WO2004048456A2 - Procede pour ameliorer les proprietes physico-chimiques de compositions de bitume ainsi que de nouvelles compositions de bitume aux proprietes ameliorees et leurs utilisations - Google Patents
Procede pour ameliorer les proprietes physico-chimiques de compositions de bitume ainsi que de nouvelles compositions de bitume aux proprietes ameliorees et leurs utilisations Download PDFInfo
- Publication number
- WO2004048456A2 WO2004048456A2 PCT/FR2003/003446 FR0303446W WO2004048456A2 WO 2004048456 A2 WO2004048456 A2 WO 2004048456A2 FR 0303446 W FR0303446 W FR 0303446W WO 2004048456 A2 WO2004048456 A2 WO 2004048456A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- bitumen
- silica
- composition
- amorphous silica
- weight
- Prior art date
Links
- 239000010426 asphalt Substances 0.000 title claims abstract description 128
- 239000000203 mixture Substances 0.000 title claims abstract description 90
- 238000000034 method Methods 0.000 title claims abstract description 57
- 239000000126 substance Substances 0.000 title claims abstract 3
- 230000002708 enhancing effect Effects 0.000 title abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 150
- 239000000377 silicon dioxide Substances 0.000 claims description 58
- 238000003756 stirring Methods 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000000839 emulsion Substances 0.000 claims description 16
- 239000007822 coupling agent Substances 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 10
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000011324 bead Substances 0.000 claims description 4
- 150000004756 silanes Chemical class 0.000 claims description 4
- 150000001343 alkyl silanes Chemical class 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 239000004570 mortar (masonry) Substances 0.000 claims description 2
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 239000000654 additive Substances 0.000 description 15
- 238000002360 preparation method Methods 0.000 description 12
- 230000000996 additive effect Effects 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- 239000011148 porous material Substances 0.000 description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 7
- 229910000077 silane Inorganic materials 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 5
- 239000004593 Epoxy Substances 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- -1 various coatings Substances 0.000 description 5
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000005070 ripening Effects 0.000 description 3
- 238000006884 silylation reaction Methods 0.000 description 3
- 238000002604 ultrasonography Methods 0.000 description 3
- 101100202447 Drosophila melanogaster sav gene Proteins 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000000518 rheometry Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 description 1
- 229920000034 Plastomer Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Definitions
- the present invention relates to a process for improving the physicochemical properties of bitumen compositions as well as to new bitumen compositions with improved properties and their uses, in particular for the preparation of bituminous mixes for road surfaces.
- bitumen-type materials such as asphalt and malthe for pavements, roofing materials, various coatings, mortar and bending.
- Bitumen compositions have been prepared by adding suitable additives such as aggregates or fillers to the bitumen-like materials mentioned above.
- suitable additives such as aggregates or fillers
- Such compositions have numerous drawbacks when they are used as such for different applications: there may be mentioned in particular a high sensitivity to temperature, poor adhesion to aggregates, poor properties at low temperatures, low resistance to abrasion, low impact resistance.
- the main constituents are bituminous mixes which consist of 95% by mass of granules and 5% by mass of bitumen which serves as a binder.
- this binder is predominant on the properties of the road which is subject to three types of mechanical stress: thermal fracture, fatigue and rutting.
- thermal fracture ie bitumen
- the binder vitrifies and becomes brittle. It can then form long transverse cracks due to thermal stresses (thermal fractures) which are microcracks due to the heterogeneity of the material.
- thermal fractures thermal stresses
- microcracks due to the heterogeneity of the material.
- the roadway can still crack under the effect of fatigue. This results in a multitude of mainly longitudinal interconnected cracks.
- bitumen changes from the solid state to the viscous state, more and more fluid. Also, the repeated passage of high masses constituted by vehicles, whose heavy vehicles on the roadway contribute to deform the bitumen permanently and therefore the roadway. This phenomenon is at the origin of ruts.
- the binder also ensures the waterproofing of the roadway, thus protecting the foundations of the road.
- the main characteristics required of the road and therefore of the composition of bitumen which serves as a binder are therefore: - good resistance to cracking at low temperature (typically - 15 ° C),
- Another object of the present invention is to provide a method for improving the rheological and mechanical properties of bitumen compositions.
- Another object of the present invention is to provide a method for improving the mechanical strength of bitumen compositions at high temperatures.
- Another object of the present invention is to provide a process for improving the properties of bitumen compositions which exhibits storage facilities and good redispersibility of the additives used in bitumen compositions.
- the present invention which in fact relates to a process for improving the physicochemical properties of bitumen, characterized in that a sufficient quantity of optionally functionalized amorphous silica is added to the bitumen composition.
