WO2004052670A2 - Vehicule dote d'une chambre de generation d'hydrogene - Google Patents
Vehicule dote d'une chambre de generation d'hydrogene Download PDFInfo
- Publication number
- WO2004052670A2 WO2004052670A2 PCT/IB2003/005568 IB0305568W WO2004052670A2 WO 2004052670 A2 WO2004052670 A2 WO 2004052670A2 IB 0305568 W IB0305568 W IB 0305568W WO 2004052670 A2 WO2004052670 A2 WO 2004052670A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- water
- aluminium
- hydrogen
- hgc
- metal
- Prior art date
Links
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 24
- 239000001257 hydrogen Substances 0.000 title claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000004411 aluminium Substances 0.000 claims abstract description 20
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 20
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000446 fuel Substances 0.000 claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 14
- 239000002184 metal Substances 0.000 claims abstract description 14
- 239000000969 carrier Substances 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 16
- 239000011734 sodium Substances 0.000 abstract description 16
- 229910052708 sodium Inorganic materials 0.000 abstract description 16
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 230000005611 electricity Effects 0.000 description 7
- 239000008188 pellet Substances 0.000 description 7
- 239000000843 powder Substances 0.000 description 5
- 239000011324 bead Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000809 air pollutant Substances 0.000 description 1
- 231100001243 air pollutant Toxicity 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Definitions
- This invention relates to an HGC, hydrogen generation chamber, installed on a vehicle for supplying hydrogen on the spot as fuel.
- Hydrogen is a desirable environmental fuel which produces no carbon dioxide or air pollutants.
- massive production of hydrogen depends on available cheap electricity supply for electrolysis and an efficient transport/storage system, liquefaction and compression difficulty apart.
- an HGC in which water is used to react with molten metal to release hydrogen for use on the spot (for example in vehicles/carriers).
- the chamber has a water infeed control system and a molten metal supply system and a metal sprinkler (for example, for aluminium pellets/powder).
- a rotating device for example, containing aluminium powder or mixed metal powder in non-piercing bullets (i.e. bullets not lined or guided as shots) enables metal bullets to be exploded (with explosives) or dropped onto the water.
- Purifier for the water used are also present. The purifier may be attached to exhaust water from combustion to provide water for recycling.
- the HGC is installed on a fuel vehicle (with the necessary adaptation device for hydrogen as fuel.)) Pressure control pump/s for fluid movement to designated areas/chambers are present.
- Figure 1 shows in perspective, a gas fuel vehicle 00, looking from the side view with the fuel supply tank (FT) 01 and the HGC 02 exposed while other parts are not shown.
- Figure 2 shows in perspective with its key features exposed: the HGC 02, has a trough (WT) 021 containing water, and a metal sprinkler (MS) 03 with a rotating disc (RD) 04. Fluid valves (FN) 05,051,052,053 etc. are present for water and gas movement control.
- WT trough
- MS metal sprinkler
- RD rotating disc
- FIG. 3 shows in perspective, with its key features exposed, an alternative HGC.
- HGC02 has an FN 053 leading to FT 01 (with feed ducts to the combustion system not shown).
- Feed ducts 041,042 connected to aluminium pellet and sodium pellet suppliers (not shown) allows aluminium and sodium pellets to get in touch with water in WT 021 so that aluminium is in touch with water supplied by a water storage/collection tank (not shown) at high temperature because of the heat generated by sodium and water reaction.
- a rotating disc or gun system ejects bullets of aluminium and sodium (in wax cover) into hot water.
- a heater with temperature control is present to supply the heat for the wax cover to melt.
- Outlet 06 allows reaction precipitates and unwanted water to run out of HGC 02 while FN 05 allows water to enter HGC 02.
- a water collection system (WCS), not shown, can be attached to the exhaust pipe (not shown) for re-cycling via FV 05.
- Aluminium or mixed metal pellets/powder e.g. sodium, calcium, etc.
- Aluminium or mixed metal pellets/powder e.g. sodium, calcium, etc.
- a mounting device not shown
- a feed device not shown
- a bullet storage system not shown
- the bullets are released onto hot water in WT 021 via a release control device (not shown). (Used bullet case disposal/storage device is present but not shown.)
- the hydrogen generated in HGC 02 is passed into FT 01 via FN 053 (with the help of a pressure control device, not shown).
- FIG. 5 Similar shows a reaction chamber RC 08 instead of a hopper.
- RC 08 in this case replaces HGC 02 and conveys hydrogen produced via valve 053 to FT 01.
- Purified water enters RC 08 via valve 05.
- Aluminium and sodium pellets are contained in a uniform rod 16 in small chambers (e.g. ceramics coated chambers) along the rod 16 with openings 10 and 11 respectively.
- a screw system 15 (for example operated by hydraulics) helps propel the forward and backward movement of the rod 16.
