bis C10-Alkyl, 5-bis 7- gliedriges Cycloalkyl, das seinerseits einen oder mehrere C1- bis C6-Alkylreste als Substituent tragen kann, C6- bis C18-Aryl, Arylalkyl oder Alkylaryl, mit der Maßgabe, dass die Reste R6/R7 oder R8/R9 in 5- bis 7- gliedrige ankondensierte Cycloalkyl- oder Arylringe eingebunden sind, wobei diese substituiert, mit Heteroatomen unterbrochen und/oder mit einem weiteren Cycloalkyl-und/oder Arylring verbunden sein können.
PCT/EP2004/000694 2003-01-28 2004-01-27 Katalysatorkombination, isotaktische polymere sowie ein verfahren zur herstellung von linearen isotaktischen polymeren und dessen verwendung WO2004067581A2 (de)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2006501622A JP2006517991A (ja) 2003-01-28 2004-01-27 触媒コンビネーション、アイソタクティックポリマー、ならびに線状のアイソタクティックポリマーの生成方法およびその使用
US10/543,703 US7381679B2 (en) 2003-01-28 2004-01-27 Catalyst combination, isotactic polymers and also a method for producing linear isotactic polymers and the use thereof
CA002514645A CA2514645A1 (en) 2003-01-28 2004-01-27 Catalyst combination, isotactic polymers, method for producing linear isotactic polymers, and the use of said polymers
EP04705387A EP1590376A2 (de) 2003-01-28 2004-01-27 Katalysatorkombination, isotaktische polymere sowie ein verfahren zur herstellung von linearen isotaktischen polymeren und dessen verwendung
NO20053659A NO20053659L (no) 2003-01-28 2005-07-27 Katalysatorkombinasjon, isotaktiske polymerer, fremgangsmate for fremstilling av lineaereisotaktiske polymerer, samt anvendeIse av polymerene
HK06110747.9A HK1090935A1 (en) 2003-01-28 2006-09-27 Catalyst combination, isotactic polymers, method for producing linear isotactic polymers, and the use of said polymers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10303225A DE10303225A1 (de) 2003-01-28 2003-01-28 Katalysatorkombination, isotaktische Polymere sowie ein Verfahren zur Herstellung von linearen isotaktischen Polymeren und dessen Verwendung
DE10303225.8 2003-01-28

Publications (2)

Publication Number Publication Date
WO2004067581A2 WO2004067581A2 (de) 2004-08-12
WO2004067581A3 true WO2004067581A3 (de) 2004-12-09

Family

ID=32667893

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2004/000694 WO2004067581A2 (de) 2003-01-28 2004-01-27 Katalysatorkombination, isotaktische polymere sowie ein verfahren zur herstellung von linearen isotaktischen polymeren und dessen verwendung

Country Status (9)

Country Link
US (1) US7381679B2 (de)
EP (1) EP1590376A2 (de)
JP (1) JP2006517991A (de)
CN (2) CN101029102A (de)
CA (1) CA2514645A1 (de)
DE (1) DE10303225A1 (de)
HK (1) HK1090935A1 (de)
NO (1) NO20053659L (de)
WO (1) WO2004067581A2 (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016171807A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
KR101910701B1 (ko) * 2015-07-02 2018-10-22 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR101917911B1 (ko) 2015-07-02 2018-11-12 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
US9803037B1 (en) 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
KR101920401B1 (ko) * 2016-12-06 2019-02-08 한화케미칼 주식회사 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀
US10703838B2 (en) 2017-10-31 2020-07-07 Exxonmobil Chemical Patents Inc. Mixed catalyst systems with four metallocenes on a single support
CN112004841B (zh) * 2018-03-19 2023-05-26 埃克森美孚化学专利公司 使用四氢引达省基催化剂体系制备具有低的玻璃化转变温度的高丙烯含量pedm的方法
US11053329B2 (en) 2018-03-19 2021-07-06 Exxonmobil Chemical Patents Inc. Multiple non-coordinating anion activators for propylene-ethylene-diene monomer polymerization reactions
CN112135831B (zh) * 2018-12-12 2023-05-16 Lg化学株式会社 过渡金属化合物，包含该过渡金属化合物的催化剂组合物以及使用该催化剂组合物制备聚合物的方法

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JP3405784B2 (ja) * 1993-09-28 2003-05-12 昭和電工株式会社 ポリオレフィンの製造方法
JP3408594B2 (ja) * 1993-10-22 2003-05-19 昭和電工株式会社 ポリオレフィンの製造方法
DE19816154A1 (de) * 1998-04-09 1999-10-21 Bernhard Rieger Lineare isotaktische Polymere, Verfahren zu ihrer Herstellung und deren Verwendung sowie eine Katalysatorkombination
JP4358470B2 (ja) * 1999-12-28 2009-11-04 バセル テクノロジー カンパニー ビー．ブイ． メタロセン化合物、リガンド、触媒、ポリマーの製造方法及びプロピレンホモポリマー
KR100675053B1 (ko) * 2000-01-18 2007-01-26 바셀 테크놀로지 캄파니 비이브이 실질적으로 무정형인 프로필렌 기재 중합체의 제조 방법

Non-Patent Citations (2)

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DIETRICH ET AL: "Control of Stereoerror Formation with High-Activity Dual-Side Zirconocene Catalysts: A Novel Strategy To Design the Properties of Thermoplastic Elastic Polypropenes", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, US JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, US, vol. 121, 1999, pages 4348 - 4355, XP002110148 *
KUKRAL J. ET AL.: "High molecular weight polypropylene elastomers via dual-side zirconocenes dichlorides", MACROMOL. SYMP., vol. 177, 2002, pages 71 - 86, XP001125914 *

Also Published As

Publication number Publication date
CA2514645A1 (en) 2004-08-12
DE10303225A1 (de) 2004-08-05
JP2006517991A (ja) 2006-08-03
NO20053659D0 (no) 2005-07-27
US7381679B2 (en) 2008-06-03
US20070015657A1 (en) 2007-01-18
CN1753914A (zh) 2006-03-29
CN100457784C (zh) 2009-02-04
HK1090935A1 (en) 2007-01-05
WO2004067581A2 (de) 2004-08-12
NO20053659L (no) 2005-10-28
CN101029102A (zh) 2007-09-05
EP1590376A2 (de) 2005-11-02

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