- the present invention also relates to a bitumen composition capable of being obtained by the process.
- the present invention also relates to a hot mix preparation process which implements the bitumen composition of the invention.
- the present invention also relates to a process for the preparation of cold mixes which implements the bitumen composition of the invention.
- the present invention relates first of all to a process for improving the physicochemical properties of bitumen, characterized in that a sufficient quantity of amorphous silica, optionally functionalized, is added to the composition of bitumen.
- the amorphous silica can be a natural silica or a synthetic silica such as precipitated silicas, silica gels or combustion silicas.
- a precipitated silica is used. It may for example be a Tixosil 38A, Tixosil 38D or Tixosil 365 silica from the company RHODIA.
- the precipitated silica may be in the form of substantially spherical beads, in particular of average size of at least 80 microns, for example at least 150 microns, obtained by means of a nozzle atomizer, as described for example in document EP 0018866. It can for example be silica called Microperle. It may for example be a Tixosil 38X or Tixosil 68 silica from the company Rhodia.
- the precipitated silica can be a highly dispersible silica, like the silicas described in documents EP 520862, WO 95/09127 or WO 95/09128, which facilitates its dispersion in bitumen and has a positive effect on the mechanical properties of the material obtained. .
- WO 95/09127 describes more precisely a precipitated silica having: a specific surface CTAB (Sr ⁇ / / B) of between 140 and 240 ⁇ g,
- S CTAB specific CTAB surface
- a highly dispersible silica mention may in particular be made of a Zl 165 MP silica or a Zl 115 MP silica from the company Rhodia.
- Amorphous silica can be silica with low water uptake.
- low water uptake is meant a water uptake of less than 6% and preferably less than 3%.
- They may be precipitated silicas described in patent application FR 01 16881 filed on December 26, 2001 by the company Rhodia, fumed silicas or partially dehydroxylated silicas by calcination or by surface treatment.
- the amorphous silica of the invention can be functionalized before it is added to the bitumen.
- silylation reaction can be carried out by a silylation reaction using a coupling agent chosen from the family of silanes.
- a coupling agent chosen from the family of silanes.
- silanes alkylsilanes or functional silanes such as amino-silanes, thiol-silanes or epoxy-silanes.
- the amount of coupling agents introduced into the amorphous silica is between 0.1 and 30% by weight relative to the weight of the amorphous silica.
- the amount of coupling agents introduced into the amorphous silica is between 5 and 15% by weight relative to the weight of the amorphous silica.
- the silylation reaction which is a grafting of the silane onto the silica can be carried out in an alcoholic medium in the presence of a catalyst.
- This catalyst can be an acid such as acetic acid, or a base such as ammonia.
- the reaction medium is then centrifuged. The mother liquors are then removed and the residue is washed with distilled water.
- a powder is recovered with a level of coupling agent of between 0.5 to 30% by weight of coupling agent relative to the total weight of the functionalized silica.
- this optionally functionalized amorphous silica of the invention is that it is very stable during storage, very easy to handle, it is very fluid, it does not clot and it is redispersed particularly well in bitumen compositions, this which facilitates the implementation of processes for preparing bitumen compositions with improved performance and processes for preparing bituminous mixes "hot” and bituminous mixes “cold”.
- the optionally functionalized silica must be added to the bitumen composition in a sufficient amount.
- the amount of optionally functionalized amorphous silica introduced into the bitumen composition is between 0.01 and 20% by weight of optionally functionalized amorphous silica relative to the total weight of the bitumen composition.
- the amount of optionally functionalized amorphous silica introduced into the bitumen composition is between 0.1 and 7% by weight of optionally functionalized amorphous silica relative to the total weight of the bitumen composition.
- bitumens to which the silica of the present invention can be added include natural bitumens, pyrobitumes and artificial bitumens. Particularly preferred bitumens are those used for pavements, such as asphalt or malthe. Even more preferably, asphalt is used.
- the first embodiment relates to a method for improving the physicochemical properties of the bitumen composition comprising the following steps: 1-the bitumen composition is heated to a temperature between 120 and 190 ° C; 2 — a sufficient amount of optionally functionalized amorphous silica is added to the bitumen composition of step 1 with stirring.
- the silica can optionally be functionalized “in situ” in the bitumen composition. That is, it is possible to add the coupling agent independently of the silica in step 2 of this process.
- the present invention also relates to a bitumen composition capable of being obtained by the process described above.
- the present invention also relates to a process for the preparation of hot mixes which implements the bitumen composition capable of being obtained by the above process.