- Rod 16 has a groove (not shown) so that as it moves past the knife-edged pointers 12, the protective covering (such as wax) for openings 10 and 11 are removed.) (Empty separation spaces for the metals along rod 16 are filled with inert gas or hydrogen.)
- Figure 5 similarly shows RC 08 with rod 16 containing one kind of metal such as aluminium: an electric melting system is present but not shown: instead of melting with the heat of chemical explosion or sodium reaction,aluminium is molten by electricity to react with water. In the case of sodium fuel, electricity is not necessary.)
- Pressure control such as pressure control valves are present and not shown.
- Water recollection, purification and re-supply systems for exhaust water are present and not shown.
- the wax covering sodium is removed in an alternative device by a heating device.
- Sodium metal with protective separation material e.g. wax
- the beaded wires are cut by a cutting device (e.g. a rotating cutter) as they are pushed into HGC 02 by automatic device.
- the beaded wires also have grooves covered with wax so that the wax is removed by a scratching edge to expose the sodium to water.
- aluminium beads with sodium metal core is the use of apatinium beads/powder and sodium beads (coated in wax). Aluminium and sodium beads enter a collector/hopper via different ducts in controlled quantities (through control device) to meet water in a hot catcher to remove wax. The reaction between sodium and water produces the heat to melt the aluminium to release heat and hydrogen.
- the HGC 02 is detachable via screw catch mechanism and a device exists to cap up the gas conveying ducts so that via a control system, the vehicle/carrier now runs on electricity supplied by a detachable battery system in the case of hybrid vehicles using fuel and electricity.
- a detachable rechargeable battery system is present so that the vehicle can run on battery electricity with or without energy supply from hydrogen burning.
- an adapting device for hydrogen burning is mounted to enable hydrogen to be used.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Fuel Cell (AREA)
- Electric Propulsion And Braking For Vehicles (AREA)
- Arrangement Or Mounting Of Propulsion Units For Vehicles (AREA)
Abstract
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2003286291A AU2003286291A1 (en) | 2002-12-09 | 2003-12-03 | Vehicle with hydrogen generation chamber |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0228598.9 | 2002-12-09 | ||
GB0228598A GB0228598D0 (en) | 2002-07-31 | 2002-12-09 | Waste gas energy generator |
Publications (3)
Publication Number | Publication Date |
---|---|
WO2004052670A2 true WO2004052670A2 (fr) | 2004-06-24 |
WO2004052670A3 WO2004052670A3 (fr) | 2004-09-10 |
WO2004052670B1 WO2004052670B1 (fr) | 2004-10-07 |
Family
ID=32482481
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2003/005568 WO2004052670A2 (fr) | 2002-12-09 | 2003-12-03 | Vehicule dote d'une chambre de generation d'hydrogene |
Country Status (2)
Country | Link |
---|---|
AU (1) | AU2003286291A1 (fr) |
WO (1) | WO2004052670A2 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7951349B2 (en) * | 2006-05-08 | 2011-05-31 | The California Institute Of Technology | Method and system for storing and generating hydrogen |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2288548A1 (fr) * | 1974-10-21 | 1976-05-21 | Broult Etienne | Reacteur pour carburation de synthese a production d'hydrogene |
GB1563453A (en) * | 1977-11-02 | 1980-03-26 | Inst Mashinostr Akad Nauk Ukra | Method of and apparatus for supplying gaseous fuel to internal combustion engines |
US4698974A (en) * | 1984-12-13 | 1987-10-13 | The Garrett Corporation | Internal combustion closed rankine cycle steam engine |
CN2130720Y (zh) * | 1992-04-12 | 1993-04-28 | 曾柱辉 | 汽车氢气箱 |
-
2003
- 2003-12-03 AU AU2003286291A patent/AU2003286291A1/en not_active Abandoned
- 2003-12-03 WO PCT/IB2003/005568 patent/WO2004052670A2/fr not_active Application Discontinuation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2288548A1 (fr) * | 1974-10-21 | 1976-05-21 | Broult Etienne | Reacteur pour carburation de synthese a production d'hydrogene |
GB1563453A (en) * | 1977-11-02 | 1980-03-26 | Inst Mashinostr Akad Nauk Ukra | Method of and apparatus for supplying gaseous fuel to internal combustion engines |
US4698974A (en) * | 1984-12-13 | 1987-10-13 | The Garrett Corporation | Internal combustion closed rankine cycle steam engine |
CN2130720Y (zh) * | 1992-04-12 | 1993-04-28 | 曾柱辉 | 汽车氢气箱 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7951349B2 (en) * | 2006-05-08 | 2011-05-31 | The California Institute Of Technology | Method and system for storing and generating hydrogen |
Also Published As
Publication number | Publication date |
---|---|
AU2003286291A1 (en) | 2004-06-30 |
WO2004052670B1 (fr) | 2004-10-07 |
WO2004052670A3 (fr) | 2004-09-10 |
AU2003286291A8 (en) | 2004-06-30 |
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