- This process includes a step additional to the previous process which consists in adding, with stirring and at a temperature between 120 and 190 ° C, aggregates in the bitumen composition before, simultaneously, or after the addition of optionally functionalized silica from step 2.
- the aggregates are preheated to a temperature above 120 ° C.
- the present invention also relates to a bitumen composition capable of being obtained by the process described above.
- the second possible embodiment for the incorporation of the amorphous silica optionally functionalized in the bitumen composition is carried out at room temperature. It is a “cold” preparation process.
- This process includes the following steps:
- bitumen emulsion is prepared by mixing water, bitumen and an emulsifier at room temperature;
- bitumen emulsion of step 1 A sufficient quantity of amorphous silica, optionally functionalized, is incorporated into the bitumen emulsion of step 1 with stirring at room temperature; 3-the emulsion obtained in step 2 is spread to obtain a uniform layer of the mixture obtained in step 2; 4-we break the bitumen emulsion.
- the present invention also relates to a bitumen composition capable of being obtained by the process described above.
- the silica can optionally be functionalized “in situ” in the bitumen composition. That is, it is possible to add the coupling agent independently of the silica in step 2 of this process.
- the present invention also relates to a “cold” mix preparation process which implements the bitumen composition capable of being obtained by the above process.
- This process comprises a step additional to the previous process which consists in adding, with stirring and at room temperature, aggregates in the bitumen composition after the addition of optionally functionalized silica from step 2.
- the present invention also relates to a bitumen composition capable of being obtained by the process described above.
- This process comprises the following stages: 1-the bitumen composition is heated to a temperature between 120 and 190 ° C;
- An emulsion of the bitumen obtained in step 2 is prepared by mixing water, said bitumen and an emulsifier; 4-the emulsion obtained in step 3 is spread to obtain a uniform layer of the mixture obtained in step 3;
- the present invention also relates to a “cold” mix preparation process which implements the bitumen composition capable of being obtained by the above process.
- This process includes a step additional to the previous process which consists in adding, with stirring and at room temperature, aggregates in the bitumen emulsion obtained in step 3 of the process.
- the amount of optionally functionalized amorphous silica introduced into the bitumen composition is between 0.01 and 20% by weight of optionally functionalized amorphous silica relative to the total weight of the bitumen composition.
- the amount of optionally functionalized amorphous silica introduced into the bitumen composition is between 0.1 and 7% by weight of optionally functionalized amorphous silica relative to the total weight of the bitumen composition.
- bitumen compositions of the invention may also contain other additives commonly used in the field of bitumen.
- the emulsifiers used to emulsify bitumen are emulsifiers usually used by a person skilled in the art in this technical field.
- bitumen used is previously oxidized hot by contact with air.
- Example A Preparation of a bitumen composition
- the silica used is a Zl 165 MP silica from the company Rhodia. It is used as it is or it undergoes a preliminary treatment.
- the mixture After ripening, the mixture is centrifuged and washed 5 times with the same volume of water.
- % N 0.37 level of coupling agent used in the powder: 6.5% by weight of silane relative to the total weight of the functionalized silica.
- the mixture After ripening, the mixture is centrifuged and washed 5 times with the same volume of water.
- Bitumen grade 70/100 (Pen) was used for the tests. Origin bitumen
- bitumen is removed from a barrel, then placed in a beaker: the beaker is then heated on a hot plate to 170 ° C.
- the mixture is then maintained at 170 ° C. for approximately 15 minutes with vigorous stirring using a rotary agitator (260 rpm).
- the temperature is kept strictly below 180 ° C, so as not to alter the characteristics of the bitumen.
- the mixture is kept for 5 minutes at approximately 170 ° C. under slow speed stirring in order to eliminate any air bubbles which may have formed.
- the mixing is then finished, and ready for use.
- Example B Evaluation of bitumen compositions 1.2 / Rheology tests The rheological characterization of the additive bitumen is made according to a procedure derived from SHRP standards: DSR Dynamic Shear Rheometer tests (AASHTO TP5-98).
- the rheology tests are carried out in annular shear, using a Metravib viscoelasticimeter.
- the liquid bitumen is introduced into the shear cell heated beforehand to 110 ° C. When the temperature has dropped to around 45 ° C, the bitumen no longer flows and the entire structure is tightened and ready for measurements.
- the bitumen sample has a thickness of 1mm on a height of 5mm (cylindrical geometry).
- the tests are carried out at different temperatures (30, 40, 50 and 60 ° C) and in a frequency range making it possible to demonstrate the behavior of the material: 7.8 - 15.6 - 31.2 - 62.5 - 125 and 200 Hz.
- the results obtained relate to the Coulomb module (complex module) G *, the elastic components G 'and viscous G ", and the phase angle ⁇ . These results can be represented either at iso-frequency as a function of temperature, or at iso-temperature (isotherms) as a function of frequency.
- Table 1 collects the values measured at 60 ° C, for a frequency of 7.8 Hz.
- phase angle ⁇ remains substantially constant, except for a rate of 15% functionalized epoxy silica which reflects a more elastic behavior of the bitumen additive.
- Table 2 collects the values measured at 25 ° C (and 40 ° C for the phase angle ⁇ ), for a frequency of 7.8 Hz.
- the critical temperature Te is determined according to the criterion described in the SHRP procedure
- Te is the temperature for which the ratio G * / sin ⁇ is greater than 1000 Pa.
- the thermal suceptibility of bitumen is determined by an IS index: thermal susceptibility index.
- the critical temperature Te is greatly increased in the presence of 5% silica. Similarly, there is a significant drop in the thermal susceptibility IS. The phase angle ⁇ (at 40 ° C) is significantly reduced, which translates into more elastic behavior of the bitumen with additives.
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2003295050A AU2003295050A1 (en) | 2002-11-22 | 2003-11-21 | Method for enhancing the physico-chemical properties of bitumen compositions and novel bitumen compositions with enhanced properties and their uses |
US10/540,783 US7335251B2 (en) | 2002-11-22 | 2003-11-21 | Method for enhancing the physico-chemical properties of bitumen compositions and novel bitumen compositions with enhanced properties and their uses |
CA002507114A CA2507114A1 (fr) | 2002-11-22 | 2003-11-21 | Procede pour ameliorer les proprietes physico-chimiques de compositions de bitume ainsi que de nouvelles compositions de bitume aux proprietes ameliorees et leurs utilisations |
MXPA05005484A MXPA05005484A (es) | 2002-11-22 | 2003-11-21 | Metodo para mejorar las propiedaes fisico-quimicas de composiciones bituminosas y novedosas composiciones bituminosas con propiedades mejoradas y sus usos. |
BR0316484-5A BR0316484A (pt) | 2002-11-22 | 2003-11-21 | Processo para melhorar as propriedades fìsico-quìmicas de composições de betume e composições de betume com propriedadades melhoradas e seus usos |
EP03786044A EP1565521A2 (fr) | 2002-11-22 | 2003-11-21 | Procede pour ameliorer les proprietes physico-chimiques de compositions de bitume ainsi que de nouvelles compositions de bitume aux proprietes ameliorees et leurs utilisations |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0214677A FR2847584A1 (fr) | 2002-11-22 | 2002-11-22 | Procede pour ameliorer les proprietes physico-chimiques de compositions de bitume ainsi que de nouvelles compositions de bitume aux proprietes ameliorees et leurs utilisations |
FR02/14677 | 2002-11-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2004048456A2 true WO2004048456A2 (fr) | 2004-06-10 |
WO2004048456A3 WO2004048456A3 (fr) | 2004-10-21 |
Family
ID=32241530
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2003/003446 WO2004048456A2 (fr) | 2002-11-22 | 2003-11-21 | Procede pour ameliorer les proprietes physico-chimiques de compositions de bitume ainsi que de nouvelles compositions de bitume aux proprietes ameliorees et leurs utilisations |
Country Status (8)
Country | Link |
---|---|
US (1) | US7335251B2 (fr) |
EP (1) | EP1565521A2 (fr) |
AU (1) | AU2003295050A1 (fr) |
BR (1) | BR0316484A (fr) |
CA (1) | CA2507114A1 (fr) |
FR (1) | FR2847584A1 (fr) |
MX (1) | MXPA05005484A (fr) |
WO (1) | WO2004048456A2 (fr) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8454739B2 (en) | 2005-09-12 | 2013-06-04 | Alm Holding Co. | Bituminous paving composition and process for bituminous paving |
US8454740B2 (en) * | 2005-09-12 | 2013-06-04 | Alm Holding Co. | Bituminous paving composition and process for bituminous paving |
CN101765641B (zh) | 2007-07-26 | 2016-09-21 | 阿克佐诺贝尔股份有限公司 | 沥青的粘附和粘结改性剂 |
US7815725B2 (en) | 2007-09-07 | 2010-10-19 | Alm Holding Co. | Warm asphalt binder compositions containing lubricating agents |
EP2062943A1 (fr) * | 2007-11-14 | 2009-05-27 | Akzo Nobel N.V. | Modificateurs d'asphalte pour des applications de mélanges chauds comprenant un promoteur d'adhésion |
US7902277B2 (en) | 2008-02-22 | 2011-03-08 | Alm Holding Co. | Processing bituminous mixtures for paving at reduced temperatures |
MX367196B (es) | 2008-08-05 | 2019-08-08 | Alm Holding Co | Proceso para el reciclamiento frio en el sitio utilizando asfalto en espuma y aditivo de lubricacion. |
AU2010233320A1 (en) * | 2009-04-07 | 2011-11-24 | D.S.I - Dimona Silica Industries Ltd. | Composition for improving the stability and operational performance and reducing the environmental impact of asphalt mixes |
WO2011074003A2 (fr) | 2009-12-14 | 2011-06-23 | Bharat Petroleum Corporation Ltd. | Compositions de bitume modifié à la poudrette de caoutchouc et procédé associé |
US20150291849A1 (en) | 2014-04-10 | 2015-10-15 | Regents Of The University Of Minnesota | Compositions including asphalt component and graphite component |
CN104559264A (zh) * | 2015-01-17 | 2015-04-29 | 吉林大学 | 一种scas改性沥青及其制备方法 |
CN107674238B (zh) * | 2017-10-10 | 2020-07-03 | 山西省交通科学研究院 | 一种废旧橡胶粉表面改性方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0048792A1 (fr) * | 1980-09-27 | 1982-04-07 | Degussa Aktiengesellschaft | Composition d'asphalte coulé |
US4410589A (en) * | 1977-12-13 | 1983-10-18 | Degussa Aktiengesellschaft | Process for improving the mineral asphalt coatings for streets and paths and products |
US5304243A (en) * | 1990-09-04 | 1994-04-19 | Agency Of Industrial Science & Technology | Method of producing organic group modified silica particles |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2941048A1 (de) | 1979-10-10 | 1981-04-23 | Schering Ag, 1000 Berlin Und 4619 Bergkamen | Verfahren zur herstellung von organomagnesiumalkoxiden |
US4410489A (en) * | 1981-07-17 | 1983-10-18 | Cabot Corporation | High chromium nickel base alloys |
US5667577A (en) * | 1995-03-24 | 1997-09-16 | Witco Corporation | Filled asphalt emulsions containing betaine emulsifier |
US6103000A (en) * | 1997-12-31 | 2000-08-15 | Saramco, Inc. | Polyphenolic surfactant compositions as universal bitumen/water emulsifiers |
FR2841561B1 (fr) * | 2002-07-01 | 2004-08-06 | Rhodia Cons Spec Ltd | Produit bitumineux et son procede de preparation |
-
2002
- 2002-11-22 FR FR0214677A patent/FR2847584A1/fr active Pending
-
2003
- 2003-11-21 EP EP03786044A patent/EP1565521A2/fr not_active Withdrawn
- 2003-11-21 CA CA002507114A patent/CA2507114A1/fr not_active Abandoned
- 2003-11-21 WO PCT/FR2003/003446 patent/WO2004048456A2/fr not_active Application Discontinuation
- 2003-11-21 BR BR0316484-5A patent/BR0316484A/pt not_active IP Right Cessation
- 2003-11-21 US US10/540,783 patent/US7335251B2/en not_active Expired - Fee Related
- 2003-11-21 MX MXPA05005484A patent/MXPA05005484A/es unknown
- 2003-11-21 AU AU2003295050A patent/AU2003295050A1/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4410589A (en) * | 1977-12-13 | 1983-10-18 | Degussa Aktiengesellschaft | Process for improving the mineral asphalt coatings for streets and paths and products |
EP0048792A1 (fr) * | 1980-09-27 | 1982-04-07 | Degussa Aktiengesellschaft | Composition d'asphalte coulé |
US5304243A (en) * | 1990-09-04 | 1994-04-19 | Agency Of Industrial Science & Technology | Method of producing organic group modified silica particles |
Also Published As
Publication number | Publication date |
---|---|
AU2003295050A8 (en) | 2004-06-18 |
US20060169173A1 (en) | 2006-08-03 |
FR2847584A1 (fr) | 2004-05-28 |
AU2003295050A1 (en) | 2004-06-18 |
EP1565521A2 (fr) | 2005-08-24 |
WO2004048456A3 (fr) | 2004-10-21 |
BR0316484A (pt) | 2005-10-11 |
MXPA05005484A (es) | 2006-05-25 |
CA2507114A1 (fr) | 2004-06-10 |
US7335251B2 (en) | 2008-02-26 |
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